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1.
In snowmelt-driven mountain watersheds, the hydrologic connectivity between meteoric waters and stream flow generation varies strongly with the season, reflecting variable connection to soil and groundwater storage within the watershed. This variable connectivity regulates how streamflow generation mechanisms transform the seasonal and elevational variation in oxygen and hydrogen isotopic composition (δ18O and δD) of meteoric precipitation. Thus, water isotopes in stream flow can signal immediate connectivity or more prolonged mixing, especially in high-relief mountainous catchments. We characterized δ18O and δD values in stream water along an elevational gradient in a mountain headwater catchment in southwestern Montana. Stream water isotopic compositions related most strongly to elevation between February and March, exhibiting higher δ18O and δD values with decreasing elevation. These elevational isotopic lapse rates likely reflect increased connection between stream flow and proximal snow-derived water sources heavily subject to elevational isotopic effects. These patterns disappeared during summer sampling, when consistently lower δ18O and δD values of stream water reflected contributions from snowmelt or colder rainfall, despite much higher δ18O and δD values expected in warmer seasonal rainfall. The consistently low isotopic values and absence of a trend with elevation during summer suggest lower connectivity between summer precipitation and stream flow generation as a consequence of drier soils and greater transpiration. As further evidence of intermittent seasonal connectivity between the stream and adjacent groundwaters, we observed a late-winter flush of nitrate into the stream at higher elevations, consistent with increased connection to accumulating mineralized nitrogen in riparian wetlands. This pattern was distinct from mid-summer patterns of nitrate loading at lower elevations that suggested heightened human recreational activity along the stream corridor. These observations provide insights linking stream flow generation and seasonal water storage in high elevation mountainous watersheds. Greater understanding of the connections between surface water, soil water and groundwater in these environments will help predict how the quality and quantity of mountain runoff will respond to changing climate and allow better informed water management decisions.  相似文献   

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3.
This study analyzes the stable isotopic compositions of hydrogen and oxygen (δ2H, δ18O) in montane meteoric waters including precipitation and stream water of central Taiwan to identify hydrological processes in montane catchments. Results of precipitation demonstrate that monsoon and altitude effects are two principal processes affecting δ and deuterium excess (dE) values of inland precipitation in central Taiwan. Furthermore, slope and intercept values of summer and winter local meteoric water line are modified by secondary evaporation effects such as moisture recycling and raindrop evaporation. Additionally, stream water's results indicate that differences in δ values among stream waters reflect isotopic altitude effect whereby lower values are more evident in stream water originating from high‐elevation catchments than low‐elevation catchments. Comparison of the isotopic results between precipitation and stream water indicates that summer precipitation containing recycled moisture is the most important water source for the studied stream waters and indicates that catchment effect and base flow contribution are the two major hydrological processes affecting mountain stream hydrology. The hydrological processes identified by the isotopic study re‐stress the important role of forests in mountain hydrology. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

4.
The local meteoric water line (LMWL), the functional relationship between locally measured values of δ18O and δ2H in precipitation, represents the isotopic composition of water entering hydrologic systems. The degree to which the LMWL departs from the global meteoric water line (GMWL), moreover, can reveal important information about meteoric sources of water (e.g. oceanic or terrestrial) and atmospheric conditions during transport. Here we characterize the isotopic composition of precipitation within an experimental watershed in the Western US that is subject to large topographic and seasonal gradients in precipitation. Interpreting the hydrometeorologic and spatial controls on precipitation, we constructed a seasonally weighted LMWL for southwestern Idaho that is expressed by the equation δ2H = 7.40 × δ18O ? 2.17. A seasonally weighted LMWL that is based on weighting isotopic concentrations by climatic precipitation volumes is novel, and we argue better represents the significant seasonality of precipitation in the region. The developed LMWL is considerably influenced by the semiarid climate experienced in southwest Idaho, yielding a slope and y‐intercept lower than the GMWL (δ2H = 8 × δ18O + 10). Moderate to strong correlations exist between the isotopic composition of precipitation from individual events and surface meteorologic variables, specifically surface air temperature, relative humidity, and precipitation amount. A strong negative correlation exists between the annual average isotopic composition of precipitation and elevation at individual collection sites, with a lapse rate of ?0.22‰/100 m. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

