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1.
One pre-requisite for the construction of a global chromium isotope mass balance is detailed understanding of Cr isotope systematics in the critical zone where redox-processes can modify the isotope signature of geogenic Cr input into the hydrosphere. A Cr isotope inventory of bedrock, soil, and runoff was performed in a Central European headwater catchment underlain by amphibolite, situated in the vicinity of two previously studied catchments underlain by different bedrock types (serpentinite and leucogranite). Fresh bedrock in the amphibolite catchment NAZ contained ~300 mg/kg Cr, serpentinite at PLB contained ~800 mg/kg Cr, and leucogranite at LYS contained ~2 mg/kg Cr. Monthly hydrochemical monitoring at all three sites revealed higher Cr(VI) export fluxes in winter than in summer. NAZ was characterized by a distinct seasonality in the δ53Cr values, with minima during winter/spring snowmelts (−0.35‰) and maxima during dry summers (0.40‰). Similar seasonality in δ53Cr values had been reported from PLB and LYS. Bedrock at all three sites had similar Cr isotope composition close to −0.10‰, a value indistinguishable from the δ53Cr value of bulk silicate Earth (BSE). Positive mean δ53Cr value of NAZ runoff indicated Cr-isotope fractionations during weathering of geogenic Cr(III), combined with adsorption of the resulting Cr(VI) on soil particles during pedogenesis. However, the mass-weighted mean δ53Cr of NAZ runoff was lower (−0.08‰), indistinguishable from the Cr isotope signature of bedrock. The same pattern of lower mass-weighted mean δ53Cr values of runoff, compared to arithmetic mean δ53Cr values of runoff, were observed also at PLB and LYS. We suggest that elevated Cr runoff fluxes in winter remove some of the residual isotopically light Cr that accumulated in the soil during summer. Seasonality in runoff δ53Cr values appears to be a relatively widespread phenomenon, de-coupled from Cr availability for chemical weathering.  相似文献   

2.
Concerns related to climate change have resulted in an increasing interest in the importance of hydrological events such as droughts in affecting biogeochemical responses of watersheds. The effects of an unusually dry summer in 2002 had a marked impact on the biogeochemistry of three watersheds in the north‐eastern USA. Chemical, isotopic and hydrological responses with particular emphasis on S dynamics were evaluated for Archer Creek (New York), Sleepers River (Vermont) and Cone Pond (New Hampshire) watersheds. From 1 August to 14 September 2002, all three watersheds had very low precipitation (48 to 69 mm) resulting in either very low or no discharge (mean 0·015, 0·15 and 0·000 mm day?1 for Archer Creek, Sleepers River and Cone Pond, respectively). From 15 September to 31 October 2002, there was a substantial increase in precipitation totals (212, 246 and 198 mm, respectively) with increased discharge. Archer Creek was characterized by a large range of SO42? concentrations (152 to 389 µeq L?1, mean = 273 µeq L?1) and also exhibited the greatest range in δ34S values of SO42? (?1·4 to 8·8 ‰ ). Sleepers River's SO42? concentrations ranged from 136 to 243 µeq L?1 (mean = 167 µeq L?1) and δ34S values of SO42? ranged from 4·0 to 9·0 ‰ . Cone Pond's SO42? concentrations (126–187 µeq L?1, mean = 154 µeq L?1) and δ34S values (2·4 to 4·3 ‰ ) had the smallest ranges of the three watersheds. The range and mean of δ18O‐SO42? values for Archer Creek and Cone Pond were similar (3·0 to 8·9 ‰ , mean = 4·5 ‰ ; 3·9 to 6·3 ‰ , mean = 4·9 ‰ ; respectively) while δ18O‐SO42? values for Sleepers River covered a larger range with a lower mean (1·2 to 10·0 ‰ , mean = 2·5). The difference in Sleepers River chemical and isotopic responses was attributed to weathering reactions contributing SO42?. For Archer Creek wetland areas containing previously reduced S compounds that were reoxidized to SO42? probably provided a substantial source of S. Cone Pond had limited internal S sources and less chemical or isotopic response to storms. Differences among the three watersheds in S biogeochemical responses during these storm events were attributed to differences in S mineral weathering contributions, hydrological pathways and landscape features. Further evaluations of differences and similarities in biogeochemical and hydrological responses among watersheds are needed to predict the impacts of climate change. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

