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1.
节水条件下土壤氮素的环境影响效应研究   总被引：4，自引：0，他引：4       下载免费PDF全文
王康  沈荣开 《水科学进展》2003,14(4):437-441
土壤无机氮素的损失主要是铵氮的挥发损失和硝氮的反硝化和淋失.土壤水分和氮素含量的增加,都将增加氮肥淋失的潜在威胁,如处置不当,获得高产可能需要以环境的污染为代价.节水条件下土壤无机氮素的损失量有所减少,但是氮素利用效率也同时受到了土壤水分状况的限制.探讨了作物产量、氮素损失和农业生产要素(水分、氮素)实际投入量之间的关系,建立了节水条件下土壤氮素损失和环境评价概念型模型,通过在北京水利科学研究所永乐店灌溉试验站3年的试验资料对模型进行了参数求解及校验.  相似文献   

2.
Nitrate contamination of groundwater arises from anthropogenic activities, such as, fertilizer and animal manure applications and infiltration of wastewater/leachates. During migration of wastewater and leachates, the vadose zone (zone residing above the groundwater table), is considered to facilitate microbial denitrification. Particle voids in vadose zone are deficient in dissolved oxygen as the voids are partially filled by water and the remainder by air. Discontinuities in liquid phase would also restrict oxygen diffusion and therefore facilitate denitrification in the vadose/unsaturated soil zone. The degree of saturation of soil specimen (S r) quantifies the relative volume of voids filled with air and water. Unsaturated specimens have S r values ranging between 0 and 100 %. Earlier studies from naturally occurring nitrate losses in groundwater aquifers in Mulbagal town, Kolar District, Karnataka, showed that the sub-surface soils composed of residually derived sandy soil; hence, natural sand was chosen in the laboratory denitrification experiments. With a view to understand the role of vadose zone in denitrification process, experiments are performed with unsaturated sand specimens (S r = 73–90 %) whose pore water was spiked with nitrate and ethanol solutions. Experimental results revealed 73 % S r specimen facilitates nitrate reduction to 45 mg/L in relatively short durations of 5.5–7.5 h using the available natural organic matter (0.41 % on mass basis of sand); consequently, ethanol addition did not impact rate of denitrification. However, at higher S r values of 81 and 90 %, extraneous ethanol addition (C/N = 0.5–3) was needed to accelerate the denitrification rates.  相似文献   

3.
包气带作为防止地下水硝酸盐污染的天然屏障,其反硝化效果通常受到碳源的限制。针对地下水硝酸盐污染防治技术现状,本文采用Ca(OH)2处理的玉米芯作为反硝化的碳源材料,构建包气带强化反应层,用响应曲面法研究硝酸盐浓度、含水量和温度的交互作用对脱氮性能影响,并用硝态氮去除率、亚硝态氮累积、pH值变化以及溶解性有机碳(dissolved organic carbon, DOC)淋失通量综合评价脱氮性能,最后采用高通量测序揭示脱氮层中微生物变化。研究结果表明:温度、含水量以及温度和含水量交互作用对硝态氮去除率影响显著,其中温度是反硝化过程中最关键的因素;系统运行74天后,硝态氮去除率达到50%,亚硝态氮累积量(以N计)大多低于3 mg/L,pH值维持在7.0左右,DOC淋失通量(以C计)介于0.10.2 mg/(cm2·d);高通量测序发现,脱氮层中微生物的丰富度降低,而与反硝化和碳分解有关的微生物相对丰度提高,在碳源的刺激下微生物向有利于脱氮的方向演变。  相似文献   

