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1.
Calcium sulfate (CaSO4), one of the major sulfate minerals in the Earth’s crust, is expected to play a major role in sulfur recycling into the deep mantle. Here, we investigated the crystal structure and phase relation of CaSO4 up to ~90 GPa and 2300 K through a series of high-pressure experiments combined with in situ X-ray diffraction. CaSO4 forms three thermodynamically stable polymorphs: anhydrite (stable below 3 GPa), monazite-type phase (stable between 3 and ~13 GPa) and barite-type phase (stable up to at least 93 GPa). Anhydrite to monazite-type phase transition is induced by pressure even at room temperature, while monazite- to barite-type transition requires heating at least to 1500 K at ~20 GPa. The barite-type phase cannot always be quenched from high temperature and is distorted to metastable AgMnO4-type structure or another modified barite structure depending on pressure. We obtained the pressure–volume data and density of anhydrite, monazite- and barite-type phases and found that their densities are lower than those calculated from the PREM model in the studied P–T conditions. This suggests that CaSO4 is gravitationally unstable in the mantle and fluid/melt phase into which sulfur dissolves and/or sulfate–sulfide speciation may play a major role in the sulfur recycling into the deep Earth. 相似文献
2.
<正>Objective The Susong complex zone(SCZ)is a relatively lowgrade metamorphic unit mostly with an epidoteamphibolite facies,located in the southernmost part of the Dabie orogen.However,its rock compositions,ages,metamorphic processes and petrogenesis are still 相似文献
3.
4.
Yasuhiro Kuwayama Toshimitsu Sawai Kei Hirose Nagayoshi Sata Yasuo Ohishi 《Physics and Chemistry of Minerals》2009,36(9):511-518
The phase relations of Fe-6.4 wt% Si and Fe-9.9 wt% Si have been investigated up to 130 GPa and 2,600 K based on in situ synchrotron
X-ray diffraction measurements in a laser-heated diamond-anvil cell along with chemical analysis of the quenched samples using
a field-emission electron probe microanalyzer. We found that the maximum solubility of silicon in solid hcp-iron increases
with increasing pressure. Linear extrapolation of the phase boundary between hcp + B2 and hcp phases for Fe-9.9 wt% Si suggests
that the solid hcp-iron can include more than 9.9 wt% Si at the Earth’s inner-core conditions. If silicon is a major light
element in the outer core, a substantial amount of silicon may be incorporated into the inner core during inner-core solidification. 相似文献
5.
The high-pressure structural evolution of hemimorphite, Zn4Si2O7(OH)2·H2O, a = 8.3881(13), b = 10.7179(11), c = 5.1311(9) Å, V = 461.30(12) Å3, space group Imm2, Z = 2, was studied by single-crystal X-ray diffraction with a diamond anvil cell under hydrostatic conditions up to 4.2 GPa. In the pressure range of 0.0001–2.44 GPa, the unit-cell parameters change almost linearly. The phase transition (probably of the second order) with symmetry reduction from Imm2 (hemimorphite-I) to Pnn2 (hemimorphite-II) was found near 2.5 GPa. The structure compressibility increases somewhat above the phase transition. Namely, the initial unit-cell volume decreases by 3.6% at 2.44 GPa and by 7.2% at 4.20 GPa. The hemimorphite framework can be described as built up of secondary building units (SBU) Zn4Si2O7(OH)2. These blocks are combined to form the rods arranged along the c-axis; these rods are multiplied by basic and I-translations of orthorhombic unit cell. The symmetry reduction is caused by the rotation of the rods along their axis. In hemimorphite-I, the compression affects mainly the SBU dimensions, whereas a rectangular section of the channels having mm2 symmetry remains practically unchanged. An appreciable decrease in this section in hemimorphite-II is determined by its oblique distortion with the loss of m planes. It results from opposite rotation of adjacent SBU, which also leads into the loss of I-translation. In hemimorphite-I, the coordination of H2O molecules is fourfold planar; the hydrogen-bonded hydroxyls and H2O molecules form infinite ribbons along the c-axis. In hemimorphite-II, an additional short H2O–O contact appears as a result of asymmetric deformation of the channels. The appearance of this new contact provides the possibility for re-orientation of hydrogen bonds. The planar coordination of H2O molecules changes to tetrahedral and the ribbons are transformed to islands (OH)2–H2O. 相似文献
6.
