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1.
Pipko  I. I.  Pugach  S. P.  Semiletov  I. P.  Salyuk  A. N. 《Doklady Earth Sciences》2011,438(2):858-863
Carbonate characteristics of the water mass of the deepwater part of the Arctic Ocean (AO) in the continental slope area were determined, and the range and reasons of their variability during summer-fall season were revealed. The AO water area is a meaningful sink for atmospheric carbon dioxide. The warm intermediate Atlantic waters (AW) are also undersaturated with carbon dioxide relative to its content in the atmosphere. While these waters move along AO continental slope, the value pCO2 in the AW core decreases to 8–10 μatm (mainly, due to drop in the water temperature). The potential absorption capacity of the AO deepwater basin is estimated at approximately 48 Tg of carbon (without sea ice taken into account). Joint analysis of carbonate and hydrological parameters showed that near-bottom waters formed on the shallow shelf of the Laptev Sea, which is rich in inorganic and organic carbon of terrestrial and marine genesis, take part in formation of halocline waters of the AO. They are modified due to interaction with AW penetrating to the shelf and are transferred to the deepwater AO segment, where they occur in the halocline according to their density. Transformed near-bottom waters of the Laptev Sea shelf, similar to waters of the halocline of Pacific origin in the eastern sector of the AO, are traced above the continental slope in Amundsen Basin on the basis of higher CO2 concentrations.  相似文献   

2.
The present analysis adjusts previous estimates of global ocean CaCO3 production rates substantially upward, to 133 × 1012 mol yr?1 plankton production and 42 × 1012 mol yr?1 shelf benthos production. The plankton adjustment is consistent with recent satellite-based estimates; the benthos adjustment includes primarily an upward adjustment of CaCO3 production on so-called carbonate-poor sedimentary shelves and secondarily pays greater attention to high CaCO3 mass (calcimass) and turnover of shelf communities on temperate and polar shelves. Estimated CaCO3 sediment accumulation rates remain about the same as they have been for some years: ~20 × 1012 mol yr?1 on shelves and 11 × 1012 mol yr?1 in the deep ocean. The differences between production and accumulation of calcareous materials call for dissolution of ~22 × 1012 mol yr?1 (~50 %) of shelf benthonic carbonate production and 122 × 1012 mol yr?1 (>90 %) of planktonic production. Most CaCO3 production, whether planktonic or benthonic, is assumed to take place in water depths of <100 m, while most dissolution is assumed to occur below this depth. The molar ratio of CO2 release to CaCO3 precipitation (CO2↑/CaCO3↓) is <1.0 and varies with depth. This ratio, Ψ, is presently about 0.66 in surface seawater and 0.85 in ocean waters deeper than about 1000 m. The net flux of CO2 associated with CaCO3 reactions in the global ocean in late preindustrial time is estimated to be an apparent influx from the atmosphere to the ocean, of +7 × 1012 mol C yr?1, at a time scale of 102–103 years. The CaCO3-mediated influx of CO2 is approximately offset by CO2 release from organic C oxidation in the water column. Continuing ocean acidification will have effects on CaCO3 and organic C metabolic responses to the oceanic inorganic C cycle, although those responses remain poorly quantified.  相似文献   

3.
The comparison between the first results of comprehensive micropaleontological analysis (pollen, spores, foraminifera, and ostracods) and those of radiocarbon dating (AMS14C) for the sediments of the eastern inner shelf of the Laptev Sea (the core collected from depth of 37 m) indicates that considerable changes in natural conditions in the sea and on land coincide in time and refer to the time period of 1500–1700 years B.P. This period is characterized by changes in microfossils: appearance of thermophilic pollen and planktonic foraminifera and increase in total number of benthic foraminifera and ostracods. Intense warming and humidification of the climate reconstructed for this 200-year period promoted the expansion of large-shrub tundra. Summer air temperatures were lower than that in the peak mid-Holocene climatic optimum by 2°–3°C, but 1°C higher than the present-day temperature. An estuary freshwater basin developed: it was strongly affected by river discharge, but North Atlantic waters also intensely penetrated here in short-term intervals. In general, the studied microfossil complex reflects the relatively stable environmental conditions and decrease in seawater salinity in the eastern part of the Laptev Sea shelf during the last 2300 years.  相似文献   

