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1.
The Tyro and Bannock Basins, which are depressions in the eastern Mediterranean, contain hypersaline anoxic brines. These brines are of different composition: Tyro brine is primarily an early-stage halite (NaCl) brine, whereas Bannock brine includes the more soluble ions of late-stage evaporite minerals. Accordingly, the Bannock brine contains a much greater sulphate concentration than the Tyro Brine. This difference in sulphate concentration is reflected in the concentrations of ions such as Ca, Sr and Ba, which form sparingly soluble sulphate minerals.Equilibrium calculations using the Pitzer specific ion interaction model indicate that the brines in both basins are saturated with respect to gypsum (CaSO4-2H2O) and supersaturated to saturated with respect to dolomite (CaMg(CO3)2). The degree of saturation with respect to dolomite is greater in the Bannock Basin than it is in the Tyro Basin. Correspondingly, recent gypsum crystals and dolomite hardgrounds have been found in the Bannock Basin but not in the Tyro Basin.The Tyro brine is homogeneous in composition, whereas the Bannock brine demonstrates a clear two-layer brine structure. At the interface of the upper and the lower brine distinct positive anomalies occur in the total alkalinity and the concentration of phosphate, and negative anomalies occur in the concentrations of Mn2+ and the rare earth elements (REE). These anomalies and the observed association of gypsum/dolomite in the sediments are all consistent with a recent precipitation of dolomite and gypsum in the Bannock Basin. The brines in both basins are also saturated with respect to barite (BaSO4).The 87Sr/86Sr and δ34S ratios of the Bannock brines are amazingly consistent but differ dramatically from the values for modern or Messinian-age seawater. The Sr concentration and Sr and S isotope ratios in the gypsum crystals indicate that most of these crystals have resulted from precipitation/recrystallization from the brine and not from seawater. The observed variations between crystals are thought to reflect the recrystallization of (sub-) outcropping Messinian gypsum with a low 87Sr/86Sr ratio in the presence of seawater or brine fluids and with different extents of diagenesis.  相似文献   

2.
Iodate (IO3−) is the predominant dissolved species of iodine in the oxygenated waters of the Mediterranean Sea. Iodide (I−) is present in significant quantities (up to 65 nM) in oxygenated waters in the photic zone and near the interface above the anoxic and saline Bannock Basin. Lesser quantities of I− (< 10 nM) are found throughout the rest of the oxic water column. An additional unidentified dissolved iodine species is present immediately above the anoxic interface.Total dissolved iodine (ΣI) increases dramatically across the seawater/brine interface. Part of this increase is undoubtedly the result of the dissolution of iodine-rich evaporites during formation of the brine bodies at the Tyro and Bannock Basins. The vertical distribution of ΣI and other dissolved chemical species (particularly PO43−) in the Bannock Basin brine, however, suggests an additional, present-day, diagenetic source of dissolved iodine to the brine. Based on the increase in the concentration of the most soluble major ions across the seawater/brine interface, 5–7 μM of the 11.5-μM increase in ΣI concentration must be attributed to diagenesis.  相似文献   

3.
Seawater and brine samples collected along vertical profiles above the Bannock and Tyro Basins (eastern Mediterranean), and gypsum samples collected by dredging and coring the anoxic section of the Bannock Basin, have been studied for their δ18O values. The following conclusions may be drawn from these data: (1) The water of the deep brines is isotopically slightly different from modern Mediterranean bottom water and might be a ‘fossil water’ possibly formed during a recent, climatically cooler stage or when the evaporation was slightly higher than nowadays. (2) The similarity between the δ18O values of the brine samples from the Bannock and Tyro Basins supports the possibility that the ages of the two basins are very close to each other. (3) Gypsum crystals on the bottom of the Bannock Basin are probably being formed by the dissolution and reprecipitation of sub-bottom (or outcropping) Messinian evaporites. This hypothesis is supported by the oxygen isotopic values exhibited by the gypsum crystallization water and by the oxygen and sulphur isotopic composition of gypsum. (4) The shells of pelagic organisms included in gypsum are probably very recent, but not contemporary, and may be referred to cooler environmental conditions.  相似文献   

