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1.
We report on simultaneous optical and infrared observations of the Halley Family comet 8P/Tuttle performed with the ESO Very Large Telescope. Such multi-wavelength and coordinated observations are a good example of what can be done to support space missions. From high resolution optical spectroscopy of the CN (0,0) 388 nm and NH2 (0,9,0) 610 nm bands using UVES at UT2 we determined 12C/13C = 90 ± 10 and 14N/15N = 150 ± 20 in CN and we derived a nuclear spin temperature of NH3 of 29 ± 1 K. These values are similar to those found in Oort-Cloud and Jupiter Family comets. From low resolution long slit spectroscopy with FORS1 at UT2 we determined the CN, C3 and C2 production rates and the parent and daughter scale lengths up to 5.2 105 km tailward. From high resolution IR spectroscopy with CRIRES at UT1 we measured simultaneously the production rates and mixing ratios of H2O, HCN, C2H2, CH4, C2H6, and CH3OH.  相似文献   

2.
《Icarus》1987,70(2):354-365
Liquid solutions of N2 containing up to one-third CH4 can exist on Triton's surface in regions T > 62.5°K. More generally, subsurface oceans of N2 solution are expected to be stable beneath overlying, thermally insulating, less dense layers of the abundant light hydrocarbon products of radiochemical synthesis: C2H6, C3H8, and C4H10. Cosmic rays are the main source of energy, capable of producing synthesis of organic compounds from N2CH4 solutions on the surface. For baseline Triton models with R = 2500 km, ϱ = 2.1 g cm−3, and Ts = 65 or 55°K, respectively, 4 × 10−3 or 7 × 10−3 erg cm−2 sec−1 (49 or 87% of the total incident flux) is deposited within a few meters below the surface. Using yields from laboratory experiments, we estimate the quantities of products produced: over 4.5 billion years, the cosmic ray flux alone produces 2 to 4 m of organic product, about half of which is C2H6. For ocean depths <250 m, C2H6 will reach its saturation limit and form a surface “slick.” For ocean depths <10 km, all of the other products also oversaturate and exsolve, adding to the surface slick and/or to a denser bottom sediment. Products produced from solid N2CH4 mixtures will accumulate as evaporite deposits because of the rapid volatile transport (of N2 and CH4) over Triton's surface. The complex, reddish organic solid found in laboratory simulations is probably the source of Triton's reddish color. Estimated yields over 4.5 billion years (for 7 × 10−3 erg cm−2 sec−1) are 190 (C2H6), 58 (NH3), 17 (HCN), 3.5 (HN3), 2.5 (C4H10), 0.35 (CH3CN), and 0.14 (C2H5N3) g cm−2. More basic laboratory work on the low-temperature, low-pressure solvent properties and phase equilibria of N2-hydrocarbon systems is clearly needed.  相似文献   

3.
《Icarus》1987,70(1):1-12
An array spectrometer was used on the nights of 1985 May 30–June 1 to observe the disks of Uranus and Neptune in the spectral regions 7–14 and 17–23 μm with effective resolution elements ranging from 0.23 to 0.87 μm. In the long-wavelength region, the spectra are relatively smooth with the broad S(1) H2 collision-induced rotation line showing strong emission for Neptune. In the short-wavelength spectrum of Uranus, an emission feature attributable to C2H2 with a maximum stratospheric mixing ratio of 9 × 10−9 is apparent. An upper limit of 2 × 10−8 is placed on the maximum stratospheric mixing ratio of C2H6. The spectrum of Uranus is otherwise smooth and quantitatively consistent with the opacity provided by H2 collision-induced absorption and spectrally continuous stratospheric emission, as would be produced by aerosols. Upper limits to detecting the planet near 8 μm indicate a CH4 stratospheric mixing ratio of 1 × 10−5 or less, below a value consistent with saturation equilibrium at the temperature minimum. In the short-wavelength spectrum of Neptune, strong emission features of CH4 and C2H6 are evident and are consistent with local saturation equilibrium with maximum stratospheric mixing ratios of 0.02 and 6 × 10−6, respectively. Emission at 8–10 μm is most consistent with a [CH3D]/[CH4] volume abundance ratio of 5 × 10−5. The spectrum of Neptune near 13.5 μm is consistent with emission by stratospheric C2H2 in local saturation equilibrium and a maximum mixing ratio of 9 × 10−7. Radiance detected near 10.5 μm could be attributed to stratospheric C2H4 emission for a maximum mixing ratio of approximately 3 × 10−9. Quantitative results are considered preliminary, as some absolute radiance differences are noted with respect to earlier observations with discrete filters.  相似文献   

