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1.
浓度是溶液中客观存在的物理性质,活度则指非理想溶液(包括非理想固溶体)中组分的"有效浓度"。本文以石榴子石-黑云母(GB)温度计、石榴子石-Al2SiO5矿物-斜长石-石英(GASP)压力计为例,探讨了矿物活度模型对于温度计与压力计的影响。将石榴子石和黑云母作为理想或非理想固溶体,根据实验数据建立的不同版本的石榴子石-黑云母温度计,都能较好地重现实验温度,还能识别递增变质带、倒转变质带、热接触变质晕中,不同地带变质温度的系统性变化。但是,将石榴子石和黑云母同时作为理想固溶体的温度计,系统误差明显较大,计算温度系统性偏低。同时采用石榴子石和黑云母非理想活度模型,得到的温度计精确度高。将石榴子石和斜长石都作为理想固溶体建立的GASP压力计,计算压力明显偏高,不能准确识别Al2SiO5矿物的稳定域,有明显的系统误差。如果同时采用石榴子石与斜长石的非理想活度模型,即便不同活度模型之间热力学参数有很大差别,得到的GASP压力计准确度都较高,还能准确识别Al2SiO5矿物的稳定域。迄今为止,还严重缺乏适用于多种岩石类型和宽广温度-压力范围的通用型矿物活度模型。此外,虽然矿物温度计、压力计不涉及流体、熔体,但是其计算结果的确能准确反映客观地质事实,并不受流体、熔体的影响。 相似文献
2.
高压变质作用压力估算的热力学方法 总被引：5，自引：0，他引：5
概述了近来提出的估计变质作用压力的几种方法，即金红石－榍石压力计，单斜辉石，石榴石，斜长石，钛铁矿，金红石（榍石）等矿物组合压力计，多硅白云母压力计，硬玉分子压力计方法。 相似文献
3.
河南桐柏北部秦岭群中麻粒岩相变质作用及变质矿物温压条件的研究 总被引：2，自引：0，他引：2
王奖臻 《成都地质学院学报》1990,17(1):13-22
本文提供了桐柏北部秦岭群麻粒岩中石榴石、辉石和黑云母的部分电子探针分析数据，根据岩石中矿物共生组合特征和4种地质温度计、地质压力计的计算，确定了麻粒岩相变质作用的温度、压力条件为790-850℃和0.8-1.0GPa，变质时的地热梯度为28-33℃/km，属中压麻粒岩相。 相似文献
4.
泥质变质岩系主要的矿物温度计与压力计 总被引：6，自引：0，他引：6
简要介绍泥质变质岩中常用的温度计和压力计,对其可适用性、适用范围、质量优劣等进行了评述。经过对这些温度计和压力计的比较研究,我们发现石榴石-黑云母温度计、石榴石-白云母温度计、石榴石-蓝晶石(夕线石、红柱石)-斜长石-石英(GASP)压力计、石榴石-黑云母-斜长石-石英(GBPQ)压力计、石榴石-白云母-斜长石-石英(GMPQ)压力计、石榴石-黑云母-白云母-蓝晶石(夕线石、红柱石)-石英(GBMAQ)压力计、石榴石-金红石-钛铁矿-斜长石-石英(GRIPS)压力计的准确度较高,可以为地质工作者所采用。二云母温度计、白云母-斜长石温度计准确度还有待大幅度改进。石榴石-金红石-蓝晶石(夕线石、红柱石)-钛铁矿-石英(GRAIL)压力计、石榴石-堇青石温度计和石榴石-堇青石-蓝晶石(夕线石、红柱石)-石英(GCAQ)压力计等温压计的准确度及其可适用性,还有待于进一步研究。 相似文献
5.
二、地质压力计1.石榴石-角门石-斜长石-石英地质压力计该压力计根据矿物组合反应的不同可分为两种,现简介如下:1.压力计之一(1)反应表达式有如下两种: 相似文献
6.
