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1.
Differentiation of the continental crust is the result of complex interactions between a large number of processes, which govern partial melting of the deep crust, magma formation and segregation, and magma ascent to significantly higher crustal levels. The anatectic metasedimentary rocks exposed in the Southern Marginal Zone of the Limpopo Belt represent an unusually well‐exposed natural laboratory where the portion of these processes that operate in the deep crust can be directly investigated in the field. The formation of these migmatites occurred via absent incongruent melting reactions involving biotite, which produced cm‐ to m‐scale, K2O‐poor garnet‐bearing stromatic leucosomes, with high Ca/Na ratios relative to their source rocks. Field investigation combined with geochemical analyses, and phase equilibrium modelling designed to investigate some aspects of disequilibrium partial melting show that the outcrop features and compositions of the leucosomes suggest several steps in their evolution: (1) Melting of a portion of the source, with restricted plagioclase availability due to kinetic controls, to produce a magma (melt + entrained peritectic minerals in variable proportions relative to melt); (2) Segregation of the magma at near peak metamorphic conditions into melt accumulation sites (MAS), also known as future leucosome; (3a) Re‐equilibration of the magma with a portion of the bounding mafic residuum via chemical diffusion (H2O, K2O), which triggers the co‐precipitation of quartz and plagioclase in the MAS; (3b) Extraction of melt‐dominated magma to higher crustal levels, leaving peritectic minerals entrained from the site of the melting reaction, and the minerals precipitated in the MASs to form the leucosome in the source. The key mechanism controlling this behaviour is the kinetically induced restriction of the amount of plagioclase available to the melting reaction. This results in elevated melt H2O and K2O and chemical potential gradient for these components across the leucosome/mafic residuum contact. The combination of all of these processes accurately explains the composition of the K2O‐poor leucosomes. These findings have important implications for our understanding of melt segregation in the lower crust and minimum melt residency time which, according to the chemical modelling, is <5 years. We demonstrate that in some migmatitic granulites, the leucosomes constitute a type of felsic refractory residuum, rather than evidence of failed magma extraction. This provides a new insight into the ways that source heterogeneity may control anatexis.  相似文献   

2.
The beginning stages of melt segregation and the formation of leucosomes are rarely preserved in migmatites. Most arrays of leucosomes record a more advanced stage where flow dominates over segregation. However, the early stages in the formation of leucosomes and the segregation of melt are preserved in a partially melted meta‐argillite from the metatexite zone (>800 °C) of the contact aureole around the Duluth Complex, Minnesota. The rock contains 2.4 modal% leucosome in a matrix consisting of 40.5% in situ neosome and 57.1% cordierite + plagioclase framework. The domainal microstructure in the matrix is a pre‐anatectic feature resulting from the bulk composition. Terminal chlorite reactions produced a large volume of cordierite which, with plagioclase, formed a framework that enclosed patches of biotite + quartz + plagioclase ± K‐feldspar. Upon melting, these fertile domains became patches of in situ neosome. Plagioclase in the neosome is less sodic than in the leucosome, hence segregation of melt occurred during crystallization, not melting. Segregation was delayed because the cordierite + plagioclase framework was strong enough to resist dilatation and compaction until after crystallization started. The leucosomes are small (i.e. they are microleucosomes) and display a systematic progression in morphology as length and aspect ratio increase from ~1 to 19 mm and from ~2.5 to >30 respectively. Small equant micropores form first, and in places these coalesce into small (~1 mm, aspect ratio ~2.5), isolated, blunt‐ended, elliptical microleucosomes. In the next stage, micropores develop ahead of, and at ~45° to the left and right of the blunt tip of a microleucosome; one of these develops into an elliptical leucosome and an en echelon array of either a left‐ or right‐stepping elliptical microleucosome forms. Each elliptical microleucosome in the en echelon arrays is separated by a bridge of matrix. Next, microleucosomes of greater length (>4 mm) and aspect ratio (>5) form when the bridges of cordierite + plagioclase matrix rupture and the elliptical microleucosomes link together to form a zigzag‐shaped microleucosome. Finally, still longer microleucosomes with greater aspect ratios (~30) are formed by the joining of zigzag arrays. Such a progression is characteristic of the way ductile fractures grow. The segregation of melt was driven by the pressure gradient between the dilatant fracture and an adjacent in situ neosome, which drew melt to the growing fracture, thereby creating a microleucosome. The microleucosomes are filled arrays of ductile fractures. Melt was contiguous only between microleucosomes and adjacent patches of in situ neosome. The length‐scale of segregation was ~5 mm, the size of a typical patch of in situ neosome, and restricted by the surrounding impermeable cordierite + plagioclase framework. The melt in the microleucosome was the most fractionated and the last to crystallize. All microleucosomes contain entrained minerals as a consequence of their mechanism of growth. Rupture of the bridges resulted in the entrainment of pre‐anatectic phases. However, microleucosomes that cross patches of in situ neosome are also contaminated with peritectic phases that were transported with the melt.  相似文献   

