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1.
Repair mortars with different B/Ag (binder/aggregate) ratios and natural stone were studied in order to understand the influence of limestone aggregate on the properties of mortar and to check the compatibility of repair mortar with a porous limestone. Three different types of mortars with three different aggregate contents were evaluated by using mercury intrusion porosimetry (MIP) and water saturation method (WSM). Changes in density and uniaxial compressive strength as a function of aggregate content were also recorded. For comparison the properties of the porous limestone were also tested, since it is used in monuments and also as aggregate in the mortar. Tested mortars had average porosities of 27.0 % (±2.0), while oolitic limestone has higher average porosity of 32.2 % (±1.9). The limestone has mainly medium and large pore radii (1–100 μm) while the repair mortars even with high aggregate content has predominantly smaller pores. All but one pure repair mortars have higher uniaxial compressive strength than that of the oolitic limestone. The strength decreases while porosity increases with increasing aggregate content.  相似文献   

2.
In the present work, the relationship between intrinsic factors, mechanical properties and durability of Miocene sandstones used in the architectural heritage of Tunisia, specifically in the Roman aqueduct of Oued Miliane and Uthina site, are studied. The petrographic study and the characterisation of porous network have been carried out using optical microscopy, mercury intrusion porosimetry and laser scanner confocal microscopy (LSCM). The hygric behaviour has also been determined from water absorption under vacuum, drying, capillary water absorption and water vapour permeability. The mechanical properties have been assessed from compressive strength and abrasion tests. Rock durability has been evaluated from salt crystallization (sodium sulphate) accelerated aging tests. The results show good hygric behaviour characterised by a high evaporation rate and almost no retention of water; due to the macroporous character of the rock and the good connectivity of the pore network. Because of the poor lithification, the stone has a very low mechanical strength which makes it very vulnerable to the salt crystallization effects. The absence of chemically unstable minerals preserves the rock from chemical alteration. The durability of the building stone is mainly conditioned by salt loading of the monument.  相似文献   

3.
Historical mortars from sixteenth to seventeenth century military forts located at the mouth of the Tagus River in Lisbon have been characterized by polarized light microscopy (PLM), thermal analysis (TG/DTA), X-ray diffractometry (XRD) and scanning electron microscopy + energy dispersive spectroscopy (SEM + EDS). The results indicate that the mortars used were all hydraulic lime-based. The presence of well-rounded lime lumps indicates a limited use of water during the lime hydration process. The detection of hydrated calcium chloroaluminate and carboaluminate compounds mostly at binder-aggregate interfaces provides evidence for the onset of pozzolanic reactions during mortar production as further confirmed by the presence of ceramic fragments in the aggregate fractions intentionally added by the fort builders to increase the hydraulic properties of the mortars. The higher mechanical strength and greater resistance to degradation processes imparted by these pozzolanic compounds could explain why, despite the extreme proximity of the investigated sites to the sea, salt weathering processes do not appear to have significantly affected the studied mortars.  相似文献   

4.
Gypsum-based mortars were widely used during the Mudejar artistic period in Spain from the 12th to 16th century. During restoration works, compatibility between the new repair mortars and the original components is essential for an adequate intervention on the monument. The increasing interest of knowing the properties of the gypsum-lime-based mortars for restoration purposes justifies the research carried out. Different mortars compatible with traditional building materials were elaborated by varying the binder proportions, the type of aggregates, the binder/aggregate ratios and the curing time. The main goal of this paper is to characterize the mechanical behaviour and the pore structure of the mortars as a function of curing time. The influence between the different variables used to prepare the mortars and the development of the carbonation process over time is also considered. Mechanical strength and porosity measurements as well as X-ray diffraction and thermal analysis were performed after curing times of 1, 28 and 90 days. The results obtained confirmed a progressive increase in mechanical strength linked to the carbonation of the mortars prepared. Less lime binder and also aggregate contents showed the highest rise in strength over time, related to the highest initial porosity which favoured the carbon dioxide flow. The use of siliceous aggregates (GL-QS mortars) obtained the best results in the development of physico-mechanical properties over curing time. The knowledge obtained from the studied mortars provides practical information to establish a suitable mortar mixture for restoration works on historic buildings and modern architecture where gypsum-lime-based mortars are used.  相似文献   