3.
Spatial and temporal patterns of spring break‐up flooding in the Slave River Delta (SRD), Northwest Territories, are characterized during three years (2003–2005) using water isotope tracers and total inorganic suspended sediment (TSS) concentrations measured from lakewater samples collected shortly after the spring melt. Strongly contrasting spring melt periods led to a moderate flood in 2003, no flooding in 2004 and widespread flooding in 2005. Flooded lakes have isotopically‐depleted δ18O (δ2H) signatures, ranging between ? 19·2‰ (?145‰) and ? 17·1‰ (?146‰) and most have high TSS concentrations (>10 mg L?1), while non‐flooded lakes have more isotopically‐enriched δ18O (δ2H) signatures, ranging between ? 18·2‰ (?149‰) and ? 10·6‰ (?118‰) and low TSS concentrations (<10 mg L?1). These results, in conjunction with the isotopic signatures of Slave River water and snowmelt, are used to estimate the proportion of river‐ or snowmelt‐induced dilution in delta lakes during the spring of each study year. Calculations indicate river flooding caused dilution of ～70–100% in delta lakes, while snowmelt dilution in the absence of river flooding ranged from ～0–56%. A positive relationship exists between the spatial extent of spring flooding in the SRD and level and discharge on the Slave River and upstream tributaries, suggesting that upstream flow generation plays a key role in determining the magnitude of spring flooding in the SRD. Parallel variations in the 46‐year instrumental Slave River discharge record and flood stratigraphy in the active delta indicate that there is potential for extending the flood history of the SRD, a development that will contribute to a more robust understanding of the drivers of historic, contemporary and future flood frequency in the delta. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

4.
This paper presents the use of stable isotopes of water for hydrological characterization and flow component partitioning in the Red River Delta (RRD), the downstream section of the Red River. Water samples were collected monthly during 2015 from the mainstream section of the river and its right bank tributaries flowing through the RRD. In general, δ18O and δ2H river signatures were depleted in summer–autumn (May–October) and elevated in winter–spring (November–April), displaying seasonal variation in response to regional monsoon air mass contest. The Pacific equatorial–maritime air mass dominates in summer and the northern Asia continental air mass controls in winter. Results show that water of the RRD tributaries stems solely from local sources and is completely separated from water arriving from upstream subbasins. This separation is due to the extensive management of the RRD (e.g., dykes and dams) for the purposes of irrigation and inundation prevention. Mainstream river section δ18O and δ2H compositions range from ?10.58 and ?73.74‰ to ?6.80 and ?43.40‰, respectively, and the corresponding ranges inside the RRD were from ?9.35 and ?64.27‰ to ?2.09 and ?15.80‰. A combination of data analysis and hydrological simulation confirms the role of upstream hydropower reservoirs in retaining and mixing upstream water. River water inside the RRD experienced strong evaporation characterized by depleted d‐excess values, becoming negative in summer. On the other hand, the main stream of the Red River has d‐excess values around 10‰, indicating moderate evaporation. Hydrograph separation shows that in upstream subbasins, the groundwater fraction dominates the river flow composition, especially during low flow regimes. Inside the RRD, the river receives groundwater during the dry season, whereas groundwater replenishment occurs in the rainy season. Annual evaporation obtained from this hydrograph separation computation was about 6.3% of catchment discharge, the same order as deduced from the difference between subbasin precipitation and discharge values. This study shows the necessity to re‐evaluate empirical approaches in large river hydrology assessment schemes, especially in the context of climate change.  相似文献   

