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1.
Toshiaki Tsunogae  M. Santosh 《Lithos》2006,92(3-4):524-536
We report here a multiphase mineral inclusion composed of quartz, plagioclase, K-feldspar, sapphirine, spinel, orthopyroxene, and biotite, in porphyroblastic garnet within a pelitic granulite from Rajapalaiyam in the Madurai Granulite Block, southern India. In this unique textural association, hitherto unreported in previous studies, sapphirine shows four occurrences: (1) as anhedral mineral between spinel and quartz (Spr-1), (2) subhedral to euhedral needles mantled by quartz (Spr-2), (3) subhedral to anhedral mineral in orthopyroxene, and (4) isolated inclusion with quartz (Spr-4). Spr-1, Spr-2, and Spr-4 show direct grain contact with quartz, providing evidence for ultrahigh-temperature (UHT) metamorphism at temperatures exceeding 1000 °C. Associated orthopyroxene shows high Mg/(Fe + Mg) ratio ( 0.75) and Al2O3 content (up to 9.6 wt.%), also suggesting T > 1050 °C and P > 10 kbar during peak metamorphism.

Coarse spinel (Spl-1) with irregular grain morphology and adjacent quartz grains are separated by thin films of Spr-1 and K-feldspar, suggesting that Spl-1 and quartz were in equilibrium before the stability of Spr-1 + quartz. This texture implies that the P–T conditions of the rock shifted from the stability field of spinel + quartz to sapphirine + quartz. Petrogenetic grid considerations based on available data from the FMAS system favour exhumation along a counterclockwise P–T trajectory. The irregular shape of the inclusion and chemistry of the inclusion minerals are markedly different from the matrix phases suggesting the possibility that the inclusion minerals could have equilibrated from cordierite-bearing silicate-melt pockets during the garnet growth at extreme UHT conditions.  相似文献   


2.
K. Sajeev  M. Santosh  H.S. Kim 《Lithos》2006,92(3-4):465-483
The Kodaikanal region of the Madurai Block in southern India exposes a segment of high-grade metamorphic rocks dominated by an aluminous garnet–cordierite–spinel–sillimanite–quartz migmatite suite, designated herein as the Kodaikanal Metapelite Belt (KMB). These rocks were subjected to extreme crustal metamorphism during the Late Neoproterozoic despite the lack of diagnostic ultrahigh-temperature assemblages. The rocks preserve microstructural evidence demonstrating initial-heating, dehydration melting to generate the peak metamorphic assemblage and later retrogression of the residual assemblages with remaining melt. The peak metamorphic assemblage is interpreted to be garnet + sillimanite + K-feldspar + spinel + Fe–Ti oxide + quartz + melt, which indicates pressure–temperature (P–T) conditions around 950–1000 °C and 7–8 kbar based on calculated phase diagrams. A clockwise P–T path is proposed by integrating microstructural information with pseudosections. We show that evidence for extreme crustal metamorphism at ultrahigh-temperature conditions can be extracted even in the cases where the rocks lack diagnostic ultrahigh-temperature mineral assemblages. Our approach confirms the widespread regional occurrence of UHT metamorphism in the Madurai Block during Gondwana assembly and point out the need for similar studies on adjacent continental fragments.  相似文献   

3.
C.W. Oh  S.W. Kim  I.S. Williams 《Lithos》2006,92(3-4):557-575
Spinel granulite formed in the Fe–Al-rich layers in migmatitic gneiss adjacent to a late Paleozoic collision-related mangerite intrusion in the Odesan area, eastern Gyeonggi Massif, South Korea, contains the high-temperature (HT) assemblage Crd + Spl + Crn. Spinel and cordierite compositions indicate peak metamorphic conditions of 914–1157 °C. Retrograde metamorphism reached amphibolite facies where garnet and cordierite broke down to biotite, sillimanite and quartz. These conditions, and the reactions inferred from mineral textures, are consistent with a clockwise PT path. Metamorphic zircon overgrowths in the spinel granulite and enclosing migmatitic gneiss, dated by SHRIMP U–Pb, yield Permo-Triassic ages of 245 ± 10 and 248 ± 18 Ma respectively, consistent with the metamorphism being a product of the late Paleozoic collision between the North and South China blocks within South Korea. The zircon core ages and textures suggest that the ultimate source of the spinel granulite was a Paleoproterozoic (1852 ± 14 Ma) igneous rock. The protolith of the host migmatitic gneiss was a sediment derived principally from 2.49, 2.16 and 1.86 Ga sources. The age and conditions of spinel granulite metamorphism are similar to those of spinel-bearing granulite in the Higo terrane in west-central Kyushu (250 Ma, > 950 °C at 8–9 kbar), consistent with a continuation of the Dabie-Sulu collision zone into Japan through the Odesan area.  相似文献   

