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对辽河油田源油、有机质的Ｐｂ,Ｓｒ,Ｎｄ同位素进行了研究。原油、有机质的Ｐｂ,Ｓｒ,Ｎｄ同位素资料的分析表明：在辽河油田,仅有极少部分原油与老乡经三系有机质热解有关,大部部分原油为地幔流体与古生界、震旦系海相碳酸盐岩壳－幔相互作用而生成,另一大部分则为地幔流体的ＣＯ,ＣＯ２与Ｈ２的费托合成反应生成。油源对比表明：老第三纪以下的古生代前陆盆地有更大的油气前景。 相似文献
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Joshua D. Cocker 《Australian Journal of Earth Sciences》2013,60(1-2):139-158
Biotite igneous ages and well‐defined isochron ages of plutons from the composite Blue Tier Batholith and the Coles Bay area in northeastern Tasmania range from 395 to 370 Ma. The older limit of this range, for the George River granodiorite, is considerably older than any age previously recorded for NE Tasmania. The ages of the youngest plutons (Mt Paris and Anchor granites), which host cassiterite ores, record pervasive hydrothermal alteration events. The initial 87Sr/80Sr ratios of the granitoids range from 0.7061 to 0.7136 and suggest different protolith compositions, consistent with mineralogical and geochemical characteristics of each pluton. The S‐type garnetbiotite granites (Ansons Bay and Booby alia granites) have initial ratios greater than 0.7119, indicative of enriched, high Rb/Sr ratio, crustal source‐rocks of Proterozoic age (1700–800 Ma). The S‐type biotite granites (Poimena and Pearson granites) have relatively high initial 87Sr/86Sr ratios (0.7070, 0.7105) but overlap with those of the I‐type granodiorites (George River, Scamander Tier, Pyengana and Coles Bay granodiorites) which are in the range of 0.7061 to 0.7073. The initial ratios of the enriched altered plutons are poorly constrained, and on both hand‐specimen and thin‐section scales, reveal open‐system Sr isotopic patterns. Isochron ages for the arenite‐lutite and lutite sedimentary associations of the Mathinna Beds, which are intruded by the granitoids, reflect an approach to Sr isotopic equilibrium during regional metamorphism. The metamorphic age (401 ± 7 Ma) of the early Pragian arenite‐lutite association indicates a relatively small time interval between deposition, regional metamorphism and granitoid intrusion. The isotopic age for the lutite sedimentary association (423 ± 22 Ma) is tentatively correlated with a Benambran‐age burial metamorphic event that has not previously been recorded in Tasmania. 相似文献
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大别山麻粒岩和TTG片麻岩的Sr,Nd,Pb同位素地球化学 总被引：4，自引：1，他引：4
北大别4个麻粒岩和4个TTG片麻岩样品的Sr,Nd同位素分析结果表明，样品普遍具有较高的锶同位素比值（^87Sr/^86Sr=0.7066-0.7461)，较低的Nd同位素比值（^143Nd/^144Nd=0.5108-0.5124)，表现出明显的壳源特征，结合铅同位素的组成来看，北大别麻粒岩及TTG片麻岩的同位素成分相当于－下地壳。岩石的特源为古老的地壳，大约在2－3Ga之间，少数样品的同位素特征可能暗示源区有年轻地壳物质的加入。 相似文献
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The current use of untreated river water for drinking purposes by the population of French Guiana has important impacts on public health. Consequently, groundwater is of major importance as a possible alternative drinking water supply to reduce these impacts. Since French Guiana belongs to the Guyana Shield, sustainable water management can be expected to depend increasingly on water from fissured aquifers in hard rocks. Groundwater samples were collected from shallow drill holes in the densely populated coastal area, and deeper wells in the basement (around Cayenne and along the Maroni and Oyapock rivers). This study reports on major and trace elements for which Na+ and Ca2+ excess with regard to Cl reflect the role of water-rock interaction, as well as Sr and Nd isotopes that reflect the role of the different lithologies. δ18O and δD in waters give constraints on the water cycle (recharge and evaporation processes). 相似文献
