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1.
Sedimentary, Magmatic and Tectonic Constraints on the Formation of the Yulong Supper-Large Porphyry Copper Polymetal Deposit, East Tibet 总被引：1，自引：0，他引：1
ＳＵＰＲＡ ＳＵＢＤＵＣSEDIMENTARY, MAGMATIC AND TECTONIC CONSTRAINTS ON THE FORMATION OF THE YULONG SUPPER0-LARGE PORPHYRY COPPER POLYMETAL DEPOSIT, EAST TIBET 相似文献
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Zhou Taofa Wu Mingan Fan Yu Duan Chao Yuan Feng Zhang Lejun Liu Jun Qian Bing Franco Pirajno David R. Cooke 《Ore Geology Reviews》2011,43(1):154-169
The Middle-Lower Yangtze (Changjiang) River Valley metallogenic belt is located on the northern margin of the Yangtze Craton of eastern China. Most polymetallic deposits in the Changjiang metallogenic belt are clustered in seven districts where magmatism of Mesozoic age (Yanshanian tectono-thermal event) is particularly extensive. From west to east these districts are: E-dong, Jiu-Rui, Anqing-Guichi, Lu-Zong, Tong-Ling, Ning-Wu and Ning-Zhen. World-class iron ore deposits occur in the Lu-Zong and Ning-Wu ore clusters, which are mainly located in continental fault-bound volcanic-sedimentary basins. One of these deposits is the Longqiao iron deposit, discovered in the northern part of the Lu-Zong Basin in 1985. This deposit consists of a single stratabound and stratiform orebody, hosted in sedimentary carbonate rocks of the Triassic Dongma'anshan Formation. A syenite pluton (Longqiao intrusion) is situated below the deposit. The iron ore is massive and disseminated and the ore minerals are mainly magnetite and minor pyrite. Wall rock alteration mostly consists of skarn minerals, such as diopside, garnet, potassic feldspar, quartz, chlorite, phlogopite and anhydrite. Thin sedimentary siderite beds of Triassic age occur as relict laminated ore at the top and the margin of the magnetite orebody. These sideritic laminae are part of Triassic evaporite-bearing carbonate deposits (Dongma'anshan Formation).Sulfur isotopic compositions show that the sulfur in the deposit was derived from a mixture of magmatic hydrothermal fluids and carbonate–evaporite host rocks. Similarly, the C and O isotopic compositions of limestones from the Dongma'anshan Formation indicate that these rocks interacted with magmatic hydrothermal fluids. The O isotopic compositions of the syenitic rocks and minerals from the deposit show that the hydrothermal magnetite and skarn minerals were formed from magmatic fluids. The Pb isotopic compositions of sulfides are similar to those of the Longqiao syenite. Phlogopite coexisting with magnetite in the magnetite ores yielded a plateau age of 130.5 ± 1.1 Ma (2σ), whereas the LA-ICP MS age of the syenite intrusion is 131.1 ± 1.5 Ma, which is slightly older than the age of phlogopite.The Longqiao syenite intrusion may have crystallized from a parental alkaline magma, generated by partial melting of lithospheric mantle, during extensional tectonics. The ore fluids were probably first derived from magma at depth, later emplaced in the sedimentary rocks of the Dongma'anshan Formation, where it interacted with siderite and evaporite-bearing carbonate strata, resulting in the formation of magnetite and skarn minerals. The Longqiao iron deposit is a skarn-type stratabound and stratiform mineral system, genetically and temporally related to the Longqiao syenite intrusion. The Longqiao syenite is part of the widespread Mesozoic intracontinental magmatism (Yanshanian event) in eastern China, which has been linked to lithospheric delamination and asthenospheric upwelling. 相似文献