5.
Periodic summer hypoxia occurring in the Northern Gulf of Mexico has been attributed to large nutrient inputs, especially nitrate‐nitrogen, from the Mississippi–Atchafalaya River system. The 2008 Gulf Hypoxia Action Plan calls for river corridor wetland restoration to reduce nitrate loads, but it is largely unknown how effective riverine wetland systems in the lower Mississippi River are for nitrate removal. We carried out an intensive isotope study to address this question by comparing nitrate isotopic signatures of the well‐channelized Mississippi River with those of the Atchafalaya River, which has extensive floodplains and backwater swamps. We investigated changes in δ15NNO3 and δ18ONO3 for water samples collected biweekly to monthly over a 2‐year period at the Atchafalaya River outlets (Morgan City and Wax Lake) and on the Mississippi River at Baton Rouge. In addition, in situ water quality parameters including temperature, dissolved oxygen and pH were recorded for each sampling date. Waters from both rivers showed moderately high nitrate concentration (>1 mg l?1) and undetectable (< 0.01 mg l?1) nitrite throughout the study period. The Mississippi River had slightly, but significantly higher (p=0.01) mean nitrate concentrations (1.5 mg l?1) and higher δ15NNO3 (7.7‰) than the Atchafalaya (1.1 mg l?1, 7.0‰); while no difference in δ18ONO3 (4.6‰) was found between the rivers. Flux‐weighted mean isotope values were overall lower than mean values for both the Mississippi and Atchafalaya Rivers, with a greater difference between the two rivers (7.4‰ versus 6.5‰, respectively). River flooding and hurricane storm surge also appeared to affect nitrate isotopic values. The lack of large difference in isotopic values between the Atchafalaya and Mississippi Rivers suggests that the majority of nitrate is transported through the Atchafalaya River with relatively little processing, and that riverine floodplains and wetlands are not effective sinks for nitrate, as previously assumed, because of insufficient residence time and well‐oxygenated river waters. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

6.
ABSTRACT

In this study, we characterized the glacial meltwater flow through a proglacial area with a focus on proglacial lakes, their hydrological regime and their connection to the stream. The studied lakes – the Adygine ice-debris complex, northern Tien Shan – showed a distinct development throughout an ablation season: at Lake 2, the mean daily water-level fluctuation amplitude increased from 0.07 m to 0.18 m (June, August), then dropped to 0.07 m in September. Glacial meltwater flows through the lakes and further downstream through a rock glacier rather fast, moving at 0.085 m s?1. However, based on the low dye recovery in the stream (0.03%), only a small portion of water was routed efficiently. The complexity of the site’s drainage system was supported by varying isotopic composition of water in the tarns situated on the rock glacier, with Tarn a (δ2H: –36.08‰; δ18O: –6.25‰) being the most enriched and Tarn c (δ2H: 78.68‰; δ18O: 11.9‰) the most depleted in heavy isotopes.  相似文献   

7.
Gypsum and halite crystals, together with saponite and phillipsite, were found in a vein in a basalt sill 625 m below the sea floor at DSDP Site 395A, located 190 km west of the crest of the Mid-Atlantic Ridge. The δ34S value of the gypsum (+19.4‰) indicates a seawater source for the sulfate. The δ18O values of the saponite (+19.9‰) and phillipsite (+18.1‰) indicate either formation from normal seawater at about 55°C or formation from18O-depleted seawater at a lower temperature.The gypsum (which could be secondary after anhydrite) was formed by reaction between Ca2+ released from basalt and SO42? in circulating seawater. The halite could have formed when water was consumed by hydration of basalt under conditions of extremely restricted circulation. A more probable mechanism is that the gypsum was originally precipitated as anhydrite at temperatures above 60°C. As the temperature dropped the anhydrite converted to gypsum. The conversion would consume water, which could cause halite precipitation, and would cause an increase in the volume of solids, which would plug the vein and prevent subsequent dissolution of the halite.  相似文献   

8.
To investigate the origin and behaviour of nitrate in alluvial aquifers adjacent to Nakdong River, Korea, we chose two representative sites (Wolha and Yongdang) having similar land‐use characteristics but different geology. A total of 96 shallow groundwater samples were collected from irrigation and domestic wells tapping alluvial aquifers. About 63% of the samples analysed had nitrate concentrations that exceeded the Korean drinking water limit (44·3 mg l?1 NO3?), and about 35% of the samples had nitrate concentrations that exceeded the Korean groundwater quality standard for agricultural use (88·6 mg l?1 NO3?). Based on nitrogen isotope analysis, two major nitrate sources were identified: synthetic fertilizer (about 4‰ δ15N) applied to farmland, and animal manure and sewage (15–20‰ δ15N) originating from upstream residential areas. Shallow groundwater in the farmland generally had higher nitrate concentrations than those in residential areas, due to the influence of synthetic fertilizer. Nitrate concentrations at both study sites were highest near the water table and then progressively decreased with depth. Nitrate concentrations are also closely related to the geologic characteristics of the aquifer. In Yongdang, denitrification is important in regulating nitrate chemistry because of the availability of organic carbon from a silt layer (about 20 m thick) below a thin, sandy surface aquifer. In Wolha, however, conservative mixing between farmland‐recharged water and water coming from a village is suggested as the dominant process. Mixing ratios estimated based on the nitrate concentrations and the δ15N values indicate that water originating from the village affects the nitrate chemistry of the shallow groundwater underneath the farmland to a large extent. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

