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1.
About 30 samples representing major lithologies of Sulu ultrahigh-pressure (UHP) metamorphic rocks were collected from surface exposures and exploration wells, and compressional (Vp) and shear wave (Vs) velocities and their directional dependence (anisotropy) were determined over a range of constant confining pressures up to 600 MPa and temperatures ranging from 20 to 600 °C. Samples range in composition from acidic to ultramafic. P- and S-wave velocities measured at 600 MPa vary from 5.08 to 8.64 km/s and 2.34 to 4.93 km/s, respectively. Densities are in the range from 2.60 to 3.68 g/cm3. To make a direct tie between seismic measurements (refraction and reflection) and subsurface lithologies, the experimental velocity data (corresponding to shallow depths) were used to calculate velocity profiles for the different lithologies and profiles of reflection coefficients at possible lithologic interfaces across the projected 5000-m Chinese Continental Scientific Drilling Program (CCSD) crustal segment. Comparison of calculated in situ velocities with respective intrinsic velocities suggests that the in situ velocities at shallow depths are lowered by an increased abundance of open microcracks. The strongly reflective zone beneath the Donghai drill site can be explained by the impedance contrasts between the different lithologies. Contacts between eclogite/peridotite and felsic rocks (gt-gneiss, granitic gneiss), in particular, may give rise to strong seismic reflections. In addition, shear-induced (lattice preferred orientation (LPO)-related) seismic anisotropy can increase reflectivity. For the explanation of the high velocity bodies (>6.4 km/s) around 1000 m and below 3200-m depth, large proportions of eclogite/peridotite (about 40 and 30 vol.%, respectively) are needed.  相似文献   

2.
The ratio of P- to S-wave velocities (Vp/Vs) is regarded as one of the most diagnostic properties of natural rocks. It has been used as a discriminant of composition for the continental crust and provides valuable constraints on its formation and evolution processes. Furthermore, the spatial and temporal changes in Vp/Vs before and after earthquakes are probably the most promising avenue to understanding the source mechanics and possibly predicting earthquakes. Here we calibrate the variations in Vp/Vs in dry, anisotropic crustal rocks and provide a set of basic information for the interpretation of future seismic data from the Wenchuan earthquake Fault zone Scientific Drilling (WFSD) project and other surveys. Vp/Vs is a constant (φ0) for an isotropic rock. However, most of crustal rocks are anisotropic due to lattice-preferred orientations of anisotropic minerals (e.g., mica, amphibole, plagioclase and pyroxene) and cracks as well as thin compositional layering. The Vp/Vs ratio of an anisotropic rock measured along a selected pair of propagation-vibration directions is an apparent value (φij) that is significantly different from the value for its isotropic counterpart (φ0). The usefulness of apparent Vp/Vs ratios as a diagnostic of crustal composition depends largely on rock seismic anisotropy. A 5% of P- and S-wave velocity anisotropy is sufficient to make it impossible to determine the crustal composition using the conventional criteria (Vp/Vs<1.756 for felsic rocks, 1.756l.944 fluid-tidied porous/fractured or partially molten rocks) if the information about the wave propagation-polarization directions with respect to the tectonic framework is unknown. However, the variations in Vp/Vs measured from borehole seismic experiments can be readily interpreted according to the orientations of the ray path and the polarization of the shear waves with respect to the present-day principal stress directions (I.e., the orientation of cracks) and the frozen fabric (I.e., foliation and lineation).  相似文献   

