共查询到20条相似文献，搜索用时 15 毫秒
1.
L.E. Fox 《Estuarine, Coastal and Shelf Science》1983,16(4):431-440
A simple method for the determination of dissolved humic acid based on carbon analysis is presented. This method was used to measure the distribution of dissolved humic acids in seven coastal plain estuaries located in the middle-Atlantic United States. Results indicate that 100% of the dissolved humic acid was removed during estuarine mixing, although concurrent measurements of dissolved organic carbon showed either production or conservative behavior in regions of the estuary where humic acid removal was observed. It is apparent from these observations that removal of dissolved humic acid is a minor part of the estuarine transport of dissolved organic carbon.Laboratory experiments carried out by mixing river water with sea water demonstrated that salt-induced removal of dissolved humic acid was insignificant in two of three estuaries studied. These results suggest in situ removal of dissolved humic acid may not be universally caused by increasing estuarine salinity. 相似文献
2.
Joan D. Willey 《Marine Chemistry》1984,15(1):19-45
Natural fluorescence, which is thought to result from low molecular weight humic and fulvic compounds, can be used as a tracer to distinguish between individual river waters. Natural fluorescence exhibits conservative mixing with seawater, except for a slight fluorescence increase which is sometimes observed in the low salinity range (0–5‰). This increase is not due to the inner filter effect (internal quenching). Laboratory experiments can reproduce this low-salinity natural fluorescence increase. Of the major seawater ions, only magnesium can cause a similar natural fluorescence increase. Variation in sample pH, ionic strength, or particle content cannot explain the natural fluorescence increase, nor does it appear to be related to the estuarine flocculation of humic material. Addition of seawater magnesium to the fluorescent material with subsequent loss of hydrogen ions could enhance fluorescence by adding crosslinking to the structure. Replacement of a fluorescence-depressing metal like copper or iron by magnesium could also enhance fluorescence, essentially by removing the quenching effect of the metal. Experimental data in this study are consistent with both of these possible mechanisms. Calcium also enhances fluorescence, however the effect of seawater calcium during estuarine mixing is not as apparent as the magnesium effect. The implications of this low-salinity natural fluorescence increase with respect to estuarine and coastal tracer applications depend on whether individual rivers mix in the high or low salinity region of an estuary or coastal area. 相似文献
3.
Bruce E. Frey G.Fritz Riedel Ann E. Bass Lawrence F. Small 《Estuarine, Coastal and Shelf Science》1983,17(2):181-187
Experiments were conducted in which we tested the effects of hexavalent chromium on both natural assemblages of phytoplankton and cultures of Thalassiosira pseudonana clone 3H. Water was collected from various locations in Yaquina Bay, Oregon, with salinities ranging from 32·5‰ to 0·03‰. A variety of nutrient regimes were tested by adding major nutrients and micro-nutrients, and/or stripping micro-nutrients with activated carbon. In one high salinity experiment, chromium was stimulatory, as were micro-nutrient additions. In other high and medium salinity experiments, chromium was neither stimulatory nor inhibitory, at levels up to 1·9 μ mole l?1 Cr. There was, however, slight inhibition of growth at 19·0 μ mole l?1 Cr, due specifically to inhibition of Skeletonema costatum. In our freshwater experiments, chromium was very inhibitory at 1·9 μ mole l?1 Cr, and slightly inhibitory at 0·19 μ mole l?1 Cr. Species inhibited by chromium were Surirella ovata, Detonula confervacea, and Cyclotella sp. Experiments were conducted with T. pseudonana grown over a wide range of salinities. Chromium was found to be very inhibitory in freshwater and became progressively less toxic as the salinity increased. Most inhibition was neutralized by a salinity of 2·1‰. 相似文献
4.
