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1.
Peter B. Larson Charles G. Cunningham Charles W. Naeser 《Contributions to Mineralogy and Petrology》1994,116(1-2):199-215
The Rico paleothermal anomaly, southwestern Colorado, records the effects of a large hydrothermal system that was active at 4 Ma. This hydrothermal system produced the deep Silver Creek stockwork Mo deposit, which formed above the anomaly's heat source, and shallower base and precious-metal vein and replacement deposits. A 65 Ma hornblende latite porphyry is present as widespread sills throughout the area and provided a homogenous material that recorded the effects of the hydrothermal system up to 8 km from the center. Hydrothermal alteration in the latite can be divided into a proximal facies which consists of two assemblages, quartz-illite-calcite and chlorite-epidote, and a distal facies which consists of a distinct propylitic assemblage. Temperatures were gradational vertically and laterally in the anomaly, and decreased away from the centra heat source. A convective hydrothermal plume, 3 km wide and at least 2 km high, was present above the stock-work molybdenum deposit and consisted of upwelling, high-temperature fluids that produced the proximal alteration facies. Distal facies alteration was produced by shallower cooler fluids. The most important shallow base and precious-metal vein deposits in the Rico district are at or close to the boundary of the thermal plume. Latite within the plume had a large loss of Na2O, large addition of CaO, and variable SiO2 exchante. Distal propylitized latite samples lost small amounts of Na2O and CaO and exchanged minor variable amounts of SiO2. The edge of the plume is marked by steep Na2O exchange gradients. Na2O exchange throughout the paleothermal anomaly was controlled by the reaction of the albite components in primary plagioclase and alkali feldspars. Initial feldspar alteration in the distal facies was dominated by reaction of the plagioclase, and the initial molar ratio of reactants (alkali feldspar albite component to plagioclase albite component) was 0.35. This ratio of the moles of plagioclase to alkali feldspar albite components that reacted evolved to 0.92 as the reaction progressed. Much of the alkali feldspar albite component in the proximal facies reacted while the, primary plagioclase was still unreacted, but the ratio for these assemblages increased to 1.51 when the plagioclase entered the reaction paragenesis. Plagioclase reaction during distal propylitic alteration resulted in pseudomorphic albite mixed with illite and a loss of Na2O. CaO is lost in the distal facies as hornblende reacts to chlorite, although some calcium may be fixed in calcite. CaO is added to the proximal facies as the quantity of chlorite replacing hornblende increases and epidote and calcite are produced. 相似文献
2.
鄂尔多斯盆地三叠系延长组砂岩钠长石化与热液成岩作用研究 总被引：2，自引：0，他引：2
鄂尔多斯盆地延长组储层砂岩发育大量自生钠长石矿物,其成因和产出与浊沸石有关,含量和分布比浊沸石多而广泛,但没有引起人们的注意。大量详细岩相学观察发现延长组储层砂岩发育丰富的自生钠长石,其主要为由斜长石碎屑蚀变形成或呈胶结物充填分布在砂岩碎屑颗粒之间。钠长石中含有大量原生的发亮黄色荧光的油气包裹体,表明其形成与油气注入同时。电子探针成分分析表明,钠长石Na2O含量较高,几乎为斜长石的纯钠长石端员(NaAlSi3O8),没有钙长石端员(CaAl2Si2O8)。激光拉曼光谱特征反映出钠长石为沉积成岩期形成的低温钠长石,而非来源于岩浆岩或者变质岩区的碎屑钠长石。应用LA-MC-ICP/MS原位微分析技术对钠长石进行的稀土元素分析表明,延长组砂岩钠长石具有热水成岩作用地球化学特征,属于热液成岩作用产物。认为大量钠长石形成与石油充注的同时进行导致了储层致密过程中岩性油藏的形成。延长组储层砂岩中热液成岩作用对油藏形成和分布意义重大,值得重视和研究。 相似文献
3.
