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1.
Ground water samples for a hydrochemical investigation were collected from 92 observation wells completed in a shallow, unconfined aquifer in southeastern North Dakota. The samples showed predominantly an increase in HCO3- (positive bias) and both a pH decrease (positive bias) and a pH increase (negative bias) from field to lab. Positive pH bias generally was associated with ground water characterized by dissolved-solids concentrations less than 400 mg/L. Negative pH bias generally was associated with ground water characterized by dissolvedsolids concentrations greater than 400 mg/L.
Observed HCO3- bias from field to lab slightly distorted ion balance distribution. Excess anions greater than 2 percent generally corresponded to increased HCO3- from field to lab.
Observed HCO3- and pH bias significantly distorted the distribution of calcite saturation indices. Samples with dissolved-solids concentrations less than 400 mg/L that generally showed a positive pH bias had a mean change in calcite saturation index of -0.214 (toward undersaturation). Samples with dissolved-solids concentrations greater than 400 mg/L that generally showed a negative pH bias had a mean change in calcite saturation of +0.132 (toward over saturation).
Calcite saturation indices were much more sensitive to observed pH bias than to observed HCO3- bias. Linear regression analysis indicates % percent of the variability in calcite saturation index change from field to lab is attributed to change in pH from field to lab. Field pH should be used to compute calcite saturation index.  相似文献   

2.
Irrigation, urbanization, and drought pose challenges for the sustainable use of ground water in the central Couloir sud rifain, a major agricultural region in north-central Morocco, which includes the cities of Fès and Meknès. The central Couloir is underlain by unconfined and confined carbonate aquifers that have suffered declines in hydraulic head and reductions in spring flow in recent decades. Previous studies have surveyed ground water flow and water quality in wells and springs but have not comprehensively addressed the chemistry of the regional aquifer system. Using graphical techniques and saturation index calculations, we infer that major ion chemistry is controlled (1) in the surficial aquifer by cation exchange, calcite dissolution, mixing with deep ground water, and possibly calcite precipitation and (2) in the confined aquifer and warm springs by calcite dissolution, dolomite dissolution, mixing with water that has dissolved gypsum and halite, and calcite precipitation. Analyses of 2H and 18O indicate that shallow ground water is affected by evaporation during recharge (either of infiltrating precipitation or return flow), whereas deep ground water is sustained by meteoric recharge with little evaporation. Mechanisms of recharge and hydrochemical evolution are broadly consistent with those delineated for similar regional aquifer systems elsewhere in Morocco and in southern Spain.  相似文献   

3.
To assess the vulnerability of ground water to contamination in the karstic Upper Floridan aquifer (UFA), age-dating tracers and selected anthropogenic and naturally occurring compounds were analyzed in multiple water samples from a public supply well (PSW) near Tampa, Florida. Samples also were collected from 28 monitoring wells in the UFA and the overlying surficial aquifer system (SAS) and intermediate confining unit located within the contributing recharge area to the PSW. Age tracer and geochemical data from the earlier stage of the study (2003 through 2005) were combined with new data (2006) on concentrations of sulfur hexafluoride (SF6), tritium (3H), and helium-3, which were consistent with binary mixtures of water for the PSW dominated by young water (less than 7 years). Water samples from the SAS also indicated mostly young water (less than 7 years); however, most water samples from monitoring wells in the UFA had lower SF6 and 3H concentrations than the PSW and SAS, indicating mixtures containing high proportions of older water (more than 60 years). Vulnerability of the PSW to contamination was indicated by predominantly young water and elevated nitrate-N and volatile organic compound concentrations that were similar to those in the SAS. Elevated arsenic (As) concentrations (3 to 19 μg/L) and higher As(V)/As(III) ratios in the PSW than in water from UFA monitoring wells indicate that oxic water from the SAS likely mobilizes As from pyrite in the UFA matrix. Young water found in the PSW also was present in UFA monitoring wells that tap a highly transmissive zone (43- to 53-m depth) in the UFA.  相似文献   

