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1.
Many gas seepages, temperature, pressure, salinity, anoxic environment and high source gas potential of the Black Sea indicates that the Black Sea might have huge potentials for biogenic and thermogenic gas hydrates. However, the last important parameter to consider gas hydrate as an energy source is the type of sediments. Coarse marine sands are considered as good hydrate reservoirs because of high porosity and high permeability. Only very limited data is available related to the types of lithology of the Black Sea sediments. Hence, in this study, the literature data (especially the drilling and coring data of DSDP Leg 42B program) about gas seepages, temperature gradient, pressure gradient, salinity, anoxic environment and high source gas potential, and the types of the sediments in the Black Sea were investigated and analyzed. Although gas seepages, temperature gradient, pressure gradient, salinity, anoxic environment and high source gas potential of the Black Sea are appropriate for producible gas hydrate reservoirs, the sediments of the Black Sea appear to be generally fine grained with high clay content. Sandy-silt and silty sand layers in turbidites of the Black Sea might be potential producible hydrate reservoirs but these sediments are fine. As well as turbidites, separate thin sand layers might be potential gas hydrate reservoirs as an energy source in the Black Sea.  相似文献   

2.
用地球化学方法勘查中国南海的天然气水合物   总被引:7,自引:0,他引:7  
天然气水合物是一种未来新型能源,赋存于低温高压环境下的海洋沉积物中,但也可形成于大陆永久冻土带中。天然气水合物资源量巨大,具有经济和环境上的研究意义。近年来,国际上己对天然气水合物的产况、分布和形成机理开展了大量研究,但国内这方面的工作还刚刚开展。对中国南海的调查表明该区存在天然气水合物赋存的有利地质条件、温压条件和富含有机质的沉积条件。在南海的许多海区还发现了指示天然气水合物存在的地震标志(BSR)。介绍了在南海天然气水合物勘查中的地球化学异常标志。这些地球化学异常的产生可能与天然气水合物的形成或分解过程有关。研究内容包括沉积物中气体含量(主要为甲烷和乙烷),甲烷的碳同位素,孔隙水中阴离子(Cl^-、SO4^2-等)、阳离子(Ca^2 、Mg^2 、Ba^2 、Sr^2 ,B^3 和NH4^ 等)浓度和δ^18,δD,δ^11B,及^87Sr/^86Sr等同位素组成,此外还对海底沉积物的热释光特征和紫外、可见、近红外反射光谱特征开展了探索性研究。通过进一步加强理论和实验研究,结合地球物理和地球化学资料,在不远的将来将会在南海发现和圈定天然气水合物矿藏。  相似文献   

3.
The sediment temperature distribution at mud volcanoes provides insights into their activity and into the occurrence of gas hydrates. If ambient pressure and temperature conditions are close to the limits of the gas hydrate stability field, the sediment temperature distribution not only limits the occurrence of gas hydrates, but is itself influenced by heat production and consumption related to the formation and dissociation of gas hydrates. Located in the Sorokin Trough in the northern Black Sea, the Dvurechenskii mud volcano (DMV) was in the focus of detailed investigations during the M72/2 and M73/3a cruises of the German R/V Meteor and the ROV Quest 4000 m in February and March 2007. A large number of in-situ sediment temperature measurements were conducted from the ROV and with a sensor-equipped gravity corer. Gas hydrates were sampled in pressurized cores using a dynamic autoclave piston corer (DAPC). The thermal structure of the DMV suggests a regime of fluid flow at rates decreasing from the summit towards the edges of the mud volcano, accompanied by intermittent mud expulsion at the summit. Modeled gas hydrate dissociation temperatures reveal that the gas hydrates at the DMV are very close to the stability limits. Changes in heat flow due to variable seepage rates probably do not result in changes in sediment temperature but are compensated by gas hydrate dissociation and formation.  相似文献   

4.
Seismic profiles from a venting area on the western margin of Paramushir Island (Sea of Okhotsk) reveal a local complex structure and an interesting, unusual pattern of the bottom simulating reflector (BSR). The BSR is gradual rising towards the venting area. The geothermal gradient and the bottom temperature confirmed the methane hydrate. The temperature appears to be the most important factor controlling the hydrate stability. A locally higher heat flow caused the upward migration of the hydrate stability field and the subsequent degradation of the hydrated sediments, causing gas vent formation and the flux of methane gas into the water column.  相似文献   