5.
Mass balance studies in forested catchments in the northeastern USA show that S losses via streamwater SO42? exceed measured atmospheric S inputs. Possible sources of the excess S loss include underestimated dry deposition, mineralization of organic S in soils, desorption of soil sulphate, oxidation of recently formed sulphides and mineral weathering. Evaluating the relative contribution of these sources and processes to SO42? export is important to our understanding of S cycling as well as to policy makers in their evaluation of the efficacy of S emission controls. In order to evaluate the potential for mineral weathering contributions to SO42? export, we measured concentration and isotopic composition (δ34S and δ18O) of SO42? in stream water, and concentration and δ34S values of four S fractions in bedrock and soil parent material in catchments of varying geological composition. Geological substrates with low S concentrations were represented by catchments underlain by quartzite and granite, whereas geological substrates with high S concentrations were represented by catchments underlain by sulphidic slate, schist and metavolcanic rocks. Catchments with S‐poor bedrock had stream‐water SO42? concentrations <100 µeq L?1 and isotopic values consistent with those of atmospheric SO42? that had been cycled through the organic soil pool. Catchments with S‐rich bedrock had stream‐water SO42? concentrations ranging from 56 to 229 µeq L?1. Isotopic values deviated from those of SO42? in atmospheric deposition, clearly indicating a mineral weathering source in some cases, whereas in others spatial variability of mineral δ34S values precluded the isotopic detection of a weathering contribution. These results, along with evidence suggesting formation of secondary sulphate minerals in bedrock weathering rinds, indicate that mineral weathering may be an important source of S in the surface waters of some forested catchments in the northeastern USA. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

6.
This study examined the weekly water vapour isotopic composition (δ18Ov) in Thailand. The water vapour was cryogenically collected from eight sites across the country. Two observational samples were collected over one 24-h period each week (a daytime and a night-time sample), from September 2013 to September 2014. The primary aim was to investigate the environmental factors influencing water vapour isotopes. The results revealed differences in water vapour isotopic values between day and night samples. Three periods of depleted δ18Ov were associated with large-scale convective systems in September, December, and May. The statistical relationship between the climate variables and water vapour isotopes indicated that the amount of precipitation and relative humidity were the primary controls on both diurnal and seasonal isotopic variability. The temperature did not affect the δ18Ov, mainly because the atmospheric processes are a function of vertical convection rather than temperature in tropical regions. The water vapour deuterium excess (d-excess) showed greater variability in 2013 than in 2014. The d-excess variation reflected the differences in convection occurring in the day and night. In addition, the vapour phase data were combined with the local meteoric water line to identify the local water vapour line and the interaction between the isotopic composition of water vapour and liquid water. The water vapour isotopic patterns paralleled the precipitation isotopes on rainy days because of equilibrium isotopic exchange. Water vapour and precipitation were isotopically similar under low humidity but showed greater differences from each other under wetter conditions. The study results provide insight into water vapour isotopic characteristics in tropical regions and constrain the role of large-scale atmospheric processes relative to isotopic variability of water vapour in Thailand and nearby countries.  相似文献   