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The Dongfengnanshan Cu polymetallic deposit is one representative deposit of the Tianbaoshan ore district in the Yanbian area, northeast(NE) China. There occur two types of ore bodies in this deposit, the stratiform ore bodies and veintype ones, controlled by the Early Permian strata and the Late Hercynian diorite intrusion, respectively. Due to the ambiguous genetic type of the stratiform ore bodies, there has been controversy on the relationship between them and veintype ore bodies. To determine the genetic type of stratiform ore bodies, laser ablation inductively coupled plasma mass spectrometry(LA-ICP-MS) in situ trace elements and S–Pb isotope analysis have been carried on the sulfides in the stratiform ore bodies. Compared with that in skarn, Mississippi Valley-type(MVT), and epithermal deposits, sphalerite samples in the stratiform ore bodies of the Dongfengnanshan deposit are significantly enriched in Fe, Mn, and In, while depleted in Ga, Ge, and Cd, which is similar to the sphalerite in volcanic-associated massive sulfide(VMS) deposits. Co/Ni ratio of pyrrhotites in the stratiform ore bodies is similar to that in VMS-type deposits. The concentrations of Zn and Cd of chalcopyrites are similar to those of recrystallized VMS-type deposits. These characteristics also reflect the intermediate ore-forming temperature of the stratiform ore bodies in this deposit. Sulfur isotope compositions of sulfides are similar to those of VMS-type deposits, reflecting that sulfur originated from the Permian Miaoling Formation. Lead isotope compositions indicate mixed-source for lead. Moreover, the comparison of the Dongfengnanshan stratiform ore bodies with some VMStype deposits in China and abroad, on the trace elements and S–Pb isotope characteristics of the sulfides reveals that the stratiform ore bodies of the Dongfengnanshan deposit belong to the VMS-type, and have closely genetic relationship with the early Permian marine volcanic sedimentary rocks. 相似文献
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《International Geology Review》2012,54(9):1031-1051
The geotectonic units of Zhejiang Province include the Yangtze Plate in the northwest juxtaposed against the South China fold system in the southeast along the Jiangshan–Shaoxing fault. The South China fold system is further divided into the Chencai–Suichang uplift belt and the Wenzhou–Linhai geotectogene belt, whose boundary is the Yuyao–Lishui fault. The corresponding metallogenic belts are the Mo–Au(–Pb–Zn–Cu) metallogenic belt in northwest Zhejiang, the Chencai–Suichang Au–Ag–Pb–Zn–Mo metallogenic belt, and the coastal Ag–Pb–Zn–Mo–Au metallogenic belt. The main Mesozoic metal ore deposits include epithermal Au–Ag(Ag), hydrothermal vein-type Ag–Pb–Zn(Cu), and porphyry–skarn-type Mo and vein-type Mo deposits. These ore bodies are related to the Mesozoic volcanic-intrusive structure: the epithermal Au–Ag(Ag) deposits are represented by the Zhilingtou Au–Ag deposit and Houan Ag deposit and their veins are controlled by volcanic structure; the hydrothermal vein-type Ag–Pb–Zn deposits are represented by the Dalingkou Ag–Pb–Zn deposit and also controlled by volcanic structure; and the porphyry–skarn-type Mo deposits are represented by the Tongcun Mo deposit and the vein-type Mo deposits are represented by the Shipingchuan Mo deposit, all of which are related to granite porphyries. These metal ore deposits have close spatio-temporal relationships with each other; both the epithermal Au–Ag(Ag) deposits and the hydrothermal vein-type Ag–Pb–Zn deposits exhibit vertical zonations of the metallic elements and form a Mo–Pb–Zn–Au–Ag metallogenetic system. These Jurassic–Cretaceous deposits may be products of tectonic-volcanic-intrusive magmatic activities during the westward subduction of the Pacific Plate. Favourable metallogenetic conditions and breakthroughs in the recent prospecting show that there is great resource potential for porphyry-type deposits (Mo, Cu) in Zhejiang Province. 相似文献
