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1.
《地质科技情报》2020,(1)
以典型纳污坑塘(污水库)周边地下水水质监测数据为基础,在对区内地下水污染源进行分析的基础上,采用水环境健康风险评估模型,对区内地下水污染健康风险进行了系统评价研究。污染来源识别结果表明:纳污坑塘周边第Ⅰ、第Ⅱ含水层地下水污染严重,其污染源主要为坑塘内堆放的工业污水以及工业废渣。污染健康风险评估结果表明:8号坑附近第Ⅰ含水层中砷浓度以及北库南侧第Ⅱ含水层中1,2-二氯乙烷总致癌风险分别为10~(-2)、10~(-3)数量级,远超可接受风险水平10~(-6)。不同含水层中污染物平均致癌风险大小关系为,第Ⅰ含水层:砷1,2-二氯乙烷;第Ⅱ含水层:1,2-二氯乙烷砷1,1,2-三氯乙烷四氯化碳。1,2-二氯乙烷等挥发性有机污染物4种潜在暴露途径的平均致癌风险大小关系表现为:饮用地下水皮肤接触地下水经室外吸入空气中气态污染物经室内吸入空气气态污染物。相对于敏感用地,非敏感用地污染物的总致癌风险以及危害商较低。 相似文献
2.
地下水微量有机污染 总被引：9，自引：1，他引：9
在简要评述其污染特征与研究特点的基础上，总结介绍了地下水微量有机污染的分布，污染物种类、性质、危害和来源，有机物的物化特征及其在环境中的迁移转化，以及污染控制技术。非极性难溶挥发性有机物（ＶＯＣ＇ｓ）是地下水中危害最大而又最为常见的有机污染物，主要由氯代脂肪烃（ＣＨＣ）和单环芳香烃（ＢＴＥＸ）构成。多数水溶相ＶＯＣ＇ｓ不易被吸附，在地下环境具有很强的迁移性，但在适当条件下可生物降解。非水溶相ＣＨＣ常在地下水中积聚潜伏于含水层底板，迁移不受地下水流向的控制；非水溶相ＢＴＥＸ则漂浮于地下水表面。非水溶相ＶＯＣ＇ｓ很难产生生物降解。ＶＯＣ＇ｓ的去除过程复杂，许多领域有待探索。 相似文献
3.
非均质含水层中渗流与溶质运移研究进展 总被引：1，自引：1，他引：0
含水层的非均质性控制着地下水渗流和溶质迁移特性,准确定量化描述非均质含水层中的渗流和溶质迁移问题受到广泛关注,已成为地球科学领域中的研究热点。首先从非均质含水层地下水流和溶质迁移理论模型、矩分析、多尺度进行系统综述,指出尺度转换在目前水文地质研究中主要解决的问题以及存在的问题;其次从非均质含水层场地试验、不确定性以及速度连通性等方面分析了该方向的研究进展;最后指出地球物理反演含水层非均质性、随机理论与随机模拟软件开发、尺度转换及速度连通性的不确定性问题、非均质性与水文地质条件关系研究4个方面是该领域今后的主要研究方向。 相似文献
4.
多元非水相流体(NAPLs)造成的地下水污染是严重的问题，这一问题的严重性推动了对这个方面的研究。NAPLs，如有机溶解物和石油烃，它们经常地随机释放到含水层中，由于蔓延引起地下水污染。因为NAPLs具有很低的水的溶解性，所以，少量NAPL便可以污染地下水长达10年。更为严重 相似文献
5.
