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1.
1 Introduction According to recent researches, the North China Craton consists of three parts: the eastern block, western block and central zone (Zhao, 2001; Wilde et al., 2002). Paleoarchean continental blocks and zircon residuals have only been found in a few regions, such as Anshan, East Liaoning (Liu et al., 1992; Song et al., 1996; Wan et al., 2002, 2005), Caozhuang, East Hebei (Liu et al., 1992) and Xinyang, West Henan (Zheng et al., 2004), which are mainly distributed in the east…  相似文献   

2.

Nd isotope studies of the oldest metasedimentary rocks from the Wonominta Block, western New South Wales reveal that these samples have a model age (TDM) of 1780–2010 Ma, slightly younger than that of low‐grade Willyama Supergroup metasediments (1920–2160 Ma), and significantly younger than those ages previously reported from high‐grade rocks of the Broken Hill Block (2200–2300 Ma). These differences have important implications for tectonic reconstruction in this region and support a model of transitional tectonics from the Broken Hill to Wonominta Blocks, as suggested by earlier geochemical studies of mafic rocks. Those studies revealed that the mafic rocks from the basal sequence of the Wonominta Block may have formed in a back‐arc basin, developed from a propagating rifting, an environment contiguous to that in which Willyama Supergroup was deposited. These results also carry significant implications for tectonic reconstruction of eastern Australia.  相似文献   

3.

The 40Ar/39Ar dating of alteration muscovite from the Peak Au mine in the Early Devonian Cobar Basin, New South Wales, has distinguished two major episodes of mineralization. Veined (Pb‐Zn‐Cu‐Au) mineralization was broadly synchronous with cleavage formation during the post‐inversion, shortening deformation of the basin sedimentary rocks, and replacive Ag‐Pb‐Zn mineralization significantly postdates the latter event. Veined base metals (Pb‐Zn‐Cu) and Au associated with silicification were coeval with three stages of cleavage formation (D1, D2 and D3) after basin inversion. The Cu‐Au phase of mineralization at the Peak Au mine which was broadly contemporaneous with the culmination of the cleavage‐forming events (D3) and with the local development of high‐strain zones occurred at 401.5 ± 1.0 Ma (40Ar/39Ar on muscovite). This date is essentially coeval with known fossil constraints on the age of basin formation, and indicates that basin inversion and deformation rapidly followed sedimentation. In contrast, replacive Ag‐Pb‐Zn mineralization occurred at 384.0 ± 1.4 Ma (40Ar/39Ar on muscovite) during an extended period of relaxation characterized by normal faulting (D4) which followed the shortening deformation. This mineralization was associated with desilicification and chlorite‐muscovite replacement assemblages which cross‐cut the cleavages, and which may have been broadly contemporaneous with the deposition of part of the Mulga Downs Group which unconformably overlies the Cobar Supergroup. Rhyolite exposed in the core of the Peak Au mine largely contains inherited zircons that range in age from ~430–1500 Ma. A few euhedral zircons have an age of ~430 Ma and this is interpreted as a maximum date for the rock. Zircons from a syn‐D3 chlorite‐muscovite replacement zone within the deposit have 206Pb/238U ages of ~410–650 Ma and are apparently inherited.  相似文献   

4.
The Willyama Supergroup of the Broken Hill region in southern Australia consists of supracrustal sedimentary and magmatic rocks, formed between 1810 and 1600 Ma. A statistical analysis of nearly 2000 SHRIMP U–Pb zircon spot ages, compiled from published and unpublished sources, provides evidence for three distinct tectonostratigraphic successions and four magmatic events during this interval. Succession 1 includes Redan Geophysical Zone gneisses and the lower part of the Thackaringa Group (Cues Formation). These rocks were deposited after 1810 Ma and host granite sills of the first magmatic event (1710–1700 Ma). Succession 2 includes the upper Thackaringa Group (Himalaya Formation), the Broken Hill Group and the Sundown Group and was deposited between 1710 and 1660 Ma. These rocks all contain detrital zircons from the first magmatic event (1710–1700 Ma) and in some cases from the second magmatic event (1690–1680 Ma). The second magmatic event (1690–1680 Ma) was bimodal, resulted from crustal extension, and was coeval with deposition of the Broken Hill Group and deepening of the basin. With this event a mafic sill swarm focused in the Broken Hill Domain. Mafic sills lack any trace of inheritance, unlike the granitoids that commonly contain inherited zircons typical of the supracrustal sediments. Succession 3, the Paragon Group and equivalents were deposited after 1660 Ma, but before a regional metamorphic event at 1600 Ma. Metamorphism was closely followed by inversion of the succession into a fold‐and‐thrust belt, accompanied by a fourth late to post‐orogenic magmatic event (ca 1580 Ma) characterised by granite intrusion and regional acid volcanism (the local equivalents of the Gawler Range Volcanics in South Australia).  相似文献   