5.
失水收缩是诱发黏性土体开裂的主要因素之一,揭示收缩开裂的内在机制对预防工程灾变具有十分重要的意义。以压实红黏土为研究对象,开展自然风干条件下4种初始干密度试样的自由收缩试验。依据试样收缩曲线的特征,确定了4个特征含水率点,包括饱和含水率、比例收缩阶段中间含水率、缩限以及残余收缩阶段中间含水率。试样从饱和含水率状态风干到上述特征含水率点后立刻用液氮冻干法干燥,并通过孔隙分析仪测定该脱湿状态下的孔隙分布特征,着重探明细观孔隙体积与宏观总体积收缩的对应过程。结果表明：失水过程的前阶段（偏湿时）团聚体间的孔隙优先收缩,表现为大孔隙体积峰值半径随着含水率的降低而减小,小孔径的孔隙体积则增多;而当达到残余阶段后团聚体内的孔隙会发生收缩,表现为小孔隙的体积峰值会减小;随着含水率进一步降低,土体进入零收缩阶段,团聚体间和团聚体内的孔隙均不会发生变化。整个失水过程中孔隙总体积明显减小,与所测得的宏观变化规律相吻合。  相似文献   

6.
干湿循环作用下红黏土收缩特征研究   总被引：5，自引：1，他引：4  
以贵州某高速公路沿线红黏土为研究对象,开展了干湿循环作用后红黏土的收缩特性试验研究,探讨了干湿循环次数和初始含水率对红黏土收缩性状的影响.试验结果表明：同一循环次数内,各试样的环向收缩率在6～8 h时达到稳定,而轴向线缩率则需更长的稳定时间;随着初始含水率增加,各试样的初始轴向线缩率减小,而初始环向收缩率增加;28%含水率试样具有相近的最终轴向变形和环向变形量,而34%含水率的试样环向变形量高于轴向变形量;初始含水率变化不大,但体缩率的变化率却明显不同,说明干湿循环过程使得土体内部结构变得不稳定,但颗粒间相互作用的本质未发生明显变化;干湿循环作用对重塑红黏土最优含水率位置的基本无影响,这说明其未能改变黏土集聚体内对结合水的最大吸附能力.通过压汞试验得到了不同干湿循环作用后试样的孔隙分布情况,随着干湿循环次数的增加小孔径尺寸和分布密度改变较小,而大孔径尺寸减小,分布密度也在减小.干湿循环作用对聚集体内孔径的影响大于对微聚体内孔隙影响,与所测得的宏观收缩规律相吻合.  相似文献   

7.
Most prehistoric plasters and mortars consist of very small amounts of burnt lime mixed with anthropogenic debris, soil, and sediment. To solve the problem of identification of such small amounts of lime in impure lime plasters, a series of experimental plasters were prepared and studied with petrographic methods. Samples of living floors from five prehistoric sites in Greece were also reanalyzed under the light of the experimental findings and compared with natural calcareous sediment. The most promising features for identifying lime are transitional textures of partially carbonized slaked lime that can be observed in the lime lumps and the binding matrix. They are usually in the form of ill‐crystallized portlandite and calcite mixtures or cryptocrystalline calcite. Well‐reacted calcitic groundmass, shrinkage fractures, and occasionally colloidal forms are also additional indications. The present experimental study shows that lime could be easily produced by heating porous, soft calcareous materials. This would probably account for the very frequent use (in small quantities) of lime in Greek prehistory. Plaster and mortars were made by mixing damp anthopogenic dirt as aggregate and fragments of quicklime, a technique known as “hot mixing.” © 2007 Wiley Periodicals, Inc.  相似文献   

