首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 31 毫秒
1.
Black shales of the Paleocene Patala Formation are proven source rocks for conventional hydrocarbons in southern Potwar Basin of Pakistan and are assumed to be effective source rocks towards north in the Margalla Hill Range of Pakistan. In this regard, the current study focuses on source rock geochemistry of the Paleocene Patala Formation to assess its source rock potential, organic matter types and thermal maturity levels in the Mar-galla Hill Range of North Pakistan. Source rock generative potential, kerogen types and thermal maturation of the analysed rock samples were unraveled by using Rock-Eval pyrolysis Tmax, TOC (total organic carbon) and vitrinite reflectance ( R0 ) analyses. TOC analysis coupled with S2 yield revealed poor to fair source rock quality encountered within the formation. The pyrolysis Tmax vs Hydrogen Index ( HI) , showed mostly Type Ⅲ kerogen dominated by thermally immature to mature organic matter. The HI and genetic potential is low and revealed poor hydrocarbon generation potential of the formation. The S1 vs TOC plots confirm the indigenous nature of the hydrocarbons hosted by Patala Formation. The vitrinite reflectance outcomes indicated immature to mature source rock beds lying in dry gas zone. The HI and OI signatures and abundance of Type Ⅲ kerogen are indica-ting dominance of terrestrial organic matter within the formation. Overall, the investigated Patala Formation ex-posed at the studied section of Margalla Hill Range, Pakistan acts as a poor source rock unit for liquid hydrocar-bon generation but holds prospects for dry gas generation in the study area.  相似文献   

2.
The Wadi Sharis orogenic gold deposit in northwestern Yemen is related to the fault and shear zones vein at medium depth in the crust in the Neoproterozoic meta-sedimentary and meta-volcanosedimentary succession of greenschist to amphibolite facies metamorphism.Three distinct fluid inclusion types have been identified in the gold-bearing quartz sulphide veins of the deposit:(1) type I:vapour-liquid two-phase(VH2O-LH2O),(2) type II:three-phase CO2(VCO2-LH2O-LCO2) and(3) type III:vapour-rich(LCO2-VCO2) inclusions.Six analysis of individual fluid inclusion indicate the fluid inclusions comprise mainly of H2O and CO2.Formation P-T conditions recorded by fluid inclusions in quartz crystals correspond to 180℃-380℃ and up to 130 MPa,as indicated by high-density CO2 bubbles(up to 0.98 g/cm3) observed in some inclusions.The estimated crystallization pressures correspond to approximately 4-10 km of overburden,assuming a lithostatic load.The salinity ranges from 0 to 22 wt%.The deposit holds at 0.2-5 g/t Au and contains low-moderate salinity.  相似文献   

3.
以四川盆地长宁构造地区古生界下志留统龙马溪组页岩为例,利用低压氮气吸附测试手段和分形法理论,分析了页岩的孔隙结构参数及分形维数,结合有机质含量和矿物组成分析,研究了页岩孔隙结构特征及其分形特征的影响因素。结果表明:龙马溪组页岩孔隙结构复杂,孔隙主要以两端开口的圆筒状孔、墨水瓶状孔等开放性孔为主,孔径主要在1~10nm之间,孔径主峰位于1.86nm附近;页岩平均孔径在1.807~4.343nm之间,与w(TOC)、石英含量呈负相关,与黏土矿物含量呈正相关,其中w(TOC)对其影响显著;页岩总孔容在0.010 76~0.025 04cm3/g之间,比表面积在5.416~25.958m2/g之间,页岩总孔容、比表面积与w(TOC)、石英含量呈正相关,与黏土矿物、碳酸盐含量呈负相关;页岩具有双重分形特征,大孔隙分形维数D1为2.091 8~2.653 7,小孔隙分形维数D2为2.724 8~2.857 5,说明大孔隙结构的复杂程度大于小孔隙;页岩孔隙的分形维数与比表面积和总孔容呈正相关,而与平均孔径呈负相关;与w(TOC)、石英含量呈正相关,与黏土矿物、碳酸盐含量呈负相关,其中w(TOC)、石英和黏土矿物含量对页岩孔隙结构复杂性影响较大。   相似文献   