4.
Late Quaternary (MIS 3 to Recent) oceanographic evolution of the Basque shelf has been analysed for the first time based on the sedimentological analysis of three cores obtained from the middle and outer shelves. The cores are located in two interfluves separated by the San Sebastian canyon. The variability of the percentage of the planktonic foraminifera species Neogloboquadrina pachyderma sin. and of δ18Obull allowed us to identify the influence of colder and warmer waters in the Basque shelf during the late Quaternary. From ～56 cal. ka BP to the end of the Last Glacial Maximum (19 cal. ka BP) the sedimentary record shows a decreasing trend in the mean grain size that correlates with the eustatic sea‐level fall. The last Deglaciation (19–11.5 cal. ka BP) is characterized by a sea‐level rise that produced an important hiatus in the western outer shelf. During the Holocene, the middle and outer shelves present different behaviours. From 11.5 to 6.7 cal. ka BP, in the outer shelf the sea‐level rise that started during the Deglaciation produced a hiatus, whereas in the middle shelf the sedimentary succession records the presence of warm to temperate waters. Between 6.7–4.9 cal. ka BP, the entrance of cold surface water‐masses that only affected the middle shelf has been identified, and temperate to warm waters occurred in the outer shelf. The cold surface water‐masses retreated during 4.9–4.3 cal. ka BP in the middle shelf. Finally, from 4.3 cal. ka BP to Recent, the middle shelf registers a hiatus due to sea‐level stabilization after a generalized transgression, synchronous to a decrease in the energy of the water‐masses in the outer shelf. In conclusion, the environmental changes detected in the Basque shelf are attributed to both regional and eustatic sea‐level changes.  相似文献   

5.
Oxygen isotope profiles along the growth axis of fossil bivalve shells of Macoma calcarea were established to reconstruct hydrographical changes in the eastern Laptev Sea since 8400 cal yr B.P.. The variability of the oxygen isotopes (δ18O) in the individual records is mainly attributed to variations in the salinity of bottom waters in the Laptev Sea with a modern ratio of 0.50‰/salinity. The high-resolution δ18O profiles exhibit distinct and annual cycles from which the seasonal and annual salinity variations at the investigated site can be reconstructed. Based on the modern analogue approach oxygen isotope profiles of radiocarbon-dated bivalve shells from a sediment core located northeast of the Lena Delta provide seasonal and subdecadal insights into past hydrological conditions and their relation to the Holocene transgressional history of the Laptev Sea shelf. Under the assumption that the modern relationship between δ18Ow and salinity has been constant throughout the time, the δ18O of an 8400-cal-yr-old bivalves would suggest that bottom-water salinity was reduced and the temperature was slightly warmer, both suggesting a stronger mixture of riverine water to the bottom water. Reconstruction of the inundation history of the Laptev Sea shelf indicates local sea level ∼27 m below present at this time and a closer proximity of the site to the coastline and the Lena River mouth. Due to continuing sea level rise and a southward retreat of the river mouth, bottom-water salinity increased at 7200 cal yr B.P. along with an increase in seasonal variability. Conditions comparable to the modern hydrography were achieved by 3800 cal yr B.P.  相似文献   

6.
The aim of this study was to identify pathways and processes of modern sediment transport from the Siberian hinterland to the Laptev Sea and further to the Arctic Ocean. Clay mineral analyses were performed on riverine suspended particulate material (SPM), surface sediments of the Laptev Sea shelf, and sea-ice sediments (SIS). Material collected during seven expeditions was included in this study. Clay mineral assemblages are used to decipher the distribution of riverine sediments on the shallow Laptev Sea shelf, the entrainment of fine particles into newly forming ice, and the transport of SIS from the Laptev Sea towards the ablation areas. A cluster analysis of our data set shows that the clay mineral assemblages of Laptev Sea shelf sediments and SIS are controlled mainly by the input of riverine SPM supplied by the Khatanga, Lena, and Yana Rivers. Whereas the western shelf clay-mineral province is characterized by enhanced smectite concentrations supplied by the Khatanga River, the eastern Laptev Sea is dominated by illite discharged through the Lena and Yana Rivers. The SIS smectite concentration serves as an indicator for sediment source areas on the circum-Arctic shelves. Subsequently, the Transpolar Drift can be distinguished into a Siberian Branch fed from the eastern Kara Sea and the western Laptev Sea, and a Polar Branch originating from the eastern Laptev Sea.  相似文献   

