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1.
Yuk L. Yung  W.B. Demore 《Icarus》1982,51(2):199-247
The photochemistry of the stratosphere of Venus was modeled using an updated and expanded chemical scheme, combined with the results of recent observations and laboratory studies. We examined three models, with H2 mixing ratio equal to 2 × 10?5, 5 × 10?7, and 1 × 10?13, respectively. All models satisfactorily account for the observations of CO, O2, O2(1Δ), and SO2 in the stratosphere, but only the last one may be able to account for the diurnal behavior of mesospheric CO and the uv albedo. Oxygen, derived from CO2 photolysis, is primarily consumed by CO2 recombination and oxidation of SO2 to H2SO4. Photolysis of HCl in the upper stratosphere provides a major source of odd hydrogen and free chlorine radicals, essential for the catalytic oxidation of CO. Oxidation of SO2 by O occurs in the lower stratosphere. In the high-H2 model (model A) the OO bond is broken mainly by S + O2 and SO + HO2. In the low-H2 models additional reactions for breaking the OO bond must be invoked: NO + HO2 in model B and ClCO + O2 in model C. It is shown that lightning in the lower atmosphere could provide as much as 30 ppb of NOx in the stratosphere. Our modeling reveals a number of intriguing similarities, previously unsuspected, between the chemistry of the stratosphere of Venus and that of the Earth. Photochemistry may have played a major role in the evolution of the atmosphere. The current atmosphere, as described by our preferred model, is characterized by an extreme deficiency of hydrogen species, having probably lost the equivalent of 102–103 times the present hydrogen content.  相似文献   

2.
A. Bar-nun 《Icarus》1980,42(3):338-342
The effects of the newly discovered thunderstorms on Venus upon the nitrogen and carbon species in its atmosphere were calculated. An Earth-like lightning frequency of 100 sec?1 was used for Venus, in accord with recent optical measurements by Pioneer-Venus (W. J. Borucki, J. W. Dyer, G. Z. Thomas, J. C. Jordon, and D. A. Comstock, submitted for publication). The rate of NO production by thunder shock waves, 2.5 × 1011 g year?1, is about an order of magnitude smaller than on the Earth. But on Venus, in the absence of precipitation, which is the major removal mechanism of odd nitrogen from the Earth's atmosphere, the mixing ratios of odd nitrogen species might be considerably higher. The global CO production is governed by CO2 photolysis rather than by CO2 pyrolysis by lightning. However, thunderstorms produce about 2.5 × 1011 g year?1 of CO in the cloud layer, far from the high altitude CO2 photolysis region.  相似文献   

3.
Atmospheric angular momentum variations of a planet are associated with the global atmospheric mass redistribution and the wind variability. The exchange of angular momentum between the fluid layers and the solid planet is the main cause for the variations of the planetary rotation at seasonal time scales. In the present study, we investigate the angular momentum variations of the Earth, Mars and Venus, using geodetic observations, output of state-of-the-art global circulation models as well as assimilated data. We discuss the similarities and differences in angular momentum variations, planetary rotation and angular momentum exchange for the three terrestrial planets. We show that the atmospheric angular momentum variations for Mars and Earth are mainly annual and semi-annual whereas they are expected to be “diurnal” on Venus. The wind terms have the largest contributions to the LOD changes of the Earth and Venus whereas the matter term is dominant on Mars due to the CO2 sublimation/condensation. The corresponding LOD variations (ΔLOD) have similar amplitudes on Mars and Earth but are much larger on Venus, though more difficult to observe.  相似文献   

4.
In absence of other mechanisms, the main input of CO2into the Venusian atmosphere is via volcanic out gassing. Since Venus can be regarded as a planet-wide large igneous province, we can expect large quantities of CO2 being transferred into its atmosphere via volcanic out gassing. We have quantified the maximum possible amount of CO2 that can be out gassed via a single massive episode of resurfacing of the planet. This figure (5.6 × 1019 kg of CO2) is about 8 times smaller than the total CO2 present in the Venusian atmosphere (4.55 × 1020 kg CO2). The lack of planet-wide, efficient mechanisms for the recycling of CO2 on Venus indicates that CO2 has progressively accumulated in the atmosphere. Based on these considerations we suggest that the “equivalent” to eight global resurfacing episodes would be required to account for the present values of CO2 atmosphere. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

