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1.
Temperate shelf carbonates form in cool marine waters and have skeletal and mineralogical compositions which are different from their tropical counterparts. They commonly lack non-skeletal grains and are often composed of low- and high-magnesium calcite with subordinate aragonite. Many of the aragonitic components found in tropical carbonates, such as corals, ooids, blue-green algae and lime mud, are absent.

Temperate shelf carbonates undergo diagenesis in marine waters with lower carbonate saturation than do tropical carbonates, and are exposed to cool climates with moderate to low rainfall. Marine cementation is rare because of low carbonate saturations in the surrounding waters. However, aragonite and high-magnesium calcite cements have been reported forming under specialized conditions associated with biogenic precipitation, submarine methane and sulphate-reducing bacteria, and more commonly in the intertidal environment where evaporation has increased carbonate concentrations.

In Pleistocene and Tertiary temperate shelf carbonates from southeastern Australia, evidence of marine diagenesis is rare to absent. Diagenetic stabilization of aragonite and high-magnesium calcite has taken from 80,000 y to 1 My, or longer, during subaerial exposure. This is slower than rates reported from tropical climates. A general lack of aragonite in some facies within these temperate carbonates leads to a lack of secondary porosity and only sparse low-magnesium calcite cement, even after prolonged fresh-water diagenesis. However, with lengthy exposure and under the right climatic conditions, karstic solution and calcrete precipitation can occur.

In sequences containing siliciclastic clays, pyrite and glauconite, abundant iron is present in interstitial waters leading to the precipitation of ferroan calcite cements in the phreatic and shallow burial environments, and to the substitution of iron for magnesium in stabilizing high-magnesium calcite skeletal material.

A unique void-filling, micritic internal sediment occurs in discrete layers in many of the Tertiary temperate shelf carbonate sequences in southeastern Australia. This internal sediment is localized as a pore-filling material above permeability barriers such as fine-grained sediments or volcanics, and above paleo-water tables which formed during periods of subaerial exposure. It is a feature of the vadose zone and lithifies to form a dense micritic low-magnesium calcite cement with characteristic pink/brown coloration, often associated with erosion surfaces and nodule beds.

Dolomite is uncommon in the southeastern Australian temperate shelf carbonates. It forms associated with preferential fluid pathways or mixing zones. Ferroan dolomite forms in siliciclastic clay-rich carbonates in the shallow burial environment. The ubiquitous fine, evaporite-related dolomite so common in tropical carbonates is absent.  相似文献   


2.
Extensive (ca. 50,000 km2) shallow-marine platforms (< 250 m) off northern (34°S) and southern (48°S) New Zealand, and more local areas of shelf between, are blanketed by skeletal carbonate sediments > 70% CaCO3), despite proximity to a tectonically active plate margin. In these regions the terrigenous sediment supply is presently low, and growth of epibenthos is fostered by firm substrates (rock, gravels, shells, seaweeds) and the generally energetic nature and high nutrient levels of open-shelf waters. Rapid transition into adjacent terrigenous-dominated facies is characteristic. Irrespective of water depth, the carbonates are coarse-grained and fragmental; carbonate mud is rare. Calcite dominates over aragonite. High-Mg calcite, widespread off northern New Zealand, is rare in the south. Skeletal material is dominated by bryozoans and bivalve molluscs, with significant local contributions from foraminifers, barnacles, calcareous red algae and echinoderms. The name bryomol is suggested for this distinctive temperate-region skeletal carbonate facies, which can be usefully subdivided based on dominant zoarial growth forms of the bryozoan component, known to be habitat-related. Bioerosion is an important mechanism of skeletal fragmentation and degradation. Many grains, especially aragontic bivalves, are infested by endolithic borers and have low preservation potential. Ages of skeletal material in the surficial deposits range from more than 20,000 years B.P. to modern, which is consistent with both low rates of carbonate production and sediment accumulation, and the wide range in preservation state of grains. Some data suggest that the skeletal carbonates are dispersed and mixed mainly during infrequent movement of sand ribbons, sand waves and sand sheets driven by storm-assisted tidal flows. Tracts of modern, palimpsest and relict carbonates can occur in juxtaposition.

