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1.
Maps of the distributions of the four major clay minerals (smectite, illite, kaolinite and chlorite) in and around the Mississippi River drainage basin and in the Northern Gulf of Mexico have been produced using newly acquired data from erodible/alluvial terrestrial sediments and marine surface sediments, as well as from previously published data. East of the Rockies, North America can be divided into four, large, clay-mineral provinces: (1) the north-western Mississippi River watershed (smectite rich), (2) the Great Lakes area and eastern Mississippi River watershed (illite and chlorite rich), (3) the south-eastern United States (kaolinite rich) and (4) the Brazos River and south-western Mississippi River watersheds (illite and kaolinite rich). The clay mineral distributions in surface sediments of the present-day Gulf of Mexico are strongly influenced by three main factors: (1) by relative fluvial contributions: the Mississippi River delivers the bulk of the clay input to the Northern Gulf of Mexico whereas the Apalachicola, Mobile, Brazos and Rio Grande rivers inputs have more local influences; (2) by differential settling of various clay mineral species, which is identified for the first time in Northern Gulf of Mexico sediments; and (3) by oceanic current transport: the Gulf of Mexico surface and subsurface circulation distributes the clay-rich sediments from river mouth sources throughout the Northern Gulf of Mexico.  相似文献   

2.
In this study, the distribution of channel‐bed sediment facies in the lowermost Mississippi River is analysed using multibeam data, complemented by sidescan sonar and compressed high‐intensity radar pulse seismic data, as well as grab and core samples of bed material. The channel bed is composed of a discontinuous layer of alluvial sediment and a relict substratum that is exposed on the channel bed and sidewalls. The consolidated substratum is made up of latest Pleistocene and Early Holocene fluvio‐deltaic deposits and is preferentially exposed in the deepest thalweg segments and on channel sidewalls in river bends. The exposed substratum commonly displays a suite of erosional features, including flutes that are quantitatively similar in form to those produced under known laboratory conditions. A total of five bed facies are mapped, three of which include modern alluvial deposits and two facies that are associated with the relict substratum. A radius of curvature analysis applied to the Mississippi River centreline demonstrates that the reach‐scale distribution of channel‐bed facies is related to river planform. From a broader perspective, the distribution of channel‐bed facies is related to channel sinuosity — higher sinuosity promotes greater substratum exposure at the expense of alluvial sediment. For example, the ratio of alluvial cover to substratum is ca 1·5:1 for a 45 km segment of the river that has a sinuosity of 1·76 and this ratio increases to ca 3:1 for a 120 km segment of the river that has a sinuosity of 1·21. The exposed substratum is interpreted as bedrock and, given the relative coverage of alluvial sediment in the channel, the lowermost Mississippi River can be classified as a mixed bedrock‐alluvial channel. The analyses demonstrate that a mixed bedrock‐alluvial channel boundary can be associated with low‐gradient and sand‐bed rivers near their marine outlet.  相似文献   

3.
Soluble reactive phosphorus (SRP) has recently been shown to be one of the limiting nutrients for the growth of phytoplankton in the northern Gulf of Mexico. We show here that during the past decade, SRP concentrations in the lower reaches of North America's largest river, the Mississippi River, were highest in summer and lowest in winter and positively correlated with water temperature. Upstream data showed this coupling to increase in a downstream trend in the Mississippi main stem. Water quality data analysis and phosphorus mass balances were conducted to examine the controls of this relationship. The results showed that the positive SRP–temperature correlation in the Mississippi River system was largely a result of gradual dilution of SRP-enriched upper Mississippi River waters, which contributed most to the Mississippi River during summer, by SRP-depleted waters from the Ohio and other tributaries. Particle buffering and organic matter mineralization might play a role in the observed SRP–temperature relationship, but their importance relative to tributary effects is not quantified. Future work on the seasonal dynamics of SRP in large river systems needs to consider the effects of both tributary dilution and in situ processes.  相似文献   

