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1.
Fluid inclusion salinities from quartz veins in the Otago Schist, New Zealand, range from 1.0 to 7.3 wt% NaCl eq. in the Torlesse terrane, and from 0.4 to 3.1 wt% NaCl eq. in the Caples terrane. Homogenization temperatures from these inclusions range from 124 to 350  °C, with modal values for individual samples ranging from 163 to 229  °C, but coexisting, low-salinity inclusions exhibiting metastable ice melting show a narrower range of T  h from 86 to 170  °C with modes from 116 to 141  °C. These data have been used in conjunction with chlorite chemistry to suggest trapping conditions of ≈350–400  °C and 4.1–6.0  kbar for inclusions showing metastable melting from lower greenschist facies rocks, with the densities of many other inclusions reset at lower pressures during exhumation of the schist. The fluid inclusion salinities and Br/Cl ratios from veins from the Torlesse terrane are comparable to those of modern sea-water, and this suggests direct derivation of the vein fluid from the original sedimentary pore fluid. Some modification of the fluid may have taken place as a result of interaction with halogen-bearing minerals and dehydration and hydration reactions. The salinity of fluids in the Caples terrane is uniformly lower than that of modern sea-water, and this is interpreted as a result of the dilution of the pore fluid by dehydration of clays and zeolites. The contrast between the two terranes may be a result of the original sedimentary provenance, as the Torlesse terrane consists mainly of quartzofeldspathic sediments, whilst the Caples terrane consists of andesitic volcanogenic sediments and metabasites which are more prone to hydration during diagenesis, and hence may provide more fluid via dehydration at higher grades.  相似文献   

2.
The garnet-olivine Fe-Mg exchange geothermometer and the garnet-olivine-plagioclase geobarometer have been simultaneously calibrated using reversed experimental data based on the model reactions and between 900 and 1500 °C at 9.1–95.0 kbar and between 4.7 and 7.0 kbar at 750–1050 °C, respectively. The resulting garnet-olivine thermometer reproduces experimental temperatures mostly within ±75 °C and the garnet-olivine-plagioclase barometer reproduces experimental pressures well within ±0.19 kbar. These new thermobarometers use the same garnet and olivine activity models and are thermodynamically consistent. Application of these thermobarometers to garnet peridotites from mantle xenoliths, orogenic garnet peridotites over the world and the Adirondack olivine-bearing metagabbros yielded reasonable P–T results. The present garnet-olivine thermometer can be used to measure medium-high-grade to ultrahigh-grade, low-pressure to ultrahigh–high-pressure garnet peridotites and metagabbros, whereas the garnet-olivine-plagioclase barometer has limited application to garnet-olivine-plagioclase-bearing granulites.  相似文献   

3.
The pressure-sensitive equilibrium among anorthite, quartz and the Ca-tschermak component in clinopyroxene (CaAl2SiO6; CaTs), CaAl2SiOCpx6+SiOQtz2=CaAl2Si2OPl8 (SCAn) ,can be used as a geobarometer in granulites with the proper assemblage, and has been calibrated using mineral composition data from partial melting experiments of natural assemblages and from phase equilibrium experiments on the end-member CMAS system. The experimental data cover the P – T  range 4–32  kbar and 900–1400  °C. Linear least-squares regression analysis of the experimental data resulted in the following empirical expressions for pressure in terms of composition and temperature: P = 5.066 [±0.760]+ 1300 [±800] T  −ln K 276 [±16] · T  [±2.5  kbar]or P = 6.330 [±0.116]−ln K 301 [±9]· T  [±1.0  kbar] ,where K = a PlAn a CpxCaTs  .The first equation incorporates an enthalpy term, but is less accurate than the second equation, in which the enthalpy of reaction is ignored. Application of these expressions to natural and experimental equilibrium mineral assemblages demonstrates that the empirical barometers are applicable over a wide range of pressures (≥4  kbar), temperatures (≥700  °C) and bulk compositions (Mg#≥32.5).  相似文献   