The facies characteristics of the New Zealand shelf carbonate deposits contrast significantly with those of the classical Bahaman-type carbonate model. However, they are similar to those reported from many other mid- to high-latitude carbonate shelves, and afford good analogues for most onland occurrences of New Zealand Cenozoic limestones.  相似文献   


3.
On the southeast Australian continental margin, mixed siliciclastic and temperate carbonate sediments are presently forming along the narrow 20–35 km‐wide northern New South Wales shelf over an area of 4960 km2. Here, year‐round, highly energetic waves rework inner and mid‐shelf clastic sediments by northward longshore currents or waning storm flows. The strong East Australian Current flows south, sweeping clastic and outer shelf biogenic sands and gravels. Quaternary siliciclastic inner shelf cores consist of fine to medium, lower shoreface sand and graded storm beds of fine to coarse sand. Physically abraded, disarticulated molluscs such as Donacidae and Glycymeridae form isolated gravel lags. Highstand inner shelf clastics accumulate at 0.53 m/103 y in less than 50 m water depth. Clastic mid‐shelf cores contain well‐sorted, winnowed, medium shoreface sands, with a fine sand component. Fine sand and mud in this area is discharged mainly from New South Wales’ largest river, the Clarence. The seaward jutting of Byron Bay results in weakened East Australia Current flows through the mid‐shelf from Ballina to Yamba allowing the fine sediments to accumulate. Quaternary carbonate outer shelf cores have uniform and graded beds forming from the East Australian Current and are also influenced by less frequent storm energy. Modern clastic‐starved outer shelf hardgrounds are cemented by coralline algae and encrusting bryozoans. Clay‐sized particles are dominantly high‐Mg calcite with minor aragonite and smectite/kaolinite. Carbonate sands are rich in bryozoan fragments and sponge spicules. Distinctive (gravel‐sized) molluscs form isolated shells or shell lag deposits comprising Limopsidae and Pectinidae. The upper slope sediments are the only significant accumulation of surficial mud on the margin (18–36 wt%), filling the interstices of poorly sorted, biogenic gravels. Pectinid molluscs form a basal gravel lag. During highstand the outer shelf accumulates sediment at 0.40 m/103 y, with the upper slope accumulating a lower 0.23 m/103 y since transgression. Transgression produced a diachronous (14–10 ka) wave‐ravinement surface in all cores. Relict marine hardgrounds overlie the wave‐ravinement surface and are cemented by inorganic calcite from the shallow and warm East Australian Current. Transgressive estuarine deposits, oxygen isotope Stage 3–5 barriers or shallow bedrock underlie the wave‐ravinement surface on the inner and mid shelf. Northern New South Wales is an example of a low accommodation, wave‐ and oceanic current‐dominated margin that has produced mixed siliciclastic‐carbonate facies. Shelf ridge features that characterise many storm‐dominated margins are absent.  相似文献   

4.
Nodular celestite in the Chihsia Formation (Middle Permian) of south China   总被引：7，自引：0，他引：7  
The middle Permian Chihsia Formation of south China accumulated on a shallow shelf, and consists mainly of black to dark grey micritic limestone rich in chert nodules and organic matter. A unique type of nodular crystal cluster is distributed widely in the carbonate succession. Most crystal clusters consist of calcite. Some, however, are composed of celestite, and geochemical, microscopic and crystal morphological data suggest that celestite was the precursor of the calcite. The celestite developed displacively within the sediments during early diagenesis, before compaction and before local dolomitization of the host rock. Similar strontium isotopic values were obtained from the celestite clusters, replacement calcite, vein calcite and host rock. The values are within the range of middle Permian sea water. The strontium in the celestite was furnished chiefly by either diagenetic alteration of strontium‐rich marine aragonite to strontium‐poor calcite, or aragonite dissolution induced by aerobic oxidation of organic matter, or both. The sulphur isotopic values of the celestite are about 6–11‰ heavier than the sulphur isotopic value of sulphate in coeval sea water. Based on geological context, this difference is attributed to microbial reduction of porewater sulphate in the Chihsia sediments.  相似文献   