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安徽的地壳演化:Sr,Nd同位素证据 总被引：13，自引：0，他引：13
在地壳(幔)演化和板块构遣的框架内，评述了有关安徽南部(扬子地块东部，包括大别遣山带和江南遣山带)的同位素地质年代学和Nd，Sr同位素地球化学示踪研究的成果。该地区出露地表的中元古界溪口群浅变质岩代表皖南的基底，沿江地区和大别山区的基底包舍太古宇或／和古元古界古老岩石。此格局还影响到从震旦纪到古生代沉积岩的物源区，江南深断裂以北的沉积岩中有古老岩石的贡献，而以南的物源主要来自出露的中元古界岩石。扬子陆块南北缘(大别和江南遣山带)的晋宁期演化可能与罗迪尼亚超大陆演化有密切关系，但有关研究开展很少。三叠纪大陆深俯冲和超高压变质作用研究已成为国际地球科学的热点。晚中生代(120-140Ma)本区发生强烈的岩浆活动，并伴有重要矿床的形成。中酸性岩的形成是一种壳幔物质混合的过程。沿江地区陆下地幔具有富集特征，为扬子型岩石圈地幔与软流圈地幔混合的产物。从晚中生代到第四纪，基性岩指示其源区的地球化学性质有随时间变得越来越亏损的趋势。 相似文献
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长江,黄河流域泛滥平原细粒沉积物^87Sr＼^86Sr空间变异的制约因 … 总被引：3，自引：1，他引：2
黄河和长江流域泛滥平原细粒沉积物的Ｓｒ同位素组成存在较大差异。前者的＾８７Ｓｒ／＾８６Ｓｒ变化范围较小,为０．７１２８６８～０．７１８８６０,平均值为０．７１５４７４;后者变化范围较大,为０．７１３０３５～０．７３６５０２,平均值为０．７２１４３８。黄河流域中、上海细粒沉积物的＾８７Ｓｒ／８７Ｓｒ低于下游;而长江流域细粒沉积物的＾８７Ｓｒ／＾８６Ｓｒ中游高于上、下游,且南侧高于北侧。由ＮＷ向ＳＥ, 相似文献
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桂林地区岩溶水87Sr/86Sr特征 总被引：2，自引：0，他引：2
锶是岩石圈上部含量最大的微量元素，其元素及其同位素化学性质都比较稳定。不同水岩作用条件下，锶元素含量及其同位素值都不一样。本文通过对桂林地区的两个典型岩溶地下河系统不同类型地下水样87Sr/86Sr值和Sr含量的分析，得出；流经不同岩层的地下水其87Sr/86Sr值和Sr含量不同，同一地下河系统中不同类型地下水的87Sr/86Sr值Sr含量不同，其值的差异由岩性和水岩作用决定。说明87Sr/86Sr值能反映地下水的形成、径流和混合作用，是较理想的示踪剂，在岩溶水研究中具有很广阔的应用前景。 相似文献
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The Coolgarra Batholith in north‐east Queensland is composed of the Go Sam and Nettle granite suites which were emplaced approximately 314 Ma ago. Initial 87Sr/86Sr ratios of the Nettle Suite appear to be marginally above 0.710, a value characteristic of a wide range of Late Palaeozoic felsic igneous rocks in the region. This suite appears to have been derived from an extensive isotopically homogeneous crustal source distinct from rocks which crop out in the Palaeozoic Hodgkinson Basin or Precambrian Georgetown Inlier. Higher and more variable initial 87Sr/86Sr ratios (0.727–0.744) of the Go Sam Suite are attributed to a combination of magmatic and hydrothermal processes. Isotopic data, thus, cannot be used to constrain the nature of the Go Sam source rocks. Tungsten (with or without tin) mineralization is associated with the Nettle Suite plutons, with which it shares a common age, whereas the Go Sam Suite is characterized by prominent tin mineralization. One tin occurrence is the same age as, or only slightly younger than, the Nettle Suite tungsten (with or without tin) mineralization. Another tin deposit yields an age of 301 Ma, suggesting the presence of a significantly younger granite at depth. 相似文献
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R. Moritz L. Fontboté J. Spangenberg S. Rosas Z. Sharp D. Fontignie 《Mineralium Deposita》1996,31(3):147-162
A combined Sr, O and C isotope study has been carried out in the Pucará basin, central Peru, to compare local isotopic trends of the San Vicente and Shalipayco Zn-Pb Mississippi Valley-type (MVT) deposits with regional geochemical patterns of the sedimentary host basin. Gypsum, limestone and regional replacement dolomite yield 87Sr/86Sr ratios that fall within or slightly below the published range of seawater 87Sr/86Sr values for the Lower Jurassic and the Upper Triassic. Our data indicate that the Sr isotopic composition of seawater between the Hettangian and the Toarcian may extend to lower 87Sr/86Sr ratios than previously published values. An 87Sr-enrichment is noted in (1) carbonate rocks from the lowermost part