8.
A record of mortar and salt analyses from the last 20 years on various monuments in Saxony demonstrates the close relation between the occurrence of magnesium sulphate salts and the use of dolomitic lime mortars in a regional frame. The regional distribution scheme of dolomitic lime in historic mortars depends on the geological setting of the territory, i.e. the natural occurrence of dolomite deposits. Sulphation of these mortars with the formation of magnesium sulphate and gypsum is mainly due to environmental pollution, as can be shown by sulphur stable isotope analyses. Exposure of the sulphated mortar surfaces to rain leads to the preferential dissolution and advective transport of the novel formed magnesium sulphate salts, which effloresce or subfloresce on the mortar surface or can be accumulated in the structure of adjoining porous building materials like natural stones. These processes may cause severe damages in mortars by the weakening of the binder and in porous stones by salt crystallisation of phases like epsomite and hexahydrite.  相似文献   

9.
抗疏力固化剂在我国黄土加固中运用较少,探究抗疏力固化剂是否有利于维持黄土内部干燥状态很有必要。采用抗疏力固化剂对重塑Q3黄土改性,室内开展水滴入渗试验、柔性壁渗透试验、收缩试验及压力膜仪脱水试验,分别探讨抗疏力固化剂掺量对黄土进水、渗透及失水能力的影响。结果显示,随抗疏力固化剂掺量提高,土样斥水性急剧增大,明显优于粉煤灰、水泥、石灰改性土;渗透系数基本不变,水的流通性基本不变;干缩失水过程改性土样含水率及土-水特征曲线毛细作用区曲线斜率均变化不大,黄土失水能力基本不变。结合电镜及压汞试验结果可知,抗疏力固化剂对黄土中大孔隙、中孔隙体积含量影响较小,从而对黄土中水的流通及失去能力影响较少,证明抗疏力固化剂改性黄土斥水性明显提高,而失水能力基本不变,有利于维持黄土内部的干燥状态。  相似文献   

10.
The sulfation of four types of calcitic and dolomitic lime mortars exposed to SO2 in the presence of particulate matter from diesel vehicle exhaust emissions has been investigated. The binders mineralogy and mortars texture are the main factors influencing the formation of deleterious sulfate salts. The type of binder also influences the pore size distribution and the total porosity of the mortars: for equal aggregate (quartz or dolomite), dolomitic lime mortars have smaller pores and higher porosity than calcitic ones. During the first 24 h exposure to SO2, calcitic lime mortars undergo a higher weight increase than dolomitic ones due to rapid formation of gypsum on their surface. However, at the end of the sulfation test (10 days), dolomitic mortars show a higher weight increase due to massive formation of epsomite and gypsum, which is facilitated by their higher porosity and the high reactivity of Mg phases in the porous and partially carbonated binder. Control samples (not covered with diesel particulate matter) also develop calcium and magnesium sulfates upon long term exposure to SO2. This is due to the presence of uncarbonated Ca and Mg hydroxides that promote SO2 fixation as sulfates. However, the amount and size of sulfate crystals are significantly smaller than those observed on samples covered with diesel particulate matter. These results show that diesel particulate matter enhances the sulfation of lime mortars and demonstrate that sulfation of dolomitic lime is an important mechanism for the in situ formation of highly soluble and deleterious hydrated magnesium sulfates (epsomite and hexahydrite). The use of dolomitic limes in the conservation of monuments exposed to air pollution in urban environments may therefore pose a significant risk.  相似文献   