The behavior of clay minerals under different salinity conditions was studied during model experiments using clay mineral suspensions (bentonite and kaolinite) and organic substance solutions (chitosan, humic acids). It was shown that the kaolinite suspension was more stable and may migrate through the river-sea barrier, while the bentonite suspension coagulated even under 1–2‰ salinity. The influence of the organic matter’s nature on the stability of clay mineral suspensions and their ability to migrate through the marginal filter was discussed. 相似文献
5.
Purple shore crabs, Hemigrapsus nudus (Crustacea: Decapoda), can survive indefinitely in salinities of 8 (25% SW), but also tolerate short-term exposure to salinities as low as 2. In the laboratory their salinity preference range, determined from choice chamber experiments, is 22–32 and they can discriminate between pairs of salinities separated by a difference of 2. These crabs show a strong positive thigmotaxis and a weak negative phototaxis and tend to choose environments with available shelter. The presence of shelter significantly alters the behaviour of this species. When shelter is available the salinity preference range is 10–32. Even in salinities below this preference range, the presence of shelter prolongs the time spent in the lower test salinities. This change in behaviour has implications on the crab's physiology: the haemolymph osmolality falls to lower levels when crabs remain in low salinity under shelters. In the field, H. nudus is found in creeks with salinities close to freshwater and they may remain in this salinity for up to 11 h, if there are rocks under which to shelter. An increase in habitat complexity increases the number of crabs that are found within the creek. These crabs in the low salinity environment have a lower haemolymph osmolality than crabs on the nearby open shore. In H. nudus the behavioural selection of a shelter appears to outweigh the physiological costs associated with osmotic regulation of the body fluids. Therefore, the distribution of H. nudus in estuaries may depend more on the availability of suitable habitats rather than the salinity tolerance of this species. 相似文献
6.
The ‘dissolved’ iron (that passed through a 0·4-μm filter) varied nonconservatively with salinity in the Connecticut River estuary. However, the total iron appeared to be conservative. Measurements of Fe(II) and Fe(III) showed that oxidation of Fe(II) was not a factor in the decrease of ‘dissolved’ iron in the low salinity region. A solubility model and analyses based on different pore-size filters indicated that a substantial amount of the ‘dissolved’ iron in the low salinity region was colloidal iron. The coagulation of fine colloidal particles led to the non-conservative behavior of ‘dissolved’ iron during estuarine mixing, but it did not necessarily lead to removal of total iron from the waters. Particulate iron was 80–90% of the total iron and it covaried with the total suspended matter during mixing and sediment resuspension. The residence time of water in the Connecticut River estuary was too short to allow removal of iron from the water column within the estuary. 相似文献
7.
The Baltic Sea is a semi-enclosed sea with a steady salinity gradient (3‰–30‰). Organisms have adapted to such low salinities, but are suspected to be more susceptible to stress. Within the frame of the integrated environmental monitoring BONUS + project “BEAST” the applicability of immune responses of the blue mussel was investigated in Danish coastal waters. The sampling sites were characterised by a salinity range (11–19‰) and different mixtures of contaminants (metals, PAHs and POPs), according to chemical analysis of mussel tissues. Variation partitioning (redundancy analysis) was applied to decompose salinity and contamination effects. The results indicated that cellular immune responses (total and differential haemocyte count, phagocytic activity and apoptosis) were mainly influenced by contaminants, whereas humoral factors (haemolytic activity) were mainly impacted by salinity. Hence, cellular immune functions may be suitable as biomarkers in monitoring programmes for the Baltic Sea and other geographic regions with salinity variances of the studied range. 相似文献
8.