4.
李静  李营  陆丽娜  孙凤霞  谢超  崔月菊 《地震》2017,37(1):61-72
根据六盘山地区泉水的化学组成和氢、 氧同位素数据, 讨论了该区地下水的化学类型、 成因及其动态变化特征。 2012年11月和2014年7月在六盘山地区采集10处泉水样品, 氢氧同位素由液态水同位素分析仪测定, 离子组分浓度由离子色谱和化学滴定法测定。 水样的TDS范围为218~27508 mg/L, δ18O和δD值分别为-12.0‰~ -8.5‰, -88.5‰ ~-61.3‰。 δ18O和δD指示该区泉水来源于大气降水, 并受水循环条件及水岩反应程度的影响。 根据舒卡列夫分类法, 所采水样可划分为10种水化学类型, 受含水层岩性控制, 宁南地区的水化类型主要为SO4-Na型, 渭北西部地区的水化类型主要为HCO3-Ca·Mg型。 两次所采水样的离子浓度显示多数水样点的HCO-3具有夏高冬低的季节性变化特征, 千川村(QC)、 双井村(SJ)等因含水层赋存环境较封闭, 受降水干扰小; 硝口村(XKH)泉水的离子毫克当量比值变幅最大, 说明该泉点水岩反应程度变化较大, 易受断层带活动的影响。 研究结果确定了六盘山地区水文地球化学背景和水的来源, 为该区流体地球化学地震监测、 预测提供了背景资料。  相似文献   

5.
Mineral and thermal water chemistry from the Azores archipelago was investigated in order to discriminate among hydrochemical facies and isotopic groups and identify the major geochemical processes that affect water composition. A systematic geochemical survey of mineral and thermal water chemistry was carried out, incorporating new data as well as results from the literature. The Azores are a volcanic archipelago consisting of nine islands and samples were collected at São Miguel, Graciosa, Faial, São Jorge, Pico and Flores islands. Hydrothermal manifestations show the effects of active volcanism on several islands. Discharges are mainly related to active Quaternary central volcanoes, of basaltic to trachytic composition, but also some springs are related to older dormant or extinct volcanoes.Multivariate analysis – principal component and cluster analysis – enables classification of water compositions into 4 groups and interpretation of processes affecting water compositions. Groups 1 and 2 discharge from perched-water bodies, and mostly correspond to Na–HCO3 and Na–HCO3–Cl type waters. These groups comprise of cold, thermal (27 °C–75 °C) and boiling waters (92.2 °C–93.2 °C), with a wide TDS range (77.3–27, 145.7 mg/L). Group 3 is made of samples of dominated Na–SO4 from very acid boiling pools (pH range of 2.02–2.27) which are fed by steam-heated perched-water bodies. Group 4 is representative of springs from the basal aquifer system and corresponds to Na–Cl type fluids, with compositions dominated by seawater.Results are used to further develop a conceptual model characterizing the geochemical evolution of the studied waters. Mineral and thermal waters discharging from perched-water bodies are of meteoric origin and chemically evolve by absorption of magmatic volatiles (CO2) and by a limited degree of rock leaching. Existing data also suggest mixture between cold waters and thermal water. Water chemistry from springs that discharge from the basal aquifer system evolves by mixing with seawater; although, processes such as absorption of magmatic volatiles (CO2), rock leaching and mixture with hydrothermal waters are not excluded by the data because the actual composition of these waters deviates from that expected considering only conservative mixing between fresh and seawater.  相似文献   

6.
根据河套盆地周缘断裂带泉水的氢、氧同位素组成和水化学组分,讨论了该区地下水的化学类型、成因及其与地震活动的关系。于2014年9月下旬和2015年4月15日MS5.8阿左旗地震震后在河套盆地周缘的乌拉山断裂带、色尔腾断裂带、狼山断裂带以及桌子山断裂带采集了17个泉水和井水样品,测得水样的TDS分布在143.8~42 553.0mg/L范围内,δD和δ18O值分别在-83.6‰~66.56‰和-11.16‰~8.2‰的范围内,来源为大气降水。根据舒卡列夫分类法,震前水样可划分为13种水化学类型,震后西山咀、圐圙朴隆等5个点采样点泉水的水化学类型发生变化。其中,乌拉山断裂带的水样以HCO3-Ca型低矿化度地表水为主;色尔腾断裂带、狼山断裂带泉水受白垩系含水层影响,矿化度较高,富含HCO-3及SO2-4;桌子山一带受煤矿开采影响,水样以富SO2-4和Cl-的高矿化度水为特征。地震前后TDS、阴、阳离子以及γNa/γCl、γ(SO4+Cl)/γHCO3、γHCO3/γCl等毫克当量比值能够较好地反映地震。2015年4月15日阿左旗MS5.8地震后,呼鲁斯太、迪延阿贵庙及八一井的水化学组成变化较大,对地震响应较为敏感。呼鲁斯太地区泉水的TDS稍有降低,但HCO-3在阴离子中所占比例有所增加,表明震后该地区含水层的泉水与较低矿化度的含碳酸盐岩含水层水发生了混合;八一井的TDS值有所增加,γNa/γCl比值有所降低,表明深部高矿化度水的混入;迪延阿贵庙水样的TDS稍有下降,但NaCl的相对含量较震前有所升高,表明有低矿化度NaCl水的混入。本工作不仅确定了该区水文地球化学背景,而且对地震监测和预测具有一定参考价值。  相似文献   