4.
The radiative lifetimes of cometary OH are calculated as a function of the heliocentric velocity of the comet and the velocity distributions of the product atoms are determined. At a distance of 1 AU from the Sun, the lifetimes vary between 1.2×105 and 1.9×105 sec at solar minimum and between 1.0×105 and 1.4×105 sec at solar maximum, depending upon velocity. Continuous absorption into the repulsive 12Σ- state is major destruction path. The calculated lifetimes are generally consistent with the lifetimes inferred from observations, but suggest some elaboration of the models is necessary. Photodissociation of OH produces a low-velocity component of hydrogen atoms at 8 km sec?1 relative to the parent OH molecule and a high-velocity component between 17 and 27 km sec?1. Photodissociation of OH leads to metastable O(1D) and O(1S) and is an additional source of the red and green line emission of atomic oxygen. The lifetime of OD is estimated to be about 4.3× 105 sec at solar minimum and 2.6×105 sec at solar maximum so that the OD/OH ratio in comets is enhanced relative to the HDO/H2O production ratio by a factor between 2 and 3. Photodissociation of OD produces only high-velocity D atoms with a mean value of 17 km sec?1.  相似文献   

5.
The Mariner 9 infrared spectrometer obtained data over a large part of Mars for almost a year beginning late in 1971. Mars' infrared emission spectrum was measured from 200 to 2000 cm?1 with an apodized resolution of 2.4 cm?1. No significant deviation from terrestrial ratios of carbon (12C/13C) or oxygen (16O/18O; 16O/17O) isotopes was observed on Mars. The 12C/13C isotopic ratio was found to be terrestrial with an uncertainty of 15%. Upper limits have been calculated for several minor constituents. With an effective noise equivalent radiance of 1.2 × 10?9 W cm?2 sr?1/cm?1, new upper limits in centimeter-atmospheres of 2 × 10?5 for C2H2, 4 × 10?3 for C2H4, 3 × 10?3 for C2H6, 2 × 10?4 for CH4, 1 × 10?3 for N2O, 1 × 10?4 for NO2, 4 × 10?5 for NH3, 1 × 10?3 for PH3, 7 × 10?4 for SO2, and 1 × 10?4 for OCS have been derived.  相似文献   

6.
Spectra of Saturn in the spectral region 10.0–10.7 μm are presented which confirm the presence of PH3. Comparison to synthetic spectra indicates a PH3 mixing ratio of at least 2 × 10?6. No spectral features due to NH3 or C2H4 were observed.  相似文献   

7.
The formation of methylamine (CH3NH2) in the upper troposphere and lower stratosphere of Jupiter is investigated. Translationally hot hydrogen atoms are produced in the photolysis of ammonia, phosphine, and acetylene which react with methane to produce methyl (CH3) radicals; the latter recombine with NH2 to form CH3NH2. Also, methane is catalytically dissociated to CH3 + H by the species C2 and C2H produced in the photolysis of acetylene. It is shown that the combined production of CH3NH2 and subsequent photolysis to HCN is unlikely to account for the HCN observed near Jupiter's tropopause. Recombination of NH2 and C2H5N followed by photolysis to HCN is the preferred path. Production of C2H6 by these two processes is negligible in comparison to the downward flux of C2H6 from the Lyman α photolysis region of CH4. An upper limit column density on CH3PH2 is estimated to be ～1013 cm?2 as compared to 1015 cm?2 for CH3NH2. Hot H atoms account for a negligible fraction of the total ortho-para conversion by the reaction H + H2  相似文献   