大别造山带黄镇榴辉岩矿物不同类型地质温度计应用和对比 总被引：4，自引：4，他引：4
常用于测定榴辉岩形成温度的有石榴石-绿辉石Fe-Mg配分温度计和石英-矿物对氧同位素温度计。最近的自然观察和实验测定发现，金红石中的Zr含量与温度之间存在线性关系，因此能够用于变质岩测温。本文首次将这三种温度计用于同一产地榴辉岩及其中的石英脉。对大别造山带黄镇低温超高压榴辉岩中金红石Zr含量的温度计算得到，产于矿物内部金红石Zr含量温度明显地高于粒间金红石Zr含量温度，产于矿物石榴石、绿辉石和黝帘石内部金红石Zr含量温度主要集中在528～589℃之间，而产于粒间金红石的温度主要集中在465～528℃之间。榴辉岩中金红石Zr含量最高的产于石榴石中，但是所计算的温度503～589℃仍然不同程度地低于榴辉岩形成温度670℃。石英脉中金红石Zr含量温度主要集中在465～528℃之间。石英-耐熔矿物对氧同位素温度主要集中在650～695℃之间，表明耐熔矿物石榴石、锆石和蓝晶石在该区榴辉岩中相对其它矿物来说保存最好，退变质作用最弱，因此其氧同位素温度与峰期超高压榴辉岩相变质奈件基本一致。而石英．易熔矿物对温度主要集中在450～510℃之间，与易熔矿物绿辉石、钠云母、斜黝帘石／黝帘石在榴辉岩中蚀变强烈一致，反映了角闪岩相退变质阶段的流体活动。石榴石-单斜辉石Fe-Mg配分温度结果分为三组：795～863℃、629～679℃和468～572℃，其中后两组与金红石Zr含量和石英-矿物对氧同位素测温结果具有可比较性，指示了榴辉岩相变质和角闪岩相退变质过程中的Fe-Mg交换平衡，而第一组温度明显高于已知的榴辉岩相变质温度，表明绿辉石后成合晶导致了部分石榴石与单斜辉石之间的Fe-Mg不平衡。榴辉岩折返过程中的流体活动可能是导致矿物之间元素和同位素扩散交换再平衡或不平衡的基本原因。粒内金红石Zr含量温度仍然不同程度地低于榴辉岩形成温度，可能说明其在进变质过程中形成后相对“孤立”，即使在峰期榴辉岩相条件下也不能与锆石之间达到Zr配分再平衡。粒间金红石Zr含量降低可能与金红石重结晶有关，结果导致它们与锆石之间的Zr配分平衡遭到破坏。 相似文献
7.
贺兰山群变质杂岩主期变质作用的温压环境研究 总被引：1，自引：0，他引：1
分布于贺兰山脉北部的贺兰山群变质杂岩的主期变质作用达角闪麻粒岩相,其矿物组合特征与低压相系麻粒岩相似、利用共生矿物组合和矿物对的温度计、压力计估算主期变质温度740—764(?),压力460—501MPa。温度压力条件与低压相系的地热梯度线较接近,变质作用强度具面型分布的特征,与东部密云、冀东等地的麻粒岩相区相似,但变质压力明显低,压力类型也不同,应属不同构造背景下的变质产物。 相似文献
8.
河南洛宁太华变质杂岩区早元古代变质作用P-T-t轨迹及其大地构造意义 总被引：3，自引：3，他引：0
太华变质杂岩广泛出露于华北克拉通南缘,总体呈SW-NE向展布.在河南洛宁地区,太华变质杂岩以TTG片麻岩、斜长角闪片麻岩和变泥质片麻岩为主.斜长角闪片麻岩中可识别出三个阶段的变质矿物组合:进变质阶段矿物组合(M1)为石榴子石变斑晶内部的包裹体矿物组合( Amp1+ Pl1+Qtz),变质高峰期矿物组合(M2)为石榴子石变斑晶边部和基质矿物组合( Grt2+ Amp2+ Pl2+ Qtz),退变质阶段矿物组合(M3)为“白眼圈”状后成合晶组合(Amp3+ Pl3+ Qtz).运用矿物温度计与压力计估算三个阶段的P-T条件分别为:进变质阶段约600 ～ 680℃/7.0～ 7.6kbar,变质高峰期为680 ～ 790℃/9.5 ～10.7kbar,退变质阶段为580～720℃/6.5 ～7.6kbar.变泥质片麻岩中保留了进变质阶段(M1)包裹体矿物组合(Bt1+Pl1+Qtz)和峰期变质阶段(M2)矿物组合(Grt2 +Bt2+Pl2 +Qtz)两个阶段.其中未发现后期退变质反应结构,石榴子石中也未发现成分环带.P-T条件估算结果分别为:M1阶段620 ～ 710℃/4.9 ～5.6kbar,M2阶段710～760℃/7.3～8.3kbar.洛宁地区太华变质杂岩记录了顺时针的近等温降压型的P-T轨迹,可能经历了与华北中部造山带其它杂岩类似的变质演化过程,推测其形成于华北克拉通东部陆块和西部陆块沿中部造山带的拼合过程中.SIMS与ICP-MS锆石U-Pb定年表明,斜长角闪片麻岩记录了1938～1967Ma的变质事件,比华北中部造山带其它变质杂岩区所广泛记录的～1850Ma变质事件早了约100Ma,暗示中部造山带的拼合可能是一个长期的、复杂的过程. 相似文献
9.