3.
Upper amphibolite facies felsic gneiss from Broken Hill records the metatexite to schlieren diatexite to massive diatexite transition in a single rock type over a scale of tens to hundreds of metres. The metatexites are characterized by centimetre‐scale segregation of melt into leucosomes to form stromatic migmatite. The schlieren diatexites are characterized by the disaggregation of the rocks and the development of schlieren migmatite. The massive diatexites represent a higher degree of disaggregation, lack schlieren and contain plagioclase and K‐feldspar phenocrysts. The transition from metatexite to schlieren diatexite and massive diatexite was heterogeneous with both disaggregation of the rock on a grain scale and disaggregation of the rock into centimetre‐ to metre‐scale rafts. As melt contents increased, the proportion of material disaggregated on a grain scale increased. The high proportion of melt needed to form diatexites at upper amphibolite facies conditions was the result of an influx of hydrous fluid at temperatures just above the solidus of the diatexites. Nearby metapelitic rocks, with a slightly higher solidus temperature, undergoing subsolidus muscovite breakdown are the likely source of the fluid. Continued heating during and after the influx of fluid led to melt contents of up to c. 60 mol.% in the massive diatexite. The metatexite zone probably involved little added fluid. Continued deformation during cooling and melt crystallization resulted in the extensive development of schlieren and late‐stage melt segregations and melt‐rich shear bands in the schlieren diatexite zone. The rocks of the massive diatexite zone lack these late‐stage segregations, consistent with the cessation of D2 deformation prior to them developing a crystal framework.  相似文献   

4.
Anatexis of metapelitic rocks at the Bandelierkop Quarry (BQ) locality in the Southern Marginal Zone of the Limpopo Belt occurred via muscovite and biotite breakdown reactions which, in order of increasing temperature, can be modelled as: (1) Muscovite + quartz + plagioclase = sillimanite + melt; (2) Biotite + sillimanite + quartz + plagioclase = garnet + melt; (3) Biotite + quartz + plagioclase = orthopyroxene ± cordierite ± garnet + melt. Reactions 1 and 2 produced stromatic leucosomes, which underwent solid‐state deformation before the formation of undeformed nebulitic leucosomes by reaction 3. The zircon U–Pb ages for both leucosomes are within error identical. Thus, the melt or magma formed by the first two reactions segregated and formed mechanically solid stromatic veins whilst temperature was increasing. As might be predicted from the deformational history and sequence of melting reactions, the compositions of the stromatic leucosomes depart markedly from those of melts from metapelitic sources. Despite having similar Si contents to melts, the leucosomes are strongly K‐depleted, have Ca:Na ratios similar to the residua from which their magmas segregated and are characterized by a strong positive Eu anomaly, whilst the associated residua has no pronounced Eu anomaly. In addition, within the leucosomes and their wall rocks, peritectic garnet and orthopyroxene are very well preserved. This collective evidence suggests that melt loss from the stromatic leucosome structures whilst the rocks were still undergoing heating is the dominant process that shaped the chemistry of these leucosomes and produced solid leucosomes. Two alternative scenarios are evaluated as generalized petrogenetic models for producing Si‐rich, yet markedly K‐depleted and Ca‐enriched leucosomes from metapelitic sources. The first process involves the mechanical concentration of entrained peritectic plagioclase and garnet in the leucosomes. In this scenario, the volume of quartz in the leucosome must reflect the remaining melt fraction with resultant positive correlation between Si and K in the leucosomes. No such correlation exists in the BQ leucosomes and in similar leucosomes from elsewhere. Consequently, we suggest disequilibrium congruent melting of plagioclase in the source and consequential crystallization of peritectic plagioclase in the melt transfer and accumulation structures rather than at the sites of biotite melting. This induces co‐precipitation of quartz in the structures by increasing SiO2 content of the melt. This process is characterized by an absence of plagioclase‐induced fractionation of Eu on melting, and the formation of Eu‐enriched, quartz + plagioclase + garnet leucosomes. From these findings, we argue that melt leaves the source rapidly and that the leucosomes form incrementally as melt or magma leaving the source dumps its disequilibrium Ca load, as well as quartz and entrained ferromagnesian peritectic minerals, in sites of magma accumulation and escape. This is consistent with evidence from S‐type granites suggesting rapid magma transfer from source to high level plutons. These findings also suggest that leucosomes of this type should be regarded as constituting part of the residuum from partial melting.  相似文献   