7.
B. G. Katz 《水文研究》1989,3(2):185-202
During 1983 and 1984, wet precipitation was primarily a solution of dilute sulphuric acid, whereas calcium and bicarbonate were the major ions in springs and ground water in two small watersheds with a deciduous forest cover in central Maryland. Dominant ions in soil water were calcium, magnesium, and sulphate. The relative importance of mineral weathering reactions on the chemical composition of these subsurface waters was compared to the contribution from wet precipitation, biological processes, and road deicing salts. Mineral reaction models, developed from geochemical mass-balance relationships, involved reactions of primary and secondary minerals in metabasalt and metarhyolite with hydrogen ion. Geochemical weathering reactions account for the majority of total ion equivalents in soil water (46 per cent), springs (51 per cent), and ground water (68 to 77 per cent). The net contribution of total ion equivalents from biological processes was 20 and 16 per cent for soil water and springs, respectively, but less than 10 per cent for ground water. The contribution of total ion equivalents from deicing salts (10 to 20 per cent) was related to proximity to roads. Strong acids in precipitation contributed 44 per cent of the total amount of hydrogen ions involved in mineral-weathering reactions for ground water in contact with metarhyolite compared to 25 per cent for ground water in contact with metabasalt, a less resistant rock type to weathering.  相似文献   

8.
Fractured rock aquifers cover much of Earth's surface and are important mountain sites for groundwater recharge but are poorly understood. To investigate groundwater systematics of a fractured-dominated aquifer in Baja California Sur, Mexico, we examined the spatial patterns of aquifer recharge and connectivity using the geochemistry of springs. We evaluate a range of geochemical data within the context of two endmember hypotheses describing spatial recharge patterns and fracture connectivity. Hypothesis 1 is that the aquifer system is segmented, and springs are fed by local recharge. Hypothesis 2 is that the aquifer system is well connected, with dominant recharge occurring in the higher elevations. The study site is a small <15 km2 catchment. Thirty-four distinct springs and two wells were identified in the study area, and 24 of these sites were sampled for geochemical analyses along an elevation gradient and canyon transect. These analyses included major ion composition, trace element and strontium isotopes, δ18O and δ2H isotopes, radiocarbon, and tritium. δ18O and δ2H isotopes suggest that the precipitation feeding the groundwater system has at least two distinct sources. Carbon isotopes showed a change along the canyon transect, suggesting that shorter flowpaths feed springs in the top of the transect, and longer flowpaths discharge near the bottom. Geochemical interpretations support a combination of the two proposed hypotheses. Understanding of the connectivity and provenance of these springs is significant as they are the primary source of water for the communities that inhabit this region and may be impacted by changes in recharge and use.  相似文献   

