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1.
Abstract— The oxidized CV3 chondrites can be divided into two major subgroups or lithologies, Bali-like (CV3oxB) and Allende-like (CV3oxA), in which chondrules, calcium-aluminum-rich inclusions (CAIs) and matrices show characteristic alteration features (Weisberg et al, 1997; Krot et al, 1997d; Kimura and Ikeda, 1997). The CV3oxB lithology is present in Bali, Kaba, parts of the Mokoia breccia and, possibly, in Grosnaja and Allan Hills (ALH) 85006. It is characterized by the presence of the secondary low-Ca phyllosilicates (saponite and sodium phlogopite), magnetite, Ni-rich sulfides, fayalite (Fa>90), Ca-Fe-rich pyroxenes (Fs10–50Wo45–50) and andradite. Phyllosilicates replace primary Ca-rich minerals in chondrules and CAIs, which suggests mobilization of Ca during aqueous alteration. Magnetite nodules are replaced to various degrees by fayalite, Ca-Fe-rich pyroxenes and minor andradite. Fayalite veins crosscut fine-grained rims around chondrules and extend into the matrix. Thermodynamic analysis of the observed reactions indicates that they could have occurred at relatively low temperatures (<300 °C) in the presence of aqueous solutions. Oxygen isotopic compositions of the coexisting magnetite and fayalite plot close to the terrestrial fractionation line with large Δ18Ofayalite-magnetite fractionation (～20%). We infer that phyllosilicates, magnetite, fayalite, Ca-Fe-rich pyroxenes and andradite formed at relatively low temperatures (<300 °C) by fluid-rock interaction in an asteroidal environment. Secondary fayalite and phyllosilicates are virtually absent in chondrules and CAIs in the CV3oxA lithology, which is present in Allende and its dark inclusions, Axtell, ALHA81258, ALH 84028, Lewis Cliff (LEW) 86006, and parts of the Mokoia and Vigarano breccias. Instead secondary nepheline, sodalite, and fayalitic olivine are common. Fayalitic olivine in chondrules replaces low-Ca pyroxenes and rims and veins forsterite grains; it also forms coarse lath-shaped grains in matrix. Secondary Ca-Fe-rich pyroxenes are abundant. We infer that the CV3oxA lithology experienced alteration at higher temperatures than the CV3oxB lithology. The presence of the reduced and CV3oxA lithologies in the Vigarano breccia and CV3oxA and CV3oXB lithologies in the Mokoia breccia indicates that all CV3 chondrites came from one heterogeneously altered asteroid. The metamorphosed clasts in Mokoia (Krot and Hutcheon, 1997) may be rare samples of the hotter interior of the CV asteroid. We conclude that the alteration features observed in the oxidized CV3 chondrites resulted from the fluid-rock interaction in an asteroid during progressive metamorphism of a heterogeneous mixture of ices and anhydrous materials mineralogically similar to the reduced CV3 chondrites.  相似文献   

2.
CV (Vigarano type) carbonaceous chondrites, comprising Allende‐like (CVoxA) and Bali‐like (CVoxB) oxidized and reduced (CVred) subgroups, experienced differing degrees of fluid‐assisted thermal and shock metamorphism. The abundance and speciation of secondary minerals produced during asteroidal alteration differ among the subgroups: (1) ferroan olivine and diopside–hedenbergite solid solution pyroxenes are common in all CVs; (2) nepheline and sodalite are abundant in CVoxA, rare in CVred, and absent in CVoxB; (3) phyllosilicates and nearly pure fayalite are common in CVoxB, rare in CVred, and virtually absent in CVoxA; (4) andradite, magnetite, and Fe‐Ni‐sulfides are common in oxidized CVs, but rare in reduced CVs; the latter contain kirschsteinite instead. Thus, a previously unrecognized correlation exists between meteorite bulk permeabilities and porosities with the speciation of the Ca‐, Fe‐rich silicates (pyroxenes, andradite, kirschsteinite) among the CVox and CVred meteorites. The extent of secondary mineralization was controlled by the distribution of water ices, permeability, and porosity, which in turn were controlled by impacts on the asteroidal parent body. More intense shock metamorphism in the region where the reduced CVs originated decreased their porosity and permeability while simultaneously expelling intergranular ices and fluids. The mineralogy, petrography, and bulk chemical compositions of both the reduced and oxidized CV chondrites indicate that mobile elements were redistributed between Ca,Al‐rich inclusions, dark inclusions, chondrules, and matrices only locally; there is no evidence for large‐scale (>several cm) fluid transport. Published 53Mn‐53Cr ages of secondary fayalite in CV, CO, and unequilibrated ordinary chondrites, and carbonates in CI, CM, and CR chondrites are consistent with aqueous alteration initiated by heating of water ice‐bearing asteroids by decay of 26Al, not shock metamorphism.  相似文献   