4.
岩溶含水层的极不均一性特征使岩溶水溶质运移受构造、裂隙空间及其发育方向控制;因环境条件复杂,开展岩溶水污染原位修复技术难度较大,截止目前,国内尚未系统地开展岩溶含水层水污染原位修复研究工作。文章选择鲁中南山区典型岩溶发育及硝酸盐污染地段,施工组合钻孔建设修复试验工程,采用“乙醇+葡萄糖”液态碳源和“聚乙烯醇+淀粉颗粒”固态反应器分别进行岩溶水硝酸盐污染原位修复试验。结果表明:浓度500 mg?L－1、1 000 mg?L－1的“乙醇+葡萄糖”反硝化溶液对硝酸盐浓度的降解率分别为6.45 %和21.52 %;单位长度组成材料“聚乙烯醇3 kg+淀粉颗粒3 kg”、“聚乙烯醇2 kg+淀粉颗粒4 kg”的两种反硝化固态反应器对硝酸盐浓度的降解率分为33.91%和34.96%。试验证明在裂隙型岩溶地区采用孔组方案进行地下水污染原位修复技术可行、且能取得较显著效果。修复工程布设方式和试验成果对类似地区开展岩溶地下水污染原位修复具一定借鉴意义。   相似文献   

5.
Groundwater degradation from irrigated agriculture is of concern in semi-arid northern China. Data-scarcity often means the causes and extent of problems are not fully understood. An irrigated area in Inner Mongolia was studied, where abstraction from an unconfined Quaternary aquifer has increased threefold over 20 years to 20 million m3/year; groundwater levels are falling at up to 0.5 m/year; and groundwater is increasingly mineralised (TDS increase from 400 to 700–1,900 mg/L), with nitrate concentrations up to 137 mg/L N. Residence-time (chlorofluorocarbons), stable-isotope and hydrogeochemical indicators helped develop a conceptual model of groundwater system evolution, demonstrating a direct relationship between modern water proportion and the degree of groundwater mineralisation, indicating that irrigation-water recycling is reducing groundwater quality. The investigations suggest that before irrigation development, active recharge to the aquifer from wadis significantly exceeded groundwater inflow from nearby mountains, previously held to be the main groundwater input. Away from active wadis, groundwater is older with a probable pre-Holocene component. Proof-of-concept groundwater modelling supports geochemical evidence, indicating the importance of wadi recharge and irrigation return flows. Engineering works protecting the irrigated area from flooding have reduced good quality recharge; active recharge is now dominated by irrigation returns, which are degrading the aquifer.  相似文献   

6.
Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N2 in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.  相似文献   

7.
Nitrogen isotope indicators of seasonal source variability to groundwater   总被引：5，自引：0，他引：5  
 A nitrogen isotope study of soil water and groundwater in southern Indiana, USA, in 1991–1992 demonstrated considerable variations in nitrate degradation processes compared to an earlier investigation in 1986–1987. Although N-fertilizers were applied in May 1991, the δ15N values in soil water decreased in February 1992, indicating its delayed release into the system after substantial rainfall. The δ15N values of groundwater decreased from +12.3‰ in November 1991 to +11.3‰ in February 1992, and to +7.5‰ in March 1992. The increased residence time of nitrate in the soil resulted in increased denitrification, ammonia volatilization and plant uptake, and reduced threat to the groundwater quality. The 1986–1987 study in the area reported that excessive rainfall during the summer rapidly transported the nitrate to deeper horizons and drastically reduced volatilization and microbial reduction of nitrate, thus increasing the immediate threat to the groundwater quality in the area. The present study demonstrated that nitrogen isotopic signatures can be used to determine the effects of local soil type, rainfall, and land-use practices on the fate of nitrate in the subsurface. Received: 18 February 1997 · Accepted: 17 June 1997  相似文献   