of the Pucará basin, and (2) different carbonate generations at the MVT deposits. This indicates that host rocks at MVT deposits and in the lower-most part of the carbonate sequence interacted with 87Srenriched fluids. The fluids acquired their radiogenic nature by interaction with lithologies underlying the carbonate rocks of the Pucará basin. The San Ramón granite, similar Permo-Triassic intrusions and their clastic derivatives in the Mitu Group are likely sources of radiogenic 87Sr. The Brazilian shield and its erosion products are an additional potential source of radiogenic 87Sr. Volcanic rocks of the Mitu Group are not a significant source for radiogenic 87Sr; however, molasse-type sedimentary rocks and volcaniclastic rocks cannot be ruled out as a possible source of radiogenic 87Sr. The marked enrichment in 87Sr of carbonates toward the lower part of the Pucará Group is accompanied by only a slight decrease in
18O values and essentially no change in
13C values, whereas replacement dolomite and sparry carbonates at the MVT deposits display a coherent trend of progressive 87Sr-enrichment, and 18O- and 13C-depletion. The depletion in 18O in carbonates from the MVT deposits are likely related to a temperature increase, possibly coupled with a 18O-enrichment of the ore-forming fluids. Progressively lower
13C values throughout the paragenetic sequence at the MVT deposits are interpreted as a gradually more important contribution from organically derived carbon. Quantitative calculations show that a single fluid-rock interaction model satisfactorily reproduces the marked 87Sr-enrichment and the slight decrease in
18O values in carbonate rocks from the lower part of the Pucará Group. By contrast, the isotopic covariation trends of the MVT deposits are better reproduced by a model combining fluid mixing and fluid-rock interaction. The modelled ore-bearing fluids have a range of compositions between a hot, saline, radiogenic brine that had interacted with lithologies underlying the Pucará sequence and cooler, dilute brines possibly representing local fluids within the Pucará sequence. The composition of the local fluids varies according to the nature of the lithologies present in the neighborhood of the different MVT deposits. The proportion of the radiogenic fluid in the modelled fluid mixtures interacting with the carbonate host rocks at the MVT deposits decreases as one moves up in the stratigraphic sequence of the Pucará Group. 相似文献
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Wudalianchi volcanic rocks are the most typical Cenozoic potassic volcanic rocks in easten China.Compositional comparisons between whole rocks and glasses of various occurrences indicate that the magma tends to become rich in silica and alkalis as a result of crystal differentiation in the course of evolu-tion.They are unique in isotopic composition with more radiogenic Sr but less radiogenic Pb.^87Sr/^86Sr is higher and ^143Nd/^144Nd is lower than the undifferentiated global values.In comparison to continental pot-ash volcanic rocks,Pb isotopes are apparently lower.These various threads of evidence indicate that the rocks were derived from a primary enriched mantle which had not been subjected to reworking and shows no sign of incorporation of crustal material.The correlation between Pb and Sr suggests the regional heterogeneity in the upper mantle in terms of chemical composition. 相似文献