3.
在常温常压条件对中国大陆科学钻CCSD主孔岩心的700样品进行了弹性波速度测量，并建立了主孔2000m的波速(Vp和Vs)连续剖面，为检验地球物理模型的合理解释提供了岩石物理学方面的宝贵资料。主孔中新鲜榴辉岩纵波速度(Vp)最大(7.86km／s)，正副片麻岩波速最小，又分别为5.53km／s和5．71km／s，榴辉岩的波速随着退变质作用的增强而明显减小。主孔2000m总平均Vp速度为6．2km／s，它与地球物理探测方法获得的大别-苏鲁造山带上地壳具有6.2-6．3km／s高速层结论是一致的。大部分岩石具有明显地震波各向异性。水饱和度使岩石纵波(Vp)速度和剪切波速度(Vs)分别增加19％和6％，而使Vp的各向异性降低3％～4％。不同岩性界面的反射系数(Rc)是产生地震反射的主要原因。金红石榴辉岩与片麻岩之间具有很高的反射系数(0.24-0．31)。韧性剪切带中糜棱岩化片麻岩和面理化榴辉岩使岩石各向异性和反射强度明显增加。岩石微裂隙与主孔原位波速变化有密切关系。饱水岩石速度(Vp和Vs)可以代表CCSD主孔原位状态的地震波速度。上述成果为本区地震反射体成因提供了重要的岩石物理性质约束。  相似文献   

4.
We present the first data on the petrology of the mantle lithosphereof the Southeastern (SE) Slave craton, Canada. These are basedon petrographic, mineralogical and geochemical studies of mantlexenoliths in Pipe 5034 of the Cambrian Gahcho Kué kimberlitecluster. Major types of mantle xenoliths include altered eclogite,coarse garnet or spinel peridotite, and deformed garnet peridotite.The peridotites belong to the low-temperature suite and formedat T=600–1300°C and P= 25–80 kbar in a thick(at least 220–250 km), cool lithosphere. The SE Slavemantle is cooler than the mantle of other Archaean cratons andthat below other terranes of the Slave craton. The thick lithosphereand the relatively cool thermal regime provide favourable conditionsfor formation and preservation of diamonds beneath the SE Slaveterrane. Similar to average Archaean mantle worldwide, the SESlave peridotite is depleted in magmaphile major elements andcontains olivine with forsterite content of 91–93·5.With respect to olivine composition and mode, all terranes ofthe Slave mantle show broadly similar compositions and are relativelyorthopyroxene-poor compared with those of the Kaapvaal and Siberiancratons. The SE Slave spinel peridotite is poorer in Al, Caand Fe, and richer in Mg than deeper garnet peridotite. Thegreater chemical depletion of the shallow upper mantle is typicalof all terranes of the Slave craton and may be common for thesubcontinental lithospheric peridotitic mantle in general. Peridotiticxenoliths of the SE Slave craton were impregnated by kimberliticfluids that caused late-stage recrystallization of primary clinopyroxene,spinel, olivine and spinel-facies orthopyroxene, and formationof interstitial clinopyroxene. This kimberlite-related recrystallizationdepleted primary pyroxenes and spinel in Al. The kimberliticfluid was oxidizing, Ti-, Fe- and K-rich, and Na-poor, and introducedserpentine, chlorite, phlogopite and spinel into peridotitesat P < 35 kbar. KEY WORDS: kimberlite xenolith; lithosphere; mantle terrane; chemical zoning; thermobarometry; Slave craton  相似文献   

5.
We have measured P- and S-wave velocities on two amphibolite and two gneiss samples from the Kola superdeep borehole as a function of pressure (up to 600 MPa) and temperature (up to 600 °C). The velocity measurements include compressional (Vp) and shear wave velocities (Vs1, Vs2) propagating in three orthogonal directions which were in general not parallel to inherent rock symmetry axes or planes. The measurements are accompanied by 3D-velocities calculations based on lattice preferred orientation (LPO) obtained by TOF (Time Of Flight) neutron diffraction analysis which allows the investigation of bulk volumes up to several cubic centimetres due to the high penetration depth of neutrons. The LPO-based numerical velocity calculations give important information on the different contribution of the various rock-forming minerals to bulk elastic anisotropy and on the relations of seismic anisotropy, shear wave splitting, and shear wave polarization to the structural reference frame (foliation and lineation). Comparison with measured velocities obtained for the three propagation directions that were not in accordance with the structural frame of the rocks (foliation and lineation) demonstrate that for shear waves propagating through anisotropic rocks the vibration directions are as important as the propagation directions. The study demonstrates that proper measurement of shear wave splitting by means of two orthogonal polarized sending and receiving shear wave transducers is only possible when their propagation and polarization directions are parallel and normal to foliation and lineation, respectively.  相似文献   