The concentrations of rare earth elements in the dissolved, acid-soluble and residual phases in surface waters of the Changjiang
Estuary were determined using ICP-MS. The main purposes of the study are to understand the estuarine geochemistry of rare
earth elements and to explore water-particle interactions in the Changjiang estuarine mixing zone. The results show that there
are two distinct processes operating on dissolved rare earth elements in the estuary: large scale removal at low salinities
due to salt-induced coagulation and remarkable release at mid to high salinities. These processes result in modification of
the effective river water flux and the systematical fractionation of the dissolved rare earth elements toward the East China
Sea. The increase in concentration of dissolved rare earth elements in the mid to high salinity waters of the Changjiang Estuary
suggests a sediment source in the mixing zone of the estuary, which is located over a shallow, broad shelf where there is
extensive physical contact between bottom sediment and estuarine waters. Acid-soluble rare earth elements, the concentrations
of which also dropped sharply in the low salinity region, appear to be controlled by salt-induced coagulation process and
intense deposition of suspended particulate matter in the low salinity region. In the mid to high salinities, all acid-soluble
rare earth element concentrations increase slightly with increasing salinity, suggesting that resuspension of sediments occurred.
In contrast, the residual rare earth element concentrations are relatively constant with salinity variation in the Changjiang
estuarine surface waters. 相似文献
9.
The concentrations of total selenium (Se) and Se (IV) were determined in the surface waters of 30 stations located in the James River and southern Chesapeake Bay. The concentrations of total Se and Se (IV) ranged from 0·28 to 1·91 nM and from 0·07 to 1·36 nM, respectively, between salinities of 31·78 and 0·06‰. The concentration of Se (VI), calculated as the difference between the concentrations of total Se and Se (IV), ranged from 0·08 to 0·67 nM. While total Se seemed to be conservative in this study area at salinities above 0·36‰, Se (IV) might have been removed during estuarine mixing. The removal of Se (IV) occurred primarily at salinities below 4‰ possibly via the oxidation of Se (IV) to Se (VI). 相似文献
10.
Sea urchin embryo-larval development (ELD) and fertilization tests have been widely used in ecotoxicity studies and are included in regulatory frameworks. Biological processes occur naturally within a range of salinity that depends on the species considered. In an attempt to determine the optimum range of salinity, ELD and fertilization bioassays were performed at different salinities (15-40.5‰) with two species of Atlantic sea urchin: Arbacia lixula and Paracentrotus lividus. In the ELD assay, the optimum range of salinity was wider for A.?lixula (29-35.5‰) than for P.?lividus (29-33‰). In the fertilization assay with P.?lividus as a bioindicator species, the highest percentage of fertilization (90%) was obtained at salinities of between 29 and 33‰. More research on A.?lixula is required, since the fertilization success was below 60%. The results of the present study demonstrate that salinity may be a confounding factor in interpreting ELD test results. 相似文献
11.
Meagan Eagle Gonneea Paul J. Morris Henrieta Dulaiova Matthew A. Charette 《Marine Chemistry》2008,109(3-4):250
Over the past decade, radium isotopes have been frequently applied as tracers of submarine groundwater discharge (SGD). The unique radium signature of SGD is acquired within the subterranean estuary, a mixing zone between fresh groundwater and seawater in coastal aquifers, yet little is known about what controls Ra cycling in this system. The focus of this study was to examine controls on sediment and groundwater radium activities within permeable aquifer sands (Waquoit Bay, MA, USA) through a combination of field and laboratory studies. In the field, a series of sediment cores and corresponding groundwater profiles were collected for analysis of the four radium isotopes, as well as dissolved and sediment associated manganese, iron, and barium. We found that in addition to greater desorption at increasing salinity, radium was also closely tied to manganese and iron redox cycling within these sediments. A series of laboratory adsorption/desorption experiments helped elucidate the importance of 1) contact time between sediment and water, 2) salinity of water in contact with sediment, 3) redox conditions of water in contact with sediment, and 4) the chemical characteristics of sediment on radium adsorption/desorption. We found that these reactions are rapid (on the order of hours), desorption increases with increasing salinity and decreasing pH, and the presence of Fe and Mn (hydr)oxides on the sediment inhibit the release of radium. These sediments have a large capacity to sorb radium from fresh water. Combined with these experimental results, we present evidence from time series groundwater sampling that within this subterranean estuary there are cyclic periods of Ra accumulation and release controlled by changing salinity and redox conditions. 相似文献
12.
