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闽西北中生代花岗岩总体上可分为重熔型和同熔型两种类型。根据研究区两种类型花岗岩产出构造部位，成岩物质来源以及成矿元素本身地球化学属性之间的差异；结合岩矿石多元素统计分析，岩石稀土元素特征及其配分型式，单矿物微量元素比值，铅同位素、氢氧同位素特征等，较系统地阐述了闽西北地区重熔、同熔型花岗岩类的成矿特点。 相似文献
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广西大容山——十万大山岩带紫苏辉石堇青石花岗岩套矿物学研究 总被引：3，自引：1，他引：3
大容山－－十万大山岩带中的紫苏辉石堇青石花岗岩套位于桂东南海西－－印支褶皱带，富含堇青石、紫苏辉石、石榴石、矽线石、红柱石、刚玉等。矿物组合复杂，成因多样，可划分为岩浆结晶成因、变质残留成因和反应成因３种类型。根据各类岩石中矿物的特征分析，认为岩套中的花岗岩类岩石部分来源于深熔花岗岩奖的源岩不熔残余，另一部分来自围岩捕虏体变质后又被熔浆改造的不熔残余，是由区域变质岩经不同温压条件，不同深度熔作用形 相似文献
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钨矿的稀土元素地球化学可以反映成矿作用的条件和过程,为矿床成因提供有效的信息。中国钨矿床稀土元素地球化学的研究硕果累累,从单矿种角度进行全国性的系统总结十分必要。本文统计了1990年至2016年间不同类型钨矿床钨矿石矿物及与成矿有关岩体的稀土元素300多组数据。通过总结可知,不同类型钨矿床钨矿石矿物及与成矿有关花岗岩中稀土元素的总量和稀土配分曲线不同,这与成矿原始物质及成矿时物理化学条件的不同有关。不同类型钨矿床大部分具有Eu负异常的特征,显示成矿条件为较高温的还原环境;黑钨矿及其成矿岩体的稀土分配模式之间存在一定的依从关系,但是,黑钨矿中的稀土元素并没有随着岩浆-流体的结晶分异而富集。 相似文献
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福建潘田铁矿床花岗岩岩石地球化学特征、锆石U-Pb年代学及其与成矿的关系 总被引：4，自引：0，他引：4
潘田铁矿床矿体主要赋存于潘田花岗岩体外接触带的“硅钙岩性界面”中,其成矿与花岗岩侵入关系密切,是一个具有很大找矿潜力的富铁矿床。但前人对该花岗岩的研究还很薄弱,本文对潘田铁矿花岗岩进行了岩石地球化学特征、锆石U-Pb定年研究,探讨其岩石成因、形成时代、构造环境、及其与成矿的关系。LA-ICP-MS锆石U-Pb定年获得其结晶年龄为131.68±0.48Ma。该岩体为高钾钙碱性系列,属弱过铝质-准铝质岩石;稀土元素总量较低,轻稀土相对于重稀土富集,具有明显铕负异常,重稀土配分模式相对平坦,中稀土相对亏损。微量元素中相对富集大离子亲石元素而亏损高场强元素。岩石地球化学特征表明潘田岩体为高分异I型花岗岩,形成于碰撞后拉张环境。潘田铁矿床矿体与花岗岩体的空间分布规律与成因关系表明,花岗岩侵入作用是控制主成矿阶段矿体空间定位的地质作用,花岗岩是铁矿床的成矿地质体,林地组碎屑岩与黄龙组-栖霞组碳酸盐岩的接触界面是成矿有利部位,矿床类型属于典型“硅钙岩性界面”成矿,本矿床的成因类型属于“多因耦合、临界转换、边界成矿”的典型案例。 相似文献
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华北板块北缘东段早前寒武纪稀土元素演化特征 总被引：1，自引：0，他引：1
通过对区内早太古宙深变质地体、晚太古宙花岗岩-绿岩地体,晚太古-早元古宙优地槽和火山岛弧各类变质岩稀土元素的研究,三个时期的稀土元素具大致相似的演化特征,不同时期相同的岩石类型的稀土配分型式也大致相似,反映了它们有着相同源岩。但是,它们又在稀土丰度、Eu异常和轻、重稀土分离程度方面表现出某些差异,表明本区在早前寒武纪的不同时期、不同构造环境中地壳成分的不均一性。不同岩石类型稀土配分的多样性,说明岩浆源不同,至少有超镁铁质、镁铁质和安山质或英云闪长岩-奥长花岗岩三种岩浆源。 相似文献
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为了探讨横贯南极山脉休斯陡崖花岗质岩体的岩石成因,对其开展了岩相学和岩石化学分析。结果表明,休斯陡崖岩体主体岩石为二长花岗岩,后期被细粒二长花岗岩岩脉侵入。二者都具有高硅、富碱和高钾特征,里特曼指数小于3,岩石铝饱和指数(A/CNK)值小于1;微量元素原始地幔标准化分布型式具有Rb、Th、U和K元素富集,Nb、Ta、Nd和Ti等元素亏损特征;稀土元素总量偏低,轻稀土富集。主期二长花岗岩的稀土元素球粒陨石标准化分布型式具有轻微的负Eu异常,而岩脉具有正的Eu异常。休斯陡崖岩体的岩石类型为钙碱性准铝质I型花岗岩,源区为下陆壳,并伴有幔源物质的混入。在源区,岩浆发生了不同程度的斜长石、钛铁矿、金红石和磷灰石的分离结晶作用,其形成的构造环境为与俯冲作用有关的火山岛弧环境。 相似文献
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新疆东准噶尔黄羊山碱性花岗岩体的锆石U-Pb年龄和岩石成因 总被引：17，自引：0，他引：17
新疆东准噶尔卡拉麦里构造带分布有多种类型花岗岩,主要包括花岗闪长岩、二长花岗岩、碱长花岗岩和碱性花岗岩.对其中最大的碱性花岗岩体(黄羊山岩体)进行定年和地球化学组成研究,结果显示,岩体的年龄约为305 Ma,岩石富含钠质角闪石(钠闪石、钠铁闪石)和少量霓石,具低铝、富碱、贫钙镁及低铁的主量元素特征,其微量元素明显富集Rb、Th等大离子亲石元素和Zr、Hf等高场强元素而强烈亏损元素Ba、Sr、Eu,稀土元素配分模式呈典型的平坦‘V'字型.这些矿物学和地球化学组成特征表明黄羊山碱性花岗岩属于典型的A型花岗岩.认为幔源岩浆高度分异、麻粒岩相残留岩及I型英云闪长质-花岗闪长质岩石部分熔融等A型花岗岩成岩模式不能解释黄羊山碱性花岗岩的成因.根据岩石的εNd(t)= 5.9～ 6.5,比当时洋壳的εNd(t)值低3～4个ε单位,认为形成该岩体的岩浆可能来源于花岗闪长质岩浆的分异结晶,而花岗闪长质岩浆则主要是玄武质洋壳和少量大洋沉积物(约5%)部分熔融的产物. 相似文献
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Apatite as an indicator mineral for mineral exploration: trace-element compositions and their relationship to host rock type 总被引：7，自引：0，他引：7
E. A. Belousova W. L. Griffin Suzanne Y. O'Reilly N. I. Fisher 《Journal of Geochemical Exploration》2002,76(1):1056
