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1.
Multiple linear regression of spatial variables including land use, soil type, and topography was applied to predict nitrate concentration and evaluate major factors affecting nitrate occurrence in springs and wells in the southern and northern areas of Jeju volcanic island, Korea. Three types of contributing area surrogates (CAS), namely circle, semicircle, and wedge, were employed to calculate the spatial variables. The regression results showed R2 of 0.81–0.84 for springs and 0.74–0.77 for wells; R2 values for wedge and semicircular CAS were more than 10% higher than those for circular CAS. The R2 of spring models was significantly affected by both the shape and size of CAS, with optimal radii of 150–250 m and 300–400 m in the southern and northern areas, respectively, corresponding to thinner upper basaltic aquifers, and implying shorter flow paths in the southern area. The most influential variables in springs were orchards and soil types related to agriculture including silty loam and silty clay loam, indicating that nitrate levels are strongly affected by N fertilization in cultivated areas. In contrast, wells showed much less sensitivity to both shapes and sizes of CAS, with less contribution of land use and soil type to the regression, which could be attributed to a mix of multiple aquifer zones and widely different factors in the installation and operation of wells. Field parameters of electrical conductivity (EC) and pH increased the R2 up to 10%, suggesting that these can be useful when regression with spatial variables yields a lower R2. The optimal spatial scales for prediction of nitrate concentration and spatial variables that significantly contribute to nitrate contamination can provide relevant criteria for establishing groundwater management policies, considering the increasing anthropogenic land‐use trends on the island, where groundwater is highly sensitive to changes in spatial variables. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

2.
To investigate the origin and behaviour of nitrate in alluvial aquifers adjacent to Nakdong River, Korea, we chose two representative sites (Wolha and Yongdang) having similar land‐use characteristics but different geology. A total of 96 shallow groundwater samples were collected from irrigation and domestic wells tapping alluvial aquifers. About 63% of the samples analysed had nitrate concentrations that exceeded the Korean drinking water limit (44·3 mg l?1 NO3?), and about 35% of the samples had nitrate concentrations that exceeded the Korean groundwater quality standard for agricultural use (88·6 mg l?1 NO3?). Based on nitrogen isotope analysis, two major nitrate sources were identified: synthetic fertilizer (about 4‰ δ15N) applied to farmland, and animal manure and sewage (15–20‰ δ15N) originating from upstream residential areas. Shallow groundwater in the farmland generally had higher nitrate concentrations than those in residential areas, due to the influence of synthetic fertilizer. Nitrate concentrations at both study sites were highest near the water table and then progressively decreased with depth. Nitrate concentrations are also closely related to the geologic characteristics of the aquifer. In Yongdang, denitrification is important in regulating nitrate chemistry because of the availability of organic carbon from a silt layer (about 20 m thick) below a thin, sandy surface aquifer. In Wolha, however, conservative mixing between farmland‐recharged water and water coming from a village is suggested as the dominant process. Mixing ratios estimated based on the nitrate concentrations and the δ15N values indicate that water originating from the village affects the nitrate chemistry of the shallow groundwater underneath the farmland to a large extent. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

3.
Nitrate contamination is a common problem in groundwater of the North China Plain (NCP) owing to overuse of fertilizers and discharge of wastewater. Accordingly, it is important to investigate nitrate contamination in recharge areas to understand the fate of nitrate in the plains area. In this study, the spatial and temporal distribution characteristics of nitrate and factors contributing to its sources and transformation in shallow groundwater of the Beiyishui River watershed, NCP, were analysed by a combination of multiple regression and multi‐tracer methods. The nitrate concentration of 79% of the samples exceeded the natural environmental standard of 13.3 mg l?1, while that of 23% of the samples exceeded the World Health Organization (WHO) drinking water standard of 50 mg l?1. Groundwater age estimation of the hill regions based on chlorofluorocarbons (CFCs) revealed a mix of young water from 1982 to 1990 and old, low CFC water. The analysis based on the variations in land use in past years revealed that part of the grassland was converted into woodland between 1980 and 1995; therefore, the land use at the recharge time was used to determine which surface conditions influence groundwater nitrate concentrations. Multiple regression analysis showed that point source pollution contributed to the high concentration of nitrate in the hill region. Fertilizer application associated with land use change from grassland to woodland was also related to the present nitrate concentration. In the plains area, the contribution of fresh water from fault fractures and denitrification led to 31 to 72% and 6 to 51% reductions in nitrate concentrations, respectively. Our results suggested that controlling point source contamination and fertilizer input to hilly regions of the study will prevent groundwater of the plains area from deterioration in future years by mixing fresh water into the aquifers and decreasing denitrification, and therefore nitrate concentrations. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