3.
Abstract— We have studied an Allende dark inclusion by optical microscopy, scanning electron microscopy, electron microprobe analysis and transmission electron microscopy. The inclusion consists of chondrules, isolated olivines and matrix, which, as in the Allende host, is mainly composed of 5–20 μm long lath-shaped fayalitic grains with a narrow compositional range (Fa42 ± 2) and nepheline. Olivine phenocrysts in chondrules and isolated olivine grains show various degrees of replacement by 5–10 μm wide fayalitic rims (Fa39 ± 2) and 100–1000 μm wide translucent zones, which consist of 5–20 μm long lath-shaped fayalitic grains (Fa41 ± 1) intergrown with nepheline. These fayalitic olivines, like those in the matrix of the dark inclusion, contain 10–20 nm sized inclusions of chromite, hercynite, and Fe-Ni sulfides. The fayalitic rims around remnant olivines are texturally and compositionally identical to those in Allende host, suggesting that they have similar origins. Chondrules are surrounded by opaque rims consisting of tiny lath-shaped fayalitic olivines (<1–3 μm long) intergrown with nepheline. As in the Allende host, fayalitic olivine veins may crosscut altered chondrules, fine-grained chondrule rims and extend into the matrix, indicating that alteration occurred after accretion. We infer that fayalitic olivine rims and lath-shaped fayalites in Allende and its dark inclusions formed from phyllosilicate intermediate phases. This explanation accounts for (1) the similarity of the replacement textures observed in the dark inclusion and Allende host to aqueous alteration textures in CM chondrites; (2) the anomalously high abundances of Al and Cr and the presence of tiny inclusions of spinels and sulfides in fayalitic olivines in Allende and Allende dark inclusions; (3) abundant voids and defects in lath-shaped fayalites in the Allende dark inclusion, which may be analogous to those in partly dehydrated phyllosilicates in metamorphosed CM/CI chondrites. We conclude that the matrix and chondrule rims in Allende were largely converted to phyllosilicates and then completely dehydrated. The Allende dark inclusions experienced diverse degrees of aqueous/hydrothermal alteration prior to complete dehydration. The absence of low-Ca pyroxene in the dark inclusion and its significant replacement by fayalitic olivine in Allende is consistent with the lower resistance of low-Ca pyroxene to aqueous alteration relative to forsteritic olivine. Hydro-thermal processing of Allende probably also accounts for the low abundance of planetary noble gases and interstellar grains, and the formation of nepheline, sodalite, salite-hedenbergite pyroxenes, wollastonite, kirschsteinite and andradite in chondrules and Ca,Al-rich inclusions.  相似文献   

4.
Abstract— The CV (Vigarano‐type) chondrites are a petrologically diverse group of meteorites that are divided into the reduced and the Bali‐like and Allende‐like oxidized subgroups largely based on secondary mineralogy (Weisberg et al., 1997; Krot et al., 1998b). Some chondrules and calcium‐aluminum‐rich inclusions (CAIs) in the reduced CV chondrite Vigarano show alteration features similar to those in Allende: metal is oxidized to magnetite; low‐Ca pyroxene, forsterite, and magnetite are rimmed and veined by ferrous olivine (Fs40–50); and plagioclase mesostases and melilite are replaced by nepheline and sodalite (Sylvester et al., 1993; Kimura and Ikeda, 1996, 1997, 1998). Our petrographic observations indicate that Vigarano also contains individual chondrules, chondrule fragments, and lithic clasts of the Bali‐like oxidized CV materials. The largest lithic clast (about 1 times 2 cm in size) is composed of opaque matrix, type‐I chondrules (400–2000 μm in apparent diameter) surrounded by coarse‐grained and fine‐grained rims, and rare CAIs. The matrix‐chondrule ratio is about 1.1. Opaque nodules in chondrules in the clast consist of Cr‐poor and Cr‐rich magnetite, Ni‐ and Co‐rich metal, Ni‐poor and Ni‐rich sulfide; low‐Ni metal nodules occur only inside chondrule phenocrysts. Chromium‐poor magnetite is preferentially replaced by fayalite. Chondrule mesostases are replaced by phyllosilicates; low‐Ca pyroxene and olivine phenocrysts appear to be unaltered. Matrix in the clast consists of very fine‐grained (<1 μm) ferrous olivine, anhedral fayalite grains (Fa80–100), rounded objects of porous Ca‐Fe‐rich pyroxenes (Fs10–50Wo50), Ni‐poor sulfide, Ni‐ and Co‐rich metal, and phyllosilicates; magnetite is rare. On the basis of the presence of the Bali‐like lithified chondritic clast—in addition to individual chondrules and CAIs of both Bali‐like and Allende‐like materials—in the reduced CV chondrite Vigarano, we infer that (1) all three types of materials were mixed during regolith gardening on the CV asteroidal body, and (2) the reduced and oxidized CV materials may have originated from a single, heterogeneously altered asteroid.  相似文献   