葛秀珍 《水文地质工程地质技术方法动态》2004,(4):1-10
本报告介绍了位于法德交界地区淤积含水层因硝酸盐和杀虫剂的扩散而受到污染的研究成果。随着地下水中硝酸盐和杀虫剂浓度的增高明显提高了利用地下水的经济部门成本费用。该研究实例研究的目的是污染物的扩散导致的经济损失以及利用货币术语评估相关的成本。该报告介绍了在法国部分(阿尔萨斯地区)含水层进行调查的结果，确定在过去15年中因受到硝酸盐、杀虫剂污染的饮用水公司(DWUs)。资料采源于三个不同方面：(1)当地出版的报纸刊物提供的数据；(2)由负责饮用水发展机构资助的公共机构的主要档案文献资料；(3)通过对22个饮用公司(2003年4月)的面对面的调查访问资料。调查确足了28处严重污染的饮用水供水单位，并强求他们采取投资处理受污染的水以使水质达到饮用水标准。确定饮用水公司使用的不同类型的策略；总的调查费用估计为26．4百万欧元，超过了过去15年总的投资额。此外，通过一家大型酿酒厂(在使用地下水之前已经用很高的费用处理了地下水)的实例确定和说明了工业部门负担的其它花费。然后，先假定污染对地下水的影响的持续时间达20年，作者评估了由于污染导致的未来潜在的损失。并推测到2020年在利用淤积含水层地下水的89个供水站中有37个将因污染扩散而受到影响，因此而增加的额外投资估计每年达到590万欧元。 相似文献
6.
地下水污染源识别模型可利用有限的观测资料估计污染源位置、污染物泄露强度及其泄露过程,是制定地下水污染修复方案的依据。在阐明地下水污染源识别基本问题基础上,综述了污染源识别研究的两大类数学方法,一类为直接方法,包括反向追踪法和基于正则化的方法;另一类为间接方法,包括基于优化的方法和基于概率统计的方法。同时指出了当前污染源识别数学方法应用中存在的主要问题:地下水污染源识别问题的复杂性、地下水有机污染问题和模型求解效率的低下性。对土壤-地下水的联合管理、基于物联网的地下水污染监测、对非水相流体（Non-aqueous Phase Liquid,NAPL）类污染源识别以及基于图形处理器（GPU）的异构并行计算将是未来研究的重点方向。 相似文献
7.
地下水污染问题日益严重,研究溶质运移的弥散理论开始应用于实际问题。建立地下水溶质运移模型,对地下水中污染物的运移及发展趋势进行准确预测,是对地下水进行保护、对地下水污染进行控制的基础。而弥散参数的确定则是地下水溶质运移模型建立的关键环节之一,直接影响着模型预测结果的精度和准确性。 对西宁市贵德县地下水污染的水质运移规律进行分析,在贵德县河滨公园林场采用径向收敛流水动力弥散理论方法进行了第四系含水层现场弥散试验,计算了试验场地潜水含水层的弥散度,获得纵向弥散度(aL)为0.843~0.998 cm,横向弥散度(aT)经验推断值为0.17~0.20 cm,为进一步建立该地区的地下水溶质运移模型、预测地下水污染的发展趋势和评价该地区地下水环境质量提供了数据参考。 相似文献
8.
某石化污染场地含水层自然降解BTEX能力评估 总被引：1，自引：0，他引：1
地下水污染问题是国家关注的重要环境问题之一,监测与评估含水层自然降解污染物能力是防治地下水污染的基本手段,也是国外地下水中修复技术研究热点课题。以华北平原某石油化工类场地为案例,通过调查场地水文地质条件、土壤及地下水污染现状,监测场地地下水中苯系物(BTEX)浓度及相关化学参数变化,运用微生物水文地球化学方法和水文地质方法,估算了该场地含水层自然降解苯系物量。这一研究成果为评估我国石油类场地地下水污染的自然修复能力提供了实证和基础数据。 相似文献
9.
北京某垃圾处置场对地下水的污染 总被引：15，自引：0，他引：15
通过对北京某垃圾场所处的环境地质条件、地层对垃圾污染物的防护能力的调查及对地下水连续1个水文年的污染监测，用单因子和多因子(综合污染指数和内梅罗污染指数)2种方法，评价了该垃圾场对地下水的污染情况。结果表明，该垃圾场对地下水的污染极其严重：综合污染指数可达到59；单项污染组分如NO2^-、NH4^ 、COD等普遍比参照值高出几十倍，致癌物质NO2^-则高出340多倍。从水质的角度看，地下水中有的污染物(NO2^-、NH4^ 、COD)已经超出地下水Ⅲ类水质标准数十倍甚至100多倍，到了不能饮用的程度。这表明地质环境对地下水资源的防护能力直接关系到国土资源的合理利用及城市管理，若垃圾处置场选址不当，将污染地下水资源，影响城市可持续发展。 相似文献
10.