4.
Multiple sets of organic-rich shales developed in the Upper Paleozoic of the northwestern Guizhong Depression in South China. However, the exploration of these shales is presently at a relatively immature stage. The Upper Paleozoic shales in the northwestern Guizhong Depression, including the Middle Devonian Luofu shale, the Nabiao shale, and the Lower Carboniferous Yanguan shale, were investigated in this study. Mineral composition analysis, organic matter analysis(including total organic carbon(TOC) content, maceral of kerogen and the vitrinite reflection(Ro)), pore characteristic analysis(including porosity and permeability, pore type identification by SEM, and pore size distribution by nitrogen sorption), methane isothermal sorption test were conducted, and the distribution and thickness of the shales were determined, Then the characteristics of the two target shales were illustrated and compared. The results show that the Upper Paleozoic shales have favorable organic matter conditions(mainly moderate to high TOC content, type Ⅰ and Ⅱ_1 kerogen and high to over maturity), good fracability potential(brittleness index(BI) 40%), multiple pore types, stable distribution and effective thickness, and good methane sorption capacity. Therefore, the Upper Paleozoic shales in the northern Guizhong Depression have good shale gas potential and exploration prospects. Moreover, the average TOC content, average BI, thickness of the organic-rich shale(TOC 2.0 wt%) and the shale gas resources of the Middle Devonian shales are better than those of the Lower Carboniferous shale. The Middle Devonian shales have better shale gas potential and exploration prospects than the Lower Carboniferous shales.  相似文献   

5.
石创 《地质科技通报》2022,41(3):166-172
沉积岩中的稀土元素具有良好的化学稳定性, 能够较好保存原始沉积记录。为了揭示阳江东凹文昌组发育时期的物源区物质来源、构造背景和沉积环境, 选取凹陷内Y-1井文昌组泥岩样品进行元素测试, 系统分析研究区文昌组泥岩稀土元素地球化学特征。结果表明, 文昌组泥岩稀土元素含量高, 轻稀土元素相对富集, Eu为明显负异常, Ce为微弱正异常特征。文昌组物质来源以花岗岩为主, 含有少量沉积岩, 沉积源区为被动大陆边缘构造背景。Ceanom和δCe参数指示文昌期水体处于还原环境, 为优质烃源岩发育提供良好的保存条件, 纵向上水体还原性演化规律为: 强→弱→强→弱, 与文昌组泥岩TOC变化趋势一致。   相似文献   

6.
This study investigates the distribution of black carbon (BC) and its correlation with total polycyclic aromatic hydrocarbons (ΣPAH) in the surface sediments of China’s marginal seas. BC content ranges from <0.10 to 2.45 mg/g dw (grams dry weight) in the sediments studied, and varied among the different coastal regions. The Bohai Bay sediments had the highest BC contents (average 2.18 mg/g dw), which comprises a significant fraction (27%–41%) of the total organic carbon (TOC) preserved in the sediments. In ...  相似文献   

7.
塑料遮阳网大棚小气候观测与分析   总被引：8，自引：0，他引：8  
通过3个晴天，对遮阳网大棚风小气候进行观测，结果表明，黑色SZW＝12型蔗阳网遮光率为53％－77％，平均为69％；对降低土壤温度十分明显，0，51，0cm降温幅度分别为：1．0－11．9℃，0.8-6.2℃，0.7-5.2℃，平均降温分别为5．6℃,3.8℃，3.3℃；而对棚内气温降低作用不明显，只有0．30m以下气层平均降低0．4℃；0.50,1.00,1.50m气层比棚外高0．2－0．9℃，并有逆温现象。此结果可为花卉度夏，超常蔬菜育秧管理提供气象依据。  相似文献   

8.
Based on introducing geological structure of Tanggu area, the authors analyzed the sedimentary environment of Paleogene Dongying Formation, and further analyzed its geothermal occurrence. The studied area spans two grade IV tectonic units which are Beitang depression and Banqiao depression. The studied area is mainly located in the Tanggu nose-like structure which is the secondary structure of Beitang depression. Its existence affects the sedimentary distribution of the part strata of Paleogene. The depositions of Dongying Ⅲ （ SQEd3 ） and Dongying Ⅱ （ SQEd2 ） are mainly delta front facies and lake sand bars which are propitious to the geothermal fluid enrichment. The favorable enrichment region of geothermal fluid is located in south Hetou- Tanggu. Most of Dongying Ⅰ （ SQEd1 ） changes into swamp plain deposition, only the northeast part of this area is the distributary riverway facies with developed sand layers. There is the favorable enrichment region of geothermal fluid. The hydraulic connection is weak among the geothermal reservoirs of Dongying Formation and its overlying Guantao and Minghuazhen formations. The underlying Shahejie Formation geothermal reservoir pro- vides a steady stream of fluid supply and ground pressure protection for Dongying Formation geothermal reservoir.  相似文献   