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WANG Xiaohu SONG Yucai ZHANG Hongrui LIU Yingchao PAN Xiaofei GUO Tao 《《地质学报》英文版》2018,92(4):1486-1507
The Lanping Basin in the Nujiang‐Lancangjiang‐Jinshajiang (the Sanjiang) area of northeastern margin of the Tibetan Plateau is an important part of eastern Tethyan metallogenic domain. This basin hosts a number of large unique sediment‐hosted Pb‐Zn polymetallic deposits or ore districts, such as the Baiyangping ore concentration area which is one of the representative ore district. The Baiyangping ore concentration area can be divided into the east and west ore belts, which were formed in a folded tectogene of the India‐Asia continental collisional setting and was controlled by a large reverse fault. Field observations reveal that the Mesozoic and Cenozoic sedimentary strata were outcropped in the mining area, and that the orebodies are obviously controlled by faults and hosted in sandstone and carbonate rocks. However, the ore‐forming elements in the east ore belt are mainly Pb‐Zn‐Sr‐Ag, while Pb‐Zn‐Ag‐Cu‐Co elements are dominant in the west ore belt. Comparative analysis of the C‐O‐Sr‐S‐Pb isotopic compositions suggest that both ore belts had a homogeneous carbon source, and the carbon in hydrothermal calcite is derived from the dissolution of carbonate rock strata; the ore‐forming fluids were originated from formation water and precipitate water, which belonged to basin brine fluid system; sulfur was from organic thermal chemical sulfate reduction and biological sulfate reduction; the metal mineralization material was from sedimentary strata and basement, but the difference of the material source of the basement and the strata and the superimposed mineralization of the west ore belt resulted in the difference of metallogenic elements between the eastern and western metallogenic belts. The Pb‐Zn mineralization age of both ore belts was contemporary and formed in the same metallogenetic event. Both thrust formed at the same time and occurred at the Early Oligocene, which is consistent with the age constrained by field geological relationship. 相似文献
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Qingdong Zeng Yongbin Wang Song Zhang Jianming Liu Kezhang Qin Jinhui Yang Weidong Sun Wenjun Qu 《Resource Geology》2013,63(1):99-109
Mesozoic ore deposits in Zhejiang Province, Southeast China, are divided into the northwestern and southeastern Zhejiang metallogenic belts along the Jiangshan–Shaoxing Fault. The metal ore deposits found in these belts are epithermal Au–Ag deposits, hydrothermal‐vein Ag–Pb–Zn deposits, porphyry–skarn Mo (Fe) deposits, and vein‐type Mo deposits. There is a close spatial–temporal relationship between the Mesozoic ore deposits and Mesozoic volcanic–intrusive complexes. Zircon U–Pb dating of the ore‐related intrusive rocks and molybdenite Re–Os dating from two typical deposits (Tongcun Mo deposit and Zhilingtou Au–Ag deposit) in the two metallogenic belts show the early and late Yanshanian ages for mineralization. SIMS U–Pb data of zircons from the Tongcun Mo deposit and Zhilingtou Au–Ag deposit indicate that the host granitoids crystallized at 169.7 ± 9.7 Ma (2σ) and 113.6 ± 1 Ma (2σ), respectively. Re–Os analysis of six molybdenite samples from the Tongcun Mo deposit yields an isochron age of 163.9 ± 1.9 Ma (2σ). Re–Os analyses of five molybdenite samples from the porphyry Mo orebodies of the Zhilingtou Au‐Ag deposit yield an isochron age of 110.1 ± 1.8 Ma (2σ). Our results suggest that the metal mineralization in the Zhejiang Province, southeast China formed during at least two stages, i.e., Middle Jurassic and Early Cretaceous, coeval with the granitic magmatism. 相似文献