11.
石灰土作为路基填料代替宕渣是一种较为经济的方案,但灰土初始强度低、硬化速率慢、碳化时间长,不利于快速施工,需要进行改良研究。利用偏高岭土与石灰发生火山灰反应的原理改良灰土,通过单轴压缩试验和三轴压缩试验,分析改良灰土冻融循环条件下力学参数变化规律,利用图像处理技术提取改良灰土图像表面孔隙,建立孔隙率与强度的关系,并通过研究龄期、石灰含量和含水率变化规律,分析偏高岭土改良灰土的机制。结果表明：偏高岭土能够有效提高灰土材料反应速率,改善灰土力学特性;偏高岭土在一定程度上能够恢复冻融循环导致的灰土力学性能损失,降低冰晶体产生的孔隙;灰土强度达到最优后,其强度随着石灰的增加而降低,而经偏高岭土改良后其强度将继续增加;火山灰反应比灰土碳化过程消耗更多的水分,有效提高了灰土的抗冻性能。  相似文献   

12.
A common decay scenario in old and new buildings was simulated: the effects on masonry structures of salt efflorescence or subefflorescence produced by the rise of saline solution. Eight different types of masonry wall each made up of a combination of different construction materials (brick, calcarenite and four types of mortar were combined as follows: pure lime mortar, mortar + air entraining agent, mortar + pozzolana, mortar + air entraining agent + pozzolana) have been tested. These materials have different textures (strong anisotropy in brick, irregular-shaped pores in calcarenite, retraction fissures or rounded pores in mortars which also show a reduction of porosity along the contact area with the stone), different hydric behaviours (under total immersion brick + mortar specimens absorb water faster than calcarenite + mortar specimens) and different pore size distribution (brick shows unimodal pore distribution, whereas calcarenite and mortars are bimodal). In the salt weathering test, mortars interlayered with masonry blocks did not act as sacrificial layers. In fact, they allowed salts to rise through them and crystallize on the brick or calcarenite pieces causing the masonry structure to decay. Only the addition of an air-entraining agent partially hindered the capillary rise of the salt-laden solutions.  相似文献   

13.
Specimens prepared from three lateritic soil samples were subjected to drying under laboratory conditions. Volumetric shrinkage strains were measured at the end of the drying period. Results of this study indicate that, for the lateritic soils tested, volumetric shrinkage strains are influenced by soil composition and compaction conditions. Volumetric shrinkage strain increased with higher compaction water content. The influence of compaction water content on measured volumetric shrinkage strain was more pronounced in specimens with higher fines content. A regression equation was developed from the data to estimate volumetric shrinkage strain given the compaction water content relative to optimum, plasticity index, fines content and compactive effort.  相似文献   

14.
Repair mortar and mixture of repair mortar with porous limestone sand aggregate were tested under laboratory conditions. Water absorption properties and micro-fabric analyses with a combination of strength tests were applied to assess the durability and compatibility of repair mortar with porous limestone. Uniaxial compressive strength and flexural strength were measured after 3, 7, 14, 28 and 90 days of casting. Durability was tested by comparing strength test results of samples kept air dry, water saturated, dried in drying chamber, freeze–thaw and non-standardized freeze–thaw cycles. The results indicate that with time various trends in strength were observed. In general, limestone aggregate content decreases more the compressive strength more than the flexural strength of the mortar. Standardized freeze–thaw tests of saturated samples caused a rapid material loss after 25 cycles, while freeze–thaw tests of undersaturated samples demonstrated that even after 100 cycles the test specimens still have a significant strength. Water-saturated samples that contain 50% of limestone aggregate have a 50% loss of strength in comparison with saturated repair mortar, while air-dry and water-saturated repair mortar has a minor strength difference after 90 days. The use of smaller amounts of porous limestone aggregate in repair mortar allow the preparation of repairs that are compatible with the monuments of Central Europe that were constructed from porous limestone.  相似文献   