5.
The ca. 2.2–2.1 Ga Magondi Supergroup on the Zimbabwe Craton in Southern Africa is mainly composed of sedimentary rocks deposited in a rift basin/passive continental margin, which record a unique episode in carbon isotope perturbation called the Lomagundi–Jatuli Event (LJE). This study reports new U–Pb ages of detrital zircons from the Deweras and Lomagundi groups of the Magondi Supergroup, and of igneous zircons from underlying granitoids, to constrain the timing of the LJE and to identify the provenance of the Magondi Supergroup. Most analysed detrital zircon grains range in ages between ca. 2.9 and 2.6 Ga. Three ca. 2.3–2.2 Ga detrital zircons from sandstone of the Deweras Group, with the youngest 207Pb‐206Pb age of 2,216 ± 22 Ma, indicate the onset of LJE in the Zimbabwe Craton was almost simultaneous to that in Fennoscandia and the Superior Craton, supporting the global synchronicity of the LJE.  相似文献   

6.
Provenance data from Paleoproterozoic and possible Archean sedimentary units in the central eastern Gawler Craton in southern Australia form part of a growing dataset suggesting that the Gawler Craton shares important basin formation and tectonic time lines with the adjacent Curnamona Province and the Isan Inlier in northern Australia. U–Pb dating of detrital zircons from the Eba Formation, previously mapped as the Paleoproterozoic Tarcoola Formation, yields exclusively Archean ages (ca 3300–2530 Ma), which are consistent with evolved whole-rock Nd and zircon Hf isotopic data. The absence of Paleoproterozoic detrital grains in a number of sequences (including the Eba Formation), despite the proximity of voluminous Paleoproterozoic rock units, suggests that the Eba Formation may be part of a Neoarchean or early Paleoproterozoic cover sequence derived from erosion of a multi-aged Archean source region. The ca 1715 Ma Labyrinth Formation, unconformably overlying the Eba Formation, shares similar depositional timing with other basin systems in the Gawler Craton and the adjacent Curnamona Province. Detrital zircon ages in the Labyrinth Formation range from Neoarchean to Paleoproterozoic, and are consistent with derivation from >1715 Ma components of the Gawler Craton. Zircon Hf and whole-rock Nd isotopic data also suggest a source region with a mixed crustal evolution (εNd –6 to –4.5), consistent with what is known about the Gawler Craton. Compared with the lower Willyama Supergroup in the adjacent Curnamona Province, the Labyrinth Formation has a source more obviously reconcilable with the Gawler Craton. Stratigraphically overlying the Eba and Labyrinth Formations is the 1656 Ma Tarcoola Formation. Zircon Hf and whole-rock Nd isotopic data indicate that the Tarcoola Formation was sourced from comparatively juvenile rocks (εNd –4.1 to + 0.5). The timing of Tarcoola Formation deposition is similar to the juvenile upper Willyama Supergroup, further strengthening the stratigraphic links between the Gawler and Curnamona domains. Additionally, the Tarcoola Formation is similar in age to extensive units in the Mt Isa and Georgetown regions in northern Australia, also shown to be isotopically juvenile. These juvenile sedimentary rocks contrast with the evolved underlying sequences and hint at the existence of a large-scale ca 1650 Ma juvenile basin system in eastern Proterozoic Australia.  相似文献   

