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盐湖湖水矿化度高低与其含铀量呈明显的正相关性, 因此, 盐湖矿化度可作为评价盐湖水含铀度的间接标志.为解决盐湖不同水域矿化度快速、精细识别, 以柴达木盆地尕斯库勒含铀盐湖为例, 基于高分辨率SPOT5卫星数据开展了盐湖水体矿化度遥感估测.对盐湖不同矿化度卤水进行光谱测试, 总结了不同矿化度卤水在可见-红外谱段的光谱识别特征, 基于该特征构建了SPOT5数据的多维矿化度估测指数, 运用比值+主成分分析法估测了湖水的矿化度信息, 发现了盐湖东部水域高矿化度环形异常现象, 找出了隐藏在湖水水域的矿化度变异部位, 为含铀盐湖富矿水域的快速定位提供了重要依据. 相似文献
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鉴于盐湖水体矿化度含量定量反演研究较少,且中、低空间分辨率遥感数据反演的矿化度含量精度偏低,文章以柴达木盆地西部尕斯库勒盐湖为例,基于WorldView-Ⅱ高空间分辨率遥感数据和实测矿化度数据,开展了盐湖湖表水体矿化度含量定量反演技术研究。通过开展盐湖水际线提取、盐湖水体矿化度光谱诊断特征分析、矿化度识别遥感指数构建、矿化度遥感信息分离和线性回归模拟,构建了盐湖矿化度含量定量反演模型。经评价,模型反演精度为96.61%。研究结果表明,基于WorldView-II高分数据定量反演盐湖矿化度含量的方法是有效的,该方法对于快速定量识别盐湖矿化度含量,降低盐湖矿化度调查和分析成本,预测富矿水域具有十分重要的意义。 相似文献
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宁夏宁东煤田东北部地下水矿化度较高,且具有分布不均和变化较大的特点。通过分析地下水矿化度的空间分布特征,结合区域地质构造、地下水补给径流条件,借助Piper三线图、Gibbs图、离子比例系数等手段,深入研究高矿化度地下水的形成机制。结果表明,宁东煤田东北部地下水矿化度为0.30~23.56 g/L,平均值为5.84 g/L,淡水、微咸水、咸水、盐水所占比例分别为3.16%、50.00%、33.68%、13.16%。水平方向上,基岩裂隙水矿化度由东向西逐渐降低,在鸳鸯湖矿区南部形成高矿化度异常带。此外,在研究区西部及南北部的零星地区出现矿化度较高区。矿化度整体较高与石膏、盐岩及黄铁矿溶解和地下水长期滞流有关,而矿化度由东向西逐渐降低则受鄂尔多斯台地逆冲推覆构造前缘坳陷影响。鸳鸯湖矿区南部位于鄂尔多斯台地南北冲断体系的过渡带,褶曲较完整,地下水环境相对封闭,形成高矿化度异常带。垂直方向上,从Ⅰ含水层至Ⅴ含水层深部含水层的矿化度比浅部高,主要与深部地下水环境封闭,更新较慢有关。该研究将为相似矿区地下水资源开发与利用提供理论依据。 相似文献
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中原油田原始地层水矿化度很高,注入水矿化度一般低于原始地层水矿化度.根据水驱油岩电实验可知,有的储层水淹后电阻率呈"U"字形变化,其变化规律随注入水和原始地层水的矿化度比值及储层孔隙结构的不同而发生变化,使得电阻率判断储层含油性存在多解性,增加了常规测井资料识别水淹层的难度.核磁共振和双频电阻率测井新技术具有受岩性和矿化度影响小的优势,在水淹层识别上具有独到之处,在一定程度上弥补了常规测井技术的不足.通过实际应用,探讨了核磁共振和双频电阻率测井资料在中原油田高矿化度地层水淹层中的评价方法,取得良好效果,为测井新技术推广应用于水淹层评价起到了借鉴作用. 相似文献
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额济纳旗浅层地下水环境分析 总被引：8，自引：2，他引：6
通过2003年野外采样和室内分析, 研究了额济纳旗浅层地下水的水环境状况和成因. 该区浅层地下水矿化度普遍比较高, 大多数地区的矿化度在800～3 000 mg·L-1之间变化; 整个区域矿化度变化幅度比较大(532～12 267.9 mg·L-1), 水化学类型主要为HCO3·SO4-Na、 Cl·SO4-Na·Ca、 HCO3·Cl-Na·Ca和SO4·Cl-Na型. 浅层地下水矿化度的高低与距离补给源的远近密切相关, 在河岸附近的矿化度变化幅度较小; 在远离河道地区, 随离岸距离的增减而升降, 体现了矿化度的高低主要依赖于补给水源. 地下水化学成分的形成主要有溶滤作用、蒸发和浓缩作用及混合作用. 相似文献
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高盐度潜水蒸发试验研究现状及展望 总被引：2，自引：0，他引：2
多年来,许多专家学者对干旱区潜水蒸发的机理和规律做了大量研究工作,并取得了明显进展.但这些传统意义上的蒸发研究均未考虑潜水矿化度对潜水蒸发的影响,将在淡水条件下得出的潜水蒸发有关参数直接用于极端干旱区高盐度潜水蒸发的计算必将产生偏差.虽然部分学者注意到矿化度对于潜水蒸发的影响,但开展的研究只限于一般矿化度(小于10 g... 相似文献
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正向构造对层间氧化带砂岩型铀矿成矿和定位的控制 总被引：1，自引：0，他引：1
正向构造指的是与铀矿带或铀矿床产出位置相关的背斜、隆起、上升断块等矿床地质构造。伊犁盆地南缘、吐哈盆地西南缘、酒东盆地东北缘等砂岩型铀矿成矿带的产出特征表明,层间氧化带砂岩型铀矿床、矿段和矿点总是选择性地就位于正向构造之中。其原因在于层间氧化带砂岩型铀矿的成矿机理所决定。即正向构造抬升了容矿层位,使其出露或接近地表,容易接受补给区含氧含铀水的渗入,造成主砂岩层的层间氧化,铀在主砂岩层中迁移,并在氧化还原界面还原成矿。因此,正向构造对氧化带砂岩型铀矿成矿和定位的作用应引起足够重视,它可以作为产铀盆地砂岩型铀矿带成矿远景区段识别和预测的一项重要判据。 相似文献
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Uranium is a common contaminant of concern in the aquifers of nuclear waste management facilities around the world. The Electrochemical Plant (ECP) (Krasnoyarsk Krai, Russia) and the Angarsk Electrolysis Chemical Complex (AEСC) (Irkutsk Region, Russia) have produced enriched uranium and related nuclear wastes (sludge materials) since the 1960s. The results of the detailed sampling of groundwater and waste solutions near the storage sites of radioactive waste are presented elsewhere (Gaskova et al., 2011, Boguslavskiy et al., 2012). A number of experimental studies were conducted in the