多期变质作用、多相变质作用与变质作用p-T-t轨迹 总被引：1，自引：0，他引：1
多期变质作用是指地质体经历过不止一次变质事件的变质过程.在某一期变质作用中,仅出现过一个温度(或压力)极值的过程称为单相变质作用,出现过不止一个温度(或压力)极值的变质过程则属于多相变质作用.研究变质作用,首要的工作是要正确区分不同期的变质作用,不过目前还缺少足够多的准则.但是,岩石中所保留的地球动力学背景不同的变质事件,必然属于不同期的变质作用.准确恢复变质作用p-T-t轨迹,须根据变质反应结构准确划分各变质期次,利用矿物温度计、压力计、变质相图等估算变质条件,根据矿物原位测年确定变质作用某个阶段的地质时间.这三方面还有一些不确定因素,相关理论及方法都有待深化. 相似文献
10.
按照构造变形不同阶段变质矿物生长发育特征，浙西南陈蔡群变质作用可分为四个阶段。变质阶段Ⅰ与Ｄ＿１变形同期，变质矿物共生组合为绿泥石＋黑云母＋白云母＋斜长石＋石英，相当于绿片岩相变质；变质阶段Ⅱ发生于Ｄ＿１变形和Ｄ＿２变形之间的静态期，变质矿物共生组合为＋字石＋石榴石＋斜长石＋石英＋黑云母＋白云母，变质温度范围为士５ｌ０℃，压力为０．７ＧＰａ；变质阶段Ⅲ与Ｄ＿２变形同期或稍后，变质矿物共生组合为矽线石＋石榴石＋斜长石＋石英＋黑云母＋白云母士钾长石，变质温度范围为６００～６５０℃，压力为０．５５～０．６５ＧＰ３；变质阶段Ｎ发生在Ｄ＿３或Ｄ＿３之后，变质矿物共生组合为绿泥石＋白云母，相当于低绿片岩相变质。根据构造变形不同阶段变质温度、压力变化所建立起来的ｐ－Ｔ－Ｄ轨迹，能够用来反映浙西南陈蔡群变质作用发生的构造环境。 相似文献
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12.
Stephen K. Donovan David A.T. Harper Roger W. Portell Willem Renema 《Proceedings of the Geologists' Association. Geologists' Association》2014
The Late Oligocene oyster Hyotissa antiguensis (Brown) is locally common in the Antigua Formation of Hughes Point, eastern Antigua, Lesser Antilles; it was not commonly bored at that time. Its valves and shells are robust, and reworked into the shallow water near-shore environment in Antigua; it could potentially be incorporated into younger rocks. Its neoichnology includes clues that would facilitate identification of these oysters as reworked fossils. The suite of modern borings found in these specimens includes common Caulostrepsis taeniola Clarke, Gastrochaenolites isp. cf. G. turbinatus Kelly and Bromley and Entobia isp., and rare Oichnus simplex Bromley and Rogerella? isp. The latter three taxa are limited to oyster shell substrates. Of the common ichnotaxa, Caulostrepsis and Gastrochaenolites are particularly prominent in limestone clasts and limestone cemented to oyster shells, which would be an indicator of reworking if found in a post-Oligocene lithified deposit. Caulostrepsis and Gastrochaenolites are relatively less common in oyster shells and valves, and in many specimens are seen to terminate against the shell. Entobia is the only common boring limited to the shell substrate. The fidelity of preservation of modern borings is also superior in limestone clasts. This suite of borings is comparable with those found in the Neogene of the Antillean region. 相似文献
13.