4.
Stream nitrate levels in a small catchment of mixed land use (the Slapton Wood catchment) have been studied since September 1970; a record of this length is possibly unique in the United Kingdom for such a small basin (94 ha). A sustained increase in nitrate concentration has been observed during the study period. In addition to this long-term trend, short-term changes in nitrate concentrations relate to stream discharge levels and to seasonal variations. Multivariate statistical analysis has been used to quantify these trends and to identify those factors controlling the production and loss of nitrate from the catchment system. The main period of nitrate removal occurs in winter when high concentrations coincide with the main period of throughflow generation. The influence of climatic variability is illustrated by reference to the 1975/76 drought and post-drought period.  相似文献   

5.
Elevated levels of nitrate in groundwater are an important concern for health and the environment. The overapplication of nitrogen fertilizer to croplands is one of the major sources of high nitrate content in groundwater. In this study, we analyse the nitrate concentrations in Korean groundwater based on data from groundwater quality monitoring wells (n = 1,022–2,072), which were sampled twice annually over a recent 13‐year analysis period (2001–2013). We report that groundwater nitrate levels are decreasing, despite steadily increasing groundwater use. The maximum nitrate concentration decreased from 168.91 to 48.11 mg/L, whereas the mean values also show a gradual decreasing trend. Non‐parametric Mann–Kendall tests on nitrate concentrations also confirm the decreasing trend. The nitrate decrease is more clearly evident in agricultural groundwater as compared to domestic and drinking groundwaters. This decrease of nitrate in groundwater coincides with a large decline in nitrogen fertilizer application due to reduced cropland areas, more sustainable agricultural practices, and progressive improvement of sewage disposal services. This study proposes that the long‐term adoption of best practices in agriculture has had a positive impact on groundwater nitrate control.  相似文献   

6.
Abstract

Knowledge of the processes that control nitrate migration and its geochemical evolution in the subsurface are fundamental for the regional management of polluted aquifers. In this paper, the spatial distribution and transient variations of nitrate concentrations, associated with manure fertilization, are used to depict hydrogeological dynamics within the sedimentary aquifer system of la Plana de Vic in the Osona region of Spain. Flow systems are identified from geological, hydraulic head, hydrochemical and isotopic data, and by considering nitrate itself as a tracer that indicates how flow paths are modified by human pressures. In this area, nitrates move through fractured aquitards in flows induced by groundwater pumping. Moreover, the lack of casing in the boreholes permits a mixing of groundwater from distinct layers inside the wells, which negates any benefits from the low-nitrate groundwater found in the deepest aquifer layers. Therefore, impacts on groundwater quality are related to intensive manure fertilization as well as to inadequate well construction and exploitation strategies.

Citation Menció, A., Mas-Pla, J., Otero, N. & Soler, A. (2011) Nitrate as a tracer of groundwater flow in a fractured multilayered aquifer. Hydrol. Sci. J. 56(1), 108–122.  相似文献   

7.
Evaluating the flow paths that contribute to solute flux in stream networks can lead to greater understanding of the linkages between biogeochemistry and hydrology. We compared the contributions of groundwater in spring brooks and in seepage through the streambed to nitrate flux in the Emmons Creek network in the Wisconsin sand plains. We predicted that spring brooks would contribute disproportionately to nitrate flux due to the presumed higher advection rates in springs and less opportunity for nitrate removal relative to seeps. Nitrate flux was measured in 15 spring brooks that entered Emmons Creek. Nitrate flux from seepage was measured at the locations of 30 piezometers, based on Darcy's Law, and by a reach‐scale injection of Rhodamine water tracing (RWT). When seepage discharge was estimated from the RWT release, groundwater inputs from seepage and springs accounted for the discharge gain in the Emmons Creek channel. Springs brooks and seepage (based on the RWT release) contributed 37% and 63%, respectively, to nitrate flux inputs in the study reach. Contrary to our prediction, seeps contributed disproportionately to nitrate flux relative to their discharge. Relatively high rates of seepage discharge and higher than anticipated nitrate concentrations in the shallow pore water at seepage locations contributed to the unanticipated result.  相似文献   