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深源岩浆作用与江西德兴大型矿集区成矿关系 总被引：6，自引：0，他引：6
德兴大型矿集区范围约长２０ｋｍ,宽１０ｋｍ,已发现３个大矿田１３个矿床和许多矿点。赣东北深断裂带控制了区域构造演化,岩浆活动和成矿作用。德兴矿集区的形成是构造－岩浆－成矿统一的地质作用的结果。深源岩浆作用对大规模多金属成矿有决定性的影响。中－新元古代海相火山喷发营造了双桥山群成矿建造— 矿源层。中生代I型花岗岩浆活动对大规模多金属成矿的制约主要有5个方面：(1)供给Cu、Pb、Zn、Au、Ag等成矿金属元素;(2)产生成矿热流体;(3)提供成矿热驱动力;(4)营造成矿空间;(5)激活围岩“矿源层”中的成矿物质参与成矿。 相似文献
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Stratiform sediment hosted Zn–Pb–Ag deposits, often referred to as SEDEX deposits, represent an economically important class of ore, that have received relatively little attention in terms of defining lithochemical halos and geochemical vectors useful to exploration. This study concentrates on the Lady Loretta deposit which is a typical example of the class of Proterozoic SEDEX deposits in northern Australia. We examined the major and trace element chemistry of carbonate-bearing sediments surrounding the deposit and defined a series of halos which extend for several hundred metres across strike and up to 1.5 km along strike. The stratiform ore lens is surrounded by an inner sideritic halo [Carr, G.R., 1984. Primary geochemical and mineralogical dispersion in the vicinity of the Lady Loretta Zn–Pb–Ag deposit, North Queensland. J. Geochem. Expl. 22, 217–238], followed by an outer ankerite/ferroan dolomite halo which merges with low iron dolomitic sediments representative of the regional background compositions. Carbonate within the inner siderite halo varies in composition from siderite to pistomesite (Fe0.6Mg0.4CO3), whereas carbonate in the outer ankerite halo varies from ferroan dolomite to ankerite (Ca0.5Mg0.3Fe0.2CO3). Element dispersion around the stratiform ore lens is variable with Pb, Cu, Ba and Sr showing very little dispersion (<50 m across strike), Zn and Fe showing moderate dispersion (<100 m) and Mn and Tl showing broad dispersion (<200 m). Within the siderite halo Cu, Mg and Na show marked depletion compared to the surrounding sediments. The magnitude of element dispersion and change in carbonate chemistry around the Lady Loretta orebody has enabled the development of three geochemical vectors applicable to exploration. Whole rock analyses are used to calculate the three vector quantities as follows: (1) SEDEX metal index = Zn + 100Pb + 100Tl; (2) SEDEX alteration index = (FeO + 10MnO)100/(FeO + 10MnO + MgO); (3) manganese content of dolomite: MnOd = (MnO × 30.41)/CaO. All three vectors increase to ore both across strike and along strike. The manganese content of dolomite (MnOd) exhibits the most systematic pattern increasing from background values of about 0.2 wt% to a maximum of around 0.6 wt% at the boundary between the ankerite and siderite halos. Siderite within the inner halo contains considerably more Mn with MnO values of 0.4 to 4.0 wt%. It is suggested here that the basket of indices defined at Lady Loretta (Zn, Tl, metal index, alteration index, MnOd and MnOs) is applicable in the exploration for stratiform Zn–Pb–Ag deposits in dolomite-rich sedimentary basins generally. The indices defined can firstly assist in the identification of sedimentary units favourable for SEDEX mineralisation, and secondly provide vectors along these units to ore. The alteration index and MnOd, however, should only be used for exploration dolomitic sequences; they are not recommended for exploration in clastic sequences devoid of carbonates. 相似文献
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太行山北段中生代成矿时间演化 总被引：2，自引：0，他引：2
晚期岩浆和水热成矿作用一直是矿床学研究的重要课题。特别是对岩浆和水热两类作用之间的过渡成矿作用（上界是岩浆水相的出现,下界是岩浆的水饱和固相线）更是当前研究工作的前缘。富水挥发物相的演化和分离是其中心问题。从实验岩石学方面探索,从总结地区和矿床成矿时间演化角度归纳分析,都是积累资料深化认识的基本方法。太行山北段中生代岩浆活动频繁,成矿作用强烈,岩体和岩石种类、矿点和矿化类型都很多。这一地区成矿顺序和矿床形成阶段有明显的规律性,反映了深处岩浆挥发物相演化和分离的特点。文章在介绍有关岩浆活动和成矿作用地质情况的基础上,讨论了成矿时间演化的特点和原因。 相似文献