laboratory (a) to investigate the uranium-containing sludge leaching by regional groundwater and (b) to understand the ability of host sediments to retain major and minor components from drainage solutions as a function of the water/rock ratio (indicating the timescale over which the behavior is observed). The geochemical modeling code “HCh” was applied to simulate these processes and to predict the long-term environmental impact of residual uranium. The experimental and thermodynamic results indicate that U leaching from the sludge materials is less dependent on the specific solubility of the sludge sediments and more dependent on the solid uranium species in this sludge. The model simulation of uranium sorption in dynamic experiments was successful only in the case of the permanent filtration of less mineralized groundwater in fine-grained clay rocks. To more accurately describe the potential future release of U from the residual waste sites, a series of batch reactor experiments needs to be conducted. 相似文献
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地浸采铀技术已成为世界采铀的主流工艺,采区退役后地下水环境修复亦为人们所关注的热点。文章简要介绍了碱法、中性和酸法三种典型地浸采铀技术的特点,系统分析了地浸采铀对地下水环境的影响,并以酸法地浸铀矿山地下水环境修复技术为例,重点介绍了物理化学修复技术和生物修复技术及其原理与应用,归纳总结了其优缺点,并对未来的研究方向进行了展望。指出下一步应加强在酸性与氧化环境中能使铀固定并长期稳定的新技术,高活性、强适应性修复菌群的选育、驯化技术,地下水异位-原位协同生物修复技术,以及放射性核素及重金属在铀矿地浸地下水环境中的吸附-解吸、氧化-还原、溶解-沉淀等行为与机理及其主控因素等方面的研究。 相似文献
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对一近地表铀矿体中某些铀系长寿命核素的放射性平衡状态和１４种微量元素迁移特征研究得出，自该铀矿床６３Ｍａ前生成至今，仅近１Ｍａ来，当上覆花岗岩遭剥蚀使矿体近地表时，矿石中天然放射性核和微量元素才因水－岩反应沿围岩破碎带，裂隙发生迁移；裂隙两侧岩石受水－岩反应影响的范围较小，裂隙面的化学组分以溶失为主，裂隙两侧粘土化花岗岩中则以核素、元素的扩散和吸附为主，最后阐述了本研究结果对高放废物处置库安全评价 相似文献
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The Mesozoic Yili Basin of NW China represents the largest known concentration of U deposits in China and contains five major deposits, namely (from west to east) the 512 (Kujie’ertai), 513, 511, 510 (Mengqiguer), and 509 deposits. Pre-mining resources within the explored sandstone-type uranium deposits in this area are reportedly as much as 20,000 t contained U. The mineralization is hosted by the Middle–Lower Jurassic Shuixigou Group, which (from base to top) is divided into the Badaowan, Sangonghe, and Xishanyao formations. The U-Pb isotopic analysis of ores from the Kujie’ertai and Mengqiguer deposits indicate that they contain high and variable amounts of initial (common) Pb, meaning that the only possible way to date these deposits is by using U-Pb isochrons. Two major stages of uranium mineralization have been identified by the U-Pb isotope dating of uranium ores in this region. The Kujie’ertai deposit apparently formed between 23.4 ± 3.3 and 20.18 ± 0.49 Ma, corresponding to a period of crustal thickening and uplift within the Tien Shan Orogen. This event (35–21 Ma) accommodated the majority of the strain generated by the northward collision of the Indian Plate with the Asian Plate. However, the dating of samples from the Mengqiguer deposit yielded much younger ages (between 0.61 ± 0.24 and 0.347 ± 0.0048 Ma). The western Tien Shan mountains expanded until the Pliocene as a result of the far-field influence of continuous penetration of the Indian Plate into the Asian Plate. This activated reverse faults and folds in the