4.
Garnet from a kinzigite, a high-grade gneiss from the central Black Forest (Germany), displays a prominent and regular retrograde diffusion zoning in Fe, Mn and particularly Mg. The Mg diffusion profiles are suitable to derive cooling rates using recent datasets for cation diffusion in garnet. This information, together with textural relationships, thermobarometry and thermochronology, is used to constrain the pressure–temperature–time history of the high-grade gneisses. The garnet–biotite thermometer indicates peak metamorphic temperatures for the garnet cores of 730–810  °C. The temperatures for the outer rims are 600–650  °C. Garnet–Al2SiO5–plagioclase–quartz (GASP) barometry, garnet–rutile–Al2SiO5–ilmenite (GRAIL) and garnet–rutile–ilmenite–plagioclase–quartz (GRIPS) barometry yield pressures from 6–9  kbar. U–Pb ages of monazite of 341±2  Ma date the low- P high- T metamorphism in the central Black Forest. A Rb/Sr biotite–whole rock pair defines a cooling age of 321±2  Ma. The two mineral ages yield a cooling rate of about 15±2  °C Ma−1. The petrologic cooling rates, with particular consideration of the f O2 conditions for modelling retrograde diffusion profiles, agree with the geochronological cooling rate. The oldest sediments overlying the crystalline basement indicate a minimum cooling rate of 10  °C Ma−1.  相似文献   

5.
This paper reports an occurrence of medium-pressure granulite facies calc-silicate rocks intercalated with pelitic gneisses in the Higo metamorphic terrane, central Kyushu, Japan, which is classified as a low- P /high- T (andalusite-sillimanite type) metamorphic belt. Three equilibrium stages are recognized in the calc-silicate rock based on reaction textures: M1 stage characterized by an assemblage of porphyroblastic garnet + coarse-grained clinopyroxene + plagioclase included in the clinopyroxene; M2 stage by two kinds of breakdown products of garnet, one is plagioclase + coronitic clinopyroxene within garnet and the other is plagioclase + vermicular clinopyroxene surrounding garnet; and M3 stage by amphibole replacing clinopyroxene. The key assemblage in the calc-silicate rock common to M1 and M2 stages is Grt + Cpx + Pl ± Qtz, which constrains the pressure and temperature ( P – T ) conditions for these stages by Fe–Mg exchange reaction and the two univariant net-transfer reactions: 2Grs + Alm + 3Qtz = 3Hd + 3An or 2Grs + Prp + 3Qtz = 3Di + 3An. The P – T conditions for M1 and M2 stages were estimated to be about 8.4 ± 1.9 kbar and 680 ± 122 °C, and 6.7 ± 1.9 to 8.9 ± 2.2 kbar and 700 ± 130 to 820 ± 160 °C, respectively. Estimates are consistent with an isobaric heating P – T path. The high peak temperature conditions at normal crustal depths and the prograde isobaric heating path probably require heat advection due to melt migration during the high- T metamorphism.  相似文献   

6.
The Okiep Copper District, part of the 1.2–1.0 Ga high-grade terrane in western Namaqualand, is composed of a mid-Proterozoic supracrustal sequence and several pre- to post-orogenic intrusive suites affected by two high-grade events (M2a/M2b, M3) of Kibaran and one low-grade event (M4) of Pan-African age. Peak assemblages in quartz-bearing pelites are characterized either by garnet+cordierite coexisting with sillimanite/biotite, or by biotite+sillimanite±garnet; a difference controlled by bulk composition and variation in water activities (0.1–0.7) during dehydration melting. Maximum P–T conditions were reached during M2a coevally with the major deformational event (D2a) and are estimated at 750–820  °C and 5–6  kbar. A counterclockwise P–T  path is indicated by regionally occurring pseudomorphs of sillimanite after andalusite and by prograde reaction textures preserved as relics in M2a porphyroblasts. Two stages of retrograde metamorphism are distinguished: M2a garnet+cordierite-bearing assemblages were retrogressed to biotite+sillimanite+quartz (M2b) along discontinuous foliation planes and shear zones (D2b). Retrograde M3 corona assemblages formed at similar P–T  conditions (580–660  °C and 5.8±0.5  kbar) to the M2b assemblages but M3 crystallization postdates penetrative D2 deformation, intrusion of 1.06 Ga granitoids and formation of associated W–Mo deposits. It is concluded that: (a) Kibaran high-grade metamorphism in the Okiep Copper District is thermally punctuated and (b) reaction textures documenting apparent isobaric cooling of this low- P high- T  terrane must be interpreted with caution.  相似文献   