4.
A new occurrence of the rare corundum + quartz assemblage and magnesian staurolite has been found in a gedrite–garnet rock from the Central Zone of the Neoarchean Limpopo Belt in Zimbabwe. Poikiloblastic garnet in the sample contains numerous inclusions of corundum + quartz ± sillimanite, magnesian staurolite + sapphirine ± orthopyroxene, and sapphirine + sillimanite assemblages, as well as monophase inclusions. Corundum, often containing subhedral to rounded quartz, occurs as subhedral to euhedral inclusions in the garnet. Quartz and corundum occur in direct grain contact with no evidence of a reaction texture. The textures and Fe–Mg ratios of staurolite inclusions and the host garnet suggest a prograde dehydration reaction of St → Grt + Crn + Qtz + H2O to give the corundum + quartz assemblage. Peak conditions of 890–930 °C at 9–10 kbar are obtained from orthopyroxene + sapphirine and garnet + staurolite assemblages. A clockwise PT path is inferred, with peak conditions being followed by retrograde conditions of 4–6 kbar and 500–570 °C. The presence of unusually magnesian staurolite (Mg / [Fe + Mg] = 0.47–0.53) and corundum + garnet assemblages provides evidence for early high-pressure metamorphism in the Central Zone, possibly close to eclogite facies. The prograde high-pressure event followed by high- to ultrahigh-temperature metamorphism and rapid uplifting of the Limpopo Belt could have occurred as a result of Neoarchean collisional orogeny involving the Zimbabwe and Kaapvaal Cratons.  相似文献   

5.
M. Santosh  K. Sajeev   《Lithos》2006,92(3-4):447-464
We report three new localities of corundum and sapphirine-bearing hyper aluminous Mg-rich and silica-poor ultrahigh-temperature granulites formed during Late Neoproterozoic-Cambrian times within the Palghat–Cauvery Shear Zone system in southern India. From petrologic characteristics, mineral chemistry and petrogenetic grid considerations, the peak metamorphic conditions of these rocks are inferred to lie around 950–1000 °C (as suggested by Al in orthopyroxene thermometer) at pressures above 10 kbar (as indicated by the equilibrium orthopyroxene–sillimanite–gedrite ± quartz assemblage). These rocks preserve several remarkable reaction textures, the most prominent among which is the triple corona of spinel–sapphirine–cordierite on corundum, with the whole textural assembly embedded within the matrix of gedrite, suggesting the reaction: Ged + Crn = Spl + Spr + Crd. The formation of sapphirine–sillimanite assemblage/symplectite associated with relict corundum and porphyroblasitc cordierite is explained by the reaction: Crd + Crn = Spr + Sil. The association of sapphirine cordierite symplectite with gedrite–sillimanite assemblage as well as with aluminosilicate boundaries indicates the gedrite consuming reaction: Ged + Sil = Spr + Crd. Extensive growth of sapphirine–cordierite observed on the rim of gedrite porphyroblasts with spinel occurring as relict inclusions within the sapphirine indicates the reaction: Ged + Spl = Spr + Crd. The pressure–temperature (PT) path defined from the observed mineral assemblages and reaction texture is characterized by anticlockwise trajectory, with a prograde segment of initial heating and subsequent deep burial, followed by retrograde near-isothermal decompression. Such an anticlockwise trajectory is being reported for the first time from southern India and has important tectonic implications since these rocks were developed at the leading edge of the crustal block that was involved in collisional orogeny and subsequent extension during the final phase of assembly of the Gondwana supercontinent. We propose that the rocks were subjected to deep subduction and rapid exhumation, and the extreme thermal conditions were attained either through input from underplated mantle-derived magmas, or convective thinning or detachment of the lithospheric thermal boundary layer during or after crustal thickening.  相似文献   