5.
Imaging spectrometers are highly effective instruments for investigation of planetary atmospheres. They present the advantage of coupling the compositional information to the spatial distribution, allowing simultaneous study of chemistry and dynamics in the atmospheres of Venus and Mars. In this work, we summarize recent results about the O2(a1Δg) night and day glows, respectively obtained by VIRTIS/Venus Express and OMEGA/Mars Express, the imaging spectrometers currently in orbit around Venus and Mars. The case of the O2(a1Δg - X3Σg−) IR emission at 1.27 μm on the night side of Venus and the day side of Mars is analyzed, pointing out dynamical aspects of these planets, like the detection of gravity waves in their atmospheres. The monitoring of seasonal and daily airglow variations provides hints about the photochemistry on these planets.  相似文献   

6.
Abstract— The origin of hematite detected in Martian surface materials is commonly attributed to weathering processes or aqueous precipitation. Here, we present a new hematite formation mechanism that requires neither water nor weathering. Glass‐rich basalts with Martian meteorite‐like chemistry (high FeO, low Al2O3) oxidized at high (700 and 900 °C) temperatures in air and CO2, respectively, form thin (<1 μm) hematite coatings on their outermost surfaces. Hematite is manifested macroscopically by development of magnetism and a gray, metallic sheen on the glass surface and microscopically by Fe enrichment at the glass surface observed in element maps. Visible and near‐infrared, thermal infrared, and Raman spectroscopy confirm that the Fe enrichment at the oxidized glass surfaces corresponds to hematite mineralization. Hematite formation on basaltic glass is enabled by a mechanism that induces migration of Fe2+ to the surface of an oxidizing glass and subsequent oxidation to form hematite. A natural example of the hematite formation mechanism is provided by a Hawaiian basalt hosting a gray, metallic sheen that corresponds to a thin hematite coating. Hematite coating development on the Hawaiian basalt demonstrates that Martian meteorite‐like FeO contents are not required for hematite coating formation on basalt glass and that such coatings form during initial extrusion of the glassy basalt flows. If gray hematite originating as coatings on glassy basalt flows is an important source of Martian hematite, which is feasible given the predominance of igneous features on Mars, then the requirement of water as an agent of hematite formation is eliminated.  相似文献   

7.
This paper deals with two common problems and then considers major aspects of chemistry in the atmospheres of Mars and Venus. (1) The atmospheres of the terrestrial planets have similar origins but different evolutionary pathways because of the different masses and distances to the Sun. Venus lost its water by hydrodynamic escape, Earth lost CO2 that formed carbonates and is strongly affected by life, Mars lost water in the reaction with iron and then most of the atmosphere by the intense meteorite impacts. (2) In spite of the higher solar radiation on Venus, its thermospheric temperatures are similar to those on Mars because of the greater gravity acceleration and the higher production of O by photolysis of CO2. O stimulates cooling by the emission at 15 μm in the collisions with CO2. (3) There is a great progress in the observations of photochemical tracers and minor constituents on Mars in the current decade. This progress is supported by progress in photochemical modeling, especially by photochemical GCMs. Main results in these areas are briefly discussed. The problem of methane presents the controversial aspects of its variations and origin. The reported variations of methane cannot be explained by the existing data on gas-phase and heterogeneous chemistry. The lack of current volcanism, SO2, and warm spots on Mars favor the biological origin of methane. (4) Venus’ chemistry is rich and covers a wide range of temperatures and pressures and many species. Photochemical models for the middle atmosphere (58-112 km), for the nighttime atmosphere and night airglow at 80-130 km, and the kinetic model for the lower atmosphere are briefly discussed.  相似文献   

8.
Classified as a terrestrial planet, Venus, Mars, and Earth are similar in several aspects such as bulk composition and density. Their atmospheres on the other hand have significant differences. Venus has the densest atmosphere, composed of CO2 mainly, with atmospheric pressure at the planet's surface 92 times that of the Earth, while Mars has the thinnest atmosphere, composed also essentially of CO2, with only several millibars of atmospheric surface pressure. In the past, both Mars and Venus could have possessed Earth-like climate permitting the presence of surface liquid water reservoirs. Impacts by asteroids and comets could have played a significant role in the evolution of the early atmospheres of the Earth, Mars, and Venus, not only by causing atmospheric erosion but also by delivering material and volatiles to the planets. Here we investigate the atmospheric loss and the delivery of volatiles for the three terrestrial planets using a parameterized model that takes into account the impact simulation results and the flux of impactors given in the literature. We show that the dimensions of the planets, the initial atmospheric surface pressures and the volatiles contents of the impactors are of high importance for the impact delivery and erosion, and that they might be responsible for the differences in the atmospheric evolution of Mars, Earth and Venus.  相似文献   