4.
The aqueous speciation of rhenium at the temperatures on or near the Earth's surface, especially in anoxic environments, is not well known. For the first time, the relative importance of ReO4− and the neutral rhenium species, Re(OH)40, is thermodynamically modeled in anoxic environments at ambient temperature where ReS2 or its solid solution(s) is likely to control the solubility. This thermodynamic model suggests that ReO4− is an insignificant species in anoxic environments. In comparison to observed total rhenium concentrations in anoxic waters (from ∼3 to ∼30 pmol/kg), the contribution from ReO4− would be less than 10−8 ppb (∼4×10−5 pmol/kg). In contrast, the neutral rhenium species is an important species in anoxic environments. At ΣH2S=10−4 molal, 10−2 ppb (∼40 pmol/kg) of Re(OH)40 can exist in equilibrium with ReS2 in the HS− field at a pH of about 9 or under the oxygen fugacity conditions imposed by the HS−/SO42− redox couple, demonstrating its importance in anoxic environments. Applications of the present study to the Black Sea indicate that rhenium concentrations in the anoxic water column at depths ranging from 105 to ∼390 m can be successfully modeled as Re(OH)40, implying that the dominant species in solution may be Re(OH)40.  相似文献   

5.
Data on temporal variations of total dimethylsulfoniopropionate (DMSPt) and the environmental factors that influence DMSPt concentrations are important in understanding the biogeochemical cycling of organic sulfur compounds. Annual and diurnal variations of DMSPt were investigated in relation to environmental variables at a fixed station in Dona Paula bay (west coast of India). DMSP concentrations were high in the day and low at night and ranged from 3.69 to 84 nM with a maximum at 17.00 h. The high concentrations of DMSPt during daytime closely followed that of Chl a concentrations. The DMSP utilizers averaged 0.8 ± 0.3 × 103 cells l?1 during night and 0.4 ± 0.1 × 103 cells l?1 during the day. The diel variation of DMSPt was influenced more by biological variables than hydrographic parameters. In the year-round study, the concentrations ranged from 0.69 to 15.8 nM. It was fourfold higher during the southwest monsoon season (13.4 ± 2 nM) and threefold higher during the post-monsoon season (9.96 ± 5 nM) compared to the pre-monsoon season (3.1 ± 1 nM). DMSPt concentrations showed temporal variability, both during diurnal and annual studies. Diatoms were identified as producers of DMSP in Dona Paula bay. Dinoflagellates also contributed during the non-monsoon seasons. Another factor involved in the variability of DMSPt was DMSP utilizing bacteria, which ranged from 1 to 10% of the total heterotrophic count.  相似文献   

6.
《Marine Chemistry》2007,103(1-2):30-45
The chemistry of dissolved Fe(III) was studied in the Scheldt estuary (The Netherlands). Two discrete size fractions of the dissolved bulk (< 0.2 μm and < 1 kDa) were considered at three salinities (S = 26, 10 and 0.3).Within the upper estuary, where fresh river water meets seawater, the dissolved Fe concentration decreases steeply with increasing salinity, for the fraction < 0.2 μm from 536 nM at S = 0.3 to 104 nM at S = 10 and for the fraction < 1 kDa from 102 nM to 36 nM Fe. Further downstream, in the middle and lower estuary, this decrease in the Fe concentration continues, but is far less pronounced. For all samples, the traditionally recognised dissolved strong organic Fe-binding ligand concentrations are lower than the dissolved Fe concentrations.Characteristics of dissolved Fe-binding ligands were determined by observing kinetic interactions with adsorptive cathodic stripping voltammetry. From these kinetic experiments we concluded that apart from the well-known strong Fe-binding organic ligands (L, logK′ = 19–22) also weak Fe-binding ligands (P) existed with an α value (binding potential = K′ · [P]) varying between 1011.1 and 1011.9. The presence of this relatively weak ligand explained the high concentrations of labile Fe present in both size fractions in the estuary. This weak ligand can retard or prevent a direct precipitation after an extra input of Fe.The dissociation rate constants of the weak ligand varied between 0.5 × 10− 4 and 4.3 × 10− 4 s− 1. The rate constants of the strong organic ligand varied between kd = 1.5 × 10− 3–17 × 10− 2 s− 1 and kf = 2.2 × 108–2.7 × 109 M− 1 s− 1. The dissociation rate constant of freshly amorphous Fe-hydroxide was found to be between 4.3 × 10− 4 and 3.7 × 10− 3 s− 1, more labile or equal to the values found by Rose and Waite [Rose, A.L., Waite, T.D., 2003a. Kinetics of hydrolysis and precipitation of ferric iron in seawater. Environ. Sci. Technol., 37, 3897–3903.] for freshly precipitated Fe in seawater.Kinetic rate constants of Fe with the ligand TAC (2-(2-Thiazolylazo)-p-cresol) were also determined. The formation rate constant of Fe(TAC)2 varied between 0.1 × 108 and 3.6 × 108 M− 1 s− 1, the dissociation rate constant between 0.2 × 10− 5 and 17 × 10− 5 s− 1 for both S = 26 and S = 10. The conditional stability constant of Fe(TAC)2 (βFe(TAC)2′) varied between 22 and 23.4 for S = 10 and S = 26 more or less equal to that known from the literature (logβFe(TAC)2′ = 22.4; [Croot, P.L., Johansson, M., 2000. Determination of iron speciation by cathodic stripping voltammetry in seawater using the competing ligand 2-(2-Thiazolylazo)-p-cresol (TAC). Electroanalysis, 12, 565–576.]). However, at S = 0.3 the logβFe(TAC)2′ was 25.3, three orders of magnitude higher. Apparently the application of TAC to samples of low salinity can only be done when the correct βFe(TAC)2′ is known.  相似文献   

