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An evaluation of metal bioaccessibility in estuarine sediments using the commercially available protein, bovine serum albumin 总被引：2，自引：0，他引：2
The bioaccessibility of metals (Al, Ca, Fe, Mn, Ag, Cd, Co, Cu, Ni, Pb, Sn, Zn) in oxic estuarine sediments has been evaluated using solutions of a commercially available protein (bovine serum albumin; BSA) that mimic the chemical conditions encountered in the gut environment of many deposit-feeding organisms. Over a 20 h incubation period with 5 g L− 1 BSA, metal mobilisation was generally biphasic in that a relatively short period of rapid release was succeeded by more gradual release or approach to equilibrium, although in some cases metal readsorption was evident during the time-courses. Availability to BSA, defined as metal released after 20 h relative to metal extracted by boiling aqua regia, was greatest for Cd, Ni, Ca and Zn and lowest for Fe and Mn, and correlated well with, but was an order of magnitude lower than, metal digested by acidified hydrogen peroxide. Time-courses conducted in the absence of the protein revealed that significant quantities of Ca and Mn were water-soluble, reflecting the partial dissolution of carbonates and hydrous Mn oxides, respectively. Additional experiments indicated a net increase in metal release with increasing BSA concentration and, with the exception of Ca and Mn, a substantial increase in metal mobilisation after sediment organic matter had been digested by peroxidation. These observations suggest that, apart from Ca and Mn, metal release proceeds via complexation with component amino acids of the protein, denudation of organic host phases, and exposure of inorganic, metal-bearing minerals. Accordingly, the bioaccessibility of a metal is predicted to be dependent on its (i) affinity for proteinaceous ligands, (ii) association with components of digestible sediment organic matter, and (iii) degree of binding at relatively weak sites on sediment phases that are exposed or modified by the action of proteins and other chemical constituents of the gut environment. 相似文献
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The determination of potential difference by the joint application of measured and synthetical gravity data: a case study in Hungary 总被引：1，自引：1，他引：0
In an elementary approach every geometrical height difference between the staff points of a levelling line should have a corresponding
average g value for the determination of potential difference in the Earth’s gravity field. In practice this condition requires as
many gravity data as the number of staff points if linear variation of g is assumed between them. Because of the expensive fieldwork, the necessary data should be supplied from different sources.
This study proposes an alternative solution, which is proved at a test bed located in the Mecsek Mountains, Southwest Hungary,
where a detailed gravity survey, as dense as the staff point density (~1 point/34 m), is available along a 4.3-km-long levelling
line. In the first part of the paper the effect of point density of gravity data on the accuracy of potential difference is
investigated. The average g value is simply derived from two neighbouring g measurements along the levelling line, which are incrementally decimated in the consecutive turns of processing. The results
show that the error of the potential difference between the endpoints of the line exceeds 0.1 mm in terms of length unit if
the sampling distance is greater than 2 km. Thereafter, a suitable method for the densification of the decimated g measurements is provided. It is based on forward gravity modelling utilising a high-resolution digital terrain model, the
normal gravity and the complete Bouguer anomalies. The test shows that the error is only in the order of 10−3mm even if the sampling distance of g measurements is 4 km. As a component of the error sources of levelling, the ambiguity of the levelled height difference which
is the Euclidean distance between the inclined equipotential surfaces is also investigated. Although its effect accumulated
along the test line is almost zero, it reaches 0.15 mm in a 1-km-long intermediate section of the line. 相似文献
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The detection of solar irradiance variations (both bolometric and at various wavelengths) by satellite-based experiments during the last one-and-a-half decades stimulated modeling efforts to help identify their causes and to provide estimates of irradiance data for those time intervals when no satellite observations exist. In this paper we present estimates of the long-term irradiance changes developed with Fourier and wavelet transforms. The month-to-month irradiance variations, after removing the solar cycle related long-term changes, are studied with the cross-correlation technique. Results of the analysis reveal a significant phase shift at 3 months between the full-disk magnetic field strength and total solar and UV irradiance, with irradiance leading the magnetic field variability. In addition to this time delay between the changes in solar irradiance and the magnetic field, a 10-month phase shift has been found between the UV flux at 280 nm and total solar irradiance corrected for sunspot darkening. The existence of these phase shifts suggests the possibility of a coupling between the physical processes taking place below, in, and above the photosphere. 相似文献
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Judit Györgyey 《Celestial Mechanics and Dynamical Astronomy》1985,36(3):281-285