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Wolfgang Siebel 《Contributions to Mineralogy and Petrology》1995,120(2):197-211
The Leuchtenberg granite (Oberpfalz, NE Bavaria) displays a continuous differentiation trend ranging from mildy peraluminous, coarse-grained, porphyritic biotite granites (BG) to strongly peraluminous, medium- to fine-grained, garnet-bearing muscovite granites (GMG). The Rb–Sr and K–Ar age determinations of whole-rock and mineral samples from the granite and associated intermediate rocks (redwitzites) have revealed two divergent age gradients: Rb–Sr wholerock dates decrease and initial 87Sr/86Sr ratios increase for successively more evolved subsets of the granite. All BG samples (87Rb/86Sr=2–16) yield a date of 326±2 Ma with a low initial 87Sr/86Sr ratio of 0.70778±0.00013 (1), while all GMG samples (87Rb/86Sr=70 to 1000) yield a younger date of 317±2 Ma with an enhanced initial 87Sr/86Sr ratio of 0.7146±0.0039. The K–Ar measurements on biotites and muscovites give closely concordant dates for the GMG (326–323 Ma) and the southern lobe of the BG (324–320 Ma). The northern lobe of the BG, including the redwitzites, shows a well-defined trend of decreasing K–Ar dates from 320 Ma to 300 Ma towards the northwest. Critical consideration of both isotope systems leads to the conclusion that the Rb–Sr system of the GMG was disturbed by a later hydrothermal event. The ca. 326 Ma whole-rock Rb–Sr date for the BG is not in conflict with any of the K–Ar mineral dates and is taken as approaching the crystallization age of the Leuchtenberg granite. The K–Ar age progression within the northern lobe of the BG indicates that this part either cooled down over a protracted period of some 20 Ma or experienced reheating at ca. 300 Ma. The study highlights the potential of combined Rb–Sr and K–Ar dating in deciphering detailed chronology on the scale of a single igneous intrusion. 相似文献
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《Applied Geochemistry》2001,16(9-10):1269-1284
Chemistry of major and minor elements, 87Sr/86Sr, δD, and δ18O of oilfield waters, and 87Sr/86Sr of whole rock were measured from Paleozoic strata in the Central Tarim basin, NW China. The aim is to elucidate the origin and migration of formation water and its relation to petroleum migration. High salinity oilfield waters in Carboniferous, Silurian and Ordovician reservoirs have maintained the same Na/Cl ratio as seawater, indicative of subaerially evaporated seawater. Two possible sources of evaporitic water are Carboniferous (CII) and Cambrian, both of which contain evaporitic sediments. Geographic and stratigraphic trends in water chemistry suggest that most of the high salinity water is from the Cambrian. Strontium, H and O isotopes as well as ion chemistry indicate at least 3 end member waters in the basin. High-salinity Cambrian evaporitic water was expelled upward into Ordovician, Silurian and Carboniferous reservoirs along faults and fractures during compaction and burial. Meteoric water has likely invaded the section throughout its history as uplift created subaerial unconformities. Meteoric water certainly infiltrated Silurian and older strata during development of the CIII unconformity and again in recent times. Modern meteoric water enters Carboniferous strata from the west and flows eastward, mixing with the high salinity Cambrian water and to a lesser degree with paleometeoric water. The third end member is highly