9.
Shrimps( Litopenaeus vannamei) were intensively cultured in a recirculating aquaculture system for 98 days to investigate effects of 0.3 mg/L Cu on its performance, Cu budget, and Cu distribution. Shrimps in Cu-treated systems had greater mean final weight(11.10 vs 10.50 g), body length(107.23 vs 106.42 mm), survival rate(67.80% vs 66.40%), and yield(6.42 vs 5.99 kg/m 3), and lower feed conversion ratio(1.20 vs 1.29) than those in control systems but the differences were not significant. Vibrio numbers remained stable(10 4 –10 6 colony forming units/mL) in the rearing tanks of both control and treated systems. Total ammonium-N, nitrite-N, nitrate-N, pH, chemical oxygen demand, 5-day carbonaceous biochemical oxygen demand, and total suspended solids were similar in controls and treatments. Dissolved Cu concentration in the treated systems decreased from 0.284 to 0.089 mg/L while in the control systems it increased from 0.006 2 to 0.018 mg/L. The main sources of Cu in the treated systems were the artificially added component(75.7% of total input), shrimp feed(21.0%), water(2.06%), and shrimp biomass(1.22%). The major outputs of Cu occurred via the mechanical filter(41.7%), water renewal(15.6%), and draining of the sediment trap(15.1%). The foam fractionator removed only 0.69% of total Cu input. Harvested shrimp biomass accounted for 11.68% of Cu input. The Cu concentration of shrimps in the Cu-treated systems(30.70 mg/kg wet weight) was significantly higher than that in control systems(22.02 mg/kg). Both were below the maximum permissible concentration(50 mg/kg) for Cu in seafood for human consumption in China. Therefore, recirculating systems can be used for commercial on-growing of Litopenaeus vannamei without loss of shrimp quality, even in water polluted by 0.30 mg/L Cu. The mechanical filter is the main route for Cu removal.  相似文献   

10.
针对4类持续性、灾害性天气,利用集合平均、离散度、概率以及盒须图等方法对T213集合预报的数据进行再加工,得到其中期概率预报,包括全国范围的持续性降水、南方春季持续低温（重度低温）、南方春季低温（重度低温）连阴雨、江淮梅雨。其结果表明：（1）对于全国范围内的持续性降水过程,各类图都能很好的反映集合预报中不同量级的降水预报在10天之内的落区变化以及持续情况,并与实况对应较好。（2）对于南方低温和低温连阴雨,集合平均、离散度和概率图都能明显的反映出实际天气过程和范围的变化。（3）对于江淮梅雨这5个指标站的盒须图,能明显看出各集合成员在15个集合成员中的相对位置,以及数据的分布情况。同时还能看出集合成员与集合平均数之间的关系。梅雨日概率图则能直观的反映出10天之内每天达到梅雨日标准的概率,更有利于判断梅雨天气．  相似文献   

11.
《山地科学学报》2020,17(6):1294-1309
Perturbations caused by windstorms usually lead to the harvesting and clearcutting of fallen trees and wood debris, especially in the areas of managed forest ecosystems. Induced shifts in soils due to management practices play a crucial role in the restoration and maintaining of key ecosystem services.This paper focuses on topsoil chemical properties in relation to vegetation type(trees, shrubs and herbs)evolving at windstorm damaged(in 2004) areas with former Norway spruce(Picea abies) forests in the Tatra Mts. region(Slovakia). We assessed the content of topsoil organic matter fractions(extractives,holocellulose(HC) and lignin(Lig)), carbon in microbial biomass(C_(mic)), soil organic matter(SOM)and the content of elements N, C, H and S. The study plots represent different types of post-windthrow disturbance history/regime: wooden debris extraction(EXT), wooden debris not extracted(NEX), wooden debris extraction followed by wildfire(FIR), affected by the windstorm in 2014 with the subsequent wooden debris extraction(REX) and unaffected(REF). Our results revealed significant differences among sites in the content of dichloromethane extractives(EXT vs. REX and FIR), acetone extractives(NEX vs. EXT, FIR and REF), ethanol extractives(FIR vs. EXT, NEX and REF), water extractives(FIR vs. REX, NEX) and C_(mic)(EXT vs.NEX, FIR and REF). The topsoil of Vaccinium myrtillus and Picea abies showed a higher ratio of C/N, N/Lig, and Lig/HC compared to Rubus idaeus,Avenella flexuosa, Calamagrostis villosa, and Larix decidua. The content of N, C, H and S varied between topsoil with shrubs(Vaccinium myrtillus, Rubus idaeus) and grasses(Avenella flexuosa,Calamagrostis villosa). A positive correlation between soil organic matter(SOM) and polar extractives(r=0.81) and a negative correlation between SOM and HC(r=-0.83) was revealed. The carbon content in microbial biomass(C_(mic)) is positively correlated with acid soluble lignin(ASL)(r=0.85). We also identified a strong correlation between Klason lignin(KL) and the Lig/HC ratio(r=0.97).  相似文献   