7.
Large raised bogs and patterned fens cover 56% of the landscape in the Glacial Lake Agassiz region of northern Minnesota (USA). Organic acids supply most of the acidity in the surface water of the bogs, but groundwater upwelling from the underlying glacial deposits neutralizes these organic acids within deep peat. Substantial concentrations of organic acids also occur in the surface waters of fens mixed with variable amounts of inorganic solutes contributed by groundwater discharge. We used a triprotic analog model to determine the extent to which organic acids in fen and bog waters behave as strong or weak acids. The modeling approach optimized charge balance by calibrating estimates of mole site density in the DOC (dissolved organic carbon) of surface and pore waters with estimates of triprotic acid dissociation constants. Before the calibration process, all of the bog waters and 76% of the fen waters had more than +20% imbalance in charge balance. After calibration, more than 75% of all waters were electrochemically balanced within 20%. In the best calibration, the mole site denisty of bog DOC was estimated as 0.05 mmol/mmol C., approximately six times smaller than that estimated for fen DOC or the DOC in the fen deeper fen peats that underlie all bog landforms. The three modeled de-protonation constants were; pKa1=3.0, pKa2=4.5 and pKa3=7.0 for the bog DOC, and; pKa1=5.2, pKa2= 6.5 and pKa3=7.0 for the fen DOC. Bog DOC, behaves as a strong acid despite its small mole site density. The DOC in bog runoff can therefore theoretically acidify the surface waters in adjacent fens wherever these waters do not receive sufficient buffering alkalinity from active groundwater seepage.  相似文献   

8.
Despite the great potential of peat bogs as climatic archives, to date only few studies have focused on the climatic controls on cellulose isotopic composition in modern bog plants. This study attempts to calibrate plant-climate relationships by sampling a set of modern plant species (both vascular plants and mosses) and bog surface waters along an altitude transect in Switzerland. Isotopic analyses of water samples show that the δ18O-values of surface bog waters follow the trend of precipitation despite significant scatter in the data set. Detailed sampling of surface waters within one bog shows that δ18O-values vary widely and are closely related to the micro-topography of the bog surface. More enriched 18O/16O ratios in water samples collected from small raised hummocks than the ones collected from hollows are documented in both horizontal and vertical profiles. A δ18O-δD plot indicates that the process leading to the isotopic enrichment of the uppermost surface waters is evaporation, greater above Sphagnum covered hummocks than above open pools. To investigate the implications of such high variability of source water for plant α-cellulose δ18O-values, a detailed study of both surface water and α-cellulose δ18O-values within one site is conducted. The large δ18O variability observed in surface waters is found to be considerably smoothed in α-cellulose (by a factor of 5-10 depending on the plant species). This indicates that the water used by plant photosynthetic processes reflects the isotopic composition of the average annual precipitation. This points to a source water level for plants of a few decimeters where the variations are smaller than at the air-water interface. The response of the α-cellulose δ18O to the environmental gradient along the altitude transect varies considerably from species to species. For most of the species studied, the δ18O-values decrease with altitude, following the trends of δ18O-values in precipitation and in surface water samples. Some species, the cotton sedge Eriophorum vaginatum and the moss Sphagnum capillifolium, show statistically significant δ18O relationships to an altitude of −1.8‰/km and −2.9‰/km respectively. However, some other plant species, Calluna vulgaris, Vaccinium uliginosum, Andromeda poliflora, Carex pauciflora, Sphagnum cuspidatum and Sphagnum magellanicum, do not, or only partially, reflect changes in climatic parameters associated with an altitude increase. Furthermore, changes in relative humidity, which are not correlated with altitude, are found to explain a large part of the variability in δ18O-values for the sedge Carex pauciflora and the moss Sphagnum cuspidatum. Therefore, this study confirms the importance of species-specific studies when interpreting 18O/16O ratios of macrofossils along a fossil peat sequence as a record of past climate changes. Our study allows to extend the mechanistic model that isotopically links source water and cellulose to the physiological specificities of sedges and mosses. A comparison of the modeled and calculated net biological fractionation factors for Eriophorum vaginatum and Sphagnum capillifolium reveals that these two species appear to have a more homogeneous leaf reservoir than trees.  相似文献   