6.
The 3-D P- and S-wave velocity models of the upper crust beneath Southwest Iberia are determined by inverting arrival time data from local earthquakes using a seismic tomo~raphy method. We used a total of 3085 P- and 2780 S-wave high quality arrival times from 886 local earthquakes recorded by a per- manent seismic network, which is operated by the Institute of Meteorology （IM）, Lisbon, Portugal. The computed P- and S-wave velocities are used to determine the 3-D distributions of Vp/Vs ratio. The 3-D velocity and Vp/Vs ratio images display clear lateral heterogeneities in the study area. Significant veloc- ity variations up to ~6% are revealed in the upper crust beneath Southwest lberia, At 4 km depth, both P- and S-wave velocity take average to high values relative to the initial velocity model, while at 12 km, low P-wave velocities are clearly visible along the coast and in the southern parts. High S-wave velocities at 12 km depth are imaged in the central parts, and average values along the coast; although some scattered patches of low and high S-wave velocities are also revealed. The Vp/Vs rztio is generally high at depths of 4 and 12 km along the coastal parts with some regions of high Vp/Vs ratio in the north at 4 km depth, and low Vp/Vs ratio in the central southern parts at a depth of 12 km, The imaged low velocity and high Vp/Vs ratios are related to the thick saturated and unconsolidated sediments covering the region; whereas the high velocity regions are generally associated with the Mesozoic basement rocks.  相似文献   

7.
焦淑娟  郑建平 《地球科学》2008,33(3):313-319
对我国西部新疆托云地区中新生代火山岩中的深源岩石包体进行了波速计算, 并与地球物理深部探测技术相结合, 共同限定了西南天山深部壳-幔过渡带的组成和性质.托云地区麻粒岩、橄榄岩的计算波速分别是6.98~7.36 km/s、7.96~8.47 km/s.这些结果与地震反射探测地震波速的对比, 说明在西南天山岩石圈剖面中的40~48km处存在较明显的壳-幔过渡带.过渡带自上而下主要由石英麻粒岩、辉石麻粒岩和橄榄石/石榴石麻粒岩组成, 然后进入尖晶石相二辉橄榄岩组成的上地幔.这样的岩石圈壳-幔结构可以用岩浆底侵-变质作用来解释.   相似文献   

8.
This study describes the petrography of peridotite xenoliths,and the major and trace element geochemistry of garnets in bothxenoliths and coarse concentrate from the Drybones Bay kimberlite.The temperature and depth of equilibration of clinopyroxeneand garnet show that the mantle lithosphere beneath the SW marginof the Slave Province was at least 160 km thick at the timeof kimberlite emplacement (  相似文献   

9.
We determined high-resolution three-dimensional P- and S-wave velocity (Vp, Vs) structures beneath Kyushu in Southwest Japan using 177,500 P and 174,025 S wave arrival times from 8515 local earthquakes. A Poisson's ratio structure was derived from the obtained Vp and Vs values. Our results show that significant low-Vp, low-Vs and high Poisson's ratio zones are extensively distributed along the volcanic front in the uppermost mantle, which extend and dip toward the back-arc side in the mantle wedge. In the crust, low-Vp, low-Vs and high Poisson's ratio anomalies exist beneath the active volcanoes. The subducting Philippine Sea slab is clearly imaged as a high-Vp, high-Vs and low Poisson's ratio zone from the Nankai Trough to the back-arc. A thin low-velocity zone is detected above the subducting Philippine Sea slab in the mantle wedge, and earthquakes in the upper mantle are distributed along the transition zone between this thin low-velocity zone and the high-velocity Philippine Sea slab, which may imply that oceanic crust exists on the top of the slab and the forearc mantle wedge is serpentinized due to the slab dehydration. The seismic velocity of the subducting oceanic crust with basaltic or gabbroic composition is lower than that of the mantle according to the previous studies. The serpentinization process could also dramatically reduce the seismic velocity in the forearc mantle wedge.  相似文献   