5.
近年的研究表明南海北部陆坡区发育有底辟构造、海底滑坡以及活动断层带等有利于天然气水合物形成的地质构造环境.受深部地幔上隆的影响,南海整个海区热流背景值偏高,地热资源十分丰富,由此提出了利用地热加热海水,用热激发法分解天然气水合物的设想,并设计了初步的生产工艺.用传统热激发方法开采天然气水合物藏本身需要消耗大量能源,而且...  相似文献   

6.
《Marine and Petroleum Geology》2012,29(10):1751-1767
Supplies of conventional natural gas and oil are declining fast worldwide, and therefore new, unconventional forms of energy resources are needed to meet the ever-increasing demand. Amongst the many different unconventional natural resources are gas hydrates, a solid, ice-like crystalline compound of methane and water formed under specific low temperature and high pressure conditions. Gas hydrates are believed to exist in large quantities worldwide in oceanic regions of continental margins, as well as associated with permafrost regions in the Arctic. Some studies to estimate the global abundance of gas hydrate suggest that the total volume of natural gas locked up in form of gas hydrates may exceed all known conventional natural gas reserves, although large uncertainties exist in these assessments. Gas hydrates have been intensively studied in the last two decades also due to connections between climate forcing (natural and/or anthropogenic) and the potential large volumes of methane trapped in gas hydrate accumulations. The presence of gas hydrate within unconsolidated sediments of the upper few hundred meters below seafloor may also pose a geo-hazard to conventional oil and gas production. Additionally, climate variability and associated changes in pressure-temperature regimes and thus shifts in the gas hydrate stability zone may cause the occurrence of submarine slope failures.Several large-scale national gas hydrate programs exist especially in countries such as Japan, Korea, Taiwan, China, India, and New Zealand, where large demands of energy cannot be met by domestic supplies from natural resources. The past five years have seen several dedicated deep drilling expeditions and other scientific studies conducted throughout Asia and Oceania to understand gas hydrates off India, China, and Korea. This thematic set of publications is dedicated to summarize the most recent findings and results of geo-scientific studies of gas hydrates in the marginal seas and continental margin of the Asia, and Oceania region.  相似文献   

7.
Supplies of conventional natural gas and oil are declining fast worldwide, and therefore new, unconventional forms of energy resources are needed to meet the ever-increasing demand. Amongst the many different unconventional natural resources are gas hydrates, a solid, ice-like crystalline compound of methane and water formed under specific low temperature and high pressure conditions. Gas hydrates are believed to exist in large quantities worldwide in oceanic regions of continental margins, as well as associated with permafrost regions in the Arctic. Some studies to estimate the global abundance of gas hydrate suggest that the total volume of natural gas locked up in form of gas hydrates may exceed all known conventional natural gas reserves, although large uncertainties exist in these assessments. Gas hydrates have been intensively studied in the last two decades also due to connections between climate forcing (natural and/or anthropogenic) and the potential large volumes of methane trapped in gas hydrate accumulations. The presence of gas hydrate within unconsolidated sediments of the upper few hundred meters below seafloor may also pose a geo-hazard to conventional oil and gas production. Additionally, climate variability and associated changes in pressure-temperature regimes and thus shifts in the gas hydrate stability zone may cause the occurrence of submarine slope failures.Several large-scale national gas hydrate programs exist especially in countries such as Japan, Korea, Taiwan, China, India, and New Zealand, where large demands of energy cannot be met by domestic supplies from natural resources. The past five years have seen several dedicated deep drilling expeditions and other scientific studies conducted throughout Asia and Oceania to understand gas hydrates off India, China, and Korea. This thematic set of publications is dedicated to summarize the most recent findings and results of geo-scientific studies of gas hydrates in the marginal seas and continental margin of the Asia, and Oceania region.  相似文献   