7.
Combined petrographic, structural and geochronological study of the Malashan dome, one of the North Himalayan gneiss domes, reveals that it is cored by a Miocene granite, the Malashan granite, that intruded into the Jurassic sedimentary rocks of Tethys Himalaya. Two other granites in the area are referred to as the Paiku and Cuobu granites. New zircon SHRIMP U-Pb and muscovite and biotite 40Ar-39Ar dating show that the Paiku granite was emplaced during 22.2–16.2 Ma (average 19.3 ± 3.9 Ma) and cooled rapidly to 350–400 °C at around 15.9 Ma. Whole-rock granite chemistry suggests the original granitic magma may have formed by muscovite dehydration melting of a protolith chemically similar to the High Himalayan Crystalline Sequence. Abundant calcareous metasedimentary rocks and minor garnet-staurolite-biotite-muscovite ± andalusite schists record contact metamorphism by three granites that intruded intermittently into the Jurassic sediments between 18.5 and 15.3 Ma. Two stages of widespread penetrative ductile deformation, D1 and D2, can be defined. Microstructural studies of metapelites combined with geothermobarometry and pseudosection analyses yield P – T conditions of 4.8 ± 0.8 kbar at 550 ± 50 °C during a non-deformational stage between D1 and D2, and 3.1–4.1 kbar at 530–575 °C during syn- to post-D2. The pressure estimates for the syn- to post-D2 growth of andalusite suggest relatively shallow (depth of ∼15.2 km) extensional ductile deformation that took place within a shear zone of the South Tibetan Detachment System. Close temporal association between intrusion of the Malashan granite and onset of D2 suggests extension may have been triggered by the intrusion of the Malashan granite.  相似文献   

8.
Ultrahigh-temperature quartz-sapphirine granulite xenoliths in the post-Karoo Lace kimberlite, South Africa, comprise mainly quartz, sapphirine, garnet and sillimanite, with rarer orthopyroxene, antiperthite, corundum and zinc-bearing spinel; constant accessories are rutile, graphite and sulphides. Comparison with assemblages in the experimentally determined FMAS and KFMASH grids indicates initial equilibration at >1040 °C and 9–11  kbar. Corona assemblages involving garnet, sillimanite and minor cordierite developed on a near-isobaric cooling P–T  path as both temperature and, to a lesser extent, pressures decreased. Garnet-orthopyroxene Fe-Mg exchange thermometers record temperatures of only 830–916 °C. These estimates do not indicate the peak metamorphic conditions but instead reflect the importance of post-peak Fe-Mg exchange during cooling. Correction of mineral Fe-Mg compositions for this exhange using a convergence approach of Fitzsimons & Harley (1994 ) leads to retrieved P–T  estimates from garnet-orthopyroxene thermobarometry ( c . 1000 °C and 10.5±0.7  kbar) that are consistent with the petrogenetic grid constraints. U-Pb dating of a single zircon grain gives an age of 2590±83  Ma, interpreted as the age of the metamorphic event. Protolith major and trace element chemistries of the xenoliths differ from sapphirine-quartzites typical of the Napier Complex (Antarctica) but are comparable to less siliceous, high Cr and Ni, sapphirine granulites reported from several ultrahigh temperature granulite terranes.  相似文献   

