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1.
Aleutian tholeiitic and calc-alkaline magma series I: The mafic phenocrysts   总被引:1,自引:0,他引:1  
Diagnostic mafic silicate assemblages in a continuous spectrum of Aleutian volcanic rocks provide evidence for contrasts in magmatic processes in the Aleutian arc crust. Tectonic segmentation of the arc exerts a primary control on the variable mixing, fractional crystallization and possible assimilation undergone by the magmas. End members of the continuum are termed calc-alkaline (CA) and tholeiitic (TH). CA volcanic rocks (e.g., Buldir and Moffett volcanoes) have low FeO/MgO ratios and contain compositionally diverse phenocryst populations, indicating magma mixing. Their Ni and Cr-rich magnesian olivine and clinopyroxene come from mantle-derived mafic olivine basalts that have mixed with more fractionated magmas at mid-to lower-crustal levels immediately preceding eruption. High-Al amphibole is associated with the mafic end member. In contrast, TH lavas (e.g., Okmok and Westdahl volcanoes) have high FeO/MgO ratios and contain little evidence for mixing. Evolved lavas represent advanced stages of low pressure crystallization from a basaltic magma. These lavas contain groundmass olivine (FO 40–50) and lack Ca-poor pyroxene. Aleutian volcanic rocks with intermediate FeO/MgO ratios are termed transitional tholeiitic (TTH) and calc-alkaline (TCA). TCA magmas are common (e.g., Moffett, Adagdak, Great Sitkin, and Kasatochi volcanoes) and have resulted from mixing of high-Al basalt with more evolved magmas. They contain amphibole (high and low-Al) or orthopyroxene or both and are similar to the Japanese hypersthene-series. TTH magmas (e.g., Okmok and Westdahl) contain orthopyroxene or pigeonite or both, and show some indication of upper crustal mixing. They are mineralogically similar to the Japanese pigeonite-series. High-Al basalt lacks Mg-rich mafic phases and is a derivative magma produced by high pressure fractionation of an olivine tholeiite. The low pressure mineral assemblage of high-Al basalt results from crystallization at higher crustal levels.  相似文献   

2.
The Late Devonian Tolmie Igneous Complex (in north-eastern Victoria, Australia) contains S-type, intracaldera, rhyolitic ignimbrites with multiple generations of phenocrysts of biotite, garnet, cordierite and orthopyroxene; one unit also contains fayalitic olivine. Geothermometry and calculated phase relations indicate high-T deep- to mid-crustal origins for the magmas, with crystallisation at several levels. At least four separate magma groups make up the complex. Compositional variations within and between ignimbrites are adequately modelled by selective entrainment of peritectic garnet, ilmenite, orthopyroxene and plagioclase into the magmas. Neither crystal fractionation nor mafic-felsic magma mixing played a role. Chemical and isotope data suggest that the magma sources were once variably Ba-enriched arc greywackes with different proportions of clay. The deep origin of some of the Tolmie Complex magmas means that supracrustal rocks underlie parts of north-eastern Victoria at depths of around 35 km. This has important implications for understanding the region’s tectonic development.  相似文献   

3.
Amphibole-bearing mafic inclusions (low to medium-K high-alumina basalt to basaltic andesite) comprise 4.1 vol% of calc-alkaline rhyolite and rhyodacite lavas on Akrotiri Peninsula, Santorini, Greece. Physical features indicate a magmatic origin for the inclusions, involving mingling with the host silicic magma and quenching. Water contents of the mafic magmas are estimated to have been above 4% at water pressures of 1.8 kbars or more at temperatures of approximately 950–1,000 °C. Three evolutionary stages are inferred in their petrogenesis. In the first stage infiltration of slab fluids promotes partial melting in the mantle to generate primitive wet basaltic magmas enriched in LREE, LILE, Th and U in comparison to N-type MORB. In the second stage storage and crystal differentiation of primitive magmas occurred in the lithospheric mantle or deep crust, involving olivine, spinel and clinopyroxene followed by amphibole and plagioclase. In the third stage differentiated mafic magma intrudes into porphyritic silicic magma at shallower crustal levels (estimated at 7–10 km). Mingling and quenching of the mafic magmas within the silicic host causes chemical or physical interactions between the inclusions and the host prior to and during eruption. The silicic lavas have geochemical affinities with the mafic inclusions, but are relatively depleted in MREE, HREE and Y and enriched in Rb relative to Ba and K. These observations are consistent with involvement of amphibole in magma genesis due either to crystal differentiation from wet basalt or to partial melting of mafic rocks with residual amphibole. Crystallization of wet basalt in the deep crust is preferred on the basis of physical considerations.Electronic Supplementary Material Supplementary material is available for this article if you access the article at . A link in the frame on the left on that page takes you directly to the supplementary material.Editorial responsibility: I. Parsons  相似文献   

