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1.
Partition coefficients (DBemineral/melt) for beryllium between hydrous granitic melt and alkali feldspars, plagioclase feldspars, quartz, dark mica, and white mica were determined by experiment at 200 MPa H2O as a function of temperature (650-900°C), activity of Be in melt (trace levels to beryl saturation), bulk composition, and thermal run direction. At trace levels, Be is compatible in plagioclase of An31 (1.84 at 700°C) and muscovite (1.35 at 700°C) but incompatible in biotite (0.39-0.54 from 650-800°C), alkali feldspar (0.38-0.19 from 680-850°C), quartz (0.24 at 800°C), and albite (0.10 at 750°C). The partition coefficients are different at saturation of the melt in beryl: lower in the case of plagioclase of An31 (0.89 at 700°C), muscovite (0.87 at 700°C), biotite (0.18-0.08 from 675-800°C), alkali feldspar (0.18-0.14 from 680-700°C), and quartz (0.17-0.08 from 750-800°C), but higher in the case of albite (0.37 at 750°C).With other data sources, these new partition coefficients were utilized to track, first, the distribution of Be between aluminous quartzofeldspathic source rocks and their anatectic melts, and second, the dispersion or concentration of Be in melt through igneous crystal fractionation of different magma types (e.g., S-type, I-type) up to beryl-saturated granitic pegmatites and, finally, into their hydrothermal aureoles. Among the rock-forming minerals, cordierite, calcic oligoclase, and muscovite (in this order) control the fate of Be because of the compatibility of Be in these phases. In general, beryl-bearing pegmatites can arise only after extended crystal fractionation of large magma batches (to F, fraction of melt remaining, ≤0.05); granitic magmas that originate from cordierite-bearing protoliths or that contain large modal quantities of calcic oligoclase will not achieve beryl saturation at any point in their evolution.  相似文献   

2.
Making a distinction between partial melting and subsolidus segregation in amphibolite facies migmatites is difficult. The only significant melting reactions at lowpressures, either vapour saturated or muscovite dehydration melting, do not produce melanocratic peritectic phases. If protoliths are Si-rich and K-poor, then peritectic sillimanite and K-feldspar will form in scarce amounts, and may be lost by retrograde rehydration. The Roded migmatites of southern Israel (northernmost Arabian Nubian Shield) formed at P = 4.5 ± 1 kbar and T ≤ 700 °C and include Si-rich, K-poor paragneissic paleosome and trondhjemitic leucosomes. The lack of K-feldspar in leucosomes was taken as evidence for the non-anatectic origin of the Roded migmatites (Gutkin and Eyal, Isr J Earth Sci 47:117, 1998). It is shown here that although the Roded migmatites experienced significant post-peak deformation and recrystallization, microstructural evidence for partial melting is retained. Based on these microstructures, coupled with pseudosection modelling, indicators of anatexis in retrograded migmatites are established. Phase diagram modelling of neosomes shows the onset of muscovite dehydration melting at 4.5 kbar and 660 °C, forming peritectic sillimanite and K-feldspar. Adjacent non-melted paleosomes lack muscovite and would thus not melt by this reaction. Vapour saturation was not attained, as it would have formed cordierite that does not exist. Furthermore, vapour saturation would not allow peritectic K-feldspar to form, however K-feldspar is ubiquitous in melanosomes. Direct petrographic evidence for anatexis is rare and includes euhedral plagioclase phenocrysts in leucosomes and quartz-filled embayments in corroded plagioclase at leucosome-melanosome interfaces. In deformed and recrystallized rocks muscovite dehydration melting is inferred by: (1) lenticular K-feldspar enclosed by biotite in melanosomes, (2) abundant myrmekite in leucosomes, (3) muscovite–quartz symplectites after sillimanite in melanosomes and associated with myrmekite in leucosomes. While peritectic K-feldspar formed in melanosomes by muscovite dehydration melting reaction, K-feldspar crystallizing from granitic melt in adjacent leucosome was myrmekitized. Excess potassium was used in rehydration of sillimanite to muscovite.  相似文献   