5.
Large areas of southern Australia and New Zealand are covered by mid‐Tertiary limestones formed in cool‐water, shelf environments. The generally destructive character of sea‐floor diagenesis in such settings precludes ubiquitous inorganic precipitation of carbonates, yet these limestones include occasional units with marine cements: (1) within rare in situ biomounds; (2) within some stacked, cross‐bedded sand bodies; (3) at the top of metre‐scale, subtidal, carbonate cycles; and (4) most commonly, associated with certain unconformities. The marine cements are dominated by isopachous rinds of fibrous to bladed spar, interstitial homogeneous micrite and interstitial micropeloidal micrite, often precipitated sequentially in that order. Internal sedimentation of microbioclastic micrite may occur at any stage. The paradox of marine‐cemented limestone units in an overall destructive cool‐water diagenetic regime may be explained by the precipitation of cement as intermediate Mg‐calcite from marine waters undersaturated with respect to aragonite. In some of the marine‐cemented limestones, aragonite biomoulds may include marine cement/sediment internally, suggesting that dissolution of aragonite can at times be wholly marine and not always involve meteoric influences. We suggest that marine cementation occurred preferentially, but not exclusively, during periods of relatively lowered sea level, probably glacio‐eustatically driven in the mid‐Tertiary. At times of reduced sea level, there was a relative increase in both the temperature and the carbonate saturation state of the shelf waters, and the locus of carbonate sedimentation shifted towards formerly deeper shelf sites, which now experienced increased swell wave and/or tidal energy levels, fostering sediment abrasion and reworking, reduced sedimentation rates and freer exchange of sediment pore‐waters. Energy levels were probably also enhanced by increased upwelling of cold, deep waters onto the Southern Ocean margins of the Australasian carbonate platforms, where water‐mass mixing, warming and loss of CO2 locally maintained critical levels of carbonate saturation for sea‐floor cement precipitation and promoted the phosphate‐glauconite mineralization associated with some of the marine‐cemented limestone units.  相似文献   

6.
杨朝青  庆安 《沉积学报》1990,8(2):59-66
云南曲靖中泥盆统曲靖组中发育了陆源碎屑与海相碳酸盐的混合沉积。混合沉积发生在以泥为背景沉积物的海湾中,系由突发性事件造成,属间断混合。主要表现为:在同一沉积环境背景上,陆源碎屑与灰泥和生物屑混合掺杂而形成混合组分沉积物。本文还对混合组分岩石的分类命名作了讨论,并命名了混合沉积的典型产物“混积岩”  相似文献   

7.
Middle and Upper Eocene biogenic sediments in the Willunga Embayment along the eastern margin of the St Vincent Basin are a series of warm‐temperate limestones, marls and spiculites. The Middle Eocene Tortachilla Limestone is a thin, coarse grained, quartzose, biofragmental, bryozoan–mollusc calcarenite of stacked metre‐scale depositional cycles with hardground caps. Lithification, aragonite dissolution and the filling of moulds by sediment and cement characterize early marine‐meteoric diagenesis. Further meteoric diagenesis at the end of Tortachilla deposition resulted in dissolution, Fe‐oxide precipitation and calcite cementation. The Upper Eocene Blanche Point Formation is composed of coccolith and spiculite marl and spiculite, all locally rich in glauconite, turritellid gastropods and sponges. Decimetre‐scale units, locally capped by firmgrounds, have fossiliferous lower parts and relatively barren upper parts. Carbonate diagenesis is minor, with much aragonite still present, but early silicification is extensive, except in the spiculite, which is still opal‐A. All depositional environments are interpreted as relatively shallow water: high energy during the Middle Eocene and low energy during the Upper Eocene, reflecting the variable importance of a basin‐entrance archipelago of carbonate highs. Marls and spiculites are interpreted to have formed under an overall estuarine circulation system in a humid climate. Basinal waters, although well mixed, were turbid and rich in land‐derived nutrients, yet subphotic near the sea floor. These low‐energy, inner‐shelf biosiliceous sediments occur in coeval environments across other parts of Australia and elsewhere in the rock record, suggesting that they are a recurring element of the cool‐water, carbonate shelf depositional system. Thus, spiculites and spiculitic carbonates in the rock record need be neither deep basinal nor polar in origin. The paradox of a shallow‐water carbonate–spiculite association may be more common in geological history than generally realized and may reflect a characteristic mid‐latitude, humid climate, temperate water, palaeoenvironmental association.  相似文献   