4.
Heterogeneous andesitic and dacitic lavas on Cordn El Guadalbear on the general problem of how magmas of differing compositionsand physical properties interact in shallow reservoirs beneathcontinental arc volcanoes. Some of the lavas contain an exceptionallylarge proportion (<40%) of undercooled basaltic andesiticmagma in various states of disaggregation. Under-cooled maficmagma occurs in the silicic lavas as large (<40 cm) basalticandesitic magmatic inclusions, as millimeter-sized crystal-clotsof Mg-rich olivine phenocrysts plus adhering Carich plagioclasemicrophenocrysts (An50–70), and as uniformly distributed,isolated phenocrysts and microphenocrysts. Compositions andtextures of plagioclase phenocrysts indicate that inclusion-formingmagmas are hybrids formed by mixing basaltic and dacitic melts,whereas textural features and compositions of groundmass phasesindicate that the andesitic and dacitic lavas are largely mechanicalmixtures of dacitic magma and crystallized basaltic andesiticmagma. This latter observation is significant because it indicatesthat mechanical blending of undercooled mafic magma and partiallycrystallized silicic magma is a possible mechanism for producingthe common porphyritic texture of many calc-alkaline volcanicrocks. The style of mafic-silicic magma interaction at CordonEl Guadal was strongly dependent upon the relative proportionsof the endmembers. Equally important in the Guadal system, however,was the manner in which the contrasting magmas were juxtaposed.Textural evidence preserved in the plagioclase phenocrysts indicatesthat the transition from liquid-liquid to solid-liquid mixingwas not continuous, but was partitioned into periods of magmachamber recharge and eruption, respectively. Evidently, duringperiods of recharge, basaltic magmas rapidly entrained smallamounts of dacitic magma along the margins of a turbulent injectionfountain. Conversely, during periods of eruption, dacitic magmagradually incorporated small parcels of basaltic andesitic magma.Thus, the coupled physical-chemical transition from mixed inclusionsto commingled lavas is presumably not coincidental. More likely,it probably provides a partial record of the dynamic processesoccurring in shallow magma chambers beneath continental arevolcanoes. KEY WORDS: Chile; commingling; magma mixing; magmatic inclusions *Present address: Department of Earth Sciences, Montana State University, Bozeman, MT 59717, USA  相似文献   

5.
Petrographic, mineral chemical and whole-rock major oxide data are presented for the lavas of the Main Volcanic Series of Patmos, Dodecanesos, Greece. These lavas were erupted about 7 m.y. ago and range in composition from ne-trachybasalts through hy-trachybasalts and trachyandesites to Q-trachytes. To some extent, the ne-trachybasalts are intermediate in composition to the alkaline lavas found on oceanic islands and the calc-alkaline lavas of destructive plate margins. Major oxide variation is largely explicable in terms of fractional crystallization involving removal of the observed phenocryst and microphenocryst phases viz. olivine, plagioclase, clinopyroxene and Ti-magnetite in the mafic lavas, plagioclase, clinopyroxene, mica and Ti-magnetite in the evolved lavas. Apatite, which occurs as an inclusion in other phenocrysts or as microphenocrysts must also have been removed. However, mass balance calculations indicate that the chemistry of the hy-trachybasalts is inconsistent with an origin via fractional crystallization alone and the complex zoning patterns and resorbtion phenomena shown by phenocrysts in these lavas show that they are hybrids formed by the mixing of 80-77% ne-trachybasalt with 20–23% trachyandesite. It is estimated that the mixing event preceded eruption by a period of 12 h-2 weeks suggesting that mixing triggered eruption. Combined fractionation and mixing cannot explain the relatively low MgO contents of the hy-trachybasalts and it is concluded that assimilation also occurred. Assimilation, and especially addition of volatiles to the magmas, may be responsible for the evolutionary trend from ne-normative to hy-normative magmas and was probably facilitated by intensified convection resulting from mixing. A model is presented whereby primitive magma undergoes fractionation in an intracrustal magma chamber to yield more evolved liquids. Influx of hot primitive magma into the base of the chamber facilitates assimilation, but eventually mixing yields the hy-trachybasalts and finally the ne-trachybasalts are erupted.  相似文献   