8.
《Icarus》1987,72(2):381-393
Bombardment of Titan by Uranus-Neptune planetesimals and/or fragments of a disrupted Hyperion progenitor supplied more than enough energy to drive vigorous atmospheric shock chemistry. Chemical equilibrium modeling of the shock products in simulated atmospheres indicates that impact energy has produced large amounts of N2 and organic compounds over Titan's history. The mole fraction of organic compounds in the shocked gas mixture (T = 1200−2500°K, P = 10−1−103bar) reaches a maximum of approximately 3% in a current Titan mixture and 12% in a primordial CH4, NH3-rich mixture. Atmospheric water mixing ratio controls the organic yield in shock reactions, but its limiting effect may have been reduced by cold-trapping of water in a cooling atmosphere. Kinetic inhibition of graphite formation in the shocked gas enhanced the yield of radicals and organic. The resulting mixture of carbonaceous soot and condensed hydrocarbons subsequently settled onto the surface; the depth of the generated layer was on the order of hundreds of meters. Impact shock energy was capable of converting massive amounts of NH3 to N2 early in Titan history—over twice the present atmospheric and 1.5 times the total ocean-atmospheric inventory of N2. Shock conversion of NH3 into N2 bypasses the difficulties of other schemes of N2 production and may have been of singular importance in Titan's atmospheric evolution.  相似文献   

9.
The 4050 Å band of C3 was observed with Keck/HIRES echelle spectrometer during the Deep Impact encounter. We perform a 2-dimensional analysis of the exposures in order to study the spatial, spectral, and temporal changes in the emission spectrum of C3. The rotational population distribution changes after impact, beginning with an excitation temperature of ～45 K at impact and increasing for 2 hr up to a maximum of 61±5 K. From 2 to 4 hours after impact, the excitation temperature decreases to the pre-impact value. We measured the quiescent production rate of C3 before the encounter to be 1.0×1023 s?1, while 2 hours after impact we recorded a peak production rate of 1.7×1023 s?1. Whereas the excitation temperature returned to the pre-impact value during the observations, the production rate remained elevated, decreasing slowly, until the end of the 4 hr observations. These results are interpreted in terms of changing gas densities in the coma and short-term changes in the primary chemical production mechanism for C3.  相似文献   

10.
Lis  D. C.  Mehringer  D. M.  Benford  D.  Gardner  M.  Phillips  T. G.  Bockelée-Morvan  D.  Biver  N.  Colom  P.  Crovisier  J.  Despois  D.  Rauer  H. 《Earth, Moon, and Planets》1997,78(1-3):13-20
We present millimeter-wave observations of HNCO, HC3N, SO, NH2CHO, H13CN, and H3O+ in comet C/1995 O1 (Hale-Bopp)obtained in February–April, 1997 with the Caltech Submillimeter Observatory (CSO). HNCO, first detected at the CSO in comet C/1996B2 (Hyakutake), is securely confirmed in comet Hale-Bopp via observations of three rotational transitions. The derived abundance with respect to H2O is (4-13) × 10-4. HC3N, SO, and NH2CHO are detected for the first time in a comet. The fractional abundance of HC3N based on observations of three rotational lines is (1.9 ± 0.2) × 10-4. Four transitions of SO are detected and the derived fractional abundance, (2-8) ×10-3, is higher than the upper limits derived from UV observations of previous comets. Observations of NH2CHO imply a fractional abundance of (1-8) × 10-4. H3O is detected for the first time from the ground. The H13CN (3-2)transition is also detected and the derived HCN/H13CN abundance ratio is 90 ± 15, consistent with the terrestrial12C/13C ratio. In addition, a number of other molecular species are detected, including HNC, OCS, HCO+, CO+, and CN(the last two are first detections in a comet at radio wavelengths). This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