8.
Irrigated agriculture allows for the increase of agrarian yields and stability in food supply and raw materials, being, at the same time, responsible for the reduction of water resources availability and for the pollution by salts and nitrate. This work aims to analyze the impact of changes in irrigation management (establishment of an on-demand flood irrigated system, assignment of irrigation allowances and water payment for surface and irrigation water consumption) in a traditional irrigated land on drainage flow, electrical conductivity and nitrate concentration in irrigation return flows between the year 2001 and the period 2005–2008. Changes in water management significantly modified quantity (lower drainage) and quality (electrical conductivity and nitrate) of irrigation return flows, keeping similar evolution paths during the year with water ameliorants in summer due to the use of good irrigation water quality. Salinity in irrigation return flows is not a current problem in the area as electrical conductivity values in water did not exceed the limit established for water used in irrigation or intended for human consumption. Despite the fact that changes in irrigation management and crop distribution have reduced nitrate concentrations in irrigation return flows by 43 %, the water still presents nitrate values exceeding the 50 mg NO3 ?/l. Thus, nitrate remains as the main agro-environmental problem in this irrigation area. However, the nitrate concentration trends detected in this work mark the possibility of reaching nitrate values below 50 mg NO3 ?/l in the case of maintenance of the conditions in this agricultural system.  相似文献   

9.
Irrigated agriculture is a clear source of non-point pollution by salts and nitrogen species. The impact of such pollution should be quantified according to specific cases. The case of the Malfarás creek basin, a sprinkler irrigation district located in the semiarid Ebro valley in northeast Spain, has been evaluated. The main crops in the district were corn, barley and alfalfa, occupying 93 % of the irrigated area. The fate of water, salts and nutrients was evaluated by a daily water balance developed at a field scale for the natural year 2010. The yearly data of the whole set of 101 irrigated fields plus the non-irrigated area compared to the measured drainage produced a basin water balance with a low degree of error. The basin consumed 90 % of the total water input of which 68 % was used for crop evapotranspiration and the rest was lost due to non-productive uses. 16 % of the incoming water left the irrigation area as drainage water. The irrigated area was responsible for 87 % of the drainage. The average volume of drained water was 152 mm year?1 for the whole basin area. The irrigated area drained 183 mm year?1. The basin exported 473 kg of salt per hectare during 2010. This value was the lowest of the sprinkler irrigation areas in the Ebro valley, mainly due to the lower soil salinity. All the crops except barley received a nitrogen surplus of 10–50 % above their needs. The extra nitrogen entered the water cycle increasing the nitrate concentration in the aquifer water (150 mg L?1) and drainage water (98 mg L?1). In 2010 the mass of nitrogen exported by drainage was 49 kg per irrigated hectare. This value is too high for this type of irrigation system and implies that 17 % of nitrogen applied as a fertilizer was lost to drainage water. The key to decreasing the nitrogen leaching and pollution that it causes could be appropriate time-controlled fertigation along with better irrigation scheduling.  相似文献   

10.
The responses of dwarf black mangroves (Avicennia germinans) and components of the microbial community to the addition of nitrate over a 2-year period were examined. The field study was conducted in the Indian River Lagoon (Florida) in a mangrove-dominated impoundment that was established for purposes of mosquito control. The responses of mangroves to the regular addition of nitrate were insignificant or relatively minor compared to responses of the components of the microbial community. Denitrification rates, measured in the field and laboratory, increased significantly in fertilized plots and nitrous oxide emission rates were almost six times higher in fertilized plots. Nitrogen fixation was significantly lower in fertilized plots. Results suggest that mangrove systems in the N-limited Indian River Lagoon are likely to be long-term sinks for any increases in N loading.  相似文献   

11.
Irrigated agriculture is causing certain deterioration of the quality of rivers and aquifers. The objective of this study is to analyse the agri-environmental repercussions caused by climatic changes in a typical irrigated land in the Ebro valley (Spain). The irrigation efficiency and agri-environmental impact in a basin of irrigated land (95 ha) were compared for two hydrological years with different pluviometry [October 2000/September 2001 (526 mm/year) vs. October 2004/September 2005 (211 mm/year)]. For this end, water balances were carried out in every plot and the quantity and quality (salinity and nitrates) of the water circulating through the drainage of the basin were gauged. The results indicate that in 2004/2005 farmers adjusted the irrigation doses better on each irrigation occasion, thus diminishing the fraction of drainage of the same (50% vs. 31%) and increasing the consumptive water use efficiency (56% vs. 79%). Nevertheless, the drought of 2004/2005 determined inappropriate irrigation management as the crops suffered a greater hydric deficit (3% vs. 23%). In 2004/2005, drainage waters presented higher electric conductivity (0.92 dS/m vs. 0.94 dS/m) and smaller nitrate concentration (96 mg/l vs. 74 mg/l). Last year, 55, 54 and 65% less of water, salts and N–NO3−, respectively, were exported in the drainage. The lesser environmental impact in the year 2004/2005 was influenced by more appropriate use of water and agrichemical resources. Nevertheless, it is necessary to continue optimizing agricultural practices, mainly irrigation and fertilization, in order to minimize nitrate pollution and to confront years of drought.  相似文献   