7.
Results of the chemical investigation on the Bannock and Tyro Basins are reported.Both basins were found to be hypersaline ( 10 times higher than salinity of normal seawater) and anoxic. In all investigated basins a region of transition, a few meters thick, was identified at depths > 3327 dbar. It is characterized by a sharp gradient of salinity, and all concentrations of analysed species increase strongly except for dissolved oxygen and nitrate, which immediately drop to zero. This region appears as a sharp boundary that prevents mixing. As a result, in the presence of organic matter, an anoxic condition developed with the complete depletion of dissolved oxygen. At the same time, hydrogen sulphide and ammonium accumulated within the brine. Between the Bannock and the Tyro brines differences occur in the measured concentrations of H2S, SO2−4, Ca2+ and NH3. There are some differences also within the Bannock area sub-basins.The Libeccio sub-basin, in the Bannock area, contains a double-layered brine: the upper layer is 140 dbar thick and the lower layer is 300 dbar thick. A second interface between upper and lower brines develops at a depth of 3500 dbar. Nearly all of the measured concentrations vs. depth show the double layer, with the exception of ammonium, the concentration of which remains nearly constant throughout the anoxic column. Profiles of the other species analyzed show remarkable differences on passing from the upper to the lower brine. Hydrogen sulphide, sulphate and fluoride concentrations appear constant and then increase at the second interface. The calcium concentration is also constant in the upper brine, but decreases at the second interface. Total alkalinity and phosphate concentrations show a maximum peak just below the first interface. However, after passing through the second interface all the chemical parameters exhibit an almost constant behaviour down to the bottom.Hypersaline conditions are attributed to the dissolution of Messinian evaporite, and anoxia is suggested to originate from the oxidation of organic matter present in sediments and from the absence of bottom water circulation in such a deep and enclosed environment.The chemical conditions can be summarized as follows: in the Libeccio Basin the values for the species analysed have the ranges: 39–321 psu for ‘salinity’, 8.2−6.5 for pH, 2.7–4.0 mM for total alkalinity, 0.2-0 mM for dissolved oxygen, 0–1669 μM for hydrogen sulphide, 0–198 μM for thiol, 31–99 mM for sulphate, 11–21 mM for calcium, 7–100 μM for fluoride, 0.2–3080 μM for ammonium, 5.8-0 μM for nitrite, 0.2–12 μM for phosphate and 8–130 μM for silicate.  相似文献   