8.
This study aims at recognizing the mechanisms of mass transport between the karst surface and the saturated zone in a morphostructural relief of the Mesozoic karst carbonate platform of Murgia (Puglia, Southern Italy). The large dimension of the karst aquifer, the regional scale of the flow system, the boundary condition constituted by the sea, and the lack of freshwater springs constrain to the use of wells as monitoring points and limit the study area to the recharge area comprising 986 endorheic basins. The concentrations of non‐reactive tracers (nitrates) in the waters of autogenic recharge (from endorheic basins) have been modeled through the evaluation of effective infiltration, land use, and nitrogen surplus, with reference to a time window, which includes a low precipitation period followed by significant rainfall events. The comparison between the modeled nitrate concentrations and the nitrate concentrations measured in ground waters, coupled with the analysis of groundwater chemograms and records of hydraulic heads (all referred to the same time window), allows inferring the mechanism of mass transport between the karst surface and the groundwater table. The mass transport conceptual model requires the presence of the epikarst. The infiltration of significant rainfall in the endorheic basins after a low precipitation period displaces waters stored in the epikarst toward the saturated zone. Ground waters in the post‐event period show higher concentrations of nitrates, lower concentrations of total organic carbon, and higher Mg/Ca ratios than both those of the pre‐event period and the autumn‐winter recharge period. The post‐event recharge from epikarst storage determines a transient hazard of groundwater pollution with a time lag from the occurrence of the heavy rainfall.  相似文献   

9.
Karst spring measurements assess biogeochemical processes occurring within groundwater contributing areas to springs (springsheds) but can only provide aggregated information. To better understand spatially distributed processes that comprise these aggregated measures, we investigated aquifer denitrification evidence in groundwater wells (n = 16) distributed throughout a springshed in the Upper Floridan aquifer in northern Florida. Aquifer geochemistry, nitrate isotopes, and dissolved gases were compared against similar measurements at the spring outlet to evaluate spatial heterogeneity of denitrification evidence in relation to land surface–aquifer connectivity. Sample locations spanned spatial variation in recharge processes (i.e., diffuse vs. focused recharge) and proximity to sources of denitrification reactants (e.g., wetlands). Although no distinct spatial pattern in denitrification was uncovered, excess dissolved N2 gas measurements were only above detection in the unconfined springshed, with some evidence of a wetland proximity effect. Measured oxidation–reduction potential and dissolved oxygen poorly predicted denitrification, indicating that measured denitrification may be occurring upgradient from sampled wells. Despite dramatic spatial chemical heterogeneity across wells, mean values for recharge nitrate concentrations (0.02 to 5.56 mg N L?1) and excess N2 from aquifer denitrification (below detection to 1.37 mg N L?1) corresponded reasonably with mean spring outlet measurements for initial nitrate (0.78 to 1.36 mg N L?1) and excess N2 (0.15 to 1.04 mg N L?1). Congruence between groundwater and spring measurements indicates that combining sampling at the spring outlet and across the springshed is useful for understanding spatial aquifer denitrification. However, this approach would be improved with a high‐density sampling network with transects of wells along distinct groundwater flow paths.  相似文献   