6.
http://www.sciencedirect.com/science/article/pii/S1674987112000060   总被引:2,自引:1,他引:1  
The Khondalite Belt within the Inner Mongolia Suture Zone(IMSZ) in the North China Craton is a classic example for Paleoproterozoic ultrahigh-temperature(UHT) metamorphism.Here we report new spinel-bearing metapelitic granulites from a new locality at Xumayao within the southern domain of the IMSZ.Petrological studies and thermodynamic modeling of the spinel+quartz-bearing assemblage shows that these rocks experienced extreme metamorphism at UHT conditions.Spinel occurs in two textural settings:(1) high XZn(Zn/(Mg+Fe+Zn)=0.071-0.232) spinel with perthitic K-feld-spar. sillimanite and quartz in the rock matrix;and(2) low XZn(0.045—0.070) spinel as inclusions within garnet porphyroblasts in association with quartz and sillimanite. Our phase equilibria modeling indicates two main stages during the metamorphic evolution of these rocks:(1) near-isobaric cooling from 975℃to 875℃around 8 kbar.represented by the formation of garnet porphyroblasts from spinel and quartz;and(2)cooling and decompression from 850℃.8 kbar to below 750℃.6.5 kbar,represented by the break-down of garnet.The spinel+quartz assemblage is considered to have been stable at peak metamorphisni.formed through the break-down of cordierite.indicating a near isothermal compression process.Our study confirms the regional extent of UHT metamorphisni within the IMSZ associated with the Paleoproterozoic subduction-collision process.  相似文献   

7.
Garnet-bearing peridotitic rocks closely associated with eclogite within the Tromsø Nappe of the northern Scandinavian Caledonides show good evidence for prograde metamorphism. Early stages are recognized as inclusions of hornblende and chlorite in the cores of large garnet poikiloblasts. Closer to the garnet rim, clinopyroxene and Cr-poor spinel appear as additional inclusion phases. Four suites of spinel inclusions can be distinguished based on optical properties and chemical composition. The innermost suite (suite 1) has the lowest Cr# and highest Mg#. Further rimward, the spinel inclusions gradually change in composition, with increasing Cr# and decreasing Mg#. Spinel is rare in the matrix, but locally chromitic spinel occurs as larger grains. Garnet poikiloblasts are rimmed by a kelyphite zone consisting of Hbl + Cr-poor Spl or Opx ± Cpx + Cr-poor Spl, and locally an inner zone of Na-rich Hbl + Chl. Matrix assemblage in the garnet-bearing peridotitic rocks is Hbl + Chl + Cpx + Ol ± Cr-rich spinel, defining a strong foliation wrapping around garnets and associated kelyphites. Thin layers of garnet-orthopyroxenite and garnet–hornblende–zoisite–chlorite rocks are presumably coeval with the matrix foliation of the peridotitic rocks.

In dunitic to harzburgitic compositions large undulatory grains of Ol + Opx ± Chl + Spl apparently define the maximum-P conditions. This assemblage is succeeded by a recrystallized assemblage of Ol ± Tlc ± Mgs, which in turn is overgrown by strain-free poikiloblasts of orthopyroxene, indicating a temperature increase. This is postdated by Tlc + Ath ± Mgs, and finally serpentine.

PT estimates for the inclusion suites of clinopyroxene and spinel in garnet clearly indicate garnet growth and spinel consumption in a regime of increasing P. The inner suite (suite 1) apparently was in equilibrium with garnet, clinopyroxene and olivine at 1.40 GPa, 675 °C, whereas included spinel with maximum Cr# (suite 4) indicate 2.40 GPa at 740 °C. Grt + Opx from garnet-orthopyroxenite give 1.5–1.9 GPa at 740–770 °C, and Grt + Hbl + Zo + Chl from a zoisite-rich rock give 1.75 ± 0.25 GPa at 740 ± 30 °C, interpreted to represent recrystallization during uplift. In dunitic to harzburgitic compositions, early Ol + Opx ± Chl + Spl is succeeded by Ol ± Tlc ± Mgs, which in turn is overgrown by neoblasts of strain-free orthopyroxene, indicating temperature increase. This is postdated by Tlc + Ath ± Mgs, and finally serpentine.

The ultramafic rocks in the Tromsø Nappe were locally strongly hydrated before subduction along with associated eclogites and metasedimentary rocks during the early (Ordovician) stages of the Caledonian orogeny.  相似文献   


8.
New evidence for high-pressure, eclogite facies metamorphism in the crystalline basement of the Tisza Megaunit (southern Hungary) is reported. The retrogressed mafic eclogite forms a small lens in the orthogneiss and it was found in the borehole near Jánoshalma. The carbonated eclogite contains the peak metamorphic assemblage omphacite + garnet + phengite + kyanite + clinozoizite + rutile + K-feldspar + quartz. Omphacite (Xjd0.40–0.41Xdio0.52–0.53Xhd0.05Xaug1.55–2.85) occurs in the matrix and as inclusions in garnet (Xpy0.37–0.38Xgrs0.21–0.22Xalm0.39–0.40Xsps0–0.01Xadr0–0.01) and kyanite. Thermobarometry based on net-transfer reactions between garnet, omphacite, kyanite and phengite yields PT conditions of 710 ± 10 °C and 2.6 ± 0.75 GPa. Retrogression during decompression is manifested by formation of symplectites; the most typical are diopside + plagioclase after omphacite, corundum + spinel + plagioclase after kyanite and biotite + plagioclase after phengite. Carbonatization along the veins of the retrogressed eclogite was probably coeval with formation of these symplectites. At places where carbonate is absent the rock was completely hydrated and retrogressed down to the greenschist facies with the development of actinolite. Similar eclogites together with abundant orthogneisses occur mainly in the eastern parts of the Tisza Megaunit, suggesting the existence of an ancient (possibly Variscan) subduction/accretionary complex.  相似文献   