7.
In contrast to I-type granites, which commonly comprise infracrustal and supracrustal sources, S-type granites typically incorporate predominantly supracrustal sources. The initial aim of this study was to identify the sources of three Scottish Caledonian (~460 Ma) S-type granites (Kemnay, Cove and Nigg Bay) by conducting oxygen, U–Pb and Hf isotope analyses in zircon in order to characterise one potential end-member magma involved in the genesis of the voluminous late Caledonian (~430–400 Ma) I-type granites. Field, whole-rock geochemical and isotopic data are consistent with the generation of the S-type granites by melting their Dalradian Supergroup country rocks. While Hf isotope compositions of magmatic zircon, U–Pb data of inherited zircons, and high mean zircon δ18O values of 9.0 ± 2.7‰ (2SD) and 9.8 ± 2.0‰ for the Kemnay and Cove granites support this model, the Nigg Bay Granite contains zircons with much lower δ18O values (6.8 ± 2.1‰), similar to those found in Scottish I-type granites. This suggests that the Nigg Bay Granite contains low-δ18O material representing either altered supracrustal material, or more likely, an infracrustal source component with mantle-like δ18O. Mixing trends in plots of δ18O vs. εHf for S-type granite zircons indicate involvement of at least two sources in all three granites. This pilot study of Scottish Caledonian S-type granites demonstrates that, while field and whole-rock geochemical data are consistent with local melting of only supracrustal sources, the oxygen isotopic record stored in zircon reveals a much more complex petrogenetic evolution involving two or more magma sources.  相似文献   

8.
In this paper,we report an integrated study of U-Pb age and Hf isotope compositions of zircons from biotite plagioclase gneiss at Lianghe in western Yunnan.The zircons preserved inherited core and rim texture.Igneous zircon grains and rims yielded a weighted mean ~(206)Pb/~(238)U age of 120.4±1.7 Ma,theirε_(Hf)(120 Ma)values were mainly negative ranging from-13.9 to-10.7,with Hf model ages between 1.9 Ga and 2.0 Ga,some zircons had positiveε_(Hf)(120 Ma)values ranging from 0.2 to 2.1.The inherited cores ...  相似文献   

9.
This paper evaluates the analytical precision, accuracy and long‐term reliability of the U‐Pb age data obtained using inductively coupled plasma–mass spectrometry (ICP‐MS) with a frequency quintupled Nd‐YAG (λ = 213nm) laser ablation system. The U‐Pb age data for seven standard zircons of various ages, from 28 Ma to 2400 Ma (FCT, SL13, 91500, AS3, FC1, QGNG and PMA7) were obtained with an ablation pit size of 30 μm diameter. For 207Pb/206Pb ratio measurement, the mean isotopic ratio obtained on National Institute of Standards and Technology (NIST) SRM610 over 4 months was 0.9105 ± 0.0014 (n = 280, 95% confidence), which agrees well with the published value of 0.9096. The time‐profile of Pb/U ratios during single spot ablation showed no significant difference in shape from NIST SRM610 and 91500 zircon standards. These results encouraged the use of the glass standard as a calibration standard for the Pb/U ratio determination for zircons with shorter wavelength (λ = 213 nm) laser ablation. But 206Pb/238U and 207Pb/235U ages obtained by this method for seven zircon standards are systematically younger than the published U‐Pb ages obtained by both isotope dilution–thermal ionization mass spectrometry (ID‐TIMS) and sensitive high‐resolution ion‐microprobe (SHRIMP). Greater discrepancies (3–4% younger ages) were found for the 206Pb/238U ages for SL13, AS3 and 91500 zircons. The origin of the differences could be heterogeneity in Pb/U ratio on SRM610 between the different disks, but a matrix effect accuracy either in the ICP ion source or in the ablation‐transport processes of the sample aerosols cannot be neglected. When the 206Pb/238U (= 0.2302) newly defined in the present study is used, the measured 206Pb/238U and 207Pb/235U ages for the seven zircon standards are in good agreement with those from ID‐TIMS and SHRIMP within ±2%. This suggests that SRM610 glass standard is suitable for ICP‐MS with laser ablation sampling (LA‐ICP‐MS) zircon analysis, but it is necessary to determine the correction factor for 206Pb/238U by measuring several zircon standards in individual laboratories.  相似文献   

10.
Abstract

U-Pb. systematics of detrital zircons carry a mineral-specific information summarizing important geologic events during the preelastic slate of the minerals. Comparisons with U/Pb isotope rati of zircons from potential provenances reveal relationships between source areas of the zircons and their final location of deposition in a sedimentary basin. The Palaeozoic zircon detritus accumulated in sedimentary basins on the Rhenohercynian crustal segment is taken as an example to elucidate the plate-tectonical induced changes of the source areas by significant changes of the 206Pb/238 vs. 207Pb/235ratios in the zircons.

