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1.
沉积物-水界面污染物迁移扩散的研究进展 总被引：6，自引：0，他引：6
污染物在沉积物-水界面的迁移扩散对研究其环境生物地球化学循环过程和评估水生态系统质量具有重要意义.本文回顾了关于沉积物-水界面的基本研究历程,重点介绍沉积物-水界面的垂向结构以及扩散边界层（DBL）的作用,展示污染物在沉积物-水界面的多维度分布（一维垂向、二维平面和三维立体）及其在沉积物-水界面的扩散过程,详细总结影响污染物在沉积物-水界面迁移扩散的环境因素（包括温度、溶解氧或氧化还原条件、pH值、离子强度或盐度、沉积物组成、共存污染物、溶解性有机质、水动力条件、生物扰动、微生物以及其他因素）,讨论当前关于沉积物-水界面污染物扩散通量估算几种方法的优缺点,最后,对沉积物-水界面污染物扩散研究在未来发展需要关注的几个方面进行了展望. 相似文献
2.
东巢湖沉积物水界面氮、磷、氧迁移特征及意义 总被引：2，自引：0，他引：2
以东巢湖近城市湖湾沉积物为研究对象,在沉积物氮、磷营养盐分析的基础上,采用沉积物柱状芯样静态释放模拟法定量评估研究区域沉积物—水界面氨氮、溶解性活性磷酸盐营养盐释放潜力,利用微电极非损伤测定技术获得沉积物—水微界面溶解氧(DO)剖面分布及微界面DO消耗和扩散特征.结果表明:东巢湖近城市湖湾沉积物氮、磷污染物蓄积量较高,受TN、TP污染程度较重.沉积物内源氨氮、磷酸盐释放明显,平均释放速率分别达到32.44 mg/(m~2·d)和1.25mg/(m~2·d),区域内沉积物已成为水柱中氮、磷营养盐的污染源.研究区域上覆水体处于好氧状态,沉积物—水微界面平均DO穿透深度(OPD)达到5.3 mm,平均DO扩散通量为4.56 mmol/(m~2·d),表现出良好的DO扩散能力.沉积物内源氨氮和磷酸盐释放能力与表层沉积物TN/TP物质含量及沉积物—水微界面DO穿透深度有关,在沉积物氮、磷污染较重的情况下,DO穿透深度越低越有利于氮、磷污染物从沉积物向上覆水体释放. 相似文献
3.
A model framework is presented for simulating nitrogen and carbon cycling at the sediment–water interface, and predicting oxygen consumption by oxidation reactions inside the sediments. Based on conservation of mass and invoking simplifying assumptions, a coupled system of diffusive–reactive partial differential equations is formulated for two-layer conceptual model of aerobic–anaerobic sediments. Oxidation reactions are modeled as first-order rate processes and nitrate is assumed to be consumed entirely in the anoxic portion of the sediments. The sediments are delineated into a thin oxygenated surface layer whose thickness is equal to the oxygen penetration depth, and a lower, but much thicker anoxic layer. The sediments are separated from the overlying water column by a relatively thin boundary layer through which mass transfer is diffusion controlled. Transient solutions are derived using the method of Laplace transform and Green’s function, which relate pore-water concentrations of the constituents to their concentrations in the bulk water and to the flux of decomposable settling organic matter. Steady-state pore-water concentrations are also obtained including expressions for the extent of methane saturation zone and methane gas flux. A relationship relating the sediment oxygen demand (SOD) to bulk water oxygen is derived using the two-film concept, which in combination with the depth-integrated solutions forms the basis for predicting the extent of oxygen penetration in the sediment. Iterative procedure and simplification thereof are proposed to estimate the extent of methane saturation zone and thickness of the aerobic layer as functions of time. Sensitivity of steady-state solutions to key parameters illustrates sediment processes interactions and synergistic effects. Simulations indicate that for a relatively thin diffusive boundary layer, d, oxygen uptake is limited by biochemical processes inside the sediments, whereas for a thick boundary layer oxygen transfer through the diffusive boundary layer is limiting. The results show an almost linear relationship between steady-state sediment oxygen demand and bulk water oxygen. For small d methane and nitrogen fluxes are sediment controlled, whereas for large d they are controlled by diffusional transfer through the boundary layer. It is shown that the two-layer model solution converges to the one-layer model (anaerobic layer) solution as the thickness of the oxygenated layer approaches zero, and that the transient solutions approach asymptotically their corresponding steady-state solutions. 相似文献
4.