12.
As a common pollutant in groundwater, nitrate poses a significant threat to drinking water safety, especially in rural areas. A feasible solution to this problem must be established. In this study, a simple sand bucket was designed to investigate the capability of denitrification with liquor as the carbon source to remove nitrate from pumped groundwater, and the feasibility of the pump-and-treat method. Results showed that addition of a proper amount of liquor enhanced the growth and metabolism of denitrifying bacteria, efficiently reduced the nitrate content in pumped groundwater, and restricted the accumulation of intermediate products. The removal rate of nitrate exceeded 99% and reached about 16.0 mg/L/day when the carbon-to-nitrogen (C/N) ratio was higher than 0.8. The accumulated concentration of nitrite as an intermediate was less than 1.0 mg/L when the C/N ratio was higher than 1.5. However, acetate accumulation was significant. Considering the accumulation of intermediates, the appropriate range of the C/N ratio should be 1.5–1.8. In addition, onset and maintenance of denitrification were not significantly influenced by dissolved oxygen and pH. The pump-and-treat method can provide a convenient and practical channel for household or collective removal of nitrate from pumped groundwater in rural areas because liquor as a household drink is frequently accessible and inexpensive in many areas.  相似文献   

13.
在青海海北高寒矮嵩草草甸设置封育禁牧(CK)、轻牧(LG)、中牧(MG)和重牧(HG)放牧梯度试验样地, 进行了土壤速效氮变化特征及影响因素的分析. 结果表明: 植物生长期的5-9月, 土壤NH4+-N、NO3--N和速效氮(NH4+-N和NO3--N之和)含量季节变化明显, 基本表现为植物生长初期高, 末期低. CK、LG、MG和HG条件下, 5-9月0~40 cm土壤NH4+-N平均含量分别为17.62 mg·kg-1、17.84 mg·kg-1、18.63 mg·kg-1和16.67 mg·kg-1, NO3--N平均含量为8.91 mg·kg-1、8.23 mg·kg-1、7.99 mg·kg-1和7.94 mg·kg-1, 速效氮平均含量为26.53 mg·kg-1、26.07 mg·kg-1、26.62 mg·kg-1和24.61 mg·kg-1, 基本表现出随放牧强度增大而降低. 土壤速效氮月际变化与地上绿体生物量具有一定的负相关关系, 表明地上生物量越大, 消耗土壤速效氮越趋明显; 与枯落物有一定的正相关关系, 与地下生物量关系不甚明显, 与湿沉降呈现负的相关性. 土壤NH4+-N含量与土壤有机碳有负相关关系, 而NO3--N含量与有机碳相关性差, 表明土壤有机碳越高, 土壤NH4+-N消耗越明显.  相似文献   

14.
不同水肥条件下水稻氮素运移与转化规律研究   总被引：31，自引：0，他引：31       下载免费PDF全文
针对不同的水肥处理,采用15N示踪方法,观测分析了氮素在稻田的时空分布及运移规律、挥发及淋失损失规律、氮素在水稻植株中的分布特征、稻田氮量平衡等。结果表明:不同灌溉方式下,由于稻田水分状况的差异导致土壤养分时空分布不同,从而影响其对作物的有效性;由于节水灌溉稻田水分相对较少,基质浓度较高,挥发损失高于淹灌。虽然节水灌溉下稻田渗漏液NH4及NO3-浓度较淹灌高,但由于此时总渗漏量显著减少,氮的总淋失较淹灌条件少;节水灌溉下,适当增加追肥次数,有利于减少各种氮素养分的损失,提高氮肥利用率;节水灌溉下水稻对氮素的吸收利用率高于淹灌,且有利于氮素养分向稻谷转移。  相似文献   