The non-linear stability of motions around L5 in the elliptic restricted problem of the three bodies is investigated numerically with emphasis on the effect of the orbital eccentricity of the primaries on the shape of the established stability regions. It is shown that with increasing eccentricity, the width of these regions is decreasing. 相似文献
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A method of visualizing structures in closed chaotic flows out of homogenous particle distributions is presented in the example of models of a meandering jet. To this end, the system will be leaked or opened up by defining a region of the flow, so that a particle is considered to be escaped if it leaves this region. By applying this method to an ensemble of nonescaped tracers, we are able to characterize mixing processes by visualizing the converging and stretching filamentations (stable and unstable manifolds) in the flow without using additional mathematical tools. The possibility of applying the algorithm to analyze buoy data, and a comparison with the finite time manifolds are discussed. 相似文献
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The Duna-Tisza Interfluve, Hungary has an agricultural economy but is plagued by severe problems of soil and wetland salinization despite 200 years of intensive research. The study’s objective was to determine the origin of salts and the mechanisms of salinity distribution. To this end, flow-patterns and chemistry of groundwater were evaluated in a 100 km?×?65 km area, with emphasis on the Kolon- and Kelemenszék Lakes region. The lakes are located 13 km apart and have chemically contrasting water and soil types. Two groundwater flow-domains were identified: a gravity-drive meteoric fresh water and an over-pressured deeper domain of saline water. The waters are channeled by a highly permeable gravel aquifer to the surface and may merge near Kelemenszék Lake, causing it to be saline. Kolon Lake receives meteoric groundwater only, hence its fresh chemical character. The cross-formational ascent of the deep waters, combined with the gravitational systems’ geometry and the flow-channeling effect of the near-surface rocks, explains the contrasting chemistry between lakes, and the origin and pattern of soil salinization. The scheme is proposed as a generally valid hydrogeological profile for the interfluve, and has been named the Duna-Tisza Interfluve Hydrogeological Type Section. 相似文献
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Michael Turmon Harrison P. Jones Olena V. Malanushenko Judit M. Pap 《Solar physics》2010,262(2):277-298
A maximum a posteriori (MAP) technique is developed to identify solar features in cotemporal and cospatial images of line-of-sight magnetic flux, continuum intensity, and equivalent width observed with the NASA/National Solar Observatory (NSO) Spectromagnetograph (SPM). The technique facilitates human understanding of patterns in large data sets and enables systematic studies of feature characteristics for comparison with models and observations of long-term solar activity and variability. The method uses Bayes’ rule to compute the posterior probability of any feature segmentation of a trio of observed images from per-pixel, class-conditional probabilities derived from independently-segmented training images. Simulated annealing is used to find the most likely segmentation. New algorithms for computing class-conditional probabilities from three-dimensional Gaussian mixture models and interpolated histogram densities are described and compared. A new extension to the spatial smoothing in the Bayesian prior model is introduced, which can incorporate a spatial dependence such as center-to-limb variation. How the spatial scale of training segmentations affects the results is discussed, and a new method for statistical separation of quiet Sun and quiet network is presented. 相似文献
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Review: Thermal water resources in carbonate rock aquifers 总被引：3，自引：1，他引：2
Nico Goldscheider Judit Mádl-Szőnyi Anita Erőss Eva Schill 《Hydrogeology Journal》2010,18(6):1303-1318
The current knowledge on thermal water resources in carbonate rock aquifers is presented in this review, which also discusses geochemical processes that create reservoir porosity and different types of utilisations of these resources such as thermal baths, geothermal energy and carbon dioxide (CO2) sequestration. Carbonate aquifers probably constitute the most important thermal water resources outside of volcanic areas. Several processes contribute to the creation of porosity, summarised under the term hypogenic (or hypogene) speleogenesis, including retrograde calcite solubility, mixing corrosion induced by cross-formational flow, and dissolution by geogenic acids from deep sources. Thermal and mineral waters from karst aquifers supply spas all over the world such as the famous bath in Budapest, Hungary. Geothermal installations use these resources for electricity production, district heating or other purposes, with low CO2 emissions and land consumption, e.g. Germany’s largest geothermal power plant at Unterhaching near Munich. Regional fault and fracture zones are often the most productive zones, but are sometimes difficult to locate, resulting in a relatively high exploration uncertainty. Geothermal installations in deep carbonate rocks could also be used for CO2 sequestration (carbonate dissolution would partly neutralise this gas and increase reservoir porosity). The use of geothermal installations to this end should be further investigated. 相似文献