5.
Abstract— We studied the petrography, mineralogy, bulk chemical, I-Xe, and O-isotopic compositions of three dark inclusions (E39, E53, and E80) in the reduced CV3 chondrite Efremovka. They consist of chondrules, calcium-aluminum-rich inclusions (CAIs), and fine-grained matrix. Primary minerals in chondrules and CAIs are pseudomorphed to various degrees by a mixture largely composed of abundant (>95%), fine-grained (>0.2 μm) fayalitic olivine (Fa35–42) and minor amounts of chlorite, poorly-crystalline Si-Al-rich material, and chromite; chondrule and CAI shapes and textures are well-preserved. Secondary Ca-rich minerals (Ti-andradite, kirschsteinite, Fe-diopside) are common in chondrule pseudomorphs and matrices in E39 and E80. The degree of replacement increases from E53 to E39 to E80. Fayalitic olivines are heavily strained and contain abundant voids similar to those in incompletely dehydrated phyllosilicates in metamorphosed CM and CI chondrites. Opaque nodules in chondrules consist of Ni- and Co-rich taenite, Co-rich kamacite, and wairauite; sulfides are rare; magnetite is absent. Bulk O-isotopic compositions of E39 and E53 plot in the field of aqueously altered CM chondrites, close to the terrestrial fractionation line; the more heavily altered E39 is isotopically heavier than the less altered E53. The apparent I-Xe age of E53 is 5.4 Ma earlier than Bjurböle and 5.7 ± 2.0 Ma earlier than E39. The I-Xe data are consistent with the most heavily altered dark inclusion, E39 having experienced either longer or later alteration than E53. Bulk lithophile elements in E39 and E53 most closely match those of CO chondrites, except that Ca is depleted and K and As are enriched. Both inclusions are depleted in Se by factors of 3–5 compared to mean CO, CV, CR, or CK chondrites. Zinc in E39 is lower than the mean of any carbonaceous chondrite groups, but in E53 Zn is similar to the means in CO, CV, and CK chondrites. The Efremovka dark inclusions experienced various degrees of aqueous alteration, followed by low degree thermal metamorphism in an asteroidal environment. These processes resulted in preferential oxidation of Fe from opaque nodules and formation of Ni- and Co-rich metal, metasomatic alteration of primary minerals in chondrules and CAIs, and the formation of fayalitic olivine and secondary Ca-Fe-rich minerals. Based on the observed similarities of the alteration mineralization in the Efremovka and Allende dark inclusions, we infer that the latter may have experienced similar alteration processes.  相似文献   

6.
Abstract— Fayalitic olivine (Fa32) is the major component of the matrices and dark inclusions of CV3 and other unequilibrated chondrites. It occurs most commonly as rims, veins and halos in and around chondrule silicates in the Allende-type (CV3OXA) chondrites and, to a much lesser extent, in the reduced (CV3R) and Bali-type (CV3OXB) chondrites. The olivines have distinctive platy, tabular and lath- or irregular-shaped crystals, with the ratio of the two types varying widely. In CV3OXB chondrites, matrix fayalitic olivines range up to Fag99.9; whereas, in the other CV3 chondrites, the range is much smaller. The platy and tabular anisotropic forms of the fayalitic olivines strongly suggest growth from a vapor, and the nature of the occurrences suggests that CV3 matrices are unequilibrated mixtures of nebular materials. We argue that the parent body hydration/dehydration model has numerous inconsistencies that make this hypothesis highly unlikely. These include: (1) There is no direct evidence linking fayalitic olivine to precursor phyllosilicates. (2) Dehydration of phyllosilicates cannot explain the wide range of morphologies of the fayalitic olivines. (3) Fayalitic olivine clearly predates the formation of the hydrous phases in CV3 chondrites and is one of the phases that breaks down to form phyllosilicates (Keller et al., 1994). (4) The unequilibrated nature of the matrix, including fine-scale zoning in 10 μm sized fayalitic olivine crystals, would not survive the parent body metamorphism required in the dehydration model. (5) A dark inclusion in the Ningqiang chondrite contains fayalitic olivine rimmed by glassy and microcrystalline material (Zolensky et al., 1997), which probably formed by radiation damage. This indicates that the fayalitic olivine was exposed to solar radiation in a nebular setting. (6) Some Allende chondrules contain unaltered primary, anhydrous glassy mesostasis in contact with the host matrix (e.g., Ikeda and Kimura, 1995). Chondrule mesostases would not have survived parent body hydration without becoming hydrated and would probably not survive the metamorphic heating required in the dehydration scenario. (7) Single platy and barrel-shaped crystals of fayalitic olivine are present in accretionary rims in calcium-aluminum-rich inclusions (CAIs) (MacPherson and Davis, 1997), which developed in the nebula. (8) Matrix lumps completely encased in chondrules in ordinary chondrites contain mainly fayalitic olivine (Scott et al., 1984), which indicates a nebular origin. (9) Oxygen isotopic compositions of Allende matrix and dark inclusions strongly indicate little or no hydration for Allende and its components (Clayton, 1997). We favor a nebular vaporization/recondensation model in which vaporization of chondritic dust produced a fayalite-rich vapor, followed by formation of the fayalitic olivine by direct recondensation from the vapor, epitactic growth on surfaces of existing forsterite and enstatite in chondrules, and replacement of existing forsterite and enstatite by gas-solid exchange.  相似文献   