ABSTRACT Two styles of feldspar alteration – carbonatization and albitization – were investigated using a cathodoluminescence (CL) technique. The nature of the alteration depends on the composition of the fluids. The infiltration of CO2 -rich fluids causes decomposition of An-rich zones in plagioclase followed by the formation of secondary calcite, albite and white mica. K-feldspar is more resistant to CO2 -induced alteration. The circulation of aqueous fluids results in decomposition of primary oligoclase into albite and clinozoisite. Secondary K-feldspar exsolved as small independent grains on the rim of the primary oligoclase, if the primary plagioclase was enriched in the orthoclase component. The fluids easily penetrate the crystals using, crystallographic plains, e.g., twinning or cleavage or simply along cracks. These migration pathways enable the fluids to enter the inner parts of the grain, which would otherwise not be affected by grain-surface alteration. 相似文献
4.
松辽盆地白垩系砂岩长石碎屑的钠长石化作用 总被引：12，自引：0，他引：12
松辽盆地白垩系砂岩以长石岩屑砂岩和岩屑长石砂岩为特征。砂岩中发育长石碎屑、岩屑等不稳定组分，而且随着埋藏深度加深（成岩作用加强）钾长石逐渐减少并最终在2700m以下消失。斜长石碎屑中钠长石组分逐渐增多，钙长石组分逐渐减少，最终形成纯钠端元的钠长石。在成岩过程中长石碎屑的钠长石化主要有3种方式：①由离子交代作用导致长石碎屑的钠长石化；②长石碎屑边缘钠长石次生生长；③与长石碎屑溶解伴生的新生钠长石作用。结合热动力学平衡原理分析，斜长石的钠长石化基本不受成岩温度和压力的制约，而钾长石的钠长石化需要较高的成岩温度和压力作用才能进行。因此，斜长石的钠长石化可见于成岩早期，而钾长石的钠长石化只发生于成岩晚期。 相似文献
5.
Petrological Implication of the Albite Rims in the Felsic Gneisses of the Fuping Complex 总被引：1，自引：0，他引：1
The albite rim is present in most felsic gneisses of the Fuping Complex. The presence of the rim indicates the coexistence of plagioclase and K-feldspar in the rock. The rim is formed immediately after the myrmekite, and both textures were derived from the alteration of K-feldspar. The difference is that that there is no quartz present in the rim, and the rim is nearly albite and the anorthite content of the rim plagioclase is substantially lower than that of the myrmekite plagioclase. Formed at 400–500°C the albite rim was derived from the K-feldspar composition adjustment in the late or post-magmatism stage. As the temperature decreased, the equilibrium between K-feldspar and plagioclase could be maintained, and reactions between the minerals occurred. The leucocratic veins in the complex show distinguished magma or migmatitic characteristics. The rim might form in the late magma or deuteric stage. The formation of the rim implies obvious granitic magma- or melt-injection activity. Typical metamorphic rocks cannot produce the rims. Anatexis after medium–high grade metamorphism might be subordinate. If present, the anatexis is water-present, but the rim texture cannot be taken as the symbol of anatexis. 相似文献
6.
Abstract Microprobe analyses of feldspars in granite mylonites containing flame perthite give compositions that invariably plot as three distinct clusters on a ternary feldspar diagram: orthoclase (Or92–97), albite and oligoclase-andesine. The albite occurs as grains in the matrix, as flame-shaped lamellae in orthoclase, and in patches within plagioclase grains. We present a metamorphic model for albite flame growth in the K-feldspar in these rocks that is related to reactions in plagioclase, rather than alkali feldspar exsolution. Flame growth is attributed to replacement and results from a combination of two retrograde reactions and one exchange reaction under greenschist facies conditions. Reaction 1 is a continuous or discontinuous (across the peristerite solvus) reaction in plagioclase, in which the An component forms epidote or zoisite. Most of the albite component liberated by Reaction 1 stays to form albite in the host plagioclase, but some Na migrates to form the flames within the K-feldspar. Reaction 2 is the exchange of K for Na in K-feldspar. Reaction 3 is the retrograde formation of muscovite (as ‘sericite’) and has all of the chemical components of a hydration reaction of K-feldspar. The Si and Al made available in the plagioclase from Reaction 1 are combined with the K liberated from the K-feldspar, to produce muscovite in Reaction 3. The muscovite forms in the plagioclase, rather than the K-feldspar, as a result of the greater mobility of K relative to Al. The composition of the albite flames is controlled by both the peristerite and the alkali feldspar miscibility gaps and depends on the position of these solvi at the pressure and temperature that existed during the reaction. Using an initial plagioclase composition of An20, the total reaction can be summarized as: 20 oligoclase + 1 K-feldspar + 2 H2O = 2 zoisite + muscovite + 2 quartz + 15 albiteplagioclase+ 1 albiteflame. This model does not require that any additional feldspar framework be accreted at replacement sites: Na and K are the only components that must migrate a significant distance (e.g. from one grain to the next), allowing Al to remain within the altering plagioclase grain. The resulting saussuritization is isovolumetric. The temperature and extent of replacement depends on when, and how much, water infiltrates the rock. The fugacity of the water, and therefore the pressure of the fluid, may have been significantly lower than lithostatic during flame growth. 相似文献
7.