H.A. van der Sloot D. Hoede J. Wijkstra J.C. Duinker R.F. Nolting 《Estuarine, Coastal and Shelf Science》1985,21(5):633-651
Oxy-anionic species of V, As, Se, Mo, Sb, Te and W were measured in solution and suspension in samples obtained during several cruises in the Dutch Wadden Sea, the offshore region of the Southern Bight (North Sea) and in the estuaries of the Rhine and Scheldt. Dissolved concentrations at salinities above 34·5 × 10?3 ( = 34·5%. S) agreed generally well with published open ocean values. It is suggested that Se speciation differs from the open ocean.In the Wadden Sea, concentrations of V, Se, Mo and Sb were linearly related to salinity (10–35 × 10?3). The good agreement between measured and extrapolated values at a salinity of 0·5 × 10?3 suggests conservative behaviour in the Rhine estuary (with residence time of freshwater in the order of a few days).Dissolved concentration vs. salinity plots in the Scheldt estuary (residence time 2–3 months) showed pronounced minima and maxima. These occurred in the low or medium salinity range for V, As and Sb. Linear behaviour was observed for Se and Mo (in some cases, relatively large differences between cruises were detected). Deviations from linearity in the plots are interpreted in terms of thermodynamic equilibrium conditions involving species with different solubilities (V), local input from land (As, Se, Sb, Te) and removal from solution (As), probably through coprecipitation with Fe(OH)3.In the offshore samples, the contributions of particulate forms to the total element concentrations were small (<15%). At higher SPM concentrations (about 30 mg dm?3), this percentage remained small for Se, Mo and Sb (<15%); it was substantial for V and As (25–50%). 相似文献
13.
Seawater Intrusion in Semi-Closed Convergent Estuaries (Case Study of Moroccan Atlantic Estuaries): Application of Salinity Analytical Models 总被引：1，自引：0，他引：1
Salinity is an important parameter influencing the water quality of estuaries, and can constitute a serious problem to society due to the need for freshwater for industry and agriculture. Therefore, the determination of salt intrusion length in estuaries is a challenge for managers as well as scientists in this field. The managers tend to use simple and reliable tools for salinity variation. Although 2-D and 3-D numerical models are common tools for the prediction of salinity intrusion now, analytical models of salinity variation are much more efficient, and also require minimal sets of river data. In this paper, two analytical solutions, Brockway and Savenije used worldwide to assess longitudinal salinity variation in alluvial estuaries, are applied to the Moroccan Atlantic semi-closed estuaries, i.e., Sebou and Loukkos. The solutions are derived from salt convection-dispersion equations, with different assumptions for the dispersion coefficient. The estuaries' bathymetry is described by an exponential function. The performance of these two solutions was evaluated by comparing their results with field-measured salinity data. The Brockway model's salinity predictions performs well to observations especially in downstream reaches of the two estuaries (Sebou: R2 = 0.95, root mean square error [RMSE] = 1.50‰, normalized root mean square error [NRMSE] = 3.45‰; Loukkos: R2 = 0.95, RMSE = 1.13‰, NRMSE = 3.01‰), while the Savenije model outperformed the Brockway's model and is better to predict salt intrusion length and salinity variation along the two estuaries (Sebou: R2 = 0.97, RMSE = 1.15‰, NRMSE = 2.85‰; Loukkos: R2 = 0.98, RMSE = 0.95‰, NRMSE = 1.94‰). This revealed that both analytical solutions apply well to the estimation of salinity variation and the prediction of salt intrusion in these two estuaries. 相似文献
14.