10.
A.L. Jones  P.L. Smart   《Journal of Hydrology》2005,310(1-4):201-215
Autoregressive modelling is used to investigate the internal structure of long-term (1935–1999) records of nitrate concentration for five karst springs in the Mendip Hills. There is a significant short term (1–2 months) positive autocorrelation at three of the five springs due to the availability of sufficient nitrate within the soil store to maintain concentrations in winter recharge for several months. The absence of short term (1–2 months) positive autocorrelation in the other two springs is due to the marked contrast in land use between the limestone and swallet parts of the catchment, rapid concentrated recharge from the latter causing short term switching in the dominant water source at the spring and thus fluctuating nitrate concentrations. Significant negative autocorrelation is evident at lags varying from 4 to 7 months through to 14–22 months for individual springs, with positive autocorrelation at 19–20 months at one site. This variable timing is explained by moderation of the exhaustion effect in the soil by groundwater storage, which gives longer residence times in large catchments and those with a dominance of diffuse flow. The lags derived from autoregressive modelling may therefore provide an indication of average groundwater residence times. Significant differences in the structure of the autocorrelation function for successive 10-year periods are evident at Cheddar Spring, and are explained by the effect the ploughing up of grasslands during the Second World War and increased fertiliser usage on available nitrogen in the soil store. This effect is moderated by the influence of summer temperatures on rates of mineralization, and of both summer and winter rainfall on the timing and magnitude of nitrate leaching. The pattern of nitrate leaching also appears to have been perturbed by the 1976 drought.  相似文献   

11.
The effect of drought on groundwater heads and discharge is often complex and poorly understood. Therefore the propagation of a drought from groundwater recharge to discharge and the influence of aquifer characteristics on the propagation was analysed by tracking a drought in recharge through a linear reservoir. The recharge was defined as a sinusoid function with a period of 1 year. The decrease in recharge owing to drought was simulated by multiplying the recharge during 1 year with a drought fraction between 0 and 1, which represents a decrease in the recharge of 100 to 0%, respectively. The droughts were identified using the threshold level approach, with a threshold that is constant in time. For this case analytical formulations were derived, which express the drought duration and deficit in the groundwater discharge in terms of the decrease in recharge, the reservoir coefficient that characterizes aquifer properties and the height of the threshold level. The results showed that the delay in the groundwater system caused a shift of the main part of the decrease in recharge from the high‐flow to the low‐flow period. This resulted in an increase in drought deficit for discharge compared with the drought deficit for recharge. Also the development of multiyear droughts caused an increase in drought deficit. The attenuation in the groundwater system caused a decrease in drought deficit. In most cases the net effect of these processes was an increase of drought deficit as a result of the propagation through groundwater. Only for small droughts the deficit decreased from recharge to discharge. The amount of increase or decrease depends on the reservoir coefficient and the severity of the drought. Under most conditions a maximum in the drought deficit occurred for a reservoir coefficient of around 200 days. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

12.
Surface water is a scarce resource in Namibia with about sixty percent of Namibia's population dependent on groundwater for drinking purposes. With increasing population, the country faces water challenges and thus groundwater resources need to be managed properly. One important aspect of Integrated Water Resources Management is the protection of water resources, including protection of groundwater from contamination and over-exploitation. This study explores vulnerability mapping as a basic tool for protecting groundwater resources from pollution. It estimates groundwater vulnerability to pollution in the upper Niipele sub-basin of the Cuvelai-Etosha in Northern Namibia using the DRASTIC index. The DRASTIC index uses GIS to estimate groundwater vulnerability by overlaying different spatially referenced hydrogeological parameters that affect groundwater contamination. The study assesses the discontinuous perched aquifer (KDP) and the Ohangwena multi-layered aquifer 1 (KOH-1). For perched aquifers, point data was regionalized by a hydrotope approach whereas for KOH-1 aquifer, inverse distance weighting was used. The hydrotope approach categorized different parts of the hydrogeological system with similar properties into five hydrotopes. The result suggests that the discontinuous perched aquifers are more vulnerable than Ohangwena multi-layered aquifer 1. This implies that vulnerability increases with decreasing depth to water table because contaminants have short travel time to reach the aquifer when they are introduced on land surface. The nitrate concentration ranges between 2 and 288 mg/l in perched aquifers while in Ohangwena multi-layered aquifer 1, it ranges between 1 and 133 mg/l. It was observed that perched aquifers have high nitrate concentrations than Ohangwena 1 aquifer, which correlates well with the vulnerability results.  相似文献   

