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碳酸盐岩石Pb—Pb和U—Pb地质年代学评述 总被引：1，自引：0，他引：1
近年来碳酸盐岩石Ｐｂ－Ｐｂ和Ｕ－Ｐｂ地质年代学的应用，对原生只作用和沉积变质作用的年龄测定做了出了重要贡献。本文总结了这方面的显著发展，讨论了碳酸盐岩石Ｕ－Ｐｂ和Ｐｂ－Ｐｂ计时器的功能，概括其主要优缺点和未来要解决的一些问题。 相似文献
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G. V. Ovchinnikova A. B. Kuznetsov M. T. Krupenin I. M. Vasil’eva O. K. Kaurova 《Doklady Earth Sciences》2018,481(2):1040-1044
For the first time, the age of magnesite in the Lower Riphean Bakal Formation of the Southern Urals is determined by the U—Pb (Pb—Pb) method: it is equal to 1366 ± 47 Ma (MSWD = 18). The stage of magnesite formation of the Bakal ore field was associated with the Mashak rifting pulse and took place prior to the formation of industrial deposits of the Bakal siderite. 相似文献
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Apatite is a common U- and Th-bearing accessory mineral in igneous and metamorphic rocks, and a minor but widespread detrital component in clastic sedimentary rocks. U–Pb and Th–Pb dating of apatite has potential application in sedimentary provenance studies, as it likely represents first cycle detritus compared to the polycyclic behavior of zircon. However, low U, Th and radiogenic Pb concentrations, elevated common Pb and the lack of a U–Th–Pb apatite standard remain significant challenges in dating apatite by LA-ICPMS, and consequently in developing the chronometer as a provenance tool.This study has determined U–Pb and Th–Pb ages for seven well known apatite occurrences (Durango, Emerald Lake, Kovdor, Mineville, Mud Tank, Otter Lake and Slyudyanka) by LA-ICPMS. Analytical procedures involved rastering a 10 μm spot over a 40 × 40 μm square to a depth of 10 μm using a Geolas 193 nm ArF excimer laser coupled to a Thermo ElementXR single-collector ICPMS. These raster conditions minimized laser-induced inter-element fractionation, which was corrected for using the back-calculated intercept of the time-resolved signal. A Tl–U–Bi–Np tracer solution was aspirated with the sample into the plasma to correct for instrument mass bias. External standards (Ple?ovice and 91500 zircon, NIST SRM 610 and 612 silicate glasses and STDP5 phosphate glass) along with Kovdor apatite were analyzed to monitor U–Pb, Th–Pb, U–Th and Pb–Pb ratiosCommon Pb correction employed the 207Pb method, and also a 208Pb correction method for samples with low Th/U. The 207Pb and 208Pb corrections employed either the initial Pb isotopic composition or the Stacey and Kramers model and propagated conservative uncertainties in the initial Pb isotopic composition. Common Pb correction using the Stacey and Kramers (1975) model employed an initial Pb isotopic composition calculated from either the estimated U–Pb age of the sample or an iterative approach. The age difference between these two methods is typically less than 2%, suggesting that the iterative approach works well for samples where there are no constraints on the initial Pb composition, such as a detrital sample. No 204Pb correction