9.
van Roermund  & Drury 《地学学报》1998,10(6):295-301
We report here for the first time the occurrence of relics of majoritic garnet within orogenic garnet peridotites from Otrøy, Western Gneiss Region, Norway. The microstructural evidence consists of two-pyroxene exsolution from garnet. Majoritic garnets are only stable at depths greater than 150 km. Estimates of the initial composition of the majoritic garnets imply pressures of 6–6.5 GPa indicating that the Otrøy peridotites were derived from depths > 185 km.
  Mineral-chemical data indicate that the present mineral compositions equilibrated at mantle conditions around 805 ± 40 °C and 3.2 ± 0.2 GPa.
  Estimates of the initial pressure temperature (PT) conditions and PTtime ( t ) path are consistent with a multistage, multiorogenic exhumation history with upwelling of hot asthenosphere up to ≈ 100 km in the Pre-Cambrian followed by subsequent crustal emplacement and exhumation during the Caledonian orogeny.  相似文献   

10.
The Lander Rock Beds form the local basement of the Reynolds Range in the Arunta Inlier of central Australia. These dominantly quartzose and pelitic lithologies underwent low-grade ( c.   400  °C) regional metamorphism prior to contact metamorphism ( c.   2.5  kbar) around S-type megacrystic granitoids at 1820–1800  Ma. The Lander Rock Beds are overlain by metasediments of the Reynolds Range Group, which were subsequently intruded by granitoids at c. 1780  Ma. Regional metamorphism at 1590–1580  Ma produced grades varying from greenschist (400  °C at 4–5  kbar) to granulite (750–800  °C at 4–5  kbar) from north-west to south-east along the length of the Reynolds Range. Oxygen isotope ratios of the Lander Rock Beds were reset from 13.4±0.8 to as low as 6.7 adjacent to the contacts of the larger plutons, and to 10.3±1.1 around the smaller plutons. Biotite in all the major rock types found in the aureoles has δD values between −52 and −69, probably reflecting resetting by a cooling igneous+metamorphic fluid near the plutons. Sapphirine-bearing and other Mg- and Al-rich rock types have low δ18O values (4.0±0.7). The precursors to these rocks were probably low-temperature ( c. 200  °C) diagenetic–hydrothermal deposits of Mg-rich chlorite, analogous to those in Proterozoic stratiform precious metal and uranium deposits that form by the infiltration of basin brines or seawater. As in the overlying Reynolds Range Group, regional metamorphism involved little fluid–rock interaction and isotopic resetting.  相似文献   

11.
Abstract CO2-bearing fluid inclusions in strongly lineated but weakly foliated late Precambrian gneisses within the Hope Valley Shear zone of Connecticut and Rhode Island are of mixed composition ( X co2± 0.1; 7 wt% NaCl equivalent) and variable density (0.59–0.86 g/ml) and occur mainly as isolated inclusions. Also present are dilute (3 wt% NaCl equivalent) aqueous inclusions which occur on healed fractures related to greenschist facies retrograde metamorphism. Isochores for dense isolated CO2-bearing inclusions indicate pressures of 7.5–9 kbar at 500–600° C, the estimated temperature conditions of peak metamorphism. Published 40Ar/39Ar hornblende plateau age spectra indicate cooling through about 500° C at 265 ± 5 Ma. Isochores for low-density CO2-bearing inclusions and aqueous inclusions intersect at the conditions of retrograde metamorphism (325–400° C) and indicate pressures of 3–4 kbar. Published 40Ar/39Ar biotite plateau ages indicate cooling through about 300° C at 250 ± 5 Ma. These data define a P–T uplift curve for the region which is convex towards the temperature axis and indicate uplift rates between 0.4 and 3.3 mm/year in Permian time. Exhumation of basement gneisses was coeval with normal (west-down) motion along the regional basement–cover contact (Honey Hill–Lake Char–Willimantic fault system), and is interpreted as due to post-orogenic extensional collapse of the Alleghanian orogeny.  相似文献   