4.
A geomorphic study of the Mississippi River and its alluvial valley between Osceola, Arkansas and Friars Point, Mississippi has identified anomalous surface features that can be linked to known geological structures. For example, relatively recent deformation along Big Creek fault zone, White River fault zone, Bolivar-Mansfield tectonic zone, Blytheville Arch, Crittenden County fault zone, and Reelfoot Rift margins is suggested by river and topographic anomalies. Faults and plutons appear to affect drainage networks, and the morphology of Crowleys Ridge suggests significant fault control. The many anomalies probably reflect a fractured suballuvial surface. Although movement along these fractures will most likely occur in seismically active areas, the probability of movement elsewhere  相似文献   

5.
Perspectives on the geoarchaeology of the Lower Mississippi Valley   总被引:1,自引:0,他引:1  
The impact of Harold N. Fisk's work on the archaeology and geoarchaeology of the Lower Mississippi Valley (LMV) has been monumental. As a result of his landmark publications on the geology of the alluvial valley of the Mississippi River our comprehension of the interplay between geological, geomorphic, and human actions is relatively well developed. However, geologists and archaeologists still need to work together more closely to appreciate and understand the contributions each field has to offer. Examination of the interplay between geologists and archaeologists in the realm of dating and landscape evolution provides the basis for an investigation of the state of geoarchaeology in the LMV today. Integration of research demands an appreciation of scale which must be approached from an historical perspective. Humans have, both in the past and the present, impacted the natural environment of the Mississippi River and its floodplain. Only when this fact is fully appreciated by archaeologists and geologists alike will it be possible to forge a new synthesis of the relationship between the dynamic alluvial valley and its human occupants.  相似文献   

6.
The response of the Lower Mississippi River to river engineering   总被引:2,自引:0,他引:2  
An examination of the response of the Lower Mississippi River (LMR) to a variety of engineering activities is presented through the discussion of: (a) a brief history of engineering investigations and activities on the LMR; (b) the impact of artificial cutoffs on the channel geometry and water surface profiles of adjacent reaches; (c) the impact of channel alignment activities on channel morphology; and (d) the apparent impact of all of the LMR engineering activities on sediment dynamics in the channel.

Investigations by many agencies reflect over 150 years of study of the hydraulics and hydrology of the LMR, which have contributed significantly to our understanding of large alluvial rivers. In an effort to provide for flood control and navigation on the largest river in North America, private landowners and the US Army Corps of Engineers have performed a wide range of river engineering activities, including construction of levees, floodways, artificial cutoffs, bank revetment, training dikes, dredging, channel alignment, and reservoirs on the major tributaries. This unprecedented program of river engineering activities on the river during the last 100 years has resulted in the evolution of a freely meandering alluvial river to a highly trained and confined meandering channel. The LMR has increased its overall gradient and average top-bank width and generally increased its channel depth. The immediate response of the river to increased gradient as a result of the construction of artificial cutoffs was dampened in some locations by local geological controls.

Examination of the trends in sediment dynamics of the LMR reveals that the suspended load of the river has decreased during the 20th century. Conversely, a trend in the bed load transport in the channel for the years 1930 and 1989 cannot be determined with confidence because of the difficulty in acquiring representative samples. The highly trained river now responds to channel forming flows by attempting to build mid-channel bars rather than natural cutoffs of meanders.