7.
It is generally accepted view that the ventilation of Southern Ocean during the last deglaciation was the key factor in atmospheric CO2 rise. Further, other sites were identified, like the western equatorial Pacific, the Sub-Antarctic Atlantic and the eastern equatorial Pacific. Now there are evidences that CO2 was also released from the eastern Arabian Sea. The Arabian Sea is unique in characteristic, being land locked from the North and affected by monsoon winds and seasonal reversing circulations. Furthermore, the CO2 outgassing noticed during deglaciation makes it an interesting region to understand if the outgassing occurred from the deeper waters and hence led to any rise in deepwater \([\rm{CO}_3^{2-}]\).  相似文献   

8.
Oxygen and hydrogen isotope analysis was performed to study the processes of distribution of water masses and modification of their salinity in the Russian Arctic seas. A wealth of new isotopic data was obtained for freshwater (river runoff, Novaya Zemlya glaciers) and seawater samples collected along a set of extended 2D profiles in the Barents, Kara, and Laptev Seas. The study presents the first δD values measured for the Northeast Atlantic Deep Water NEADW dominated the water column of the Barents Sea (S = 34.90 ± 0.05, δD = +1.55 ± 0.4‰, δ18O = +0.26 ± 0.1‰, n = 44). This water mass is present in the Kara Sea and western Laptev Sea. The relationship between δD, δ18О, and salinity data was used to calculate the fractions of waters of different origin, including the fractions of continental runoff in waters of the Barents, Kara, and Laptev Seas. It was shown that the relationships between the isotopic parameters (δD, δ18О) and salinity in waters of the Kara and Laptev Seas is controlled by the intensity of continental runoff and sea ice processes. Sea ice formation is the main factor controlling the formation of the water column on the Laptev Sea shelf, whereas the surface waters of the middle Kara Sea are dominated by the contribution of river runoff. A very strong stratification in the Kara Sea is caused by the presence of a relatively fresh surface layer mostly contributed by estuarine water inputs from the Ob and Yenisei Rivers. The contribution of river waters reaches 40–60% in the surface layer in the central part of the sea and decreases to a few percent down 100 m water depth. Stratification in the western part of the Laptev Sea is controlled by the contribution of freshwater input from the Lena River and modification of salinity by sea ice formation.  相似文献   

9.
The Holocene paleogeography of the Laptev Sea eastern shelf is reconstructed based on mollusks, foraminifers, ostracodes, spores and pollen found for the first time. Environmental changes in the course of the postglacial (Holocene) transgression are detectable from quantitative analysis of three ostracod assemblages. Three phases of the transgression are established based on ostracode assemblages from the AMS 14C-dated core from the ancient valley of Yana River, central part of the Laptev Sea eastern shelf. After the first phase of coastal brackish-water environment (11.3–11.1 ka), shallow-water marine taxa appeared in the transitional phase (11.1–10.3 ka), and the third phase of modern sea conditions commenced 10.3 ka ago. Spore and pollen assemblages from the core indicate that the early Holocene land vegetation was dominated by tundra plant communities adapted to climatic conditions not warmer than at present. In the interval of 9.3–8.0 ka, climate was increasingly humid and warm, and forest-tundra vegetation occupied more favorable zones of the region.  相似文献   

