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1.
楚翔凯  申萍  李昌昊  林强 《岩石学报》2023,(11):3461-3478
内蒙古乌努格吐山斑岩铜钼矿床是中国东北地区最大的斑岩矿床之一,发育显著的石英-绢云母化蚀变,对早期的钾硅化蚀变有强烈的叠加改造,模糊了各蚀变的分带特征和不同矿化之间的关系,复杂的流体改造阻碍了精细热液演化过程的重建。本文以白云母为研究对象,在细致的显微镜、扫描电镜分析确定云母的形态特征以及矿物共生组合等基础上,利用电子探针(EPMA)、激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)以及短波红外光谱(SWIR)分析手段,详细揭示不同阶段、不同产状白云母的成分差异,探讨了其对矿床热液演化以及成矿机制的指示意义。结果显示,乌山斑岩矿床的白云母由白云母端员及少量钠云母、绿鳞石、伊利石端员组成。与辉钼矿有关的云母更富集Al、K、Sr、Ba,且Al-OH特征波长在2197~2203nm之间。与黄铜矿有关的云母具有更高的Si、Ti、Fe、Mn、Mg、Cu、Zn、Sn、W等元素含量,Al-OH特征波长在2200~2206nm之间。氧化环境下形成的云母更富集Sc、V、W。乌山斑岩矿床的白云母在2200nm处吸收峰位置的波长偏移与距离成矿中心的远近及矿化类型有关,特征波长<2203nm则指示钼矿化,并且靠近成矿中心,因此可以利用SWIR特征圈定热液活动区域,确定矿化类型,指导找矿勘查工作。石英流体包裹体测温证据、白云母成分等信息,暗示铜沉淀阶段存在其他流体补充注入。综上所述,白云母作为常见的蚀变、热液矿物,对研究成矿流体演化及矿床勘查评价具有重要的科学意义。  相似文献   

2.
贺文  林彬  宋英昕  方向  王勤  杨欢欢  李发桥 《地质学报》2023,97(6):1938-1955
铁格隆南矿床产出了西藏班公湖- 怒江成矿带多龙矿集区最大的斑岩- 高硫型铜(金银)成矿系统。由于高硫型矿化与蚀变对斑岩型矿化和蚀变的广泛叠加,导致其成矿系统结构和成矿作用机制变得十分复杂,一定程度阻碍了其精细成矿模型的构建。本文基于铁格隆南矿床现有的勘查和研究成果,从矿物学的角度,以白云母为典型蚀变矿物,通过详细的镜下鉴定、扫描电镜和电子探针分析,详细揭示不同空间位置、不同产状白云母的矿物学特征和成因,探究其对铁格隆南矿床成矿机制的指示意义。结果显示,铁格隆南矿床的热液白云母主要由白云母端元、伊利石端元、绿鳞石端元以及少量钠云母端元组成。矿体中白云母与铜矿物具有成因联系。在深部的早期水岩反应中,白云母主要与黄铜矿伴生,热液蚀变斑岩形成的白云母呈现高Si低Al的特征,而热液蚀变砂岩呈高Al低Si的特征。随着流体向浅部继续运移,白云母共生的金属矿化转换为斑铜矿和铜蓝,多形成高Al低Si的白云母。相对于在侵入岩中产出的白云母,在砂岩中形成的白云母的FeT、Fe3+、Na+含量更高。侵入岩中形成富Fe2+白云母,指示热液还原性较强。此外,在黄铁绢英岩化带较中—浅部产出的白云母常与较多高岭石和铜蓝、斑铜矿伴生,指示了热液中的SO2发生聚集、温度降低、酸性增强并导致水岩反应增强和矿质沉淀的过程。综上,白云母与不同矿物组合及其地球化学特征,对成矿流体环境及勘查评价有良好的指示意义。  相似文献   

3.
富克山铜钼矿是黑龙江省近年来的重大找矿成果之一.详细的野外观察和室内研究发现该矿床具有典型斑岩矿化特征.该矿床致矿斑岩为闪长玢岩,该岩性的侵位导致其自身及围岩中的钾化、黄铁绢英岩化和晚期绿泥石-黄铁矿三期蚀变.矿化主要赋存在与黄铁绢英岩化相关的伟晶岩和花岗闪长岩中.蚀变矿化与致矿闪长玢岩枝的空间分布特征指示矿区南西向深部可能存在大规模致矿岩体.白云母族矿物Pos2200和绿泥石的Pos2250峰位值研究发现,二者受原岩成分影响较大,不宜作为下一步找矿的勘查指标.白云母族IC值(伊利石结晶度)和绿泥石中MnO则主要受到温度的控制,是寻找热液矿化中心的有力工具.该项研究表明,蚀变矿化特征与SWIR分析结合将对矿床勘查起到较为重要的指示作用.   相似文献   

4.
工业白云母的成因类型、控制矿化因素及其矿物学特征的研究,有助于白云母矿床的工业评价。作者根据三年的室內外工作所获实际资料对本区上述问题作一探讨。不当之处,敬希指正。在野外工作期间,得到张克安、刘人俊工程师和队上领导及其他同志的帮助;本文完  相似文献   

5.
通过对矿床中不同世代及不同地质产状石英的颜色、形态、物理性质、化学成分、晶胞参数、结晶度的研究及X射线分析及红外光谱、电子顺磁共振谱等近代物理分析方法的测试,找出了矿化石英与非矿化石英及不同类型矿化石英的标型特征,这些标型特征具有重要的找矿勘探意义  相似文献   