5.
Migmatite structures in the Central Gneiss Complex, Boca de Quadra, Alaska   总被引：3，自引：0，他引：3  
Abstract Migmatite structures in the Coast Plutonic-Metamorphic Complex are well exposed in the inlet of Boca de Quadra, southeast Alaska. Two types of anatectic migmatites are present. Patch migmatites formed by in situ melting and subsequent crystallization of melt. Diktyonitic migmatites comprise a discontinuous veined network of leucocratic material, in which leucosomes enclose boudins of host rock. The margins of these boudins show the development of both melanosomes and shear band fabrics.
Strain analysis of diktyonitic melanosomes indicates that these regions have undergone volume decreases of 20-27%. This volume decrease is attributed to melt extraction into the adjacent fracture-filling leucosomes. Thus, diktyonitic migmatites formed by shear-induced segregation of partial melt, whereas in patch migmatites the lack of shear stresses inhibited melt segregation. The variable structural style of anatectic migmatites in Boca de Quadra is not related to host-rock composition, but may be due to differences in the amount of differential stress during migmatization. These in turn may be controlled by host-rock strength and/or diachroneity of migmatization and deformation.
Determination of volume changes during migmatization using strain analysis is potentially capable of discriminating intrusive and anatectic migmatites and consequently of documenting melt segregation and subsequent migration across crustal levels.  相似文献   

6.
The grain‐ and outcrop‐scale distribution of melt has been mapped in anatectic rocks from regional and contact metamorphic environments and used to infer melt movement paths. At the grain scale, anatectic melt is pervasively distributed in the grain boundaries and in small pools; consequently, most melt is located parallel to the principal fabric in the rock, typically a foliation. Short, branched arrays of linked, melt‐bearing grain boundaries connect melt‐depleted parts of the matrix to diffuse zones of melt accumulation (protoleucosomes), where magmatic flow and alignment of euhedral crystals grown from the melt developed. The distribution of melt (leucosome) and residual rocks (normally melanocratic) in outcrop provides different, but complementary, information. The residual rocks show where the melt came from, and the leucosomes preserve some of the channels through which the melt moved, or sites where it pooled. Different stages of the melt segregation process are recorded in the leucosome–melanosome arrays. Regions where melting and segregation had just begun when crystallization occurred are characterized by short arrays of thin, branching leucosomes with little melanosome. A more advanced stage of melting and segregation is marked by the development of residual rocks around extensive, branched leucosome arrays, generally oriented along the foliation or melting layer. Places where melting had stopped, or slowed down, before crystallization began are marked by a high ratio of melanosome to leucosome; because most of the melt has drained away, very few leucosomes remain to mark the melt escape path — this is common in melt‐depleted granulite terranes. Many migmatites contain abundant leucosomes oriented parallel to the foliation; mostly, these represent places where foliation planes dilated and melt drained from the matrix via the branched grain boundary and larger branched melt channel (leucosome) arrays collected. Melt collected in the foliation planes was partially, or fully, expelled later, when discordant leucosomes formed. Leucosomes (or veins) oriented at high angles to the foliation/layering formed last and commonly lack melanocratic borders; hence they were not involved in draining the matrix of the melting layer. Discordant leucosomes represent the channels through which melt flowed out of the melting layer.  相似文献   

7.
Evidence of melting is presented from the Western Gneiss Region (WGR) in the core of the Caledonian orogen, Western Norway and the dynamic significance of melting for the evolution of orogens is evaluated. Multiphase inclusions in garnet that comprise plagioclase, potassic feldspar and biotite are interpreted to be formed from melt trapped during garnet growth in the eclogite facies. The multiphase inclusions are associated with rocks that preserve macroscopic evidence of melting, such as segregations in mafic rocks, leucosomes and pegmatites hosted in mafic rocks and in gneisses. Based on field studies, these lithologies are found in three structural positions: (i) as zoned segregations found in high‐P (ultra)mafic bodies; (ii) as leucosomes along amphibolite facies foliation and in a variety of discordant structures in gneiss; and (iii) as undeformed pegmatites cutting the main Caledonian structures. Segregations post‐date the eclogite facies foliation and pre‐date the amphibolite facies deformation, whereas leucosomes are contemporaneous with the amphibolite facies deformation, and undeformed pegmatites are post‐kinematic and were formed at the end of the deformation history. The geochemistry of the segregations, leucosomes and pegmatites in the WGR defines two trends, which correlate with the mafic or felsic nature of the host rocks. The first trend with Ca‐poor compositions represents leucosome and pegmatite hosted in felsic gneiss, whereas the second group with K‐poor compositions corresponds to segregation hosted in (ultra)mafic rocks. These trends suggest partial melting of two separate sources: the felsic gneisses and also the included mafic eclogites. The REE patterns of the samples allow distinction between melt compositions, fractionated liquids and cumulates. Melting began at high pressure and affected most lithologies in the WGR before or during their retrogression in the amphibolite facies. During this stage, the presence of melt may have acted as a weakening mechanism that enabled decoupling of the exhuming crust around the peak pressure conditions triggering exhumation of the upward‐buoyant crust. Partial melting of both felsic and mafic sources at temperatures below 800 °C implies the presence of an H2O‐rich fluid phase at great depth to facilitate H2O‐present partial melting.  相似文献   