was undertaken because of low 204Pb counts on single collector instruments and 204Pb interference by 204Hg in the argon gas supply.Age calculations employed between 11 and 33 analyses per sample and used a weighted average of the common Pb-corrected ages, a Tera–Wasserburg Concordia intercept age and a Tera–Wasserburg Concordia intercept age anchored through common Pb. The samples in general yield ages consistent (at the 2σ level) with independent estimates of the U–Pb apatite age, which demonstrates the suitability of the analytical protocol employed. Weighted mean age uncertainties are as low as 1–2% for U- and/or Th-rich Palaeozoic–Neoproterozoic samples; the uncertainty on the youngest sample, the Cenozoic (31.44 Ma) Durango apatite, ranges from 3.7–7.6% according to the common Pb correction method employed. The accurate and relatively precise common Pb-corrected ages demonstrate the U–Pb and Th–Pb apatite chronometers are suitable as sedimentary provenance tools. The Kovdor carbonatite apatite is recommended as a potential U–Pb and Th–Pb apatite standard as it yields precise and reproducible 207Pb-corrected, 232Th–208Pb, and common Pb-anchored Tera–Wasserburg Concordia intercept ages. 相似文献
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北京十三陵地区中—新元古界碳酸盐岩Pb—Pb年龄研究 总被引：8，自引：0，他引：8
对北京十三陵地区中一新元古界碳酸盐岩进行了系统地采样和207pb/204pb-206Pb/204Pb年龄测定.共测定了63个样品(大部分样品采取两种溶解方式),得到中元古界雾迷山组第三段的207Pb/204pb-206Pb/204pb等时线年龄为1373±92Ma(95%置信度误差,下同,MSWD＝4.7),杨庄组为1488±55Ma(MSWD＝14),高于庄组第三段为1608±74Ma(MSWD＝8.1).这些年龄数据与目前已有地质记录相吻合.串岭沟组的碳酸盐相的206Pb/204Pb-207Pb/204Pb未构成等时线,但全岩的206Pb/204pb-207Pb/204Pb比碳酸盐相具有更明显的线性趋势,其原因尚待进一步研究.另外,根据同一个样品用稀盐酸溶解和用氢氟酸加硝酸混合酸溶解的铅同位素比值的接近的现象,显示碳酸盐岩中的硅质没有陆源的特征,是沉积盆地中的产物. 相似文献
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210Pb等核素对于大气物质传输途径、流域侵蚀作用和水体沉积过程有重要示踪价值.认识它们在环境运移过程的作用机理、速率和通量是示踪研究的基本内容.我们最新的研究进展主要有1)取得采样及分析数据的国际可比性;2)揭示黔中地区近地面空气210Pb呈现高浓度U型年分布特征;3)获得青海瓦里及山关顶部7Be的高浓度分布;气流强下沉影响在观风山的滞后性和低海拔气团上升影响在瓦里关山的滞后性;4)模拟显示210Pb在一些地区近地面空气的高浓度分布和在全球的高沉降通量环带分布;5)揭示富营养湖泊出现的微粒清洗效应及210Pbex对湖泊生产力变化的示踪价值. 相似文献
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直接测定颗粒锆石^207Pb／^206Pb年龄的方法 总被引：13，自引：1，他引：13
用B·Kober(1986—1987)所提出的热离子源发射质谱计分层蒸发、直接测定颗粒锆石~(207)Pb/~(206)Pb年龄的方法,6件锆石样品试验表明,其年龄值能与同一样品的常规锆石U-Pb法的交点年龄及其它方法的结果完全一致,并能给出更多具有一定地质意义的年龄信息。 相似文献
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直接测定内蒙古腮林忽洞组碳酸盐岩Pb—Pb同位素年龄 总被引：7，自引：0，他引：7
碳酸盐岩Ｐｂ－Ｐｂ同位素测年是地质年代学一个新的分支，本文利用这一技术，直接测定了内蒙古地区腮林忽洞组年龄，是本区首次直接获得地质年龄，不仅为碳酸盐地区确定地质年代提供了新的方法，同时对本区地层研究提供了新的数据，本文期待引起同行讨论，使这一新方法在地质研究应用中臻于完善。 相似文献
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安徽铜陵新桥矿区土壤Pb的富集特征及Pb同位素源解析 总被引：1，自引：0，他引：1
本文研究了安徽铜陵新桥矿区土壤中的Pb富集特征,并采用Pb同位素示踪法进行了Pb来源解析。结果表明,研究区多数0~20cm表层土壤Pb发生了中等以上的富集,20cm以下深层土壤的Pb无明显富集。Pb同位素组成分析表明,土壤中Pb主要来源于矿区石英二长闪长岩、花岗岩闪长岩等岩石风化的自然源Pb以及矿山黄铁矿、黄铜矿、方铅矿等矿石构成的矿石源Pb所组成的二元Pb。其中,表层土壤73.6%~98.7%的Pb来自于矿山开采的矿石,深层土壤中61.4%~76.1%的Pb来源于侵入岩的风化。 相似文献
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陈福坤 《中国地球化学学报》2001,20(2):189-192