7.
Abstract— Thermochemical equilibria are calculated in the multicomponent gas‐solution‐rock system in order to evaluate the formation conditions of fayalite, (Fe0.88–1.0Mg0.12–0)2SiO4, Fa88–100, in unequilibrated chondrites. Effects of temperature, pressure, water/rock ratio, rock composition, and progress of alteration are evaluated. The modeling shows that fayalite can form as a minor secondary and transient phase with and without aqueous solution. Fayalite can form at temperatures below ?350 °C, but only in a narrow range of water/rock ratios that designates a transition between aqueous and metamorphic conditions. Pure fayalite forms at lower temperatures, higher water/rock ratios, and elevated pressures that correspond to higher H2/H2O ratios. Lower pressure and water/rock ratios and higher temperatures favor higher Mg content in olivine. In equilibrium assemblages, fayalite usually coexists with troilite, kamacite, magnetite, chromite, Ca‐Fe pyroxene, and phyllosilicates. Formation of fayalite can be driven by changes in temperature, pressure, H2/H2O, and water/rock ratios. However, in fayalite‐bearing ordinary and CV3 carbonaceous chondrites, the mineral could have formed during the aqueous‐to‐metamorphic transition. Dissolution of amorphous silicates in matrices and/or silica grains, as well as low activities of Mg solutes, favored aqueous precipitation of fayalite. During subsequent metamorphism, fayalite could have formed through the reduction of magnetite and/or dehydration of ferrous serpentine. Further metamorphism should have caused reductive transformation of fayalite to Ca‐Fe pyroxene and secondary metal, which is consistent with observations in metamorphosed chondrites. Although bulk compositions of matrices/chondrites have only a minor effect on fayalite stability, specific alteration paths led to different occurrences, quantities, and compositions of fayalite in chondrites.  相似文献   

8.
TAM5.29 is an extraterrestrial dust grain, collected on the Transantarctic Mountains (TAM). Its mineralogy is dominated by an Fe‐rich matrix composed of platy fayalitic olivines and clasts of andradite surrounded by diopside‐jarosite mantles; chondrules are absent. TAM5.29 records a complex geological history with evidence of extensive thermal metamorphism in the presence of fluids at T < 300 °C. Alteration was terminated by an impact, resulting in shock melt veins and compaction‐orientated foliation of olivine. A second episode of alteration at lower temperatures (<100 °C) occurred postimpact and is either parent body or terrestrial in origin and resulted in the formation of iddingsite. The lack of chondrules is explained by random subsampling of the parent body, with TAM5.29 representing a matrix‐only fragment. On the basis of bulk chemical composition, mineralogy, and geological history TAM5.29 demonstrates affinities to the CVox group with a mineralogical assemblage in between the Allende‐like and Bali‐like subgroups (CVoxA and TAM5.29 are rich in andradite, magnetite, and FeNiS, but CVoxA lacks hydrated minerals, common in TAM5.29; conversely, CVoxB are rich in hydrated phyllosilicates but contain almost pure fayalite, not found in TAM5.29). In addition, TAM5.29 has a slightly different metasomatic history, in between the oxidized and reduced CV metamorphic grades while also recording higher oxidizing conditions as compared to the known CV chondrites. This study represents the third CV‐like cosmic dust particle, containing a unique composition, mineralogy, and fabric, demonstrating variation in the thermal metamorphic history of the CV parent body(‐ies).  相似文献   

9.
Abstract— We describe a previously unreported meteorite found in Axtell, Texas, in 1943. Based on the mineralogical composition and texture of its matrix and the sizes and abundance of chondrules, we classify it as a CV3 carbonaceous chondrite. The dominant opaque phase in the chondrules is magnetite, and that in refractory inclusions is Ni-rich NiFe metal (awaruite). Axtell, therefore, belongs to the oxidized subgroup of CV3 chondrites, although unlike Allende it escaped strong sulfidation. The meteorite bears a strong textural resemblance to Allende, and its chondrule population and matrix appear to be quite similar to those of Allende, but its refractory inclusions, thermoluminescence properties, and cosmogenic 60Co abundances are not. Our data are consistent with a terrestrial age for Axtell of ～100 years and a metamorphic grade slightly lower than that of Allende.  相似文献   