9.
Flooding associated with tropical storms can cause extreme perturbations in riverine and coastal ecosystems. Measuring isotope variability of tropical storm events can help investigate the impacts of flooding. We measured the water isotope composition (δD and δ18O) of rain and associated floodwater collected during two storms and subsequent major and minor flooding events in the subtropical coast of eastern Australia. Compared with baseline regional rainfall isotope values of ?15.0 ± 1.9‰ for δD and ?3.3 ± 0.2‰ for δ18O, floodwater had lower values with ?33.8 ± 2.5‰ δD and ?5.1 ± 0.4‰ δ18O for the major flood and ?29.4 ± 1.0‰ δD and ?4.6 ± 0.1‰ δ18O for the minor flood. The low isotope composition of the floodwater was associated with the transport of large quantities of suspended sediments, with sediment loads 30 to 70 times larger than during base flow conditions. Floods carried up to 35% of the annual phosphorus and up to 208% of the currently calculated average annual nitrogen load of the Brisbane River. The dramatic changes caused by a rapid increase in discharge from 2 to 2015 m3 s?1 over 2 days in the major flood would have major consequences in riverine and coastal ecosystems of the region. These changes could potentially be traced using the isotope composition of the floodwaters. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

10.
Data on temporal variability in Mg isotope ratios of atmospheric deposition and runoff are critical for decreasing the uncertainty associated with construction of isotope mass balances in headwater catchments, and statistical evaluation of isotope differences among Mg pools and fluxes. Such evaluations, in turn, are needed to distinguish between biotic and abiotic contributions to Mg2+ in catchment runoff. We report the first annual time-series of δ26Mg values simultaneously determined for rainfall, canopy throughfall, soil water and runoff. The studied 55-ha catchment, situated in western Czech Republic, is underlain by Mg-rich amphibolite and covered by mature spruce stands. Between 1970 and 1996, the site received extremely high amounts of acid deposition and fly ash form nearby coal-burning power plants. The δ26Mg values of open-area precipitation (median of −0.79‰) at our study site were statistically indistinguishable from the δ26Mg values of throughfall (−0.73‰), but significantly different from the δ26Mg values of soil water (−0.55‰) and runoff (−0.55‰). The range of δ26Mg values during the observation period decreased in the order: open-area precipitation (0.57‰) > throughfall (0.27‰) > runoff (0.21‰) > soil water (0.16‰). The decreasing variability in δ26Mg values of Mg2+ from precipitation to soil water and runoff reflected an increasing homogenization of atmospheric Mg in the catchment and its mixing with geogenic Mg. In addition to atmospheric Mg, runoff also contained Mg mobilized from the three major solid Mg pools, bedrock (δ26Mg of −0.32‰), soil (−0.28‰), and vegetation (−0.31‰). The drought of summer 2019 did not affect the nearly constant δ26Mg value of runoff. Collectively, our data show that within-catchment processes buffer the Mg isotope variability of the atmospheric input.  相似文献   

11.
Precisely dated high-resolution speleothems may record past typhoon events, however, the state of the art cave monitoring is a prerequisite to identify suitable stalagmites for the reconstruction of such events. With this motivation, we examined the isotopic composition (δ18O and d-excess values) of rainfall, outside river, cave drip water, and an underground river in the Xianyun cave system, located in southeastern China. Monthly to bi-monthly monitoring of environmental and isotopic conditions was conducted for 1 year, from December 2018 to December 2019, including a typhoon event (August 24, 2019 to August 26, 2019), called Bailu. The δ18O of rainfall samples over the cave and outside river water ranged from −9.7‰ to −1.9‰ and −8.2‰ to −6.3‰, respectively, while the δ18O of Typhoon Bailu rainfall and instantaneous outside river water ranged from −19.6‰ to −6.3‰ and −10.4‰ to −7.7‰, respectively. Typhoon Bailu-induced rainfall showed distinctly negative δ18O values as compared to those of the monthly and bi-monthly rainfall, exhibiting a three-stage inverted U-shaped variation characteristic. Four drip water monitoring sites inside the cave revealed low variations during the studied period with average values of −7.8‰, −8.0‰, −8.0‰, and −8.1‰. However, during the typhoon, the drip water δ18O values exhibited similar characteristic as outside rainfall but with just 0.2‰ negative deviation owing to precipitation amount and drip water source reservoir. The integration of rainfall amount with drip water source reservoir determines the degree to which a typhoon isotopic signature gets diluted during epikarst infiltration. This study provides the first instrumental evidence of typhoon signal in karst system in southeastern China. Our results imply that the δ18O of drip water in Xianyun cave can instantaneously respond to typhoon rainfall. However, the 0.2‰ shift in drip water δ18O is difficult to be recorded by speleothems. We suggest multi-year monitoring to ascertain fully if the stalagmites could be used as paleotyphoon proxy.  相似文献   