12.
This paper reports lithologic features,K--Ar age and geochemical data of riebeckite granophyres from Aliwula area in the southern Da Hinggan Mts.,aiming to reveal the petrogenesis of riebeckite granophyres.K-Ar age of riebeckite granophyres is 126 ± 2 Ma,implying that the riebeckite granophyres formed in the Early Cretaceous.The granophyres are rich in riebeckites and with a lot of melt-fluid inclusion in its quartz phenocrysts.The granophyres are characterized by extensive enrichment in SiO2,FeO,and(Na2O+K2O) and depletion in MgO and CaO,strong negative Eu anomalies and strong positive Ce anomalies.Additionally,the riebeckite granophyres not only have high total REE contents and display enrichment of HFSEs(for example Zr,Hf,Nb,Ta),but also are strong in depletion of LILEs(e.g.Ba,Sr) as well as high Ga /Al ratios.Primitive mantle-normalized REE pattern significantly displays REE M--W tetrad effect.REEs fractionate evidently and highly enrich in LREE,but are uneven distribution in the rocks.Taken together,we conclude that the riebeckite granophyres are similar to typical A-type granite,which could be derived from stretching environments in the Early Cretaceous.The granophyres originated from residual melt which underwent highly differentiation process,and were formed in magmatic-hydrothemal transition stage at last.  相似文献   

13.
在室内水泥池,利用沙层自净养殖模式和直接铺沙养殖模式对不同规格的方斑东风螺(Babylonia areolataLink)进行了高密度养殖的研究。结果表明,沙层自净养殖模式养殖小螺、中螺、大螺组日均增重分别为0.031、0.088、0.098 g/d,沙层NH4+-N最高含量w分别为1.3、2.1、3.1 mg/L,H2S最高含量w分别为0.03、0.07、0.14mg/L,各规格组东风螺保持正常生长和活动,成活率92.9%以上;直接铺沙养殖模式养殖小螺、中螺、大螺日均增重分别为:0.023、0.051、0.068 g/d,成活率分别为95.2%、86.7%、84.9%,沙层NH4+-N最高含量w达到13.7mg/L,H2S最高含量w达到0.47 mg/L,沙层底质恶化,东风螺活动异常、不摄食。可见,沙层自净养殖模式对方斑东风螺的生长、成活率、沙层水质控制效果显著,在一定程度上克服了直接铺沙养殖底质恶化问题。  相似文献   

14.
The Early Cretaceous deposits are composed of important source rocks in Boli Basin. The types of the source rocks include black mudstones and coal (with carbonaceous mudstone). By the organic geochemical analysis methods, the authors discussed the organic petrological characters, abundance of organic matter, degree of maturity and the type of source rocks. The main micro-component of black mudstone is exinite or vitrinite, and the content of vitrinite is high in coal. The weathering of the outcrop is very serious. The abundance of organic matter in source rock reaches the poor to better rank. The major kerogens in mudstone are type-Ⅲ, type-Ⅱ2 and some type-Ⅱ1; the organic type of coal is type-Ⅲ. The thermal evolution of the source rocks in every structural unit is very different, from low-maturity to over-maturity. The depositional environment is reductive, which is good for the preservation of organic matter. The organic matter in source rocks is mainly from aquatic organisms and terrigenous input.  相似文献   

15.
通过调查发现,慈利县分布有大面积的富硒土壤,960 km~2范围重点区中富硒土壤面积占524.2 km~2,土壤硒平均含量达0.54 mg/kg。各类成土母岩中,属二叠系的炭质页岩与灰岩硒含量最高,与其对应的是在各地质背景中二叠系表层土壤硒含量同样最高,其次为三叠系、志留系土壤,硒元素在土壤与母岩中具有显著继承性。各地层剖面均显示出硒元素呈现出表聚性规律,硒元素在表层土壤中大于深层土壤,而深层土壤硒含量则大于母岩硒含量。  相似文献   