10.
Abstract— Two unusual dark clasts found in the Vigarano CV3 chondrite were examined using an optical microscope and a scanning electron microscope (SEM). Both clasts lack chondrules, Ca-Al-rich inclusions, and coarse-grained mineral fragments; they, instead, contain abundant inclusions that consist of fine grains (<1 μm) of homogeneous Fe-rich olivine, thus resembling the fine-grained variety of dark inclusions in CV3 chondrites. The external shapes of inclusions in the clasts bear a close resemblance to those of chondrules and chondrule fragments; some of the inclusions are surrounded by dark rims similar to chondrule rims. Our SEM observations reveal the following unusual characteristics: 1) the inclusions are not mere random aggregates of olivine grains but have peculiar internal textures, that is, assemblages of round or oval shaped outlines, which are suggestive of pseudomorphs after porphyritic olivine chondrules; 2) one of thick inclusion rims contains a network of vein-like strings of elongated olivine grains; 3) an Fe-Ni metal aggregate in one of the clasts has an Fe-, Ni-, S-rich halo suggesting a reaction between its precursor and the surrounding matrix; and 4) olivine in the clasts commonly shows a swirly, fibrous texture similar to that of phyllosilicate. These characteristics suggest that the dark clasts in Vigarano are not primary aggregates of dust in the solar nebula but were affected by aqueous alteration and subsequent dehydration by heating after accretion to the meteorite parent body. The fine olivine grains in these clasts were presumably produced by thermal transformation of phyllosilicate, as is the case with those in the two thermally metamorphosed Antarctic CM chondrites, Belgica-7904 and Yamato-86720. From textural and mineralogical similarities, some of the dark inclusions and clasts previously reported from CV3 chondrites and other types of meteorites may have origins common with these clasts in Vigarano.  相似文献   

11.
Abstract— Calcium- and aluminum-rich inclusions (CAIs), chondrules, dark inclusions and matrices in certain CV3 carbonaceous chondrites appear to have been modified by different degrees of late-stage alteration processes that caused significant variations in mineralogy and chemistry. Some chondrules and CAIs are rimmed with fayalitic olivine. Metal in all components may be oxidized and sulphidized to magnetite, Ni-rich metal and sulfides. Silicates in all components are aqueously altered to different degrees to phyllosilicates. Primary minerals in some CAIs experienced Fe-alkali-halogen metasomatism forming nepheline, sodalite, wollastonite, hedenbergite and other secondary minerals. In CV3 chondrites with metasomatized CAIs, nepheline, sodalite, etc. are also present in chondrule mesostases and in matrices. McSween's (1977b) reduced subgroup of CV3 chondrites generally shows minimal alteration of all components and may represent the unaltered precursors for the oxidized CV3 chondrites, which generally show major alteration. Most studies have been focused on specific components in CV3 chondrites and have not considered possible relationships between alteration processes. We infer from the correlated occurrences of the alteration features that they were closely related in time and space and review nebular and asteroidal models for their origins. We prefer an asteroidal model.  相似文献   

12.
The single parent body model for the CV and CK chondrites (Greenwood et al. 2010 ) was challenged by Dunn et al. ( 2016a ), who argued that magnetite compositions could not be reconciled by a single metamorphic sequence (i.e., CV3 → CK3 → CK4–6). Cr isotopic compositions, which are distinguishable between the CV and CK chondrites, also support two different parent bodies (Yin et al. 2017 ). Despite this, there are many petrographic and mineralogical similarities between the unequilibrated (petrologic type 3) CK chondrites and the CV chondrites (also type 3), which may result in misclassification of samples. Hart and Northwest Africa 6047 (NWA 6047) are an excellent example of this. In this study, we revisit the classification of Hart and NWA 6047 using magnetite compositions, petrography, and compositions of olivine, the most ubiquitous mineral in both CV and CK chondrites. Not only do our results suggest that NWA 6047 and Hart were misclassified, but our assessment of CV and CK3 chondrites has also led to the development of criteria that can be used to distinguish between CV and CK3 chondrites. These criteria include: abundances of Cr2O3, TiO2, NiO, and Al2O3 in magnetite; Fa content and NiO abundance of matrix olivine; FeO content of chondrules; and the chondrule:matrix ratio. Classification as a CV chondrite is also supported by the presence of igneous chondrule rims, calcium‐aluminum‐rich inclusions, and an elongated petrofabric. However, none of these petrographic characteristics can be used conclusively to distinguish between CV and CK3 chondrites.  相似文献   