12.
This paper reports the first results on δ18O and δ2H analysis of precipitations, cave drip waters, and groundwaters from sites in Mallorca (Balearic Islands, western Mediterranean), a key region for paleoclimate studies. Understanding the isotopic variability and the sources of moisture in modern climate systems is required to develop speleothem isotope‐based climate reconstructions. The stable isotopic composition of precipitation was analysed in samples collected between March 2012 and March 2013. The values are in the range reported by GNIP Palma station. Based on these results, the local meteoric water line (LMWL) δ2H = 7.9 (±0.3) δ18O + 10.8 (±2.5) was derived, with slightly lower slope than Global Meteoric Water Line. The results help tracking two main sources of air masses affecting the study sites: rain events with the highest δ18O values (> ?5‰) originate over the Mediterranean Sea, whereas the more depleted samples (< ?8‰) are sourced in the North Atlantic region. The back trajectory analysis and deuterium excess values, ranging from 0.4 to 18.4‰, further support our findings. To assess the isotopic variation across the island, water samples from eight caves were collected. The δ18O values range between ?6.9 and ?1.6‰. With one exception (Artà), the isotopic composition of waters in caves located along the coast (Drac, Vallgornera, Cala Varques, Tancada, and Son Sant Martí) indicates Mediterranean‐sourced moisture masses. By contrast, the drip water δ18O values for inland caves (Campanet, ses Rates Pinyades) or developed under a thick (>50 m) limestone cap (Artà) exhibit more negative values. A well‐homogenized aquifer supplied by rainwaters of both origins is clearly indicated by groundwater δ18O values, which show to be within 2.4‰ of the unweighted arithmetic mean of ?7.4‰. Although limited, the isotopic data presented here constitute the baseline for future studies using speleothem δ18O records for western Mediterranean paleoclimate reconstructions. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

13.
The South Sandwich volcanic arc is sited on a young oceanic crust, erupts low-K tholeiitic rocks, is characterized by unexotic pelagic and volcanogenic sediments on the down-going slab, and simple tectonic setting, and is ideal for assessing element transport through subduction zones. As a means of quantifying processes attending transfer of subduction-related fluids from the slab to the mantle wedge, boron concentrations and isotopic compositions were determined for representative lavas from along the arc. The samples show variable fluid-mobile/fluid-immobile element ratios and high enrichments of B/Nb (2.7 to 55) and B/Zr (0.12 to 0.57), similar to those observed in western Pacific arcs. δ11B values are among the highest so far reported for mantle-derived lavas; these are highest in the central part of the arc (+ 15 to + 18‰) and decrease toward the southern and northern ends (+ 12 to + 14‰). δ11B is roughly positively correlated with B concentrations and with 87Sr/86Sr ratios, but poorly coupled with other fluid-mobile elements such as Rb, Ba, Sr and U. Peridotites dredged from the forearc trench also have high δ11B (ca. + 10‰) and elevated B contents (38–140 ppm). Incoming pelagic sediments sampled at ODP Site 701 display a wide range in δ11B (+ 5 to ? 13‰; average = ? 4.1‰), with negative values most common. The unusually high δ11B values inferred for the South Sandwich mantle wedge cannot easily be attributed to direct incorporation of subducting slab materials or fluids derived directly therefrom. Rather, the heavy B isotopic signature of the magma sources is more plausibly explained by ingress of fluids derived from subduction erosion of altered frontal arc mantle wedge materials similar to those in the Marianas forearc. We propose that multi-stage recycling of high-δ11B and high-B serpentinite (possibly embellished by arc crust and volcaniclastic sediments) can produce extremely 11B-rich fluids at slab depths beneath the volcanic arc. Infiltration of such fluids into the mantle wedge likely accounts for the unusual magma sources inferred for this arc.  相似文献   