The U-Pb systematic of detrital zircon- from the Cambrian sediments deposited in the Brabant Massif and in the Ardennes indicale two source areas. Part of the detritus derived from an area. where strong Cadomian-Panafrican events influenced the U-Pb systems of the zircons. The oilier part reflects a source, in which the U-Pb systems were able to preserve their Arehaean to Early Proterozoic age information. Zircons of the latter source record the most ancient ages so far observed in detrital zircons of the later Rhenohercynian crustal seg ment. The similarities with the U/Pb isotope ratios of zircons from the Armorican Massif, the Bohemian Massif. and certain regions of the Mps indicate a geotectonic position of the sedimentar) basin during Cambrian times in the periphery of the Condwana mega-continent.

The detrital zircons accumulated in the Variscan Rhenish basin during the Lower Devonian show a completely different summarizing age information. The majority of the zircons reflect a Laurussian-type origin. which suggests a palaeogeographic position of the Variscan Rhenohercynian basin close to Laurussia. Euhedral zircons crystallized during Caledonian times document the erosion of Caledonian granitoids from structural highs in the Mid European Caledonides.

Zircons of the Lower Carboniferous flysch sediments of todays Eastern Rhenish Massif originate from two source areas characterised by very different geologic histories. Euhedral zircons represent a rather young component of about 410 Ma in the detritus, whereas. in contrast. the well rounded crystals show a summarizing age-information identical to that of the zircons found in the Cambrian sandstones. The low ages resemble intrusion ages as recorded from the Mid-German-Crystalline-Rise, the high age reflect a Gondwana-type input into the Rhenohercynian sedimentary basin during Lower Carboniferous times. The detritus thus documents the Variscan collision and a renewed coherence of the Rhenohercynian crustal segment to Cnndwana.

The zircon population from Upper Carboniferous molasse deposits is comprised of Condwana-tуpc material and of mate rial with similar U/Pb ratios as recorded in the Lower Devonian zircons. In parts the Variscan molasse must have been derived from sediments once deposited in a southern part of the Rhenohercynian basin and in the Saxothurìngian basin. U/Pb ratios of euhedral and round diamond-like lustrous zircons indicate a major geologic event at the Namurian/Westphalian boundary (310-315 Ma). These zircons thus reflect an influx of detritus into the molasse from other source rocks, probably synsedimentary volcanics.  相似文献   

11.
The Tongshankou Cu-Mo deposit, located in southeast Hubei province, is a typical skarn–porphyry type ore deposit closely related to the Tongshankou granodiorite porphyry, characterized by a high Sr/Y ratio.Detailed in situ analyses of the trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry were performed.Scarcely any inherited zircons were observed, and the analyzed zircons yielded highly concordant results with a weighted mean 206Pb/238 U age of 143.5 ± 0.45 Ma(n=20, mean square weighted deviation was 0.75), which was interpreted to represent the crystallization age of the Tongshankou granodiorite porphyry.The chondrite-normalized rare-earth element pattern was characterized by a slope that steeply rises from the light-group rare-earth elements(LREE) to the heavy-group rare-earth elements(HREE) with a positive Ce-anomaly and inconspicuous Eu-anomaly, which was coincident with the pattern of the zircons from the Chuquicamata West porphyry, Chile.The analyzed zircons also had relatively low 176Hf/177 Hf ratios of 0.282526–0.282604.Assuming t=143 Ma, the corresponding calculated initial Hf isotope compositions(εHf(t)) ranged from-5.6 to-2.9.The results of the in situ analysis of trace elements and U–Pb and Lu–Hf isotopes in zircons from the Tongshankou granodiorite porphyry suggest that a deep-seated process involving a thickened-crust/enriched-mantle interaction may play an important role in the generation of high Sr/Y-ratio magma and potentially in the generation of porphyry Cu-Mo systems.  相似文献   