8.
The Taixinan Basin is one of the most potential gas hydrate bearing areas in the South China Sea and abundant gas hydrates have been discovered during expedition in 2013. In this study, geochemical and microbial methods are combinedly used to characterize the sediments from a shallow piston Core DH_CL_11(gas hydrate free) and a gas hydrate-bearing drilling Core GMGS2-16 in this basin. Geochemical analyses indicate that anaerobic oxidation of methane(AOM) which is speculated to be linked to the ongoing gas hydrate dissociation is taking place in Core DH_CL_11 at deep. For Core GMGS2-16, AOM related to past episodes of methane seepage are suggested to dominate during its diagenetic process; while the relatively enriched δ18O bulk-sediment values indicate that methane involved in AOM might be released from the "episodic dissociation" of gas hydrate.Microbial analyses indicate that the predominant phyla in the bacterial communities are Firmicutes and Proteobacteria(Gammaproteobacteria and Epsilonproteobacteria), while the dominant taxa in the archaeal communities are Marine_Benthic_Group_B(MBGB), Halobacteria, Thermoplasmata, Methanobacteria,Methanomicrobia, Group C3 and MCG. Under parallel experimental operations, comparable dominant members(Firmicutes and MBGB) are found in the piston Core DH_CL_11 and the near surface layer of the long drilling Core GMGS2-16. Moreover, these members have been found predominant in other known gas hydrate bearing cores, and the dominant of MBGB has even been found significantly related to gas hydrate occurrence. Therefore,a high possibility for the existing of gas hydrate underlying Core DH_CL_11 is inferred, which is consistent with the geochemical analyses. In all, combined geochemical and microbiological analyses are more informative in characterizing sediments from gas hydrate-associated areas in the South China Sea.  相似文献   

9.
An anomalous strong, shallow reflector has been observed in several deep-tow subbottom profiler records in a region of the northern Black Sea characterised by seafloor fluid seeps, mud volcanoes, and the occurrence of gas hydrates. The digital data were processed using adapted seismic processing methods. Synthetic seismograms created to model representative traces from the observed profiles require anomalous alternations of acoustic properties in the upper sediments which can best be explained by interbedded layers of normal sediments and sediments with gas hydrates. The enigmatic strong reflector can be explained by constructive interference of reflections from five of these thin layers. It is proposed that the uppermost region of the gas hydrate stability zone here is represented by thinning layers of interbedded gas hydrates or layers with lower concentrations of gas hydrates.  相似文献   

10.
Two sites of the Deep Sea Drilling Project in contrasting geologic settings provide a basis for comparison of the geochemical conditions associated with marine gas hydrates in continental margin sediments. Site 533 is located at 3191 m water depth on a spit-like extension of the continental rise on a passive margin in the Atlantic Ocean. Site 568, at 2031 m water depth, is in upper slope sediment of an active accretionary margin in the Pacific Ocean. Both sites are characterized by high rates of sedimentation, and the organic carbon contents of these sediments generally exceed 0.5%. Anomalous seismic reflections that transgress sedimentary structures and parallel the seafloor, suggested the presence of gas hydrates at both sites, and, during coring, small samples of gas hydrate were recovered at subbottom depths of 238m (Site 533) and 404 m (Site 568). The principal gaseous components of the gas hydrates wer methane, ethane, and CO2. Residual methane in sediments at both sites usually exceeded 10 mll?1 of wet sediment. Carbon isotopic compositions of methane, CO2, and ΣCO2 followed parallel trends with depth, suggesting that methane formed mainly as a result of biological reduction of oxidized carbon. Salinity of pore waters decreased with depth, a likely result of gas hydrate formation. These geochemical characteristics define some of the conditions associated with the occurrence of gas hydrates formed by in situ processes in continental margin sediments.  相似文献   

11.
This paper presents a computational model for mapping the regional 3D distribution in which seafloor gas hydrates would be stable, that is carried out in a Geographical Information System (GIS) environment. The construction of the model is comprised of three primary steps, namely: (1) the construction of surfaces for the various variables based on available 3D data (seafloor temperature, geothermal gradient and depth-pressure); (2) the calculation of the gas function equilibrium functions for the various hydrocarbon compositions reported from hydrate and sediment samples; and (3) the calculation of the thickness of the hydrate stability zone. The solution is based on a transcendental function, which is solved iteratively in a GIS environment.The model has been applied in the northernmost continental slope of the Gulf of Cadiz, an area where an abundant supply for hydrate formation, such as extensive hydrocarbon seeps, diapirs and fault structures, is combined with deep undercurrents and a complex seafloor morphology. In the Gulf of Cadiz, the model depicts the distribution of the base of the gas hydrate stability zone for both biogenic and thermogenic gas compositions, and explains the geometry and distribution of geological structures derived from gas venting in the Tasyo Field (Gulf of Cadiz) and the generation of BSR levels on the upper continental slope.  相似文献   