12.
Apatite fission track dating from a central transect in the Argentera massif (southernmost External Crystalline Massif = ECM) yielded ages between 8.05 ± 0.6 and 2.4 ± 0.2 Myr, with a positive age/altitude correlation above 3 Ma, 1200 m. Recognising a thermal peak at c . 250°C, 33 Ma, based on stratigraphic, metamorphic and 39Ar/40Ar data, the present results suggest a slow cooling rate (8–5°C) for the Argentera massif during the Oligocene–early Pliocene. This rate compares with that from the Pelvoux massif, but contrasts with those observed in the northern ECM (Mont-Blanc and Aar: up to 14°C Myr−1) for the same time interval. This can be related to the different location of the ECM within the collided European margin. At about 3–4 Ma, the denudation rate would have increased up to c . 1 mm yr−1 in the Argentera massif, reaching the same value as in the Belledonne and northern ECM, likely a consequence of Penninic thrust inversion.  相似文献   

13.
Magnesian metapelites of probable Archaean age from Forefinger Point, SW Enderby Land, East Antarctica, contain very-high-temperature granulite facies mineral assemblages, which include orthopyroxene (8–9.5 wt% Al2O3)–sillimanite ± garnet ± quartz ± K-feldspar, that formed at 10 ± 1.5 kbar and 950 ± 50°C. These assemblages are overprinted by symplectite and corona reaction textures involving sapphirine, orthopyroxene (6–7 wt% Al2O3), cordierite and sometimes spinel at the expense of porphyroblastic garnet or earlier orthopyroxene–sillimanite. These textures mainly pre-date the development of coarse biotite at the expense of initial mesoperthite, and the subsequent formation of orthopyroxene (4–6 wt% Al2O3)–cordierite–plagioclase rinds on late biotite.
The early reaction textures indicate a period of near-isothermal decompression at temperatures above 900°C. Decompression from 10 ± 1.5 kbar to 7–8 kbar was succeeded by biotite formation at significantly lower temperatures (800–850°C) and further decompression to 4.5 ± 1 kbar at 700–800°C.
The later parts of this P–T evolution can be ascribed to the overprinting and reworking of the Forefinger Point granulites by the Late-Proterozoic ( c . 1000 Ma) Rayner Complex metamorphism, but the age and timing of the early high-temperature decompression is not known. It is speculated that this initial decompression is of Archaean age and therefore records thinning of the crust of the Napier Complex following crustal thickening by tectonic or magmatic mechanisms and preceding the generally wellpreserved post-deformational near-isobaric cooling history of this terrain.  相似文献   

14.
The 'TitaniQ' (Ti-in-quartz) solubility thermometer was applied to migmatitic metapelites from the southern and western Adirondack Highlands, New York, to examine the effect of granulite facies metamorphism on the distribution of Ti in quartz. Both cathodoluminescence imaging and quantitative traverses revealed that individual grains of Adirondack quartz are highly zoned with respect to Ti, and that core-to-rim decreases of Ti are common. Large ranges in calculated temperature were observed within each sample. One sample, not considered to be saturated with respect to TiO2, gave maximum temperatures more than 100 °C lower than previously estimated peak temperatures. Rutile-saturated southern and western Adirondack samples yielded peak estimates of ≥803 ± 11 °C and ∼860–870 °C, respectively, which are similar to previous estimates from major phase thermometry. Minimum Ti-in-quartz matrix temperatures from rutile-saturated samples are 630 °C, which is interpreted as the closure temperature for Ti diffusion in quartz in these samples. This study demonstrates that Ti-in-quartz thermometry can yield details of rock evolution if the textural setting and reaction history of the quartz is clear, and can yield near-peak metamorphic temperatures in some cases, if care is taken to test for post-peak diffusional resetting.  相似文献   