10.
After more than a decade of multidisciplinary studies of the Central American subduction zone mainly in the framework of two large research programmes, the US MARGINS program and the German Collaborative Research Center SFB 574, we here review and interpret the data pertinent to quantify the cycling of mineral-bound volatiles (H2O, CO2, Cl, S) through this subduction system. For input-flux calculations, we divide the Middle America Trench into four segments differing in convergence rate and slab lithological profiles, use the latest evidence for mantle serpentinization of the Cocos slab approaching the trench, and for the first time explicitly include subduction erosion of forearc basement. Resulting input fluxes are 40–62 (53) Tg/Ma/m H2O, 7.8–11.4 (9.3) Tg/Ma/m CO2, 1.3–1.9 (1.6) Tg/Ma/m Cl, and 1.3–2.1 (1.6) Tg/Ma/m S (bracketed are mean values for entire trench length). Output by cold seeps on the forearc amounts to 0.625–1.25 Tg/Ma/m H2O partly derived from the slab sediments as determined by geochemical analyses of fluids and carbonates. The major volatile output occurs at the Central American volcanic arc that is divided into ten arc segments by dextral strike-slip tectonics. Based on volcanic edifice and widespread tephra volumes as well as calculated parental magma masses needed to form observed evolved compositions, we determine long-term (105 years) average magma and K2O fluxes for each of the ten segments as 32–242 (106) Tg/Ma/m magma and 0.28–2.91 (1.38) Tg/Ma/m K2O (bracketed are mean values for entire Central American volcanic arc length). Volatile/K2O concentration ratios derived from melt inclusion analyses and petrologic modelling then allow to calculate volatile fluxes as 1.02–14.3 (6.2) Tg/Ma/m H2O, 0.02–0.45 (0.17) Tg/Ma/m CO2, and 0.07–0.34 (0.22) Tg/Ma/m Cl. The same approach yields long-term sulfur fluxes of 0.12–1.08 (0.54) Tg/Ma/m while present-day open-vent SO2-flux monitoring yields 0.06–2.37 (0.83) Tg/Ma/m S. Input–output comparisons show that the arc water fluxes only account for up to 40 % of the input even if we include an “invisible” plutonic component constrained by crustal growth. With 20–30 % of the H2O input transferred into the deeper mantle as suggested by petrologic modeling, there remains a deficiency of, say, 30–40 % in the water budget. At least some of this water is transferred into two upper-plate regions of low seismic velocity and electrical resistivity whose sizes vary along arc: one region widely envelopes the melt ascent paths from slab top to arc and the other extends obliquely from the slab below the forearc to below the arc. Whether these reservoirs are transient or steady remains unknown.  相似文献   

11.
The spatial and temporal variations of the flux of CO2 were determined during 2007 in the Recife estuarine system (RES), a tropical estuary that receives anthropogenic loads from one of the most populated and industrialized areas of the Brazilian coast. The RES acts as a source of nutrients (N and P) for coastal waters. The calculated CO2 fluxes indicate that the upstream inputs of CO2 from the rivers are largely responsible for the net annual CO2 emission to the atmosphere of +30 to +48 mmol m?2 day?1, depending on the CO2 exchange calculation used, which mainly occurs during the late austral winter and early summer. The observed inverse relationship between the CO2 flux and the net ecosystem production (NEP) indicates the high heterotrophy of the system (except for the months of November and December). The NEP varies between ?33 mmol m?2 day?1 in summer and ?246 mmol m?2 day?1 in winter. The pCO2 values were permanently high during the study period (average ~4,700 μatm) showing a gradient between the inner (12,900 μatm) and lower (389 μatm) sections on a path of approximately 30 km. This reflects a state of permanent pollution in the basin due to the upstream loading of untreated domestic effluents (N/P?=?1,367:6 μmol kg?1 and pH?=?6.9 in the inner section), resulting in the continuous mineralization of organic material by heterotrophic organisms and thereby increasing the dissolved CO2 in estuarine waters.  相似文献   

