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1.
Aerosol optical properties have been studied for spring seasons when increased values of PM10 are registered. Measurements of aerosol optical properties were taken by collocated lidar and sun-photometers at Belsk, Poland, and Minsk, Belarus. A significant increase of registered aerosol optical thickness (AOT) was found during episodes with elevated PM10 concentrations. An increase of AOT at 1020 nm amounted to 50% in the case of Minsk and 18% in the case of Belsk, while an increase of AOT at 400 nm was 66% and 33%, respectively. We noted an increase of Ångström exponent by 6% at both stations and no significant increase of single scattering albedo. The LIDAR measurements together with NAAPS model results and backtrajectory analysis suggest that both the biomass burning products and the Saharan dust are responsible for increased PM10 concentrations and large AOT values during spring time. The smoke aerosol is transported over Central Europe mainly in the boundary layer, increasing both PM10 concentration and AOT. The dust aerosol transported in the free troposphere slightly affects the AOT values only. Statistically significant correlation between PM10 concentration and AOT was found during reporting period.  相似文献   

2.
Two significant volcanic eruptions, i.e., Eyjafjallajökull (April–May 2010) and Grímsvötn (May 2011) took place recently in Iceland. Within a few days after eruptions, layers of high aerosol concentration have been observed by multiwavelength lidar of the Polish Polar Station at Hornsund, Svalbard. Measurements of the aerosol’s optical properties indicated a possible presence of volcanic ash transported over the Station. The latter presumption was confirmed by the computed backward trajectories of air masses, showing their paths passing over the location of volcanoes.  相似文献   

3.
Exploring the chemical characterization of dissolved organic matter (DOM) is important for understanding the fate of laterally transported organic matter in watersheds. We hypothesized that differences in water-extractable organic matter (WEOM) in soils of varying land uses and rainfall events may significantly affect the quality and the quantity of stream DOM. To test our hypotheses, characteristics of rainfall-runoff DOM and WEOM of source materials (topsoil from different land uses and gullies, as well as typical vegetation) were investigated at two adjacent catchments in the Loess Plateau of China, using ultraviolet–visible absorbance and excitation emission matrix fluorescence with parallel factor analysis (PARAFAC). Results indicated that land-use types may significantly affect the chemical composition of soil WEOM, including its aromaticity, molecular weight, and degree of humification. The PARAFAC analysis demonstrated that the soils and stream water were dominated by terrestrial/allochthonous humic-like substances and microbial transformable humic-like fluorophores. Shifts in the fluorescence properties of stream DOM suggested a pronounced change in the relative proportion of allochthonous versus autochthonous material under different rainfall patterns and land uses. For example, high proportions of forestland could provide more allochthonous DOM input. This study highlights the relevance of soils and hydrological dynamics on the composition and fluxes of DOM issuing from watersheds. The composition of DOM in soils was influenced by land-use type. Precipitation patterns influenced the proportion of terrestrial versus microbial origins of DOM in surface runoff. Contributions of allochthonous, terrestrially derived DOM inputs were highest from forested landscapes.  相似文献   

4.
Detecting organic tracers from biomass burning in the atmosphere.   总被引：1，自引：0，他引：1  
This is a brief review key to the literature on the determination of organic tracers from biomass burning which are detectable even after long-range global transport in total extracts of atmospheric particles. The major tracers are thermal degradation products from the biopolymer cellulose, namely the didehydromonosaccharide derivatives levoglucosan, galactosan and mannosan and the resin acid derivative dehydroabietic acid, with minor beta-sitosterol. Dehydroabietic acid is emitted primarily from burning of conifer fuel and these tracers are found in most aerosol samples from the North American continent. Particulate matter from the atmosphere over oceanic areas contains organic tracers from both natural and biomass burning emissions. The major biomarker compounds characterized are natural products from continental vegetation consisting primarily of epicuticular wax components and trace components from biomass burning emissions. The presence of these tracers in atmospheric particulate matter over the ocean confirms the long-range transport of smoke from biomass burning off the continents.  相似文献   