12.
ABSTRACT

The Tiantang Cu–Pb–Zn polymetallic deposit in western Guangdong, South China, is hosted in the contact zone between the monzogranite porphyry and limestone of the Devonian Tianziling Formation. Orebodies occur in the skarn and skarnized marble as bedded, lenses, and irregular shapes. In this study, we performed LA-ICP-MS zircon U–Pb dating, zircon trace elements, and Hf isotopic analyses on the Tiantang monzogranite porphyry closely related to Cu–Pb–Zn mineralization. Twenty-two zircons from the sample yield excellent concordia results with a weighted mean 206Pb/238U age of 104.5 ± 0.7 Ma, which shows that the emplacement of the monzogranite porphyry in the Tiantang deposit occurred in the Early Cretaceous. The zircon U–Pb age is largely consistent with the sulphide Rb–Sr isochron ages, indicating that both the intrusion and Cu–Pb–Zn mineralization were formed during the Early Cretaceous in South China. The εHf(t) values of three inherited zircons from the monzogranite porphyry are 13.1, 11.9, and 12.9, respectively, and the two-stage Hf model ages are 1096 Ma, 1087 Ma, and 1055 Ma, respectively. Except for the three inherited zircons, all εHf(t) values of zircons are negative and have a range of ?7.6 to ?3.4, with the two-stage model ages (TDM2) of 1380–1643 Ma, which indicates the rock-forming materials were mainly derived from the partial melting of Mesoproterozoic to Neoproterozoic crust rocks, and probably included some Neoproterozoic arc-related volcanic-sedimentary materials. In this study, the monzogranite porphyry from the Tiantang deposit has calculated Ce4+/Ce3+ ratios of zircon ranging from 91 to 359, indicative of a more oxidized signature and significant prospecting potential for ore-related magmatism. Based on ore deposit geology, isotope geochemistry, and geochronology of the Tiantang Cu–Pb–Zn deposit and regional geodynamic evolution, the formation of Early Cretaceous magmatism and associated polymetallic mineralization in South China is believed to be related to large-scale continental extension and subsequent upwelling of the asthenosphere.  相似文献   

13.
U‐Pb isotopic systems of zircons from the Boobina and Spinaway Porphyries from the Precambrian Pilbara Block of Western Australia indicate ages of 3307± 19 Ma and 2768 ± 16 Ma, respectively. The Boobina Porphyry intrudes upper members of the Archaean greenstones of the Warrawoona Group. The Spinaway Porphyry intrudes basal units of the unconformably overlying volcanics and sediments of the Mt Bruce Supergroup. The age of the Boobina Porphyry, together with previous zircon U‐Pb and whole rock Sm‐Nd age determinations on stratigraphically older units, indicate that early Archaean volcanism in the Pilbara took place between 3560 Ma and 3300 Ma. On the basis of the age determination of the Spinaway Porphyry, and the chronometric definition of 2500 Ma for the Archaean—Proterozoic boundary, by the International Subcommis‐sion on Precambrian Stratigraphy (James H. L. 1978, Precambrian Res. 7, 193–204), the lower units of the Mt Bruce Supergroup should now be assigned to the Archaean.  相似文献   

14.
The Liushanyan deposit is an important volcanic‐host massive sulfide (VMS) Cu–Zn deposit in the Qinling‐Tongbai‐Dabie orogenic belt, central China, with reserve of 2.38 Mt Cu and 16.11 Mt Zn. Orebodies occur in the meta‐quartz keratophyre of the Liushanyan formation. In this paper, we present textural features and laser ablation ICP‐MS U–Pb dating results of zircons from the ore‐bearing mylonitized meta‐quartz keratophyre. The hydrothermal zircons are distinct from metamorphic zircons in this rock, showing low cathodoluminescence (CL) response and hydrothermal rims (black in CL images). They have relatively flat light rare earth element patterns and high La content and low (Sm/La)N and Ce/Ce* values. These features are typical of hydrothermal zircons. The cores of metamorphic zircons yield a weighted mean 206Pb/238U age of 900 ± 26 Ma, interpreted as the volcanic and related VMS mineralizing age. Two much younger events are also recorded by zircons in this rock: (i) the Early Silurian amphibolites–greenschist facies metamorphism at 435 ± 26 Ma; and (ii) the growth of hydrothermal zircons at ca. 241 ± 1 Ma, associated with the ductile shear deformation. The Silurian metamorphic event is probably associated with the arc–continent collision, while the Triassic ductile deformation event formed in the final continent–continent collision setting.  相似文献   