10.
横波地震基本理论的研究   总被引：10，自引：0，他引：10  
The people have highly attached importance to the technipues of S-wave seismics. It is basic
premise of S一wave exploration or combining S-wave and P-wave study the basic theory for S-wave seismics. In the basic theory，especially，seismic-wave velocities(Vp,Vs) and its ratio(Vp,Vs) must be studied.
  相似文献   

11.
New trace-element data of rutile in kimberlite-borne ~1.85 Ga eclogite and pyroxenite xenoliths from the central Slave craton, as well as ~110 Ma MARID xenoliths from the Kaapvaal craton, provide constraints on the origins of lithospheric and sublithospheric mantle variability in high field strength element ratios. Rutiles in eclogites and pyroxenites have Zr/Hf ranging from 20 to 62 and Nb/Ta ranging from 10 to 40. Rutiles in MARID xenoliths have Zr/Hf from 24 to 33 and Nb/Ta from 10 to 41. Calculated whole-rock Zr/Hf is suprachondritic for eclogites with suggested gabbroic protoliths and subchondritic for boninite-like eclogites; the latter is consistent with cpx-controlled depletion in the protolith source. Within each eclogite type, positive correlations of Zr/Hf with La/Lu and negative correlations with Lu/Hf likely reflect fractionation of cpx and/or plagioclase during crystallisation of the protoliths. Zr/Hf–Nb/Ta relationships of some MARID-type rocks, which are products of lithospheric mantle metasomatism, and eclogite xenoliths plot on a silicate differentiation trend, whereas other samples have higher Nb/Ta at a given Zr/Hf. Fractionation of a few percent rutile from an HFSE-rich mafic melt can generate a trend towards strongly increased Nb/Ta at minimally changed Zr/Hf in the residual melt. Superposition of rutile fractionation on the effects of silicate differentiation, which fractionates Zr/Hf more strongly than Nb/Ta, can explain the Zr/Hf–Nb/Ta relationships of most eclogites from the central Slave craton as well as those of MARID rocks, metasomatised peridotites and group II kimberlites. By contrast, Zr/Hf–Nb/Ta relationships suggest that Group I kimberlites are mixtures between depleted peridotite and carbonatite. Thus, high Nb/Ta is a signature of lithospheric processes and may not be important in deeply subducted eclogites that bypass extended residence in the lithosphere. Conversely, considerable primary Zr/Hf variability was inherited by the eclogites, which is indicative of the compositional diversity of ancient subducted oceanic crust, which is expected to have generated substantial heterogeneity in sublithospheric basalt sources.  相似文献   

12.
The concentrations of platinum-group elements (PGE; Os, Ir, Ru, Pd and Pt) and Re, and the Os isotopic compositions were determined for 33 lithospheric mantle peridotite xenoliths from the Somerset Island kimberlite field. The Os isotopic compositions are exclusively less radiogenic than estimates of bulk-earth (187Os/188Os as low as 0.1084) and require a long-term evolution in a low Re–Os environment. Re depletion model ages (TRD) indicate that the cratonic lithosphere of Somerset Island stabilised by at least 2.8 Ga, i.e. in the Neoarchean and survived into the Mesozoic to be sampled by Cretaceous kimberlite magmatism. An Archean origin also is supported by thermobarometry (Archean lithospheric keels are characterised by >150 km thick lithosphere), modal mineralogy and mineral chemistry observations. The oldest ages recorded in the lithospheric mantle beneath Somerset Island are younger than the Mesoarchean (>3 Ga) ages recorded in the Slave craton lithospheric mantle to the southwest [Irvine, G.J., et al., 1999. Age of the lithospheric mantle beneath and around the Slave craton: a Rhenium–Osmium isotopic study of peridotite xenoliths from the Jericho and Somerset Island kimberlites. Ninth Annual V.M. Goldschmidt Conf., LPI Cont., 971: 134–135; Irvine, G.J., et al., 2001. The age of two cratons: a PGE and Os-Isotopic study of peridotite xenoliths from the Jericho kimberlite (Slave craton) and the Somerset Island kimberlite field (Churchill Province). The Slave–Kaapvaal Workshop, Merrickville, Ontario, Canada]. Younger, Paleoproterozoic, TRD model ages for Somerset Island samples are generally interpreted as the result of open system behaviour during metasomatic and/or magmatic processes, with possibly the addition of new lithospheric material during tectono-thermal events related to the Taltson–Thelon orogen. PGE patterns highly depleted in Pt and Pd generally correspond to older Archean TRD model ages indicating closed system behaviour since the time of initial melt extraction. Younger Proterozoic TRD model ages generally correspond to more complex PGE patterns, indicating open system behaviour with possible sulfide or melt addition. There is no correlation between the age of the lithosphere and depth, at Somerset Island.  相似文献   