3.
Garnet-sillimanite gneisses, locally known as khondalites, occur abundantly in the Chilka Lake granulite terrane belonging to the Eastern Ghats Proterozoic belt of India. Though their chemistry has been modified by partial melting, it is evident that the majority of these rocks are metapelitic, with some tending to be metapsammitic. Five petrographically distinct groups are present within the khondalites of which the most abundant group is characteristically low in Mg:Fe ratios — the main chemical discriminant separating the five groups. The variations in Mg:Fe ratios of the garnets, biotites, cordierites, orthopyroxenes and spinels from the metapelites are compatible with those in the bulk rocks. A suite of granitoids containing garnet, K-feldspar, plagioclase and quartz, commonly referred to as leptynites in Indian granulite terranes, are interlayered with khondalites on the scale of exposures; in a few spots, the intercalated layers are thin. The peraluminous character of the leptynites and presence of sillimanite trails within garnets in some of them suggest derivation of leptynites by partial melting of khondalites. Here we examine this connection in the light of results derived from dehydration melting experiments of micas in pelitic and psammitic rocks. The plots of leptynites of different chemical compositions in a (MgO + FeO)-Na2O-K2O projection match the composition of liquids derived by biotite and muscovite dehydration melting, when corrected for co-products of melting reactions constrained by mass balance and modal considerations. The melt components of the leptynites describe four clusters in the M-N-K diagram. One of them matches melts produced dominantly by muscovite dehydration melting, while three clusters correspond to melting of biotite. The relative disposition of the clusters suggests two trends, which can be correlated with different paths that pelitic and psammitic protoliths are expected to generate during dehydration melting. Thus the leptynites evidently represent granitoids which were produced by dehydration melting in metapelites of different compositions. The contents of Ti, Y, Nb, Zr and Th in several leptynites indicate departures from equilibrium melt compositions, and entrainment of restites is considered to be the main causative factor. Disequilibrium in terms of major elements is illustrated by leucosomes within migmatites developed in a group of metapelites. But the discrete leptynites that have been compared with experimental melts approach equilibrium melt compositions closely.  相似文献   

4.
The Winding Stair Gap in the Central Blue Ridge province exposes granulite facies schists, gneisses, granofelses and migmatites characterized by the mineral assemblages: garnet–biotite–sillimanite–plagioclase–quartz, garnet–hornblende–biotite–plagioclase–quartz ± orthopyroxene ± clinopyroxene and orthopyroxene–biotite–quartz. Multiple textural populations of biotite, kyanite and sillimanite in pelitic schists support a polymetamorphic history characterized by an early clockwise P–T path in which dehydration melting of muscovite took place in the stability field of kyanite. Continued heating led to dehydration melting of biotite until peak conditions of 850 ± 30 °C, 9 ± 1 kbar were reached. After equilibrating at peak temperatures, the rocks underwent a stage of near isobaric cooling during which hydrous melt ± K‐feldspar were replaced by muscovite, and garnet by sillimanite + biotite + plagioclase. Most monazite crystals from a pelitic schist display patchy zoning for Th, Y and U, with some matrix crystals having as many as five compositional zones. A few monazite inclusions in garnet, as well as Y‐rich cores of some monazite matrix crystals, yield the oldest dates of c. 500 Ma, whereas a few homogeneous matrix monazites that grew in the main foliation plane yield dates of 370–330 Ma. Culling and analysis of individual spot dates for eight monazite grains yields three age populations of 509 ± 14 Ma, 438 ± 5 Ma and 360 ± 5 Ma. These data suggest that peak‐temperature metamorphism and partial melting in the central Blue Ridge occurred during the Salinic or Taconic orogeny. Following near isobaric cooling, a second weaker thermal pulse possibly related to intrusion of nearby igneous bodies resulted in growth of monazite c. 360 Ma, coinciding with the Neoacadian orogeny.  相似文献   

5.
This study uses field, microstructural and geochemical data to investigate the processes contributing to the petrological diversity that arises when granitic continental crust is reworked. The Kinawa migmatite formed when Archean TTG crust in the São Francisco Craton, Brazil was reworked by partial melting at ~730 °C and 5–6 kbar in a regional‐scale shear zone. As a result, a relatively uniform leucogranodiorite protolith produced compositionally and microstructurally diverse diatexites and leucosomes. All outcrops of migmatite display either a magmatic foliation, flow banding or transposed leucosomes and indicate strong, melt‐present shearing. There are three types of diatexite. Grey diatexites are interpreted to be residuum, although melt segregation was incomplete in some samples. Biotite stable, H2O‐fluxed melting is inferred via the reaction Pl + Kfs + Qz + H2O = melt and geochemical modelling indicates 0.35–0.40 partial melting. Schlieren diatexites are extremely heterogeneous; residuum‐rich domains alternate with leucocratic quartzofeldspathic domains. Homogeneous diatexites have the highest SiO2 and K2O contents and are coarse‐grained, leucocratic rocks. Homogeneous diatexites, quartzofeldspathic domains from the schlieren diatexites and the leucosomes contain both plagioclase‐dominated and K‐feldspar‐dominated feldspar framework microstructures and hence were melt‐derived rocks. Both types of feldspar frameworks show evidence of tectonic compaction. Modelling the crystallization of an initial anatectic melt shows plagioclase appears first; K‐feldspar appears after ~40% crystallization. In the active shear zone setting, shear‐enhanced compaction provided an essentially continuous driving force for segregation. Thus, Kinawa migmatites with plagioclase frameworks are interpreted to have formed by shear‐enhanced compaction early in the crystallization of anatectic melt, whereas those with K‐feldspar frameworks formed later from the expelled fractionated melt. Trace element abundances in some biotite and plagioclase from the fractionated melt‐derived rocks indicate that these entrained minerals were derived from the wall rocks. Results from the Kinawa migmatites indicate that the key factor in generating petrological diversity during crustal reworking is that shear‐enhanced compaction drove melt segregation throughout the period that melt was present in the rocks. Segregation of melt during melting produced residuum and anatectic melt and their mixtures, whereas segregation during crystallization resulted in crystal fractionation and generated diverse plagioclase‐rich rocks and fractionated melts.  相似文献   