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The Qingchengzi orefield is a large polymetallic ore concentration area in the Liaodong peninsula,northeastern China,that includes twelve Pb-Zn deposits and five Au-Ag deposits along its periphery.The ore-forming age remains much disputed,which prevents the identification of the relationship between the mineralization and the associated magmatism.In this paper,we quantitatively present the feasibility of making ore mineral ~(40)Ar/~(39)Ar dating and report reliable ~(40)Ar/~(39)Ar ages of lamprophyre groundmass,K-feldspar and sphalerite from the Zhenzigou deposit.Direct and indirect methods are applied to constrain the timing of mineralization,which plays a vital role in discussing the contribution of multistage magmatism to ore formation.The low-potassium sphalerite yielded an inverse isochron age of 232.8±41.5 Ma,which features a relatively large uncertainty.Two lamprophyre groundmasses got reliable inverse isochron ages of 193.2±1.3 Ma and 152.3±1.5 Ma,respectively.K-feldspar yielded a precise inverse isochron age of 134.9±0.9 Ma.These four ages indicate that the mineralization is closely associated with Mesozoic magmatism.Consequently,regarding the cooling age of the earliest Mesozoic Shuangdinggou intrusion(224.2±1.2 Ma)as the initial time of mineralization,we can further constrain the age of the sphalerite to 224–191 Ma.These new and existing geochronological data,combined with the interaction cutting or symbiotic relationship between the lamprophyre veins and ore veins,suggest that the Pb-Zn-Au-Ag mineralization in the Qingchengzi orefield mainly occurred during three periods:the late Triassic(ca.224–193 Ma),the late Jurassic(ca.167–152 Ma)and the early Cretaceous(ca.138–134 Ma).This polymetallic deposits are shown to have been formed during multiple events coinciding with periods of the Mesozoic magmatic activity.In contrast,the Proterozoic magmatism and submarine exhalative and hydrothermal sedimentation in the Liaolaomo paleorift served mainly to transport and concentrate the ore-forming substances at the Liaohe Group with no associated Pb-Zn-Au-Ag mineralization. 相似文献
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本文以地层地球化学、同位素地球化学等理论为指导,论证了西成铅锌矿田成矿金属物质主要来自基底前泥盆系;在查明矿田成矿物理化学条件和基底地层铅锌赋存形式的基础上,以成矿模拟实验为手段,探讨了基底地层中成矿元素Pb、Zn的活化机理及其控制因素。 相似文献
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The Xiaohongshilazi deposit located in central Jilin Province, Northeast China, is a newly discovered and medium‐scale Pb–Zn–(Ag) deposit with ore reserves of 34,968 t Pb, 100,150 t Zn, and 158 t Ag. Two‐stage mineralization has been identified in this deposit. Stratiform volcanic‐associated massive sulfide (VMS) Pb–Zn mineralization interbedding with the marine volcanic rocks of the Late Carboniferous–Early Permian Daheshen Formation was controlled by the premineralization E–W‐trending faults. Vein‐type Pb–Zn–(Ag) mineralization occurs within or parallel to the granodiorite and diorite porphyries controlled by the major‐mineralization N–S‐trending faults that cut the stratiform mineralization and volcanic rocks. To constrain the age of vein‐type Pb–Zn–(Ag) mineralization and determine the relationship between mineralization and magmatism, we conducted LA–ICP–MS U–Pb dating on zircon from the ore‐bearing granodiorite and diorite porphyries and Rb–Sr dating on metal sulfide. Granodiorite and diorite porphyries yield zircon U–Pb weighted‐mean 206Pb/238U ages of 203.6 ± 1.8 Ma (Mean Standard Weighted Deviation [MSWD] = 1.8) and 225.6 ± 5.1 Ma (MSWD = 2.3), respectively. Sulfides from four vein‐type ore samples yield a Rb–Sr isochron age of 195 ± 17 Ma (MSWD = 4.0). These results indicate a temporal relationship between the granodiorite porphyry and vein‐type Pb–Zn–(Ag) mineralization. The granodiorite associated with vein‐type mineralization has high SiO2 (68.99–70.49 wt.