Fabien Knoll Gilles Cuny Pierre-Olivier Mojon Raquel López-Antoñanzas 《Proceedings of the Geologists' Association. Geologists' Association》2014
The palaeontological content (charophytes and vertebrates) of organic-rich layers from the Middle Jurassic (Bathonian) of the Grands Causses at Mostuéjouls (Aveyron, France) has been examined. It is rich in gyrogonites of Porochara douzensis. The vertebrates of the lower layer include a single hybodontiform tooth, “semionotiform” teeth and scales, and one pycnodontiform tooth whereas the upper layer has yielded one hybodontiform tooth, a variety of actinopterygian remains (mostly Caturus sp. and indeterminate pycnodontiforms) and a few possible reptile remains. The variation in fauna between the two layers is ascribed to a different degree of marine influence. 相似文献
14.
Stephen K. Donovan James Isted 《Proceedings of the Geologists' Association. Geologists' Association》2014
Nineteenth-century references to clavate borings in woody substrates in the Lower Greensand of the Isle of Wight used a variety of names, but Teredo (a wood-boring bivalve, not a boring), Teredolithes (a junior synonym of Teredolites) and Gastrochaena (a bivalve borer of rock and shelly substrates, not a boring in wood) are all nomenclatorially incorrect. Borings in a beach clast derived from the Lower Greensand Group and recently collected from Sandown Bay, Isle of Wight, are referred to Teredolites isp. cf. T. longissimus Kelly and Bromley. This specimen confirms the presence of Teredolites in the Lower Greensand Group and demonstrates a common ichnological problem of beach clasts; borings, either fossil or modern, are incompletely preserved, making confident classification below the level of ichnogenus problematic. 相似文献
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16.
The origin of the genus Bos is a debated issue. From ∼ 0.5 Ma until historic times, the genus is well known in the Eurasian large mammal assemblages, where it is represented by Bos primigenius. This species has a highly derived cranial anatomy that shows important morphological differences from other Plio-Pleistocene Eurasian genera of the tribe Bovini such as Leptobos, Bison, Proamphibos-Hemibos, and Bubalus. The oldest clear evidence of Bos is the skull fragment ASB-198-1 from the middle Pleistocene (∼ 0.6-0.8 Ma) site of Asbole (Lower Awash Valley, Ethiopia). The first appearance of Bos in Europe is at the site of Venosa-Notarchirico, Italy (∼ 0.5-0.6 Ma). Although the origin of Bos has traditionally been connected with Leptobos and Bison, after a detailed anatomical and morphometric study we propose here a different origin, connecting the middle Pleistocene Eurasian forms of B. primigenius with the African Late Pliocene and early Pleistocene large size member of the tribe Bovini Pelorovis sensu stricto. The dispersal of the Bos lineage in Western Europe during middle Pleistocene times seems to coincide with the arrival of the Acheulean tool technology in this continent. 相似文献
17.
Indigofera melanadenia and Tephrosia longipes plant species, collected from Cu–Ni mining area, were evaluated for accumulation of Cu and Ni. The total and bioavailable concentrations of Cu and Ni in the host soils were also determined. Flame Atomic Absorption Spectrometry was used for all metal determinations. The total and bioavailable concentrations of Cu in the soils were in the range 900–9000 μg/g and 200–2000 μg/g respectively. For Ni, the total and bioavailable concentrations were in the range 900–2000 μg/g and ∼ 40–100 μg/g respectively. The concentrations of Cu and Ni in the leaves of I. melanadenia were higher than in the roots with a range 80–130 μg/g in the leaves and 20–80 μg/g in the roots for Cu and a range of 150–200 μg/g in the leaves and 20–60 μg/g in the roots for Ni. Concentration of Cu in T. longipes was in the range of 37–240 μg/g and 150–200 μg/g in the leaves and roots respectively while the concentration of Ni was 80–140 μg/g in the leaves and 25–100 μg/g in the roots. Results indicate that both species have a potential for accumulating Cu and Ni. Translocation factor, a ratio of shoots to roots metal concentration, was used to evaluate the translocation properties of the plants from roots to shoots. Translocation factors of the plants were ≥ 1 suggesting efficient translocation of metals from roots to shoots. 相似文献
18.