The LMR should maintain a relatively stable plan form in the intermediate future, barring a very large and unprecedented flood. The river will continue to adjust its channel geometry and its local gradients as a response to variations in significant discharges. Continued channel maintenance and occasional dredging will insure the present state of sediment and water transport efficiency.  相似文献   


7.
The potential health impact of As in drinking water supply systems in the Mississippi River Valley alluvial aquifer in the state of Arkansas, USA is significant. In this context it is important to understand the occurrence, distribution and mobilization of As in the Mississippi River Valley alluvial aquifer. Application of surface complexation models (SCMs) to predict the sorption behavior of As and hydrous Fe oxides (HFO) in the laboratory has increased in the last decade. However, the application of SCMs to predict the sorption of As in natural sediments has not often been reported, and such applications are greatly constrained by the lack of site-specific model parameters. Attempts have been made to use SCMs considering a component additivity (CA) approach which accounts for relative abundances of pure phases in natural sediments, followed by the addition of SCM parameters individually for each phase. Although few reliable and internally consistent sorption databases related to HFO exist, the use of SCMs using laboratory-derived sorption databases to predict the mobility of As in natural sediments has increased. This study is an attempt to evaluate the ability of the SCMs using the geochemical code PHREEQC to predict solid phase As in the sediments of the Mississippi River Valley alluvial aquifer in Arkansas. The SCM option of the double-layer model (DLM) was simulated using ferrihydrite and goethite as sorbents quantified from chemical extractions, calculated surface-site densities, published surface properties, and published laboratory-derived sorption constants for the sorbents. The model results are satisfactory for shallow wells (10.6 m below ground surface), where the redox condition is relatively oxic or mildly suboxic. However, for the deep alluvial aquifer (21-36.6 m below ground surface) where the redox condition is suboxic to anoxic, the model results are unsatisfactory.  相似文献   

8.
Fisk's work provided a three-dimensional pattern of occurrence and composition of sediments in the alluvial valley and deltaic plain of the lower Mississippi River. He also interpreted the processes by which the sediments were deposited and the relevance of tectonism in their history. These data provide site characterizations that are basic for all major categories of engineering. His work has found applications in better methods for control of the river, stabilizing its banks, locating sources of aggregate for concrete, management of groundwater, maintenance of wetlands, and generally for more reliable, timely and economical evaluations in selecting optimum site locations and determining foundation conditions. Since then, work in the Lower Mississippi Valley (LMV) has expanded enormously and continues to be greatly indebted to formative interpretations by Fisk.  相似文献   