8.
We discuss nitrous oxide (N2O) and methane (CH4) distributions in 49 vertical profiles covering the upper ∼300 m of the water column along two ∼13,500 km transects between ∼50°N and ∼52°S during the Atlantic Meridional Transect (AMT) programme (AMT cruises 12 and 13). Vertical N2O profiles were amenable to analysis on the basis of common features coincident with Longhurst provinces. In contrast, CH4 showed no such pattern. The most striking feature of the latitudinal depth distributions was a well-defined “plume” of exceptionally high N2O concentrations coincident with very low levels of CH4, located between ∼23.5°N and ∼23.5°S; this feature reflects the upwelling of deep waters containing N2O derived from nitrification, as identified by an analysis of N2O, apparent oxygen utilization (AOU) and NO3−, and presumably depleted in CH4 by bacterial oxidation. Sea-to-air emissions fluxes for a region equivalent to ∼42% of the Atlantic Ocean surface area were in the range 0.40–0.68 Tg N2O yr−1 and 0.81–1.43 Tg CH4 yr−1. Based on contemporary estimates of the global ocean source strengths of atmospheric N2O and CH4, the Atlantic Ocean could account for ∼6–15% and 4–13%, respectively, of these source totals. Given that the Atlantic Ocean accounts for around 20% of the global ocean surface, on unit area basis it appears that the Atlantic may be a slightly weaker source of atmospheric N2O than other ocean regions but it could make a somewhat larger contribution to marine-derived atmospheric CH4 than previously thought.  相似文献   

9.
Iron could play a key role in controlling phytoplankton biomass and productivity in high-nutrient, low-chlorophyll regions. As a part of the iron fertilization experiment carried out in the western subarctic Pacific from July to August 2004 (Subarctic Pacific iron Experiment for Ecosystem Dynamics Study II—SEEDS II), we analysed the concentrations of trace gases in the seawater for 12 d following iron fertilization. The mean concentrations of chlorophyll a in the mixed layer (5–30 m depth) increased from 0.94 to 2.81 μg L–1 for 8 d in the iron patch. The mean concentrations of methyl bromide (CH3Br; 5–30 m depth) increased from 6.4 to 13.4 pmol L–1 for 11 d; the in-patch concentration increased relative to the out-patch concentration. A linear correlation was observed between the concentrations of 19′-hexanoyloxyfucoxanthin, which is a biomarker of several prymnesiophytes, and CH3Br in the seawater. After fertilization, the air–sea flux of CH3Br inside the patch changed from influx to efflux from the ocean. There was no clear evidence for the increase in saturation anomaly of methyl chloride (CH3Cl) due to iron fertilization. Furthermore, CH3Cl fluxes did not show a tendency to increase after fertilization of the patch. In contrast to CH3Br, no change was observed in the concentrations of bromoform (in-patch day 11 and out-patch day 11: 1.7 and 1.7 pmol L–1), dibromomethane (2.1 and 2.2 pmol L–1), and dibromochloromethane (1.0 and 1.2 pmol L–1, respectively). The concentration of isoprene, which is known to have a relationship with chlorophyll a, did not change in this study. The responses of trace gases during SEEDS II differed from the previous findings (in situ iron enrichment experiment—EisenEx, Southern Ocean iron experiment—SOFeX, and Subarctic Ecosystem Response to Iron Enrichment Study—SERIES). Thus, in order to estimate the concomitant effect of iron fertilization on the climate, it is important to assess the induction of biological activity and the distributions/air–sea fluxes of trace gases by iron addition.  相似文献   