8.
SAWYER  E. W. 《Journal of Petrology》1987,28(3):445-473
Anatectic migmatite leucosomes in the Quetico MetasedimentaryBelt (Superior Province) are discordant to the host rock layering.Two morphological varieties within the anatectic leucosome suiteare distinguished. The first type show little compositionalor textural variation either across, or along, the leucosomes.In contrast, the second variety exhibits both compositionaland textural variations in a single leucosome, typically withinternal cross-cutting relationships. Major-oxide contents varycomparatively little in the Quetico anatectic leucosome suite,but there is a considerable range in the incompatible element(REE, Hf, Zr, Y and Th) concentrations. In particular La contentsrange from 1.8 to 78.1 p.p.m. and the La/Yb ratios from 9.1to 101.9. Samples with high REE contents have negative Eu anomalies,whereas those with low total REE abundances have positive Euanomalies, which indicate that feldspar fractionation was importantin their petrogenesis. Three samples which have no Eu anomalies,and which are taken not to have experienced significant feldsparfractionation, are regarded as the closest approximation toa primary melt composition. Petrographic evidence indicates that only the most aluminousbulk compositions in the host rocks have melted, with cordieriteand biotite as the principal residual phases. Batch partialmelting models indicate that the three leucosomes without Euanomalies could have been derived from 40–80 per centpartial melting of the aluminous metasediments, but garnet musthave been a residual phase. Since the residuum from 40 per centpartial melting is more mafic than any of the rocks currentlyexposed in the area, it is concluded that the melting whichgave rise to the leucosomes occurred at greater depth. Crystallization models indicate that the observed range of leucosomecompositions can be derived by crystal fractionation of meltcompositions similar to the three leucosomes lacking Eu anomalies(i.e. the assumed primary melts). Samples with high abundancesof incompatible elements and negative Eu anomalies representfractionated melts, whereas those with low levels of REE andpositive Eu anomalies represent cumulates. Leucosome composition,morphology and texture can be related to crystallization history,notably the timing of crystallization with respect to leucosomeintrusion. In particular, those leucosomes that exhibit compositionaland textural zoning are interpreted to have undergone crystalfractionation during intrusion. Although a suite of migmatite leucosomes may be derived by partialmelting, it is concluded that the trace-element compositionof any particular leucosome depends, to a great extent, uponits segregation and crystallization history. Indeed, the primarymelt composition may not be preserved.  相似文献   

9.
华北克拉通阜平杂岩的深熔和混合岩化作用   总被引：3，自引：2，他引：1  
华北克拉通的阜平杂岩长英质岩石中常产出显著的浅色体、岩脉和花岗岩侵入体,并形成广泛的混合岩化作用。通过矿物自形晶的形成、黑云母向角闪石的转换和大量钠长石净边的出现以及其它与熔体活动有关结构的分析,浅色脉体和混合岩化作用的发生与外来熔体的注入有关。在长英质片麻岩中可出现明显的熔体注入,在一些不易片理化的岩石如石英岩中亦可形成浸染状熔体渗入。熔体汇集可形成浅色体、岩脉,直至花岗岩侵入体。而深熔作用本身形成熔体的作用在本区几乎可以忽略不计。在遭受渗透式混合岩化作用的过程中,岩石成分发生了改变,形成开放系统。随着渗透熔体的结晶,可形成一些岩浆锆石,在副片麻岩中则很容易被当作碎屑锆石。  相似文献   

10.
Abstract Migmatites in the Quetico Metasedimentary Belt contain two types of leucosome: (1) Layer-parallel leucosomes that grew during deformation and prograde metamorphism. These are enriched in SiO2, Sr, and Eu, but depleted in TiO2, Fe2O3, MgO, Cs, Rb, REE, Sc, Th, Zr, and Hf relative to the Quetico metasediments. (2) Discordant leucosomes that formed after the regional folding events when metamorphic temperatures were at their peak. These are enriched in Rb, Ba, Sr and Eu, but display a wide range of LREE, Th, Zr, and Hf contents relative to the Quetico metasediments.
Layer-parallel leucosomes formed by a subsolidus process termed tectonic segregation. This stress-induced mass transfer process began when the Quetico sediments were deformed during burial, and continued whilst the rocks were both stressed and heterogeneous. Subsolidus leucosome compositions are consistent with the mobilization of quartz and feldspar from the host rocks by pressure solution. The discordant leucosomes formed by partial melting of the Quetico metasediments, possibly during uplift of the belt. The range of composition displayed by the anatectic leucosomes arises from crystal fractionation during leucosome emplacement. Some anatectic leucosomes preserve primary melt compositions and have smooth REE patterns, but those with negative Eu anomalies represent fractionated melts, and others with positive Eu anomalies represent accumulations of feldspar plus trapped melt.  相似文献   