9.
The period in the Upper Mississippi Valley (UMV) from about 25 000 years B.P. until the time of strong human influence on the landscape beginning about 150–200 years ago can be characterized by three distinctly different alluvial episodes. The first episode is dominated by the direct and indirect effects of Late Wisconsin glacial ice in the basin headwaters. This period, which lasted until about 14 000 years B.P., was generally a time of progressive valley aggradation by a braided river system transporting large quantities of bedload sediment. An island braided system evolved during the second episode, which extended from about 14 000 to 9000 years B.P. The second episode is associated with major environmental changes of deglaciation when occurrences of major floods and sustained flows of low sediment concentration from drainage of proglacial lakes produced major downcutting. By the time of the beginning of the third episode about 9000 years B.P., most vegetation communities had established their approximate average Holocene locations. The change of climate and establishment of good vegetation cover caused upland landscapes of the UMV to become relatively stable during the Holocene in comparison to their relative instability during the Late Wisconsin. However, Holocene remobilization of Late Wisconsin age sediment stored in tributary valleys resulted in a return to long-term upper Mississippi River aggradation. The dominance of Holocene deposition over transportation reflects the abundance of sandy bedload sediment introduced from tributaries and the situation that energy conditions for floods and the hydraulic gradient of the upper Mississippi River are much less for the Holocene than they were for the Late Wisconsin and deglaciation periods.Outburst floods from glacial lakes appear to have been common in the UMV during the Late Wisconsin and especially during deglaciation. Magnitudes for the Late Wisconsin floods are generally poorly understood, but an estimate of 10 000–15 000 m3 s−1 was determined for one of the largest events in the northern UMV based on heights of paleo-foreset beds in a flood unit deposited in the Savanna Terrace. For comparison, the great flood of 1993 on the upper Mississippi River was about 12 000 m3 s−1 at Keokuk, Iowa, near the Des Moines River confluence where it represented the 500-year event in relation to modem flood series. Exceptionally large outburst floods derived from the rapid drainage of pro-glacial Lake Michigan and adjacent smaller proglacial lakes between about 16 000 and 15 500 years B.P. are a likely cause of the final diversion of the Mississippi River through the Bell City-Oran Gap at the upstream end of the Lower Mississippi Valley (LMV). The largest outburst flood from northern extremities of the UMV appears to have occurred between about 11700 and 10 800 years B.P. when the southern outlet of Lake Agassiz was incised. Based on the probable maximum capacity of the Agassiz flood channel 600 km downstream near the junction of the Wisconsin and Mississippi Rivers, the Agassiz flood discharge apparently did not exceed 30 000 m3 s−1. However, if the Agassiz flood channel here is expanded to include an incised component, then the flood discharge maximum could have been as large as 100,000 to 125 000 m3 s−1. The larger flood is presently viewed as unlikely, however, because field evidence suggests that the incised component of the cross-section probably developed after the main Agassiz flood event. Nevertheless, the large Agassiz flood between about 11 700 and 10 800 years B.P. produced major erosional downcutting and removal of Late Wisconsin sediment in the UMV. This flood also appears to be mainly responsible for the final diversion of the Mississippi River through Thebes Gap in extreme southwestern Illinois and the formation of the Charleston alluvial fan at the head of the LMV.After about 9000 years B.P. prairie-forest ecotones with associated steep seasonal climatic boundaries were established across the northern and southern regions of the UMV. The general presence of these steep climatically sensitive boundaries throughout the Holocene, in concert with the natural tendency for grasslands to be especially sensitive to climatic change, may partially explain why widespread synchroneity of Holocene alluvial episodes is recognized across the upper Mississippi River and Missouri River drainage systems. Comparison of estimated beginning ages of Holocene flood episodes and alluvial chronologies for upper Mississippi River and Missouri River systems with beginning ages for LMV meander belts and delta lobes shows a relatively strong correlation. At present, dating controls are not sufficiently adequate and confidence intervals associated with the identified ages representing system changes are too large to establish firm causal connections. Although the limitations of the existing data are numerous, the implicit causal connections suggested from existing information suggest that further exploration would be beneficial to improving the understanding of how upper valley hydrological and geomorphic events are influencing hydrological and geomorphic activity in the LMV. Since nearly 80% of the Mississippi River drainage system lies upstream of the confluence of the Mississippi and Ohio Rivers, there is a strong basis for supporting the idea that UMV fluvial activity should be having a strong influence on LMV fluvial activity. If this assertion is correct, then the traditional assignment of strong to dominant control by eustatic sea level variations for explaining channel avulsions, delta lobes, and meander belts in the LMV needs re-examination. A stronger role for upper valley fluvial activity as a factor influencing lower valley fluvial activity does not disregard the role of eustatic sea level, tectonic processes or other factors. Rather, upper valley fluvial episodes or specific events such as extreme floods may commonly serve as a “triggering mechanism” that causes a threshold of instability to be exceeded in a system that was poised for change due to sea level rise, tectonic uplift, or other environmental factors. In other situations, the upper valley fluvial activity may exert a more dominant control over many LMV fluvial processes and landforms as frequently was the case during times of glacial climatic conditions.  相似文献   

10.
大型水利水电工程对下游冲积性河道的影响分析   总被引:2,自引:0,他引:2       下载免费PDF全文
依据冲积河流的自动调整原理,研究了大型水利水电工程的运用对黄河内蒙河段的影响,分析了近期河性改变的原因以及河床调整的自由度与河流体系能量分配、耗散间的制约关系,并从协调河流与人类活动关系的角度,对冲积河流上游大型水库的运用提出了建议.  相似文献   