5.
Contamination by the pollutants SO2 and SO=4 was analyzed for the 1989–1992 period at four regional stations in Spain under the auspices of the EMEP-BAPMON program. The evolution of the time series of the daily pollution has also been assessed, and high mean concentrations at La Cartuja and Logroño observed, with values of 3.8 and 4.5 g m−3 for SO2, respectively. Maximum annual concentrations were recorded in 1989, when SO2 reached values of 6.24, 5.39, 5.71, and 9.30 g m−3 for the stations of La Cartuja, San Pablo de los Montes, Roquetas, and Logroño, respectively. This work attempts to establish a relationship between the concentrations of the pollutants - both SO2 gas and SO=4 aerosol - and the zones of emission or persistence of these long-range transported pollutants. In this way, those regions showing a greater impact on the air quality in each season have been determined. To achieve this, the trajectories of the air masses carrying away the pollution to each of the receiving stations were considered and followed by a sectorial analysis. Nonparametric statistical methods were implemented to contrast the chemical homogeneity among the different sectors. The criterion that several homogeneous sectors form a chemically homogeneous region was used. To improve this sectorial analysis, we have proposed a new technique based on the Potential-Source-Contribution Function (PSCF). Starting out from a set of specified regions, considered to be chemically homogeneous domains, it is possible to determine the likelihood that an air mass with particular characteristics (e.g., that a value of the daily concentration higher than the mean recorded at the station has been obtained) will arrive at a given station after having crossed one of the previously defined regions. Using this technique, it is possible to determine the source regions through which the air masses circulate and bring high pollution concentrations to the studied stations. Thanks to the PSCF, these statistical methods offer, through a sectorial analysis, the possibility to pass from a qualitative to a more quantitative view.  相似文献   

6.
Agriculture crop residue burning in tropics is an important source of atmospheric aerosols and monitoring their long-range transport is an important element in climate change studies. Synchronous measurements using micro-pulsed lidar, MICROTOPS-II sun photometer, multi-filter rotating shadow band radiometer (MFRSR) on aerosol optical depth and ground reaching solar irradiance were carried at an urban location in central region of India. Aerosol backscatter profiles obtained from micro-pulse lidar showed elevated aerosol layers up to ～3 km on certain days during October 2007. Satellite data observations on aerosol properties suggested transport of particles from agriculture crop residue burning in Indo-Gangetic Plains over large regions. Radiative forcing of aerosols estimated from SBDART model with input information on aerosol chemical properties, aerosol optical depth and single scattering albedo and broadband solar irradiance measurements using MFRSR showed good correlation (R=0.98).  相似文献   

7.
Anthropogenic derived pollution episodes at Barrow, Alaska occur when air masses under anticyclonic influence emanate from the Arctic Basin. The high frequency of above-normal wind speeds and the only slightly above-normal pressures characteristic of these Arctic air masses suggest that pollutants are transported to Barrow along the periphery of the Arctic anticyclone within a zone of rapid transport.  相似文献   

8.
This paper presents the results of the studies of aerosol optical properties measured using lidars and sun photometers. We describe two case studies of the combined measurements made in two coastal zones in Crete in 2006 and in Rozewie on the Baltic Sea in 2009. The combination of lidar and sun photometer measurements provides comprehensive information on both the total aerosol optical thickness in the entire atmosphere as well as the vertical structure of aerosol optical properties. Combination of such information with air mass back-trajectories and data collected at stations located on the route of air masses provides complete picture of the aerosol variations in the study area both vertically and horizontally. We show that such combined studies are especially important in the coastal areas where depending on air mass advection directions and altitudes the influence of fine or coarse mode (in this case possibly sea-salt) particles on the vertical structure of aerosol optical properties is an important issue to consider.  相似文献   

9.
2001年3月7日与8日在香港与昆明用电化学臭氧探空仪探测到了对流层低层异常的高浓度臭氧分布. 本文使用NCEP（美国环境预报中心）分析资料、中尺度数值模式MM5模拟的大气环流数据、卫星观测的东南亚地区的生物体燃烧状况、气溶胶指数等资料,分析了这段时间的天气形势、大气环流、空气的后向轨迹以及生物体燃烧产生的烟尘的轨迹,结果发现高浓度的臭氧空气来源于有生物体燃烧的中南半岛地区. 燃烧烟尘的轨迹还表明生物体燃烧地区的下风方的对流层低层臭氧的分布会受到上游地区生物体燃烧产物的影响.  相似文献   