9.
Hydroxyl nightglow is intensively studied in the Earth atmosphere, due to its coupling to the ozone cycle. Recently, it was detected for the first time also in the Venus atmosphere, thanks to the VIRTIS-Venus Express observations. The main Δν=1, 2 emissions in the infrared spectral range, centred, respectively, at 2.81 and 1.46 μm (which correspond to the (1-0) and (2-0) transitions, respectively), were observed in limb geometry (Piccioni et al., 2008) with a mean emission rate of 880±90 and 100±40 kR (1R=106 photon cm−2 s−1 (4πster)−1), respectively, integrated along the line of sight. In this investigation, the Bates-Nicolet chemical reaction is reported to be the most probable mechanism for OH production on Venus, as in the case of Earth, but HO2 and O may still be not negligible as mechanism of production for OH, differently than Earth. The nightglow emission from OH provides a method to quantify O3, HO2, H and O, and to infer the mechanism of transport of the key species involved in the production. Very recently, an ozone layer was detected in the upper atmosphere of Venus by the SPICAV (Spectroscopy for Investigation of Characteristics of the Atmosphere of Venus) instrument onboard Venus Express (Montmessin et al., 2009); this discovery enhances the importance of ozone to the OH production in the upper atmosphere of Venus through the Bates-Nicolet mechanism. On Venus, OH airglow is observed only in the night side and no evidence has been found whether a similar emission exists also in the day side. On Mars it is expected to exist both on the day and night sides of the planet, because of the presence of ozone, though OH airglow has not yet been detected.In this paper, we review and compare the OH nightglow on Venus and Earth. The case of Mars is also briefly discussed for the sake of completeness. Similarities from a chemical and a dynamical point of view are listed, though visible OH emissions on Earth and IR OH emissions on Venus are compared.  相似文献   

10.
We calculate the amount of methane that may form via reactions catalyzed by metal-rich dust that condenses in the wake of large cometary impacts. Previous models of the gas-phase chemistry of impacts predicted that the terrestrial planets' atmospheres should be initially dominated by CO/CO2, N2, and H2O. CH4 was not predicted to form in impacts because gas-phase reactions in the explosion quench at temperatures ∼2000 K, at which point all of the carbon is locked in CO. We argue that the dust that condenses out in the wake of a large comet impact is likely to have very effective catalytic properties, opening up reaction pathways to convert CO and H2 to CH4 and CO2, at temperatures of a few hundred K. Together with CO2, CH4 is an important greenhouse gas that has been invoked to compensate for the lower luminosity of the Sun ∼4 Gyr ago. Here, we show that heterogeneous (gas-solid) reactions on freshly-recondensed dust in the impact cloud may provide a plausible nonbiological mechanism for reducing CO to CH4 before and during the emergence of life on Earth, and perhaps Mars as well. These encouraging results emphasize the importance of future research into the kinetics and catalytic properties of astrophysical condensates or “smokes” and also more detailed models to determine the conditions in impact-generated dust clouds.  相似文献   

11.
Consideration of theoretical limits and experimental data for the kinetics of the reaction quartz + calcite → wollastonite + CO2 supports the concept of a shortterm quasiequilibrium state for the atmosphere of Venus. These data indicate that the time scale of this reaction and of any competing CO2 producing reaction may be as short as several hundred years or less at the inferred Venus surface temperatures.  相似文献   

12.
Consequences of a heavy bombardment for the atmospheres of Earth and Mars are investigated with a stochastic model. The main result is the dominance of the accumulation. The atmospheric pressure is strongly increasing both for Earth and Mars in the course of an enhanced bombardment. The effect of atmospheric erosion is found to be minor, regarding escape during meteorite entry, in the expanding vapor plume, and ejection due to free-surface motion. The initial atmospheric surface pressure if comparable to the modern value turns out as a less important additive constant of the final pressure. Impactor retention and atmospheric erosion are parametrized in terms of scaling laws, compatible with recent numerical simulations. The dependence on impactor size, atmospheric and planetary parameters is analyzed among alternative models and numerical results. The stochastic model is fed with the net replenishment originating from impactor material and the loss of preexisting atmospheric gas. Major input parameters are the total cumulative impactor mass and the relative mass of atmophile molecules in comets and asteroids. Input size distributions of the impactor ensemble correspond to presently observed main belt asteroids and KBOs. Velocity distributions are taken from dynamical simulations for the Nice model. Depending on the composition of large cometary impactors, the Earth could acquire a more massive atmosphere, a few bars in terms of surface pressure, mostly as CO and CO2. For Mars accumulation of 1–4 bars of CO and CO2 requires an asteroidal ‘late veneer’ of the order of 1024 g containing 2% atmophiles.  相似文献   