通过对焦作地区浅层地下水中铬(Ⅵ)污染物分布特征进行调查,分析了研究区浅层地下水中铬(Ⅵ)的污染机理,并运用Visual MODFLOW建立地下水流模型及溶质运移模型,模拟预测了浅层地下水中铬(Ⅵ)的迁移规律。结果表明:研究区浅层地下水铬(Ⅵ)污染严重,污染源是位于老君庙西南方向的焦作某电厂堆灰场,主要原因是露天堆放的粉煤灰中的铬(Ⅵ)污染物在长期淋滤作用下下渗污染含水层。气候条件、包气带岩性、地下水化学环境以及人为因素等也间接使浅层地下水铬(Ⅵ)浓度升高;模拟结果显示在未来的五年时间内,受地形和地下水动力场的影响,浅层地下水中铬(Ⅵ)的迁移方向与地下径流方向一致,沿大沙河水流方向上扩散速度更快,污染区域面积逐渐增大。 相似文献
11.
Identification of a karst system’s intrinsic hydrodynamic parameters: upscaling from single springs to the whole aquifer 总被引：1，自引：1，他引：0
Andreas Hartmann Martin Kralik Franko Humer Jens Lange Markus Weiler 《Environmental Earth Sciences》2012,65(8):2377-2389
For water management purposes, information about an entire aquifer system is generally more important than information about
a specific spring. Since a karstic aquifer system might drain to several outlets, conclusions derived from a single spring
can be misleading for characterization and modeling. In this study we apply a conceptual model to an Alpine dolomite karst
system in Austria. The particular challenge was that several small springs with strongly varying hydrological behavior and
diffuse flow into surrounding streams drain this system. Instead of applying the model to a single spring, it was calibrated
simultaneously to several observations within the system aiming to identify the karst system’s intrinsic hydrodynamic parameters.
Parameter identification is supported by modeling the transport of water isotopes (δ18O). The parameters were transferred to the whole system with a simple upscaling procedure and a sensitivity analysis was performed
to unfold influence of isotopic information on parameter sensitivity and simulation uncertainty. The results show that it
is possible to identify system intrinsic parameters. But the sensitivity analysis revealed that some are hardly identifiable.
Only by considering uncertainty reasonable predictions can be provided for the whole system. Including isotopic information
increases the sensitivity of some intrinsic parameters, but it goes along with a sensitivity decrease for others. However,
a possible reduction of prediction uncertainty by isotopic information is compensated by deficiencies in the transport modeling
routines. 相似文献
12.
赵勇胜 《吉林大学学报(地球科学版)》1992,(2)
弥散理论是污染质在含水层中运移模型的基本理论.但在实际应用中存在着不少问题和争议.本文对污染质在含水层中运移的弥散作用进行了分析探讨.并应用MOC水质模型对弥散参数的作用进行了分析,证明了在一般情况下,污染质在含水层中的运移主要受对流作用控制,弥散参数的变化对水质模型结果的影响相对较小.在特定的水文地质条件下,弥散作用对污染质的运移是重要的. 相似文献
13.
选择北京平原区水文地质、环境地质等方面都比较典型的沙子营垃圾堆放场,建立了其水文地质模型。在充分收集资料、分析得出部分计算所需参数后,采用现场弥散实验、勘查取样测试等方法,求得了该含水层的弥散系数等参数;用二维非稳定流溶质运移方程对污染物在此含水层中的迁移扩散规律、速度和污染范围等进行了模拟计算;采用现场钻探、取样测试分析等方法,评价了该含水层的实际污染状况。实验模拟计算和现场调查结果表明:污染物在潜水含水层中的运移规律遵循二维非稳定流场中的溶质运移方程,污染物在潜水含水层中的运移速度约为86.25m/a,迁移扩散主要发生在地下水流向上,侧向扩散宽度极小,是地下水流向上的1/17。 相似文献
14.