15.
Annealing experiments on agate, quartz schist and metachert at 800–1000 °C, confining pressures of 400 and 800  MPa, and annealing times of 6.0×10–3.6×105s revealed normal grain growth of quartz in the agate, grain-size increasing with time, but the rate of grain growth decreasing with increasing grain size.
The boundaries of agate with quartz schist and metachert migrated into the agate at the expense of fine-grained quartz in the agate. The driving force for the migration appears to be the reduction of surface energy associated with removal of fine-grained quartz in the agate. Assuming the activation energy as Q m =11  kcal mol−1, a general expression for the relationship between velocity of boundary migration ( V   ) and driving force ( P ) is where γ is the specific surface energy of quartz, R is the gas constant and T  is the absolute temperature. The velocity is relatively fast at high temperatures on a geological time-scale. The expression assists a quantitative understanding of the microstructural development of quartz at metamorphic conditions.  相似文献   

16.
Abstract Petrological data from intercalated pelitic schists and greenstones are used to construct a pressure–temperature path followed by the Upper Schieferhülle (USH) series during progressive metamorphism and uplift in the south-west Tauern Window, Italy. Pseudomorphs of Al–epidote + Fe-epidote + albite + oligoclase + chlorite after lawsonite and data on amphibole crystal chemistry indicate early metamorphism in the lawsonite-albite-chlorite subfacies of the blueschist facies at P ± 7–8 kbar. Geothermometry and geobarometry yield conditions of final equilibration of the matrix assemblage of 475±25°C, 5–6 kbar; calculations with plagioclase and phengite inclusions in garnet indicate early garnet growth at pressures of ∼ 7.5 kbar. Garnet zoning patterns are complex and reversals in zoning can be correlated between samples. Thermodynamic modelling of these zoning profiles implies garnet growth in response to four distinct phases of tectonic activity. Fluid inclusion data from coexisting immiscible H2O–CO2–NaCl fluids constrain the uplift path to have passed through temperatures of 380 + 30°C at 1.3 + 0.2 kbar.
There is no evidence for metamorphism of USH at pressures greater than ∼ 7.5 kbar in this area of the Tauern Window. This is in contrast to pressures of ± 10 kbar recorded in the Lower Schieferhülle only 2–3 km across strike. A history of differential uplift and thinning of the intervening section during metamorphism is necessary to reconcile the P–T data obtained from these adjacent tectonic units.  相似文献   

17.
P–T  paths based on parageneses in the immediate vicinity of former high-temperature contact zones between mantle peridotites and granulitic country rocks of the Central Vosges (NE France) were derived by applying several conventional thermometers and thermobarometric calculations with an internally consistent dataset. The results indicate that former garnet peridotites and garnet–spinel peridotites were welded together with crustal rocks at depths corresponding to 1–1.2 GPa. The temperature of the crustal rocks was about 650–700 °C at this stage, whereas values of 1100 °C (garnet peridotites) and 800–900 °C (garnet–spinel peridotites) were calculated for the ultramafic rocks. After emplacement of the mantle rocks, exhumation of the lower crust took place to a depth corresponding to 0.2–0.3 GPa. The temperatures of the incorporated peridotite slices were still high (900–1000 °C) at this stage. This is indicated by the presence of high- T  /low- P parageneses ( c . 800 °C, 0.2–0.3 GPa) in a small (1–10 m) contact aureole around a former garnet peridotite. Crustal rocks distant to the peridotites equilibrated in the same pressure range at lower temperature (650–700 °C). High cooling rates (102–103 °C Ma−1) were calculated for a garnet–biotite rock inclusion in the peridotites and for the crustal rocks at the contact by applying garnet–biotite diffusion modelling. Minimum rates of 0.75–7.5 cm a−1 are required for vertical ascent of rock units (30 km vertical distance) derived from the crust–mantle boundary, resulting in a late Variscan (340 Ma) high- T  /low- P event.  相似文献   