piedmont of the Tien Shan mountains and caused the continuous uplift of the southern flank of the Yili Basin. The uplift caused the erosion of anticline hinge zones, introducing significant amounts of oxidizing water into the Shuixigou Group, generating a second stage of uranium mineralization. Hydrological sampling also suggests that the Mengqiguer deposit continues to grow, indicating a possible third stage of uranium mineralization (∼0 Ma). This also indicates that the U within these deposits is derived not only from U-bearing sediments but from the Tien Shan mountains as a result of groundwater cycling. The evolution of the U contents of groundwater that was initially derived from cold springs that flow into the mineralized units indicates that these cold springs have an essential role in mobilizing U from the Tien Shan mountains, with rivers flowing through areas of outcropping mineralized units acting as a source of mineralizing fluids during the formation of the Mengqiguer deposit. 相似文献
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Reactive transport modeling of uranium 238 and radium 226 in groundwater of the Königstein uranium mine, Germany 总被引：2，自引：0，他引：2
Knowledge of the transport behavior of radionuclides in groundwater is needed for both groundwater protection and remediation of abandoned uranium mines and milling sites. Dispersion, diffusion, mixing, recharge to the aquifer, and chemical interactions, as well as radioactive decay, should be taken into account to obtain reliable predictions on transport of primordial nuclides in groundwater. This paper demonstrates the need for carrying out rehabilitation strategies before closure of the Königstein in-situ leaching uranium mine near Dresden, Germany. Column experiments on drilling cores with uranium-enriched tap water provided data about the exchange behavior of uranium. Uranium breakthrough was observed after more than 20 pore volumes. This strong retardation is due to the exchange of positively charged uranium ions. The code TReAC is a 1-D, 2-D, and 3-D reactive transport code that was modified to take into account the radioactive decay of uranium and the most important daughter nuclides, and to include double-porosity flow. TReAC satisfactorily simulated the breakthrough curves of the column experiments and provided a first approximation of exchange parameters. Groundwater flow in the region of the Königstein mine was simulated using the FLOWPATH code. Reactive transport behavior was simulated with TReAC in one dimension along a 6000-m path line. Results show that uranium migration is relatively slow, but that due to decay of uranium, the concentration of radium along the flow path increases. Results are highly sensitive to the influence of double-porosity flow. 相似文献
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目前,沙特阿拉伯西北部Jabal Twalah地区铀钍资源勘查程度较低,对该地区的铀成矿机制研究相对薄弱.本文主要对该地区新发现的伟晶岩型和花岗岩热液型铀矿化带的矿化特征和成矿机制开展研究.区内与铀钍矿化相关的伟晶岩和围岩花岗岩中锆石LA-ICP-MS U-Pb年龄分别为638.6±3.2 Ma和632.5±1.5 Ma,两者时代基本一致.综合岩相学、地球化学以及扫描电镜能谱分析等研究结果,发现矿化伟晶岩强烈富集U、Th、稀土及稀有金属元素,复杂的高温蚀变矿物组合特征暗示可能经历了岩浆期后热液的改造,改造前后矿化伟晶岩中的铀和钍未发生分离,以副矿物形式存在而无独立铀矿物,具岩浆矿物组合的特征,如金红石、锆石、氟碳铈矿、磷钇矿、钍石等.花岗岩热液型单铀矿化带的地表样品中铀矿物主要为硅铅铀矿和硅钙铀矿,脉石矿物主要为赤铁矿、萤石、石英以及少量方解石,铀矿化受控于高铀含量的碱性花岗岩、强烈硅化构造破碎带以及晚期酸性基性脉岩活动等因素.强烈硅化的构造破碎带及其转折部位或者与脉岩交汇部位是今后重要的找矿方向. 相似文献