9.
The Tertiary volcanic rocks of the central and the eastern parts of the Oman Mountains consist mainly of basanites with abundant upper mantle ultramafic xenoliths. The lavas are alkaline (42–43 wt.% SiO2; 3.5–5.5 wt.% Na2O + K2O). They include primitive (11–14 wt.% MgO) features with strong OIB-like geochemical signatures. Trace element and Sr–Nd isotope data for the basanites suggest mixing of melts derived from variable degrees of melting of both garnet- and spinel lherzolite-facies mantle source. The associated xenolith suite consists mainly of spinel and Cr-bearing diopside wehrlite, lherzolite and dunite with predominantly granuloblastic textures. No significant difference in chemistry was found between the basanites and xenoliths from the central and eastern Oman Mountains, which indicate a similar mantle source. Calculated oxygen fugacity indicates equilibration of the xenoliths at − 0.43 to − 2.2 log units above the fayalite–magnetite–quartz (FMQ) buffer. Mantle xenolith equilibration temperatures range from 910–1045 + 50 °C at weakly constrained pressures between 13 and 21 kbar. Xenolith data and geophysical studies indicate that the Moho is located at a depth of  40 km. A geotherm substantially hotter (90 mW m− 2) than the crust–mantle boundary (45 mW m− 2) is indicated and probably relates to tectonothermal events associated with the local and regional Tertiary magmatism. The petrogenesis of the Omani Tertiary basanites is explained by partial melting of an asthenospheric mantle protolith during an extension phase predating opening of the Gulf of Aden and plume-related alkaline volcanic rocks.  相似文献   

10.
We report here for the first time, the occurrence of sapphirine+quartz assemblage in textural equilibrium from quartzo-feldspathic and pelitic granulites from southern India. The sapphirine-bearing rocks occur as layered gneisses associated with pink granite within massive charnockite in Rajapalaiyam area in the southern part of Madurai Block. Sapphirine occurs in three associations: (i) fine-grained subhedral mineral associated with quartz enclosed in garnet, (ii) intergrowth with Al-rich orthopyroxene (up to 9.7 wt.% Al2O3), and (iii) in symplectitic intergrowth with orthopyroxene (Al2O3= 5.9–6.7 wt.%) and cordierite surrounding garnet. The sapphirine in association with quartz is slightly magnesian (XMg = 0.79–0.80) and low in Si content (1.55–1.56 pfu) as compared with those associated with orthopyroxene and cordierite (XMg= 0.77–0.79, Si = 1.59–1.63 pfu). The sapphirine+quartz assemblage suggests that the granulites underwent T>1050 °C peak metamorphism. Cores of porphyroblastic orthopyroxene in the sapphirine-bearing rocks shows high-Al2O3 content of up to 9.7 wt.%, suggesting T = 1040–1060°C and P = 8 kbar. FMAS reaction of sapphirine+quartz→garnet+sillimanite+cordierite indicates a cooling from sapphirine+quartz stability field after the peak ultrahigh-temperature metamorphism. Slightly lower temperature estimates from ternary feldspar and sapphirine-spinel geothermometers (T = 950–1000°C) also support a post-peak isobaric cooling. Corona textures of orthopyroxene+cordierite (±sapphirine), orthopyroxene+sapphirine, and cordierite+spinel around garnet suggest subsequent decompression. The sapphirine-quartz association and related textures reported in this study have important bearing on the ultrahigh-temperature metamorphism and exhumation history of the Madurai Block as well as on the tectonic evolution of the continental deep crust in southern India.  相似文献   