9.
This study used a two‐dimensional steady‐state finite‐element groundwater flow model to simulate groundwater flow in two Newfoundland blanket peat complexes and to examine flow system sensitivity to changes in water table recharge and aquifer properties. The modelling results were examined within the context of peat‐forming processes in the two complexes. Modelled flow compared favourably with observed flow. The sensitivity analyses suggested that more highly decomposed bog peat along bog margins probably has/had a positive impact on net peat accumulation within bog interiors. Peat with lower hydraulic conductivity along bog margins effectively impedes lateral drainage, localizes water table drawdown to extreme bog margins, and elevates water tables along bog interiors. Peat formation and elevated water tables in adjacent poor fens/laggs currently rely on placic and ortstein horizons impeding vertical drainage and water flow inputs from adjacent bogs. Modest reductions in atmospheric recharge were found to govern bog‐flow‐system geometries in a way that would adversely affect paludification processes in adjacent fens/laggs. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

10.
Secondary calcite residing in open cavities in the unsaturated zone of Yucca Mountain has long been interpreted as the result of downward infiltration of meteoric water through open fractures. In order to obtain information on the isotopic composition (δD and δ18O) of the mineral-forming water we studied fluid inclusions from this calcite. Water was extracted from inclusions by heated crushing and the δD values were measured using a continuous-flow isotope-ratio mass spectrometry method. The δ18O values were calculated from the δ18O values of the host calcite assuming isotopic equilibrium at the temperature of formation determined by fluid-inclusion microthermometry.The δD values measured in all samples range between ? 110 and ? 90‰, similar to Holocene meteoric water. Coupled δ18O–δD values plot significantly, 2 to 8‰, to the right of the meteoric water line. Among the various processes operating at the topographic surface and/or in the unsaturated zone only two processes, evaporation and water–rock exchange, could alter the isotope composition of percolating water. Our analysis indicates, however, that none of these processes could produce the observed large positive δ18O-shifts. The latter require isotopic interaction between mineral-forming fluid and host rock at elevated temperature (>100 °C), which is only possible in the deep-seated hydrothermal environment. The stable isotope data are difficult to reconcile with a meteoric origin of the water from which the secondary minerals at Yucca Mountain precipitated; instead they point to the deep-seated provenance of the mineral-forming waters and their introduction into the unsaturated zone from below, i.e. a hypogene origin.  相似文献   

11.
12.
A systematic study of the chemo-isotopic characteristics and origin of the groundwater was carried out at six major qanats in the hyper-arid Gonabad area, eastern Iran. These qanats as a sustainable groundwater extraction technology have a long history, supporting human life for more than a thousand years in this region. The Gonabad qanats are characterized by outlet electrical conductivity (EC) values of 750 to 3900 µS/cm and HCO3-Na-Mg and Cl-Na water types. The Gonabad meteoric water line (GnMWL) was drawn at the local scale as δ2H = 6.32×δ18O + 8.35 (with R2 = 0.90). It has a lower slope and intercept than the global meteoric water line due to different water vapor sources and isotope kinetic fractionation effects during precipitation in this arid region. The altitude effects on isotopic content of precipitation data were derived as δ18O = (−0.0031 × H(m.a.s.l))−1.3). The δ2H and δ18O isotopes signatures demonstrate a meteoric origin of the groundwater of these qanats. The shift of the qanat's water samples from the local meteoric water line (LMWL) in a dry period with higher temperatures is most probably due to evaporation during the infiltration process and water movement in qanat gallery. Based on the isotopic results and mass balance calculations, the qanats are locally recharged from an area between 2000 to 2400 m.a.s.l of nearby carbonate formations and coarse alluvial sediments. The dissolution of evaporate interlayers in Neogene deposits deteriorates the groundwater quality, especially in Baidokht qanat.  相似文献   