13.
The Coyote Lake basalt, located near the intersection of the Hayward and Calaveras faults in central California, contains spinel peridotite xenoliths from the mantle beneath the San Andreas fault system. Six upper mantle xenoliths were studied in detail by a combination of petrologic techniques. Temperature estimates, obtained from three two-pyroxene geothermometers and the Al-in-orthopyroxene geothermometer, indicate that the xenoliths equilibrated at 970–1100 °C. A thermal model was used to estimate the corresponding depth of equilibration for these xenoliths, resulting in depths between 38 and 43 km. The lattice preferred orientation of olivine measured in five of the xenolith samples show strong point distributions of olivine crystallographic axes suggesting that fabrics formed under high-temperature conditions. Calculated seismic anisotropy values indicate an average shear wave anisotropy of 6%, higher than the anisotropy calculated from xenoliths from other tectonic environments. Using this value, the anisotropic layer responsible for fault-parallel shear wave splitting in central California is less than 100 km thick. The strong fabric preserved in the xenoliths suggests that a mantle shear zone exists below the Calaveras fault to a depth of at least 40 km, and combining xenolith petrofabrics with shear wave splitting studies helps distinguish between different models for deformation at depth beneath the San Andrea fault system.  相似文献   

14.
Suites of mantle-derived xenoliths in volcanic rocks provide estimates of the geothermal gradient and composition of the subcontinental lithospheric mantle (SCLM) at the time of the volcanic eruption. The development of single-grain thermometry and barometry, applied to xenocryst minerals in volcanic rocks, has greatly expanded the number of localities for which such data can be obtained and made it feasible to map the geology of the SCLM on a broader scale, both vertically and laterally. From garnet xenocrysts, it is possible to derive profiles showing mean values of olivine composition, bulk-rock composition, density and seismic velocities, as well as geotherm parameters and constraints on the thickness of the SCLM. Geochemical profiles, coupled with Re–Os dating of peridotites and their enclosed sulfide minerals, show that Archean or Proterozoic SCLM is preserved at shallow levels beneath many areas of younger tectonothermal age; this implies rapid vertical variations in Vs and Vp with depth, which may affect seismic interpretations. Data from several hundred localities worldwide define a secular evolution in the composition of the SCLM, related to the tectonothermal age of the overlying crust. Archean SCLM is typically strongly depleted in basaltic components, highly magnesian and thick (160–250 km), and has low geotherms; Phanerozoic SCLM is typically fertile (rich in basaltic components), Fe-rich, thin (50–100 km) and has a range of high geotherms; Proterozoic SCLM (much of which may be reworked Archean mantle) tends to be intermediate in all respects. The correlated variations in SCLM fertility, lithospheric thickness and geotherm reinforce the effects of each on seismic velocity, and produce more rapid lateral variations in seismic response than would result from thermal effects alone. These correlations are the key to using seismic tomography images to map the lateral extent of different types of SCLM.  相似文献   