10.
《Marine Chemistry》2006,98(2-4):210-222
This study presents concentrations of dimethylsulphide (DMS) and its precursor compound dimethylsulphoniopropionate (DMSP) in a variety of sea ice and seawater habitats in the Antarctic Sea Ice Zone (ASIZ) during spring and summer. Sixty-two sea ice cores of pack and fast ice were collected from twenty-seven sites across an area of the eastern ASIZ (64°E to 110°E; and the Antarctic coastline north to 62°S). Concentrations of DMS in 81 sections of sea ice ranged from < 0.3 to 75 nM, with an average of 12 nM. DMSP in 60 whole sea ice cores ranged from 25 to 796 nM and showed a negative relationship with ice thickness (y = 125x− 0.8). Extremely high DMSP concentrations were found in 2 cores of rafted sea ice (2910 and 1110 nM). The relationship of DMSP with ice thickness (excluding rafted ice) suggests that the release of large amounts of DMSP during sea ice melting may occur in discrete areas defined by ice thickness distribution, and may produce ‘hot spots’ of elevated seawater DMS concentration of the order of 100 nM. During early summer across a 500 km transect through melting pack ice, elevated DMS concentrations (range 21–37 nM, mean 31 nM, n = 15) were found in surface seawater. This band of elevated DMS concentration appeared to have been associated with the release of sea ice DMS and DMSP rather than in situ production by an ice edge algal bloom, as chlorophyll a concentrations were relatively low (0.09–0.42 μg l− 1). During fast ice melting in the area of Davis station, Prydz Bay, sea ice DMSP was released mostly as extracellular DMSP, since intracellular DMSP was negligible in both hyposaline brine (5 ppt) and in a melt water lens (4–5 ppt), while extracellular DMSP concentrations were as high as 149 and 54 nM, respectively in these habitats. DMS in a melt water lens was relatively high at 11 nM. During the ice-free summer in the coastal Davis area, DMS concentrations in surface seawater were highest immediately following breakout of the fast ice cover in late December (range 5–14 nM), and then remained at relatively low concentrations through to late February (< 0.3–6 nM). These measurements support the view that the melting of Antarctic sea ice produces elevated seawater DMS due to release of sea ice DMS and DMSP.  相似文献   

11.
The chemical speciation of iron was determined in the Southern Ocean along a transect from 48 to 70°S at 20°E. Dissolved iron concentrations were low at 0.1–0.6 nM, with average concentrations of 0.25±0.13 nM. Organic iron complexing ligands were found to occur in excess of the dissolved iron concentration at 0.72±0.23 nM (equivalent to an excess of 0.5 nM), with a complex stability of log KFeL′=22.1±0.5 (on the basis of Fe3+ and L′). Ligand concentrations were higher in the upper water column (top 200 m) suggesting in situ production by microorganisms, and less at the surface consistent with photochemical breakdown. Our data are consistent with the presence of stable organic iron-complexing ligands in deep global ocean waters at a background level of ∼0.7 nM. It has been suggested that this might help stabilise iron at levels of ∼0.7 nM in deep ocean waters. However, much lower iron concentrations in the waters of the Southern Ocean suggest that these ligands do not prevent the removal of iron (by scavenging or biological uptake) to well below the concentration of these ligands. Scavenging reactions are probably inhibited by such ligand competition, so it is likely that biological uptake is the chief cause for the further removal of iron to these low levels in waters that suffer from very low iron inputs.  相似文献   

12.
The total organic carbon (TOC) and total inorganic carbon (CT) exchange between the Atlantic Ocean and the Mediterranean Sea was studied in the Strait of Gibraltar in September 1997. Samples were taken at eight stations from western and eastern entrances of the Strait and at the middle of the Strait (Tarifa Narrows). TOC was analyzed by a high-temperature catalytic oxidation method, and CT was calculated from alkalinity–pHT pairs and appropriate thermodynamic relationships. The results are used in a two-layer model of water mass exchange through the Strait, which includes the Atlantic inflow, the Mediterranean outflow and the interface layer in between. Our observations show a decrease of TOC and an increase of CT concentrations from the surface to the bottom: 71–132 μM C and 2068–2150 μmol kg−1 in the Surface Atlantic Water, 74–95 μM C and 2119–2148 μmol kg−1 in the North Atlantic Central Water, 63–116 μM C and 2123–2312 μmol kg−1 in the interface layer, and 61–78 μM C and 2307–2325 μmol kg−1 in the Mediterranean waters. However, within the Mediterranean outflow, we found that the concentrations of carbon were higher at the western side of the Strait (75–78 μM C, 2068–2318 μmol kg−1) than at the eastern side (61–69 μM C, 2082–2324 μmol kg−1). This difference is due to the mixing between the Atlantic inflow and the Mediterranean outflow on the west of the Strait, which results in a flux of organic carbon from the inflow to the outflow and an opposite flux of inorganic carbon. We estimate that the TOC input from the Atlantic Ocean to the Mediterranean Sea through the Strait of Gibraltar varies from (0.97±0.8)104 to (1.81±0.90)104 mol C s−1 (0.3×1012 to 0.56×1012 mol C yr−1), while outflow of inorganic carbon ranges from (12.5±0.4)104 to (15.6±0.4)104 mol C s−1 (3.99–4.90×1012 mol C yr−1). The high variability of carbon exchange within the Strait is due to the variability of vertical mixing between inflow and outflow along the Strait. The prevalence of organic carbon inflow and inorganic carbon outflow shows the Mediterranean Sea to be a basin of active remineralization of organic material.  相似文献   