Groundwater vulnerability assessment in shallow aquifer of Kathmandu Valley using GIS-based DRASTIC model 总被引：1，自引：0，他引：1
Dhundi Raj Pathak Akira Hiratsuka Isao Awata Luonan Chen 《Environmental Geology》2009,57(7):1569-1578
In this paper, groundwater aquifer vulnerability map has been developed by incorporating the major geological and hydro-geological
factors that affect and control the groundwater contamination using GIS based DRASTIC model. This work demonstrates the potential
of GIS to derive a map by overlying various spatially referenced digital data layers that portrays cumulative aquifer sensitivity
ratings across the Kathmandu Valley, Nepal, providing a relative indication of groundwater vulnerability to contamination.
In fact, the groundwater is the major natural resources in Kathmandu for drinking purpose. The decline in groundwater levels
due to the over exploitation and thus extracted water from shallow aquifer has been contaminated by the infiltration of pollutants
from polluted river and land surface is continuous and serious. As the demand for water for human and industrial use has escalated
and at the same time, the engineering and environmental costs are much higher for new water supplies than maintaining the
existing sources already in use. Management of groundwater source and protecting its quality is therefore essential to increase
efficient use of existing water supplies. Aquifer vulnerability maps developed in this study are valuable tools for environmental
planning and predictive groundwater management. Further, a sensitivity analysis has been performed to evaluate the influence
of single parameters on aquifer vulnerability assessment such that some subjectivity can be reduced to some extent and then
new weights have been computed for each DRASTIC parameters. 相似文献
15.
基于MODFLOW参数不确定性的地下水水流数值模拟方法 总被引：1，自引：0，他引：1
考虑到模型不确定性引起的地下水数值模拟不确定性对模拟过程的影响,在简要介绍含水层水文地质参数变异性研究进展和地质统计学的基础上,基于常用的确定性地下水流数值模拟软件MODFLOW开发了MODFLOW-Gslib软件,相较于传统的数值模拟方法,将地质统计学与数值模拟结合的方法能够模拟非均质含水层中的参数变异性问题。将MODFLOW-Gslib软件运用于模拟实例中,选择常见的不确定性因素进行模拟,并对其模拟产生的数据进行统计分析,结果表明,软件转化后的参数符合水文地质参数不确定性的相关特征;与原模拟结果进行对比,该软件能够更加真实地刻画含水层参数变异性特征。 相似文献
16.
Gradients controlling natural attenuation of ammonium 总被引：1，自引：0，他引：1
Oxidation of reduced pollutants such as in groundwater often takes place at steep redox gradients where oxygenated water is being mixed into polluted water such as landfill leachate. In order to identify controlling parameters and quantify the influence of environmental factors for degradation, sensitivity analysis was performed by means of scenario specific numerical modelling. Geometrical factors such as aquifer thickness have been shown to be very influential on the capability of natural attenuation of pollutants in groundwater. The scenarios investigated here include biodegradation at redox gradients in groundwater, so called fringe processes, for (i) a partly contaminated aquifer with two reaction fronts, (ii) and a spatially variable aquifer thickness. In addition, (iii) the influence of groundwater recharge and (iv) restricted supply of O2 to contaminated water by slow dispersion and diffusion across the capillary fringe are investigated. Contaminated aquifer thickness, zones of enhanced mixing due to flow focussing and diffusion/dispersion coefficients in the capillary fringe are identified qualitatively as controlling factors for natural attenuation under complex conditions, whereas predictive functions will require further research. 相似文献
17.
为了解沉积变质型铁矿床开采后矿区地下水化学特征的变化趋势,在充分掌握矿区含水系统划分和流动系统发育规律的基础上,通过对四含上、四含下、基岩含水层148个水样常规离子的相关性、水化学类型及公因子的分析,得出水化学类型分区和公因子得分等值线,将二者叠加,分析各含水层潜在的形成作用及其控制因素.研究结果表明,四含上以碳酸盐溶滤、污染、氧化作用为主;四含下以污染、溶滤、局部脱硫酸作用为主;基岩含水层以离子交换吸附、第四系水的混合、硅酸盐矿物的不全等溶解作用为主.除了背景因素外,矿山开采后的三维流场控制了基岩含水层的形成作用和原生水化学类型,影响了第四系含水层的局部形成作用,水化学类型分区界线明显移动. 相似文献
18.