11.
The River Mati in Albania has formed a coastal plain with Holocene and Pleistocene sediments. The outer portion of the plain is clay, with three underlying aquifers that are connected to an alluvial fan at the entry of the river into the plain. The aquifers supply water for 240,000 people. Close to the sea the aquifers are brackish. The brackish water is often artesian and found to be thousands of years old. Furthermore, the salinity, supported by δ18O results, does not seem to be due to mixing with old seawater but due to diffusion from intercalated clay layers. Heavy metals from mines in the upstream section of River Mati are not an immediate threat, as the pH buffering of the river water is good. Moreover, the heavy metals are predominantly found in suspended and colloidal phases. Two sulphur isotope signatures, one mirroring seawater sulphate in the brackish groundwater (δ34S >21 ‰) and one showing the influence of sulphide in the river and the fresh groundwater (δ34S <10 ‰), indicate that the groundwater in the largest well field is recharged from the river. The most serious threat is gravel extraction in the alluvial fan, decreasing the hydraulic head necessary for recharge and causing clogging of sediments.  相似文献   

12.
黄河三角洲地区地下淡水(微咸水)的形成与演化   总被引:10,自引:0,他引:10  
黄河三角洲地区地下淡水(微咸水)资源贫乏,咸水广布。南部冲洪积平原受第二次海侵层位的影响形成大面积咸水,后被逐渐淡化。近年来由于开采量加大,又使北部咸水南侵。海积冲积平原随着黄河河道的变迁,仅在黄河现行河道两侧和充水的黄河故道带分布有淡水(微咸水)。近代,现代黄河三角洲古河道带和决口扇淡水体已被咸化。  相似文献   

13.
Mei-e Ren 《GeoJournal》1995,37(4):473-478
The Yellow River, China is noted for its extremely heavy sediment load, about 5 times that of the Mississippi and very small flow, only 8% that of the Mississippi. Owing to the construction of reservoirs and increasing withdrawal of the river water for agriculture, industry and urban water supply, the flow of the Lower Yellow River is greatly reduced causing more serious siltation in the river channel and river mouth, threaterning the stabilization of the present outlet to the sea and economic growth of the delta. It is suggested that a more rational use of the river water resources should be formulated to mitigate this situation.  相似文献   

14.
The San Juan River, located in San Juan Province (Argentina), crosses the Precordillera and other geologic units including the Ullum tectonic valley and the La Laja Zone between latitudes 31°S and 32°S. The San Juan River is antecedent as is suggested by its two perpendicular segments linked by an almost parallel segment to the main structural trend. Along the Precordillera, the San Juan River valley has many different alluvial fans at the river junctions with its tributaries. The Quaternary alluvial fans display surfaces cut in a series of steps which we consider to be alluvial terraces generated by aggradation and repeated incision episodes. The studied sector includes one area with recent major seismic activity (La Laja Zone), another without major seismic activity (Precordillera area), and a subsident area (Ullum area) where a large lake was formed 6500 yr BP. The old San Juan River was captured by the Quebrada de Ullum valley by means of a 25-m incision, which resulted in river-gradient headward erosion. The San Juan River gradient shows some irregularities that, although unrelated to the main structures, are associated with river dynamics, which emphasizes lithologic differences. The main river valley width, the geometry and gradient of each tributary, together with the basement rock lithologies and the size of each local source area are the major factors which control the alluvial terrace generation processes. In the La Laja Zone, where the uppermost terrace is capped by travertine, dating of travertine deposits suggests that the maximum incision rate is 0.9–1 mm/yr related to episodic activity on the La Laja Fault.  相似文献   