6.
The Kelly's Mountain gneiss complex of Cape Breton Island, Nova Scotia, is a migmatitic paragneiss dominated by biotite- and cordierite-bearing assemblages. Metamorphic grade throughout the complex is in the upper amphibolite facies, with garnet absent and only retrograde muscovite present. In the high grade core of the complex the reaction biotite+andalusite+quartz=cordierite+K-feldspar+sillimanite+ilmenite+H2O is preserved. The pelitic migmatites contain cordierite- and K-feldspar-rich leucosomes and biotite-rich melanosomes. Minor clinopyroxene-bearing amphibolite in the complex does not show migmatitic textures. The migmatites are interpreted as in situ peraluminous partial melts on the basis of phase relations and textural criteria. Retrograde metamorphism under conditions of high fluid pressure locally produced muscovite after K-feldspar and muscovite+green biotite+chlorite after cordierite in paragneiss, and sphene after ilmenite in amphibolite. Peak metamorphic conditions of 1–3.5 kb and 580–700° C are estimated. The high geothermal gradient inferred from these conditions was probably caused by the intrusion of diorites associated with the gneiss complex. The Kelly's Mountain complex represents a rare example of migmatites formed in the low-pressure facies series, and illustrates some of the reactions involving melting in high grade pelitic rocks.  相似文献   

7.
Advances in field observations and experimental petrology on anatectic products have motivated us to investigate the geochemical consequences of accessory mineral dissolution and nonmodal partial melting processes. Incorporation of apatite and monazite dissolution into a muscovite dehydration melting model allows us to examine the coupling of the Rb-Sr and Sm-Nd isotope systems in anatectic melts from a muscovite-bearing metasedimentary source. Modeling results show that (1) the Sm/Nd ratios and Nd isotopic compositions of the melts depend on the amount of apatite and monazite dissolved into the melt, and (2) the relative proportion of micas (muscovite and biotite) and feldspars (plagioclase and K-feldspar) that enter the melt is a key parameter determining the Rb/Sr and 87Sr/86Sr ratios of the melt. Furthermore, these two factors are not, in practice, independent. In general, nonmodal partial melting of a pelitic source results in melts following one of two paths in εNd-87Sr/86Sr ratio space. A higher temperature, fluid-absent path (Path 1) represents those partial melting reactions in which muscovite/biotite dehydration and apatite but not monazite dissolution play a significant role; the melt will have elevated Rb/Sr, 87Sr/86Sr, Sm/Nd, and εNd values. In contrast, a lower temperature, fluid-fluxed path (Path 2) represents those partial melting reactions in which muscovite/biotite dehydration plays an insignificant role and apatite but not monazite stays in the residue; the melt will have lower Rb/Sr, 87Sr/86Sr, Sm/Nd, and εNd values than its source. The master variables controlling both accessory phase dissolution (and hence the Sm-Nd system), and melting reaction (and hence the Rb-Sr systematics) are temperature and water content. The complexity in Sr-Nd isotope systematics in metasediment-derived melts, as suggested in this study, will help us to better understand the petrogenesis for those granitic plutons that have a significant crustal source component.  相似文献   