不同溶解氧水平下湖泊底泥-水界面磷交换影响因素分析 总被引：15，自引：2，他引：13
在实验室控制条件下,研究了玄武湖底泥在饱和溶解氧、75%、50%、25%、0%溶解氧水平下底泥-水界面磷交换,探讨了溶解氧对底泥-水界面磷交换的影响途径.结果表明:(1)上覆水溶解氧与玄武湖底泥溶解性磷酸盐、溶解性总磷释放速率呈开口向上的抛物线关系;(2)上覆水溶解氧水平可以决定磷在底泥-水界面交换中的转换方向,而且还影响间隙水中溶解氧扩散深度,25%、50%、75%和饱和溶解氧水平下溶解氧最大扩散深度分别为0.974cm、1.377cm、1.687cm和1.948cm,溶解氧在间隙水中最大扩散深度影响底泥-水界面的磷交换;(3)溶解氧可通过影响底泥-水界面处电位、藻类聚磷作用以及pH来影响底泥-水界面的磷交换. 相似文献
5.
EKKEHARD HOLZBECHER 《水文科学杂志》2013,58(4):641-649
Abstract Models on flow and transport in surface water sediments currently neglect compaction, although it is well understood that compaction is one of the major processes below the free fluid-sediment interface. Porosity changes in the sediment layers, as a result of compaction, are measured in almost all probes: porosity decreases with the distance from the surface water-sediment interface. This paper provides a rigorous derivation of basic flux terms for a frame of reference that is moving with the fluid-sediment interface. It is shown how burial rate, interface velocity, velocities of fluid and solid phase and porosity are connected—under steady-state conditions. It turns out that porosity and the velocities in a one-dimensional column can be directly computed from each other. These findings are important not only for the understanding of compaction-driven flow itself; they are crucial for all studies on storage and transport of chemical components in sediments. As mass fluxes across the sediment-water interface may be affected, there is an indirect link on surface water quality, making these findings relevant also for research on eutrophication of surface water bodies and/or on biogeochemical cycles. 相似文献
6.
水动力条件对沉积物-水界面氧通量的影响 总被引：2，自引：0，他引：2
氧环境决定了水体沉积物中各种生命所需元素的最终归趋,沉积物-水界面是水相与沉积物相氧传递的重要场所,而水动力条件是影响沉积物-水界面氧传递的重要因素.选择三峡库区一级支流御临河为研究对象,根据长年监测数据建立实验室模型,采用声学多普勒流速测试仪及微电极测试系统构建了非侵入式涡度相关测试系统,探究了不同水动力条件对沉积物-水界面氧通量的影响.结果表明：水体静止状态下沉积物-水界面溶解氧浓度随时间的增加而减少,非静止状态下随时间的增加而增加;沉积物-水界面氧通量随水体流速的增加而增加.根据氧通量求解对应流速下垂直涡动扩散系数并进行线性拟合,当水体流速为0.01~0.14 m/s时,垂直涡动扩散系数与水体流速的相关性最好,此时沉积物-水界面氧通量的传递以涡动扩散为主导. 相似文献
7.
研究湿地底泥污染特性及水-土界面边界层性质是明确大型人工湿地长期运行下底泥内源污染问题的关键.本文以典型人工湿地为例,通过综合布点垂向分层监测湿地底泥理化性质,明确底泥污染特性,分析水-土界面边界氧化层现象、性质及形成机理,探讨其性质成因.结果表明：与湖泊类似,长期运行人工湿地底泥也会产生氧化层,垂向由上到下分为氧化层、污染层、过渡层和健康层;运行6年的湿地底泥可形成厚约1 cm、无明显臭味、棕黄色可塑状的氧化层;与污染层相比,氧化层色味变淡、流动性减弱,含水率、d（0.9）、亚铁、总有机碳和总氮含量分别降低7.20%、54.04%、54.59%、17.89%和7.00%,氧化还原电位和总磷含量分别升高150.41%和18.17%;氧化层是由氧化、沉降协同作用下形成的底泥表层氧化态微环境,其中上覆水溶解氧水平越高越有利于提高氧化层致密程度,降低氧化层有机质、总氮含量,上覆水悬浮物浓度越高、水深越深越有利于增加氧化层厚度. 相似文献
8.