15.
Eclogitic xenoliths consisting of tschermakitic augite and pyrope garnet, together with variable amounts of kaersutitic hornblende, are common in a volcanic breccia of Lower Oligocene age at Kakanui, New Zealand. The breccia also contains xenocrysts of these minerals, and xenoliths of peridotite. Modal analyses are given of a number of the eclogitic xenoliths, and chemical analyses of two of them and their component minerals. They are compared with similar xenoliths from Hoggar (Algeria), Salt Lake Crater (Hawaii), and Delegate (Australia), with eclogite xenoliths from kimberlites, and with garnet peridotites. These three types of igneous eclogites can be characterized by the nature of their clinopyroxene: tschermakitic in the xenoliths from basaltic rocks, jadeitic in the xenoliths from kimberlites, and chrome diopside in the garnet peridotites. The eclogitic xenoliths in basaltic rocks probably crystallized in the mantle at depths of about 60 km, but their rarity in contrast to the numerous occurrences of peridotite xenoliths poses some significant problems.  相似文献   

16.
Chondrodite, a member of the humite group of minerals, forms by hydration of olivine and is stable over a range of temperatures and pressures that includes a portion of the uppermost mantle. We have measured the single crystal elastic properties of a natural chondrodite specimen at ambient conditions using Brillouin spectroscopy. The isotropic aggregate bulk (K) and shear (μ) moduli calculated from the single-crystal elastic moduli, Cij, are: KS=118.4(16) GPa and μ=75.6(7) GPa. A comparison of the structures and elasticity of olivine and chondrodite indicate that the replacement of O with (OH,F) in M2+O6 octahedra has a small effect on the elasticity of humite-group minerals. The slightly diminished elastic moduli of humite-group minerals (as compared to olivine) are likely caused by a smaller ratio of strong structural elements (SiO4 tetrahedra) to weaker octahedra, and perhaps a more flexible geometry of edge-sharing MO4(O,OH,F)2 octahedra. In contrast to the humite-olivine group minerals, the incorporation of water into garnets and spineloids leads to a more substantial decrease in the elastic properties of these minerals. This contrasting behavior is due to formation of O4H4 tetrahedra and vacant hydroxyl-bearing octahedra in the garnets and spineloids, respectively. Therefore, the mechanism of incorporation of H/OH into mineral phases, not only degree of hydration, should be taken into account when estimating the effect of water on the elastic properties of minerals. The bulk elastic wave velocities of chondrodite and olivine are very similar. If humite-like incorporation of OH is predominant in the upper mantle, then the reaction of OH with olivine will have a minor or possibly no detectable effect on seismic velocities. Thus, it may be difficult to distinguish chondrodite-bearing rocks from “anhydrous” mantle on the basis of seismically determined velocities for the Earth. Received: 25 February 1998 / Revised, accepted: 18 August 1998  相似文献   

17.
东南沿海地区古近纪大陆岩石圈地幔特征及成因   总被引：3，自引：0，他引：3  
东南沿海地区新生代玄武岩中的橄榄岩包体来自岩石圈地幔 ,上地幔橄榄岩包体的岩石学及地球化学特征都记录了地幔演化的历史。普宁橄榄岩包体斜方辉石含量与太古宙克拉通地幔类似 ,但在矿物学、REE、痕量元素和Sr Nd同位素上又与太古宙岩石圈地幔不同。橄榄岩包体的岩相学、矿物学、REE、痕量元素特征都提供了含H2 O富Si流体交代橄榄岩的证据 ,这种流体可能主要是洋壳物质局部熔融而成。流体交代使橄榄岩富Si,同时富Sr、Pb和强不相容元素等大洋岩石圈物质。这表明普宁大陆岩石圈地幔既保留太古宙岩石圈地幔的特征 ,又具有大洋俯冲地幔的特征 ,它是古老岩石圈地幔向大洋岩石圈地幔转换的一部分 ,这种转换可能是大洋岩石圈与大陆岩石圈地幔相互作用的结果。  相似文献   