13.
Recent radar measures of the radius and mass of Mercury imply a composition for the planet containing about 60% iron. One or other of two conclusions seems inescapable: either that Mercury is a highly exceptional object among terrestrial planets, or that all measures to date of the planet involve substantial systematic error. In either case the situation is such that independent checking of the radius and mass of Mercury by some entirely different means has become of the greatest importance to planetary physics and cosmogony.The recent radar and other determinations of the solid radius of Venus imply an internal structure similar to that of the Earth, namely a liquid core surrounded by a solid mantle and outer-shell zone. The theory also implies that the temperatures within Venus should be slightly higher than at the corresponding parts of the Earth. The proportion of mass in the core of Venus (about 25% of the whole) is entirely consistent with the phase-change hypothesis as to its nature, as of course is also the absence of any liquid or iron core in both Mars and the Moon. On the older iron-core hypothesis, Venus with considerably less iron content by mass than the Earth, and Mars and the Moon with none, would all present problems in different degrees to account for the differences of composition.If Venus began as an all-solid planet, the initial radius would have been about 6300 km, and the total amount of surface reduction to date owing to contraction of the planet would have been almost 40 million km2, and as a proportion of the total area only slightly less than the contraction of the Earth. The theory thus predicts the existence of folded and thrusted mountain-systems of terrestrial type at the surface of Venus.  相似文献   

14.
A. Aitta 《Icarus》2012,218(2):967-974
The mass and radius of our closest neighbour Venus are only slightly smaller than those of the Earth indicating a similarity in composition. However, the lack of self-sustained internal magnetic field in Venus points to a difference in the core structure. The theory of tricritical phenomena has recently been used to study solidification at the high pressures and temperatures of the Earth, revealing how the Earth’s core works. This theoretical approach is here applied to Venus. While keeping Venus’ mantle density similar to the Earth’s, one obtains the gravitational acceleration g inside Venus, its moment of inertia factor, the size, pressure and density of its core, together with the planet’s temperature profile. Mainly due to the temperature difference between the core–mantle boundary and surface being 21% smaller than on the Earth, and the 11.5% smaller gravitational acceleration, Venus’ Rayleigh number Ra parameterizing mantle convection is only 54% of the Earth’s, offering a possible explanation for the present lack of plate tectonics on Venus. The theory as discussed predicts that Venus is molten at the centre, with temperature about 5200 K, and has 8 mol.% impurities there, slightly more impurities than in the Earth’s inner core boundary fluid. These impurities are likely to be a combination of MgO and MgSiO3.  相似文献   

15.
The sunlit portion of planetary ionospheres is sustained by photoionization. This was first confirmed using measurements and modelling at Earth, but recently the Mars Express, Venus Express and Cassini-Huygens missions have revealed the importance of this process at Mars, Venus and Titan, respectively. The primary neutral atmospheric constituents involved (O and CO2 in the case of Venus and Mars, O and N2 in the case of Earth and N2 in the case of Titan) are ionized at each object by EUV solar photons. This process produces photoelectrons with particular spectral characteristics. The electron spectrometers on Venus Express and Mars Express (part of ASPERA-3 and 4, respectively) were designed with excellent energy resolution (ΔE/E=8%) specifically in order to examine the photoelectron spectrum. In addition, the Cassini CAPS electron spectrometer at Saturn also has adequate resolution (ΔE/E=16.7%) to study this population at Titan. At Earth, photoelectrons are well established by in situ measurements, and are even seen in the magnetosphere at up to 7RE. At Mars, photoelectrons are seen in situ in the ionosphere, but also in the tail at distances out to the Mars Express apoapsis (∼3RM). At both Venus and Titan, photoelectrons are seen in situ in the ionosphere and in the tail (at up to 1.45RV and 6.8RT, respectively). Here, we compare photoelectron measurements at Earth, Venus, Mars and Titan, and in particular show examples of their observation at remote locations from their production point in the dayside ionosphere. This process is found to be common between magnetized and unmagnetized objects. We discuss the role of photoelectrons as tracers of the magnetic connection to the dayside ionosphere, and their possible role in enhancing ion escape.  相似文献   