%) and Na2O (3.9–4.2 wt.%; Na2O/K2O = 1.07–1.10) concentrations, and A/CNK values of 0.95–1.04; consequently, the intrusion is classified as a high‐K, calc‐alkaline, metaluminous I‐type granite. The granodiorite porphyry is enriched in large‐ion lithophile elements (e.g. Rb, Th, U, and K) and light REE and is depleted in high‐field‐strength elements (e.g. Nb, Ta, P, and Ti) and heavy REE, indicating that it represents a subduction‐related rock that formed at an active continental margin. Furthermore, the granodiorite porphyry has Mg# values of 31–34, indicating a lower crustal source. Based on petrological and geochemical features, we infer that the ore‐bearing granodiorite porphyry was derived from the partial melting of the lower crust. In summary, mineralization characteristics, cross‐cutting relationships, geochronological data, and regional tectonic evolution indicate that the region was the site of VMS Pb–Zn mineralization that produced stratiform orebodies within the Late Carboniferous–Early Permian marine volcanic rocks of the Daheshen Formation, followed by mesothermal magmatic hydrothermal vein‐type Pb–Zn–(Ag) mineralization associated with granodiorite porphyry induced by the initial subduction of the Paleo‐Pacific Plate beneath the Eurasia Plate during the Late Triassic–Early Jurassic. 相似文献
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对冀北１７个银矿床地质调查和５个大一中型银矿床地质、地球化学剖析研究基础上,从银矿床产出的区域地质、矿床地质、控制地质条件、围岩蚀变、矿石类型、成矿机理、成矿时代和成矿物质演化上,确定了冀北银矿床有３个成矿系列,８种矿床类型。提出牛圈子为火山喷气－热泉型银矿床;蔡家营为古喷气－热水沉积变质－热液叠加型铅锌银矿床;银冶岭为层控－热液叠加型铅锌银矿床的新认识,建立了冀北银矿床成矿模式和地史演化的区域成 相似文献
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Peter Marchev Majka Kaiser-Rohrmeier Christoph Heinrich Maria Ovtcharova Albrecht von Quadt Raya Raicheva 《Ore Geology Reviews》2005,27(1-4):53
The Rhodope Massif in southern Bulgaria and northern Greece hosts a range of Pb–Zn–Ag, Cu–Mo and Au–Ag deposits in high-grade metamorphic, continental sedimentary and igneous rocks. Following a protracted thrusting history as part of the Alpine–Himalayan collision, major late orogenic extension led to the formation of metamorphic core complexes, block faulting, sedimentary basin formation, acid to basic magmatism and hydrothermal activity within a relatively short period of time during the Early Tertiary. Large vein and carbonate replacement Pb–Zn deposits hosted by high-grade metamorphic rocks in the Central Rhodopean Dome (e.g., the Madan ore field) are spatially associated with low-angle detachment faults as well as local silicic dyke swarms and/or ignimbrites. Ore formation is essentially synchronous with post-extensional dome uplift and magmatism, which has a dominant crustal magma component according to Pb and Sr isotope data. Intermediate- and high-sulphidation Pb–Zn–Ag–Au deposits and minor porphyry Cu–Mo mineralization in the Eastern Rhodopes are predominantly hosted by veins in shoshonitic to high-K calc-alkaline volcanic rocks of closely similar age. Base-metal-poor, high-grade gold deposits of low sulphidation character occurring in continental sedimentary rocks of synextensional basins (e.g., Ada Tepe) show a close spatial and temporal relation to detachment faulting prior and during metamorphic core complex formation. Their formation predates local magmatism but may involve fluids from deep mantle magmas.The change in geochemical signatures of Palaeogene magmatic rocks, from predominantly silicic types in the Central Rhodopes to strongly fractionated shoshonitic (Bulgaria) to calc-alkaline and high-K calc-alkaline (Greece) magmas in the Eastern Rhodopes, coincides with the enrichment in Cu and Au relative to Pb and Zn