One of the most cost-effective in situ technologies for soil and groundwater (i.e., aquifer) remediation is electrokinetic remediation. In electrokinetic remediation, electromigration due to electric field is combined with hydromigration due to hydraulic flow by purge water to remove pollutants from aquifers through the pore water. This study aims at investigating theoretically the role of electromigration (as active movement) of pollutants and the role of hydromigration (as passive movement) of pollutants in electrokinetic remediation, and making it clear that the control variables for electrokinetic remediation are the applied voltage and the hydraulic flow rate. These aims are pursued by construction of a mathematical model based on physico-chemical considerations and by model simulations of the electrokinetic remediation applied to the virtual aquifer polluted by heavy metals of copper sulfate. According to numerical simulations with the model: (1) heavy metal (nonanionic copper) is removed from the upstream anode region and accumulated in the downstream cathode region; (2) to carry away the heavy metal outside the aquifer (global removal), hydromigration by purge water flow is essential; and (3) electromigration contributes mainly to the redistribution of heavy metals within the aquifer (local removal and local accumulation). 相似文献
19.
One of the most important observations that can be obtained from the study of an aquifer system dominated by mixing is the contribution of each end-member water to the chemical composition of every water parcel in the aquifer. Once the first-order effect of mixing has been taken into account via the mixing proportions, water–rock interaction can be used to explain the remaining variability. There are many sources of uncertainty that can prevent the accurate calculation of the mixing proportions of a mixing-dominated system, but the type and intensity of the chemical reactions that have taken place as a consequence of mixing is one of the most critical. Here the uncertainty in the computed mixing proportions of samples from a “synthetic” aquifer system derived from the actuation of different chemical reactions are assessed (always remembering that the chemical reactions are a second-order effect). These uncertainties are explored using two different geochemical codes in order to infer the limits of both methodological approaches: PHREEQC, as an example of a standard geochemical code; and M3, as an example of a Principal Component-based geochemical code. Several synthetic water samples are created with the direct approach of PHREEQC, both by pure mixing and including different types of chemical reactions. Together with the chemical information of the end-member waters, these samples are then fed into PHREEQC (inverse modelling) and M3 and the mixing proportions and mineral mass transfers are computed. PHREEQC calculations give a reasonable estimate of the real mixing proportions and the chemistry of the groundwaters. However, similar mixing proportions and mass transfers can be obtained using different sets of reactions, indicating a source of uncertainty that should be overcome with additional chemical information. For M3, where synthetic samples have been included in a real data set of groundwater samples from the Scandinavian Shield, mixing proportions are only mildly affected either by the number of compositional variables or the number of samples used for the Principal Component Analysis (PCA). However, the robustness of the output is quite sensitive to whether only conservative compositional variables are used or both conservative and non-conservative compositional variables. Mass balance calculations in M3 are much more sensitive to non-conservative compositional variables and the recommendation here is not to use non-conservative variables with PCA-based codes if any information about reactions is to be obtained. 相似文献
20.
在室内砂槽实验尺度,建立了潜水-微承压含水层中电化学-水动力循环系统下混合氯代烃生物降解的反应迁移模型,求取了混合氯代烃体系中各组分的反应动力学参数,并基于模型探究了含水层性质及工艺参数对该修复过程的影响机制.研究结果表明:（1）增大抽水流量可加快反应速率常数大的污染物降解,同时也会抑制反应速率常数较小的污染物去除.（2）增大电流强度和井内电极对氯代烃的好氧降解和厌氧脱氯过程分别具有促进和抑制作用.（3）含水层非均质性越强,氯代烃降解速率越小,这尤其体现在低渗区,且含水层非均质性对易降解污染物修复效果的影响较小. 相似文献