13.
Hydrographic, geochemical, and direct velocity measurements along two zonal (7.5°N and 4.5°S) and two meridional (35°W and 4°W) lines occupied in January–March, 1993 in the Atlantic are combined in an inverse model to estimate the circulation. At 4.5°S, the Warm Water (potential temperature θ>4.5°C) originating from the South Atlantic enters the equatorial Atlantic, principally at the western boundary, in the thermocline-intensified North Brazil Undercurrent (33±2.7×106 m3 s−1 northward) and in the surface-intensified South Equatorial Current (8×106 m3 s−1 northward) located to the east of the North Brazil Undercurrent. The Ekman transport at 4.5°S is southward (10.7±1.5×106 m3 s−1). At 7.5°N, the Western Boundary Current (WBC) (17.9±2×106 m3 s−1) is weaker than at 4.5°S, and the northward flow of Warm Water in the WBC is complemented by the basin-wide Ekman flow (12.3±1.0×106 m3 s−1), the net contribution of the geostrophic interior flow of Warm Water being southward. The equatorial Ekman divergence drives a conversion of Thermocline Water (24.58⩽σ0<26.75) into Surface Water (σ0<24.58) of 7.5±0.5×106 m3 s−1, mostly occurring west of 35°W. The Deep Water of northern origin flows southward at 7.5°N in an energetic (48±3×106 m3 s−1) Deep Western Boundary Current (DWBC), whose transport is in part compensated by a northward recirculation (21±4.5×106 m3 s−1) in the Guiana Basin. At 4.5°S, the DWBC is much less energetic (27±7×106 m3 s−1 southward) than at 7.5°N. It is in part balanced by a deep northward recirculation east of which alternate circulation patterns suggest the existence of an anticyclonic gyre in the central Brazil Basin and a cyclonic gyre further east. The deep equatorial Atlantic is characterized by a convergence of Lower Deep Water (45.90⩽σ4<45.83), which creates an upward diapycnal transport of 11.0×106 m3 s−1 across σ4=45.83. The amplitude of this diapycnal transport is quite sensitive to the a priori hypotheses made in the inverse model. The amplitude of the meridional overturning cell is estimated to be 22×106 m3 s−1 at 7.5°N and 24×106 m3 s−1 at 4.5°S. Northward heat transports are in the range 1.26–1.50 PW at 7.5°N and 0.97–1.29 PW at 4.5°S with best estimates of 1.35 and 1.09 PW.  相似文献   

14.
We report dissolved iron (Fed) concentrations measured in the upper 600 m in the central region of the Gulf of California (GC) under spring conditions. Our results showed the complex nature of Fe cycling within the GC. In the northern region of the study area, surface waters were relatively enriched, with Fed concentrations >5.0 nM, which can be partially explained by an atmospheric source. These concentrations are 12 times higher than those found in the adjacent Pacific Ocean. In contrast, Fed depth profiles in the southern region did not show any Fed surface enrichment (concentrations <1.5 nM) because of particle scavenging and higher stratification of the water-column. The most southern station in our area of study was the most stratified and showed an excess Fed and PO4 with respect to NO3, conditions favorable for nitrogen fixation. This station also showed the least negative surface value of N* of all stations. However, despite the adequate levels of Fed and PO4 at that location, the surface temperature (22.6 °C) was probably not high enough for diazotrophs to develop. A slight increase in Fed levels in intermediate waters at the southern region was associated with the oxygen minimum zone. Finally, our results suggest that remineralization of organic matter is probably the major source of Fed in subsurface waters of the GC.  相似文献   