of the associated ore deposits. This trend also correlates with a decrease in the radiogenic Pb and Sr isotope components of the magmatic rocks from west to east, reflecting a reduced crustal contamination of mantle magmas, which in turn correlates with a decreasing crustal thickness that can be observed today. Hydrogen and oxygen isotopic compositions of the related hydrothermal systems show a concomitant increase of magmatic relative to meteoric fluids, from the Pb–Zn–Ag deposits of the Central Rhodopes to the magmatic rock-hosted polymetallic gold deposits of the Eastern Rhodopes. 相似文献
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作为华南大面积低温成矿域的重要组成部分,川滇黔铅锌矿集区是我国重要的铅锌银等资源基地之一,同时该矿集区也是Ge、Cd、Ga和In等稀散元素的超常富集区域。毛坪矿床是该矿集区内第二大铅锌矿床,累计探明铅锌金属储量超过3Mt(Pb+Zn平均品位≥18%),锗(Ge)保有储量182t。本文以新发现的Ⅵ矿带(铅锌金属已探明储量≥60万t,Pb+Zn平均品位≥20%)为研究对象,利用LA-ICPMS对主要矿石矿物闪锌矿和黄铁矿进行了微区原位微量元素组成和Mapping分析。研究结果显示Ⅵ矿带闪锌矿普遍富集Ge(最高580×10^(-6),均值81.1×10^(-6))、Cd(最高3486×10^(-6),均值1613×10^(-6))和Ga(最高190×10^(-6),均值44.4×10^(-6));黄铁矿普遍富集Mn、As、Pb、Cu、Ag和Sb。与Ⅰ和Ⅱ号矿带闪锌矿相比,Ⅵ号矿带闪锌矿更富集Ge和Ga。闪锌矿中Fe和Pb以类质同象为主,偶见黄铁矿和方铅矿显微包体;Cu、Ge、Ag和As赋存形式主要为类质同象,替代方式为Ge^(4+)+2(Cu+,Ag+,As+)↔3Zn^(2+);Cd以类质同象方式赋存为主,替代机制为Cd^(2+)↔Zn^(2+);Ga和In可能主要以类质同象方式存在。黄铁矿中Pb和Mn主要以方铅矿和碳酸盐矿物显微包体为主;Cu、As和Sb以类质同象形式存在于黄铁矿中;Ag和Zn可能以独立矿物形式赋存;Co和Ni以类质同象方式替代Fe进入黄铁矿晶格中,替代方式为Ni^(2+)+Co^(2+)↔2Fe^(2+)。毛坪矿床新发现Ⅵ矿带硫化物相比典型MVT矿床硫化物具有不同的In和Ge含量以及Cd/Fe比值,结合矿床地质特征和其他证据,表明毛坪矿床成因类型特殊,有别于经典MVT铅锌矿床,属于川滇黔型铅锌矿床。 相似文献
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Gejiu is geographically located near Gejiu city, SW China. It is one of the largest tin-polymetallic districts in the world and contains approximately 3 million tons (Mt) of Sn and smaller quantities of Cu, Pb, and Zn. The deposit primarily yields three different types of ore: skarn-hosted ore, basalt-hosted stratiform ore, and carbonate-hosted stratiform ore. Kafang is one of the primary ore deposits in the Gejiu district and is an unusual occurrence hosted in basaltic rocks. Genetic models of the Kafang deposit suggest that it is related either to Anisian (Lower stage of Middle Triassic) Gejiu basalts or to Cretaceous Gejiu granite. In this study, we performed zircon SIMS U–Pb dating, major and trace element analyses, and Sr–Nd–Pb isotopic analyses for the Gejiu basalts and S isotopic analyses for stratiform Cu ore. Our results and previous studies are used to interpret the petrogenesis of the Gejiu basalts and the origin of the basalt-hosted stratiform Cu deposit. The SIMS zircon U–Pb analyses of the Gejiu basalts yield an age of 244.4 Ma. The trace element ratios of the Gejiu basalts are similar to those of ocean island basalt and have positive εNd(t) values (ranging from 0.6 to 2.5) and uniform (87Sr/86Sr)i values (ranging from 0.70424 to 0.70488). These ratios are close to those of the Permian Emeishan flood basalt. Thus, the Gejiu basalts may represent coeval volcanisms within the plate involving remelting of the Emeishan plume head through a stress relaxation process after the main plume event. The Pb and S isotopic compositions of the Gejiu basalts and the stratiform Cu ores indicate that the source of Cu and S is primarily derived from the Gejiu basalts. However, the age of sulfide mineralization (84.2–79.6 Ma) and the age of hydrothermal alteration (85.5–81.9 Ma) are temporally consistent with the age of the Cretaceous granite emplacement (85.5–83.3 Ma). From a petrological and geochemical study, we determine that the Gejiu basalts may have been subjected to pervasive granite-related hydrothermal alteration during the emplacement of granite. These processes increase the K and Mg contents of basalt and probably caused the formation of the Cu ores. Thus, the Kafang stratiform Cu deposit can be considered as a granite-related hydrothermal deposit. 相似文献