15.
Several studies have shown that the degradation of architectural monuments constructed using Tuffeau stones from Val de Loire region of France over a period of time are often related to use of mortars that are not compatible with the Tuffeau stones. For this reason, it is important to ensure physico-chemical compatibility between Tuffeau and the mortar. To alleviate differences in compatibility characteristics, a mortar is prepared from hydrated lime and aggregates obtained from the crushing of Tuffeau stone and used in this study. The key parameters that influence the strength and durability characteristics such as mechanical resistance, water transfer properties, and physico-chemical properties were identified and studied. Based on these studies, recommendations are offered for the preparation of a more compatible mortar that can be used in the construction and restoration of monuments using Tuffeau stone.  相似文献   

16.
谈云志  胡焱  邓永锋  曹玲  左清军  明华军 《岩土力学》2019,40(11):4213-4219
红黏土失水易收缩开裂而诱发工程灾害,为抑制或缓减红黏土的收缩特征,添加4%偏高岭土和5%石灰改善其水敏性。按照最优含水率制备压实试样,养护180 d后抽真空饱和,脱湿到预定含水率,随后开展收缩、无侧限抗压强度、吸力和孔隙分析等试验。结果表明,压实红黏土随着含水率降低,其无侧限抗压强度呈现先增大后减少的变化规律,这是脱湿导致的红黏土衍生微裂隙,进而引起结构性损伤所致。红黏土掺入石灰,尤其是掺入石灰-偏高岭土后,虽然脱湿也会引起强度减小,但接近完全干燥时,其强度又会增大。由此说明,偏高岭土协同石灰可以更加有效地抑制红黏土收缩效应,提高其整体强度。究其原因,是偏高岭土含有大量无定形硅、铝氧化物,且呈现边-面“搭接”的独特结构形态,使其能够快速捕获氢氧化钙溶液中的钙离子,在红黏土团（颗）粒间形成了胶结性水化物。  相似文献   

17.
Desiccation cracking of clay soil is of critical importance in many applications, such as industrial waste containment, hydraulic barriers, road embankments, and agricultural operations. The factors that influence cracking are known qualitatively, but it is not clear how to predict the initiation and propagation of cracks. This study presents a discrete element approach to modeling desiccation cracking in thin clay layers, considering material property changes. First, an aggregate shrinkage model based on the aggregate structure of clay was proposed, and the drying shrinkage of clay soil was modeled by imposing drying shrinkage kinetics for each aggregate at the micro-scale. Second, the clay soil was represented by an assembly of aggregates linked by bonds, and desiccation cracking of the clay layer was modeled using a three-dimensional discrete element code (PFC3D), with the aid of the embedded programming language FISH. When the clay layer is sufficiently thin, the water content gradient along the section can be neglected; thus, the shrinkage kinetics are the same for all of the grains of clay. In the model based on the discrete element method (DEM), the bond strength and contact stiffness changed during drying. Their changes were determined by matching the simulation results with the experimental data. Third, the DEM approach was validated by reproducing experimental desiccation tests performed on a thin clay layer in a disk shape. The geometric parameters of surface cracks were quantified using image analysis techniques and were compared with experimental observations. Fourth, some factors of influence, such as the sample thickness, the properties of the soil–base interface, micro-mechanical parameters, and shrinkage parameters, were investigated using the DEM model. The results obtained from the DEM analyses were compared with the results of prior research in this field of study. The approach used in this study is very promising for simulating desiccation cracking in thin clay soil because the model captures the initiation and propagation mechanism of desiccation cracks. Although this study was carried out on surface cracking in a thin clay layer, the extension of this methodology is of potential benefit not only for predicting three-dimensional desiccation cracking in real clay liners but also for modeling cracking in other materials with properties that vary with water content or temperature, such as concrete and rock.  相似文献   