11.
Xenoliths collected from Prindle volcano, Alaska (Lat. 63.72°N; Long. 141.82°W) provide a unique opportunity to examine the lower crust of the northern Canadian Cordillera. The cone's pyroclastic deposits contain crustal and mantle-derived xenoliths. The crustal xenoliths include granulite facies metamorphic rocks and charnockites, comprising orthopyroxene (opx)–plagioclase (pl)–quartz (qtz) ± mesoperthite (msp) and clinopyroxene (cpx). Opx–cpx geothermometry yields equilibrium temperatures (T) from 770 to 1015 °C at 10 kbar. Pl–cpx–qtz geobarometry yields pressures (P) of  6.6–8.0 kbar. Integrated mesoperthite compositions suggest minimum temperatures of 1020–1140 °C at 10 kbar using solvus geothermometry. The absence of garnet in these rocks indicates a range of maximum pressure of 5–11.3 kbar, and calculated solidi constrain upper temperature limits. We conclude that the granulite facies assemblages represent relatively dry metamorphism at pressures indicative of crustal thicknesses similar to present day ( 36 km). Zircon separates from a single crustal xenolith yield mainly Early Tertiary (48–63 Ma) U–Pb ages which are considerably younger than the cooling ages of the high-pressure amphibolites exposed at the surface. The distribution of zircon ages is interpreted as indicating zircon growth coincident with at least two different thermal events as expressed at surface: (i) the eruption of the Late Cretaceous Carmacks Group volcanic rocks in western Yukon and adjacent parts of Alaska, and (ii) emplacement of strongly bimodal high level intrusions across much of western Yukon and eastern Alaska possibly in an extensional tectonic regime. The distributions of zircon growth ages and the preservation of higher-than-present-day (> 25 ± 3 °C km− 1) geothermal gradients in the granulite facies rocks demonstrate the use of crustal xenoliths for recovering records of past, lithospheric-scale thermal–tectonic events.  相似文献   

12.
Corundum+quartz-bearing assemblages occur in small lenses in granulite facies metapelites in Rayagada, north-central part of the Eastern Ghats Granulite Belt, India. Corundum porphyroblasts and quartz coexist with porphyroblastic almandine-rich garnet, hercynite spinel, ilmenite and magnetite. Corundum and quartz are separated by sillimanite or a composite corona consisting of sillimanite and garnet, whereas corundum shows sharp grain boundaries with spinel, ilmenite and magnetite. Porphyroblastic corundum contains prismatic sillimanite inclusions in which irregularly shaped quartz is enclosed. Two distinct reactions are inferred from the textural features: corundum+quartz=sillimanite and spinel+quartz=garnet+sillimanite. From the petrographical features, we infer that corundum–quartz–garnet–spinel was the peak metamorphic assemblage. Although large uncertainties exist regarding the positions of the respective reactions in P–T  space, from several published experimental results and theoretical calculations a peak metamorphic condition of 12  kbar and 1100  °C is estimated as the lower stability limit of the corundum–quartz assemblage. Decompression from the peak P–T  condition to c .  9  kbar, 950  °C is inferred.  相似文献   

13.
Zircons from an eclogite and a diamond-bearing metapelite near the Kimi village (north-eastern Rhodope Metamorphic Complex, Greece) have been investigated by Micro Raman Spectroscopy, SEM, SHRIMP and LA-ICPMS to define their inclusion mineralogy, ages and trace element contents. In addition, the host rocks metamorphic evolution was reconstructed and linked to the zircon growth domains.

The eclogite contains relicts of a high pressure stage (ca. 700 °C and > 17.5 kbar) characterised by matrix omphacite with Jd40–35. This assemblage was overprinted by a lower pressure, higher temperature metamorphic event (ca. 820 °C and 15.5–17.5 kbar), as indicated by the presence of clinopyroxene (Jd35–20) and plagioclase. Biotite and pargasitic amphibole represent a later stage, probably related to an influx of fluids. Zircons separated from the eclogite contain magmatic relicts indicating Permian crystallization of a quartz-bearing gabbroic protolith. Inclusions diagnostic of the high temperature, post-eclogitic overprint are found in metamorphic zircon domain Z2 which ages spread over a long period (160 – 95 Ma). Based on zircon textures, zoning and chemistry, we suggest that the high-temperature peak occurred at or before ca. 160 Ma and the zircons were disturbed by a later event possibly at around 115 Ma. Small metamorphic zircon overgrowths with a different composition yield an age of 79 ± 3 Ma, which is related to a distinct amphibolite-facies metamorphic event.