15.
《Marine Chemistry》2007,103(1-2):131-145
We have investigated submarine groundwater discharge to Nueces Bay (Texas) using naturally occurring Ra isotopes. Dissolved Ra activities in Nueces Bay are among the highest observed in coastal estuaries; as great as 2600 dpm m− 3 for 228Ra and 1000 dpm m− 3 for 226Ra. Using a combination of salt and Ra mass balances, we demonstrate that river discharge and bay bottom sediments cannot supply the Ra needed to balance tidal export. In the case of 226Ra there is an additional source of 218 × 106 ± 105% dpm day− 1 which is 9 times the maximum supply from bay bottom sediments and 50 times the Ra supplied by the Nueces River. A groundwater flux of 310,000 m3 day− 1 is required to supply the needed 226Ra, based on the measured maximum Ra activity of local groundwater. Though as little as 10% of this flux may be advecting terrestrial groundwater this would still represent 160% of the Nueces River discharge. This makes it unlikely that groundwater discharge alone is supplying all of the additional 226Ra. Oil-field brine could potentially account for the remainder. Leakage of 6290 m3 day− 1 of oil-field brine from the submerged petroleum wells and pipelines within the bay could supply all of the needed 226Ra. Such large fluxes of brackish groundwater and oil-field brine could significantly affect bay nitrogen budgets, salinities, and dissolved oxygen concentrations and should be considered when determining the freshwater inflow requirements for Nueces Bay and similar estuaries.  相似文献   

16.
Concentrations of dissolved Al and Fe in the surface mixed layer were measured during five cruises of the 1995 US JGOFS Arabian Sea Process Study, Concentrations of both Al and Fe were relatively uniform between January and April, the NE Monsoon and the Spring Intermonsoon period, ranging from 2 to 11 nM Al (mean 5.3 nM) and 0.5 to 2.4 nM Fe (mean 1.0 nM). In July/August, after the onset of the SW Monsoon, surface water Al and Fe concentrations increased significantly (Al range 4.5–20.1 nM; mean=10 nM, Fe range 0.57–2.4 nM; mean=1.3 nM), particularly in the NE part of the Arabian Sea, as the result of the input and partial dissolution of eolian dust. Using the enrichment of Al in the surface waters, we estimate this is the equivalent to the deposition of 2.2–7.4 g m−2 dust, which is comparable to values previously estimated for this region. Approximately one month later (August/September), surface water concentrations of both Al and Fe were found to have decreased significantly (mean Al 7.4 nM, mean Fe 0.90 nM) particularly in the same NE region, as the result of export of particulate material from the euphotic zone. Fe supply to the surface waters is also affected by upwelling of sub-surface waters in the coastal region of the Arabian Sea during the SW Monsoon. Despite the proximity of high concentrations of Fe in the shallow sub-oxic layer, freshly upwelled water is not drawn from this layer and the NO3/Fe ratio in the initially upwelled water is below the value at which Fe limitation is through to occur. Continued deposition of eolian Fe into the upwelled water as it advects offshore provides the Fe required to raise this ratio above the Fe limitation value.  相似文献   

17.
Cu speciation was characterized at three stations in the sub arctic NW Pacific and Bering Sea using cathodic stripping voltammetry with the competing ligands benzoylacetone and salicylaldoxime. A single ligand model was fit to the titration data, yielding concentrations throughout the water column of ∼3–4 nM, and conditional stability constants ranging from 1012.7 to 1014.1, this range being partly due to the choice of competing ligand. Free Cu2+ in surface waters was 2–4×10−14 M, in close agreement with values reported by previous workers in the NE Pacific using anodic stripping voltammetry (ASV). However, those results showed that complexation by strong organic ligands becomes unimportant below 200–300 m, while our data indicated Cu is strongly complexed to depths as great as 3000 m. Free Cu2+ concentrations in surface waters reported here and in previous work are close to the threshold value where Cu can limit the acquisition of Fe by phytoplankton.  相似文献   