15.
古滦河冲积扇研究的关注点更多在全新世,对其更新世的演化与变迁一直没有进行过系统研究。根据古滦河冲积扇上PZK10、PZK20钻孔的磁性地层学、年代地层学、沉积学、测井沉积学、岩芯色度分析等,对古滦河冲积平原的第四纪三维地质结构、冲积扇体的规模以及迁移规律进行综合研究,结果表明:PZK10孔揭露了上新世时沉积的巨厚洪积成因“泥包砾”地层,早更新世时发育两个冲积扇-湖相旋回,中更新世时发育辫状河沉积,晚更新世发育湖相、冲积扇相、辫状河相沉积。PZK20孔上新世沉积了一套巨厚“泥包砾”层,早更新世为扇前平原-辫状河相沉积,中更新世为辫状河-冲积扇相沉积,晚更新世为辫状河沉积。古滦河发育两期冲积扇,第一期为早更新世早期,在沙流河镇一带出山口形成的规模较大的冲积扇;第二期为早更新世中期,古滦河在现今丘庄水库一带发生分流,在丰润区一带出山口形成的冲积扇。中更新世,第一期冲积扇开始萎缩,第二期冲积扇继续发育,形成巨厚砾石层;晚更新世,古滦河在迁西县城以北发生袭夺,东流迁移出研究区,在西峡口进入迁安盆地,形成以西峡口为顶点的冲积扇。  相似文献   

16.
Previous work has demonstrated that suspended clay accumulating on filter paper can act as a membrane and affect chemical concentrations in the filtered water. For this reason, we looked at the possibility of membrane effects altering water chemistry during filtering for Missouri Rivers. Membrane effects during filtering could cause an initial decrease in sample concentrations as the filter cake began acting as a membrane, with a corresponding increase of concentration as the concentration polarization layer was formed behind the filter cake. Samples from five Missouri rivers were tested: the Mississippi River at St. Louis, the Missouri River at Kansas City, the Gasconade River at Jerome, the Osage River at the junction of Highway 63 and 50, and the Meramec River one mile downstream from springs. Three 1-l samples were filtered from each river using a 0.45 m filter. An unfiltered sample from each river underwent dialysis to determine the actual ion concentrations of the overall sample. None of the filtered samples demonstrated a statistically significant alteration of water chemistry using current filtering techniques in this preliminary study, suggesting that membrane effects due to accumulation of clay particles on filter paper may not be a common problem in Missouri and similar regions.  相似文献   

17.
The geological and geomorphic information preserved in the tributary valleys of the lower Mississippi River (LMR) contributes to our understanding of the lower valley's Quaternary geological history. Prominent Pleistocene terraces are preserved in the tributary valleys. Fisk first formulated his four terraces framework on the Red River. Caution needs to be followed in projecting the Red River terraces across the entire Lower Mississippi Valley (LMV). The tributary system cannot be assumed to operate in a synchronized fashion in response to changes in climate and base level. To compare the collective contribution of the tributaries of the LMR, the streams are described in terms of. (1) their characteristics, (2) geomorphic development, (3) process and response of the tributaries to and from the LMR, and (4) engineering investigations and implications. The characteristics of the tributaries are a direct function of their drainage basin size and geology. The tributary system drains portions of six physiographic provinces. Synoptically, the tributaries can be viewed as two groups: the eastern and western tributaries. All of the eastern tributaries are intra-regional, i.e., they drain only one physiographic province, the Coastal Plain, and therefore, have a restricted sediment source. Generally, the eastern tributaries are more numerous and shorter than the western tributaries. The longer western tributaries drain outside the Coastal Plain. The extra-regional nature of the western tributaries adds to the variability of discharge and sediment types. The sediment record of the tributaries reflects response to the trunk Mississippi. During glacial outwash flushes, many of the tributaries were alluvially drowned, producing alluvial cones expressed as flattened longitudinal profiles. More recently, a number of tributaries in the state of Mississippi have experienced episodes of accelerated channel erosion. The effects of navigation and flood control modification of the Mississippi River on the tributaries have not been fully studied. Therefore, fluvial geomorphic research in the tributaries is essential to understanding ways to mitigate the adverse effects of river engineering, thereby designing engineering works in balance with the alluvial architecture and processes of the stream system.  相似文献   