13.
Abstract— Chondrules in the Bali-like CV chondrite Kaba and the Allende-like portion of the Mokoia breccia have been studied to explore the relationship between hydrous alteration to form phyllosilicates and anhydrous alteration resulting in secondary olivine zonation, replacement of enstatite by ferroan olivine and formation of feldspathoids (nepheline and sodalite). All Kaba chondrules experienced extensive hydrous alteration; whereas, anhydrous alteration was minor and resulted only in the olivine zonation. On the other hand, all of the Mokoia chondrules experienced both extensive anhydrous and hydrous alteration. Bronzite rims formed between relic enstatite grains and phyllosilicates in both Kaba and Mokoia during the hydrous alteration. Petrographic observations indicate that phyllosilicates in Mokoia postdate formation of the secondary ferroan olivine and feldspathoids. We conclude that anhydrous alteration in Kaba and Mokoia predated hydrous alteration and took place before accretion of chondrules into the CV parent asteroid.  相似文献   

14.
Meteoritic matrices are commonly classified by their modal mineralogy, alteration, and shock levels. Other “textural” characteristics are not generally considered in classification schemes, yet could carry important information about their genesis and evolution. Terrestrial rocks are routinely described by grain morphology, which has led to morphology‐driven classifications, and identification of controlling processes. This paper investigates three CV chondrites—Allende (CV3.2oxA), Kaba (CV3.0oxB), and Vigarano (CV3.3red)—to determine the morphologic signature of olivine matrix grains. 2D grain size and shape, and crystallographic preferred orientations (CPOs) are quantified via electron backscatter diffraction mapping. Allende contains the largest and most elongate olivine grains, while Vigarano contains the least elongate, and Kaba contains the smallest grains. Weak but notable CPOs exist in some regions proximal to chondrules and one region distal to chondrules, and CPO geometries reveal a weak flattening of the matrix grains against the edge of chondrules within Allende. Kaba contains the least plastically deformed grains, and Allende contains the most plastically deformed grains. We tentatively infer that morphology is controlled by the characteristics of the available population of accreting grains, and aqueous and thermal alteration of the parent body. The extent of overall finite deformation is likely dictated by the location of the sample with respect to compression, the localized environment of the matrix with respect to surrounding material, and the post deformation temperature to induce grain annealing. Our systematic, quantitative process for characterizing meteorite matrices has the potential to provide a framework for comparison within and across meteorite classes, to help resolve how parent body processing differed across and between chondritic asteroids.  相似文献   

15.
Abstract— Petrographic, compositional, and isotopic characteristics were studied for three calcium‐aluminum‐rich inclusions (CAIs) and four plagioclase‐bearing chondrules (three of them Al‐rich) from the Axtell (CV3) chondrite. All seven objects have analogues in Allende (CV3) and other primitive chondrites, yet Axtell, like most other chondrites, contains a distinctive suite of CAIs and chondrules. In common with Allende CAIs, CAIs in Axtell exhibit initial 26Al/27Al ratios ((26Al/27Al)0) ranging from ～5 × 10?5 to <1.1 × 10?5, and plagioclase‐bearing chondrules have (26Al/27Al)0 ratios of ～3 × 10?6 and lower. One type‐A CAI has the characteristics of a FUN inclusion. The Al‐Mg data imply that the plagioclase‐bearing chondrules began to form >2 Ma after the first CAIs. As in other CV3 chondrites, some objects in Axtell show evidence of isotopic disturbance. Axtell has experienced only mild thermal metamorphism (<600 °C), probably not enough to disturb the Al‐Mg systematics. Its CAIs and chondrules have suffered extensive metasomatism, probably prior to final accretion. These data indicate that CAIs and chondrules in Axtell (and other meteorites) had an extended history of several million years before their incorporation into the Axtell parent body. These long time periods appear to require a mechanism in the early solar system to prevent CAIs and chondrules from falling into the Sun via gas drag for several million years before final accretion. We also examined the compositional relationships among the four plagioclase‐bearing chondrules (two with large anorthite laths and two barred‐olivine chondrules) and between the chondrules and CAIs. Three processes were examined: (1) igneous differentiation, (2) assimilation of a CAI by average nebular material, and (3) evaporation of volatile elements from average nebular material. We find no evidence that igneous differentiation played a role in producing the chondrule compositions, although the barred olivine compositions can be related by addition or subtraction of olivine. Methods (2) and (3) could have produced the composition of one chondrule, AXCH‐1471, but neither process explains the other compositions. Our study indicates that plagioclase‐bearing objects originated through a variety of processes.  相似文献   