11.
Petrological and geochemical variations are used to investigatethe formation of granite magma from diatexite migmatites derivedfrom metasedimentary rocks of pelitic to greywacke compositionat St. Malo, France. Anatexis occurred at relatively low temperaturesand pressures (<800°C, 4–7 kbar), principally throughmuscovite dehydration melting. Biotite remained stable and servesas a tracer for the solid fraction during melt segregation.The degree of partial melting, calculated from modal mineralogyand reaction stoichiometry, was <40 vol. %. There is a continuousvariation in texture, mineralogy and chemical composition inthe diatexite migmatites. Mesocratic diatexite formed when metasedimentaryrocks melted sufficiently to undergo bulk flow or magma flow,but did not experience significant melt–residuum separation.Mesocratic diatexite that underwent melt segregation duringflow generated (1) melanocratic diatexites at the places wherethe melt fraction was removed, leaving behind a biotite andplagioclase residuum (enriched in TiO2, FeOT, MgO, CaO, Sc,Ni, Cr, V, Zr, Hf, Th, U and REE), and (2) a complementary leucocraticdiatexite (enriched in SiO2, K2O and Rb) where the melt fractionaccumulated. Leucocratic diatexite still contained 5–15vol. % residual biotite (mg-number 40–44) and 10–20vol. % residual plagioclase (An22). Anatectic granite magmadeveloped from the leucodiatexite, first by further melt–residuumseparation, then through fractional crystallization. Most biotitein the anatectic granite is magmatic (mg-number 18–22). KEY WORDS: anatexis; diatexite; granite magma; melt segregation; migmatite  相似文献   

12.
This study uses field, petrographic and geochemical methods to estimate how much granitic melt was formed and extracted from a granulite facies terrane, and to determine what the grain‐ and outcrop‐scale melt‐flow paths were during the melt segregation process. The Ashuanipi subprovince, located in the north‐eastern Superior Province of Quebec, is a large (90 000 km2) metasedimentary terrane, in which > 85% of the metasediments are of metagreywacke composition, that was metamorphosed at mid‐crustal conditions (820–900 °C and 6–7 kbar) in a late Archean dextral, transpressive orogen. Decrease in modal biotite and quartz as orthopyroxene and plagioclase contents increase, together with preserved former melt textures indicate that anatexis was by the biotite dehydration reaction: biotite + quartz + plagioclase = melt + orthopyroxene + oxides. Using melt/orthopyroxene ratios for this reaction derived from experimental studies, the modal orthopyroxene contents indicate that the metagreywacke rocks underwent an average of 31 vol% partial melting. The metagreywackes are enriched in MgO, CaO and FeOt and depleted in SiO2, K2O, Rb, Cs, and U, have lower Rb/Sr, higher Rb/Cs and Th/U ratios and positive Eu anomalies compared to their likely protolith. These compositions are modelled by the extraction of between 20 and 40 wt %, granitic melt from typical Archean low‐grade metagreywackes. A simple mass balance indicates that about 640 000 km3 of granitic melt was extracted from the depleted granulites. The distribution of relict melt at thin section‐ and outcrop‐scales indicates that in layers without leucosomes melt extraction occurred by a pervasive grain boundary (porous) flow from the site of melting, across the layers and into bedding planes between adjacent layers. In other rocks pervasive grain boundary flow of melt occurred along the layers for a few, to tens of centimetres followed by channelled flow of melt in a network of short interconnected and structurally controlled conduits, visible as the net‐like array of leucosomes in some outcrops. The leucosomes contain very little residual material (< 5% biotite + orthopyroxene) indicating that the melt fraction was well separated from the residuum left in situ as melt‐depleted granulite. Only 1–3 vol percentage melt remained in the melt‐depleted granulites, hence, the extraction of melt generated by biotite dehydration melting in these granulites, was virtually complete under conditions of natural melting and strain rates in a contractional orogen.  相似文献   