13.
Geochemical data indicate that the Springfield Plateau aquifer, a carbonate aquifer of the Ozark Plateaus Province in central USA, has two distinct hydrochemical zones. Within each hydrochemical zone, water from springs is geochemically and isotopically different than water from wells. Geochemical data indicate that spring water generally interacts less with the surrounding rock and has a shorter residence time, probably as a result of flowing along discrete fractures and solution openings, than water from wells. Water type throughout most of the aquifer was calcium bicarbonate, indicating that carbonate‐rock dissolution is the primary geochemical process occurring in the aquifer. Concentrations of calcium, bicarbonate, dissolved oxygen and tritium indicate that most ground water in the aquifer recharged rapidly and is relatively young (less than 40 years). In general, field‐measured properties, concentrations of many chemical constituents, and calcite saturation indices were greater in samples from the northern part of the aquifer (hydrochemical zone A) than in samples from the southern part of the aquifer (hydrochemical zone B). Factors affecting differences in the geochemical composition of ground water between the two zones are difficult to identify, but could be related to differences in chert content and possibly primary porosity, solubility of the limestone, and amount and type of cementation between zone A than in zone B. In addition, specific conductance, pH, alkalinity, concentrations of many chemical constituents and calcite saturation indices were greater in samples from wells than in samples from springs in each hydrochemical zone. In contrast, concentrations of dissolved oxygen, nitrite plus nitrate, and chloride generally were greater in samples from springs than in samples from wells. Water from springs generally flows rapidly through large conduits with minimum water–rock interactions. Water from wells flow through small fractures, which restrict flow and increase water–rock interactions. As a result, springs tend to be more susceptible to surface contamination than wells. The results of this study have important implications for the geochemical and hydrogeological processes of similar carbonate aquifers in other geographical locations. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   

14.
《Advances in water resources》2007,30(4):1046-1052
Submarine springs discharge offshore groundwater from confined aquifers extending under the sea. The effects of these springs on the propagation of tidal oscillations in coastal confined aquifers are not known. This paper presents an approximate analytical solution of tidal head fluctuations in a confined aquifer with one submarine spring. The aquifer is assumed to extend in all directions infinitely. The spring is represented by a permeable round column on the seabed, which penetrates completely the impermeable layer overlying the confined aquifer. The error of the approximate solution is negligible if the distance from the spring to the coastline is much greater than the radius of the permeable column representing the spring. Through a hypothetical example, we demonstrate that it is possible to identify the spring’s location using tidal signals observed from inland wells. Tidal groundwater head fluctuations from three inland observation wells at least are needed to determine the 5 model parameters, including the location (2 parameters), the radius of the permeable column representing the spring, the diffusivity of the aquifer, and the tidal loading efficiency of the system.  相似文献   

15.
Alan R. Hill 《水文研究》2012,26(20):3135-3146
The effect of preferential flow in soil pipes on nitrate retention in riparian zones is poorly understood. The characteristics of soil pipes and their influence on patterns of groundwater transport and nitrate dynamics were studied along four transects in a 1‐ to >3‐m deep layer of peat and marl overlying an oxic sand aquifer in a riparian zone in southern Ontario, Canada. The peat‐marl deposit, which consisted of several horizontal layers with large differences in bulk density, contained soil pipes that were generally 0.1 to 0.2 m in diameter and often extended vertically for 1 to >2 m. Springs that produced overland flow across the riparian area occurred at some sites where pipes extended to the peat surface. Concentrations of NO3?–N (20–30 mg L?1) and dissolved oxygen (DO) (4–6 mg L?1) observed in peat pipe systems and surface springs were similar to values in the underlying sand aquifer, indicating that preferential flow transported groundwater with limited nitrate depletion. Low NO3?–N concentrations of <5 mg L?1 and enriched δ15N values indicated that denitrification was restricted to small areas of the peat where pipes were absent. Groundwater DO concentrations declined rapidly to <2 mg L?1 in the peat matrix adjacent to pipes, whereas high NO3?–N concentrations of >15 mg L?1 extended over a larger zone. Low dissolved organic carbon values at these locations suggest that supplies of organic carbon were not sufficient to support high rates of denitrification, despite low DO conditions. These data indicate that it is important to develop a greater understanding of pipes in peat deposits, which function as sites where the transport of large fluxes of water with low biogeochemical reaction rates can limit the nitrate removal capacity of riparian zones. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