14.
High-elevation mountains often constitute for basins important groundwater recharge sources through mountain-front recharge processes. These processes include streamflow losses and subsurface inflow from the mountain block. However, another key recharge process is from irrigation practices, where mountain streamflow is distributed across the irrigated piedmont. In this study, coupled groundwater fluctuation measurements and environmental tracers (18O, 2H, and major ions) were used to identify and compare the natural mountain-front recharge to the anthropogenically induced irrigation recharge. Within the High Atlas mountain front of the Ourika Basin, Central Morocco, the groundwater fluctuation mapping from the dry to wet season showed that recharge beneath the irrigated area was higher than the recharge along the streambed. Irrigation practices in the region divert more than 65% of the stream water, thereby reducing the potential for in-stream groundwater recharge. In addition, the irrigation areas close to the mountain front had greater water table increases (up to 3.5 m) compared with the downstream irrigation areas (<1 m increase). Upstream crops have priority to irrigation with stream water over downstream areas. The latter are only irrigated via stream water during large flood events and are otherwise supplemented by groundwater resources. These changes in water resources used for irrigation practices between upstream and downstream areas are reflected in the spatiotemporal evolution of the stable isotopes of groundwater. In the upstream irrigation area, the groundwater stable isotope values (δ18O: −8.4‰ to −7.4‰) reflect recharge by the diverted stream water. In the downstream irrigation area, the groundwater isotope values are lower (δ18O: −8.1‰ to −8.4‰) due to recharge via the flood water. In the nonirrigation area, the groundwater has the highest stable isotope values (δ18O: −6.8‰ to −4.8‰). This might be due to recharge via subsurface inflow from the mountain block to the mountain front and/or recharge via local low altitude rainfall. These findings highlight that irrigation practices can result in the dominant mountain-front recharge process for groundwater.  相似文献   

15.
Time series of hydrogen and oxygen stable isotope ratios (δ2H and δ18O) in rivers can be used to quantify groundwater contributions to streamflow, and timescales of catchment storage. However, these isotope hydrology techniques rely on distinct spatial or temporal patterns of δ2H and δ18O within the hydrologic cycle. In New Zealand, lack of understanding of spatial and temporal patterns of δ2H and δ18O of river water hinders development of regional and national-scale hydrological models. We measured δ2H and δ18O monthly, together with river flow rates at 58 locations across New Zealand over a two-year period. Results show: (a) general patterns of decreasing δ2H and δ18O with increasing latitude were altered by New Zealand's major mountain ranges; δ2H and δ18O were distinctly lower in rivers fed from higher elevation catchments, and in eastern rain-shadow areas of both islands; (b) river water δ2H and δ18O values were partly controlled by local catchment characteristics (catchment slope, PET, catchment elevation, and upstream lake area) that influence evaporation processes; (c) regional differences in evaporation caused the slope of the river water line (i.e., the relationship between δ2H and δ18O in river water) for the (warmer) North Island to be lower than that of the (cooler, mountain-dominated) South Island; (d) δ2H seasonal offsets (i.e., the difference between seasonal peak and mean values) for individual sites ranged from 0.50‰ to 5.07‰. Peak values of δ18O and δ2H were in late summer, but values peaked 1 month later at the South Island sites, likely due to greater snow-melt contributions to streamflow. Strong spatial differences in river water δ2H and δ18O caused by orographic rainfall effects and evaporation may inform studies of water mixing across landscapes. Generally distinct seasonal isotope cycles, despite the large catchment sizes of rivers studied, are encouraging for transit time analysis applications.  相似文献   