13.
The grain‐scale spatial arrangement of melt in layer‐parallel leucosomes in two anatectic rocks from two different contact aureoles located in central Maine, USA, is documented and used to constrain the controls on grain‐scale melt localization. The spatial distribution of grain‐scale melt is inferred from microstructural criteria for recognition of mineral pseudomorphs after melt and mineral grains of the solid matrix that hosted the melt. In both rocks, feldspar mimics the grain‐scale distribution of melt, and quartz is the major constituent of the solid matrix. The feldspar pockets consist of individual feldspar grains or aggregates of feldspar grains that show cuspate outlines. They have low average width/length ratios (0.54 and 0.55, respectively), and are interstitial between more rounded and equant (width/length ratios 0.65 for both samples) quartz grains. In two dimensions, the feldspar pockets extend over distances equivalent to multiple quartz grain diameters, possibly forming a connected three‐dimensional intergranular network. Both samples show similar mesoscopic structural elements and in both samples the feldspar pockets have a shape‐preferred orientation. In one sample, feldspar inferred to replace melt is aligned subparallel to the shape‐preferred orientation of quartz, indicating that pre‐ or syn‐anatectic strain controlled the grain‐scale distribution of melt. In the other sample, the preferred orientation of feldspar inferred to replace melt is different from the orientations of all other mesoscopic or microscopic structures in the rock, indicating that differential stress controlled grain‐scale melt localization. This is probably facilitated by conditions of higher differential stress, which may have promoted microfracturing. Grain‐scale melt distribution and inferred melt localization controls give insight into possible grain‐scale deformation mechanisms in melt‐bearing rocks. Application of these results to the interpretation of deep crustal anatectic rocks suggests that grain‐scale melt distribution should be controlled primarily by pre‐ or syn‐anatectic deformation. Feedback relations between melt localization and deformation are to be expected, with important implications for deformation and tectonic evolution of melt‐bearing rocks.  相似文献   

14.
Migmatites from Cone Peak, California, USA and the Satnur-Sangam road, Southern Karnataka, India contain coarser grained orthopyroxene-bearing leucosomes with subordinate biotite in finer grained hornblende-biotite-pyroxene-bearing hosts. At both localities the leucosomes are enriched in quartz and feldspar and have a higher ratio of pyroxene to hornblende + biotite compared to the host rocks. Biotite grains in leucosomes along the Satnur-Sangam road are concentrated at the margins of orthopyroxene grains and have lower abundances of Ti, Fe, and Cl and a higher abundance of F than biotite grains from the host rock. Fluorapatite grains in all rocks from both localities contain monazite inclusions similar to those produced experimentally by metasomatically induced dissolution and reprecipitation. Some fluorapatite grains at both localities are partially rimmed by allanite. The only compositional differences found between fluorapatite grains in the leucosomes and host rocks were higher concentrations of Cl in grains in leucosomes from Cone Peak. The mineralogies of the rocks suggest that the leucosomes formed by dehydration melting reactions that consumed feldspar, quartz, hornblende, and biotite and produced orthopyroxene. Allanite rims at the margins of fluorapatite grains may have formed by the later retrogression of monazite rims formed by incongruent dissolution of fluorapatite in the melt. Biotite grains at the margins of orthopyroxene crystals in the leucosomes from the Satnur-Sangam road apparently formed by retrogression of orthopyroxene upon the solidification of the anatectic melt. A similar high-grade retrogression did not affect orthopyroxene crystals at Cone Peak, indicating that H2O was removed from the crystallizing leucosomes probably in a low H2O activity fluid. Compositional differences between the paleosome and neosomes at Cone Peak are best explained by metasomatic interaction with concentrated brines while elevated Cl concentrations in fluorapatites in the leucosome suggest interaction with a Cl-bearing fluid. Brines may have been responsible for an exchange of elements between the host rock along the Satnur-Sangam road and zones of melt generation now marked by leucosomes, but fluid flow appears to have been less vigorous than at Cone Peak.  相似文献   

15.
Contact aureoles of the anorthositic to granitic plutons of the Mesoproterozoic Nain Plutonic Suite (NPS), Labrador, are particularly well developed in the Palaeoproterozoic granulite facies, metasedimentary, Tasiuyak gneiss. Granulite facies regional metamorphism (MR), c. 1860 Ma, led to biotite dehydration melting of the paragneiss and melt migration, leaving behind biotite‐poor, garnet–sillimanite‐bearing quartzofeldspathic rocks. Subsequently, Tasiuyak gneiss within a c. 1320 Ma contact aureole of the NPS was statically subjected to lower pressure, but higher temperature conditions (MC), leading to a second partial melting event, and the generation of complex mineral assemblages and microstructures, which were controlled to a large extent by the textures of the MR assemblage. This control is clearly seen in scanning electron microscopic images of thin sections and is further supported by phase equilibria modelling. Samples collected within the contact aureole near Anaktalik Brook, west of Nain, Labrador, mainly consist of spinel–cordierite and orthopyroxene–cordierite (or plagioclase) pseudomorphs after MR sillimanite and garnet, respectively, within a quartzofeldspathic matrix. In addition, some samples contain fine‐grained intergrowths of K‐feldspar–quartz–cordierite–orthopyroxene inferred to be pseudomorphs after osumulite. Microstructural evidence of the former melt includes (i) coarse‐grained K‐feldspar–quartz–cordierite–orthopyroxene domains that locally cut the rock fabric and are inferred to represent neosome; (ii) very fine‐ to medium‐grained cordierite–quartz intergrowths interpreted to have formed by a reaction involving dissolution of biotite and feldspar in melt; and (iii) fine‐scale interstitial pools or micro‐cracks filled by feldspar interpreted to have crystallized from melt. Ultrahigh temperature (UHT) conditions during contact metamorphism are supported by (i) solidus temperatures >900 °C estimated for all samples, coupled with extensive textural evidence for contact‐related partial melting; (ii) the inferred (former) presence of osumilite; and (iii) titanium‐in‐quartz thermometry indicating temperatures within error of 900 °C. The UHT environment in which these unusual textures and minerals were developed was likely a consequence of the superposition of more than one contact metamorphic event upon the already relatively anhydrous Tasiuyak gneiss.  相似文献   