8.
 The beginning of dehydration melting in the tonalite system (biotite-plagioclase-quartz) is investigated in the pressure range of 2–12 kbar. A special method consisting of surrounding a crystal of natural plagioclase (An45) with a biotite-quartz mixture, and observing reactions at the plagioclase margin was employed for precise determination of the solidus for dehydration melting. The beginning of dehydration melting was worked out at 5 kbar for a range of compositions of biotite varying from iron-free phlogopite to iron-rich Ann70, with and without titanium, fluorine and extra aluminium in the biotite. The dehydration melting of phlogopite + plagioclase (An45) + quartz begins between 750 and 770°C at pressures of 2 and 5 kbar, at approximately 740°C at 8 kbar and between 700 and 730°C at 10 kbar. At 12 kbar, the first melts are observed at temperatures as low as 700°C. The data indicate an almost vertical dehydration melting solidus curve at low pressures which bends backward to lower temperatures at higher pressures (> 5 kbar). The new phases observed at pressures ≤ 10 kbar are melt + enstatite + clinopyroxene + potassium feldspar ± amphibole. In addition to these, zoisite was also observed at 12 kbar. With increasing temperature, phlogopite becomes enriched in aluminium and deficient in potassium. Substitution of octahedral magnesium by aluminium and titanium in the phlogopite, as well as substitution of hydroxyl by fluorine, have little effect on the beginning of dehydration melting temperatures in this system. The dehydration melting of biotite (Ann50) + plagioclase (An45) + quartz begins 50°C below that of phlogopite bearing starting composition. Solid reaction products are orthopyroxene + clinopyroxene + potassium feldspar ± amphibole. Epidote was also observed above 8 kbar, and garnet at 12 kbar (750°C). The experiments on the iron-bearing system performed at ≤ 5 kbar were buffered with NiNiO. The f O 2 in high pressure runs lies close to CoCoO. With the substitution of octahedral magnesium and iron by aluminium and titanium, and replacement of hydroxyl by fluorine in biotite, the beginning of dehydration melting temperatures in this system increase up to 780°C at 5 kbar, which is 70°C above the beginning of dehydration melting of the assemblage containing biotite (Ann50) of ideal composition. The dehydration melting at 5 kbar in the more iron-rich Ann70-bearing starting composition begins at 730°C, and in the Ann25-bearing assemblage at 710°C. This indicates that quartz-biotite-plagioclase assemblages with intermediate compositions of biotite (Ann25 and Ann50) melt at lower temperatures as compared to those containing Fe-richer or Mg-richer biotites. This study shows that the dehydration melting of tonalites may begin at considerably lower temperatures than previously thought, especially at high pressures (>5 kbar). Received: 27 December 1995 / Accepted: 7 May 1996  相似文献   

9.
Dehydration melting of muscovite in metasedimentary sequences is the initially dominant mechanism of granitic melt generation in orogenic hinterlands. In dry (vapour-absent) crust, muscovite reacts with quartz to produce K-feldspar, sillimanite, and monzogranitic melt. When water vapour is present in excess, sillimanite and melt are the primary products of muscovite breakdown, and any K-feldspar produced is due to melt crystallization. Here we document the reaction mechanisms that control nucleation and growth of K-feldspar, sillimanite, and silicate melt in the metamorphic core of the Himalaya, and outline the microstructural criteria used to distinguish peritectic K-feldspar from K-feldspar grains formed during melt crystallization. We have characterized four stages of microstructural evolution in selected psammitic and pelitic samples from the Langtang and Everest regions: (a) K-feldspar nucleates epitaxially on plagioclase while intergrowths of fibrolitic sillimanite and the remaining hydrous melt components replace muscovite. (b) In quartzofeldspathic domains, K-feldspar replaces plagioclase by K+–Na+ cation exchange, while melt and intergrowths of sillimanite+quartz form in the aluminous domains. (c) At 7–8 vol.% melt generation, the system evolves from a closed to open system and all phases coarsen by up to two orders of magnitude, resulting in large K-feldspar porphyroblasts. (d) Preferential crystallization of residual melt on K-feldspar porphyroblasts and coarsened quartz forms an augen gneiss texture with a monzogranitic-tonalitic matrix that contains intergrowths of sillimanite+tourmaline+muscovite+apatite. Initial poikiloblasts of peritectic K-feldspar trap fine-grained inclusions of quartz and biotite by replacement growth of matrix plagioclase. During subsequent coarsening, peritectic K-feldspar grains overgrow and trap fabric-aligned biotite, resulting in a core to rim coarsening of inclusion size. These microstructural criteria enable a mass balance of peritectic K-feldspar and sillimanite to constrain the amount of free H2O present during muscovite dehydration. The resulting modal proportion of K-feldspar in the Himalayan metamorphic core requires vapour-absent conditions during muscovite dehydration melting and leucogranite formation, indicating that the generation of large volumes of granitic melts in orogenic belts is not necessarily contingent on an external source of fluids.  相似文献   