9.
The use of reclaimed water and its impact on groundwater quality in the middle and southern parts of the Jordan Valley are investigated. The chemical analyses indicate that nitrate and bacteriological pollution is widespread, and thus, seriously affects groundwater use. During the study, 365 water samples were collected from wells and springs to determine the water chemistry and the extent of nitrate pollution. Three hydrochemical facies are identifed, i. e., (Ca–(Mg)–Na–HCO3), (Ca–Na–SO4–Cl) and (Ca–Na–Cl). The change of facies is accompanied by a gradual increase in the groundwater total dissolved solids (TDS), which is mainly controlled by evaporates and carbonates dissolution in the aquifer matrix. Water analyses indicate that the shallow aquifer in the study area is affected by non‐point pollution sources, primarily from natural (manure) and chemical nitrogen (N)‐fertilizers and treated wastewater used for agriculture. The concentration of nitrate in the groundwater ranges from 10 to 355 mg/L. Considerable seasonal fluctuations in groundwater quality are observed as a consequence of agricultural practices and other factors such as annual rainfall distribution and the Zarqa River flow. The noticeable levels of total coliform and Escherichia coli in the northern part of the study area may be attributed to contamination from the urban areas, intensive livestock production, and illegal dumping of sewage. Heavy metal concentrations in all samples were found to be significantly lower than the permissible limits for drinking water standards.  相似文献   

10.
The hydrochemical analyses of twenty-three springs were used to determine the properties and types of groundwater of the Tertiary-Quaternary Aquifer of northern Jordan. The result shows that the geological formation influences the quality of the investigated groundwater more than the anthropogenic factors. The water of the Quaternary-Tertiary aquifer is enriched in Ca++ due to the dissolution of the nearby carbonate rocks. The investigated water has a low EC values with Ca(Na)-HCO3 water type. Most springs belong to this hydrochemical facies except Malka. Groundwater in the Malka wells has high salinity with NaCl waters and a strong Ca(Mg)-HCO3 facies (900 to 1000 mg/l TDS). The area long-term hydrochemical data have been also evaluated; general trend of increase of the analyzed ion was observed. Bicarbonate represents the most abundant anion in the studied water, which exceeds the permissible limits. Nitrates (NO 3 ? ) also exceed the permissible limit and are the most common contaminant in the investigated water. Data on dissolved major and trace elements (K+, Na+, Mg2+, Ca2+, Cl?, SO 4 2? , Fe, Zn, Cu and Pb) in the investigated water revealed that the concentrations lie within the natural background range. The positive correlation values between various ions indicate that most of ions come from same lithological sources. According to the residual sodium carbonate, and EC values, the studied springs are suitable for agricultural purposes.  相似文献   

11.
Warner KL 《Ground water》2001,39(3):433-442
The lower Illinois River Basin (LIRB) covers 47,000 km2 of central and western Illinois. In the LIRB, 90% of the ground water supplies are from the deep and shallow glacial drift aquifers. The deep glacial drift aquifer (DGDA) is below 152 m altitude, a sand and gravel deposit that fills the Mahomet Buried Bedrock Valley, and overlain by more than 30.5 m of clayey till. The LIRB is part of the USGS National Water Quality Assessment program, which has an objective to describe the status and trends of surface and ground water quality. In the DGDA, 55% of the wells used for public drinking-water supply and 43% of the wells used for domestic drinking water supply have arsenic concentrations above 10 micrograms/L (a new U.S. EPA drinking water standard). Arsenic concentrations greater than 25 micrograms/L in ground water are mostly in the form of arsenite (AsIII). The proportion of arsenate (AsV) to arsenite does not change along the flowpath of the DGDA. Because of the limited number of arsenic species analyses, no clear relations between species and other trace elements, major ions, or physical parameters could be established. Arsenic and barium concentrations increase from east to west in the DGDA and are positively correlated. Chloride and arsenic are positively correlated and provide evidence that arsenic may be derived locally from underlying bedrock. Solid phase geochemical analysis of the till, sand and gravel, and bedrock show the highest presence of arsenic in the underlying organic-rich carbonate bedrock. The black shale or coal within the organic-rich carbonate bedrock is a potential source of arsenic. Most high arsenic concentrations found in the DGDA are west and downgradient of the bedrock structural features. Geologic structures in the bedrock are potential pathways for recharge to the DGDA from surrounding bedrock.  相似文献   

12.
In order to delineate geochemical processes and its relation with groundwater quality evolution, hydrochemical and isotopic analysis were carried out in coastal groundwater of Saijo plain, western Japan. From analytical results, even within a small distance from the coast; ionic concentration of water samples varies a lot which infers non-homogenous and patchy distribution of different aquifer system (complex geology). From stable isotopic results, it was found that most of sample points plotted near the local meteoric water line (LMWL) i.e. origin of ground water is meteoric in principle; however point away from the LMWL might favors exchange with rock minerals.  相似文献   