12.
东海天然气水合物的地震特征   总被引:1,自引:0,他引:1  
使用中国科学院海洋研究所“科学一号”调查船于2001年以及20世纪80年代在东海地区采集的多道地震资料,以海域天然气水合物研究为目的,对这些资料进行了数据处理并获得了偏移地震剖面。通过对地震剖面的解释,在6条剖面上确定了6段异常反射为BSR,均有振幅强、与海底相位相反的特点。6段BSR基本上都没有出现和沉积地层相交的现象。分析认为,这与东海地区第四纪以来的沉积特征有关,并不能由此否认这些异常反射是BSR。6段BSR出现的水深为750~2 000 m,埋深在0.1~0.5 s(双程时间)之间。随着海底深度的增大,BSR埋深有增大的趋势。计算结果显示,6段BSR所处的温度和压力条件都满足水合物稳定赋存所需要的温度和压力条件。本文的BSR主要与北卡斯凯迪亚盆地以及智利海域水合物的温度、压力条件相似,而与日本南海海槽、美国布莱克海台等海域水合物的温度、压力条件相差比较大。在地震剖面上,6段BSR所处的局部构造位置都和挤压、断层有关,有利于水合物的发育;在空间上,它们主要分布在东海陆坡近槽底的位置以及与陆坡相近的槽底。在南北方向上,除分布在吐噶喇断裂和宫古断裂附近外,还与南奄西、伊平屋和八重山热液活动区相邻。热液活动和水合物虽然没有直接的成因关系,但岩浆活动为水合物气源的形成提供了热源条件,为流体和气体的运移、聚集提供了通道条件,从而有利于水合物的发育与赋存。根据地震剖面反射特征推断,剖面A1A2和A14A23发育BSR的位置应该有气体或者流体从海底流出,可能是海底冷泉发育的位置。剖面A14A23上BSR发育处,振幅比的异常增大和BSR埋深的降低是相关联的。这种关联支持该处发育海底冷泉的推测。  相似文献   

13.
The geochemical cycling of barium was investigated in sediments of pockmarks of the northern Congo Fan, characterized by surface and subsurface gas hydrates, chemosynthetic fauna, and authigenic carbonates. Two gravity cores retrieved from the so-called Hydrate Hole and Worm Hole pockmarks were examined using high-resolution pore-water and solid-phase analyses. The results indicate that, although gas hydrates in the study area are stable with respect to pressure and temperature, they are and have been subject to dissolution due to methane-undersaturated pore waters. The process significantly driving dissolution is the anaerobic oxidation of methane (AOM) above the shallowest hydrate-bearing sediment layer. It is suggested that episodic seep events temporarily increase the upward flux of methane, and induce hydrate formation close to the sediment surface. AOM establishes at a sediment depth where the upward flux of methane from the uppermost hydrate layer counterbalances the downward flux of seawater sulfate. After seepage ceases, AOM continues to consume methane at the sulfate/methane transition (SMT) above the hydrates, thereby driving the progressive dissolution of the hydrates “from above”. As a result the SMT migrates downward, leaving behind enrichments of authigenic barite and carbonates that typically precipitate at this biogeochemical reaction front. Calculation of the time needed to produce the observed solid-phase barium enrichments above the present-day depths of the SMT served to track the net downward migration of the SMT and to estimate the total time of hydrate dissolution in the recovered sediments. Methane fluxes were higher, and the SMT was located closer to the sediment surface in the past at both sites. Active seepage and hydrate formation are inferred to have occurred only a few thousands of years ago at the Hydrate Hole site. By contrast, AOM-driven hydrate dissolution as a consequence of an overall net decrease in upward methane flux seems to have persisted for a considerably longer time at the Worm Hole site, amounting to a few tens of thousands of years.  相似文献   