6.
Lavas from Medicine Lake volcano, Northern California have been examined for evidence of magma mixing. Mixing of magmas has produced basaltic andesite, andesite, dacite and rhyolite lavas at the volcano. We are able to identify the compositional characteristics of the components that were mixed and to estimate the time lag between the mixing event and eruption of the mixed magma. Compositional data from pairs of phenocrysts identify a high alumina basalt (HAB) and a silicic rhyolite as endmembers of mixing. Mg-rich olivine or augite and Ca-rich plagioclase are associated with the HAB component, and Fe-rich orthopyroxene and Na-rich plagioclase are associated with the rhyolitic component. Some lavas contain multiple phenocryst assemblages suggesting the incorporation of several magmas intermediate between the HAB and silicic components. Glass inclusions trapped in Mg-rich olivine and Na-rich plagioclase are similar in composition to the proposed HAB and rhyolite end members and provide supportive evidence for mixing. Textural criteria are also consistent with magma mixing. Thermal curvature of the liquidus surfaces in the basalt-andesite-rhyolite system allows magmas produced by mixing to be either supercooled or superheated. Intergranular textures of basaltic andesites and andesites result from cooling initiated below the liquidus. The trachytic textures of silicic andesites form from cooling initiated above the liquidus. Reversed compositional zoning profiles in olivine crystals were produced by the mixing event, and the homogenization of the compositional zoning has been used to estimate the time interval between magma mixing and eruption. Time estimates are on the order of 80 to 90 h, suggesting that the mixing event triggered eruption.  相似文献   

7.
Andesite and dacite from Barren and Narcondam volcanic islands of Andaman subduction zone are composed of plagioclase, orthopyroxene, clinopyroxene, olivine, titanomagnetite, magnesio-hornblende and rare quartz grains. In this study, we use the results of mineral chemical analyses of the calc-alkaline rock suite of rocks as proxies for magma mixing and mingling processes. Plagioclase, the most dominant mineral, shows zoning which includes oscillatory, patchy, multiple and repetitive zonation and ‘fritted’ or ‘sieve’ textures. Zoning patterns in plagioclase phenocrysts and abrupt fluctuations in An content record different melt conditions in a dynamic magma chamber. ‘Fritted’ zones (An55) are frequently overgrown by thin calcic (An72) plagioclase rims over well-developed dissolution surfaces. These features have probably resulted from mixing of a more silicic magma with the host andesite. Olivine and orthopyroxene with reaction and overgrowth rims (corona) suggest magma mixing processes. We conclude that hybrid magma formed from the mixing of mafic and felsic magma by two-stage processes – initial intrusion of hotter mafic melt (andesitic) followed by cooler acidic melt at later stage.  相似文献   

8.
The crustal history of volcanic rocks can be inferred from the mineralogy and compositions of their phenocrysts which record episodes of magma mixing as well as the pressures and temperatures when magmas cooled. Submarine lavas erupted on the Hilo Ridge, a rift zone directly east of Mauna Kea volcano, contain olivine, plagioclase, augite ±orthopyroxene phenocrysts. The compositions of these phenocryst phases provide constraints on the magmatic processes beneath Hawaiian rift zones. In these samples, olivine phenocrysts are normally zoned with homogeneous cores ranging from ∼ Fo81 to Fo91. In contrast, plagioclase, augite and orthopyroxene phenocrysts display more than one episode of reverse zoning. Within each sample, plagioclase, augite and orthopyroxene phenocrysts have similar zoning profiles. However, there are significant differences between samples. In three samples these phases exhibit large compositional contrasts, e.g., Mg# [100 × Mg/(Mg+Fe+2)] of augite varies from 71 in cores to 82 in rims. Some submarine lavas from the Puna Ridge (Kilauea volcano) contain phenocrysts with similar reverse zonation. The compositional variations of these phenocrysts can be explained by mixing of a multiphase (plagioclase, augite and orthopyroxene) saturated, evolved magma with more mafic magma saturated only with olivine. The differences in the compositional ranges of plagioclase, augite and orthopyroxene crystals between samples indicate that these samples were derived from isolated magma chambers which had undergone distinct fractionation and mixing histories. The samples containing plagioclase and pyroxene with small compositional variations reflect magmas that were buffered near the olivine + melt ⇒Low-Ca pyroxene + augite + plagioclase reaction point by frequent intrusions of mafic olivine-bearing magmas. Samples containing plagioclase and pyroxene phenocrysts with large compositional ranges reflect magmas that evolved beyond this reaction point when there was no replenishment with olivine-saturated magma. Two of these samples contain augite cores with Mg# of ∼71, corresponding to Mg# of 36–40 in equilibrium melts, and augite in another sample has Mg# of 63–65 which is in equilibrium with a very evolved melt with a Mg# of ∼30. Such highly evolved magmas also exist beneath the Puna Ridge of Kilauea volcano. They are rarely erupted during the shield building stage, but may commonly form in ephemeral magma pockets in the rift zones. The compositions of clinopyroxene phenocryst rims and associated glass rinds indicate that most of the samples were last equilibrated at 2–3 kbar and 1130–1160 °C. However, in one sample, augite and glass rind compositions reflect crystallization at higher pressures (4–5 kbar). This sample provides evidence for magma mixing at relatively high pressures and perhaps transport of magma from the summit conduits to the rift zone along the oceanic crust-mantle boundary. Received: 8 July 1998 / Accepted: 2 January 1999  相似文献   