radiogenic, shale-derived water which has migrated eastward from the Awati Depression to the west. Enrichment of Ca and Sr and depletion of K, Mg, and SO4 relative to the seawater evaporation trajectory suggest waters were affected by albitization of feldspars, dolomitization, illitization of smectite, and SO4 reduction. The mixing of meteoric water occurred subsequently to seawater evaporation, main water-rock interactions, and brine migration. The direction of brine migration is consistent with that of petroleum migration, suggesting water and petroleum have followed the same migration pathways. 相似文献
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A. Krabbenhöft F. Böhm J. Fietzke N. Augustin M.N. Müller C. Horn N. Nolte 《Geochimica et cosmochimica acta》2010,74(14):4097-4109
We present strontium (Sr) isotope ratios that, unlike traditional 87Sr/86Sr data, are not normalized to a fixed 88Sr/86Sr ratio of 8.375209 (defined as δ88/86Sr = 0 relative to NIST SRM 987). Instead, we correct for isotope fractionation during mass spectrometry with a 87Sr-84Sr double spike. This technique yields two independent ratios for 87Sr/86Sr and 88Sr/86Sr that are reported as (87Sr/86Sr∗) and (δ88/86Sr), respectively. The difference between the traditional radiogenic (87Sr/86Sr normalized to 88Sr/86Sr = 8.375209) and the new 87Sr/86Sr∗ values reflect natural mass-dependent isotope fractionation. In order to constrain glacial/interglacial changes in the marine Sr budget we compare the isotope composition of modern seawater ((87Sr/86Sr∗, δ88/86Sr)Seawater) and modern marine biogenic carbonates ((87Sr/86Sr∗, δ88/86Sr)Carbonates) with the corresponding values of river waters ((87Sr/86Sr∗, δ88/86Sr)River) and hydrothermal solutions ((87Sr/86Sr∗, δ88/86Sr)HydEnd) in a triple isotope plot. The measured (87Sr/86Sr∗, δ88/86Sr)River values of selected rivers that together account for ∼18% of the global Sr discharge yield a Sr flux-weighted mean of (0.7114(8), 0.315(8)‰). The average (87Sr/86Sr∗, δ88/86Sr)HydEnd values for hydrothermal solutions from the Atlantic Ocean are (0.7045(5), 0.27(3)‰). In contrast, the (87Sr/86Sr∗, δ88/86Sr)Carbonates values representing the marine Sr output are (0.70926(2), 0.21(2)‰). We estimate the modern Sr isotope composition of the sources at (0.7106(8), 0.310(8)‰). The difference between the estimated (87Sr/86Sr∗, δ88/86Sr)input and (87Sr/86Sr∗, δ88/86Sr)output values reflects isotope disequilibrium with respect to Sr inputs and outputs. In contrast to the modern ocean, isotope equilibrium between inputs and outputs during the last glacial maximum (10-30 ka before present) can be explained by invoking three times higher Sr inputs from a uniquely “glacial” source: weathering of shelf carbonates exposed at low sea levels. Our data are also consistent with the “weathering peak” hypothesis that invokes enhanced Sr inputs resulting from weathering of post-glacial exposure of abundant fine-grained material. 相似文献
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福建北部元古代麻源群地层发育,对其中7个变质岩和2个白云母花岗岩样品进行了Sm-Nd及Rb-Sr同位素年龄研究。7个样品的Sm-Nd同位素全岩等时线年龄为2116±22(2δ)Ma,INd=0.51027±2(2δ),εNd(t)=7.29±0.17。6个样品的Rb-Sr同位素全岩等时线年龄为375±28(2δ)M,(87Sr/86Sr)i=0.707±34(2δ).2116Ma的年龄值代表麻源群原岩的成岩年龄,375Ma年龄值代表麻源群的变质年龄。 相似文献
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8411地区深熔作用的同位素地质研究表明,J_(1-2)砂岩是以元古代古陆壳供源的湖相沉积岩、岩浆岩为元古代古陆在下地壳局部重熔或重熔-混染的产物。铀的预富集与深熔作用中硅铝质地壳岩浆混染有关。铀矿物和岩浆岩的同位素组成相似。这些研究结果,结合岩石学、矿物学、同位素演化和稀土含量分析,认识到铀来自深源,元古代地层是铀源层。 相似文献