10.
The beginning of melting in the system Qz-Or-Ab-An-H2 O was experimentally reversed in the pressure range kbar using starting materials made up of mixtures of quartz and synthetic feldspars. With increasing pressure the melting temperature decreases from 690° C at 2 kbar to 630° C at 17 kbar in the An-free alkalifeldspar granite system Qz-Or-Ab-H2O. In the granite system Qz-Or-Ab-An-H2O the increase of the solidus temperature with increasing An-content is only very small. In comparison to the alkalifeldspar granite system the solidus temperature increases by 3° C (7° C) if albite is replaced by plagioclase An 20 (An 40). The difference between the solidus temperatures of the alkalifeldspar granite system and of quartz — anorthite — sanidine assemblages (system Qz-Or-An-H2O) is approximately 50° C. With increasing water pressures plagioclase and plagioclase-alkalifeldspar assemblages become unstable and are replaced by zoisite+kyanite+quartz and zoisite+muscovite-paragonitess +quartz, respectively. The pressure stability limits of these assemblages are found to lie between 6 and 16 kbar at 600° C. At high water pressures (10–18 kbar) zoisite — muscovite — quartz assemblages are stable up to 700 and 720° C. The solidus curve of this assemblage is 10–20° C above the beginning of melting of sanidine — zoisite — muscovite — quartz mixtures. The amount of water necessary to produce sufficient amounts of melt to change a metamorphic rock into a magmatic looking one is only small. In case of layered migmatites it is shown that 1 % of water (or even less) is sufficient to transform portions of a gneiss into (magmatic looking) leucosomes. High grade metamorphic rocks were probably relatively dry, and anatectic magmas of granitic or granodioritic composition are usually not saturated with water.  相似文献   

11.
The melting of plagioclase and quartz has been investigated at P H2O =2kb. A single crystal of plagioclase was surrounded by quartz powder and water. A reaction rim consisting of glass and of An-rich plagioclase developed around unchanged starting plagioclase. Microprobe determinations of melt and coexisting plagioclase compositions reveal a strong fractionation of plagioclase components between melt and new plagioclase. For example at 850° C the approximate X An of melt is 0.3 and that of plagioclase is 0.8. The temperature interval between beginning of melting and complete melting of cotectic compositions is 100° C or more for quartz-plagioclase mixtures with plagioclases between An 40 and An 75. In comparison to the system Ab-An-H2O the plagioclase melting loop is somewhat wider in the investigated system Qz-Ab-An-H2O but the temperature interval is much smaller (100° C) than in the system Ab-An-H2O (200° C). The solidus data indicated by the new plagioclase compositions are practically identical with those observed in beginning of melting experiments. The results show that fractionation of plagioclase components between partial melts and restite plagioclase can be more pronounced in multi-component rocks than in the pure plagioclase system. This finding is important for the development of albite rich rocks from more basic compositions.  相似文献   

12.
Cordierite and orthopyroxene (or orthoamphibole) are widespread in migmatitic terranes, and partial melting of pelitic rocks may be important in their production. In particular, the reaction quartz +albite+biotite+garnet+water vapor = cordierite +orthopyroxene or orthoamphibole+melt was among reactions discussed by Grant (1973) but poorly constrained in pressure-temperature space.This reaction involves too many phases to be readily studied experimentally. Therefore simpler melting and dehydration reactions involving quartzalbite-biotite-cordierite-orthopyroxene were investigated.In conjunction with the work of Hoffer (1976, 1978) these experiments place useful constraints on the above reaction and on the reaction quartz+albite+aluminosilicate+biotite+vapor = cordierite+garnet+melt. In pelitic rocks near the second illimanite isograd, cordierite and garnet may coexist with melt as low as 660° C and cordierite and orthopyroxene may coexist with melt at temperatures less than 675° C. In the absence of significant Mn or Ca, in pelitic rocks within the realm of melting, biotite+garnet assemblages are probably limited to pressures greater than 2kb and aluminosilicate+biotite assemblages to pressures greater than 3kb.  相似文献   

13.
P -T paths from anatectic pelites   总被引：2，自引：1，他引：1  
A relatively simple petrogenetic grid for partial melting of pelitic rocks in the NCKFMASH system is presented based on the assumption that the only H2O available for melting is through dehydration reactions. The grid includes both discontinuous and continuous Fe-Mg reactions; contours of Fe/(Fe+Mg) for continuous reactions define P-T vectors along which continuous melting will occur. For biotite-bearing assemblages (garnet+biotite + sillimanite + K-feldspar + liquid and garnet + biotite + cordierite + K-feldspar + liquid), Fe/(Fe+Mg) contours have negative slopes and melting will occur with increasing temperature or pressure. For biotite-absent assemblages (garnet + cordierite + sillimanite + K-feldspar + liquid or garnet + cordierite + orthopyroxene + K-feldspar + liquid) Fe/(Fe + Mg) contours have flat slopes and melting will occur only with increasing pressure. The grid predicts that abundant matrix K-feldspar should only be observed if rocks are heated at P < 3.8 kbar, that abundant retrograde muscovite should only be observed if rocks are cooled at P > 3.8 kbar, and that generation of late biotite + sillimanite replacing garnet, cordierite, or as selvages around leu- cosomes should be common in rocks in which melt is not removed. There is also a predicted field for dehydration melting of staurolite between 5 and 12 kbar. Textures in migmatites from New Hampshire, USA, suggest that prograde dehydration melting reactions are very nearly completely reversible during cooling and crystallization in rocks in which melt is not removed. Therefore, many reaction textures in “low grade” migmatites may represent retrograde rather than prograde reactions. Received: 5 March 1998 / Accepted: 7 August 1998  相似文献   