Vegetation and climate change on the Bolivian Altiplano between 108,000 and 18,000 yr ago 总被引：1，自引：0，他引：1
Alex Chepstow-Lusty Mark B. Bush Paul A. Baker Sherilyn C. Fritz James Aronson 《Quaternary Research》2005,63(1):90-98
A 90,000-yr record of environmental change before 18,000 cal yr B.P. has been constructed using pollen analyses from a sediment core obtained from Salar de Uyuni (3653 m above sea level) on the Bolivian Altiplano. The sequence consists of alternating mud and salt, which reflect shifts between wet and dry periods. Low abundances of aquatic species between 108,000 and 50,000 yr ago (such as Myriophyllum and Isoëtes) and marked fluctuations in Pediastrum suggest generally dry conditions dominated by saltpans. Between 50,000 yr ago and 36,000 cal yr B.P., lacustrine sediments become increasingly dominant. The transition to the formation of paleolake “Minchin” begins with marked rises in Isoëtes and Myriophyllum, suggesting a lake of moderate depth. Similarly, between 36,000 and 26,000 cal yr B.P., the transition to paleolake Tauca is also initiated by rises in Isoëtes and Myriophyllum; the sustained presence of Isoëtes indicates the development of flooded littoral communities associated with a lake maintained at a higher water level. Polylepis tarapacana-dominated communities were probably an important component of the Altiplano terrestrial vegetation during much of the Last Glacial Maximum (LGM) and previous wet phases. 相似文献
19.
William T. Blows Kerri Honeysett 《Proceedings of the Geologists' Association. Geologists' Association》2014
A new partial skeleton of the armoured ornithischian dinosaur Polacanthus found in the Wadhurst Clay Formation (Valanginian stage) of Bexhill, Sussex is the oldest recorded occurrence of this taxon. Previous discoveries suggested that at least two armoured ornithischians occur in the Wealden succession: Polacanthus, which was mostly restricted to the Barremian, and Hylaeosaurus, which was recorded as present only in the Valanginian. The new discovery extends the stratigraphic range of Polacanthus into the Valanginian. Although these two taxa appear to be closely similar anatomically, their osteology now suggests they are not synonymous. The new specimen includes the first known jugal as well as a comparatively rare polacanthid plate/spine (splate) which probably comes from the shoulder (pectoral) area of these animals. 相似文献
20.
缅甸硬玉岩地区的热液型钠长石岩 总被引：2，自引：0，他引：2
产于俯冲带内的低温高压带的由单矿物构成的硬玉岩通常伴有钠长石岩,目前对于硬玉岩研究的关注度较高,而对于钠长石岩则相对较低,很少有相关论文报导.产于缅甸翡翠矿区的钠长石岩,经常与硬玉岩相伴而生,是良好的研究样品.钠长石岩的主要矿物成分是低温钠长石,其次含有硬玉、绿辉石、透辉石等辉石类矿物和钠透闪石、蓝透闪石、镁钠闪石等闪石类矿物,此外还有钠沸石等.钠长石沿着解理和裂隙交代硬玉,说明钠长石形成晚于硬玉岩.钠长岩中的主要组成矿物钠长石的形成温度小于300℃,且其形成压力小于0.5kb,推测是在硬玉岩抬升程中通过交代与沉淀作用形成.其内的透辉石有两种类型,一类可能是被交代的硬玉中的透辉石组分会渐进增加,最终形成透辉石.另一类是被绿辉石包裹的透辉石残留,其很有可能是早期来自地幔楔或者俯冲带岩石中的矿物残留,即异剥钙榴岩或辉石岩类,可以视作硬玉化绿辉石岩和硬玉化异剥钙榴岩的矿物学证据.热液型钠长石岩的存在进一步说明缅甸翡翠矿区钠化热液存在现象的普遍性与穿越性. 相似文献