16.
CO2–CH4 fluid inclusions are present in anatectic layer-parallel leucosomes from graphite-bearing metasedimentary rocks in the Skagit migmatite complex, North Cascades, Washington. Petrological evidence and additional fluid inclusion observations indicate, however, that the Skagit Gneiss was infiltrated by a water-rich fluid during high-temperature metamorphism and migmatization. CO2-rich fluid inclusions have not been observed in Skagit metasedimentary mesosomes or melanosomes, meta-igneous migmatites, or unmigmatized rocks, and are absent from subsolidus leucosomes in metasedimentary migmatites. The observation that CO2-rich inclusions are present only in leucosomes interpreted to be anatectic based on independent mineralogical and chemical criteria suggests that their formation is related to migmatization by partial melting. Although some post-entrapment modification of fluid inclusion composition may have occurred during decompression and deformation, the generation of the CO2-rich fluid is attributed to water-saturated partial melting of graphitic metasedimentary rocks by a reaction such as biotite + plagioclase + quartz + graphite ± Al2SiO5+ water-rich fluid = garnet + melt + CO2–CH4. The presence of CO2-rich fluid inclusions in leucosomes may therefore be an indication that these leucosomes formed by anatexis. Based on the inferences that (1) an influx of fluid triggered partial melting, and (2) some episodes of fluid inclusion trapping are related to migmatization by anatexis, it is concluded that a free fluid was present at some time during high-temperature metamorphism. The infiltrating fluid was a water-rich fluid that may have been derived from nearby crystallizing plutons. Because partial melting took place at pressures of at least 5 kbar, abundant free fluid may have been present in the crust during orogenesis at depths of at least 15 km.  相似文献   

17.
Considering physical segregation of melt from its residue, the chemical potentials of the components (oxides) are the same in both when segregation occurs. Then, as P–T conditions change, gradients in chemical potential are established between the melt‐rich domains and residue permitting diffusional interaction to occur. In particular, on cooling, the chemical potential of H2O becomes higher in the melt segregation than in the residue, particularly when biotite becomes stable in the residue assemblage. Diffusion of water from the melt to the residue promotes crystallization of anhydrous products from the melt and hydrous products in the residue. This diffusive process, when coupled with melt loss from the rocks subsequent to some degree of crystallization, can result in a significant degree of anhydrous leucosome being preserved in a migmatite with only minor retrogression of the residue. If H2O can diffuse between the melt segregation and all of the residue, then no apparent selvedge between the two will be observed. Alternatively, if H2O can diffuse between the melt segregation and only part of the residue, then a distinct selvedge may be produced. Diffusion of H2O into the residue may be in part responsible for the commonly anhydrous nature of leucosomes, especially in granulite facies migmatites. Diffusion of other relatively mobile species such as Na2O and K2O has a lesser effect on overall melt crystallization but can change the proportion of quartz, plagioclase and K‐feldspar in the resultant leucosome. The diffusion of H2O out of the melt results in the enhanced crystallization of the melt in the segregation and increases the amount of resulting anhydrous leucosome relative to the amount produced if melt crystallized in chemical isolation from the residue. For high residue:melt ratios, the proportion of resulting near‐anhydrous leucosome can approach that of the proportion of melt present at the onset of cooling with only minor loss of melt from a given segregation required. Crystallization of melt segregations via the diffusion of H2O out of them into the host may also play a major role in driving melt‐rich segregations across key rheological transitions that would allow the expulsion of remaining melt from the system.  相似文献   