12.
Benthic microalgae (BMA) inhabit the upper few centimeters of shelf sediments. This review summarizes the current information on BMA communities in the South Atlantic Bight (SAB) region of the Southeastern US continental shelf to provide insights into the potential role of these communities in the trophodynamics and biogeochemical cycling in shelf waters. Benthic irradiance is generally 2–6% of surface irradiance in the SAB region, providing sufficient light to support BMA primary production over 80–90% of the shelf width. BMA biomass greatly exceeds that of integrated phytoplankton biomass in the overlying water column on an areal basis. The SAB appears to have lower BMA biomass, but higher production than most temperate continental shelves. Annual production estimates average 101 and 89 g C m?2 year?1 for 5–20 and >?20 depth intervals, respectively. However, high variation in rates and biomass in time and space make comparisons between studies difficult. Submarine groundwater discharge (SGD) rather than the water column or in situ N regeneration from organic matter maybe the major “new” N source for BMA. The estimated supply of N (1.2 mmol N m?2 day?1) by SGD closely approximates the rates needed to support BMA primary production (3.1 to 1.6 mmol N m?2 day?1) in the sediments of the SAB. Identifying the source(s) of fixed N supporting the BMA community is essential for understanding the carbon dynamics and net ecosystem metabolism within the large area (76,000 km2) of the continental shelf in the SAB as well other temperate shelves worldwide.  相似文献   

13.
Stable carbon isotope ratios in the organic fraction of surface sediments from the Laptev Sea shelf were analyzed in order to study the modern distribution pattern of terrestrial organic matter. The '13Corg signature of the surface sediments range from -26.6‰ near the coastal margin to -22.8‰ in the north towards the outer shelf. Characterizing the possible sources of organic matter by their '13Corg signature reveals that the terrestrial influence reaches further north in the eastern than in the western Laptev Sea. Downcore records of the '13Corg, measured on three AMS 14C-dated cores from water depths between 46 and 77 m, specify the spatial and temporal changes in the deposition of terrestrial organic matter on the Laptev Sea shelf during the past 12.7 ka. The major depositional changes of terrestrial organic matter occurred between 11 and 7 ka and comprised the main phase of the southward retreat of the coastline and of the river depocenters due to the postglacial sea level rise.  相似文献   

14.
A comparison of the first results of a comprehensive micropaleontological analysis (pollen, spores, organic-walled microfossils, diatoms, ostracods) and radiocarbon ages (AMS14C) from sediment core recovered in the northeastern outer shelf of the Laptev Sea (51 m water depth) revealed a temporal coincidence between terrestrial and marine environmental changes that occurred between 11.2–10.3 cal ka. This interval provided evidence for a landscape transition from grass tundra to shrub tundra and the development of a freshwater estuarine basin with the strong influence of riverine discharge and a minor advection of North Atlantic waters. The establishment of a warmer and wetter climate promoted the expansion of shrub tundra habitats. The interval of 9.5–7.5 cal ka recorded a transition from a shrub tundra environment to forest-tundra vegetation. This interval also revealed a series of short-term temperature fluctuations, when summer temperatures were 3–4°C higher than today. The active advection of North Atlantic waters and the increase in salinity were also recorded by this interval.  相似文献   

15.
The present study examines the temporal variability of air–water CO2 fluxes (FCO2) and seawater carbonate chemistry in a Baja California coastal lagoon during an exceptionally warm anomaly that was developed in Northeast Pacific coasts during 2014. This oceanographic condition led to a summer-like season (weak upwelling condition) during the study period, which reached a maximum surface temperature anomaly of 2 °C in September 2014. San Quintín Bay acts as a source of CO2 to the atmosphere in 2014 (3.3 ± 4.8 mmol C m?2 day?1) with the higher positive fluxes mainly observed in summer months (9.0 ± 5.3 mmol C m?2 day?1). Net ecosystem production (NEP) switched seasonally between net heterotrophy and net autotrophy during the study period, with an annual average of 2.2 ± 7.1 mmol C m?2 day?1, which indicates that San Quintín Bay was a net autotrophic system during the atypical warm oceanographic condition in 2014. This pattern of seasonal variations in the carbon balance at San Quintín Bay appears to be linked to the life cycle of benthic communities, which play an important role in the whole-ecosystem metabolism. Under the limited input from external sources coupled with an increase in seawater temperatures, the recycled benthic carbon and nutrient fluxes play a major role to sustain water-column processes within the bay. Since the upwelling condition may influence the magnitude of the air–water CO2 fluxes, our results clearly indicated that San Quintín Bay is a net source of carbon to the atmosphere regardless of the adjacent oceanic conditions. Our study sheds light on the carbon dynamics and its metabolic implications in a shallow coastal ecosystem under a regional warm anomaly and contributes potentially relevant information in view of the likely future scenario of global climate change.  相似文献   