15.
U–Pb ages, trace elements, and Hf isotope compositions of zircons from the Mayuan migmatite complex in NW Fujian province have been determined to provide constraints on the source and genesis of anatexis and tectonothermal evolution related to the Caledonian orogeny in South China. The migmatites investigated consist of various amounts of mesosome, leucosome, and melansome. Zircons extracted from mesosome, leucosome, and granite samples are characterized by oscillatory overgrowths enclosing inherited cores or occur as newly grown grains. The ages of the inherited zircons from the leucosome and granite samples are consistent with those of adjacent basement paragneiss in the study area, suggesting that both leucosome and granite were generated by partial melting of the latter. A comparison of Hf isotopes between the newly-formed zircons and inherited cores indicates that the former resulted from the breakdown of preexisting inherited zircons and/or less Hf-rich minerals other than zircons at the source. One mesosome sample contains typical metamorphic zircons that yielded a weighted mean 206Pb/238U age of 453 ± 3 Ma. They show enrichments in heavy REEs (LuN/LaN up to 22,709), indicating their growth prior to garnet crystallization. The other mesosome sample, in contrast, contains both newly-formed metamorphic rims and grains that gave a weighted mean 206Pb/238U age of 442 ± 8 Ma. They are characterized by relatively low Th/U ratios, depletions in heavy REEs (LuN/LaN = 117–396), and low 176Lu/177Hf ratios, suggesting their growth synchronous with garnet crystallization. The U–Pb ages of the mesosome samples are interpreted as recording the time of early (ca. 453 Ma) to peak (442 Ma) stages of a regional metamorphic event. Two leucosome and two granite samples yield consistent U–Pb ages of 438 ± 5 Ma to 442 ± 4 Ma, which provide constraints on the timing of subsequent anatexis and magmatism. The geochronological data reported here reveal a consecutive sequence of regional metamorphism, anatexis, and magmatism in NW Fujian province, lasting for at least 15 Myr, which was driven by the Caledonian orogeny that have affected a major part of the SCB.  相似文献   

16.
http://www.sciencedirect.com/science/article/pii/S1674987112000564   总被引:10,自引:0,他引:10  
High-pressure(HP) granulites widely occur as enclaves within tonalite-trondhjemitegranodiorite (TTG) gneisses of the Early Precambrian metamorphic basement in the Shandong Peninsula, southeast part of the North China Craton(NCC).Based on cathodoluminescence(CL),laser Raman spectroscopy and in-situ U-Pb dating,we characterize the zircons from the HP granulites and group them into three main types:inherited(magmatic) zircon,HP metamorphic zircon and retrograde zircon.The inherited zircons with clear or weakly defined magmatic zoning contain inclusions of apatites,and 207Pb/206Pb ages of 2915—2890 Ma and 2763—2510 Ma,correlating with two magmatic events in the Archaean basement. The homogeneous HP metamorphic zircons contain index minerals of high-pressure metamorphism including garnet,clinopyroxene.plagioclase,quartz,rutile and apatite,and yield 207Pb/206Pb ages between 1900 and 1850 Ma,marking the timing of peak HP granulite fades metamorphism.The retrograde zircons contain inclusions of orthopyroxene.plagioclase.quartz,apatite and amphibole.and yield the youngest 207Pb/206Pb ages of 1840—1820 Ma among the three groups,which we correlate to the medium to low-pressure granulite fades retrograde metamorphism.The data presented in this study suggest subduction of Meso- and Neoarchean magmatic protoliths to lower crust depths where they were subjected to HP granulite facies metamorphism during Palaeoproterozoic(1900—1850 Ma).Subsequently, the HP granulites were exhumated to upper crust levels,and were overprinted by medium to low-pressure granulite and amphibolite facies retrograde event at ca.1840—820 Ma.  相似文献   