藏南沉错钻孔沉积物金属元素分布特征及其与粒度的关系 总被引：4，自引：1，他引：3
从沉积物磷的化学形态特征、沉积物-水界面的环境条件和水库的水文参数等角度探讨了山仔水库沉积物磷对上覆水体的磷浓度贡献,并从沉积物间隙水与水体垂向溶解性磷的浓度梯度估算对水体磷浓度的贡献大小．结果表明：山仔水库沉积物具有大的释放磷的潜力,沉积物间隙水和水体之间存在着明显的溶解性磷的浓度梯度,沉积物的溶解性磷释放通量在0．0420—0．167μg／（cm^2·d））之间,沉积物磷对水体营养贡献大小在0．7％-6％之间,其中秋冬季节沉积物磷对水体的贡献大于春夏季节,当外源减少时,沉积物磷负荷在一定时间内将成为水库营养状态的重要贡献因子。 相似文献
9.
双向环形水槽模拟变化水位和流速下洞庭湖沉积物氮释放特征 总被引：1，自引：0，他引：1
浅水湖泊生态系统中的沉积物—水界面是湖泊内源氮释放的重要界面,而水动力因素是改变沉积物氮释放的重要因素.三峡大坝修建以后,长江中下游通江湖泊的水动力条件发生了明显的变化.通过采集洞庭湖湖口区域的沉积物和水样,在双向环形水槽动力模拟装置内模拟湖泊水位和流速的变化,探讨湖泊沉积物氮在沉积物和水系统中的二次释放特征.结果表明,随着扰动强度的增加,上覆水悬浮物浓度增大,上覆水中总氮浓度增加,沉积物向上覆水释放氮的强度增强,水动力条件的改变所引起的沉积物内源氮释放不容忽视.在该模拟实验条件下,沉积物存在最适扰动水位(20cm),此水位下上覆水中悬浮物浓度最低,总氮浓度最小.水动力条件的改变对上覆水和沉积物—水界面处铵态氮和硝态氮浓度的影响并不明显,孔隙水中铵态氮与硝态氮之间发生形态的转化. 相似文献
10.
Sediment movement in the wave boundary layer above a mobile sediment bed is complex.A velocity formula for the boundary layer is proposed for sheet flow induced by asymmetric waves above a mobile sediment bed.The formula consists of a free stream velocity and a defect function which contains a phase-lead,boundary layer thickness and mobile sediment bed.Phase-lag of sediment movement is considered in the formula for the mobile sediment bed.The formula needs six dependent variables about asymmetric wave and sediment characteristics.Asymmetry effects on parameters(orbital amplitude,roughness height,bed shear stress,and boundary layer thickness)are properly considered such that the formula can yield velocity differences among onshore,offshore,acceleration,and deceleration stages.The formula estimates the net boundary layer velocity resulting from the mobile sediment bed and asymmetric boundary layer thickness.In addition,a non-constant phase-lead also contributes to the net boundary layer velocity in asymmetric oscillatory sheet flow.Results of the formula are as good as that of a two-phase numerical model.Sheet flow transport induced by asymmetric waves,and the offshore net sediment transport rate with a large phase-lag under velocity-skewed waves,can be adequately estimated by the formula with a power sediment concentration function. 相似文献
11.
鄱阳湖沉积物和水界面磷的交换通量 总被引：6，自引：0，他引：6
采用扩散模型法与实验培养法对鄱阳湖沉积物和水界面间可溶性总磷和可溶性磷酸盐的界面交换过程进行研究,并探讨了其影响因素.结果表明,利用2种方法得到鄱阳湖各站点可溶性总磷和可溶性磷酸盐在沉积物与水界面间的交换方向不完全相同,大部分站点沉积物是磷的源,其中,利用扩散模型法估算的可溶性总磷和可溶性磷酸盐平均扩散通量分别为0.052和0.047 mg/(m~2·d),而实验培养法测得可溶性总磷和可溶性磷酸盐的平均交换通量则分别为0.25和0.24 mg/(m~2·d),且各站点利用扩散模型法测得磷的交换通量均小于实验培养法的计算结果.此外,上覆水溶解氧浓度及水体温度对可溶性总磷和可溶性磷酸盐的交换过程均具有一定的影响,表现为温度越高,溶解氧浓度越小,可溶性总磷和可溶性磷酸盐的交换越强烈. 相似文献
12.