15.
为了识别石家庄市南部污灌区地下水硝酸盐污染来源, 采集5种潜在污染源和19组地下水样用于化学和氮同位素分析.灌溉污水NH4+的δ15N值较低(4.0‰), 施化肥土壤和粪堆下土壤NO3-的δ15N值分别为1.4‰和12.4‰; 仅施厩肥的蔬菜种植区下伏近30 m厚包气带沉积物NO3-的δ15N分布显示, 来自动物粪便的NO3-已运移到11.5 m以下包气带, 均值10.9‰; 污水灌溉农田下伏厚层包气带沉积物样品分析结果指示, 土壤层下伏包气带沉积物δ15N值变幅较小, 均值5.7‰.污灌区内除一深井外, 其他水井地下水硝酸盐浓度变化在52.6~124.5 mg/L之间, 均值79.72 mg/L, δ15N值变化在5.3‰~8.3‰之间, 均值7.0‰.污灌区地下水的δ15N值较污灌区土壤层下伏包气带沉积物的δ15N值高, 表明地下水NO3-除了来自灌溉的污水外, 还有δ15N值更高的其他来源, 这些来源主要是人和动物粪便.利用线性混合模型计算, 污灌区地下水NO3-来自灌溉的污水, 约占76%, 而来自人和动物粪便的NO3-约占24%.为控制污灌区地下水NO3-浓度进一步增长, 不仅要加强污水灌溉管理, 还要加强人和动物粪便的管理.   相似文献   

16.
Toxicity of heavy metals adversely affects environment and human health. Organic materials derived from natural matters or wastes have been applied to soils to reduce the mobility of contaminants such as heavy metals. However, the application of cow bone powder (CB), biochar (BC), and eggshell powder (ES) is rarely investigated for the reduction of Pb bioavailability in soils irrigated with saline water. The objective of this study was to assess the effectiveness of CB, BC, and ES additions as immobilizing substances on Pb bioavailability in shooting range soil irrigated with deionized and saline water. Each additive of CB, BC, and ES at 5 % (w/w) was mixed with soils and then the deionized and saline water were irrigated for 21 days. With deionized water irrigation, the soils treated with CB, BC, and ES exhibited higher pH when compared with saline water irrigation. With saline water irrigation, the electrical conductivity, water-soluble anions, and cations were significantly increased in soils treated with CB, BC, and ES. The water-soluble Pb in soils treated with CB, BC, and ES was significantly decreased with saline water irrigation. On the other hand, the water-soluble Pb in soil treated with CB was increased with deionized water irrigation. Only BC with saline water irrigation decreased the Pb concentration in maize shoots.  相似文献   

17.
以黑龙江省大庆市林甸县长青林场3个不同小区为实验地,分别采用酸雨石等5种吸盐材料对不同小区盐碱土壤进行改良,根据改良后土壤pH、导电率变化,对不同材料的盐碱土壤改良效果进行比较。研究表明,短期内吸盐速率:酸雨石活性炭腐熟牛粪沸石稻壳,长期吸盐量:酸雨石活性炭沸石稻壳腐熟牛粪,效果持久性为酸雨石最强,活性炭、沸石次之,稻壳较弱,腐熟牛粪最弱。酸雨石解碱能力最强,活性炭次之,沸石、牛粪、稻壳解碱能力较弱。因此,酸雨石在5种盐碱土改良剂中具有最强吸盐解碱能力。  相似文献   