8.
Pelagic micritic limestones within an upper Cretaceous accretionary complex in the Tavşanlı Zone, NW Turkey, preserve textures indicating incomplete prograde transformation of micritic calcite to aragonite, representing the only known example of this type. Aragonitization starts at the central parts of the micritic limestone beds and advances towards the lower and upper parts of the layers at the expense of micrite. Micrite is very fine grained (<0.003 mm) and contains radiolaria, foraminifera and thin shell fragments. Aragonite forms large crystals, up to 3 cm across, with straight grain boundaries and c-axis mostly subparallel to the carbonate beds. Relict micritic portions are devoid of any aragonite grain. Stylolites characterized by the accumulation of clay minerals, Fe-Mn-hydroxides and quartz are concentrated in the upper and lower parts of the beds. Stylolite formation precedes aragonitization. Conditions of aragonitization are estimated as 200 ± 50 °C and 0.45–0.65 GPa, based on metamorphic mineral assemblages observed in associated basalts. Several features such as (i) constant composition of micritic calcite (98–99 mol.% CaCO3) throughout individual beds, (ii) enormous grain size difference between micritic calcite and aragonite (up to 1200 times), and (iii) absence of any aragonite grains within the relict micritic portions suggest that kinetic rather than thermodynamic factors controlled selective aragonite formation in the central portions of carbonate layers.  相似文献   

9.
Surface carbonate and land-derived deposits in the sea off southern Chile were investigated for their mineralogical and geochemical composition. The data were related to environmental features and compared with those of similar temperate and polar carbonate deposits from Tasmania, New Zealand, Arctica, and Antarctica. The mineralogy of the siliciclastic fraction is typical of cold areas and is mainly composed of chlorite, mica, quartz, feldspars and amphibole. The CaCO3 content varies from 30 to 90%; carbonate mineralogy is made up of low-Mg calcite, high-Mg calcite and minor amounts of aragonite. The Ca, Mg, Sr, Fe, and Mn contents of bulk carbonates and some selected skeletal hard parts are comparable to those of carbonates from Tasmania. The elemental composition is mainly related to carbonate mineralogy, skeletal components, and seawater conditions. The δ13C and δ18O values of carbonates are positive, and their field falls between the “seafloor diagenesis” and “upwelling water” trend lines, because the sediments are likely to be in equilibrium with waters of Antarctic origin. The mineralogical, elemental, and isotopic compositions of carbonates from southern Chile show better similarities with the “temperate” carbonates from Tasmania and New Zealand than with the “polar” carbonates from Arctica and Antarctica. Carbonate deposition is allowed by the low terrigenous input, the low SPM concentration and, probably, the upwelling of seawater from Antarctica.  相似文献   

10.
Among several lithostratigraphic subdivisions of the Gaj Formation of Miocene age, the Jhill limestone is entirely different with respect to its colour, texture and structures. This limestone unit has been evaluated to elaborate its geochemical and sedimentological characteristics. The distribution of various elements in the acid-soluble fraction has been studied in order to determine their mineralogy, sedimentary environment, facies and diagenesis. Mineralogy, recrystallization and other diagenetic changes are the main factors affecting the distribution of trace elements and their mutual relationships in the limestones. Samples of the Jhill limestone show depletion in large-sized ions (Sr, Pb & K) and also in the ions that are not compatible with calcite space group. Elements (Fe, Mn, Zn, Cu & Co) having distribution coefficient (D) above unity for natural calcites, are more enriched. Microscopic and X-ray studies revealed nearly complete conversion of aragonite into stable low-Mg calcite. An attempt has also been made to verify the reefal conditions for these limestones on the basis of geochemical studies. The plots of Sr and other facies-indicator elements show that the majority of the beds belong to forereef flank facies with some algal banks. Low Mg/Ca and Sr/Ca ratios suggest that a phreatic diagenetic environment prevailed after the deposition. High concentrations of Cr, Ni, and Co in the Jhill limestone show a positive correlation with a higher amount of insoluble residue, which reflects a relatively high rate of influx of terrigenous material.  相似文献   