13.
Changes in the level of the Yangtze River caused by anthropogenic water regulation have major effects on the hydrological processes and water cycle in surrounding lakes and rivers. In this study, we obtained isotopic evidence of changes in the water cycle of Yangtze River during the two drought years of 2006 and 2013. Isotopic evidence demonstrated that the δ18O and δD levels in Yangtze River exhibited high spatial heterogeneity from the upper to lower reaches, which were controlled by atmospheric precipitation, tributary/lake water mixing, damming regulation, and water temperature. Both the slope and intercept of Yangtze River evaporative line (δD = 7.88 δ18O + 7.96) were slightly higher than those of local meteoric water line of Yangtze River catchment (δD = 7.41 δ18O + 6.01). Most of the river isotopic values were located below the local meteoric water line, thereby implying that the Yangtze River water experienced a certain degree of evaporative enrichment on isotopic compositions of river water. The high fluctuations in the isotopic composition (e.g., deuterium excess [d‐excess]) in the middle to lower reaches during the initial stage of operation for the Three Gorges Dams (2003–2006) were due to heterogeneous isotopic signatures from the upstream water. In contrast to the normal stage (after 2010) characterized by the maximum water level and largest water storage, a relatively small variability in the deuterium excess was found along the middle to lower reaches because of the homogenization of reservoir water with a longer residence time and complete mixing. The effects of water from lakes and tributaries on the isotopic compositions in mainstream water were highlighted because of the high contributions of lakes water (e.g., Dongting Lake and Poyang Lake) efflux to the Yangtze River mainstream, which ranged from 21% to 85% during 2006 and 2013. These findings suggest that the retention and regulation of the Three Gorges Dams has greatly buffered the isotopic variability of the water cycle in the Yangtze catchment, thereby improving our understanding of the complex lake–river interactions along the middle to lower reaches in the future.  相似文献   

14.
Abstract

Stable isotopes are powerful research tools in environmental sciences and their use in ecosystem research is increasing. Stable isotope measurements allow the study of evapotranspiration fluxes, soil evaporation and leaf transpiration phenomena. Soil water and leaf water are the sources of the evapotranspiration that transfers large quantities of water from land to the atmosphere; as a result the isotopic composition of water left in the leaves is modified towards enrichment. Evaporation also changes the isotopic composition of water bodies creating a natural isotopic signal. The isotopic identity of soil water affects the oxygen isotopic signature of leaf and stem water. In this paper we present the isotopic data of bulk leaf water, showing the enrichment in isotopic value of oxygen due to evapotranspiration from leaves in conjunction with the isotopic signal of rainwater and other environmental factors such as humidity and temperature. Results suggest that the variation in the values of δ18O of Eucalyptus citriodora, Dalbergia sissoo, Melia azedarach and Pinus roxburghii is due to the seasonal changes in the δ18O of the source water for plants, i. e. rain. It is further observed that leaf water δ18O values are depleted during the months of July, August and September. This occurs due to the following reasons: (a) the sampling areas receive about 50% of the average annual rain during these months, and (b) rainfalls during these months are isotopically depleted compared with winter rains.

Citation Butt, S., Ali, M., Fazil, M. & Latif, Z. (2010) Seasonal variations in the isotopic composition of leaf and stem water from an arid region of Southeast Asia. Hydrol. Sci. J. 55(5), 844–848.  相似文献   

15.
Ground water recharge is assumed to occur primarily at raised bog crests in northern peatlands, which are globally significant terrestrial carbon reservoirs. We synoptically surveyed vertical profiles of peat pore water δ18O and δ2H from a range of bog and fen landforms across the Glacial Lake Agassiz Peatlands, northern Minnesota. Contrary to our expectations, we find that local‐scale recharge penetrates to not only the basal peat at topographically high bog crests but also transitional Sphagnum lawns and low‐lying fen water tracks. Surface landscape characteristics appear to control the isotopic composition of the deeper pore waters (depths ≥0.5 m), which are partitioned into discrete ranges of δ18O on the basis of landform type (mean ± standard deviation for bog crests = ?11.9 ± 0.4‰, lawns = ?10.6 ± 0.1‰, fen water tracks = ?8.8 ± 1.0‰). Fen water tracks have a shallow free‐water surface that is seasonally enriched by isotope fractionating evaporation, fingerprinting recharge to underlying pore waters at depths ≥3 m. Isotope mass balance calculations indicate on average 12% of the waters we sampled from the basal peat of the fen water tracks was lost to surface evaporation, which occurred prior to advection and dispersion into the underlying formation. These new data provide direct support for the hypothesis that methane production in deeper peat strata is fuelled by the downward transport of labile carbon substrates from the surface of northern peat basins. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