16.
Characterization of stable isotope compositions (δ2H and δ18O) of surface water and groundwater in a catchment is critical for refining moisture sources and establishing modern isotope–elevation relationships for paleoelevation reconstructions. There is no consensus on the moisture sources of precipitation in the Yellow River source region during summer season. This study presents δ2H and δ18O data from 111 water samples collected from tributaries, mainstream, lakes, and groundwater across the Yellow River source region during summertime. Measured δ18O values of the tributaries range from ?13.5‰ to ?5.8‰ with an average of ?11.0‰. Measured δ18O values of the groundwater samples range from ?12.7‰ to ?10.5‰ with an average of ?11.9‰. The δ18O data of tributary waters display a northward increase of 1.66‰ per degree latitude. The δ18O data and d‐excess values imply that moisture sources of the Yellow River source region during summertime are mainly from the mixing of the Indian Summer Monsoon and the Westerlies, local water recycling, and subcloud evaporation. Analysis of tributary δ18O data from the Yellow River source region and streamwater and precipitation δ18O data from its surrounding areas leads to a best‐fit second‐order polynomial relationship between δ18O and elevation over a 4,600 m elevation range. A δ18O elevation gradient of ?1.6‰/km is also established using these data, and the gradient is in consistence with the δ18O elevation gradient of north and eastern plateau. Such relationships can be used for paleoelevation reconstructions in the Yellow River source region.  相似文献   

17.
We characterize the precipitation and groundwater in a mountainous (peaks slightly above 3000 m a.s.l.), semi‐arid river basin in SE Spain in terms of the isotopes 18O and 2H. This basin, with an extension of about 7000 km2, is an ideal site for such a study because fronts from the Atlantic and the Mediterranean converge here. Much of the land is farmed and irrigated both by groundwater and runoff water collected in reservoirs. A total of approximately 100 water samples from precipitation and 300 from groundwater have been analysed. To sample precipitation we set up a network of 39 stations at different altitudes (800–1700 m a.s.l.), with which we were able to collect the rain and snowfall from 29 separate events between July 2005 and April 2007 and take monthly samples during the periods of maximum recharge of the aquifers. To characterize the groundwater we set up a control network of 43 points (23 springs and 20 wells) to sample every 3 months the main aquifers and both the thermal and non‐thermal groundwater. We also sampled two shallow‐water sites (a reservoir and a river). The isotope composition of the precipitation forms a local meteoric water line (LMWL) characterized by the equation δD = 7·72δ18O + 9·90, with mean values for δ18O and δD of − 10·28‰ and − 69·33‰, respectively, and 12·9‰ for the d‐excess value. To correlate the isotope composition of the rainfall water with groundwater we calculated the weighted local meteoric water line (WLMWL), characterized by the equation δD = 7·40δ18O + 7·24, which takes into account the quantity of water precipitated during each event. These values of (dδD/dδ18O)< 8 and d‐excess (δD–8δ18O)< 10 in each curve bear witness to the ‘amount effect’, an effect which is more manifest between May and September, when the ground temperature is higher. Other effects noted in the basin were those of altitude and the continental influence. The isotopic compositions of the groundwater are represented by the equation δD = 4·79δ18O − 18·64. The groundwater is richer in heavy isotopes than the rainfall, with mean values of − 8·48‰ for δ18O and − 59·27‰ for δD. The isotope enrichment processes detected include a higher rate of evaporation from detrital aquifers than from carbonate ones, the effects of recharging aquifers from irrigation return flow and/or from reservoirs' leakage and enrichment in δ18O from thermal water. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

18.
The direct H2Oliquid–H2Ovapour equilibration method utilizing laser spectroscopy (DVE-LS) is a way to measure soil pore water stable isotopes. Various equilibration times and calibration methods have been used in DVE-LS. Yet little is known about their effects on the accuracy of the obtained isotope values. The objective of this study was to evaluate how equilibration time and calibration methods affect the accuracy of DVE-LS. We did both spiking and field soil experiments. For the spiking experiment, we applied DVE-LS to four soils of different textures, each of which was subjected to five water contents and six equilibration times. For the field soil experiment, we applied three calibration methods for DVE-LS to two field soil profiles, and the results were compared with cryogenic vacuum distillation (CVD)-LS. Results showed that DVE-LS demonstrated higher δ2H and δ18O as equilibration time increased, but 12 to 24 hr could be used as optimal equilibration time. For field soil samples, DVE-LS with liquid waters as standards led to significantly higher δ2H and δ18O than CVD-LS, with root mean square error (RMSE) of 8.06‰ for δ2H and 0.98‰ for δ18O. Calibration with soil texture reduced RMSE to 3.53‰ and 0.72‰ for δ2H and δ18O, respectively. Further, calibration with both soil texture and water content decreased RMSE to 3.10‰ for δ2H and 0.73‰ for δ18O. Our findings conclude that the calibration method applied may affect the measured soil water isotope values from DVE-LS.  相似文献   