9.
GANDY  M. K. 《Journal of Petrology》1975,16(1):189-211
The calc-alkaline lava sequence of the eastern Sidlaw Hillsforms a small part of an extensive volcanic province of LowerOld Red Sandstone (Devonian) age in Scotland and N. England.The Sidlaw lavas ranging from olivine basalt to dacite are allporphyritic with combinations of olivine, plagioclase, clinopyroxene,orthopyroxene, and opaque oxide pheno-crysts. Chemically, thelavas are slightly more alkalic than modern calc-alkaline lavas.There is considerable variation in the ‘incompatible elements’.The differentiation of the lavas can be accounted for by fractionationof olivine+plagioclase+minor ore from a chemically variable,immediately parental magma at low pressure (c. 1 kb PH2O). Itis suggested that fractionation of variable amounts of olivineand clinopyroxene from an olivine tholeiite at moderate PH2Ocould give rise to this chemically variable, high alumina, immediatelyparental magma.  相似文献   

10.
Major and trace element data for a sequence of peralkaline silicic lavas and pyroclastic flows, exposed in the caldera wall of the Paisano volcano, west Texas, document systematic fractional crystallization during magmatic evolution and an open system, magma mixing event in the upper parts of the sequence. Stratigraphically lowest flows are comendite and comenditic quartz trachyte lavas and ash flow tufts. Overlying these units is a trachyte with compositional, textural and mineralogical features indicating that it is the product of magma-mixing; similar flows occur in other parts of the volcano at the same stratigraphic level. This composite trachyte is considered to be a mixture of mugearitic or mafic trachytic magma, derived from a similar source region which yielded the earlier caldera wall flows. Trace element concentrations of the post-trachyte comenditic quartz trachyte lavas suggest they were erupted from a chamber whose magma was diluted by an influx of mugearitic or mafic trachytic magma during a magma mixing event.Rayleigh fractionation calculations show that the comendites and comenditic quartz trachytes can be derived from a parental mugearite magma by 88% to 93% fractionation of dominantly plagioclase and alkali feldspar, with lesser amounts of clinopyroxene, magnetite and apatite. Zircon was not a significant fractionating phase. The composition, mineralogy and depth of the source region(s) which generated these magmas cannot be constrained from the present data set.  相似文献   

11.
Andesites from northeastern Kanaga Island,Aleutians   总被引:1,自引:0,他引:1  
Kanaga island is located in the central Aleutian island arc. Northeastern Kanaga is a currently active late Tertiary to Recent calc-alkaline volcanic complex. Basaltic andesite to andesite lavas record three episodes (series) of volcanic activity. Series I and Series II lavas are all andesite while Series III lavas are basaltic andesite to andesite. Four Series II andesites contain abundant quenched magmatic inclusions ranging in composition from high-MgO low-alumina basalt to low-MgO highalumina basalt. The spectrum of lava compositions is due primarily to fractional crystallization of a parental low-MgO high-alumina basalt but with variable degrees of crustal contamination and magma mixing. The earliest Series I lavas represent mixing between high-alumina basalt and silicic andesite with maximum SiO2 contents of 65–67 wt %. Later Series I and all Series II lavas are due to mixing of andesite magmas of similar composition. The maximum SiO2 content of the pre-mixed andesites magmas is estimated at 60–63 wt %. The youngest lavas (Series III) are all non-mixed and have maximum estimated SiO2 contents of 59 wt %. The earliest Series I lavas contain a significant crustal component while all later lavas do not. It is concluded that the maximum SiO2 contents of silicic magmas, the contribution of crustal material to silicic magma generation, and the role of magma mixing all decrease with time. Furthermore, silicic magmas generated by fractional crystallization at this volcanic center have a maximum SiO2 content of 63 wt %. All of these features have also been documented at the central Aleutian Cold Bay Volcanic Center (Brophy 1987). Based on data from these two centers a model of Aleutian calc-alkaline magma chamber development is proposed. The main features are: (1) a single low pressure magma chamber is continuously supplied by primitive low-alumina basalt; (2) non-primary high-alumina basalt is formed along the chamber margins by selective gravitational settling of olivine and clinopyroxene and retention of plagioclase; (3) sidewall crystallization accompanied by crustal melting produces buoyant silicic (>63 wt % SiO2) liquids that pond at the top of the chamber, and; (4) continued sidewall crystallization, now isolated from the chamber wall, produces silicic liquids with 63 wt % SiO2 that increase the thickness and lowers the overall SiO2 content of the upper silicic zone. It is suggested that the maximum SiO2 content of 63% imposed on fractionation-generated magmas is due to a rheological barrier that prohibits the extraction of more silicic liquids from a crystal-liquid mush along the chamber wall.  相似文献   