The methods of deriving Fe O and Ti O_2 contents from the Clementine spacecraft data were discussed,and an approach was developed to derive the content from the measurements using the Moon Mineralogy Mapper (M~3) instrument on Chandrayaan-1.The density of lunar bedrock was then modeled on the basis of the derived Fe O and Ti O_2 abundances.The Fe O and Ti O_2 abundances derived from the M~3 data were compared with the previous results of the Clementine data and were in good agreement.The Fe O abundance data also agreed well with the Lunar Prospector data,which were used as an independent source.The previous Clementine and newly M~3 derived abundances were compared with the laboratory measured Fe O and Ti O_2 contents in the Apollo and Luna returned samples.The Clementine derived Fe O content was systematically 1%–2%lower than the laboratory measurements in all the returned samples.The M~3 derived content agreed well with the returned Apollo samples and was within±2.8%of the laboratory measurements.The Clementine derived Ti O_2abundance was systematically 0.1%–4%higher than the laboratory measurements of the returned samples.The M~3 derived Ti O_2 agreed well (±0.6%) with the laboratory measurements of the returned samples,except for samples with high Ti O_2content.However,these results should be carefully interpreted because the error range requires verification.No error analysis was provided with the previous Clementine derived contents. 相似文献
7.
M. Kumar 《Physics and Chemistry of Minerals》2000,27(9):650-655
A simple theoretical method for the determination of equation of state and bulk modulus under the effect of pressure and
temperature is investigated. The calculations are performed for MgO and Mg2SiO4 at different temperatures and atmospheric pressure. The results obtained are discussed in the light of recent research on
minerals under the effect of high temperatures. A good agreement between theory and experiment is obtained. The method is
also discussed to predict the equation of state and bulk modulus at different pressures along the isotherms 300, 1000, 1500
and 2000 K for MgO. The results are found to present a good agreement with the studies based on ab initio calculations at
high pressures and high temperatures.
Received: 26 May 1998 / Accepted: 22 April 2000 相似文献
8.
Malcolm W. Clark Frank Gnanam David M. McConchie Lee Fergusson 《中国地球化学学报》2006,25(B08):141-141
Bauxsol（TM） is a trade marked name for a modified bauxite refining residue where Ca and Mg are used to transform carbonate and hydroxide alkalinity from soluble to insoluble forms within the bauxite refinery residue （red mud）, This leads to a pH reduction from 〉13 to ≈8.5 and reduces soluble Al and Na contents. The concentration ratios of Ca and Mg in the treatment brine can be manipulated to provide neo-formational mineral assemblages dominated by either Mg, or Ca end members; hydrotalcite and brucite （Mg-rich）, or hydrocalumite, para-aluminohydrocalcite, aragonite and portlandite （Ca-rich）. The Bauxsol（TM） raw material （BRM） has excellent metal binding capacity （〉1500 meq/kg）, good P binding capacity （〉2% by mass） and a good acid neutralising capacity （3.5-7 M/kg）, however the BRM can be further blended with other mineral additives to enhance the geochemical properties and improve specific performance. This paper reports on the use of a high-Mg Bauxsol（TM） blend to treat waters that have high P, NH4＋ and polyacrylamide （flocculant） loadings in Biological Nutrient Reduction （BNR） plant digested sewage sludge centrates. Initial analysis of the centrate indicated it contained 325 mg/L total-P （225 mg/L P as ortho-P）, 767 mg/L N as NH4^＋, suspended solids loads （TSS） of 683 mg/L and chemical oxygen demand （COD） of 480 mg/L （although the day to day variability in nutrient loadings can be as much as 25%）. This was then treated using 1.7 g/L of a high-Mg Bauxsol （TM） blend to yield a water with 〈1.8 mg/L total-P （ortho-P is 〈0.5 mg/L）, NH4^＋ 〈460 mg/L N, 〈60 mg/L TSS, and 〈300 mg/L COD. Small additions of ferric chloride post Bauxsol （TM） addition reduced the soluble ortho-P load by about 50% and about 30% of the COD, but these additions appear largely unnecessary. Analysis of the solid residue indicates it contains 11.5% P, 0.39% N, 21% Mg, and 2.44% crude protein making the solid residue a potentially useful fertilizer. It is likely that P and NH4^＋ is affected by the formation of MgHPO4 and Mg （NH4）PO4 （Struvite） within the solids. Calculations from the solids indicate that 85% of the P removal is as MgHPO4, which appears consistent with literature on the formation geochemistry of struvite around pH 8.0. Further manipulation of the geochemistry of waters and kinetics of crystal growth may allow for a greater struvite recovery, and further enhanced ammonia removal. The treated centrate is then reported back to the head of works and solids are removed with the sludge at the primary and secondary clarifier. 相似文献
9.