19.
The hydrology of oxygen‐18 (18O) isotopes was monitored between 1995 and 1998 in the Allt a' Mharcaidh catchment in the Cairngorm Mountains, Scotland. Precipitation (mean δ18O=−7·69‰) exhibited strong seasonal variation in δ18O values over the study period, ranging from −2·47‰ in the summer to −20·93‰ in the winter months. As expected, such variation was substantially damped in stream waters, which had a mean and range of δ18O of −9·56‰ and −8·45 to −10·44‰, respectively. Despite this, oxygen‐18 proved a useful tracer and streamwater δ18O variations could be explained in terms of a two‐component mixing model, involving a seasonally variable δ18O signature in storm runoff, mixing with groundwater characterized by relatively stable δ18O levels. Variations in soil water δ18O implied the routing of depleted spring snowmelt and enriched summer rainfall into streamwaters, probably by near‐surface hydrological pathways in peaty soils. The relatively stable isotope composition of baseflows is consistent with effective mixing processes in shallow aquifers at the catchment scale. Examination of the seasonal variation in δ18O levels in various catchment waters provided a first approximation of mean residence times in the major hydrological stores. Preliminary estimates are 0·2–0·8 years for near‐surface soil water that contributes to storm runoff and 2 and >5 years for shallow and deeper groundwater, respectively. These 18O data sets provide further evidence that the influence of groundwater on the hydrology and hydrochemistry of upland catchments has been underestimated. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   

20.
This paper focuses on the chemical and isotopic features of dissolved gases (CH4 and CO2) from four meromictic lakes hosted in volcanic systems of Central–Southern Italy: Lake Albano (Alban Hills), Lake Averno (Phlegrean Fields), and Monticchio Grande and Piccolo lakes (Mt. Vulture). Deep waters in these lakes are characterized by the presence of a significant reservoir of extra-atmospheric dissolved gases mainly consisting of CH4 and CO2. The δ13C-CH4 and δD-CH4 values of dissolved gas samples from the maximum depths of the investigated lakes (from ?66.8 to ?55.6?‰ V-PDB and from ?279 to ?195?‰ V-SMOW, respectively) suggest that CH4 is mainly produced by microbial activity. The δ13C-CO2 values of Lake Grande, Lake Piccolo, and Lake Albano (ranging from ?5.8 to ?0.4?‰ V-PDB) indicate a significant CO2 contribution from sublacustrine vents originating from (1) mantle degassing and (2) thermometamorphic reactions involving limestone, i.e., the same CO2 source feeding the regional thermal and cold CO2-rich fluid emissions. In contrast, the relatively low δ13C-CO2 values (from ?13.4 to ?8.2?‰ V-PDB) of Lake Averno indicate a prevalent organic CO2. Chemical and isotopic compositions of dissolved CO2 and CH4 at different depths are mainly depending on (1) CO2 inputs from external sources (hydrothermal and/or anthropogenic); (2) CO2–CH4 isotopic exchange; and (3) methanogenic and methanotrophic activity. In the epilimnion, vertical water mixing, free oxygen availability, and photosynthesis cause the dramatic decrease of both CO2 and CH4 concentrations. In the hypolimnion, where the δ13C-CO2 values progressively increase with depth and the δ13C-CH4 values show an opposite trend, biogenic CO2 production from CH4 using different electron donor species, such as sulfate, tend to counteract the methanogenesis process whose efficiency achieves its climax at the water–bottom sediment interface. Theoretical values, calculated on the basis of δ13C-CO2 values, and measured δ13CTDIC values are not consistent, indicating that CO2 and the main carbon-bearing ion species (HCO3 ?) are not in isotopic equilibrium, likely due to the fast kinetics of biochemical processes involving both CO2 and CH4. This study demonstrates that the vertical patterns of the CO2/CH4 ratio and of δ13C-CO2 and δ13C-CH4 are to be regarded as promising tools to detect perturbations, related to different causes, such as changes in the CO2 input from sublacustrine springs, that may affect aerobic and anaerobic layers of meromictic volcanic lakes.  相似文献   

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