8.
《International Geology Review》2012,54(7):1076-1085
Magmatic origin of large (up to 5 cm) phenocrysts of K-feldspar is indicated by mineralogical, chemical, and roentgenometric-structural analysis of the crystals. Perthites are found to be metasomatic products of replacement of plagioclase by K-feldspar. This reaction is accompanied by albitization of plagioclase and then by growth of albite after feldspar, in cleavage planes and elsewhere, or by spot-segregations of albite in places formerly occupied by plagioclase. — V.P. Sokoloff 相似文献
9.
CIPW标准矿物计算法应用时存在问题的探讨 总被引：1，自引：0，他引：1
CIPW法是当今最广泛应用的岩石化学计算法之一,其目的在于提供模拟矿物成分和相对数量,为岩石正确命名提供依据.作者在应用CIPW法过程中,发现不同教科书上的计算原理及方法存在差异,给实际应用造成不便;本文就斜长石牌号的计算方法、CIPW计算原理以及钠长石分配方法等问题进行了探讨. 相似文献
10.
Robert J. Stull 《Lithos》1978,11(3):243-249
Mantled feldspars that formed by resorption, development of skeletal plagioclase crystals, and filling with alkali feldspar are common in the Golden Horn batholith, Washington. Subhedral plagioclase mantles have weak normal zoning from An17 to An10. Plagioclase zoning and twinning are crosscut by resorption channels. Resorption cavities and channels are coated with albite (An10). Anhedral, perthitic orthoclase within the plagioclase is optically continuous with orthoclase in channels and on the mantle exterior.This texture resulted from resorption of calcic cores of plagioclase as pressure decreased when water-undersaturated granite magma intruded to a shallow crustal level. At shallow level, only alkali feldspar and quartz crystallized and were available to fill the skeletal plagioclase. 相似文献
11.
《International Geology Review》2012,54(4):322-326
Feldspar group minerals reacting with water at depth determine, by their reaction with environment, the character of newly formed minerals. Although plagioclase is the most abundant member of this group experimental data are very limited on the nature of its reactions under high pressure and temperature conditions. The author experimented on acid plagioclase with analytical data and physical constants corresponding to those of oligoclase. The reaction between oligoclase and water was studied under various pressures and temperatures, using a diffusion autoclave (previously described by the author [1]). Silicon, sodium, and aluminum in significant amounts went into solution; and, smaller amounts of calcium and potassium were observed. With increased temperature, larger amounts of material constituting oligoclase went into solution: The maximum occurred at 350 to 400° C; and, a marked decrease, at 500 to 600° C. Quantitative ratios of material in the condensate were found to correspond to albite indices. Increased pressure does not alter this behavior, there is only increased passage of separate components of the mineral into solution. At 350°, newly formed material was not observed microscopically; at higher temperatures, kaolinite and chalcedony appeared at sucessively higher temperatures. Experimentation by Morey and Chen on albite indicate that transfer of the albite component of oligoclase into solution is predominant. By comparison of its stability with that of two other minerals, albite is the most reactive with water. At 350° Centigrade and under pressure of 350 kilograms per square centimeter, the transfer into solution (in milligrams per liter) is for albite, 318; for microcline, 268; and, for oligoclase, 220. Labradorite was studied under analogous conditions; in that the transfer of labradorite predominates over that of the anorthite molecule, its behavior corresponds to albite. It was found that basic plagioclase shows less stability than is evident from microscopic examination of plagioclase in rocks. Data from these and previous experiments indicate possible types of solutions that can form within intragranular spaces in rocks by reaction between acid plagioclase and water. It is evident from the data that leaching of the albite component predominates by variation in composition of the solution throughout a wide range of temperature and pressure conditions. --D. D.Fisher 相似文献
12.