Pierre Goovaerts 《Mathematical Geosciences》2008,40(1):101-128
This paper presents a methodology to conduct geostatistical variography and interpolation on areal data measured over geographical units (or blocks) with different sizes and shapes, while accounting for heterogeneous weight or kernel functions within those units. The deconvolution method is iterative and seeks the point-support model that minimizes the difference between the theoretically regularized semivariogram model and the model fitted to areal data. This model is then used in area-to-point (ATP) kriging to map the spatial distribution of the attribute of interest within each geographical unit. The coherence constraint ensures that the weighted average of kriged estimates equals the areal datum.This approach is illustrated using health data (cancer rates aggregated at the county level) and population density surface as a kernel function. Simulations are conducted over two regions with contrasting county geographies: the state of Indiana and four states in the Western United States. In both regions, the deconvolution approach yields a point support semivariogram model that is reasonably close to the semivariogram of simulated point values. The use of this model in ATP kriging yields a more accurate prediction than a naïve point kriging of areal data that simply collapses each county into its geographic centroid. ATP kriging reduces the smoothing effect and is robust with respect to small differences in the point support semivariogram model. Important features of the point-support semivariogram, such as the nugget effect, can never be fully validated from areal data. The user may want to narrow down the set of solutions based on his knowledge of the phenomenon (e.g., set the nugget effect to zero). The approach presented avoids the visual bias associated with the interpretation of choropleth maps and should facilitate the analysis of relationships between variables measured over different spatial supports. 相似文献
10.
The paper deals with the approximation and optimal interpolation of functions defined on the bisphere
\mathbb S2×\mathbb S2\mathbb {S}^{2}\times \mathbb {S}^{2} from scattered data. We demonstrate how the least square approximation to the function can be computed in a stable and efficient
manner. The analysis of this problem is based on Marcinkiewicz–Zygmund inequalities for scattered data which we present here
for the bisphere. The complementary problem of optimal interpolation is also solved by using well-localized kernels for our
setting. Finally, we discuss the application of the developed methods to problems of texture analysis in material science. 相似文献
11.
The Tau Model for Data Redundancy and Information Combination in Earth Sciences: Theory and Application 总被引：3，自引：0，他引：3
Sunderrajan Krishnan 《Mathematical Geosciences》2008,40(6):705-727
Many decision-making processes in the Earth sciences require the combination of multiple data originating from diverse sources.
These data are often indirect and uncertain, and their combination would call for a probabilistic approach. These data are
also partially redundant with each other or with all others taken jointly. This overlap in information arises due to a variety
of reasons—because the data arises from the same geology, because they originate from the same location or the same measurement
device, etc. The proposed tau model combines partially redundant data, each taking the form of a prior probability for the
event being assessed to occur given that single datum. The parameters of that tau model measure the additional contribution
brought by any single datum over that of all previously considered data; they are data sequence-dependent and also data value-dependent.
Data redundancy depends on the sequence in which the data is considered and also on the data values themselves. However, for
a given sequence, averaging the tau model parameters over all possible data values leads to exact analytical expressions and
corresponding approximations and inference avenues. Information on multiple-point connectivity of permeability arrives from
core data, well-test data and seismic data which are defined over varying supports with complex redundancy between these information
sources. In order to compute these tau weights for determining connectivity, one needs a model of data redundancy, here expressed
as a vectorial training image (Ti) constructed using a prior conceptual knowledge of geology and the physics of data measurement.
From such a vectorial Ti, the tau weights can be computed exactly. Neglecting data redundancy leads to an over-compounding
of individual data information and the possible risk of making extreme decisions. 相似文献
12.
A great deal of early-to-mid Early Cretaceous magmatic activities have been recorded in the Zhalantun area of Inner Mongolia,while the late Early to Late Cretaceous magmatic rocks have been barely reported(Guo et al.,2018;Zhang Xiangxin et al.,2017).At present,only a few Late Cretaceous magmatic activities were reported in the Arongqi area,such as volcanic rocks of the Gushanzhen Formation.However,the Gushanzhen Formation lacks accurate isotopic age,and contemporaneous intrusive rocks has not been reported yet.In this work,we collected the volcanic rocks from the Gushanzhen Formation and contemporaneous intrusive rocks in the Zhanlantun and nearby,and aim to figure out the formation ages of volcanic rocks of the Gushanzhen Formation and accompanied intrusive rocks by analyzing zircon U-Pb isotopes(Fig.1). 相似文献
13.