11.
A radiative seasonal model which incorporates a multilayer radiative transfer treatment at wave-lengths longward of 7 μm is presented and applied to Saturn's stratosphere. Opacities due to H2-He, CH4, C2H2, and C2H6 are included. Season-dependent insolation is shown to produce a strong hemispheric asymmetry decreasing with depth at the Voyager encounter times, and seasonal amplitudes of 30°K at the poles are predicted in the high stratosphere. The ring-modulated dependence of the insolation and the orbital eccentricity are shown to have a significant effect. Calculations agree closely with the Voyager 1 and 2 radio occultation ingress profiles recorded at 76°S and 36.5°S for CH4/H2 = 3.5 + 1.4/? 1.0 × 10?3;the estimated errors include modeling systematic errors and uncertainties in the occultations profiles. The possible role of aerosols in the stratospheric heating is analyzed. The Voyager 2 egress profile recorded at 31°S cannot be reproduced by calculations. Some constraints on the C2H2 and C2H6 abundances are derived. The upper portion of the occultation profiles (p < 3mbar) can be matched for C2H2/H2 = 1.0 + 1.3/?0.6 × 10?7, C2H6/H2 = 1.5 + 1.8/?0.9 × 10?6 at 76°S and C2H2/H2 = 4 + 6/?4 × 10?8, C2H6/H2 = 6 + 9/?6 × 10?7 at 36.5°N. At the northern occultation latitude, the discrepancy with the concentrations derived from analysis of IRIS spectra by R. Courtin, D. Gautier, A. Marten, B. Bézard, and R. Hanel (1984, Astrophys. J.287) can be explained by a sharp variation of the mixing ratios of these gases with altitude in the upper stratosphere. Other interpretations are discussed.  相似文献   

12.
One-dimensional radial models of the chemistry in cometary comae have been constructed for heliocentric distances ranging from 2 to 0.125 AU. The coma's opacity to solar radiation is included and photolytic reaction rates are calculated. A parent volatile mixture similar to that found in interstellar molecular clouds is assumed. Profiles through the coma of number density and column density are presented for H2O, OH, O, CN, C2, C3, CH, and NH2. Whole-coma abundances are presented for NH2, CH, C2, C3, CN, OH, CO+, H2O+, CH+, N2+, and CO2+.  相似文献   

13.
C/2006 P1 McNaught is a dynamically new comet from the Oort cloud that passed very close to the Sun, driving overall volatile production rates up to about 1031 molecules s−1. Post-perihelion observations were obtained in a target-of-opportunity campaign using the CSHELL instrument at the NASA Infrared Telescope Facility atop Mauna Kea, Hawaii, on UT 2007 January 27 and 28. Eight parent volatiles (H2O, CH4, C2H2, C2H6, HCN, CO, NH3, H2CO) and two daughter fragments (OH and NH2) were detected, enabling the determination of a rotational temperature and production rate for H2O on UT January 27 and absolute and relative production rates for all the detected parent species on UT January 28. The chemical composition measured in the coma suggests that this close perihelion passage stripped off processed outer surface layers, likely exposing relatively fresh primordial material during these observations. The post-perihelion abundances we measure for CO and CH4 (relative to H2O) are slightly depleted while C2H2, NH2 and possibly NH3 are enhanced when compared to the overall comet population. Measured abundances for other detected molecular species were within the range typically observed in comets.  相似文献   

14.
The formation of cometary CN, C2 and C3 radicals is investigated in a photochemical reaction scheme. From an analysis of the observed brightness profiles of these radicals, it is shown that CN is formed as a primary product in the photolysis of its parent molecules, whereas C2 and C3 are formed via two-step photodissociation of their parents. We suggest that major parent of C2 is different species from those of CN and C3 on the basis of the difference of the variation with heliocentric distance of the sublimation rate of the parents of these radicals. Parent molecules and reaction schemes for the formation of these radicals are discussed.  相似文献   