The 117.38 m of gabbroic core drilled during the Ocean Drilling Program (ODP) Leg 153 at Sites 921 to 924 in the Mid-Atlantic Ridge (MAR) between 23 °N and the Kane Fracture Zone, exhibits a remarkable primary compositional heterogeneity, such as magmatic layering, intrusive contacts and late magmatic veining, which express a succession of magmatic events. Textural indicators suggest that the cooling of the crystal mush occurred in a dynamic environment, with infiltration of progressively evolved liquids. Magmatic features include random shape fabric and magmatic lamination; the subsequent deformational overprint occurred in subsolidus conditions. The ductile deformation, generally concentrated in discrete domains of the gabbro, is associated with continuous re-equilibration of the metamorphic assemblages of (1) olivine + clinopyroxene + orthopyroxene + plagioclase + ilmenite + Ti-magnetite, (2) olivine + clinopyroxene + plagioclase + ilmenite + Ti-magnetite + red hornblende. At lower temperatures brittle deformation prevails and subsequent fractures control the development of metamorphic assemblages: (3) clinopyroxene + plagioclase + red brown hornblende + Ti-magnetite + magnetite (?) + ilmenite, (4) plagioclase + brown hornblende + Ti-magnetite + magnetite + hematite + titanite ± Ti-oxide, (5) plagioclase + green hornblende + magnetite + titanite, (6) plagioclase + actinolite + chlorite + titanite + magnetite, (7) albite + actinolite + chlorite + prehnite ± epidote ± titanite and (8) albite + prehnite + chlorite ± smectite. Assemblages 1 to 8 express increasing water/rock ratios and decreasing degrees of recrystallization.
During the ductile phase, red hornblende is stable and its abundance increases with deformation intensity, possibly as an effect of the introduction of hydrous fluids. During the brittle phase, water diffusion controls the development of the fracture-filling mineral assemblages and re-equilibration of the adjacent rock; temperatures decrease further, as demonstrated by mineral zoning and incompletely re-equilibrated assemblages. The lowest temperatures correspond to the development of hydrothermal assemblages.
Compared with oceanic gabbros from fast-spreading transform environments, high-temperature ductile phases (granulite and amphibolite) are well developed, whereas brittle phases are widespread, as microcracks, prevalent on fracturing associated with discrete veins. 相似文献
13.
Kanenori Suwa 《Lithos》1979,12(2):99-107
Twinning patterns and petrofabrics of plagioclases are examined in three specimens of anorthosite from the Bushveld Complex, the Quebec Massif, and the Fiskenaesset Complex. Their plagioclases have petrographical characteristics exhibiting their different petrogeneses.In an anorthosite from the Bushveld Complex, plagioclase grains are twinned after the albite-Carlsbad, pericline, albite and Carlsbad laws. Frequency percentage of the albite-Carlsbad and Carlsbad laws reaches 43% Plagioclase grains in the adcumulate layers are developed with their composition plane (010) subparallel to the cumulate plane, whereas those in the heteradcumulate layers are developed with their composition plane (010) subperpendicular to the cumulate plane.In an equigranular anorthosite from the Quebec Massif, plagioclase grains are polysynthetically twinned after the albite and pericline laws with rare examples of the albite-Carlsbad and Carlsbad laws. Frequency percentage of the latter two laws is only 1% together. Some regularities are recognized in the petrofabrics of c-axis and (010) plane.In a calcic anorthosite from the Fiskenaesset Complex, plagioclase grains are polysynthetically twinned, exclusively according to the pericline law or a combination of pericline and albite laws. The pericline law is predominant and reaches 64% and this twinning pattern cleaarly differs from that of the former two anorthosites. 相似文献
14.