14.
During the Russian Academy of Sciences “MIRI na Baikale, 2008–2010” expedition, deep-water experiments with the bubbles of methane seeping from the bottom at depths 405, 860 and 1400 meters were carried out. These depths correspond to gas hydrate stability zone. Bubbles were caught by the trap which was looked like an inverted glass. It was found that the behavior of bubbles in a trap depends on the depth. At depth of 405 meters formation of hydrates was not observed. Having got to a trap at the depth of 860 meters, bubbles became covered by solid hydrate envelope, kept the initial form, and after a time period collapsed in a number of hydrate fragments which showed all properties of a granular matter. No visible changes in the hydrate granular matter were observed in the course of lifting it to a depth of 380 meters. Shallower, the decomposition of the hydrate granular matter into methane gas was observed. In the experiments at depth of 1400 meters the caught bubbles, becoming covered by hydrate envelope formed solid hydrate foam in the trap. At lifting this foam structure was deformed slightly but simultaneously a free gas left the foam and filled the trap. The volume of free gas in the trap at lifting varied according to the Boyle-Mariotte law.  相似文献   

15.
We have implemented a 2-dimensional numerical model for simulating gas hydrate and free gas accumulation in marine sediments. The starting equations are those of the conservation of the transport of momentum, energy, and mass, as well as those of the thermodynamics of methane hydrate stability and methane solubility in the pore-fluid. These constitutive equations are then integrated into a finite element in space, finite-difference in time scheme. We are then able to examine the formation and distribution of methane hydrate and free gas in a simple geologic framework, with respect to the geothermal heat flow, fluid flow, the methane in-situ production and basal flux. Three simulations are performed, leading to the build up of hydrate emplacements largely linear through time. Models act primarily as free gas accumulators and are relatively inefficient with respect to hydrate emplacements: 26–33% of formed methane are converted to hydrate. Seepage of methane across the sea-floor is negligible for fluid flow below 2. 10−11 kg/m2/s. At 5.625 10−11 kg/m2/s however, 9.7% of the formed methane seeps out of the model. Moreover, along strike variation arising in the 2-dimensional model are outlined. In the absence of focused flow, the thermodynamics of hydrate accumulation are primarily one-dimensional. However, changes in free methane compressibility (density) and methane solubility (the intrinsic dissolved methane flux) subtlety impact on the formation of a free gas zone and the distribution of the hydrate emplacements in our 2-dimensional simulations.  相似文献   

16.
《Marine and Petroleum Geology》2012,29(10):1856-1869
We have implemented a 2-dimensional numerical model for simulating gas hydrate and free gas accumulation in marine sediments. The starting equations are those of the conservation of the transport of momentum, energy, and mass, as well as those of the thermodynamics of methane hydrate stability and methane solubility in the pore-fluid. These constitutive equations are then integrated into a finite element in space, finite-difference in time scheme. We are then able to examine the formation and distribution of methane hydrate and free gas in a simple geologic framework, with respect to the geothermal heat flow, fluid flow, the methane in-situ production and basal flux. Three simulations are performed, leading to the build up of hydrate emplacements largely linear through time. Models act primarily as free gas accumulators and are relatively inefficient with respect to hydrate emplacements: 26–33% of formed methane are converted to hydrate. Seepage of methane across the sea-floor is negligible for fluid flow below 2. 10−11 kg/m2/s. At 5.625 10−11 kg/m2/s however, 9.7% of the formed methane seeps out of the model. Moreover, along strike variation arising in the 2-dimensional model are outlined. In the absence of focused flow, the thermodynamics of hydrate accumulation are primarily one-dimensional. However, changes in free methane compressibility (density) and methane solubility (the intrinsic dissolved methane flux) subtlety impact on the formation of a free gas zone and the distribution of the hydrate emplacements in our 2-dimensional simulations.  相似文献   