13.
In order to delineate geochemical processes and its relation with groundwater quality evolution, hydrochemical and isotopic analysis were carried out in coastal groundwater of Saijo plain, western Japan. From analytical results, even within a small distance from the coast; ionic concentration of water samples varies a lot which infers non-homogenous and patchy distribution of different aquifer system (complex geology). From stable isotopic results, it was found that most of sample points plotted near the local meteoric water line (LMWL) i.e. origin of ground water is meteoric in principle; however point away from the LMWL might favors exchange with rock minerals.  相似文献   

14.
艾比湖水化学演化的初步研究   总被引：10，自引：0，他引：10  
李涛 《湖泊科学》1993,5(3):234-243
本文通过野外地质调查和大量样品的分析测试结果,从以下三个方面对艾比湖湖水的水化学特征进行论述:(1)湖水的矿化度和pH;(2)湖水的化学组成;(3)湖水化学组分的侧向分布。初步揭示了湖水水化学变化和主要化学元素迁移和富集的规律。艾比湖沉积物中碳酸盐矿物组成及其地球化学性质反映湖水化学组成的变动。这种变动明显受气候环境变化的影响。因此,CK4孔和湖底沉积物中的碳酸盐沉积,提供了许多信息作为湖水化学演化和古气候波动的标志,根据其碳酸盐含量、方解石含量、方解石格架中MgCO_3mol.％、Sr含量和Sr×1000/Ca比值,最后结合碳酸盐的沉积特征、地球化学演化和古沙嘴的演变,进一步阐明了湖水化学演化的趋势。  相似文献   

15.
Advances over the past 40 years have resulted in a clear understanding of how dissolution processes in carbonate rocks enhance aquifer permeability. Laboratory experiments on dissolution rates of calcite and dolomite have established that there is a precipitous drop in dissolution rates as chemical equilibrium is approached. These results have been incorporated into numerical models, simulating the effects of dissolution over time and showing that it occurs along the entire length of pathways through carbonate aquifers. The pathways become enlarged and integrated over time, forming self‐organized networks of channels that typically have apertures in the millimeter to centimeter range. The networks discharge at point‐located springs. Recharge type is an important factor in determining channel size and distribution, resulting in a range of aquifer types, and this is well demonstrated by examples from England. Most carbonate aquifers have a large number of small channels, but in some cases large channels (i.e., enterable caves) can also develop. Rapid velocities found in ground water tracer tests, the high incidence of large‐magnitude springs, and frequent microbial contamination of wells all support the model of self‐organized channel development. A large majority of carbonate aquifers have such channel networks, where ground water velocities often exceed 100 m/d.  相似文献   

16.
Water chemical data from the Botucatu Sandstone aquifer in the São Paulo State part of the Paraná Basin, Brazil, was evaluated using geochemical methods and two statistical analyses: cluster analysis and factor analysis. The results were used to develop a conceptual geochemical model, in which three geochemical regions were identified, and their chemical behavior was modeled. The characteristic chemicals, changing from the recharge area to the center of the basin, are: SiO2—(HCO3− and Ca2+)—(Na+, CO32−, and SO42−). The distribution of the chemicals is interpreted as controlled by different water–rock interaction processes in the different regions. In the recharge area, dissolution of alkali–feldspar minerals in the sandstone is the main reaction observed; in the mid-section of the basin, calcite dissolution results in high calcium and bicarbonate concentration; in the center of the basin, leakage from underlying layers becomes the governing factor.  相似文献   

17.
The results of geological, geochemical and isotopic investigations in the Hengill thermal area in Iceland are presented. This area may be regarded as typical of the Icelandic high temperature areas. The Hengill area is mainly built up of pillow lavas and hyaloclastites, which were piled up in subglacial eruptions. Its western half is traversed by a very active NE-SW trending fault zone about 5 km broad, within which are several eruptive fissures of postglacial age. The volcanic rocks are basalts of various kinds, but minor occurrences of intermediate and rhyolitic rocks are also found. Solfataras and fumaroles occur mainly at higher altitude. Within the fault zone they have a linear distribution along faults. Hot water springs are found in the lowlands on the southern border of the thermal area. The concentrations of chlorine, tritium and deuterium in the water indicate that the hot springs on the lowland are fed by a deep lying aquifer which receives water from a recharge area situated in the western branch of the active volcanic zone upto 70 km to the northeast. The hot springs at higher altitude are the outlets of a secondary circulation system fed by local rain water. This water derives its heat partly from the heat content of the rocks penetrated and partly by steam and gas boiled off from the deeper lying aquifer. Preliminary results from other high temperature areas in Iceland indicate the presence of similar hydrological systems.  相似文献   