18.
The Lower Mississippi River, a several thousand years old graded meandering river system, became strongly affected in its equilibrium by a river regulation program. This included cutoffs (1929–1942), crossectional changes by dike systems, and revetments. The cutoff program changed the river in such a way that sinuosity and slope shifted into the reach where the river starts to develop a braided channel. This is indicated by the increasing number of sandbars with time. Dike constructions decreased the river width in the pool areas causing incision there but consequently also widening and shallowing of the river crossings. Here the river is shallower and wider than ever before. The increase of the width/depth ratio of the river crossings is correlated to decreasing sinuosity. The alteration of the river's regime is probably best documented by the changes of the rating curves with time. The cutoff program initially lowered the stages for given discharges, but since 1950 a reverse trend, particularly for flood flows, can be observed. This indicates a decrease of the mean crossectional area and/or a raising of the mean stream bed elevation. The 1973 flood and a particular reach of the river are regarded as examples in this context. From the engineering point of view the present Lower Mississippi River is less efficient than it was before the river regulations. From the sedimentological and geomorphological point of view the recent processes can be regarded as the result of a large scale experiment, modelling a river's adjustment to changed conditions.  相似文献   

19.
永定河形成时代研究   总被引:6,自引:0,他引:6       下载免费PDF全文

通过对永定河冲洪积物的研究发现,永定河形成前后的沉积环境明显不同。钻探资料表明永定河形成前本地区沉积环境主要为湖泊相,当时湖水宁静,沉积物主要为泥岩和粉砂。永定河形成时洪水裹携大量碎屑形成巨厚的泥石流堆积,沉积环境为冲洪积相,主要为砂砾石、砂、粉砂和粘土互层,形成巨大的冲洪积扇。通过新5孔钻孔岩芯273块古地磁样品的系统剩磁测试,获得了该钻孔岩芯的古地磁极性序列,对比国际地磁极性年表,认为该钻孔岩芯剖面 0~96.59m以正极性带为主,对应布容正极性时,其地质时代为0~0.78Ma;  96.59~246.79m则以反极性带为主,对应松山反极性时,其地质时代为0.78~2.58Ma;  246.79~413.64m以正极性带为主,则对应高斯正极性时,其地质时代为2.58~3.58Ma,属于新近纪上新世。研究推测永定河最早的沉积物为上新世形成,距今3.33~3.58Ma。
  相似文献   

20.
The effects of discharge of municipal wastes on water quality within the lower Mississippi River below Old River have been reevaluated using published water quality data in the Louisiana reach of the river for the water years 1974–1984. A novel graphical technique has facilitated the evaluation of upriver controls on water quality and the identification of sources and sinks along the lower Mississippi. Comparison of calculated annual fluxes at different downstream monitoring stations has simplified some of the problems inherent in evaluating analyses of samples collected from different water masses during a typical sampling run. The absolute concentrations of chloride, nitrite plus nitrate, total phosphorous, dissolved oxygen, BOD, and COD are all strongly dependent on processes occurring upriver. Nonpoint influx of materials from agricultural wastes and natural plant debris may be the dominant upstream sources of N, P, BOD, and COD. Increases in chloride and phosphorous downstream within the Lower Mississippi appear to be caused by discharge of industrial wastes. Nitrogen fluxes decrease downriver, except where there is local discharge of high-N, high-P industrial waste water, possibly from fertilizer plants. Removal of N and increases in BOD may be due in part to biological uptake. High river discharge rates and efficient, natural processes of reaeration maintain high oxygen saturation levels. With the exception of an increase in bacterial count, the discharge of municipal waste into the Mississippi River in Louisiana appears to have had no significant effect on water quality, a finding consistent with the earlier U.S. Geological Survey study of Wells (1980). It would be highly desirable for future mass balance studies if existing water quality programs on the Mississippi River were to adopt a Lagrangian sampling approach.  相似文献   

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