江苏海岸带盐沼潮滩在小尺度下的沉积变化过程 总被引：1，自引：0，他引：1
在小尺度范围内,潮滩沉积的研究一般都是基于几个站位或断面进行短时日的调查和监测来获取数据,或多或少地存在数据的连续性不足等问题。基于此,本文在潮滩地貌典型的江苏平原海岸选取了约160 000 m2的盐沼潮滩作为研究对象,在多年的野外连续观测下,分析了人类围垦活动对盐沼潮滩沉积过程及变化的影响。结果表明：人类围垦活动（如堤坝建设等）对潮滩沉积和盐沼植被覆盖的变化有重要影响。围垦堤坝修建之前,研究区向陆一侧为盐沼植物（现为养殖池）,向海一侧为光滩,岸线形态比较平直。在2006年围垦堤坝修建后,研究区变为“凹岸”型的人工岸线,沉积环境变得更有利于泥沙的淤积。根据2007-2012年对滩面高程的野外观测,在风暴潮的影响下,潮滩最大淤积率高达23 cm/a。盐沼植被在泥沙快速淤积的基础上不断发育生长,盐沼植物覆盖面积不断扩张。同时外部的沙嘴也在不断增长,潮汐风浪侵蚀携带沙嘴外部泥沙进入盐沼滩地,盐沼植物在泥沙的覆盖下,出现萎缩退化,覆盖面积减少,但是对潮滩上的泥沙而言还是不断堆积增厚。柱状样岩芯的粒度垂向剖面特征也记录了盐沼潮滩沉积环境的变化。小尺度下盐沼潮滩沉积表现出的阶段性变化规律,揭示出合理的围垦活动有利于堤坝前的潮滩淤积和盐沼植被的扩张。 相似文献
15.
The effects of three photoperiods (24 hr illumination, 12 hr illumination + 12 hr darkness and 24 hr darkness) and three salinities (20‰, 30‰ and 35‰) on the uptake of 60Co and 137Cs for Chlorella sp. and on the growth of its algae are studied. The uptake of 60Co for the algae is two orders of magnitude higher than that of 137Cs. Of factorial effects, the effect of photoperiod is most significant either on the uptake of the radionuclides or on the growth of the algae; the effect of salinity comes next in order and that of their interaction remains with the last. The uptake of the two radionuclides increases with extended photoperiod while the uptake of 137Cs declines with increasing of salinity. The growth of the algae appears to be the best under the conditions of 24 hr illumination and 30‰ salinity. 相似文献
16.
Martin E. Lebo 《Marine Chemistry》1991,34(3-4)
The distribution of particle-bound phosphorus in the suspended sediment of the Delaware Estuary was examined with a sequential chemical leaching technique. The phosphorus content of particles was highest in the tidal river (140–250 μmol g−1) near major anthropogenic inputs. Despite this enrichment of river particles with phosphorus, suspended particles within the salinity gradient had a phosphorus content more similar to the world's average. Sequential chemical leaches revealed that particulate phosphorus was associated with organic matter, aluminum oxides, iron oxides, and apatite in all areas of the estuary. However, ‘excess’ particle-bound phosphorus in the tidal river was associated mainly with iron oxides (27%), aluminum oxides (23%), and organic matter (50%). Within the salinity gradient, particulate phosphorus associated with iron oxides, aluminum oxides, and apatite all decreased with increasing salinity. Estuarine mixing was simulated to determine whether the observed decreases in particle-bound phosphorus pools in field samples were due to release into solution. During simulated mixing, particulate phosphorus associated with iron and aluminum oxides decreased, but no change was observed in apatite-bound phosphorus. The results of the mixing study combined with the observed particle-bound phosphorus distributions suggest that phosphate concentrations along the Delaware Estuary may be partially ‘buffered’ by aluminum and iron oxide phases. 相似文献
17.