18.
Spatial heterogeneity in the subsurface of karst environments is high, as evidenced by the multiphase porosity of carbonate rocks and complex landform features that result in marked variability of hydrological processes in space and time. This includes complex exchange of various flows (e.g., fast conduit flows and slow fracture flows) in different locations. Here, we integrate various “state‐of‐the‐art” methods to understand the structure and function of this poorly constrained critical zone environment. Geophysical, hydrometric, and tracer tools are used to characterize the hydrological functions of the cockpit karst critical zone in the small catchment of Chenqi, Guizhou Province, China. Geophysical surveys, using electrical resistivity tomography (ERT), inferred the spatial heterogeneity of permeability in the epikarst and underlying aquifer. Water tables in depression wells in valley bottom areas, as well as discharge from springs on steeper hillslopes and at the catchment outlet, showed different hydrodynamic responses to storm event rainwater recharge and hillslope flows. Tracer studies using water temperatures and stable water isotopes (δD and δ18O) could be used alongside insights into aquifer permeability from ERT surveys to explain site‐ and depth‐dependent variability in the groundwater response in terms of the degree to which “new” water from storm rainfall recharges and mixes with “old” pre‐event water in karst aquifers. This integrated approach reveals spatial structure in the karst critical zone and provides a conceptual framework of hydrological functions across spatial and temporal scales.  相似文献   

19.
A field study was conducted to assess purging requirements for dedicated sampling systems in conventional monitoring wells and for pumps encased in short screens and buried within a shallow sandy aquifer. Low-flow purging methods were used, and wells were purged until water quality indicator parameters (dissolved oxygen, specific conductance, turbidity) and contaminant concentrations (chromate, trichloroethylene, dichloroethylene) reached equilibrium. Eight wells, varying in depth from 4.6 to 15.2 m below ground surface, were studied. The data show that purge volumes were independent of well depth or casing volumes. Contaminant concentrations equilibrated with less than 7.5 I. of purge volume in all wells. Initial contaminant concentration values were generally within 20 percent of final values. Water quality parameters equilibrated in less than 10 L in all wells and were conservative measures for indicating the presence of adjacent formation water. Water quality parameters equilibrated faster in dedicated sampling systems than in portable systems and initial turbidity levels were lower.  相似文献   

20.
Models for contaminant transport in streams commonly idealize transient storage as a well mixed but immobile system. These transient storage models capture rapid (near‐stream) hyporheic storage and transport, but do not account for large‐scale, stage‐dependent interaction with the alluvial aquifer. The objective of this research was to document transient storage of phosphorus (P) in coarse gravel alluvium potentially influenced by large‐scale, stage‐dependent preferential flow pathways (PFPs). Long‐term monitoring was performed at floodplain sites adjacent to the Barren Fork Creek and Honey Creek in northeastern Oklahoma. Based on results from subsurface electrical resistivity mapping which was correlated to hydraulic conductivity data, observation wells were installed both in higher hydraulic conductivity and lower hydraulic conductivity subsoils. Water levels in the wells were monitored over time, and water samples were obtained from the observation wells and the stream to document P concentrations at multiple times during high flow events. Contour plots indicating direction of flow were developed using water table elevation data. Contour plots of total P concentrations showed the alluvial aquifer acting as a transient storage zone, with P‐laden stream water heterogeneously entering the aquifer during the passage of a storm pulse, and subsequently re‐entering the stream during baseflow conditions. Some groundwater in the alluvial floodplains had total P concentrations that mirrored the streams' total P concentrations. A detailed analysis of P forms indicated that particulate P (i.e. P attached to particulates greater than 0·45 µm) was a significant portion of the P transport. This research suggests the need for more controlled studies on stage‐dependent transient storage in alluvial systems. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

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