An approach is recommended for the correction of common Pb contribution to ^207Pb/^206Pb ages obtained by the zircon evaporation technique.A comparison with that by Cocherie et al.(1992)shows that two approaches yield similar results in the ^207Pb*/^206Pb* ratios.But when using the new approach,only two errors of the measured ^204Pb/^206Pb and ^207Pb/^207Pb ratios are introduced to the calculated ^207Pb^*/^206Pb^* ratios. 相似文献
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青藏高原Pb同位素地球化学及其意义 总被引：12，自引：1，他引：11
根据青藏高原不同构造单元基底片麻岩、花岗岩类和火山岩等不同类型岩石的486套Pb同位素数据的整理和分析,发现青藏高原岩石圈存在3种主要类型,即亏损Pb同位素的特提斯洋地幔域端元、富集Pb同位素的喜马拉雅成熟大陆地壳端元和青藏高原北部的过渡型Pb同位素的地幔端元。这3类地球化学端元与前人通过Sr-Nd同位素研究获得的3类端元一致。拉萨地块内部不同类型岩石的Pb同位素地球化学特征指示出两类岩浆作用,一类是特提斯洋岩石圈俯冲消减再循环和亏损地幔物质注入导致的亲特提斯洋型岩浆作用,另一类是与类似于喜马拉雅大陆地壳物质加入导致的富集地幔源区有关的超钾质岩浆作用。岩浆作用的Pb同位素地球化学记录了特提斯洋俯冲消减作用和随后发生的印度大陆向北拼合、碰撞和俯冲过程,也记录了大规模的壳幔相互作用对高原岩石圈演化与隆升的贡献。 相似文献
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马达加斯加是位于莫桑比克带东界的一个研究程度较低的前寒武纪地区，遭受了泛非运动的强烈影响。这个巨大的岛屿是冈瓦纳大陆的关键部分，因而主变质事件的精确测年对于复原这一超大陆是至关重要的。在该岛的东南部，变质作用达到高温低压条件（８５０℃，５ｋｂａｒ），并受到了中级退变质作用。变质长英质岩石的常规多颗粒Ｕ－Ｐｂ、单颗粒锆石Ｐｂ逐层蒸发法和Ｓｍ－Ｎｄ同位素年代学研究表明，至少具下元古界年龄的基底是在约５ 相似文献
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The 3.09 to 2.97 Ga Murchison Greenstone Belt is an important metallotect in the northern Kaapvaal Craton (South Africa), hosting several precious and base metal deposits. Central to the metallotect is the Antimony Line, striking ENE for over 35?km, which hosts a series of structurally controlled Sb–Au deposits. To the north of the Antimony Line, hosted within felsic volcanic rocks, is the Copper–Zinc Line where a series of small, ca. 2.97 Ga Cu–Zn volcanogenic massive sulfide (VMS)-type deposits occur. New data are provided for the Malati Pump gold mine, located at the eastern end of the Antimony Line. Crystallizations of a granodiorite in the Malati Pump Mine and of the Baderoukwe granodiorite are dated at 2,964?±?7 and 2,970?±?7?Ma, respectively (zircon U–Pb), while pyrite associated with gold mineralization yielded a Pb–Pb age of 2,967?±?48?Ma. Therefore, granodiorite emplacement, sulfide mineral deposition and gold mineralization all happened at ca. 2.97?Ga. It is, thus, suggested that the major styles of orogenic Au–Sb and the Cu–Zn VMS mineralization in the Murchison Greenstone Belt are contemporaneous and that the formation of meso- to epithermal Au–Sb mineralization at fairly shallow levels was accompanied by submarine extrusion of felsic volcanic rocks to form associated Cu–Zn VMS mineralization. 相似文献
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210Pb方法被广泛运用于不同环境沉积物年龄和沉积速率的测定[1~7],以及陆地沉积环境侵蚀速率研究[8]。本文拟运用210Pb方法对前人未涉及过的沙漠沉积环境作初步研究,了解在沙漠风沙沉积中210Pb比活度的分布,探讨210Pb方法对风沙沉积物年龄和沉积速率的适用性。同时,试图通过对样品粒径与总210Pb(210Pbtot)比活度的关系建立拟合方程,为运用210Pb方法进行沉积物研究提供粒度校正方面的参考。运用210Pb计年的前提之一是具有稳定的沉积环境[9]。腾格里沙漠位于阿拉善台地东南部一断陷盆地,东界贺兰山,西北以雅布赖山与巴丹吉林沙漠相隔,南侧… 相似文献
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Pb分配系数是描述Pb在地下水中迁移性质的重要参数。研究对象和目的不同，计算Pb分配系数的方法也不同。静态吸附平衡方法简便易行，适用于计算不同岩性的Pb分配系数；动态土柱实验方法难度较大，主要用于建立Pb迁移方程；阳离子交换系数方法计算过程复杂，适用于解决野外实际问题。 相似文献