10.
Organic compounds are removed from the atmosphere and deposited to the Earth's surface via precipitation. In this study, we quantified variations of dissolved organic carbon (DOC) in precipitation during storm events at the Shale Hills Critical Zone Observatory, a forested watershed in central Pennsylvania (USA). Precipitation samples were collected consecutively throughout the storm during 13 events, which spanned a range of seasons and synoptic meteorological conditions, including a hurricane. Further, we explored factors that affect the temporal variability by considering relationships of DOC in precipitation with atmospheric and storm characteristics. Concentrations and chemical composition of DOC changed considerably during storms, with the magnitude of change within individual events being comparable or higher than the range of variation in average event composition among events. Although some previous studies observed that concentrations of other elements in precipitation typically decrease over the course of individual storm events, results of this study show that DOC concentrations in precipitation are highly variable. During most storm events, concentrations decreased over time, possibly as a result of washing out of the below‐cloud atmosphere. However, increasing concentrations that were observed in the later stages of some storm events highlight that DOC removal with precipitation is not merely a dilution response. Increases in DOC during events could result from advection of air masses, local emissions during breaks in precipitation, or chemical transformations in the atmosphere that enhance solubility of organic carbon compounds. This work advances understanding of processes occurring during storms that are relevant to studies of atmospheric chemistry, carbon cycling, and ecosystem responses.  相似文献   

11.
Scattering ratios of stratospheric aerosol obtained by lidar at McMurdo Station, Antarctica (78°S, 167°E), during February–December 1993, have been analysed in relation to the stratospheric polar vortex. Seasonal changes in their properties are used to infer dynamic processes occurring in the Antarctic stratosphere during the year. Descent rates are calculated and compared to values obtained with different studies. Our analysis suggests that the apparent springtime cleansing of the Antarctic stratosphere is the result of subsidence of air masses inside the vortex and of sedimentation of larger particles. Below 20 km of height, an enhancement of the aerosol descent rates during July was associated with high occurrence of Polar Stratospheric Cloud events above McMurdo Station in that period. A synoptic approach using potential vorticity values at 425 K above the station has been employed to figure out the behaviour of the aerosol across the vortex boundary during its early formation.  相似文献   

12.
PM2.5 is the key pollutant in atmospheric pollution in China.With new national air quality standards taking effect,PM2.5 has become a major issue for future pollution control.To effectively prevent and control PM2.5,its emission sources must be precisely and thoroughly understood.However,there are few publications reporting comprehensive and systematic results of PM2.5 source apportionment in the country.Based on PM2.5 sampling during 2009 in Shenzhen and follow-up investigation,positive matrix factorization(PMF)analysis has been carried out to understand the major sources and their temporal and spatial variations.The results show that in urban Shenzhen(University Town site),annual mean PM2.5 concentration was 42.2μg m?3,with secondary sulfate,vehicular emission,biomass burning and secondary nitrate as major sources;these contributed30.0%,26.9%,9.8%and 9.3%to total PM2.5,respectively.Other sources included high chloride,heavy oil combustion,sea salt,dust and the metallurgical industry,with contributions between 2%–4%.Spatiotemporal variations of various sources show that vehicular emission was mainly a local source,whereas secondary sulfate and biomass burning were mostly regional.Secondary nitrate had both local and regional sources.Identification of secondary organic aerosol(SOA)has always been difficult in aerosol source apportionment.In this study,the PMF model and organic carbon/elemental carbon(OC/EC)ratio method were combined to estimate SOA in PM2.5.The results show that in urban Shenzhen,annual SOA mass concentration was 7.5μg m?3,accounting for 57%of total organic matter,with precursors emitted from vehicles as the major source.This work can serve as a case study for further in-depth research on PM2.5 pollution and source apportionment in China.  相似文献   

13.
The contribution from agricultural catchments to stream nitrogen and phosphorus concentrations was assessed by evaluation of the chemical composition of these nutrients in agricultural runoff for both surface and subsurface flow pathways. A range of land uses (grazed and ungrazed grassland, cereals, roots) in intensive agricultural systems was studied at scales from hillslope plots (0.5 m2) to large catchment (>300 km2). By fractionating the total nutrient load it was possible to establish that most of the phosphorus was transported in the unreactive (particulate and organic) fraction via surface runoff. This was true regardless of the scale of measurement. The form of the nitrogen load varied with land use and grazing intensity. High loads of dissolved inorganic nitrogen (with >90% transported as NH4-N) were recorded in surface runoff from heavily grazed land. In subsurface flow from small (2 km2) subcatchments and in larger (>300 km2) catchments, organic nitrogen was found to be an important secondary constituent of the total nitrogen load, comprising 40% of the total annual load.  相似文献   