G. M. Gibson 《Contributions to Mineralogy and Petrology》1979,68(2):171-179
Margarite is both abundant and widespread throughout a sequence of interstratified amphibolite, hornblendite, and metamorphosed anorthosite from the upper Lyvia River, central Fiordland. These rock types comprise part of a metamorphosed layered intrusion. Assemblages recorded from these rocks are the product of two distinct phases of metamorphism. First generation assemblages typically comprise plagioclase (An84–96), hornblende, kyanite, and minor corundum. Clinozoisite and chlorite occur as late stage breakdown products of plagioclase and hornblende. Margarite developed during the second phase of metamorphism.Within the corundum-bearing rocks replacement of corundum or plagioclase by margarite can be observed directly. On the basis of these observations the following reaction is evident: 1 corundum+1 anorthite+1H2O=1 margarite.In other assemblages the formation of margarite can be attributed to the breakdown of kyanite and clinozoisite according to the reaction: 2 kyanite+2 clinozoisite=1 margarite+3 anorthite.Margarite is found, however, to contain appreciable amounts of paragonite solid-solution (up to 28 mol%) and plagioclase produced (second generation) is not pure anorthite but of intermediate compositions (An46–62). The reaction therefore involves the introduction of both soda and silica. Margarite also crystallized independently of clinozoisite according to a reaction of the general form: 5 pargasite+17 kyanite+19 H2O =8 margarite+4 chlorite+7 plagioclase.Application of available experimental data suggests that the margarite formed between 550 and 720 ° C up to a maximum pressure of 9.5 kb. Whereas the involvement of albite component (second generation plagioclase) will tend to lower the temperatures and pressures necessary for the occurrence of margarite, this effect is partially offset by the significant amounts of paragonite end-member held within the margarite. An independent estimate of the metamorphic conditions in metapelites suggests that the introduction of albite lowers equilibration temperatures by about 2 ° C for every 1% albite. 相似文献
15.
The maximum limits of the assemblage albiteforsterite have been determined experimentally at high pressures and temperatures. At subsolidus temperatures, albite plus forsterite is replaced at high pressures by jadeitic clinopyroxene and enstatitic orthopyroxene. The boundary for this reaction lies within experimental uncertainity of that for jadeite=albite+nepheline. Melting of albite+forsterite at high pressures produces enstatite+liquid, which is different from the low-pressure eutectic behavior. Melting rates are very slow and several hundred hours are required to establish equilibrium near the solidus. The subsolidus boundary for albite plus forsterite lies near that for sanidine plus forsterite, but with a shallower slope which more closely matches that of anorthite plus forsterite. Both albite plus forsterite and anorthite plus forsterite are replaced at high pressures by an assemblage containing clinopyroxene plus orthopyroxene, unlike sanidine plus forsterite, which is replaced by a feldspathoid plus orthopyroxene. The presence of sodium enlarges the depth region over which plagioclase lherzolite can stably exist; it may also stabilize alkali feldspar plus olivine in crustal rocks. 相似文献
16.
The bulk compositions of the groundmass alkali feldspar from the Hell Canyon Pluton is 0.146mole% albite. The composition of the outermost zone of the oscillatory zoned plagioclase is 0.686 mole% albite, whereas the most calcic cores have a composition of 0.43 mole% albite. The structural state of the alkali feldspar is near orthoclase. Both composition of coexisting feldspars and structural state of the alkali feldspar are nearly constant throughout the pluton.Exsolved albite in the alkali feldspar have a composition of 0.965 mole% albite and the orthoclase host has a composition of 0.032 mole%. Singe crystal X-ray studies indicate that the albite intergrowths are coherent with the host.Equilibrium temperatures derived from the coexisting feldspar average 554 ° C; about 150 ° C, too low for the minimum solidus temperatures for reasonable emplacement pressures (2 kb). If this minimum solidus temperature is assumed, then the alkali feldspar has lost about 0.15 mole% albite. This loss was most likely caused by hydrothermal solutions associated with the crystallizing magma and equilibrated at about 550 ° C. However, based on the coherent albite intergrowths and the orthoclase structure state it can be inferred that the system was relatively free of volatiles below 500 ° C. Final equilibirium between orthoclase host and albite intergrowths occurred at about 311 ° C. 相似文献
17.