16.
Urbanization negatively impacts water quality in streams by reducing stream-groundwater interactions, which can reduce a stream's capacity to naturally attenuate nitrate. Meadowbrook Creek, a first order urban stream in Syracuse, New York, has an inverse urbanization gradient, with heavily urbanized headwaters that are disconnected from the floodplain and downstream reaches that have intact riparian floodplains and connection to riparian aquifers. This system allows assessment of how stream-groundwater interactions in urban streams impact the net sources and sinks of nitrate at the reach scale. We used continuous (15-min) streamflow measurements and weekly grab samples at three gauging stations positioned longitudinally along the creek to develop continuous nitrate load estimates at the inlet and outlet of two contrasting reaches. Nitrate load estimates were determined using a USGS linear regression model, RLOADEST, and differences between loads at the inlet and outlet of contrasting reaches were used to quantify nitrate sink and source behaviour year-round. We observed a nitrate load of 1.4 × 104 kg NO3− per water year, on average, at the outlet of the urbanized reach while the nitrate load at the outlet of the downstream, connected reach was 1.0 × 104 kg NO3− per water year, on average. We found the more heavily urbanized, hydrologically-disconnected reach was a net source of nitrate regardless of season. In contrast, stream-groundwater exchange caused the hydrologically connected reach to be both a source and sink for nitrate, depending on time of year. Both reaches alter nitrate source and sink behaviour at various spatiotemporal scales. Groundwater connection in the downstream, connected reach reduces annual nitrate loads and provides more opportunities for sources and sinks of nitrate year-round than the hydrologically disconnected stream reach. Mechanisms include groundwater discharge into the stream with variable nitrate concentrations, surface-water groundwater interactions that foster denitrification, and stream load loss to surrounding near-stream aquifers. This study emphasizes how loads are important in understanding how stream-groundwater interactions impact reach scale nitrate export in urban streams.  相似文献   

17.
S. V. Panno  W. R. Kelly   《Journal of Hydrology》2004,290(3-4):229-242
This investigation was designed to estimate the mass loading of nitrate (NO3−) and herbicides in spring water discharging from groundwater basins in an agriculturally dominated, mantled karst terrain. The loading was normalized to land use and NO3− and herbicide losses were compared to estimated losses in other agricultural areas of the Midwestern USA. Our study area consisted of two large karst springs that drain two adjoining groundwater basins (total area of 37.7 km2) in southwestern Illinois' sinkhole plain, USA. The springs and stream that they form were monitored for almost 2 years. Nitrate–nitrogen (NO3–N) concentrations at three monitoring sites were almost always above the background concentration (1.9 mg/l). NO3–N concentrations at the two springs ranged from 1.08 to 6.08 with a median concentration of 3.61 mg/l. Atrazine and alachlor concentrations ranged from <0.01 to 34 μg/l and <0.01 to 0.98 μg/l, respectively, with median concentrations of 0.48 and 0.12 μg/l, respectively. Approximately 100,000 kg/yr of NO3–N, 39 kg/yr of atrazine, and 2.8 kg/yr of alachlor were discharged from the two springs. Slightly more than half of the discharged NO3− came from background sources and most of the remainder probably came from fertilizer. This represents a 21–31% loss of fertilizer N from the groundwater basins. The pesticide losses were 3.8–5.8% of the applied atrazine, and 0.05–0.08% of the applied alachlor. The loss of atrazine adsorbed to the suspended solid fraction was about 2 kg/yr, only about 5% of the total mass of atrazine discharged from the springs.  相似文献   