11.
Previous studies in Silurian carbonates from Gotland (Sweden) have led to a model for the development of limestone-marl alternations. This model postulates that early diagenesis of precursor sediments without strong primary differences can result in a differentiation by selective dissolution of aragonite in marl beds and reprecipitation of calcite cement in limestone beds. This model is described as a set of mathematical equations that quantify the diagenetic processes (aragonite dissolution and calcite reprecipitation) that occur during the formation of limestone-marl interbeds from a hypothetical homogeneous precursor sediment. The calculations demonstrate that resulting hypothetical limestone-marl alternations show characteristic mathematical relationships between the ratios of the bed thicknesses of limestones and marls on one side, and the carbonate contents, on the other. By reversing this model, the original mineralogical composition of the precursor sediment of real-world rhythmic successions can be determined. In this study, alternations from the Silurian of Gotland, the Cambrian, Devonian, and Mississippian of North America, the Jurassic of France and Germany, and the Cretaceous of France are shown to exhibit mathematical relationships similar to those calculated for hypothetical precursor sediments without primary differences. Therefore, the mineralogical composition of their precursor sediments can be estimated. In contrast, the clear mismatch shown by the Lower Jurassic Belemnite Marls from Dorset indicates that these rhythms did not suffer an early diagenetic overprint. Our model helps to differentiate between rhythmites with strong depositional variations and those without; however, it cannot indicate whether a given alternation is the product of rhythmic diagenesis of a homogeneous precursor sediment or the result of diagenetic enhancement of subtle underlying sedimentary rhythms. For horizontally correlated patterns, such as laterally extensive beds and layers of nodules, an a priori unknown external signal has to be assumed.  相似文献   

12.
Cementation of bryozoan-echinoid-benthic foraminiferal temperate shelf carbonates of the Oligocene Te Kuiti Group, North Island, New Zealand, occurred mainly during subsurface burial. The calcite cements in the limestones are dominated by equant and syntaxial rim spar which typically becomes ferroan (given an iron supply) and, compared to the skeletal material with normal marine δ18O values from +2 to −1‰, more depleted in 18O with depth of burial, the δ18O composition of bulk cement samples ranging from −1 to −7‰. These trends reflect the establishment in pore waters during sediment burial of reducing conditions and gradually increasing temperatures (20–50°C), respectively. The δ13C values (0 to +3‰) of the cements remain the same as the host marine shells, suggesting the source of carbon in the cements was simply redistributed marine carbonate derived from shell dissolution.

Two gradational burial diagenetic environments influenced by marine-derived porewaters are arbitrarily distinguished: shallow burial phase and moderate burial phase. During the shallow burial phase, down to 500–600 m sub-bottom depth, the carbonates lost at least 25% of their original porosity by mechanical compaction and were selectively cemented by non-ferroan or usually ferroan, variably luminescent, slightly 18O-depleted sparry calcite cement (δ18O −2 to −4‰), mainly as syntaxial rims about echinoid grains. These shallow-burial cements form less than about 10% of total cement in the majority of the limestones and their source was probably mainly mild intergranular dissolution of calcitic skeletal fragments accompanying the onset of chemical compaction. During the moderate burial phase, between about 600 and 1100 m sub-bottom depth, porosity loss continued (typically to about 70% of its original value) as a result of pressure-solution of calcitic bioclasts associated with more advanced stages of chemical compaction. This involved development of a wide variety of non-sutured and microstylolitic solution seams, including both single and composite, wispy or continuous, bedding-parallel types and non-parallel reticulate forms. The released carbonate was precipitated as ferroan (or non-ferroan where iron supply was negligible), dull luminescent, strongly 18O-depleted (δ18O −4 to −7‰), mainly equant calcite spar cement, occluding available pore space in the limestones.  相似文献   