12.
The Cordillera del Paine pluton in the southernmost Andes of Chile represents a deeply dissected magma chamber where mafic magma intruded into crystallizing granitic magma. Throughout much of the 10x15 km pluton, there is a sharp and continuous boundary at a remarkably constant elevation of 1,100 m that separates granitic rocks (Cordillera del Paine or CP granite: 69–77% SiO2) which make up the upper levels of the pluton from mafic and comingled rocks (Paine Mafic Complex or PMC: 45–60% SiO2) which dominate the lower exposures of the pluton. Chilled, crenulate, disrupted contacts of mafic rock against granite demonstrate that partly crystallized granite was intruded by mafic magma which solidified prior to complete crystallization of the granitic magma. The boundary at 1,100 m was a large and stable density contrast between the denser, hotter mafic magma and cooler granitic magma. The granitic magma was more solidified near the margins of the chamber when mafic intrusion occurred, and the PMC is less disrupted by granites there. Near the pluton margins, the PMC grades upward irregularly from cumulate gabbros to monzodiorites. Mafic magma differentiated largely by fractional crystallization as indicated by the presence of cumulate rocks and by the low levels of compatible elements in most PMC rocks. The compositional gap between the PMC and CP granite indicates that mixing (blending) of granitic magma into the mafic magma was less important, although it is apparent from mineral assemblages in mafic rocks. Granitic magma may have incorporated small amounts of mafic liquid that had evolved to >60% SiO2 by crystallization. Mixing was inhibited by the extent of crystallization of the granite, and by the thermal contrast and the stable density contrast between the magmas. PMC gabbros display disequilibrium mineral assemblages including early formed zoned olivine (with orthopyroxene coronas), clinopyroxene, calcic plagioclase and paragasite and later-formed amphibole, sodic plagioclase, mica and quartz. The early formed gabbroic minerals (and their coronas) are very similar to phenocrysts in late basaltic dikes that cut the upper levels of the CP granite. The inferred parental magmas of both dikes and gabbros were very similar to subalkaline basalts of the Patagonian Plateau that erupted at about the same time, 35 km to the east. Mafic and silicic magmas at Cordillera del Paine are consanguineous, as demonstrated by alkalinity and trace-element ratios. However, the contemporaneity of mafic and silicic magmas precludes a parent-daughter relationship. The granitic magma most likely was derived by differentiation of mafic magmas that were similar to those that later intruded it. Or, the granitic magma may have been contaminated by mafic magmas similar to the PMC magmas before its shallow emplacement. Mixing would be favored at deeper levels when the cooling rate was lower and the granitic magma was less solidified.  相似文献   

13.
Suprasolidus phase relations at pressures from 8 to 30 kb andtemperatures from 950 to 1380C have been determined experimentallyfor a glassy armalcolite–phlogopite lamproite from thechilled margin of a medium–grained lamproite from SmokyButte, Montana: The armalcolite-phlogopite lamproite has microphenocrystsof olivine in a groundmass of phlogopite, sanidine, armalcolite,clinopyroxene, chromite, priderite, apatite, and abundant glass.The lamproite is SiO2-rich and has high F/H2O relative to lamproitesthat have been investigated in previous experimental studies.Our data show that with decreasing temperature from the liquidusat pressures above 12 kb, melt coexists successively with:olivine; orthopyroxene + clinopyroxene; orthopyroxene + clinopyroxene+ phlogopite; clinopyroxene +phlogopite; and clinopyroxene +orthopyroxene + K-richterite. Below 12 kb, the assemblage successionis: olivine; olivine + clinopyroxene; olivine + clinopyroxene+ phlogopite; and olivine +clinopyroxene + phlogopite + armalcolite.The main difference from the natural paragenesis is that therock does not contain any orthopyroxene—a feature thatis rather remarkable inasmuch as it has 16% normative hypersthene—andthe rock differs also in that it contains sanidine and priderite.In the experiments, sanidine is observed only as ghostlike domainsin some of the glass and appears to have formed during quenching. The solid phases crystallized experimentally are generally compositionallysimilar to the minerals in the rock. These similarities andthe experimental phase relations support the concept of a rapidinitial magma ascent with only a small temperature drop andcrystallization of olivine, but not of orthopyroxene. At lowerpressures, less than 12 kb, it appears that the magma ascendedmore slowly with a larger temperature drop suggested by thesimilarity of the experimentally determined sequence of assemblagesto the paragenesis of the rock. No quasi-invariant multiphase-saturation point was found suchas might be indicative of pressure and temperature conditionsfor formation of the lamproite magma by eutectic-type partialmelting of a mantle source. The occurrence of olivine, orthopyroxene,and clinopyroxene near the liquidus, and the high proportionof normative hypersthene in the melt suggest that lherzoliteor harzburgite was probable in the magma source rock. The highSiO2 and MgO contents of the Smoky Butte lamproites may indicatethat orthopyroxene was a source mineral even though it did notcrystallize under near-surface conditions. The curve definingthe appearance of phlogopite appears at progressively lowertemperatures from the liquidus as pressure increases, so itwould appear that either phlogopite was not the mantle K-reservoir,or it was entirely consumed during the partial melting process.The composition of the near-liquidus glass in the experimentsis likely to be the composition of the bulk rock less the verysmall amounts of olivine + clinopyroxene + orthopyroxene crystallizedwithin a few degrees below the liquidus. From the inferred compositionof this glass, anhydrous phlogopite is a potential mineral.The principal variable that determines whether phlogopite crystallizesas a near-liquidus mineral is F/H2O; low values of this ratiopromote the presence of phlogopite as a near-liquidus mineralwhereas high values deter its crystallization. The common practiceof adding H2O but not F in experiments to compensate for degassingmay obscure the role of phlogopite in the evolution of lamproitemagmas.  相似文献   