J. BARRY MAYNARD 《Sedimentology》1984,31(4):493-501
Microprobe analysis of plagioclase in deep-sea sands from various tectonic settings gives averages ranging from 19% An for trailing-edge continental margins to 56% An for basins on the ocean side of an island arc. For each setting except island arcs, anomalously high amounts of pure albite are found. These albitic grains may be recycled from pre-existing sedimentary rocks. Potassium-rich plagioclase, thought to be indicative of a volcanic provenance, is less abundant than would be expected from the proportion of volcanic rock fragments. Perhaps such high-K plagioclases are less resistant to weathering than low-K plagioclase. 相似文献
18.
Simon K. Hanmer 《Journal of Structural Geology》1982,4(2):197-213
Naturally deformed feldspars from foliated granites in a shear zone in Newfoundland exhibit transitional brittle-ductile behaviour. Brittle failure is subordinate to dynamic recrystallization, microcracking, strain enhanced diffusion and reaction enhanced ductility during the deformation. Both plagioclase (An28) and K-feldspar are transformed to albite with increasing strain. Interaction of metamorphic and structural processes at the grain scale is emphasised. This is illustrated with examples of quartz-filled veins (segregation bands) in plagioclase and recrystallized polycrystalline aggregates in plagioclase and K-feldspar. The role of microcracking in plagioclase and of pre-existing internal growth structures in the formation of initially coarse grained recrystallized aggregates from large single crystals is suggested. 相似文献
19.
Samples of essentially “dry” high-pressure felsic granulites from the Bohemian Massif (Variscan belt of Central Europe) contain up to 2-mm-large perthitic alkali feldspars with several generations of plagioclase precipitates in an orthoclase-rich host. The first generation takes the form of lenses homogeneous in size, whereas the size of a second generation of very thin albite-rich precipitates is more variable with comparatively high aspect ratios. In the vicinity of large kyanite, garnet or quartz inclusions, the first generation of plagioclase precipitates is significantly less abundant, the microstructure is coarser than in the remainder of the perthitic grain and the host is a tweed orthoclase. The first generation of precipitates formed at around 850 °C during the high-pressure stage (16–18 kbar) of metamorphism. Primary exsolution was followed by primary coarsening of the plagioclase precipitates, which still took place at high temperatures (850–700 °C). The coarsening was pronounced due to the access of fluids in the outer portions of the perthitic alkali feldspar and in more internal regions around large inclusions. The second generation of albite-rich precipitates was formed at around 570 °C. TEM investigations revealed that the interfaces between the second-generation plagioclase lamellae and the orthoclase-rich host are coherent or semi-coherent. During late evolutionary stages of the perthite, albite linings were formed at phase boundaries, and the perthitic microstructure was partially replaced by irregularly shaped precipitates of pure albite with incoherent interfaces. The albitization occurred below 400 °C and was linked to fluid infiltration in the course of deuteric alteration. Based on size-distribution analysis, it is inferred that the precipitates of the first generation were most probably formed by spinodal decomposition, whereas the precipitates of the second generation rather were formed by nucleation and growth. 相似文献
20.
The replacement of plagioclase feldspars by albite: observations from hydrothermal experiments 总被引：7，自引：3，他引：4
Jörn Hövelmann Andrew Putnis Thorsten Geisler Burkhard C. Schmidt Ute Golla-Schindler 《Contributions to Mineralogy and Petrology》2010,159(1):43-59
Oligoclase and labradorite crystals have been experimentally replaced by albite in an aqueous sodium silicate solution at
600°C and 2 kbars. The replacement is pseudomorphic and is characterised by a sharp chemical interface which progresses through
the feldspar while preserving the crystallographic orientation. Reaction rims of albite, up to 50 μm thick, can be readily
achieved within 14 days. Re-equilibration of plagioclase in an 18O-enriched sodium- and silica-bearing solution results in oxygen isotope redistribution within the feldspar framework structure.
The observed characteristics of the reaction products are similar to naturally albitised plagioclase and are indicative of
an interface-coupled dissolution–reprecipitation mechanism. Chemical analyses demonstrate that the albitisation is accompanied
by the mobilisation of major, minor and trace elements also including elements such as Al and Ti which are commonly regarded
as immobile during hydrothermal alteration. The results contribute to developing our understanding of the close association
between large-scale albitisation and secondary ore mineralisation which is common in nature. 相似文献