18.
The paper presents the results of an experimental study on the effects of the initial water content and dry density on the soil–water retention curve and the shrinkage behavior of a compacted Lias-clay. The initial conditions after compaction (initial water content and initial dry density) have been chosen on the basis of three Proctor tests of different compaction efforts. According to the eight chosen initial conditions clay samples have been compacted statically. The relation between total suction and water content was determined for the drying path starting from the initial conditions without previous saturation of the specimens. A chilled-mirror dew-point hygrometer was used for the suction measurements. For the investigation of the shrinkage behavior cylindrical specimens were dried to desired water contents step-by-step without previous saturation. The volume of the specimens was measured by means of a caliper. Based on the test results the influence of different initial conditions on the soil suction and the shrinkage behavior is analyzed. The soil–water retention curves obtained in terms of the gravimetric water content are independent of the initial dry density. At water contents above approximately 11–12.5% a strong influence of the compaction water content is observed. At smaller water contents, the soil–water retention curve is independent of the compaction water content. The results of the shrinkage tests show that the influence of the compaction dry density on the shrinkage behavior is negligible. Similar to the drying behavior of saturated samples a primary and a residual drying process could be distinguished. The primary drying process is strongly influenced by the initial water content. In contrast, the rate of the volume change of the residual drying process is unaffected by the initial water content.  相似文献   

19.
Pozzolanic fly ash as a hydraulic barrier in land fills   总被引：2，自引：0，他引：2  
The liner plays an important role in controlling migration of contaminants present in the leachate in waste containment systems such as land fills and impoundments. Although questions have been raised about the performance of clay liners, they are increasingly used singly or as double liners in disposal sites. Though the clay liners possess many advantages such as low permeability and large attenuative capacity, they also possess high shrinkage potential and hence can crack under unsaturated conditions causing instability and increase in leakage rates. Further, the permeability of the clay linear can increase due to clay–pollutant interaction. This study examines the potential of pozzolanic fly ash as a hydraulic barrier in land fill. The behaviour of three different types of fly ashes, showing a range of physical properties and chemical composition from three different sources are reported in the study. Geotechnical properties, needed to evaluate the use of fly ashes as barriers, such as shrinkage, compaction, permeability, consolidation and strength characteristics are reported. The results show that fly ashes possess low shrinkage and hence do not crack. Compacted fly ashes undergo very little volume changes. They also show that pozzolanic fly ashes develop good strength properties with time. Pozzolanic fly ashes containing sufficient lime develop strength even without addition of lime. Non-pozzolanic fly ashes do not develop strength even on addition of lime. Fly ashes generally consist of silt size particles and consequently possess high permeability. However, pozzolanic fly ashes with lime exhibit low permeability on curing because of the formation of gelatinous compounds which block the pores. Thus, pozzolanic fly ashes appear to be promising for construction of liners to contain alkaline leachate.  相似文献   

20.
This paper presents new petro-chemical data on some typical mortars found in many buildings in the historic city centre of Catania (Eastern Sicily). Extensively used in the architecture of the city from the second half of the nineteenth century until the mid-twentieth century, these mortars are characterised by a particular aggregate locally known as “agghiara” or “ghiara”. This is the product of thermal transformation induced by the heating undergone by palaeo-soils, originally rich in organic matter, covered by lava flows, which change their colour to reddish nuances. The volcanic origin of ghiara is a peculiar feature of the Etnean area. Mixed with lime, it gives to mortars an intense reddish colour, as well as hydraulic properties, which are comparable with those of the historically used pozzolana. This work aimed at complete characterisation of these ghiara mortars, for providing information on several important technological aspects. In order to get information on used raw materials, sampling of some ancient underground quarries, located both in the historic city centre and at the periphery, was also performed. Results led to the complete characterisation of the selected ghiara mortars and yielded information on some technological features and the composition of both newly formed and secondary phases, these latter due to alteration processes. The hydraulic properties of mortars have been related to the occurrence of amorphous phases within the ghiara aggregate, which were identified by means of SEM morphological observations. These phases, formed during the “firing” process of palaeo-soils, react with lime producing hydraulic compounds (C–S–H and C–A–H), which are responsible for the mortars durability.  相似文献   

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