14.
In the Boi Massif of Western Timor the Mutis Complex, which is equivalent to the Lolotoi Complex of East Timor, is composed of two lithostratigraphical components: various basement schists and gneisses; and the dismembered remnants of an ophiolite. Cordierite-bearing pelitic schists and gneisses carry an early mineral assemblage of biotite + garnet + plagioclase + Al-silicate, but contain no prograde muscovite; sillimanite occurs in a textural mode which suggests that it replaced and pseudomorphed kyanite at an early stage and some specimens of pelitic schist contain tiny kyanite relics in plagioclase. Textural relations between, and mineral chemistries of, ferro-magnesian phases in these pelitic chists and gneisses suggest that two discontinuous reactions and additional continuous compositional changes have been overstepped, possibly with concomitant anatexis, as a result of decrease in Pload during high temperature metamorphism. The simplified reactions are: garnet and/or biotite + sillimanite + quartz + cordierite + hercynite + ilmenite + excess components. P-T conditions during the development of the early mineral assemblage in the pelitic gneisses are estimated to have been P + 10 kbar and T > 750°C, based upon the plagioclase-garnet-Al-silicate-quartz geobarometer and the garnet-biotite geothermometer. P-T conditions during the subsequent development of cordierite-bearing mineral assemblages in the pelitic gneisses are estimated to have been P + 5 kbar and T + 700°C with XH2O < 0.5, based upon the Fe content of cordierite occurring in the assemblage quartz + plagioclase + sillimanite + biotite + garnet + cordierite coexisting with melt. Final equilibration between some of the phases suggests that conditions dropped to P > 2.3 kbar and T > 600°C. A similar exhumation P-T path is suggested for the pelitic schists with early metamorphic conditions of P > 6.2 kbar and T > 745°C and subsequent development of cordierite under conditions in the range P = 3-4 kbar and T = 600-700°C. The tectonic implications of these P-T estimates are discussed and it is concluded that the P-T path followed by these rocks was caused by decompression during rifting and synmetamorphic ophiolite emplacement resulting from processes during the initiation and development of a convergent plate junction located in Southeast Asia during late Jurassic to Cretaceous time.  相似文献   

15.
We investigate the inclusions hosted in peritectic garnet from metapelitic migmatites of the Kinzigite Formation (Ivrea Zone, NW Italy) to evaluate the starting composition of the anatectic melt and fluid regime during anatexis throughout the upper amphibolite facies, transition, and granulite facies zones. Inclusions have negative crystal shapes, sizes from 2 to 10 μm and are regularly distributed in the core of the garnet. Microstructural and micro‐Raman investigations indicate the presence of two types of inclusions: crystallized silicate melt inclusions (i.e., nanogranitoids, NI), and fluid inclusions (FI). Microstructural evidence suggests that FI and NI coexist in the same cluster and are primary (i.e., were trapped simultaneously during garnet growth). FI have similar compositions in the three zones and comprise variable proportions of CO2, CH4, and N2, commonly with siderite, pyrophyllite, and kaolinite, suggesting a COHN composition of the trapped fluid. The mineral assemblage in the NI contains K‐feldspar, plagioclase, quartz, biotite, muscovite, chlorite, graphite and, rarely, calcite. Polymorphs such as kumdykolite, cristobalite, tridymite, and less commonly kokchetavite, were also found. Rehomogenized NI from the different zones show that all the melts are leucogranitic but have slightly different compositions. In samples from the upper amphibolite facies, melts are less mafic (FeO + MgO = 2.0–3.4 wt%), contain 860–1700 ppm CO2 and reach the highest H2O contents (6.5–10 wt%). In the transition zone melts have intermediate H2O (4.8–8.5 wt%), CO2 (457–1534 ppm) and maficity (FeO + MgO = 2.3–3.9 wt%). In contrast, melts at granulite facies reach highest CaO, FeO + MgO (3.2–4.7 wt%), and CO2 (up to 2,400 ppm), with H2O contents comparable (5.4–8.3 wt%) to the other two zones. Our results represent the first clear evidence for carbonic fluid‐present melting in the Ivrea Zone. Anatexis of metapelites occurred through muscovite and biotite breakdown melting in the presence of a COH fluid, in a situation of fluid–melt immiscibility. The fluid is assumed to have been internally derived, produced initially by devolatilization of hydrous silicates in the graphitic protolith, then as a result of oxidation of carbon by consumption of Fe3+‐bearing biotite during melting. Variations in the compositions of the melts are interpreted to result from higher T of melting. The H2O contents of the melts throughout the three zones are higher than usually assumed for initial H2O contents of anatectic melts. The CO2 contents are highest at granulite facies, and show that carbon‐contents of crustal magmas are not negligible at high T. The activity of H2O of the fluid dissolved in granitic melts decreases with increasing metamorphic grade. Carbonic fluid‐present melting of the deep continental crust represents, together with hydrate‐breakdown melting reactions, an important process in the origin of crustal anatectic granitoids.  相似文献   