18.
The expanding use of horizontal drilling and hydraulic fracturing technology to produce oil and gas from tight rock formations has increased public concern about potential impacts on the environment, especially on shallow drinking water aquifers. In eastern Kentucky, horizontal drilling and hydraulic fracturing have been used to develop the Berea Sandstone and the Rogersville Shale. To assess baseline groundwater chemistry and evaluate methane detected in groundwater overlying the Berea and Rogersville plays, we sampled 51 water wells and analyzed the samples for concentrations of major cations and anions, metals, dissolved methane, and other light hydrocarbon gases. In addition, the stable carbon and hydrogen isotopic composition of methane (δ13C‐CH4 and δ2H‐CH4) was analyzed for samples with methane concentration exceeding 1 mg/L. Our study indicates that methane is a relatively common constituent in shallow groundwater in eastern Kentucky, where methane was detected in 78% of the sampled wells (40 of 51 wells) with 51% of wells (26 of 51 wells) exhibiting methane concentrations above 1 mg/L. The δ13C‐CH4 and δ2H‐CH4 ranged from ?84.0‰ to ?58.3‰ and from ?246.5‰ to ?146.0‰, respectively. Isotopic analysis indicated that dissolved methane was primarily microbial in origin formed through CO2 reduction pathway. Results from this study provide a first assessment of methane in the shallow aquifers in the Berea and Rogersville play areas and can be used as a reference to evaluate potential impacts of future horizontal drilling and hydraulic fracturing activities on groundwater quality in the region.  相似文献   

19.
Water from the San Joaquin Delta, having chloride concentrations up to 3590 mg/L, has intruded fresh water aquifers underlying Stockton, California. Changes in chloride concentrations at depth within these aquifers were evaluated using sequential electromagnetic (EM) induction logs collected during 2004 through 2007 at seven multiple‐well sites as deep as 268 m. Sequential EM logging is useful for identifying changes in groundwater quality through polyvinyl chloride‐cased wells in intervals not screened by wells. These unscreened intervals represent more than 90% of the aquifer at the sites studied. Sequential EM logging suggested degrading groundwater quality in numerous thin intervals, typically between 1 and 7 m in thickness, especially in the northern part of the study area. Some of these intervals were unscreened by wells, and would not have been identified by traditional groundwater sample collection. Sequential logging also identified intervals with improving water quality—possibly due to groundwater management practices that have limited pumping and promoted artificial recharge. EM resistivity was correlated with chloride concentrations in sampled wells and in water from core material. Natural gamma log data were used to account for the effect of aquifer lithology on EM resistivity. Results of this study show that a sequential EM logging is useful for identifying and monitoring the movement of high‐chloride water, having lower salinities and chloride concentrations than sea water, in aquifer intervals not screened by wells, and that increases in chloride in water from wells in the area are consistent with high‐chloride water originating from the San Joaquin Delta rather than from the underlying saline aquifer.  相似文献   

20.
South Florida's Miami‐Dade agricultural area is located between two protected natural areas, the Biscayne and Everglades National Parks, subject to the costliest environmental restoration project in history. Agriculture, an important economic activity in the region, competes for land and water resources with the restoration efforts and Miami's urban sprawl. The objective of this study, understanding water quality interactions between agricultural land use and the shallow regional aquifer, is critical to the reduction of agriculture's potentially negative impacts. A study was conducted in a 4‐ha square field containing 0·9 ha of corn surrounded by fallow land. The crop rows were oriented NW–SE along the dominant groundwater flow in the area. A network of 18 monitoring wells was distributed across the field. Shallow groundwater nitrate–nitrogen concentration [N‐NO3?] was analyzed on samples collected from the wells biweekly for 3 years. Detailed hydrological (water table elevation [WTE] at each well, groundwater flow direction [GwFD], rainfall) and crop (irrigation, fertilization, calendar) data were also recorded in situ. Flow direction is locally affected by seasonal regional drainage through canal management exercised by the local water authority. The data set was analyzed by dynamic factor analysis (DFA), a specialized time series statistical technique only recently applied in hydrology. In a first step, the observed nitrate variation was successfully described by five common trends representing the unexplained variability. By including the measured hydrological series as explanatory variables the trends were reduced to only three. The analysis yields a quantification of the effects of hydrological factors over local groundwater nitrate concentration. Furthermore, a spatial structure across the field, matching land use, was found in the five remaining common trends whereby the groundwater [N‐NO3?] in wells within the corn rows could be generally separated from those in fallow land NW and SE of the crop strip. Fertilization, masked by soil/water/plant‐delayed processes, had no discernible effect on groundwater nitrate levels. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

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