16.
A field facility located in Bozeman, Montana provides the opportunity to test methods to detect, locate, and quantify potential CO2 leakage from geologic storage sites. From 9 July to 7 August 2008, 0.3 t CO2 day−1 were injected from a 100-m long, ~2.5-m deep horizontal well. Repeated measurements of soil CO2 fluxes on a grid characterized the spatio-temporal evolution of the surface leakage signal and quantified the surface leakage rate. Infrared CO2 concentration sensors installed in the soil at 30 cm depth at 0–10 m from the well and at 4 cm above the ground at 0 and 5 m from the well recorded surface breakthrough of CO2 leakage and migration of CO2 leakage through the soil. Temporal variations in CO2 concentrations were correlated with atmospheric and soil temperature, wind speed, atmospheric pressure, rainfall, and CO2 injection rate.  相似文献   

17.
This paper estimates CO2 fluxes in a municipal site for final disposal of solid waste, located in Gualeguaychu, Argentina. Estimations were made using the accumulation chamber methods, which had been calibrated previously in laboratory. CO2 fluxes ranged from 31 to 331 g m−2 day−1. Three different populations were identified: background soil gases averaging 46 g m−2 day−1, intermediate anomalous values averaging 110 g m−2 day−1 and high anomalous values averaging 270 g m−2 day−1. Gas samples to a depth of 20 cm were also taken. Gas fractions, XCO2 < 0.1, XCH4 < 0.01, XN2 ~0.71 and XO2 ~0.21, δ13C of CO2 (−34 to −18‰), as well as age of waste emplacement, suggest that the study site may be at the final stage of aerobic biodegradation. In a first approach, and following the downstream direction of groundwater flow, alkalinity and δ13C of dissolved inorganic carbon (−15 to 4‰) were observed to increase when groundwater passed through the disposal site. This suggests that the CO2 generated by waste biodegradation dissolves or that dissolved organic matter appears as a result of leachate degradation.  相似文献   

18.
The impact of water quality changes in River Changjiang (formally known as the Yangtze River) on dissolved CO2 and silicate concentrations and seasonal carbon flux in the past several decades (1960s–2000) was evaluated, based on monitoring data from hydrographic gauge. It was found that dissolved CO2 and silicate in Changjiang decreased dramatically during this decades, as opposed to a marked increase in nutrient (e.g. NO3 -) concentrations. Our analyses revealed that dissolved CO2 in Changjiang was over-saturated with the atmosphere CO2, and its concentration had showed a declining trend since the 1960s, despite that fluvial DIC flux had maintained stable. Analysis results also suggested that the decrease in dissolved CO2 concentration was attributed to changes on the riverine trophic level and river damming activities in the Changjiang drainage basin. Due to the economic innovation (e.g. agriculture and industry development) across the Changjiang watershed, fertilizers application and river regulations have significantly altered the original state of the river. Its ecosystem and hydrological condition have been evolving toward the "lacustrine/reservoir" autotrophic type prevailing with plankton. Accordingly, average CO2 diffusing flux to the atmosphere from the river had been reduced by three-fourth from the 1960s to 1990s, with the flux value being down to 14.2 mol.m-2.yr-1 in the 1990s. For a rough estimate, approximately 15.3 Mt of carbon was degassed annually into the atmosphere from the entire Changjiang drainage basin in the 1990s.  相似文献   