The metapelitic host rock consists of a mesosome with garnet, mica and kyanite, and a quartz- and plagioclase-bearing leucosome, which formed at granulite-facies conditions. Based on previously reported micro-diamond inclusions in garnet, the mesosome is assumed to have experienced UHP conditions. Nevertheless, (U)HP mineral inclusions were not found in the zircons separated from the diamond-bearing metapelite. Inclusions of melt, kyanite and high-Ti biotite in a first metamorphic zircon domain suggest that zircon formation occurred during pervasive granulite-facies metamorphism. An age of 171 ± 1 Ma measured on this zircon domain constrains the high-temperature metamorphic event. A second, inclusion-free metamorphic domain yielded an age of 160 ± 1 Ma that is related to decompression and melt crystallization.

The similar age data obtained from the samples indicate that both rock types recorded a high-T metamorphic overprint at granulite-facies conditions at ca. 170 – 160 Ma. This age implies that any high pressure or even ultra-high pressure metamorphism in the Kimi Complex occurred before that time. Our findings define new constraints for the geodynamic evolution for the Alpine orogenic cycle within the northernmost Greek part of the Rhodope Metamorphic Complex. It is proposed that the rocks of the Kimi Complex belong to a suture zone squeezed between two continental blocks and result from a Paleo-ocean basin, which should be located further north of the Jurassic Vardar Ocean.  相似文献   


14.
A combined fluid inclusion and mineral thermobarometric study in groups of synchronous inclusions in quartz within weakly foliated granites from the Chottanagpur Gneissic Complex, India, reveals super dense carbonic (CO2 with minor CH4 and H2O) inclusions and hypersaline (H2O–NaCl ± NaHCO3) inclusions, with halite- and nahcolite daughter phases. This study documents the highest density (1.115 g cm− 3) CO2 fluids ever reported in granites. Fluid isochores, constructed from CO2 (± CH4) and halite-bearing inclusions, coupled with two-feldspar thermometry constrain the minimum P–T at 8 kbar/ 750 °C for fluid entrapment in granites. By contrast, the carbonic inclusions in quartz from granite-hosted metapelite enclaves contain substantial CH4 (up to 30 mol%), and the entrapment pressure ( 4.3 kbar/600 °C) is considerably lower compared to those in the granites. By implication, the sillimanite-free granites were not derived from the metapelitic enclaves, and instead were formed by partial melting of fluid-heterogeneous lower crustal protoliths, with fluid entrapment at magmatic conditions.  相似文献   

15.
Stability of the assemblage sapphirine + quartz in Mg–Al-rich granulites implies ultrahigh temperature (UHT) condition of metamorphism but their direct contact is rarely preserved in natural rocks. The present study shows contrasting textural relations between sapphirine and quartz in different parts of the same occurrence of a Mg–Al-rich granulite, Eastern Ghats Belt, India. Textural data suggest stabilization of the assemblage sapphirine + quartz with orthopyroxene and cordierite during the metamorphic peak. Thermometric estimates yield temperature exceeding 950 °C for the stability of this assemblage. Most of such sapphirine grains (Spr1) are texturally separated from quartz and cordierite grains by double corona of sillimanite + orthopyroxene that results due to isobaric cooling during the post-peak stage. Sapphirine (Spr2) also forms a symplectic intergrowth with quartz and orthopyroxene at the fringe of coarse orthopyroxene. This textural feature can be explained by the breakdown of (Fe, Mg)-Tschermak components of orthopyroxene during the same isobaric cooling episode from UHT peak condition. The preservation of grain contact of this intergrown sapphirine and quartz can be attributed to a problem in reaction kinetics. In the other mode, sapphirine (Spr3) occurs with quartz with a thin skin of cordierite near a quartz vein. Such texture could result from isothermal decompression of the cooled crust. Alternatively and more possibly, cordierite could form from ingress of CO2–H2O rich fluid during terminal stage of cooling. Finally, sapphirine (Spr4) and quartz show direct contact close to the quartz vein. Direct contact of such sapphirine and quartz represents textural disequilibrium as this particular quartz is introduced as a vein much later than the peak metamorphism but prior to the major foliation-forming deformation. Coarse sapphirine and vein quartz, therefore, accidentally came in contact with each other and persisted metastably. Therefore, though coexistence of sapphirine and quartz is considered to be a strong evidence for ultrahigh temperature condition, care should be taken to decipher their stable coexistence. Different types of textural relations involving this mineral pair could originate in a single rock, probably in different stages of its metamorphic history.  相似文献   

16.
The Tso Morari Complex, which is thought to be originally the margin of the Indian continent, is composed of pelitic gneisses and schists including mafic rock lenses (eclogites and basic schists). Eclogites studied here have the mineral assemblage Grt + Omp + Ca-Amp + Zo + Phn + Pg + Qtz + Rt. They also have coesite pseudomorph in garnet and quartz rods in omphacite, suggesting a record of ultrahigh-pressure metamorphism. They occur only in the cores of meter-scale mafic rock lenses intercalated with the pelitic schists. Small mafic lenses and the rim parts of large lenses have been strongly deformed to form the foliation parallel to that of the pelitic schists and show the mineral assemblages of upper greenschist to amphibolite facies metamorphism. The garnet–omphacite thermometry and the univariant reaction relations for jadeite formation give 13–21 kbar at 600 °C and 16–18 kbar at 750 °C for the eclogite formation using the jadeite content of clinopyroxene (XJd = 0.48).