15.
Altitude profiles for the number densities of NO, NO2, NO3, N2O5, HNO2, CH3O, CH3O2, H2CO, OH, and HO2 are calculated as a function of time of day with a steady-state photochemical model in which the altitude profiles for the number densities of H2O, CH4, H2, CO, O3, and the sum of NO and NO2 are fixed at values appropriate to a summer latitude of 34°. Average daily profiles are calculated for the long-lived species, HNO3, H2O2, and CH3O2H.The major nitrogen compound HNO3 may have a number density approaching 5 × 1011 molecules cm?3 at the surface, although an effective loss path due to collisions with particulates could greatly reduce this value.The number density of OH remains relatively unchanged in the first 6 km and reaches 1 × 107 molecules cm?3 at noon, while the number density of HO2 decreases throughout the lower troposphere from its noontime value of 8 × 108 molecules cm?3 at the surface.H2O2 and H2CO both have number densities in the ppb range in the lower troposphere.Owing to decreasing temperature and water concentration, the production of radicals and their steady-state number densities decrease with altitude, reaching a noontime minimum of 1 × 108 molecules cm?3 for OH and 3 × 107 molecules cm?3 for HO2 at the tropopause. The related minor species show even sharper decreases with increasing altitude.The primary path for interconverting OH and HO2 serves as the major sink for CO and leads to a tropospheric lifetime for CO of ~0.1 yr.Another reaction cycle, the oxidation of CH4, is quite important in the lower troposphere and leads to the production of H2CO along with the destruction of CH4 for which a tropospheric lifetime of ~2 yr is estimated.The destruction of H2CO that was produced in the CH4 oxidation cycle provides the major source of CO and H2 in the atmosphere.  相似文献   

16.
We studied the intermediate polar TVCol during and after its flare in November 1982 observed in the ultraviolet range with the International Ultraviolet Explorer. Two spectra revealing the variations of emission lines at different times are presented. We have estimated a new value of the reddening from the 2200 Å absorption feature, E (B ? V ) = 0.12 ± 0.02, and calculated the line fluxes of C IV and He II emission lines produced in the outer accretion disk. The average ultraviolet luminosity of emitting region during and after the flare is approximately 4 × 1032 erg s?1 and 9 × 1030 erg s?1, the corresponding average mass accretion rate is nearly 3 × 1015 erg s?1 (4.76 × 10?11M⊙ yr?1) and 5 × 1013 erg s?1 (7.93 × 10?13M⊙ yr?1), and the average temperature of the emitting region during and after flare is estimated to be of about 3.5 × 103 K and 2 × 103 K. We attribute this flare to a sudden increase in the mass accretion rate leading to the outburst activity.  相似文献   

17.
Spectroscopic observations of Comet Hale-Bopp were made at the 2.6 m Shajn Telescope of the Crimean Astrophysical Observatory. Some spectra were obtained with high spectral resolution, FWHM = 0.18–0.4Å, in the coude focus on February 22 and 26, 1997. The observations were made in selected spectral windows (4805–4872 Å,6528–6595 Å, 7186–7253 Å, 8276–8408 Å).The spectrograph slit was centered on the nucleus and had dimensions of 25.2 × 0.6 arcsec2 on the plane of the sky. The continuum spatial profiles were extremely asymmetrical toward the Sun. However, the continuum-subtracted spatial profiles of the molecular emissions were symmetrical relative to the nucleus, except for C2. The shape of the spatial profiles of the C2 emissions is similar to that one of continuum but is more flattened. So, there are evidences that dust can be an additional source of the C2 radicals in the cometary coma. The main aim of our research was identification of the cometary emissions. Using recent laboratory spectroscopic data we identified newlines of C2 associated with the transitions from high rotational levels in the 4805–4872 Å spectral region. We detected cometary Hα emission as well. Emissions of NH2, H2O+,and C2 (Phillips system) were found in the red spectral windows. Some emission features are still unassigned.  相似文献   