Groundwater flow of freshwater from upland forests into salt marshes is influenced by hydrologic forces that operate over a wide range of temporal scales, including storm events, tidal fluctuations, seasonal variations in rainfall and evapotranspiration (ET). Groundwater salinity can be a useful first order indicator of the balance between these flow processes. A dipole-dipole electrical resistivity survey was conducted approximately monthly during 2005 to measure groundwater salinity across a portion of Crabhaul Creek, a tidal salt marsh basin at the boundary of the upland forest and the North Inlet marsh in South Carolina. The monthly electrical resistivity surveys were designed to provide a detailed, spatially continuous measurement of subsurface conductivity to a depth of 4 m in order to further investigate the seasonal variation in groundwater salinity. Resistivity models were corroborated by simultaneous measurements of salinity in nearby piezometers. The freshwater-brackish water interface was clearly imaged by the resistivity. Movement of this interface occurs on a timescale of months rather than a regular seasonal variation. The average salinity in the marsh basin is highest in late Summer (July–August) when ET is highest, and lowest during the Winter (November–December). The position of the brackish-freshwater interface changes, but is not well correlated to local rainfall or tidal cycles except under specific circumstances. A steady-state hydrological model correctly predicts the average position of the freshwater-brackish interface and suggests a linear relationship between the height of the water table and the location of the interface. These results suggest a complex relationship between precipitation events and groundwater flow from the forest into the marsh. 相似文献
18.
《Estuarine, Coastal and Shelf Science》2005,62(1-2):119-130
Salt marsh morphology is known to be strongly correlated to vegetation patterns through a complex interplay of biological and physical processes. This paper presents the results of field surveys at several study salt marshes within the Venice Lagoon (Italy), which indicate that salt-marsh macrophyte species may indeed be associated with narrow ranges of soil topographic elevation. Statistical analyses show that several properties of the frequency distributions of halophytes presence are sensitive not only to variations in soil elevation, but also to the specific marsh considered. Through direct in situ sampling and by use of a finite-element hydrodynamic model the role of plant submersion duration and frequency in determining the observed variability of vegetation species is then studied. Measurements of soil salinity have also been performed at selected salt marshes to address its influence on vegetation occurrence. With implications for tidal marshes in general, the distribution of halophytes in the salt marshes considered is found not to be responding to simple rules dictated by the tidal cycle or to salinity, and that such factors, when singularly considered, cannot explain the observed spatial distribution of halophytes. On the basis of observations and modelling results it is thus concluded that a combination of multiple factors, likely dominated by saturated/unsaturated flow in the soil, may be responsible for the observed macrophyte distribution. 相似文献
19.
利用新型间歇增氧垂直流人工湿地,揭示了不同进水N H4+-N浓度下盐度提升对湿地脱氮性能及微生物群落的影响.试验结果表明:间歇增氧垂直流人工湿地在盐胁迫下的脱氮性能明显优于传统垂直流人工湿地,高盐(2.0％ 盐度)对TN去除性能影响较大,对COD去除性能影响相对较小.进水NH4+-N浓度为40 mg/L时,当盐度由0％... 相似文献
20.
Temporal and spatial variations in Synechococcus abundance were investigated over an annual cycle (February'10–January'11) along a salinity gradient (0–35) in the tropical Zuari estuary, influenced by south-west monsoons. Synechococcus exhibited salinity preferences with phycoerythrin-rich cells at salinities >2 (Synechococcus-PEI), >20 (Synechococcus-PEII) and <1 (Synechococcus-PEIII) whereas phycocyanin-rich (Synechococcus-PC) dominant at lower salinities. Downstream stratification during monsoon caused Synechococcus group segregation in the surface and near-bottom waters. During monsoon-break and non-monsoon period stabilized waters, increased salinity, temperature, solar radiation and low rainfall favored high Synechococcus abundance whereas unstable waters, increased turbidity and low solar radiation during active monsoon lowered abundance. SYN-PC positively co-related with nitrate and phosphate and SYN-PEI with phosphate. Synechococcus contribution to phytoplankton carbon biomass ranged from 9 to 29%. In monsoonal estuaries, rainfall intensity regulates freshwater runoff which modulates the estuarine environment, creating temporal–spatial niche segregation of Synechococcus groups thereby serving as indicator organisms of the estuarine hydrodynamics. 相似文献