17.
Raman spectroscopic measurements of synthetic gas hydrates in the ocean   总被引:1,自引:0,他引:1  
A Raman spectrometer extensively modified for deep ocean use was used to measure synthetic hydrates formed in an ocean environment. This was the first time hydrates formed in the ocean have been measured in situ using Raman spectroscopy. Gas hydrates were formed in situ in the Monterey Bay by pressurizing a Pyrex cell with various gas mixtures. Raman spectra were obtained for sI methane hydrate and sII methane + ethane hydrate. Gas occlusion resulting from rapid gas growth of methane hydrate was measured immediately after formation. The Raman shift for methane free gas was coincident with that of methane in the small 512 hydrate cage. The methane Raman peak widths were used to discriminate between methane in the free gas and hydrate phase. Methane + ethane sII hydrate was formed for 43 days on the seafloor. In this case, gas occlusion was not measured when the gas hydrates were allowed to form over an extended time period. Equivalent Raman spectra were obtained for the in situ and laboratory-formed sII methane + ethane hydrates, under similar p, T, and x conditions. With the Raman spectrometer operating in the ocean, seawater contributes to the Raman spectra obtained. Both the Raman bands for the sulfate ion and water were used to qualitatively determine the distribution of water phases measured (hydrate, seawater) in the Raman spectra.  相似文献   

18.
使用重力取样器、渔网、深潜器等手段,已经在海底及以下浅表层的区域采获天然气水合物样品,但关于浅表层水合物的发育机制、分布规律、与海底地形的关系等问题还缺乏基本认识。根据2006年鄂霍次克海天然气水合物调查航次的调查数据,发现萨哈林东北陆坡区,特别是中、下陆坡区发育大量海底凸起。这些凸起一般呈不对称的丘形,宽几百米,高几十米。与海底沙波、沙脊不同,海底凸起为孤立海底地形,在南北方向上并不连续。海底剖面仪结果清楚地显示古陆坡凸起的发育。现今海底陆坡凸起的幅度普遍地要小于古陆坡凸起的幅度,个别地方古今陆坡凸起的形态有所变化,但大部分古、今陆坡凸起是一一对应的,基本形态没有根本变化。在萨哈林陆坡地区存在两个方向的挤压应力场,分别是由德鲁根盆地向萨哈林陆坡方向的挤压应力场和萨哈林陆坡沿萨哈林走滑断裂向南的挤压应力场,海底陆坡凸起是这两大应力场复合作用的结果。浊反射区中的游离气是底辟构造中的超高压多相物质向上迁移形成的,浊反射区上方对应的海底凸起应该是宏观构造挤压和局部底辟发育叠合的结果,浊反射区上方的海底凸起,在形态等方面应该和其他仅由挤压构造原因形成的凸起有所区别,比如顶部发育裂口等。在底辟构造中,由于游离气体的向上迁移,在整个水合物稳定域中从下到上,直至海底都可能形成水合物。  相似文献   

19.
建立了沉积物中水合物含气量的测定方法;测定了人工松散沉积物中甲烷水合物、南海神狐海域及祁连山冻土区天然气水合物样品的含气量;计算了样品的表观水合指数(水与气体的摩尔比);探讨了水合物含气量的影响因素.测试结果表明,人工甲烷水合物样品表观水合指数与晶体水合指数相近,样品中水合物的浓度大,含气量较高;南海神狐海域及祁连山冻...  相似文献   

20.
天然气水合物目前已经成为世界范围的一个研究热点,而我国的天然气水合物研究起步则相对较晚,通过阅读国内外有关文献,总结了天然气水合物在海底的分布特征,聚集和形成机制,产状及其形成机理,甲烷羽的形成过程,天然气水合物在沉积物中的聚集位置通常有两种情况:一是较浅的沉积物(海底以下几米)中,受控于泥底辟,泥火山,断层等;二是较深的沉积物(海底以下几十米,甚至更深)中,受控于流体,当断层延伸至海底时,通常在水合物聚集处的上部发现甲烷羽,天然气以溶解气,游离气或分子扩散的形式运移,在温,压适宜的沉积物中,即水合物稳定带内聚集并形成水合物,水合物的形成过程是:最初形成晶体,呈分散状分布于沉积物中,之后逐渐聚集,生长成结核状,层状,最后形成块状,在细粒的浅层沉积物中,通常以较慢的速度生长,形成分散状的水合物;而在粗粒沉积物中,水合物通常呈填隙状,并且这种产状可能位于较深层位中,我国南海在温度,压力,构造条件,天然气来源等方面都能满足天然气水合物的形成条件,并且在南海也发现了一些水合物存在的标志,如似海底反射层(BSR)以及孔隙水中氯离子浓度的降低。因此,天然气水合物在我国南海海域可能有很好的前景。  相似文献   

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