Phengites in pelitic schists show variable Si / Al and Na / K ratios among grains as well as within single grains, and give K–Ar ages of 50–87 Ma. The pelitic schist with paragonite and phengite yielded K–Ar ages of 83.5 Ma (K = 4.9 wt.%) for paragonite–phengite mixture and 85.3 Ma (K = 7.8 wt.%) for phengite and an isochron age of 91 ± 13 Ma from the two dataset. The eclogite gives a plateau age of 132 Ma in Ar/Ar step-heating analyses using single phengite grain and an inverse isochron age of 130 ± 39 Ma with an initial 40Ar / 36Ar ratio of 434 ± 90 in Ar/Ar spot analyses of phengites and paragonites. The Cretaceous isochron ages are interpreted to represent the timing of early stage of exhumation of the eclogitic rocks assuming revised high closure temperature (500 °C) for phengite K–Ar system. The phengites in pelitic schists have experienced retrograde reaction which modified their chemistry during intense deformation associated with the exhumation of these rocks with the release of significant radiogenic 40Ar from the crystals. The argon release took place in the schists that experienced the retrogression to upper greenschist facies metamorphisms from the eclogite facies conditions.  相似文献   


17.
http://www.sciencedirect.com/science/article/pii/S1674987112001314   总被引:4,自引:0,他引:4  
As one of the areas where typical late Archean crust is exposed in the Eastern Block of the North China Craton, the northern Laioning Complex consists principally of tonalitic-trondhjemitic-granodioritic (TTG) gneisses, massive granitoids and supracrustal rocks. The supracrustal rocks, named the Qingyuan Group, consist of interbedded amphibolite, hornblende granulite, biotite granulite and BIF. Petrological evidence indicates that the amphibolites experienced the early prograde (M1), peak (M2) and post-peak (M3) metamorphism. The early prograde assemblage (M1) is preserved as mineral inclusions, represented by actinotite + hornblende + plagioclase + epidote + quartz + sphene, within garnet porphyroblasts. The peak assemblage (M2) is indicated by garnet + clinopyroxene + hornblende + plagioclase + quartz + ilmenite, which occur as major mineral phases in the rock. The post-peak assemblage (M3) is characterized by the garnet + quartz symplectite. The P–T pseudosections in the NCFMASHTO system constructed by using THERMOCALC define the P–T conditions of M1, M2 and M3 at 490–550 °C/<4.5 kbar, 780–810 °C/7.65–8.40 kbar and 630–670 °C/8.15–9.40 kbar, respectively. As a result, an anticlockwise P–T path involving isobaric cooling is inferred for the metamorphic evolution of the amphibolites. Such a P–T path suggests that the late Archean metamorphism of the northern Liaoning Complex was related to the intrusion and underplating of mantle-derived magmas. The underplating of voluminous mantle-derived magmas leading to metamorphism with an anticlockwise P–T path involving isobaric cooling may have occurred in continental magmatic arc regions, above hot spots driven by mantle plumes, or in continental rift environments. A mantle plume model is favored because this model can reasonably interpret many other geological features of late Archean basement rocks from the northern Liaoning Complex in the Eastern Block of the North China Craton as well as their anticlockwise P–T paths involving isobaric cooling.  相似文献   

18.
The Variscan Hauzenberg pluton consists of granite and granodiorite that intruded late- to postkinematically into HT-metamorphic rocks of the Moldanubian unit at the southwestern margin of the Bohemian Massif (Passauer Wald). U–Pb dating of zircon single-grains and monazite fractions, separated from medium- to coarse-grained biotite-muscovite granite (Hauzenberg granite II), yielded concordant ages of 320 ± 3 and 329 ± 7 Ma, interpreted as emplacement age. Zircons extracted from the younger Hauzenberg granodiorite yielded a 207Pb–206Pb mean age of 318.6 ± 4.1 Ma. The Hauzenberg granite I has not been dated. The pressure during solidification of the Hauzenberg granite II was estimated at 4.6 ± 0.6 kbar using phengite barometry on magmatic muscovite, corresponding to an emplacement depth of 16-18 km. The new data are compatible with pre-existing cooling ages of biotite and muscovite which indicate the Hauzenberg pluton to have cooled below T = 250–400 °C in Upper Carboniferous times. A compilation of age data from magmatic and metamorphic rocks of the western margin of the Bohemian Massif suggests a west- to northwestward shift of magmatism and HT/LP metamorphism with time. Both processes started at > 325 Ma within the South Bohemian Pluton and magmatism ceased at ca. 310 Ma in the Bavarian Oberpfalz. The slight different timing of HT metamorphism in northern Austria and the Bavarian Forest is interpreted as being the result of partial delamination of mantle lithosphere or removal of the thermal boundary layer.  相似文献   