16.
Spatial and temporal variations of the isotopic composition of precipitation over Thailand were investigated. The local meteoric water line for Thailand deviates slightly from the global meteoric water line, with lower slopes (7.62 ± 0.07, 7.59 ± 0.08) and intercepts (6.42 ± 0.39, 6.22 ± 0.42) using ordinary and precipitation weighted methods. Differences in spatial and temporal δ18O distributions between the tropical monsoon and tropical savanna climate zones were found due to differing moisture source contributions and seasonal precipitation patterns. The temporal data reveals that the northeast monsoon rains originate from isotopically-enriched local moisture with isotope values of −9.36 to −0.09‰ (mean − 3.73 ± 0.42‰), whereas the southwest monsoon clouds had a more significant rainout effect from Rayleigh distillation, with isotope values of −9.56 to −1.78‰ (mean − 5.40 ± 0.38‰). The precipitation amount at each site was negatively correlated with δ18O (−0.24 to −3.20‰ per 100 mm, R2 = 0.1–0.9). Furthermore, δ18O was negatively correlated with geography (latitude, altitude) for the southwest monsoon periods, as expected based on other observed correlations. However, an inverse correlation was seen in the northeast monsoon due to differing moisture transportation as part of the continental effect. The correlation coefficient (R) was higher in the southwest monsoon (−0.84 for latitude effect, −0.64 for altitude effect) than the northeast monsoon (0.67 for latitude effect, 0.35 for altitude effect). The spatial pattern of isotopic composition reflects the southwest monsoon more clearly than the northeast monsoon, but the two monsoons also have a cancelling impact on orographic patterns. An agreement of the δ18O and deuterium excess (d-excess) was a negative correlation and found to reflect precipitation sources and re-evaporation processes. The d-excess was slightly higher for the northeast monsoon, bringing moisture from the Pacific Ocean and travelling across the continent before reaching the observed stations. By contrast, the d-excess was relatively lower for the Indian Ocean's moisture in the southwest monsoon.  相似文献   

17.
Luc Rock  Bernhard Mayer 《水文研究》2007,21(24):3301-3315
The partially semi-arid Oldman River basin (OMRB), located in southern Alberta (Canada), has an area of 28 200 km2, is forested in its western headwater part, and is used for agriculture in its eastern part. Hydrometric measurements indicate that flow in the Oldman River has decreased by ∼34% between 1913 and 2003, and it is predicted that water withdrawals will increase in the next 20 years. The objective of this study was to determine whether isotope ratio measurements can provide further insight into the water dynamics of the Oldman River and its tributaries. Surface water samples were collected monthly between December 2000 and March 2003. Groundwater samples were taken from 58 wells during one-time sampling trips. Runoff within the OMRB is currently about 70 mm year−1, with a corresponding runoff ratio of 0·18. Seasonal flow characteristics are markedly different upstream and downstream of the Oldman River reservoir. Upstream, sharp increases in flow in late spring and early summer are followed by a rapid decrease to base flow levels. Downstream, a prolonged high flow peak is observed due to the storage effect of the Oldman River reservoir. The seasonal variation in the isotopic composition of surface water from upstream sites is small. This suggests that peak runoff is not predominantly generated by melting snow accumulated during the preceding winter, but mainly by relatively well-mixed young groundwater. A significant increase in the δ18O and δ2H values in the downstream part of the basin was observed. The increase in the isotopic values is partly due to surface water and groundwater influx with progressively higher δ18O and δ2H values in the eastern part, and partly due to evaporation. Hence, the combination of hydrometric data with isotope measurements yields valuable insights into the water dynamics in the OMRB that may be further refined with more intensive measurement programmes in the future. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