Representing Spatial Uncertainty Using Distances and Kernels 总被引：8，自引：7，他引：1
Assessing uncertainty of a spatial phenomenon requires the analysis of a large number of parameters which must be processed
by a transfer function. To capture the possibly of a wide range of uncertainty in the transfer function response, a large
set of geostatistical model realizations needs to be processed. Stochastic spatial simulation can rapidly provide multiple,
equally probable realizations. However, since the transfer function is often computationally demanding, only a small number
of models can be evaluated in practice, and are usually selected through a ranking procedure. Traditional ranking techniques
for selection of probabilistic ranges of response (P10, P50 and P90) are highly dependent on the static property used. In
this paper, we propose to parameterize the spatial uncertainty represented by a large set of geostatistical realizations through
a distance function measuring “dissimilarity” between any two geostatistical realizations. The distance function allows a
mapping of the space of uncertainty. The distance can be tailored to the particular problem. The multi-dimensional space of
uncertainty can be modeled using kernel techniques, such as kernel principal component analysis (KPCA) or kernel clustering.
These tools allow for the selection of a subset of representative realizations containing similar properties to the larger
set. Without losing accuracy, decisions and strategies can then be performed applying a transfer function on the subset without
the need to exhaustively evaluate each realization. This method is applied to a synthetic oil reservoir, where spatial uncertainty
of channel facies is modeled through multiple realizations generated using a multi-point geostatistical algorithm and several
training images. 相似文献
14.
Caroline Bollinger Paul Raterron Olivier Castelnau Fabrice Detrez Sébastien Merkel 《Physics and Chemistry of Minerals》2016,43(6):409-417
We report results from axisymmetric deformation experiments carried out on forsterite aggregates in the deformation-DIA apparatus, at upper mantle pressures and temperatures (3.1–8.1 GPa, 1373–1673 K). We quantified the resulting lattice preferred orientations (LPO) and compare experimental observations with results from micromechanical modeling (viscoplastic second-order self-consistent model—SO). Up to 6 GPa (~185-km depth in the Earth), we observe a marked LPO consistent with a dominant slip in the (010) plane with one observation of a dominant [100] direction, suggesting that [100](010) slip system was strongly activated. At higher pressures (deeper depth), the LPO becomes less marked and more complex with no evidence of a dominant slip system, which we attribute to the activation of several concurrent slip systems. These results are consistent with the pressure-induced transition in the dominant slip system previously reported for olivine and forsterite. They are also consistent with the decrease in the seismic anisotropy amplitude observed in the Earth’s mantle at depth greater than ~200 km. 相似文献
15.
Based on the fracture trace length distribution, conditions for the existence, uniqueness, and correctness of the fracture diameter distribution are given using Warburton’s fracture model. In particular, a solution for the fracture diameter distribution exists and is unique for all trace length probability density functions, h A (y), such that \(h_{A}(y)/\sqrt{y^{2}-x^{2}}\) is Lebesgue integrable on [x,∞). This condition is met by the uniform, exponential, gamma, lognormal, and power-law trace length distributions as well as by the trace length distributions that arise from a deterministic fracture diameter or from a discontinuous fracture diameter length distribution. Exponential, gamma, lognormal, and power-law trace length distributions satisfy necessary conditions for the diameter distribution to be non-negative, and necessary and sufficient conditions for the distribution to have unit integral over the real line. Negative values of the fracture diameter distribution arise when the trace has a uniform distribution and the lower bound of the fracture trace is greater than zero. 相似文献
16.
In this paper we consider an anisotropic scaling approach to understanding rock density and surface gravity which naturally
accounts for wide range variability and anomalies at all scales. This approach is empirically justified by the growing body
of evidence that geophysical fields including topography and density are scaling over wide range ranges. Theoretically it
is justified, since scale invariance is a (geo)dynamical symmetry principle which is expected to hold in the absence of symmetry
breaking mechanisms. Unfortunately, to date most scaling approaches have been self-similar, i.e., they have assumed not only
scale invariant but also isotropic dynamics. In contrast, most nonscaling approaches recognize the anisotropy (e.g., the strata),
but implicitly assume that the latter is independent of scale. In this paper, we argue that the dynamics are scaling but highly
anisotropic, i.e., with scale dependent differential anisotropy.