19.
Zircon U–Pb ages and trace elements were determined for granulites and gneiss at Huangtuling, which are hosted by ultrahigh-pressure metamorphic rocks in the Dabie Orogen, east-central China. CL images reveal core–rim structure for most zircons in the granulites. The cores show oscillatory zoning, relatively high Th/U ratios, and HREE enriched patterns, consistent with a magmatic origin. They gave a weighted mean 207Pb/206Pb age of 2766 ± 9 Ma, interpreted as dating magma emplacement of the protolith. The rims are characterized by sector or planar zoning, low Th/U ratios, negative Eu anomalies and flat HREE patterns, consistent with their formation under granulite-facies metamorphic conditions. Zircon U–Pb dating yields a weighted mean 207Pb/206Pb age of 2029 ± 13 Ma, which is interpreted to record a metamorphic event, possibly during assembly of the supercontinent Columbia. The gneiss has a protolith age of 1982 ± 14 Ma, which is younger than the zircon age of the granulite-facies metamorphism, suggesting a generally delay between HT metamorphism and the intrusion of post-collisional granites. A few inherited cores with igneous characteristics have 207Pb/206Pb ages of 2.90, 3.28 and 3.53 Ga, suggesting the presence of Mesoarchean to Paleoarchean crustal remnants in the Yangtze Craton. A few Cretaceous metamorphic ages were also obtained, suggesting the influence of post-collisional collapse in response to Cretaceous extension of the Dabie Orogen. It is inferred that the recently discovered Archean basement of the Yangtze Craton occurs as far north as the Dabie Orogen.  相似文献   

20.
Here new mineralogical data is presented on the occurrence of K-feldspar in granulite-facies metagabbronorite xenoliths found in recent alkaline lavas from Western Sardinia, Italy. The xenoliths originated from the underplating of variably evolved subduction-related basaltic liquids, which underwent cooling and recrystallisation in the deep crust (T = 850–900 °C, P = 0.8–1.0 GPa). They consist of orthopyroxene + clinopyroxene + plagioclase porphyroclasts (An = 50–66 mol%) in a granoblastic, recrystallised, quartz-free matrix composed of pyroxene + plagioclase (An = 56–72 mol%) + Fe–Ti oxides ± K-feldspar ± biotite ± fluorapatite ± Ti-biotite. Texturally, the K-feldspar occurs in a variety of different modes. These include: (1) rods, blebs, and irregular patches in a random scattering of plagioclase grains in the form of antiperthite; (2) micro-veins along plagioclase–plagioclase and plagioclase–pyroxene grain rims; (3) myrmekite-like intergrowths with Ca-rich plagioclase along plagioclase–plagioclase grain boundaries; and (4) discrete anhedral grains (sometimes microperthitic). The composition of each type of K-feldspar is characterized by relatively high albite contents (16–33 mol%). An increasing anorthite content in the plagioclase towards the contact with the K-feldspar micro-vein and myrmekite-like intergrowths into the K-feldspar along the plagioclase–K-feldspar grain boundary are also observed. Small amounts of biotite (TiO2 = 4.7–6.5 wt.%; F = 0.24–1.19 wt.%; Cl = 0.04–0.20 wt.%) in textural equilibrium with the granulite-facies assemblage is present in both K-feldspar-bearing and K-feldspar-free xenoliths. These K-feldspar textures suggest a likely metasomatic origin due to solid-state infiltration of KCl-rich fluids/melts. The presence of such fluids is supported by the fluorapatite in these xenoliths, which is enriched in Cl (Cl = 6–50% of the total F + Cl + OH). These lines of evidence suggest that formation of K-feldspar in the mafic xenoliths reflects metasomatic processes, requiring an external K-rich fluid source, which operated in the lower crust during and after in-situ high-T recrystallisation of relatively dry rocks.  相似文献   

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