16.
A thermodynamical analysis of the multicomponent system SiTiAlFeMnMgCaNaKPCHO open with respect to CO2, CO, H2O was carried out. Hydration and carbonatization processes are proposed to be geochemical consequences of the hypothesis of quasi-equilibrium conditions between the troposphere and crustal surface rocks. The probable rock-forming hydrated mineral phases are represented by epidote, glaucophane, tremolite, phlogopite, and annite; the carbonatization results in existence of calcite and dolomite as rock-forming minerals of weathered alkaline lavas. The surface rocks are assumed to have high ferric/ferrous iron ratios. The wollastonite equilibrium is rejected as a buffering chemical reaction. Hydrated minerals could be stable at least up to 5-km depths and contribute about 0.1 × 1024 g of H2O whereas about (0.7–0.8) × 1024 g of H2O would be consumed in ferrous iron oxidation with concomitant hydrogen dissipation. The distribution of H2O in the outer planetary shells is possibly a function of their temperatures.  相似文献   

17.
Despite a fainter Sun, the surface of the early Earth was mostly ice-free. Proposed solutions to this so-called “faint young Sun problem” have usually involved higher amounts of greenhouse gases than present in the modern-day atmosphere. However, geological evidence seemed to indicate that the atmospheric CO2 concentrations during the Archaean and Proterozoic were far too low to keep the surface from freezing. With a radiative-convective model including new, updated thermal absorption coefficients, we found that the amount of CO2 necessary to obtain 273 K at the surface is reduced up to an order of magnitude compared to previous studies. For the late Archaean and early Proterozoic period of the Earth, we calculate that CO2 partial pressures of only about 2.9 mb are required to keep its surface from freezing which is compatible with the amount inferred from sediment studies. This conclusion was not significantly changed when we varied model parameters such as relative humidity or surface albedo, obtaining CO2 partial pressures for the late Archaean between 1.5 and 5.5 mb. Thus, the contradiction between sediment data and model results disappears for the late Archaean and early proterozoic.  相似文献   

18.
We have introduced a method of partitioning the radiance emerging from a planetary atmosphere in proportion to the average number of scatterings in each atmospheric layer in order to gain a more fundamental understanding of the so-called level of line formation. A realistic model of the Venus atmosphere was used to compute the radiance for a range of phase angles and two planetary colatitudes, namely, 20 and 90°. We computed the core and continuum radiances for the P(16) line of 8689-Å CO2 band and introduced two ways of computing an effective temperature. Both definitions yielded similar results. We found that these effective temperatures varied little with phase angles up to 120°, but fell rather rapidly beyond this point. Also colder effective temperatures were found as we went from equator to pole. The results obtained are all consistent with the spectroscopic temperature determination from CO2 band studies. We have also defined an effective optical depth, τeff, which we feel gives a better understanding of the level of line formation than other definitions used to date.  相似文献   

19.
The available solar flux at a given altitude in the atmospheres of Mars and Venus is attenuated mainly by CO2 (molecular absorption and Rayleigh scattering) with an extra contribution due to SO2 on Venus. The dissociation cross section of CO2 depends on temperature. At temperatures appropriate for these atmospheres (～250°K), the cross sections are about 15% lower than those at room conditions (Y.L. Yung and W.B. De More, 1982, Icarus, 51, 199). It is shown that this temperature effect cannot be neglected in the evaluation of photolysis rates. Calculations of the photodissociation coefficients of CO2, SO2, HCl, and H2O are presented. For example, at the surface of Mars, the coefficient of H2O is nearly multiplied by a factor of 10!  相似文献   

20.
Clouds and hazes composed of sulfuric acid are observed to exist or postulated to have once existed on each of the terrestrial planets with atmospheres in our solar system. Venus today maintains a global cover of clouds composed of a sulfuric acid/water solution that extends in altitude from roughly 50 km to roughly 80 km. Terrestrial polar stratospheric clouds (PSCs) form on stratospheric sulfuric acid aerosols, and both PSCs and stratospheric aerosols play a critical role in the formation of the ozone hole. Stratospheric aerosols can modify the climate when they are enhanced following volcanic eruptions, and are a current focus for geoengineering studies. Rain is made more acidic by sulfuric acid originating from sulfur dioxide generated by industry on Earth. Analysis of the sulfur content of Martian rocks has led to the hypothesis that an early Martian atmosphere, rich in SO2 and H2O, could support a sulfur-infused hydrological cycle. Here we consider the plausibility of frozen sulfuric acid in the upper clouds of Venus, which could lead to lightning generation, with implications for observations by the European Space Agency's Venus Express and the Japan Aerospace Exploration Agency's Venus Climate Orbiter (also known as Akatsuki). We also present simulations of a sulfur-rich early Martian atmosphere. We find that about 40 cm/yr of precipitation having a pH of about 2.0 could fall in an early Martian atmosphere, assuming a surface temperature of 273 K, and SO2 generation rates consistent with the formation of Tharsis. This modeled acid rain is a powerful sink for SO2, quickly removing it and preventing it from having a significant greenhouse effect.  相似文献   

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