6.
周曙光 《安徽地质》2003,13(2):111-114
天马山硫金矿床位于铜官山矿田内,经铜陵有色(集团)公司的勘探和开发,对矿床的地质特征及成因有了新的认识。通过对矿床的成矿特征分析,认为矿体矿化类型有3种:层控夕卡岩型、夕卡岩型和热液型,它们是受统一成矿作用控制的产物。根据矿床中矿体的矿化类型不同以及不同矿化类型矿体的赋存空间位置不同等特征,提出了在天马山矿区及铜陵成矿区的地质找矿意义。  相似文献   

7.
本文采用短波-热红外光谱联合测量技术+矿物地球化学分析手段,以川西打枪沟花岗伟晶岩型Li-Be稀有金属矿床的13个钻孔岩心样品为研究对象,开展了花岗伟晶岩型稀有金属矿床蚀变系统与矿物光谱-地球化学特征的耦合性研究。结果表明:(1)研究区蚀变分带特征表现为(浅→深):白云母→白云母+钠长石→白云母+角闪石+黑云母+其他斜长石,其中Li、Be矿体均赋存于白云母+钠长石蚀变带。(2)白云母矿物地球化学计算结果显示研究区短波白云母(波长小于2200nm),形成压力在0.03~0.25GPa之间,形成深度为1.3~9.6km,相关矿化类型为Li-Be;波长位于2200~2206nm之间的白云母,形成压力在0.16~0.38GPa之间,深度为6.1~14.5km,相关矿化类型为Be;长波白云母(波长大于2206nm)形成压力为0.45GPa,形成深度为17.1km,无矿化。由此认为研究区成矿环境温度在200~500℃之间、压力在0.03~0.34GPa之间、成矿深度在1.3~14.5km之间。(3)与Li矿化相关的白云母波长均小于2200nm,位移处于10nm波动范围,说明Li矿可能形成于岩浆-热...  相似文献   

8.
以列廷冈-勒青拉Fe-Cu-Pb-Zn多金属矿床为研究对象,通过对其Fe矿化阶段白云母的定年研究,从成矿流体演化持续时间的角度对该问题进行了新的探索。系统的野外踏勘、显微镜下观察和电子探针工作表明,列廷冈-勒青拉矿床中发育与磁铁矿共生的白云母。对白云母进行的Ar-Ar同位素测年工作表明,白云母Ar-Ar坪年龄为51.00±0.38 Ma,等时线年龄为50.45±0.62 Ma,认为其代表了列廷冈-勒青拉矿床氧化物阶段铁矿化过程中开始结晶的白云母达到Ar-Ar体系封闭后的年龄。对比前人得出的辉钼矿年龄(61.96±0.58 Ma),提出二者年龄的差异可能由于不同同位素体系在不同矿物中封闭温度的不同所致,认为该矿床热液演化经历了较长时间,演化过程导致的温度梯度的出现加剧了岩浆热液中带来的多金属物质(如Pb、Zn、Cu、Fe)的分异,为矿区多种金属矿物的共存提供了重要条件;该矿床所属的冈底斯北成矿亚带相比较于其它两个成矿亚带具有更长的岩浆演化时间和区域矿化持续时间,与其丰富的矿种组合发育相一致。  相似文献   

9.
粤北大宝山斑岩钼钨矿床赋矿岩体出露面积0.18km2,矿化主要以细脉状及浸染状产于斑岩及其内外接触带中。系统的薄片观察表明,该岩体岩性比较复杂,有碱长花岗斑岩、普通花岗斑岩、白云母二长花岗斑岩及白云母花岗闪长斑岩。本文分析了碱长花岗斑岩及白云母二长花岗斑岩锆石LA-ICP-MSU-Pb年龄,碱长花岗斑岩锆石年龄为166.6±2.1Ma,MSWD=1.17;白云母二长花岗斑岩锆石年龄为166.2±3.1Ma,MSWD=2.3。两个样品的锆石U-Pb年龄基本一致,表明大宝山斑岩钼钨矿床岩体形成于燕山早期。据斑岩矿床年龄、斑岩矿床在十杭带时空分布特征及华南地区中生代构造背景,提出大宝山斑岩钼钨矿床岩体的形成可能与侏罗纪太平洋洋壳向南西俯冲而引发的的十杭带深断裂构造活动复活有关。  相似文献   

10.
蒋国豪  胡瑞忠 《矿物学报》2007,27(Z1):271-272
大吉山钨矿床是一个石英脉型钨矿床,同时伴有铌、钽、铍、钼等矿化,是南岭成矿带典型的钨多金属矿床.隐伏于大吉山钨矿深部的白云母花岗,具有钠长石化和云英岩化,是钨、铌、钽等稀有元素矿化花岗岩.白云母是一个含矿化剂(F、Cl等)的矿物,矿物中矿化剂的多寡可以反映岩浆体系矿化剂的含量.因此通过对花岗岩和矿脉中自云母成分分析研究可以了解岩石成因、岩石形成的构造背景以及体系挥发分或矿化剂的地球化学特性.  相似文献   

11.
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.  相似文献   

12.
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.  相似文献   

13.
Robert L. Linnen   《Lithos》2005,80(1-4):267-280
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.  相似文献   

14.
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).  相似文献   

15.
HYDROGEOLOGY     
正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level  相似文献   

16.
正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7),  相似文献   

17.
18.
正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci-  相似文献   

19.
正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli-  相似文献   

20.
正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.)  相似文献   

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