18.
Highly sensitive STOX O2 sensors were used for determination of in situ O2 distribution in the eastern tropical north and south Pacific oxygen minimum zones (ETN/SP OMZs), as well as for laboratory determination of O2 uptake rates of water masses at various depths within these OMZs. Oxygen was generally below the detection limit (few nmol L−1) in the core of both OMZs, suggesting the presence of vast volumes of functionally anoxic waters in the eastern Pacific Ocean. Oxygen was often not detectable in the deep secondary chlorophyll maximum found at some locations, but other secondary maxima contained up to ~0.4 µmol L−1. Directly measured respiration rates were high in surface and subsurface oxic layers of the coastal waters, reaching values up to 85 nmol L−1 O2 h−1. Substantially lower values were found at the depths of the upper oxycline, where values varied from 2 to 33 nmol L−1 O2 h−1. Where secondary chlorophyll maxima were found the rates were higher than in the oxic water just above. Incubation times longer than 20 h, in the all-glass containers, resulted in highly increased respiration rates. Addition of amino acids to the water from the upper oxycline did not lead to a significant initial rise in respiration rate within the first 20 h, indicating that the measurement of respiration rates in oligotrophic Ocean water may not be severely affected by low levels of organic contamination during sampling. Our measurements indicate that aerobic metabolism proceeds efficiently at extremely low oxygen concentrations with apparent half-saturation concentrations (Km values) ranging from about 10 to about 200 nmol L−1.  相似文献   

19.
Ectohydrolase activities of suspended microbiota were compared to those associated with sinking particles (sed-POM) retrieved from sediment traps deployed in the permanently anoxic Cariaco Basin. In shore-based assays, activities of aminopeptidase, β-glucosidase, chitinase and alkaline phosphatase were measured in samples obtained from oxic and anoxic depths using MUF- and MCA-labeled fluorogenic substrate analogs. Hydrolysis potentials for these enzymes in the seston varied widely over the nine cruises sampled (8 Nov 1996–3 May 2000) and among depths (15–1265 m); from <10 to over 1600 nM d?1 hydrolysate released, generally co-varying with one another and with suspended particulate organic carbon (POC) and particulate nitrogen (PN). Hydrolytic potentials, prokaryotic abundances and POC/PN concentrations in sinking debris were 400–1.3×107 times higher than in comparable volumes of seawater. However when normalized to PN, hydrolytic potentials in sediment trap samples were not demonstrably higher than in Niskin bottle samples. We estimate that PN pools in sediment trap samples were turned over 2–1400 times (medians=7–26x) slower by hydrolysis than were suspended PN pools. Median prokaryotic growth rates (divisions d?1) in sinking debris were also ～150 times slower than for bacterioplankton. Hydrolytic potentials in surface oxic waters were generally faster than in underlying anoxic waters on a volumetric basis (nM hydrolysate d?1), but were not significantly (p>0.05) different when normalized to PN or prokaryote abundances. Alkaline phosphatase was consistently the most active ectohydrolase in both sample types, suggesting that Cariaco Basin assemblages were adapted to decomposing phosphate esters in organic polymers. However, phosphorus limitation was not evident from nutrient inventories in the water column. Results support the hypothesis that efficiencies of polymer hydrolysis in anoxic waters are not inherently lower than in oxic waters.  相似文献   

20.
Sulfate reduction rate measurements by the 35SO42− core injection method were carried out in situ with a benthic lander, LUISE, and in parallel by shipboard incubations in sediments of the Black Sea. Eight stations were studied along a transect from the Romanian shelf to the deep western anoxic basin. The highest rates measured on an areal basis for the upper 0–15 cm were 1.97 mmol m−2 d−1 on the shelf and 1.54 mmol m−2 d−1 at 181 m water depth just below the chemocline. At all stations sulfate reduction rates decreased to values <3 nmol cm−3 d−1 below 15 cm depth in the sediment. The importance of sulfate reduction relative to the total mineralization of organic matter was very low, 6%, on the inner shelf, which was paved with mussels, and increased to 47% on the outer shelf at 100 m depth. Where the oxic–anoxic interface of the water column impinged on the sea floor at around 150 m depth, the contribution of sulfate reduction increased from >50% just above the chemocline to 100% just below. In the deep sea, mean sulfate reduction rates were 0.6 mmol m−2 d−1 corresponding to an organic carbon oxidation of 1.3 mmol m−2 d−1. This is close to the mean sedimentation rate of organic carbon over the year in the western basin. A comparison with published data on sulfate reduction in Black Sea sediments showed that the present results tend to be higher in shelf sediments and lower in the deep-sea than most other data. Based on the present water column H2S inventory and the H2S flux out of the sediment, the calculated turnover time of H2S below the chemocline is 2100 years.  相似文献   

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