Over 700 apatite grains from a range of rock types have been analysed by laser-ablation microprobe ICPMS for 28 trace elements, to investigate the potential usefulness of apatite as an indicator mineral in mineral exploration. Apatites derived from different rock types have distinctive absolute and relative abundances of many trace elements (including rare-earth elements (REE), Sr, Y, Mn, Th), and chondrite-normalised trace-element patterns. The slope of chondrite-normalised REE patterns varies systematically from ultramafic through mafic/intermediate to highly fractionated granitoid rock types. (Ce/Yb)cn is very high in apatites from carbonatites and mantle-derived lherzolites (over 100 and over 200, respectively), while (Ce/Yb)cn values in apatites from granitic pegmatites are generally less than 1, reflecting both HREE enrichment and LREE depletion. Within a large suite of apatites from granitoid rocks, chemical composition is closely related to both the degree of fractionation and the oxidation state of the magma, two important parameters in determining the mineral potential of the magmatic system. Apatite can accept high levels of transition and chalcophile elements and As, making it feasible to recognise apatite associated with specific types of mineralisation. Multivariate statistical analysis has provided a user-friendly scheme to distinguish apatites from different rock types, based on contents of Sr, Y, Mn and total REE, the degree of LREE enrichment and the size of the Eu anomaly. The scheme can be used for the recognition of apatites from specific rock types or styles of mineralisation, so that the provenance of apatite grains in heavy mineral concentrates can be determined and used in geochemical exploration. 相似文献
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The Southern Cross Province in the Archean Yilgarn Block of Western Australia comprises large dome-shaped granitoid bodies surrounded by narrow greenstone belts. Determination of the emplacement mechanism of these domes is fundamental for understanding the tectonic history of this region. Many structures in the greenstone belts show trends which reflect their tectonic relationships with the granitoid domes. Some of these structures host large gold occurrences. The domes have concentric foliation patterns, both within the granitoids themselves, and in the neighbouring greenstone belts. The smaller domes only have radial mineral lineation patterns in their wall rocks, but the largest dome, the Ghooli Dome, has also a tangential pattern. The prevailing gentle dip of the foliation in the centre of this dome and the abundance of greenstone xenoliths suggest that the present exposures are close to its roof. Geothermometry and geobarometry on mineral assemblages in the Ghooli granitoid and its xenoliths show that its crystallisation temperature was just above 700 °C at a relatively high pressure of 4.3 to 6.2 kbar. These P-T conditions are higher than those inferred for peak metamorphism in the greenstones. Therefore, this granitoid must have been emplaced initially at crustal levels deeper than the maximum burial of the greenstones which flank the dome. The Ghooli Dome has a SHRIMP U-Pb zircon age of 2691 ± 7 Ma. Diapiric rise of the granitoid plutons taking place in a regional compressive tectonic regime is considered to be the most likely mechanism for the final emplacement of these bodies into their host rock at about 2636–2620 Ma. This concept is preferred over the alternatives because it best reconciles the calculated P-T data, the observed structural patterns, the presence of pegmatites and aplites in the host rock, and the orientation of the mineral-bearing structures. 相似文献