18.
In southern Hodna, an arid region of Algeria, the extension of irrigated agriculture and overexploitation of groundwaters have led to a rupture with traditional land use by pastoralism. Due to the arid conditions, groundwaters are the only water resources for man and irrigation. This study focuses on nitrate contamination of groundwaters and its increase since the last 40 years, on the basis of two archives and recent analyses. The chemical facies of waters is sulphate-chloride, the risk of salinity is moderate to large. The sodicity risk, as estimated by the SAR, is low due to the large salinity and the sandy soil texture. Nitrate contamination of deep groundwater is a clear evidence when recent data are compared to the historical data. From 1996 to 2008, the proportion of samples with NO 3 ? concentrations larger than 50 mg/L increases from 24 to 61 %, the proportion of samples with NO 3 ? concentrations larger than 100 mg/L increases from 12 to 27 %. The study points at a general contamination of aquifers from anthropic origin: phreatic water was already contaminated when pastoralism was dominant (1967); as population increased and irrigation agriculture developed with large use of N-fertilizers and organic amendments, contamination extended spatially and vertically to deep aquifer. To remediate this contamination, fertilizers should be fractionated and limited to plant requirements on the basis of soil and plant analyses. Excess of irrigation should be avoided. Soil surface should be continuously covered to prevent nitrate leaching. Secondly, more efficient irrigation techniques, such as localized irrigation, should be implemented, with adaptation of crop systems and fertilizer inputs to arid conditions. Farmers should then be trained; simultaneously, local agronomic references that are presently lacking should be acquired.  相似文献   

19.
Over the past decades, the Gujarat state of India experienced intensive agricultural and industrial activities, fertilizer consumption and abstraction of groundwater, which in turn has degraded the ground water quality. Protection of aquifers from nitrate pollution is a matter of prime concern for the planners and decision-makers. The present study assessed the spatial and temporal variation of groundwater nitrate levels in areas with different land use/land cover activities for both pre- and post-monsoon period. The pre-monsoon nitrate level (1.6–630.7 mg/L) in groundwater was observed to be higher as compared to the post-monsoon level (2.7–131.7 mg/L), possibly due to insufficient recharge and evaporation induced enrichment of agrichemical salts in groundwater. High HCO3 ? (200–1,000 mg/L) as well as SO4 2?/Cl? (0.111–0.992) in post-monsoon period provides a favourable environment for denitrification, and lower the NO3 levels during the post-monsoon period. The K vs NO3 scatter plot suggests a common source of these ions when the concentration is <5 mg/L, the relationships between different pollutants and nitrate also suggest that fertilizers and other sources, such as, animal waste, crop residue, septic tanks and effluents from different food processing units present in the area can be attributed to higher nitrate levels in the groundwater. Appropriate agronomic practices such as application of fertilizers based on calibrated soil tests and proper irrigation with respect to crop can minimize the requirement for inorganic fertilizers, which can bring down the cost of cultivation considerably, and also protect groundwater from further degradation.  相似文献   

20.
A parametric crop yield model YIELD, which was developed by Prof. W. Terjung and his team at UCLA, was applied to calculate yield and water consumption for corn in Saudi Arabia. The model employs climatic and environmental data in order to simulate yield for several crops in different places all over the world. A network of 22 stations provided climatic data averaged over a period of 17 years (1967–1983). The nonclimatic data was derived from the FAO soil map of the world and the writer's personal experience. The main objectives of this paper are: [1] to determine suitable places and times for planting corn, under rainfed and irrigated conditions in Saudi Arabia; [2] to contrast irrigation water for corn in each province; and [3] to assess the potential yield for corn in the country in a year. This study concluded that highest yields of corn under fully-irrigated conditions (primary growing season) occurred in the mountainous region in SW Saudi Arabia (about 12,000 kg/ha, and more than 18,000 in Nimas) while lowest yields occurred in Tabuk and Al-Khawsh (about 4,000 kg/ha). Yields in most of the other stations were (5,000–8,000 kg/ha). Under rainfed conditions crop failed in all regions except in the SW region in which yields range between 2,000 kg/ha in Al-Khawsh and — 6,000 kg/ha as in Nimas. According to the findings of this study, the most suitable months for corn sowing in Saudi Arabia are December and January.  相似文献   

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