18.
Deep-seated xenoliths entrained in the Hannuoba basalts of the northern Sino-Korean Craton include mafic and felsic granulites, mantle wall-rock from spinel– and garnet–spinel peridotite facies, and basaltic crystallisation products from the spinel-pyroxenite and garnet-pyroxenite stability fields. The mineral compositions of the xenoliths have been used to estimate temperatures and, where possible, pressures of equilibration, and to construct a geothermal framework to interpret the upper mantle and lower crustal rock-type sequences for the region. The xenolith-derived paleogeotherm is constrained in the depth interval of 45–65 km and like others from areas of young basalt magmatism, is elevated and strongly convex toward the temperature axis. Two-pyroxene granulites give the lowest temperatures and garnet pyroxenites the highest, while the spinel lherzolites fall between these two groups. The present-day Moho beneath the Hannuoba area is defined at 42 km by seismic data, and coincides with the deepest occurrence of granulite. Above this boundary, there is a lower crust–upper mantle transition zone about 10-km thick, in which spinel lherzolites and mafic granulites (with variable plagioclase contents) are intermixed. It is inferred that this underplating has resulted in a lowering of the original pre-Cenozoic Moho (then coinciding with the crust–mantle boundary, CMB) from about 30 km to its present-day position and was due to intrusions of basaltic magmas that displaced peridotite mantle wall-rock and equilibrated to mafic granulites. Trace element patterns of the diopsides (analysed by laser ablation-ICPMS) from the Cr-diopside series spinel lherzolites and associated layered xenoliths (spinel lherzolites and pyroxenites) indicate a fertile uppermost mantle with moderate depletion by low degrees of partial melting and little evidence of metasomatic activity. The similarity in major and trace element compositions of the minerals in both rock types suggests that the layered ultramafic xenoliths formed by mantle deformation processes (metamorphic segregation), rather than by melt veining or metasomatism.  相似文献   

19.
The authors report a redox profile based on Mössbauer data of spinel and garnet to a depth of 210 km from mantle xenoliths of the northern (N) and southeastern (SE) Slave craton (northern Canada). The profile transects three depth facies of peridotites that form segments of different bulk composition, represented by spinel peridotite, spinel–garnet peridotite, low-temperature garnet peridotite, high-temperature garnet peridotite, and pyroxenite. The shallow, more depleted N Slave spinel peridotite records lower oxygen fugacities compared to the deeper, less depleted N Slave spinel–garnet peridotite, consistent with their different spinel Fe3+ concentrations. Garnet peridotites show a general reduction in log fO2 (FMQ)s with depth, where values for garnet peridotites are lower than those for spinel–garnet peridotites. There is a strong correlation between depletion and oxygen fugacity in the spinel peridotite facies, but little correlation in the garnet peridotite facies. The strong decrease in log fO2 (FMQ) with depth that arises from the smaller partial molar volume of Fe3+ in garnet, and the observation of distinct slopes of log fO2 (FMQ) with depth for spinel peridotite compared to spinel–garnet peridotite strongly suggest that oxygen fugacity in the cratonic peridotitic mantle is intrinsically controlled by iron equilibria involving garnet and spinel.
C. McCammonEmail: Phone: +49-921-553709Fax: +49-921-553769
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20.
Nature and origin of eclogite xenoliths from kimberlites   总被引：16，自引：0，他引：16  
D.E. Jacob   《Lithos》2004,77(1-4):295-316
Eclogites from the Earth's mantle found in kimberlites provide important information on craton formation and ancient geodynamic processes because such eclogites are mostly Archean in age. They have equilibrated over a range of temperatures and pressures throughout the subcratonic mantle and some are diamond-bearing. Most mantle eclogites are bimineralic (omphacite and garnet) rarely with accessory rutiles. Contrary to their overall mineralogical simplicity, their broadly basaltic-picritic bulk compositions cover a large range and overlap with (but are not identical to) much younger lower grade eclogites from orogenic massifs. The majority of mantle eclogites have trace element geochemical features that require an origin from plagioclase-bearing protoliths and oxygen isotopic characteristics consistent with seawater alteration of oceanic crust. Therefore, most suites of eclogite xenoliths from kimberlites can be satisfactorily explained as samples of subducted oceanic crust. In contrast, eclogite xenoliths from Kuruman, South Africa and Koidu, Sierra Leone stem from protoliths that were picritic cumulates from intermediate pressures (1–2 Ga) and were subsequently transposed to higher pressures within the subcratonic mantle, consistent with craton growth via island arc collisions. None of the eclogite suites can be satisfactorily explained by an origin as high pressure cumulates from primary melts from garnet peridotite.  相似文献   

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