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为研究兴蒙造山带-华北克拉通地球化学走廊带区域地球化学组成及其横向空间变化,统计分析不同地理单元和五万图幅单元的REE含量并绘制其空间分布折线图.内蒙古半干旱草原土壤中稀土含量较低,与其草原沙土的粘土矿物较少有关;江苏北部冲积平原区的土壤中稀土含量较高,与降雨量存在良好空间对应关系.内蒙古红格尔到河北张家口,土壤与岩石∑REE的比值绝大多数小于1,REE发生贫化;山东章丘到江苏连云港,比值基本大于1,REE发生富集.华北克拉通内蒙地块土壤稀土特征与兴蒙造山带相似,可能受其草原沙土景观的影响.在不同构造单元之间,LREE与HREE亏损与富集的空间分布存在细微差异.结果表明:地理景观,特别是黏土矿物是影响土壤REE含量的重要因素,降雨量与REE存在良好空间对应关系,REE自身的地球化学性质的差异在土壤形成过程中对轻重稀土元素分异具有重要影响. 相似文献
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岩体的生长方式可概括为中心式、偏心式、侧向式、不规则式、中心多点式。它们可提供反演区域构造动力学特点的信息。非极性生长可能暗示,在岩浆生成与上升定位的有限的时、空间范围内,上下圈层之间相对运动不大;有规律的极性生长很可能揭示了上下圈层之间有相对运移。秦岭造山带核部某些晋宁期H 型花岗岩体具南北向极性生长特点,反映了构造块体垂直造山带方向的运动特点;加里东-海西期很多H 型花岗岩体生长呈侵位中心东移的极性生长,揭示了秦岭杂岩平行造山带的侧向运移及剪刀状双向俯冲的板块构造动力学特点。 相似文献
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REE示踪沉积物物源研究进展 总被引：101，自引：0，他引：101
ＲＥＥ作为一种重要的沉积物物源示踪剂运用很广。在介绍了ＲＥＥ性质的基础上，对海水、河水、沉积岩、河流及边缘海沉积物中的ＲＥＥ元素丰度与配分模式特征进行了深入综述，概述了影响和控制ＲＥＥ丰度、模式及分馏特征的主要因素；论述了ＲＥＥ的物泊示踪意义以及在国内外应用情况与存在问题：源岩风化对ＲＥＥ分馏的影响；颗粒运及沉积时水动力分选对ＲＥＥ分馏可能造成的影响，即不同粒级中的ＲＥＥ不同的丰度与配分模式和碎屑 相似文献
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M. F. J. Flower 《Contributions to Mineralogy and Petrology》1971,31(4):335-346
Lavas and included xenoliths from the Comores Archipelago have been analysed for the rare earth elements (REE) La-Lu. Among basaltic lava types fractionation of REE rock/chondrite distribution patterns is more extreme with greater SiO2 undersaturation and contents of incompatible elements. Enrichment and slight fractionation of REE in the rock series basanite-phonolite is considered compatible with a model of fractional crystallisation at low pressures involving mainly olivine and clinopyroxene, and to a much lesser extent, plagioclase. Apatite is probably effective in curtailing further enrichment of REE. High level fractional crystallisation and eclogite fractionation at depth appear unlikely causes for the relative enrichment of light REE (La-Eu) in the undersaturated basalts. This effect is more probably due to mineralogical control during partial melting in the upper mantle. Lherzolite xenoliths are poor in REE, exhibiting a slight relative depletion in the light REE. These patterns are interpreted as those of possible mantle material subjected to small degrees of partial melting, although not necessarily related to those melts erupted as lava flows at the surface. 相似文献
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岩体的生长方式可概括为中心式、偏心式、侧向式、不规则式、中心多点式。它们可提供反演区域构造动力学特点的信息。非极性生长可能暗示,在岩浆生成与上升定位的有限的时、空间范围内,上下圈层之间相对运动不大;有规律的极性生长很可能揭示了上下圈层之间有相对运移。秦岭造山带核部某些晋宁期H 型花岗岩体具南北向极性生长特点,反映了构造块体垂直造山带方向的运动特点;加里东-海西期很多H 型花岗岩体生长呈侵位中心东移的极性生长,揭示了秦岭杂岩平行造山带的侧向运移及剪刀状双向俯冲的板块构造动力学特点。 相似文献
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A pilot study with Holocene fluvial sands was undertaken in order to evaluate the effects of source rock composition and climate on natural abundances of rare elements (REE) in the first leg of the sedimentary cycle. We have analysed the medium grained sand fraction of samples collected from first order streams exclusively draining granitic plutons in Montana (semi-arid), Georgia (humid), and in South Carolina (humid). Despite compositional differences between parent plutons the REE distribution