14.
The Cretaceous M?gantic intrusive complex of southern Qu?beccontains early noritic gabbrodiorites which represent cumulatesfrom crustally contaminated hawaiite to syenite magmas. Wholerock and mineral chemistry, as well as textural evidence, indicatethat post-cumulus recrystallization and reaction were important,and most of the amphibole and biotite are thought to have formedin this way. A younger plutonic quartz-syenite ringdyke maynot be cogenetic with the gabbro-diorites sice it lacks orthopyroxene.It may, however, be cogenetic with basaltic to riebeckite granitedykes. Fractionation of olivine, plagioclase, aluminous clinopyroxene,and minor Ti-magnetite from critically undersaturated alkalibasaltic magmas generated hawaiitic magmas. The developmentof quartzbearing mugearitic and syenitic residua from the hawaiitescan best be modelled by fractionation of amphibole, plagioclase,olivine, oxides, and apatite. Attempts to model fractionationusing observed phenocrysts (including clinopyroxene) were unsuccessful.Amphibole fractionation is interpreted to have taken place througha reaction with still-porous, higher-temperature cumulates onthe walls of the magma chamber. The plutonic syenites probablyrepresent alkali feldspar cumulates from the residual syeniticmelts. Magnesian calc-alkaline lamprophyres exhibit olivineto phlogopite reaction textures, are enriched in Cr, Ni, K,Rb, Nb, Y, Zr, and Si relative to the basaltic dykes, yet havesimilar incompatible element ratios. Their relation to the basaltsis problematical. The late biotite-granite core to the complexis identical to typical White Mountain granites and may haveformed as an anatectic cap on rising, fractionating, mantlederivedmagmas.  相似文献   

15.
One mantle xenolith from a basanite host of the Mt. Melbourne Volcanic Field (Ross Sea Rift) is extraordinary in containing veins filled with leucite, plagioclase, clinopyroxene, nepheline, Mg-ilmenite, apatite, titaniferous mica, and the rare mineral zirconolite. These veins show extensive reaction with the dunitic or lherzolitic host (olivine+spinel+orthopyroxene+clinopyroxene). The reaction areas contain skeletal olivine and diopside crystals, plagioclase, phlogopite, aluminous spinel and ilmenite in a fine grained groundmass of aluminous spinel, clinopyroxene, olivine, plagioclase and interstitial leucite. The vein composition estimated from modal abundances and microprobe analyses is a mafic leucite-phonolite with high amounts of K, Al, Ti, Zr and Nb but low volatile contents. The melt is unrelated to the host basanite and was probably derived by smallscale melting of incompatible element-enriched phlogopite-bearing mantle material and must have lost most of its volatile content during migration, crystallization and reaction with the host dunite. While the veins are completely undeformed the dunitic host shows slight deformation. Vein minerals crystallized at high temperatures above 1000°C and pressures below 5 kbar according to the phase assemblage including leucite, nepheline and K-feldspar. Spinel/olivine geothermometry yielded 800–920°C for the re-equilibration of the host peridotite. Thus the xenolith must have been at shallow depth prior to and during the late veining event. Mantle material at shallow depths is consistent with rifting and the regional extreme displacement at the transition from the rifted Victoria Land Basin in the Ross Sea to the uplifted Trans-Antarctic Mountains.  相似文献   