13.
地震液化脉是地震作用引起的软沉积变形的重要构造之一,前人对脉体形态学和动力学做了大量的研究工作,但对其成因的微观地球化学行为研究较少。笔者采取开化裴岭脚剖面2期地震事件沉积的3套地震液化脉层样品21块,分别对其脉体和含脉体围岩做了微量元素分析。结果显示,液化脉中Cs、Ba、Th、Zr、Hf、Cr、Rb、Nb等反映陆源性质元素明显高于含脉体围岩,而Sr、Y、Ni反映海相沉积特征元素则表现为含脉体围岩高于脉体。通过对V、Mo富集度和微量元素特征参数Sr/Ba、Th/U等的综合研究,发现液化脉体表现为氧化环境,含脉体围岩为还原环境,且脉体和围岩均具有淡水作用特点。研究认为,早寒武世大陈岭期白云质灰岩沉积过程中有蚀源区陆源碎屑物的补入;在地震突发振动力作用下,富含水的软沉积层液化泄水,因化学沉积物和碎屑沉积物性质的差异,塑性碳酸盐沉积物随水部分流失,使得单位体积内碳酸盐沉积含量低于围岩,导致脉体中更富陆源物质;地震事件沉积层属潮上带,特别是地震液化泄水后期至成岩期,含地震液化脉沉积层曾暴露地表,受后期陆源物的再补给及大气降水淋滤蚀变作用影响,表现为古气候和古盐度异常,为浙西大陈岭组浅水沉积提供了地球化学的证据。  相似文献   

14.
Aragonite and calcite needles, 30–500 μm long, were found to be prominent visual components throughout the water column in some areas of the New England (northeastern U.S.A.) continental shelf during winter months. Further investigation showed these‘needles’to be laths derived from the degradation of mollusc shells which were resuspended from bottom sediments during winter storms. Such degradation and subsequent transport/dissolution of carbonate particles may help explain why the terrigenous 'starved’shelf sediments off New England contain such small amounts of calcium carbonate.  相似文献   

15.
柴达木盆地西部地区古近系及新近系碳酸盐岩沉积相   总被引：10，自引：3，他引：7       下载免费PDF全文
柴达木盆地西部地区古近系和新近系湖相碳酸盐岩主要分布于下干柴沟组上段到油砂山组,其中,下干柴沟组上段和上干柴沟组的碳酸盐岩更发育。碳酸盐岩主要岩石类型有泥晶灰岩、藻灰岩和颗粒灰岩等三大类,此外,还普遍发育由石灰质、白云质和陆源碎屑等3种组分构成的混积岩。碳酸盐岩沉积相可划分为滨湖灰泥坪、滨湖藻坪、浅湖颗粒滩、浅湖藻丘以及半深湖泥灰岩相。滨湖灰泥坪的主要岩石类型有泥晶灰岩、含陆屑泥晶灰岩、陆屑泥晶灰岩以及陆屑泥灰岩等;滨湖藻坪为藻泥晶灰岩、藻纹层灰岩、含陆屑藻泥晶灰岩;浅湖颗粒滩有亮晶或泥微晶的鲕粒灰岩、生屑灰岩和内碎屑灰岩,其次为含陆屑颗粒灰岩;浅湖藻丘为藻叠层灰岩、藻团块灰岩、藻泥晶灰岩和含陆屑藻泥晶灰岩;而半深湖泥灰岩相的主要岩石类型为泥晶灰岩、泥灰岩以及含少量陆屑泥和粉砂的泥晶灰岩或泥灰岩。碳酸盐岩沉积相表现出很强的由西南向东北的迁移性。  相似文献   