patterns (but not the total absolute abundances) of the daughter sands are very similar. Averages of the three areas have a La/Lu ratio of ～ 103 showing a depletion of heavy REE with respect to an ‘average granite’ (La/Lu = 79) or the composite of North American Shales (NAS; La/Lu = 55). Also, the Eu/Sm ratio in sands from these areas is ～ 0·22 which is very close to the NAS ratio of 0·21. However, the overall REE distribution of these sands is not similar to that of NAS in any way. We conclude that the major rock type, but neither its minor subdivisions nor the climate (in the source area), controls the REE distribution patterns in first cycle daughter sands. But, the total and the parent rock-normalized abundances of REE in sands from the humid areas are much lower than those in sands from the arid areas. 相似文献
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We present new geochemical data on alkali and nepheline syenites from various complexes of different age within the Ukrainian Shield. The results reveal a correlation between the content of trace elements in the syenites, their assignment to a particular rock complex, the chemistry of primary melts, and the degree of their differentiation. The data also suggest regional geochemical heterogeneity in the ultramafic-alkaline complexes of the Ukrainian Shield. The alkali and nepheline syenites in the ultramafic-alkaline massifs from the eastern and western parts of the region exhibit similar REE contents and Eu/Eu* ratios but are markedly different in Nb, Ta, Zr, and Hf content and are of the miaskitic type. These rocks have lower REE, Nb, and Zr and higher Sr and Ba compared with early foidolites. The rocks of the gabbro-syenite complexes define a distinct Fe-enrichment fractionation trend from early syenitic intrusions to more differentiated varieties; they are also characterized by lower Sr, Ba, and Eu/Eu* and significantly lower contents of some major elements, e.g., Ti, Mg, and P. The agpaitic index and concentrations of Zr, Nb, Y, and REE increase in the same direction. A similar geochemical feature is observed in the alkali syenites genetically associated with anorthositerapakivi-granite plutons, which show incompatible-element enrichment and strong depletion in Sr and Ba. The distinctive evolutionary trends of alkali and nepheline syenites from different rock complexes of the Ukrainian Shield can be explained by different mechanisms of their formation. The main petrogenetic mechanism controlling the distribution of trace elements in the rocks of ultramafic-alkaline complexes was the separation of parent melts of melanephelinite and melilitite types into immiscible phonolite and carbonatite liquids. The gabbro-syenite complexes and alkali syenites from anorthosite-rapakivi granite plutons evolved via crystallization differentiation, which involved extensive feldspar fractionation. 相似文献
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龙脖河铜矿床位于滇中地区红河成矿带南段,矿区火山岩发育、与铜矿化时空密切共生。区内火山岩遭受了不同程度的蚀变或区域变质作用,根据矿物组合可分为变安山岩、变次火山岩和变基性火山岩。三类变火山岩均相对富Na,在地球化学分类图解上样品主要位于碱性玄武岩区域。除个别微量元素外,三类岩石的微量元素含量相近,与各种构造环境玄武岩相比,本区变火山岩富集HFSE(Th、Nb等)、亏损LILE(Sr、Ba等),微量元素配分模式出现明显Th、Nb正异常和Sr、Ba负异常。三类岩石的REE含量范围相互重叠,除Eu异常外,其REE配分模式均为相似的LREE富集型。各种地球化学证据表明,本区三类变火山岩为同源岩浆不同演化阶段的产物,其原始岩浆为大陆板内拉张构造环境交代富集地幔部分熔融的产物,结晶分异作用在岩浆演化过程中具有重要地位。 相似文献