16.
The North Puruliya Shear zone (NPSZ) is characterized by occurrence of mafic-ultramafic rocks aligned parallel to the shear zone, intruding the high grade Proterozoic rocks of Chhotanagpur Gneissic Complex. The ultramafic rocks occur as small lenses, pockets, veins, thin dykes and are intimately associated with mafic (gabbro, norite) rocks. Pyroxenites (viz. olivine websterite, websterite, plagioclase websterite) and hornblendite are the two important members of the ultramafic rocks containing clinopyroxene, orthopyroxene, olivine, plagioclase, amphibole, phlogopite and ilmenite. The mafic-ultramafic rocks show evidence of shearing and retrogressive metamorphism. Linear correlation of chemical attributes suggests fractionation-controlled magmatic differentiation. Enrichment of LILE and LREE in the mafic-ultramafic suite suggests an enriched mantle source and pronounced negative Eu-anomalies in all the rock types except hornblendite suggest fractionation of plagioclase under low fO2 condition. Progressive iron enrichment trend in rocks of the mafic-ultramafic suite also indicate magmatic differentiation under low fO2 condition. Early fractionation and accumulation of clinopyroxene and plagioclase from a basaltic magma may have given rise to the ultramafic rocks of the area. Little change in the Nb/Zr and Ce/Zr ratios of ultramafic and mafic rocks (except alkali norite) strongly support low crustal contamination. A few samples of norite and gabbro-norites appeared to be variably contaminated by a crustal component or affected by late granitic intrusion resulting in enrichment of alkali in the former.  相似文献   

17.
Primitive andesites from the Taupo Volcanic Zone formed by magma mixing   总被引:1,自引:0,他引:1  
Andesites with Mg# >45 erupted at subduction zones form either by partial melting of metasomatized mantle or by mixing and assimilation processes during melt ascent. Primitive whole rock basaltic andesites from the Pukeonake vent in the Tongariro Volcanic Centre in New Zealand’s Taupo Volcanic Zone contain olivine, clino- and orthopyroxene, and plagioclase xeno- and antecrysts in a partly glassy matrix. Glass pools interstitial between minerals and glass inclusions in clinopyroxene, orthopyroxene and plagioclase as well as matrix glasses are rhyolitic to dacitic indicating that the melts were more evolved than their andesitic bulk host rock analyses indicate. Olivine xenocrysts have high Fo contents up to 94%, δ18O(SMOW) of +5.1‰, and contain Cr-spinel inclusions, all of which imply an origin in equilibrium with primitive mantle-derived melts. Mineral zoning in olivine, clinopyroxene and plagioclase suggest that fractional crystallization occurred. Elevated O isotope ratios in clinopyroxene and glass indicate that the lavas assimilated sedimentary rocks during stagnation in the crust. Thus, the Pukeonake andesites formed by a combination of fractional crystallization, assimilation of crustal rocks, and mixing of dacite liquid with mantle-derived minerals in a complex crustal magma system. The disequilibrium textures and O isotope compositions of the minerals indicate mixing processes on timescales of less than a year prior to eruption. Similar processes may occur in other subduction zones and require careful study of the lavas to determine the origin of andesite magmas in arc volcanoes situated on continental crust.  相似文献   

18.
Understanding the mechanisms responsible for the generation of chemical gradients in high-volume ignimbrites is key to retrieve information on the processes that control the maturation and eruption of large silicic magmatic reservoirs. Over the last 60 ky, two large ignimbrites showing remarkable zoning were emplaced during caldera-forming eruptions at Campi Flegrei (i.e., Campanian Ignimbrite, CI, ~?39 ka and Neapolitan Yellow Tuff, NYT, ~?15 ka). While the CI displays linear compositional, thermal and crystallinity gradients, the NYT is a more complex ignimbrite characterized by crystal-poor magmas ranging in composition from trachy-andesites to phonolites. By combining major and trace element compositions of matrix glasses and mineral phases from juvenile clasts located at different stratigraphic heights along the NYT pyroclastic sequence, we interpret such compositional gradients as the result of mixing/mingling between three different magmas: (1) a resident evolved magma showing geochemical characteristics of a melt extracted from a cumulate mush dominated by clinopyroxene, plagioclase and oxides with minor sanidine and biotite; (2) a hotter and more mafic magma from recharge providing high-An plagioclase and high-Mg clinopyroxene crystals and (3) a compositionally intermediate magma derived from remelting of low temperature mineral phases (i.e., sanidine and biotite) within the cumulate crystal mush. We suggest that the presence of a refractory crystal mush, as documented by the occurrence of abundant crystal clots containing clinopyroxene, plagioclase and oxides, is the main reason for the lack of erupted crystal-rich material in the NYT. A comparison between the NYT and the CI, characterized by both crystal-poor extracted melts and crystal-rich magmas representing remobilized portions of a “mature” (i.e., sanidine dominated) cumulate residue, allows evaluation of the capability of crystal mushes of becoming eruptible upon recharge.  相似文献   