It is argued in this commentary that, in order to understand better the physical mechanisms that generate boundary shear stress over water‐worked gravel beds, flow velocity data should be re‐evaluated by spatial averaging the Reynolds equations to produce time‐ and space‐averaged (double‐averaged) momentum equations. A series of laboratory experiments were conducted in which the flow velocities were measured using a PIV system over two water‐worked gravel deposits. Combined with detailed data on the bed surface topography and vertical porosity, the physical components of shear stress were obtained. This enabled the various momentum transfer mechanisms present above, within and at the interface of a porous, fluvial deposit, to be quantified. This included the examination of the relevant contributions of temporal and spatial fluctuations in velocity and surface drag to the overall momentum transfer. It is demonstrated that double‐averaging represents a logical framework for assessing the fluid forces responsible for sediment entrainment and for investigating intragravel flow and sediment–water interface exchange mechanisms within the roughness layer in water‐worked gravel deposits. By considering the physical components of shear stress and their relative sizes it was possible to provide a physically based explanation for existing observations of enhanced mobility of gravel–sand mixtures and the transfer of solutes into porous, gravel deposits. This analysis reveals the importance of obtaining co‐located, high quality spatial data on the flow field and bed surface topography in order to gain a physical understanding of the mechanisms which generate boundary shear stress. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
13.
采用平面光电极技术研究了霍甫水丝蚓(Limnodrilus hoffmeisteri)扰动对湖泊沉积物-水界面二维pH值分布特征的影响.结果表明水丝蚓扰动能将沉积物-水界面处pH值的变化梯度由2.5 mm内降低1.6个pH值单位减缓至约1 cm内降低0.6个pH值单位,并在界面处形成约1 cm深的pH值缓冲区域.水丝蚓的造穴活动也会对沉积物的二维pH值分布产生影响,洞穴内的pH值高于洞穴周边沉积物约0.6个pH值单位. 相似文献
14.
15.
水丝蚓(Tubificid worms)扰动对磷在湖泊沉积物-水界面迁移的影响 总被引：20，自引：6，他引：14
为探讨水丝蚓(Tubificid worms)扰动对磷在湖泊沉积物-水界面间迁移的影响,选取太湖梅梁湾与大浦口两富营养化湖区为研究对象,通过室内培养实验,利用Rhizon间隙水采样器等技术,研究了水丝蚓扰动对太湖沉积物-水界面理化性质及溶解活性磷(SRP)在界面通量的影响.结果表明水丝蚓扰动能够增大表层沉积物含水率、氧化还原电位,减小间隙水中Fe2+浓度.水丝蚓没有显著改变梅梁湾间隙水中SRP浓度,同时促进了梅梁湾沉积物中SRP向上覆水的释放;但水丝蚓显著减小了大浦口间隙水中SRP浓度,并抑制了大浦口沉积物中SRP向上覆水的释放.水丝蚓扰动对磷在沉积物-水界面间迁移的不同影响可能是由沉积物中Fe2+含量差异较大造成的. 相似文献
16.
J. Kirk Cochran 《Earth and Planetary Science Letters》1980,49(2):381-392
The flux of226Ra from bottom sediments has been determined from patterns of226Ra/230Th disequilibrium in ten deep-sea cores from the world oceans. Values range from ? 0.0015 dpm/cm2 yr (in the Atlantic) to 0.21 dpm/cm2 yr (in the north equatorial Pacific). The flux is poorly related to sediment type, but is inversely correlated in a non-linear fashion with sediment accumulation rate. There is a direct relationship between the production rate of226Ra near the sediment-water interface (i.e. the integrated230Th activity in the biologically mixed zone) and the226Ra flux. The226Ra concentration in near-bottom water follows the geographic variation in the226Ra flux. The high flux from north equatorial Pacific sediments especially is reflected in the high bottom water226Ra concentrations in that area. The data suggest that both rate of circulation and the magnitude of the radium flux influence the near-bottom226Ra concentration. 相似文献
17.