16.
Abstract— CK carbonaceous chondrites contain rare (～0.1 vol%) magnetite-sulfide chondrules. These objects range from ～240 to 500 μm in apparent diameter and have ellipsoidal to spheroidal morphologies, granular textures and concentric layering. They are very similar in size, shape, texture, mineralogy and mineral composition to the magnetite-sulfide nodules which occur inside mafic silicate chondrules in CK chondrites. It seems likely that the magnetite-sulfide chondrules constitute the subset of magnetite-sulfide nodules that escaped as immiscible droplets from their molten silicate chondrule hosts during chondrule formation. The intactness of the magnetite-sulfide chondrules and nodules implies that oxidation of CK metal occurred before agglomeration; otherwise, the factor of two increase in molar volume associated with the conversion of metallic Fe-Ni into magnetite would have disrupted the objects and destroyed their concentrically layered textures. Hence, the pervasive silicate darkening of CK chondrites documented previously was caused by the shock mobilization of magnetite and sulfide, not metallic Fe-Ni and sulfide as in shock-darkened ordinary chondrites.  相似文献   

17.
Abstract— The Y-86751 chondrite (CV3) consists of fine-grained Ca- and Al-rich inclusions (CAIs), amoeboid olivine inclusions (AOIs), spinel-rich inclusions, chondrules with and without dark rims, dark inclusions, isolated minerals, metal-sulfide aggregates, and matrix. Olivines in chondrules without dark rims and AOIs coexist with magnetite and show strong zoning from a magnesian core to a ferroan rim. Spinels in spinel-rich inclusions show similar zoning. This zoning seems to be caused by exchange reaction of olivine and spinel with an oxidized nebular gas prior to the accretion onto the parent body, and the Mg/Fe diffusion in olivines and spinels took place at a temperature of about 830–860 K. At the same time, enstatite in chondrules without dark rims was replaced by ferroan olivine at the grain boundaries. This feature suggests that chondrules without dark rims, fine-grained CAIs, spinel-rich inclusions, and AOIs have experienced oxidation in an oxidizing nebular gas. The oxygen fugacity of the oxidized nebular gas was >10?27.3 bars at about 830 K, being more than 104x larger than that of the canonical nebular gas. Magnetite occurs in the Y-86751 matrix in close association with Ni-rich taenite and Co-rich metal, and it was produced under a condition with the oxygen fugacity of ～10?38 bars at a temperature of about 620–650 K. On the other hand, olivines in chondrules with dark rims and dark inclusions are magnesian and rich in MnO. They do not show such strong zoning. Probably they were in equilibrium with a nebular gas under a redox condition different from the oxidized nebular gas that produced the zoned olivines in chondrules without dark rims.  相似文献   

18.
Abstract— It was suggested that multilayered accretionary rims composed of ferrous olivine, andradite, wollastonite, salite‐hedenbergitic pyroxenes, nepheline, and Ni‐rich sulfides around Allende calcium‐aluminum‐rich inclusions (CAIs) are aggregates of gas‐solid condensates which reflect significant fluctuations in physico‐chemical conditions in the slowly cooling solar nebula and grain/gas separation processes. In order to test this model, we studied the mineralogy of accretionary rims around one type A CAI (E104) and one type B CAI (E48) from the reduced CV3 chondrite Efremovka, which is less altered than Allende. In contrast to the Allende accretionary rims, those in Efremovka consist of coarse‐grained (20–40 μm), anhedral forsterite (Fa1–8), Fe, Ni‐metal nodules, amoeboid olivine aggregates (AOAs) and fine‐grained CAIs composed of Al‐diopside, anorthite, and spinel, ± forsterite. Although the fine‐grained CAIs, AOAs and host CAIs are virtually unaltered, a hibonite‐spinel‐perovskite CAI in the E48 accretionary rim experienced extensive alteration, which resulted in the formation of Fe‐rich, Zn‐bearing spinel, and a Ca, Al, Si‐hydrous mineral. Forsterites in the accretionary rims typically show an aggregational nature and consist of small olivine grains with numerous pores and tiny inclusions of Al‐rich minerals. No evidence for the replacement of forsterite by enstatite was found; no chondrule fragments were identified in the accretionary rims. We infer that accretionary rims in Efremovka are more primitive than those in Allende and formed by aggregation of high‐temperature condensates around host CAIs in the CAI‐forming regions. The rimmed CAIs were removed from these regions prior to condensation of enstatite and alkalies. The absence of andradite, wollastonite, and hedenbergite from the Efremovka rims may indicate that these rims sampled different nebular regions than the Allende rims. Alternatively, the Ca, Fe‐rich silicates rimming Allende CAIs may have resulted from late‐stage metasomatic alteration, under oxidizing conditions, of original Efremovka‐like accretionary rims. The observed differences in O‐isotope composition between forsterite and Ca, Fe‐rich minerals in the Allende accretionary rims (Hiyagon, 1998) suggest that the oxidizing fluid had an 16O‐poor oxygen isotopic composition.  相似文献   