18.
《Icarus》1987,71(3):337-349
This paper represents a final report on the gravity analysis of radio Doppler and range data generated by the Deep Space Network (DSN) with Mariner 10 during two of its encounters with Mercury in March 1974 and March 1975. A combined least-squares fit to Doppler data from both encounters has resulted in a determination of two second degree gravity harmonics, J2 = (6.0 ± 2.0) × 10−5 and C22 = (1.0 ± 0.5) × 10−5, referred to an equatorial radius of 2439 km, plus an indication of a gravity anomaly in the region of closest approach of Mariner 10 to Mercury in March 1975 amounting to a mass deficiency of about GM = −0.1 km3sec−2. An analysis is included that defends the integrity of previously published values for the mass of Mercury (H. T. Howard et al. 1974, Science 185, 179–180; P. B. Esposito, J. D. Anderson, and A. T. Y. Ng 1978, COSPAR: Space Res. 17, 639–644). This is in response to a published suggestion by R. A. Lyttleton (1980, Q. J. R. Astron. Soc. 21, 400–413; 1981, Q. J. R. Astron. Soc. 22, 322–323) that the accepted values may be in error by more than 30%. We conclude that there is no basis for being suspicious of the earlier determinations and obtain a mass GM = 22,032.09 ± 0.91 km3sec−2 or a Sun to Mercury mass ratio of 6,023,600 ± 250. The corresponding mean density of Mercury is 5.43 ± 0.01 g cm−3. The one-sigma error limits on the gravity results include an assessment of systematic error, including the possibility that harmonics other than J2and C22 are significantly different from zero. A discussion of the utility of the DSN radio range data obtained with Mariner 10 is included. These data are most applicable to the improvement of the ephemeris of Mercury, in particular the determination of the precession of the perihelion.  相似文献   

19.
The abundances of PH3, CH3D, and GeH4 are derived from the 2100- to 2250-cm?1 region of the Voyager 1 IRIS spectra. No evidence is seen for large-scale variations of the phosphine abundance over Jovian latitudes between ?30 and +30°. In the atmospheric regions corresponding to 170–200°K, the derived PH3/H2 value is (4.5 ± 1.5) × 10?7 or 0.75 ± 0.25 times the solar value. This result, compared with other PH3 determinations at 10 μm, suggests than the PH3/H2 ratio on Jupiter decreases with atmospheric pressure. In the 200–250°K region, we derive, within a factor of 2, CH3D/H2 and GeH4/H2 ratios of 2.0 × 10?7 and 1.0 × 10?9, respectively. Assuming a C/H value of 1.0 × 10?3, as derived from Voyager, our CH3D/H2 ratio implies a D/H ratio of 1.8 × 10?5, in reasonable agreement with the interstellar medium value.  相似文献   

20.
Glenn S. Orton 《Icarus》1975,26(2):142-158
Observations of Jovian limb structure at 8.11 and 8.45 microns are reported. These are used along with other limb structure and spectral data in the 8–14 micron region to derive a model of the thermal and cloud structure within the 1.0-0.01 bar pressure regime. The model is generally consistent with models derived from Pioneer 10 infrared radiometer data reported by Orton (1975b). The temperature is about 165K at 1.00 bar, 108K at 0.01 bar, and 143K at 0.03 bar. In zones, an optically opaque cloud of NH3 exists near the 143K (0.60 bar) level. A partly transparent haze of solid NH3 particles overlies the cloud. Belts are free of the cloud and have a much lower abundance of NH3 haze than the zones. The data are consistent with an NH3 gas abundance defined by saturation equilibrium, with a mixing ratio of 1.5 × 10?4 deep in the atmosphere, and with a CH4 mixing ratio of 2 × 10?3, about three times the currently accepted value.  相似文献   

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