16.
丽水凹陷作为东海陆架盆地具有较大勘探潜力的凹陷，其勘探程度较低，近年来钻探成果较小，因此亟需对烃源岩进行综合评价。通过烃源岩岩石热解实验，饱和烃气相色谱及饱和烃色质分析，对丽水凹陷烃源岩进行综合评价。结果表明，丽水凹陷烃源岩有机质类型以Ⅲ型为主，存在少量的Ⅱ1及Ⅱ2型。月桂峰组烃源岩处于成熟到过成熟阶段，灵峰组烃源岩处于成熟阶段，多数明月峰组烃源岩成熟度较低。根据烃源岩热解参数S1及有机碳含量（TOC）的关系确定月桂峰组有效烃源岩w（TOC）下限为0.7%，灵峰组有效烃源岩w（TOC）下限为1.0%，明月峰组有效烃源岩w（TOC）下限为0.9%。生标参数显示丽水凹陷烃源岩有机质具有混合来源特征，沉积于海陆过渡环境中。有效烃源岩平面分布预测显示，丽水凹陷有效烃源岩的分布较为局限，丽水凹陷西次凹的东北部为有效烃源岩的集中分布区。月桂峰组及灵峰组烃源岩具有较大的产气潜力，应加大丽水凹陷西次凹东北部的气藏勘探力度。   相似文献   

17.
西湖凹陷是中国近海最重要的煤成油气凹陷。近年来，油气勘探证实平湖组煤系烃源岩为西湖凹陷提供了丰富的油气资源。与陆上其他中生代煤成油气盆地不同，近海新生代海陆过渡相平湖组煤系烃源岩在母质来源、生烃条件和演化特征上都有其独特性。研究表明，平湖组煤和炭质泥岩具有富含树脂体、高IH指数、Ⅱ1-Ⅱ2型干酪根、广覆式分布特点；煤系烃源岩富含三环二萜异海松烷、四环二萜β-扁植烷和五环三萜奥利烷，指示了针叶类裸子植物、蕨类植物和被子植物多植被母质来源；有机质组成差异、"内热外冷"地温和差异的沉积沉降速率造成了煤和泥岩在不同构造带成烃演化具有明显不同。这种差异决定了煤成油气资源具有"油气并举、东气西油"的分布格局，烃源岩成烃演化表现为"早期有利生油，晚期持续生气"模式。   相似文献   

18.
Two hundred and thirty-five samples collected from Weinan loess section (L2 – S0) have been analyzed by TOC (total organic carbon) and pyrolysis hydrocarbons. The curve of TOC with depth has been set up and compared well with other climatic markers. The main periods of TOC variation of the last 0.14 Ma are 67.08 ka and 18.29 ka, which is near with the periods of the variation of sunshine, showing that the TOC variation may be controlled by the variation of 65°N sun-shine. The distribution of pyrolysis hydrocarbon and its parameters shows that there are two kinds of hydrocarbon associated with climatic change. One is called hydrocarbon pyrolysted directly from organism (pHC2–1) which is in the range of T max350°C – 500°C, and associated with atmospheric water. The other is called carbonate inclusion hydrocarbon (pHC2–2) which is in the range of T max 500°C – 600°C and formed by evaporation and associated with dry climate. The formula calculating humidity has been deduced Og=pHC2–1/(pHC2–1 + pHC2–2). The range of humidity of the section is 47% – 77% and the reducing order is S1–3, S1–2, S0, S1–1, S1–4, S1–1, L1–1, L1–3, and L1–5. And the trend of the humidity is still increasing today.  相似文献   

19.
Sipingshan gold deposit is gold-bearing sillcalite in type. There only exist a few kinds of sulfide in the ore and it is lower in content. The gold degree is lower. Au is closely related to the Ag,Cu,Pb,As and Hg elements. The upper sillcalite has Eu and Ce negative anomaly,and the lower sillcalite has Eu positive anomaly. however,the hot spring cemented breccia and rhyolite porphyry have Eu negative anomaly;the S isotope component has deep-seated magmatic sulfur and terrestrial sulfate characteristic;and the Pb isotope has the character of the mixture origin of crust and mantle that is mainly dominated by Pb in the orogenic belt. The ore-forming fluid temperature is 180℃-244℃,characterized by magmatic hydrothermal and meteoric water;and the ore-forming age is 87 Ma. The deposit was formed by the metallogenic fluid in the tectonic fault zone overflowing near the earth’s surface and leading to the metallogenic function and the metallogenic substance deposition.  相似文献   

20.
The pigments in Laminariajaponica was extracted with six organic solvents and analyzed in spectroscopy analysis. The extractions conditions were screened by an orthogonal test and the quantity of extracted pigments was determined spectroscopically. The results show that： （1） among the six organic solvents, acetone was the most effective one for the extraction; （2） the optimum extraction conditions were as follows： the ratio of S/M （solvent volume/ material weight） was 30 ml/g; fresh seaweed was extracted 2 times in 2 h; （3） the average total content of pigments was 1.85 mg/g （calculated with dry L. japonica）.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号