14.
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15.
A. Malmer  H. Grip 《水文研究》1994,8(3):195-209
Streamwater chemistry was monitored for five years in six streams in a paired catchment experiment in Mendolong, Sabah, Malaysia, comparing the effects of different ways to establish forest plantations with Acacia mangium. At the start of the monitoring in 1985 three catchments were covered with selectively logged rain forest (W4-W6) and three with secondary vegetation after forest fire (W1-W3). The treatments were: (1) clearing of secondary vegetation, burning and planting (W1 and W2); (2) clear-felling, crawler tractor extraction, burning and planting (W5); and (3) clear-felling, manual extraction, no burning and planting (W4). W3 and W6, with no treatment, were monitored as control catchments. Reference monitoring at all streams was for two years and was followed by treatments which lasted for nine months before the full establishment of a new vegetation cover. This paper covers monitoring for a further 2.5 years. The soil types of the catchments were Orthic Acrisol in W3, Gleyic Podsol in W6 and a mix of both soil types in the other catchments. The effect of treatments on streamwater chemistry was clear at both base- and stormflows. Concentrations of major plant nutrients (N, P and K.) became positively correlated to streamflow during treatments. The response of leaching from slash at clear-felling was fast and larger from the clear-felling residues (W4 and W5) than the cleared secondary vegetation (W1 and W2). The intense response to burning was more marked. The stormflow period mean nutrient concentrations were approximately 10-fold for N and K and 10-100 fold for P after burning compared with baseflow mean concentrations over the same period. Significant differences in baseflow concentrations in treated streams generally lasted one year for most elements, but elevated concentrations were still detectable after three years. The first large pulse of leaching was related to mineralization after tree-felling and particularly burning. The longer lasting elevated concentrations in baseflow were associated with the loss of weathering products. The amounts of nutrients lost, calculated by regression analysis as the effect of treatment compared with control, were found to be higher with the degree of vegetation killed and with increased soil disturbance. Consequently, normal forestry practices, with crawler tractor extraction and burning before planting, created the largest leaching losses. The total calculated effect of losses in total N, P and K were (i) W1 + W2 0.5, 1.8, 83.9; (ii) W4 0.8, 0.8, 105.6; and (iii) W5 1.3, 1.3, 189.4 kg ha?1 for the period of 33 months during and after treatment. With normal forestry practice using crawler tractors and with burning before planting (W5), the treatment-induced loss of K was equivalent to 86% of the content of easily decomposed parts of the biomass (leaves, twigs, fine roots and ground vegetation) of the old forest, or larger than K removed by harvest. Exhaustion effects of lowered leaching after repeated burning (forest fire and pre-planting fire) was observed for several elements, indicating possible nutrient deficiencies.  相似文献   

16.
A lightweight unmanned aerial vehicle (UAV) and a tethered balloon platform were jointly used to investigate three-dimensional distributions of ozone and PM2.5 concentrations within the lower troposphere (1000 m) at a localized coastal area in Shanghai, China. Eight tethered balloon soundings and three UAV flights were conducted on May 25, 2016. Generalized additive models (GAMs) were used to quantitatively describe the relationships between air pollutants and other obtained parameters. Field observations showed that large variations were captured both in the vertical and horizontal distributions of ozone and PM2.5 concentrations. Significant stratified layers of ozone and PM2.5 concentrations as well as wind directions were observed throughout the day. Estimated bulk Richardson numbers indicate that the vertical mixing of air masses within the lower troposphere were heavily suppressed throughout the day, leading to much higher concentrations of ozone and PM2.5 in the planetary boundary layer (PBL). The NO and NO2 concentrations in the experimental field were much lower than that in the urban area of Shanghai and demonstrated totally different vertical distribution patterns from that of ozone and PM2.5. This indicates that aged air masses of different sources were transported to the experimental field at different heights. Results derived from the GAMs showed that the aggregate impact of the selected variables for the vertical variations can explain 94.3% of the variance in ozone and 94.5% in PM2.5. Air temperature, relative humidity and atmospheric pressure had the strongest effects on the variations of ozone and PM2.5. As for the horizontal variations, the GAMs can explain 56.3% of the variance in ozone and 57.6% in PM2.5. The strongest effect on ozone was related to air temperature, while PM2.5 was related to relative humidity. The output of GAMs also implied that fine aerosol particles were in the stage of growth in the experimental field, which is different from ozone (aged air parcels of ozone). Geographical parameters influenced the horizontal variations of ozone and PM2.5 concentrations by changing underlying surface types. The differences of thermodynamic properties between land and sea resulted in quick changes of PBL height, air temperature and dew point over the coastal area, which was linked to the extent of vertical mixing at different locations. The results of GAMs can be used to analyze the sources and formation mechanisms of ozone and PM2.5 pollutions at a localized area.  相似文献   