18.
The Western Alps are a classic subduction-related collisional orogen with well-preserved, deeply subducted ophiolitic remnants of oceanic lithosphere. Some (e.g. Monviso, Voltri) were recognized as a palaeo-subduction channel, with tectonic blocks showing a wide range of pressure–temperature conditions. We herein evaluate for the first time the metamorphic homogeneity of the extensive Zermatt-Saas ophiolite. Zermatt-Saas peak eclogitic assemblages are represented by omphacite–garnet ± phengite ± epidote ± lawsonite ± glaucophane in MORB-derived metabasalts and garnet–chloritoid–talc ± lawsonite ± phengite in hydrothermalized metabasalts. Thermobarometric estimates with thermocalc and Raman Spectroscopy of carbonaceous material reveal homogeneous peak burial conditions at around 540 ± 20 °C and 23 ± 1 kbar. P – T paths indicate that the whole of the ophiolite, at least 60 km across, strikingly underwent similar burial and exhumation patterns and detached from the slab at depths around 80 km. The Zermatt-Saas ophiolite thus appears to be the world's largest oceanic lithosphere fragment exhumed from such depths, which provides important constraints on interplate coupling mechanisms.  相似文献   

19.
Bimodal metavolcanic rocks, granitic gneisses and metasediments are associated in the Frankenberg massif, Germany. These rocks are faulted against underlying very low-grade Palaeozoic sequences and adjacent metamorphic complexes of the Variscan basement. The granitic gneisses record an Rb–Sr whole-rock isochron age of 461±20  Ma that is taken as at least a minimum protolith age. The bimodal meta-igneous suites are interpreted to have formed during rifting of the Gondwana continental margin in the Cambro-Ordovician. The various metamorphic units have all experienced a common P–T  history. The peak-pressure stage is constrained to around 490–520  °C and 10–14  kbar (10–12  kbar being most realistic). The metamorphism proceeded along a clockwise P–T path towards conditions of around 580–610  °C and 7–8.5  kbar at the thermal peak followed by a final low-pressure overprint which spanned amphibolite facies to prehnite–actinolite facies temperatures. Owing to a secondary Rb–Sr whole-rock isochron age of 381±24  Ma, interpreted to date the retrograde stage, the whole metamorphic cycle in the Frankenberg massif is ascribed to the late Silurian–early Devonian high-pressure event widely recorded in the European Variscides. The antiformal complexes bordering the Frankenberg massif underwent a well-documented early Carboniferous metamorphism, suggesting that the Frankenberg massif constitutes a klippe which was overthrust towards the end of this second metamorphic cycle.  相似文献   

20.
Chemical disequilibrium exists between all phases of the Alpe Arami garnet-peridotite body (Ticino, Switzerland) which hampers the evaluation of P–T  conditions of origin, yet disequilibrium offers the inherent possibility to derive a P–T–t path for this mantle slice. We tried to tackle this problem by carrying out new mineral analyses and taking diffusion rates and bulk-rock compositional effects into consideration. Peak metamorphic conditions from mineral core compositions were estimated as 1120±50 °C/5±0.2 GPa. These values are significantly higher than previously published results and were determined from a combination of the O'Neill & Wood (1979) Fe/Mg garnet–olivine exchange thermometer and the Al-in-orthopyroxene barometer (Brey & Köhler, 1990), and are supported by the Ca/Cr ratios in garnet, which are in accord with these conditions. Details of the exhumation path were derived from (1) rim compositions of minerals that yield a first retrograde stage of 720±50 °C/2±0.25 GPa (2) a spinel lherzolite assemblage in narrow shear zones (tectonic phase F0', after Möckel, 1969) which documents a second retrograde stage at 500–600 °C/0.8–1.5 GPa. The Ca content in olivine (Köhler & Brey, 1989) can be used to evaluate further P–T  conditions along the retrograde path. We measured very low values (30–40  ppm Ca) in the cores of olivine and a remarkable increase towards the rim (120  ppm). The low core values may reflect an equilibrium stage during the main Alpine metamorphism. The increasing values towards the olivine rims probably represent a late-stage heating event. The initial cooling rates for the peridotite body are between 2700 and 5100 °C Ma−1, depending on which diffusion data are used.  相似文献   

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