16.
Metavolcanic rocks containing low-Ca amphiboles (gedrite, cummingtonite) and biotite can undergo substantial dehydration-melting. This is likely to be most prominent in Barrovian Facies Series (kyanite-sillimanite) and occurs at the same time as widespread metapelite dehydrationmelting. In lower pressure facies series, metavolcanics will be represented by granulites rich in orthopyroxene when dehydration occurs at much lower temperatures than melting. In higher pressure facies series it is not well known whether metavolcanic rocks dehydrate or melt at temperatures lower or similar to that of metapelites.  相似文献   

17.
Calculated phase equilibria among the minerals sodic amphibole, calcic amphibole, garnet, chloritoid, talc, chlorite, paragonite, margarite, omphacite, plagioclase, carpholite, zoisite/clinozoisite, lawsonite, pyrophyllite, kyanite, sillimanite, quartz and H2O are presented for the model system Na2O-CaO-FeO-MgO-Al2O3-SiO2-H2O (NCFMASH), which is relevant for many greenschist, blueschist, amphibolite and eclogite facies rocks. Using the activity-composition relationships for multicomponent amphiboles constrained by Will and Powell (1992), equilibria containing coexisting calcic and sodic amphiboles could be determined. The blueschist–greenschist transition reaction in the NCFMASH system, for example, is defined by the univariant reaction sodic amphibole + zoisite = calcic amphibole + chlorite + paragonite + plagioclase (+ quartz + H2O) occurring between approximately 420 and 450 °C at 9.5 to 10 kbar. The calculated petrogenetic grid is a valuable tool for reconstructing the PT-evolution of metabasic rocks. This is shown for rocks from the island of Samos, Greece. On the basis of mineral and whole rock analyses, PT-pseudosections were calculated and, together with the observed mineral assemblages and reaction textures, are used to reconstruct PT-paths. For rocks from northern Samos, pseudomorphs after lawsonite preserved in garnet, the assemblage sodic amphibole-garnet-paragonite-chlorite-zoisite-quartz and the retrograde appearance of albitic plagioclase and the formation of calcic amphibole around sodic amphibole constrain a clockwise PT-path that reaches its thermal maximum at some 520 °C and 19 kbar. The derived PT-trajectory indicates cooling during exhumation of the rocks and is similar to paths for rocks from the western part of the Attic-Cycladic crystalline complex. Rocks from eastern Samos indicate lower pressures and are probably related to high-pressure rocks from the Menderes Massif in western Turkey. Received: 8 July 1997 / Accepted: 11 February 1998  相似文献   

18.
Petrological and geochemical variations are used to investigatethe formation of granite magma from diatexite migmatites derivedfrom metasedimentary rocks of pelitic to greywacke compositionat St. Malo, France. Anatexis occurred at relatively low temperaturesand pressures (<800°C, 4–7 kbar), principally throughmuscovite dehydration melting. Biotite remained stable and servesas a tracer for the solid fraction during melt segregation.The degree of partial melting, calculated from modal mineralogyand reaction stoichiometry, was <40 vol. %. There is a continuousvariation in texture, mineralogy and chemical composition inthe diatexite migmatites. Mesocratic diatexite formed when metasedimentaryrocks melted sufficiently to undergo bulk flow or magma flow,but did not experience significant melt–residuum separation.Mesocratic diatexite that underwent melt segregation duringflow generated (1) melanocratic diatexites at the places wherethe melt fraction was removed, leaving behind a biotite andplagioclase residuum (enriched in TiO2, FeOT, MgO, CaO, Sc,Ni, Cr, V, Zr, Hf, Th, U and REE), and (2) a complementary leucocraticdiatexite (enriched in SiO2, K2O and Rb) where the melt fractionaccumulated. Leucocratic diatexite still contained 5–15vol. % residual biotite (mg-number 40–44) and 10–20vol. % residual plagioclase (An22). Anatectic granite magmadeveloped from the leucodiatexite, first by further melt–residuumseparation, then through fractional crystallization. Most biotitein the anatectic granite is magmatic (mg-number 18–22). KEY WORDS: anatexis; diatexite; granite magma; melt segregation; migmatite  相似文献   