17.
F. Worrall  J. K. Adamson 《水文研究》2008,22(14):2531-2541
This study considers the impact of managed rotational burning of vegetation and sheep grazing upon the composition of soil waters within an upland peat soil. The study has considered soil water compositions from a complete factorial design of treatment plots where three different burning treatments were considered in replication with grazing and no grazing. All plots were sampled across a complete year with three dipwells in each plot. The study included aluminium (Al), iron, calcium, sodium (Na), magnesium (Mg), potassium, sulphate, chloride (Cl?), bromide, fluoride, phosphate (PO )and nitrate; and in order to clarify the nature of the results, the pH, conductivity and dissolved organic carbon were also considered, but the major results for these are reported elsewhere. The study finds: (1) Ca, Na, Mg and PO concentrations are significantly lower on all burnt plots, with only Al concentration being significantly higher on burnt plots. (2) Only Cl? showed any significant changes (a decrease) with the presence of sheep grazing, and then only when plots were also burnt. (3) A principal component analysis shows that the composition of most soil waters can be described by rainwater and soil water components, but in unburnt plots a base‐rich, high ionic strength water is sometimes present. The study suggests that burning, but not grazing, caused significant changes in soil water composition leading to increased interaction between incoming rainwaters and the peat soil but led to loss of interaction with deeper waters. However, no evidence was found for structural change in the soils even after long term (50 years) grazing and burning management. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

18.
To reconstruct the evolution of Late-Quaternary river network in the southeastern part of the Great Hungarian Plain, we have used optically stimulated luminescence (OSL) and heavy mineral analysis of 25 sand samples from the upper 2–8 m of the fluvial units, complemented by four radiocarbon ages. The estimated OSL depositional ages vary between 10 and 47 ka. The heavy mineral composition of the OSL samples was compared to the compositional data of recent river sediments using cluster analysis. The new OSL and heavy mineral data show that from 47 to 10 ka ago the sediments were transported mainly from the northeast direction into the southeastern part of the Great Hungarian Plain by the ancestor of the Tisza river and its northern tributaries, and probably by another large river which also flowed northeast–southwest, parallel to the modern Tisza. Between 23 and 14 ka sediments periodically came from the east and reached the eastern part of our study area. Between 15 and 12 ka ago, sands transported from the southeast also occur in the southeastern and central part of the study area. These data suggest that the modern rivers occupied their present courses only in the last 10 ka.  相似文献   

19.
The Kings River Experimental Watersheds (KREW) were established in 2002 to expand our knowledge of catchment physical, chemical, and biological processes in Sierra Nevada headwater forests, and to better understand the impacts of prescribed burning and forest thinning on these processes. Two elevation strata (high and low) were selected for the KREW sites, with four independent catchments and one nested catchment within each stratum. Both high and low elevation study areas were instrumented for continuous measurements of meteorology, streamflow, and turbidity. Atmospheric and stream chemistry, suspended sediment concentration, and bedload sediment delivery were measured on a regular schedule. Soil chemical and physical properties and vegetation were systematically sampled before and after the initial thinning and prescribed burning treatments, which were implemented between 2012 and 2016. Post-treatment data collection continues today as we explore opportunities for the second round of possible treatments. The critical research infrastructure and long-term baseline data collection has been instrumental in building partnerships with downstream managers, end users, non-governmental organizations, academic researchers, and national research programmes. Contributions to date include fundamental understanding of magnitude and variability of nutrient deposition; carbon, nutrient, and major ion dynamics in headwater streams; aquatic algae and macroinvertebrate populations; vegetation composition and structure; and streamflow responses to precipitation in the two elevation strata. Data from the experimental watersheds also support calibration and validation of diverse hydrologic models used for water resources planning.  相似文献   

20.
There are many influences on precipitation chemistry and its variation. The transport paths of air masses before rainfall provide useful knowledge for evaluating and understanding the results of the analysis of the chemical compositions of precipitation. As a consequence, it is important to determine the variation of the chemical composition of rainwater by back trajectory analysis for estimating the source of the emissions. In this study, the rainwater samples were collected using specially designed collectors between November 1997 and June 1998 in the urban and forest areas of Istanbul. The rainwater samples were analyzed for major ion concentrations and pH. The volume‐weighed mean pH values were 5.8. The rainwater samples were classified to determine the source region of pollutants in rainwater using synoptic maps. In general, the results of the analysis on the chemical concentrations of precipitation during the measurement period showed that most of ions reached Istanbul from the directions of W‐SW, NW‐W, and NE‐N, respectively.  相似文献   

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