17.
An intramontane collapse basin developed within the hanging wall above the large-scale extensional Fjord Regional Detachment of NE Greenland in middle to late Devonian times. The continental clastic sediments within the basin are derived locally from Laurentian source rocks, which makes them well suited for a study of the crustal evolution of the source terrain. This is the first integrated in-situ Pb and Hf isotope study to be presented, and zircon data on a selected sandstone from the basin are combined with Sm-Nd whole-rock data on sand/siltstones. Nd whole-rock ages of two samples of sandstones and a siltstone are 2.0-2.1 Ga. Peak frequencies of zircon 207Pb/206Pb ages at 1,764-1,912 Ma, and 176Hf/177Hf values at 0.28142-0.28163 (tDM=2.47 to 2.06) for the sandstone suggest the generation of a considerable volume of juvenile continental crust in the ultimate zircon provenance at 1.9-2.0 Ga. The Hf isotopic compositions of Archaean zircons in the sandstone are distinct from those of the source materials of Proterozoic protocrust at 1.9-2.0 Ga, but zircons with elevated Hf-tDM ages of up to 2.47 Ga can be related to a component of Archaean crust or reworked Archaean material in the ultimate zircon source area. Zircon 207Pb/206Pb ages are also recorded at 1,480-1,572, 1,318 and 1,014 Ma (Grenvillian). The Hf isotope compositions of these zircons are consistent with reworking of the Proterozoic protocrust at these times, with little or no juvenile input. The Proterozoic zircons form two distinct groups defined by 176Yb/177Hf>0.05055 and 176Yb/177Hf<0.03301, and the latter group overlaps with Yb-Hf isotope data on the Archaean zircons. The two groups may represent zircons derived from evolved granites and intermediate to mildly felsic rocks, respectively. The repeated reworking of the continental crust also comprised erosion and deposition of sediments in the Proterozoic (the Krummedal sequence and the Eleonore Bay Supergroup, EBS) and intrusion of Caledonian anatectic granites in the EBS, which both represent provenance components to the Devonian sediments. No discrete Caledonian Pb-Pb zircon ages are recorded, but Caledonian magmatism may be represented by strongly discordant zircons which form arrays with a lower intercept age at ca. 400 Ma and an upper intercept at 1,600-2,000 Ma. One undated zircon records a 176Hf/177Hf ratio of 0.282218, higher than that of the Proterozoic protocrust in Caledonian/late-Caledonian times (380-450 Ma) which may represent a Caledonian mantle contribution.  相似文献   

18.
Zircons and other heavy minerals (corundum, rutile, ilmenite, magnetite, sillimanite) are identified in the Nsanaragati gem corundum placer deposit, in the western part of the Mamfe sedimentary basin, SW Cameroon. These alluvial minerals have different morphological characteristics and zircons, in particular, vary mostly in colour and shape. They are reddish, brownish, yellowish, pink or colourless. These minerals form rounded and sub‐rounded alluvial grains, prismatic, pyramidal or dipyramidal crystals. Reddish zircons retain their original crystallographic shape. Trace element and U–Pb isotopic geochemical analyses of these reddish zircons, using the LA‐ICP‐MS method give significant Hf (4576–6334 ppm), Th (46–1565 ppm) and U (66–687 ppm) contents, with Th/U ratio ranging from 0.6 to 3.0. The 206Pb/238U corrected mean age gave 12.39 ± 0.55 Ma, which characterizes an Upper Cenozoic (Serravallian) magmatic event. The zircons are probably sourced from a magmatic field in the South eastern boundary of the Cross River Formation. The Cameroon Volcanic Line of basaltic and alkaline lavas and intrusions which lie east of the Mamfe Basin mostly range in age from 37 Ma to <1 Ma. The zircons may also relate to the Mount Bambouto plateau lavas which lie northeast of the Mamfe sedimentary basin and have an eruptive age range of 21–14 Ma. The oldest Nsanaragati reddish zircon ages overlap within error with the end stages of the Bambouto eruptions. This eruptive or a related episode provides a potential source for megacrystic reddish zircons within the Nsanagarati placer deposit.  相似文献   