16.
Faunally restricted argillaceous wackestones from the Middle Jurassic of eastern England contain evidence of early diagenetic skeletal aragonite dissolution and stabilization of the carbonate matrix, closely followed by precipitation of zoned calcite cements, and precipitation of pyrite. Distinctive cathodoluminescence and trace element trends through the authigenic calcites, their negative δ13C compositions and the location of pyrite in the paragenetic sequence indicate that calcite precipitation took place during sequential bacterial Mn, Fe and sulphate reduction. Calcite δ18O values are compatible with cementation from essentially marine pore fluids, although compositions vary owing to minor contamination with 18O-depleted ‘late’cements. Mg and Sr concentrations in the calcites are lower than those in recent marine calcite cements. This may be a result of kinetic factors associated with the shallow burial cementation microenvironments. Bicarbonate for sustained precipitation of the authigenic calcites was derived largely from aragonite remobilization, augmented by that produced through anaerobic organic matter oxidation in the metal and sulphate reduction environments. Aragonite dissolution is thought to have been induced by acidity generated during aerobic bacterial oxidation of organic matter. Distinction of post-oxic metal reduction and anoxic sulphate reduction diagenetic environments in modern carbonate sediments is uncommon outside pelagic settings, and early bacterially mediated diagenesis in modern platform carbonates is associated with extensive carbonate dissolution. High detrital Fe contents of the Jurassic sediments, and their restricted depositional environment, were probably the critical factors promoting early cementation. These precipitates constitute a unique example of calcite authigenesis in shallow water limestones during bacterial Mn and Fe reduction.  相似文献   

17.
祝仲蓉 Marsh.  J 《沉积学报》1992,10(1):133-145
更新世以来,剧烈的构造运动已将巴布亚新几内亚合恩半岛东北海岸的晚第四纪珊瑚礁阶地抬升上千米.阶地中造礁珊瑚的成岩变化和成岩产物的组构特征反映了该礁的成岩历史,充分体现该区快速构造上升的影响.海水潜流带和淡水渗流带为上升礁的主要成岩环境.生物钻孔、生物碎屑填隙、珊瑚文石针粗化、珊瑚骨骼的溶解和新生变形转化,以及其不同矿物成分和组构的种种胶结物的胶结作用是造礁珊瑚经历的主要成岩作用.地球化学资料表明其成岩变化发生于开放的化学体系之中.  相似文献   

18.
The Carboniferous system in the Xiaohaizi area, Bachu County, Xinjiang Uygur Autonomous Region, composed of typical mixed terrigenous clastic, carbonate and sulphate sediments, was mainly deposited in the tidal flat and lagoon environments. The mixed sediments occur as the following eleven types: 1. limestone intercalated with siltstone; 2. interbeds of shale and limestone; 3. gypsolyte interbedded with limestone; 4. gypsolyte intercalated with siltstone; 5. gypsolyte interbedded with shale; 6. gypsolyte intercalated with siltstone, limestone and dolomite; 7. siltstone interbedded with gypsolyte and limestone; 8. terrigenous detritus scattered in carbonate matrix; 9. carbonate as cement in clastic rocks; 10. mixed sediments of carbonate and terrigenous mud; 11. mixed sediments of carbonate grains with terrigenous sand. Based on the analysis of the dynamic mechanism of mixed sediments, it is believed that these types of mixed sediments in the study area were controlled by climate, sea level change and so  相似文献   