19.
Holocene lavas from Craters of the Moon (COM) National Monument are representative of differentiated lavas which occur around the margins of the Snake River Plains (SRP) and they range serially in composition from alkali- and phosphorous-rich ferrobasalts to ferrolatites. Petrographic study indicates that these lavas evolved primarily by cotectic crystallization of olivine, plagioclase, magnetite and apatite in the mafic members of the suite (ferrobasalts), and by cotectic crystallization of plagioclase, magnetite, clinopyroxene and minor olivine in the salic members. Quantitative phase relations in the COM lavas, calculated by means of a leastsquares mixing program, indicate that the observed range in composition among these lavas corresponds to at least 70 percent crystallization of a magma similar to the most mafic COM lavas. Anhydrous one-atmosphere experimental crystallization studies fail to reproduce exactly the inferred phase relations; the discrepancy is attributed to the presence of water in the naturally crystallized magmas. The origin of COM parental magma cannot be unequivocably resolved. Available evidence suggests that COM lavas do not represent melts derived directly from the mantle: (1) high Sr87/Sr86 ratios (0.708 to 0.712), (2) relatively high Fe/(Fe+Mg) and excluded-element content in even the most mafic COM lavas, (3) occurrence of megacrysts of inferred high-pressure origin in the Lava Creek flow. Megacrysts occur in the Lava Creek flow as clusters of labradorite, aluminous clinopyroxene, and olivine. Analogy with the experiments of Thompson [1] and least squares mixing calculations indicate that intermediate (ca. 8 to 10 Kbar) pressure fractionation of such megacrysts from olivine tholeiite magma may yield derivative COM-type liquids.  相似文献   

20.
Disequilibrium phenocryst assemblages in the Younger Andesitesand Dacites of Iztacc?huatl, a major Quaternary volcano in theTrans-Mexican Volcanic Belt, provide an excellent record ofepisodic replenishment, magma mixing, and crystallization processesin calc-alkaline magma chambers. Phenocryst compositions andtextures in ‘mixed’ lavas, produced by binary mixingof primitive olivine-phyric basalt and evolved hornblende dacitemagmas, are used to evaluate the mineralogical and thermal characteristicsof end-members and the physical and chemical interactions thatattend mixing. Basaltic end-members crystallized olivine (FO90–88) andminor chrome spinel during ascent into crustal magma chambers.Resident dacite magma contained phenocrysts of andesine (An45–35),hypersthene (En67–61), edenitic-pargasitic hornblende,biotite, quartz, .titanomagnetite, and ilmenite. On reachinghigh-level reservoirs, basaltic magmas were near their liquidiat temperatures of about 1250–1200?C according to theolivine-liquid geothermometer. Application of the Fe-Ti-oxidegeothermometer-oxygen barometer indicates that hornblende dacitemagma, comprising phenocrysts (<30 vol. per cent) and coexistingrhyolitic liquid, had an ambient temperature between 940 and820?C at fO2s approximately 0?3 log units above the nickel-nickeloxide buffer assemblage. Mixing induced undercooling of hybridliquids and rapid crystallization of skeletal olivine (Fo88–73),strongly-zoned clinopyroxene (endiopside-augite), calcic plagioclase(An65–60); and orthopyroxene (bronzite), whereas low-temperaturephenocrysts derived from hornblende dacite were resorbed ordecomposed by hybrid melts. Quartz reacted to form coronas ofacicular augite and hydroxylated silicates were heated to temperaturesabove their thermal stability limit ({small tilde}940?C foramphibole, according to clinopyroxene-orthopyroxene geothermometry,and {small tilde}880?C for biotite). Calculations of phenocrystresidence times in hybrid liquids based on reaction rates suggestthat the time lapse between magma chamber recharge and eruptionwas extremely short (hours to days). It is inferred that mixing of magmas of diverse compositionis driven by convective turbulence generated by large differencesin temperature between end-members. The mixing mechanism involves:(1)rapid homogenization of contrasting residual liquid compositionsby thermal erosion and diffusive transfer (liquid blending);(2) assimilation of phenocrysts derived from the low-temperatureend-member; and (3) dynamic fractional crystallization of rapidlyevolving hybrid liquids in a turbulent boundary layer separatingbasaltic and dacitic magmas. The mixed lavas of lztacc?huatlrepresent samples of this boundary layer quenched by eruption.  相似文献   

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