19.
The magnetite-series (I-type) calc-alkaline granitoid suit, ranging from pyroxene monzodiorite to granodiorite, is associated with the porphyry and skarn gold–copper deposits at the Shizishan orefield in Tongling district, Anhui Province. In-situ U–Pb dating and Hf isotope analysis of magmatic and inherited zircons are combined with whole rock Sr–Nd–Pb isotopic data and mineral thermobarometry to interpret the petrogenesis. The magmatic zircons from the quartz monzodiorites yield weighted average 206Pb/238U ages of ca. 139 Ma and mean εHf(t) value of −19.8 ± 3.9 (1σ), while those from the pyroxene monzodiorite show a similar mean age but notably higher mean εHf(t) value (−8.5 ± 1.4). The inherited zircons from the quartz monzodiorite yield ages of 0.8, 2.0 and 2.4 Ga with mean εHf(t) value of −2.9 ± 1.4, while those from the pyroxene monzodiorite show younger ages (165 to 245 Ma) but similar mean εHf(t) value (−5.6 ± 4.5). Whole rock Sr–Nd–Pb isotope data indicate that crustal material significantly contributed to the magma. Mineral thermobarometry results reveal that the depths of the discrete magma chambers were about 23 km, and 10 to 2 km deep.The data above combined with previous studies suggest that: 1) The magma emplacement and crystallization (typically for zircons) mainly occurred at about 139 Ma, consistent with the age of mineralization; 2) The primary pyroxene monzodioritic magma might have mixed with the magma produced by partial melting of the Yangtze lower crust, and accumulated in the magma chamber at ca. 23 km deep in the lower crust level; 3) AFC and magma mixing were the dominate processes for the magmatic evolutions at shallow level (2 to 10 km), where the circumstances were favorable for mineralization.  相似文献   

20.
Sensitive high-resolution ion microprobe (SHRIMP) U–Pb dating, laser-ablation multi-collector ICPMS Hf isotope and electron microprobe element analyses of inherited/antecrystal and magmatic zircons from five granitoid intrusions of Linxi area, in the southern segment of the Great Xing’an Range of China were integrated to solve continental crustal growth mechanisms. These intrusions were divided into two suites. Suites 1 and 2 are mainly granodiorite and syenogranite and correspond to magnesian and ferroan granites, respectively. SHRIMP dating establishes an Early Cretaceous (135–125 Ma) age for most Linxi granitoids and a time of ∼146 Ma when their source rocks were generated or re-melted. However, some granitoids were generated in Early Triassic (241 Ma) and Late Jurassic (146 Ma), after their source rock experienced precursory melting episodes at 263 Ma and 165 Ma, respectively. All zircon 206Pb/238U ages (<300 Ma, n = 100), and high positive zircon εHf(t) values (n = 175) suggest juvenile source materials with an absence of Precambrian basement. Hf–Nd isotopic decoupling of Linxi granitoids suggests a source component of pelagic sediments, i.e. Paleozoic subduction accretion complexes. Zircon εHf(t) values (t = 263–165 Ma) form a trend sub-parallel to the depleted mantle Hf isotope evolution curve, whilst those with t = 146–125 Ma fall markedly below the latter. The first trend indicates a provenance from essentially subducted oceanic slabs. However, the abrupt εHf(t) decrease, together with extensive Early Cretaceous magmatism, is interpreted as reflecting mantle upwelling and resultant underplating, and exhumation of subducted oceanic slabs. Suite 1 granitoids derive mainly from subducted oceanic slabs or Paleozoic subduction accretion complex, whereas Suite 2 from underplated mafic rock and, subordinately, Paleozoic subduction accretion complex. Compositions of Suites 1 and 2 depend on the hydrous, oxidized or relatively anhydrous, reduced nature of source rocks. Among each of these five intrusions, magmatic zircons have systematically lower 176Hf/177Hf than inherited/antecrystal zircons. Hf isotopic and substituting element profiles through inherited/antecrystal zircons (t = 263 to ∼146 Ma) indicate repeated low melt-fraction melting in the source region. In contrast, profiles through inherited/antecrystal and magmatic zircons (t = 146–125 Ma) reveal melting region expansion with a widening range of source compositions and increasing melt fractions. These results lead to the conclusion that continental growth in this region involved a three-step process. This included subduction accretion and repeated underplating, intermediary differentiation of juvenile rocks, and granitoid production from these differentiated rocks.  相似文献   

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