18.
Partial melting has been shown to be an important mechanism for intracrustal differentiation and granite petrogenesis. However, a series of compositional differences between granitic melt from experiments and natural granites indicate that the processes of crustal differentiation are complex. To shed light on factors that control the processes of crustal differentiation, and then the compositions of granitic magma, a combined study of petrology and geochemistry was carried out for granites (in the forms of granitic veins and parautochthonous granite) from a granulite terrane in the Tongbai orogen, China. These granites are characterized by high SiO2 (>72 wt%) and low FeO and MgO (<4 wt%) with low Na2O/K2O ratios (<0.7). Minerals in these granites show variable microstructures and compositions. Phase equilibrium modelling using P–T pseudosections shows that neither anatectic melts nor fractionated melts match the compositions of the target granites, challenging the conventional paradigm that granites are the crystallized product of pure granitic melts. Based on the microstructural features of minerals in the granites, and a comparison of their compositions with crystallized minerals from anatectic melts and minerals in granulites, the minerals in these granitoids are considered to have three origins. The first is entrained garnets, which show comparable compositions with those in host granulites. The second is early crystallized mineral from melts, which include large plagioclase and K-feldspar (with high Ca contents) crystals as well as a part of biotite whose compositions can be reproduced by crystallization of the anatectic melts. The compositions of other minerals such as small grained plagioclase, K-feldspar and anorthoclase in the granites with low Ca contents are not well reconstructed, so they are considered as the third origin of crystallized products of fractionated melts. The results of mass balance calculation show that the compositions of these granites can be produced by mixing between different proportions of crystallized minerals and fractionated melts with variable amounts of entrained minerals. However, the calculated modal proportions of different crystallized minerals (plagioclase, K-feldspar, biotite and quartz) in the granites are significantly different from those predicted by melt crystallization modelling. Specifically, some rocks have lower modes of biotite and plagioclase, whereas others show lower K-feldspar modes than those produced by melt crystallization. This indicates that the crystallized minerals would be differentially separated from the primary magmas to form the evolved magmas that produce these granites. Therefore, the crystal entrainment and differential melt-crystal separation make important contributions to the composition of the target granites. Compared with leucogranites worldwide, the target granites show comparable compositions. As such, the leucogranites may form through the crystal fractionation of primary granitic magmas at different extents in addition to variable degrees of partial melting.  相似文献   

19.
In most of the rocks of the Fuping Complex in the Trans-North China Orogen, a large quantity of leucocratic veins, dykes and granitic intrusions are present as migmatites. The incongruent partial melting of biotite to hornblende suggests the water-fluxed anatexis of the migmatization of which the melt is manifested by the euhedral crystallization of some quartzofeldspathic minerals and presence of albite rim on earlier plagioclase or K-feldspar. Importantly, some melt may be segregated in the sillimanite gneisses or extracted and injected as faint dispersed melt into the competent metasedimentary quartzite of the Wanzi series rocks. The quartzite has plenty of zircon ages cluster at c 2.5 Ga and some at c 2.1–2.0 Ga, the former may be detrital zircon age, while the latter represents the age of migmatization or crystallization of the injected melt, not detrital zircon ages as conventionally believed. The data have constrained that the sedimentation time of the protolith of the quartzite of the Wanzi series was between c 2.5 Ga and c 2.1–2.0 Ga, not younger than c 2.1–2.0 Ga as once proposed. Therefore it must be cautious in applying detrital zircon ages in constraining the time of sedimentation if the rocks have undergone middle-high grade metamorphism, especially when migmatization was involved in the metamorphism process.  相似文献   

20.
Melt infiltration into quartzite took place due to generation and migration of partial melts within the high‐grade metamorphic rocks of the Big Cottonwood (BC) formation in the Little Cottonwood contact aureole (UT, USA). Melt was produced by muscovite and biotite dehydration melting reactions in the BC formation, which contains pelite and quartzite interlayered on a centimetre to decimetre scale. In the migmatite zone, melt extraction from the pelites resulted in restitic schollen surrounded by K‐feldspar‐enriched quartzite. Melt accumulation occurred in extensional or transpressional domains such as boudin necks, veins and ductile shear zones, during intrusion‐related deformation in the contact aureole. The transition between the quartzofeldspathic segregations and quartzite shows a gradual change in texture. Here, thin K‐feldspar rims surround single, round quartz grains. The textures are interpreted as melt infiltration texture. Pervasive melt infiltration into the quartzite induced widening of the quartz–quartz grain boundaries, and led to progressive isolation of quartz grains. First as clusters of grains, and with increasing infiltration as single quartz grains in the K‐feldspar‐rich matrix of the melt segregation. A 3D–μCT reconstruction showed that melt formed an interconnected network in the quartzites. Despite abundant macroscopic evidence for deformation in the migmatite zone, individual quartz grains found in quartzofeldspathic segregations have a rounded crystal shape and lack quartz crystallographic orientation, as documented with electron backscatter diffraction (EBSD). Water‐rich melts, similar to pegmatitic melts documented in this field study, were able to infiltrate the quartz network and disaggregate grain coherency of the quartzites. The proposed mechanism can serve as a model to explain abundant xenocrysts found in magmatic systems.  相似文献   

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