19.
During the formation and development of glacial meltwater runoff, hydrochemical erosion is abundant, especially the hydrolysis of K/Na feldspar and carbonates, which can consume H+ in the water, promote the formation of bicarbonate by dissolving atmospheric CO2, and affect the regional carbon cycle. From July 21, 2015, to July 18, 2017, the CO2 concentration and flux were observed by the eddy covariance (EC) method in the relatively flat and open moraine cover area of Koxkar Glacier in western Mt. Tianshan, China. We found that: (1) atmospheric CO2 fluxes ranged from ??408.95 to 81.58 mmol m?2 day?1 (average ? 58.68 mmol m?2 day?1), suggesting that the study area is a significant carbon sink, (2) the CO2 flux footprint contribution areas were primarily within 150 m of the EC station, averaging total contribution rates of 93.30%, 91.39%, and 90.17% of the CO2 flux in the snow accumulation, snow melting, and glacial melting periods, respectively. Therefore, the contribution areas with significant influences on CO2 flux observed at EC stations were concentrated, demonstrating that grassland CO2 flux around the glaciers had little effect at the EC stations, (3) in the predominant wind direction, under stable daytime atmospheric stratification, the measurement of CO2 flux, as interpreted by the Agroscope Reckenholz Tanikon footprint tool, was 79.09% ± 1.84% in the contribution area. This was slightly more than seen at night, but significantly lower than the average under unstable atmospheric stratification across the three periods of interest (89%). The average distance of the farthest point of the flux footprint under steady state atmospheric conditions was 202.61?±?69.33 m, markedly greater than that under non-steady state conditions (68.55?±?10.34 m). This also indicates that the CO2 flux observed using EC was affected primarily by hydrochemical erosion reactions in the glacier area, (4) a good negative correlation was found between net glacier exchange (NGE) of CO2 and air temperature on precipitation-free days. Strong ice and snow ablation could promote hydrochemical reactions of soluble substances in the debris area and accelerated sinking of atmospheric CO2. Precipitation events might reduce snow and ice melting, driven by reduced regional temperatures. However, a connection between NGE and precipitation, when less than 8.8 mm per day, was not obvious. When precipitation was greater than 8.8 mm per day, NGE decreased with increasing precipitation, (5) graphically, the slope of NGE, related to daily runoff, followed a trend: snow melting period?>?snow accumulation period?>?early glacial ablation period?>?late glacier ablation period?>?dramatic glacier ablation period. The slope was relatively large during snow melting, likely because of CO2 sinking caused by water–rock interactions. The chemical reaction during elution in the snow layer might also promote atmospheric CO2 drawdown. At the same time, the damping effect of snow cover and the almost-closed glacier hydrographic channel inhibited the formation of regional runoff, possibly providing sufficient time for the chemical reaction, thus promoting further CO2 drawdown.  相似文献   

20.
This paper presents the results of two cruises in the Northern Gulf of Mexico in 2008 that investigated local and short-term factors influencing the carbonate chemistry dynamics and saturation state with respect to aragonite (Ωaragonite) of surface seawater in this region. One cruise covered much of the northern half of the Gulf, and the other focused on the coastal zone west of the Atchafalaya Bay outlet of the Mississippi River—the region where the hypoxic “dead zone” occurs on the Louisiana shelf. Offshore waters (>100 m depth) exhibited only small variations in CO2 fugacity (fCO2), total alkalinity (TA) and Ωaragonite. Values were close to those typically observed in subtropical Atlantic Ocean and Caribbean Sea waters of similar salinity. However, inner shelf waters (<50 m depth) exhibited large variations in fCO2, TA, and Ωaragonite that were not directly related to salinity or distance from the Mississippi River plume. Changes in TA values were not the result of simple mixing of end-member freshwater and seawater TA concentrations but exhibited a minimum in values near salinity of 25. This minimum could be the result of microbial recycling across salinity gradients, biological removal of alkalinity by formation of calcium carbonate or mixing of a third end-member with a low alkalinity such as Terrebonne Bay. All waters were supersaturated with respect to aragonite. Offshore waters had an average Ωaragonite of 3.86 with a standard deviation of only ±0.06 and inner shelf waters had a range in Ωaragonite values from 3.9 to 9.7 with a median of 4.3. Shelf water Ωaragonite values were elevated relative to the offshore as a consequence of both high TA input from Mississippi River and biological drawdown of CO2. A dominant factor controlling Ωaragonite distribution in offshore waters with relatively constant temperatures was fCO2, with higher supersaturation occurring in areas with low fCO2.  相似文献   

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