19.
Partial melting experiments on plagioclase (An60) and diopside have been carried out using pairs of large crystals to investigate textures and kinetics of melting. The experiments were done at one atmosphere pressure as a function of temperature (1,190–1,307° C) and time (1.5–192 h). Melting took place mainly at the plagioclase-diopside contact planes. Reaction zones composed of fine mixtures of calcic plagioclase and melt were developed from the surface of the plagioclase crystal inward. There exists a critical temperature, below which only a few % melting can occur over the duration of the experiments. This sluggish melting is caused by slow NaSi-CaAl diffusion in plagioclase, because the plagioclase crystal must change its composition to produce albite-rich cotectic melts. Diffusion in the solid also affects the chemical composition of the melts. During initial melting, potassium is preferentially extracted from plagioclase because K-Na diffusion in plagioclase is faster than that of NaSi-CaAl. This also causes a shift in the cotectic compositions. Above the critical temperature, on the other hand, melting is promoted by a metastable reaction in which the plagioclase composition does not change, and which produces melts with compositional gradients along the original An60-diopside tie line. The critical temperature is determined by the intersection of the cotectic and the An60-diopside tie line. Interdiffusion coefficients of plagioclase-diopside components in the melt are estimated from melting rates above the critical temperature by using a simplified steady-state diffusion model (e.g., 10–8 cm2/sec at 1,300° C).Many examples of reaction zones due to partial melting have been described as spongy or fingerprint-like textures in xenoliths. Metastable melting above the critical temperature is considered to take place in natural melting where there is a high degree of melting. However, we cannot exclude the possibility of disequilibrium created by sluggish melting controlled by diffusion in the minerals. If melting occurs close to the solidus, this process can be important even for partial melting in the upper mantle.  相似文献   

20.
The metamorphic evolution of rocks cropping out near Stoer, within the Assynt terrane of the central region of the mainland Lewisian complex of NW Scotland, is investigated using phase equilibria modelling in the NCKFMASHTO and MnNCKFMASHTO model systems. The focus is on the Cnoc an t’Sidhean suite, garnet‐bearing biotite‐rich rocks (brown gneiss) with rare layers of white mica gneiss, which have been interpreted as sedimentary in origin. The results show that these rocks are polymetamorphic and experienced granulite facies peak metamorphism (Badcallian) followed by retrograde fluid‐driven metamorphism (Inverian) under amphibolite facies conditions. The brown gneisses are inferred to have contained an essentially anhydrous granulite facies peak metamorphic assemblage of garnet, quartz, plagioclase and ilmenite (±rutile, K‐feldspar and pyroxene) with biotite, hornblende, muscovite, chlorite and/or epidote as hydrous retrograde minerals. P–T constraints imposed by phase equilibria modelling imply conditions of 13–16 kbar at >900 °C for the Badcallian granulite facies metamorphic peak, consistent with the field evidence for partial melting in most lithologies. The white mica gneiss comprises a muscovite‐dominated matrix containing porphyroblasts of staurolite, corundum, kyanite and rare garnet. Previous studies have suggested that staurolite, corundum, kyanite and muscovite all grew at the granulite facies peak, with partial melting and melt loss producing a highly aluminous residue. However, at the inferred peak P–T conditions, staurolite and muscovite are not predicted to be stable, suggesting they are retrograde phases that grew during amphibolite facies retrograde metamorphism. The large proportion of mica suggests extensive H2O‐rich fluid‐influx, consistent with the retrograde growth of hornblende, biotite, epidote and chlorite in the brown gneisses. P–T conditions of 5.0–6.5 kbar at 520–550 °C are derived for the Inverian event. In situ dating of zircon from samples of the white mica gneiss yield apparent ages that are difficult to interpret. However, the data are permissive of granulite facies (Badcallian) metamorphism having occurred at c. 2.7–2.8 Ga with subsequent fluid driven (Inverian) retrogression at c. 2.5–2.6 Ga, consistent with previous interpretations.  相似文献   

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