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水文地质作用是砂岩型铀矿成矿过程中不可缺少的重要作用之一。通过陕西彬县地区水文地质条件和水文地球化学环境分析,将中新生代地层地下水划分为松散岩类孔隙水、碎屑岩类孔隙裂隙水和碎屑岩类裂隙水3种类型。根据地下水的补给、径流、排泄条件,划分出水交替强烈带、水交替缓慢带和水交替滞缓带3个不同的水动力分带。不同类型地下水的含铀性、不同分带铀的运移和富集特征,以及酸、碱性地下水对围岩蚀变与铀成矿的作用表明,中侏罗统直罗组砂岩含矿含水层中铀成矿主要经历了沉积成岩时期铀的预富集作用、古地下水的后生改造叠加成矿作用和深部油田水的还原成矿作用,铀成矿作用为复合成因类型。 相似文献
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C. Frick 《Journal of Geochemical Exploration》1986,25(3)
During the routine analysis of chip samples from water boreholes it was noted that the DeBakken granite south of Kenhardt has high uranium and tin contents. Rock samples collected on surface, however, revealed low concentrations of both these elements indicating that they have been leached from the surface samples. The distribution of thorium in the borehole profiles showed that while both tin and uranium have been removed above the water table, other “immobile” elements and thorium remained unaffected.The geological data showed that the leaching took place since the start of the Tertiary. Initially, the movement of uranium was vertical and accumulated in pedogenic calcrete above the granite. This vertical leaching was controlled by fluctuations in the water table and took place from the Pliocene to Pleistocene. Later, in the Holocene, the pedogenic calcrete was removed and deposited as non-pedogenic calcrete along the rivers. These nodular calcrete deposits, which are abundant in Namaqualand, are mineralized only along those rivers which drain the DeBakken granite, indicating that this granite was the source of the uranium.When the water table reached depths of ten metres or more the vertical migration of uranium ceased and horizontal leaching caused by the movement of ground water became active. Where the water table cuts the surface, such as in the pans, uranium deposition due to evaporation of groundwater is still active.Leaching of uranium from this granite, together with the formation of the secondary deposits is mineralogically controlled, and is ascribed to the fact that uranium is not hosted in zircon. Granites such as the DeBakken granite, in which the uranium is hosted in biotite, monazite and apatite, cannot be recognized by surface sampling and hence a lithogeochemical approach, using sub-surface samples has to be adopted. Calculations showed that approximately 1400 tons of uranium metal has been leached from this granite since the start of the Tertiary and that the maximum reserve of the province as a whole is relatively small.The distribution of tin is erratic, and although it has been leached from the surface samples, it has not been transported for any significant distance. Thus the tin distribution in the profiles does not show the same degree of leaching as does uranium. This is ascribed to the fact that samples from a percussion drill would include both the rock fragments from which tin has been leached and the clay-rich alteration products in which it has been trapped. Tin is generally immobile when present as cassiterite, but when enclosed in biotite, and when the groundwater is enriched in chlorine and fluorine, it leaches readily from the biotite. 相似文献