19.
Abstract— We report detailed chemical, petrological, and mineralogical studies on the Ningqiang carbonaceous chondrite. Ningqiang is a unique ungrouped type 3 carbonaceous chondrite. Its bulk composition is similar to that of CV and CK chondrites, but refractory lithophile elements (1.01 × CI) are distinctly depleted relative to CV (1.29 × CI) and CK (1.20 × CI) chondrites. Ningqiang consists of 47.5 vol% chondrules, 2.0 vol% Ca,Al‐rich inclusions (CAIs), 4.5 vol% amoeboid olivine aggregates (AOAs), and 46.0 vol% matrix. Most chondrules (95%) in Ningqiang are Mg‐rich. The abundances of Fe‐rich and Al‐rich chondrules are very low. Al‐rich chondrules (ARCs) in Ningqiang are composed mainly of olivine, plagioclase, spinel, and pyroxenes. In ARCs, spinel and plagioclase are enriched in moderately volatile elements (Cr, Mn, and Na), and low‐Ca pyroxenes are enriched in refractory elements (Al and Ti). The petrology and mineralogy of ARCs in Ningqiang indicate that they were formed from hybrid precursors of ferromagnesian chondrules mixed with refractory materials during chondrule formation processes. We found 294 CAIs (55.0% type A, 39.5% spinel‐pyroxene‐rich, 4.4% hibonite‐rich, and several type C and anorthite‐spinel‐rich inclusions) and 73 AOAs in 15 Ningqiang sections (equivalent to 20 cm2surface area). This is the first report of hibonite‐rich inclusions in Ningqiang. They are texturally similar to those in CM, CH, and CB chondrites, and exhibit three textural forms: aggregates of euhedral hibonite single crystals, fine‐grained aggregates of subhedral hibonite with minor spinel, and hibonite ± Al,Ti‐diopside ± spinel spherules. Evidence of secondary alteration is ubiquitous in Ningqiang. Opaque assemblages, formed by secondary alteration of pre‐existing alloys on the parent body, are widespread in chondrules and matrix. On the other hand, nepheline and sodalite, existing in all chondritic components, formed by alkali‐halogen metasomatism in the solar nebula.  相似文献   

20.
Abstract— The carbonaceous chondrite MacAlpine Hills (MAC) 88107 has bulk composition and mineralogy that are intermediate between those of CO and CM chondrites. This meteorite experienced minor alteration and a low degree of thermal metamorphism (petrologic type 3.1) and escaped post‐accretional brecciation. The alteration resulted in the formation of fayalite (Fa90–100). Al‐free hedenbergite (～Fs50Wo50), phyllosilicates (saponite‐serpentine intergrowths), magnetite, and Ni‐bearing sulfides (pyrrhotite and pentlandite). Fayalite and hedenbergite typically occur as veins, which start at the opaque nodules in the chondrule peripheries, crosscut fine‐grained rims and either terminate at the boundaries with the neighboring fine‐grained rims or continue as layers between these rims. These observations suggest that fayalite and hedenbergite crystallized after accretion and compaction of the fine‐grained rims. Fayalite also overgrows isolated forsteritic (Fa1–5) and fayalitic (Fa20–40) olivine grains without any evidence for Fe‐Mg interdiffusion; it also replaces massive magnetite‐sulfide grains. The initial 53Mn/55Mn ratio of (1.58 ± 0.26) × 10?6 in the MAC 88107 fayalite corresponds to an age difference between the formation of fayalite and refractory inclusions in Allende of either ～9 or 18 Ma, depending upon the value of the solar system initial abundance of 53Mn used in age calculations. Formation of secondary fayalite and hedenbergite requires mobilization and transport of Ca, Si, and Fe either through a high‐temperature gaseous phase (Hua and Buseck, 1995) or low‐temperature aqueous solution (Krot et al., 1998a, b). The high‐temperature nebular model for the origin of fayalite (Hua and Buseck, 1995) fails to explain (a) formation of fayalite‐hedenbergite assemblages after accretion of fine‐grained rims that lack any evidence for high‐temperature processing; (b) extreme fractionation of refractory lithophile elements of similar volatility, Ca and Al, in hedenbergite; and (c) absence of Fe‐Mg interdiffusion along fayalite‐forsterite boundaries. We conclude that fayalite and hedenbergite in MAC 88107 formed during late‐stage, low‐temperature (approximately 150–200 °C) aqueous alteration. The data for MAC 88107 extend the evidence for an early onset of aqueous activity on chondrite parent bodies and reinforce the conclusion that liquid water played an important role in the chemical and mineralogical evolution of the first chondritic planetesimals.  相似文献   

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