18.
Stable water isotopes δ18O and δ2H are used to investigate precipitation trends and storm dynamics to advance knowledge of precipitation patterns in a warming world. Herein, δ18O and δ2H were used to determine the relationship between extratropical cyclonic precipitation and local meteoric water lines (LMWLs) in the eastern Ohio Valley and the eastern United States. Precipitation volume weighted and unweighted central Ohio LMWLs, created with samples collected during 2012–2018, showed that temperature had the greatest effect on precipitation isotopic composition. HYSPLIT back trajectory modelling showed that precipitation was primarily derived from a mid-continental moisture source. Remnants of major hurricanes were collected as extratropical precipitation during the 2012–2018 sampling period in central Ohio. Extratropical precipitation samples were not significantly different from the samples that created the central Ohio LMWL. Six additional LMWLs were derived from United States Geological Survey (USGS) Atmospheric Integrated Research Monitoring Network (AIRMoN) samples collected in Pennsylvania, Delaware, Tennessee, Vermont, New Hampshire, and Oxford, Ohio. Meteoric water lines describing published samples from Superstorm Sandy, plotted with these AIRMoN LMWLs, showed isotopic composition of Superstorm Sandy precipitation was commonly more depleted than the average isotopic composition at the mid-latitude locations. Meteoric water lines describing the Superstorm Sandy precipitation were not significantly different in slope from LMWLs generated within 300 km of the USGS AIRMoN site. This finding, which was observed across the eastern Ohio Valley and eastern United States, demonstrated a consistent precipitation δ2H–δ18O relationship for extratropical cyclonic and non-cyclonic events. This work also facilitates the analysis of storm development based on the relationship between extratropical event signature and the LMWL. Analysis of extratropical precipitation in relation to LMWLs along storm tracks allows for stronger development of precipitation models and understanding of which climatic and atmospheric factors determine the isotopic composition of precipitation.  相似文献   

19.
18O is an ideal tracer for characterizing hydrological processes because it can be reliably measured in several watershed hydrological compartments. Here, we present multiyear isotopic data, i.e. 18O variations (δ18O), for precipitation inputs, surface water and groundwater in the Shingobee River Headwaters Area (SRHA), a well‐instrumented research catchment in north‐central Minnesota. SRHA surface waters exhibit δ18O seasonal variations similar to those of groundwaters, and seasonal δ18O variations plotted versus time fit seasonal sine functions. These seasonal δ18O variations were interpreted to estimate surface water and groundwater mean residence times (MRTs) at sampling locations near topographically closed‐basin lakes. MRT variations of about 1 to 16 years have been estimated over an area covering about 9 km2 from the basin boundary to the most downgradient well. Estimated MRT error (±0·3 to ±0·7 years) is small for short MRTs and is much larger (±10 years) for a well with an MRT (16 years) near the limit of the method. Groundwater transit time estimates based on Darcy's law, tritium content, and the seasonal δ18O amplitude approach appear to be consistent within the limits of each method. The results from this study suggest that use of the δ18O seasonal variation method to determine MRTs can help assess groundwater recharge areas in small headwaters catchments. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

20.
The Marcell Experimental Forest (MEF) in northern Minnesota, USA, with hydrological research and monitoring of peatland catchments in a low-topographic relief landscape, contrasts with the mountainous terrain that typifies most research catchments. Six research catchments were instrumented and hydrological and meteorological monitoring was initiated during 1960. Paired-catchment studies, which started during 1969, have been used to assess land management and environmental change effects on forests, water availability, and biogeochemistry. Over the decades, the research and collaborations have proliferated to include new monitoring and ecosystem experiments. We provide an overview of available datasets and access information for hydrological and meteorological data. Data on streamflow, water table elevation, precipitation, snow, ground frost, air temperature, soil moisture, upland runoff, and water chemistry are discoverable with associated metadata and are archived through several Web-based, community repositories. The research programme is ongoing and we anticipate updates on an annual or more frequent basis. Additionally, we aim to release other physical, chemical, and isotopic measurements associated with long-term catchment monitoring and studies at the MEF.  相似文献   

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