By using empirical density statistics in the crust and a statistical theory of high Prandtl number convection in the mantle,
we argue that
is a reasonable model for the 3-D spectrum (K is the horizontal wavevector and K is its modulus, k
z
is a vertical wavenumber), (s,H
z
) are fundamental exponents which we estimate as (5.3,3), (3,3) in the crust and mantle, respectively. We theoretically derive
expressions for the corresponding surface gravity spectrum. For scales smaller than ≈100 km, the anisotropic crust model of
the density (with flat top and bottom) using empirically determined vertical and horizontal density spectra is sufficient
to explain the (Bouguer) g
z
spectra. However, the crust thickness is highly variable and the crust-mantle density contrast is very large. By considering
isostatic equilibrium, and using global gravity and topography data, we show that this thickness variability is the dominant
contribution to the surface g
z
spectrum over the range ≈100–1000 km. Using estimates of mantle properties (viscosity, thermal conductivity, thermal expansion
coefficient, etc.), we show that the mantle contribution to the mean spectrum is strongest at ≈1000 km and is comparable to
the variable crust thickness contribution. Overall, we produce a model which is compatible with both the observed (horizontal
and vertical) density heterogeneity and surface gravity anomaly statistics over a range of meters to several thousand kilometers. 相似文献
17.
Norboo Tsering 《中国地球化学学报》2006,25(B08):69-69
Background： Radiographic signs of Pneumoconiosis found in farming Ladakhi despite absences of mines and industries were believed to be due to exposure to frequent dust storms and domestic fire pollutions. Seasonal Koilonychia （spoon nail） occurring predominantly in farming women in absences of iron deficiency anaemia was thought to arise from exposure to water made alkaline by weathering of hornblende minerals. The relation of these health conditions to environmental geohydrochemistry is postulated as the source of irrigation water in the affected population originates from glaciers in trans-Himalaya range of sedimentary geology and steep landscape favouring flushing of silica/silicate containing silts. Methods and results： Survey in two central Ladakh villages revealed radiographic evidence of silicosis in all middle aged women and half in middle aged men. In a large-scale study of 3105 subjects aged over 30 years from three villages; 101 （22.5%） of the 449 radiographed showed signs of pneumoconiosis （ILO 1980 criteria） including eggshell calcification of hilar gland and progressive massive fibrosis. Indoor dust analyzed using Philips 400T electron microscope with energy dispersive analysis system attached showed SiO2 levels upto 53.27% with particle size of 0.5 to 5.0 microns and the concentration during cooking period in the worst affected area was 7.495 mg/m^3. Microscopy and histopathology from the subject was characteristic of pneumoconiosis. Analysis of the inorganic dust in the lung showed 40.2% muscovite, 37.3% quartz with the extracted dust wt 147.9 mg/gm of dry tissue. Prevalence of chronic cough with chronic phlegm and percentage of villagers with FEV1/FVC ratio of less than 65% rose with age. Of 70 subjects studied 19 women and 2 men had Koilonychia with incidence being highest in summer. Absence of seasonal Koilonychia in villages fed by water derived from northern mountain range glaciers with mainly igneous geology supports our hypothesis. 相似文献
18.
19.
Modelling Syntectonic Sedimentation: Combining a Discrete Element Model of Tectonic Deformation and a Process-based Sedimentary Model in 3D 总被引：1，自引：0，他引：1
This paper presents a new numerical program able to model syntectonic sedimentation. The new model combines a discrete element
model of the tectonic deformation of a sedimentary cover and a process-based model of sedimentation in a single framework.
The integration of these two methods allows us to include the simulation of both sedimentation and deformation processes in
a single and more effective model. The paper describes briefly the antecedents of the program, Simsafadim-Clastic and a discrete
element model, in order to introduce the methodology used to merge both programs to create the new code. To illustrate the
operation and application of the program, analysis of the evolution of syntectonic geometries in an extensional environment
and also associated with thrust fault propagation is undertaken. Using the new code, much more complex and realistic depositional
structures can be simulated together with a more complex analysis of the evolution of the deformation within the sedimentary
cover, which is seen to be affected by the presence of the new syntectonic sediments. 相似文献
20.
Hugo A. Loáiciga 《Mathematical Geosciences》2008,40(2):199-211
The equation of groundwater flow in marine island aquifers in which there is time-independent, spatially-variable recharge
and pumping is solved in closed form for rectangular, circular, and elliptical island geometries. The solution of the groundwater
flow equation is expressed in terms of the elevation of the phreatic surface within the flow domain. The depth of the seawater-freshwater
interface below mean sea level follows from the Dupuit–Ghyben–Herzberg relation. The method of solution presented in this
work relies on expanding the hydraulic head and forcing function (recharge and groundwater extraction) as Fourier series that
transforms the two-dimensional Poisson-type flow equations into second-order ordinary differential equations solvable using
classical theory. The important case of constant recharge (without groundwater extraction) leads to solutions in which the
hydraulic head is expressible as the product of a flow factor equal to the squared root of the ratio of recharge over hydraulic
conductivity times a geometric factor involving island shape parameters and flow boundary conditions. Estimability conditions
for the hydraulic conductivity are derived for the cases of constant recharge and spatially variable recharge with pumping. 相似文献