19.
Bulk carbonate samples of hemipelagic limestone–marl alternations from the Middle and Upper Triassic of Italy are analysed for their isotopic compositions. Middle Triassic samples are representative of the Livinallongo Formation of the Dolomites, while Upper Triassic hemipelagites were sampled in the Pignola 2 section, within the Calcari con Selce Formation of the Southern Apennines in Southern Italy. Triassic hemipelagites occur either as nodular limestones with chert nodules or as plane‐bedded limestone–marl alternations which are locally silicified. In the Middle Triassic Livinallongo Formation, diagenetic alteration primarily affected the stable isotopic composition of sediment surrounding carbonate nodules, whereas the latter show almost pristine compositions. Diagenesis lowered the carbon and oxygen isotope values of bulk carbonate and introduced a strong correlation between δ13C and δ18O values. In the Middle Triassic successions of the Dolomites, bulk carbonate of nodular limestone facies is most commonly unaltered, whereas carbonate of the plane‐bedded facies is uniformly affected by diagenetic alteration. In contrast to carbonate nodules, plane‐bedded facies often show compaction features. Although both types of pelagic carbonate rocks show very similar petrographic characteristics, scanning electron microscopy studies reveal that nodular limestone consists of micrite (< 5 μm in diameter), whereas samples of the plane‐bedded facies are composed of calcite crystals ca 10 μm in size showing pitted, polished surfaces. These observations suggest that nodular and plane‐bedded facies underwent different diagenetic pathways determined by the prevailing mineralogy of the precursor sediment, i.e. probably high‐Mg calcite in the nodular facies and aragonite in the case of the plane‐bedded facies. Similar to Middle Triassic nodular facies, Upper Triassic nodular limestones of the Lagonegro Basin are also characterized by uncorrelated δ13C and δ18O values and exhibit small, less than 5 μm size, crystals. The alternation of calcitic and aragonitic precursors in the Middle Triassic of the Dolomites is thought to mirror rapid changes in the type of carbonate production of adjacent platforms. Bioturbation and dissolution of metastable carbonate grains played a key role during early lithification of nodular limestone beds, whereby early stabilization recorded the carbon isotopic composition of sea water. The bulk carbonate δ13C values of Middle and Upper Triassic hemipelagites from Italy agree with those of Tethyan low‐Mg calcite shells of articulate brachiopods, confirming that Triassic hemipelagites retained the primary carbon isotopic composition of the bottom sea water. A trend of increasing δ13C from the Late Anisian to the Early Carnian, partly seen in the data set presented here, is also recognized in successions from tropical palaeolatitudes elsewhere. The carbon isotopic composition of Middle and Upper Triassic nodular hemipelagic limestones can thus be used for chemostratigraphic correlation and palaeoenvironmental studies.  相似文献   

20.
Limestone–marl alternations are usually directly interpreted to reflect cyclic palaeoenvironmental signals. However, uncertainty in such interpretations stems from the differential diagenesis that most limestone–marl alternations have undergone. Differential diagenesis results in markedly different alterations between limestones and marls and in the loss of comparability of many measurable parameters. For an unequivocal interpretation of the origin of rhythmic alternations, diagenetically robust parameters or parameters that clearly indicate the degree of diagenetic bias are required. The present study uses a multiproxy approach (independent biotic, sedimentary and geochemical parameters) in order to unravel the palaeoenvironmental signal recorded in Valanginian (Early Cretaceous) limestone–marl alternations from the Blake‐Bahama Basin (DSDP site 391). Using this approach, terrestrial and marine influences can be distinguished, changes in nutrient levels estimated and prediagenetic differences in the non‐carbonate fraction constrained. Surprisingly, no systematic variations in any of these parameters were observed between limestone and marl layers, implying that none of these was directly responsible for the formation of the rhythmic alternation. Hence, none of the current models of sedimentary formation of limestone–marl rhythmites is applicable here. Calcareous nannofossils are equally well preserved in limestone and marl layers, ruling out their dissolution in marl layers as a source of the calcite cement in the limestone beds. Sr values of 700–900 p.p.m. indicate that aragonite may have been present in the original, pelagic sediment. The assumption of fine‐grained sedimentary aragonite imported from nearby carbonate platforms as the source of the cement would explain a number of otherwise enigmatic features in these rhythmites, including the source of the calcite cement observed in the limestones, the equally good preservation of calcareous nannofossils in limestones and marls and the higher concentration of calcareous nannofossils in marl layers. The study demonstrates that examination of diagenetically inert parameters or parameters in which diagenetic effects can be filtered can yield unexpected results. Clearly, careful analysis of such parameters needs to be undertaken in order to make reliable palaeoenvironmental interpretations from rhythmite successions.  相似文献   

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