季节性缺氧导致夏季沉积物内源磷强烈释放,加剧水体富营养化,是我国西南地区深水湖泊（水库）面临的重要挑战.有效增加夏季缺氧期深水沉积物-水界面的含氧量,是减少内源磷释放的关键.现有的深水增氧技术由于缺乏对沉积物-水界面增氧的针对性,因此治理效果有限.近年来,纳米气泡已被证实具有的稳定性好、氧传质速率高和环境风险低等优点,为新型深水增氧技术研发提供了巨大潜力.本文以天然矿物材料白云母、绢云母、硅藻土和沸石为基底,负载纳米气泡,研发纳米气泡改性矿物颗粒技术,开展湖泊沉积物-水界面增氧模拟实验研究,运用平面光电极技术评估其界面增氧效果.结果表明,纳米气泡改性矿物颗粒对沉积物-水界面具有比较明显的增氧效果.其中,改性白云母、绢云母和沸石的界面持续增氧时间可达7天以上,增氧后的界面最大溶解氧（DO）浓度达4.40 mg/L,而改性硅藻土不具有增氧能力.其次,矿物粒度对改性颗粒的增氧效果有一定影响：粒度越细,界面的最大增氧浓度越高,且持续增氧时间越长.纳米气泡改性矿物颗粒技术有望成为夏季缺氧期深水沉积物-水界面精准增氧和内源污染控制的有效技术手段. 相似文献
18.
Xiao Lin Mark J. McCarthy Stephen A. Carini Wayne S. Gardner 《Continental Shelf Research》2011,31(2):120-128
A new approach, combining 15NH4+ isotope dilution and continuous-flow techniques, provided estimates of “actual” and “net” NH4+ flux and sediment NH4+ demand (SAD) at the sediment-water interface (SWI) of sites in the northern Gulf of Mexico (NGOMEX). The sites included a hypoxic site (C6), two sites with intermediate oxygen levels (B7 and F5), and a normoxic site (CT). Control cores without isotope addition and other cores from the same site treated with 15NH4+ labeled overflowing water differentiated between net and actual regeneration flux and actual vs. potential uptake flux of NH4+. Experiments were conducted in 2008 before (July) and after (September) two successive hurricanes (Gustav and Ike) and in January and August, 2009. Actual regeneration was significantly higher than net flux at most sites. Net flux did not differ significantly in most sites/dates, but the actual regeneration, and the actual and potential uptake, showed temporal and spatial variation; the flux at the hypoxic site was more active than non-hypoxic sites. SAD, the difference between potential and actual NH4+ uptake flux, was higher at the hypoxic site than at non-hypoxic sites before and after the hurricanes in 2008 and during the hypoxia season in 2009. SAD related negatively to bottom water DO values. Conclusions: (1) net flux often underestimated actual regeneration, (2) hurricane activity decreased N dynamics, and (3) microbial N limitation status at the hypoxic site related to NH4+ removal processes that were independent of oxygen (e.g., anaerobic heterotrophic uptake or anammox). These results indicate a rather consistent NH4+ demand at the SWI during the hypoxic season and suggest that reduced nitrogen may limit microbial dynamics in the region. 相似文献
19.
以三峡水库香溪河库湾为研究对象,采用原位加密采样(2021年5月)和室内培养方法,结合沉积物特性与水环境因子分析,探讨了香溪河库湾沉积物甲烷(CH4)释放潜力、沉积物-水界面CH4产生和氧化通量空间分布规律及其影响因素。结果表明:三峡水库泄水期间,香溪河库湾沉积物CH4释放潜力的变化范围是6.35-2029.37 mg/(kg·d),沉积物-水界面CH4产生通量和氧化通量的变化范围分别为0.04～0.73、0.03～0.62 mmol/(m2·d);空间上,沉积物CH4释放潜力、沉积物-水界面CH4产生及氧化通量在香溪河库湾和各典型横切面(XX02、XX05和XX06)间表现出空间差异性,主要受水深、TOC和温度的影响。垂向上,CH4产生速率随沉积物深度的增加而减小,表层20 cm沉积物CH4释放潜力占整柱沉积物的70%,可以用于估算库湾沉积物CH4释放潜力。此外,沉积... 相似文献
20.
[专稿]湖泊沉积物-水界面研究进展与展望 总被引：2，自引：0，他引：2
湖泊沉积物-水界面是以水层/沉积层物相为基础、具有一定立体尺度的交接面,界面上所发生的由生物积极参与的物理、化学和生物学微小反应和环境变化,都会对界面附近物质的状态和迁移转化行为产生着复杂影响.本文首先回顾了沉积物-水界面研究100多年来的发展历程及国内外近20年发展.然后系统介绍了国际上对沉积物-水界面的物理尺度与结构的宏观和微观认识;重点综述了沉积物间隙水的取样、物化性质的多维测定与结构表征、过程的静态和动态模拟等湖泊沉积物-水界面研究技术与方法;分析和展示了氮磷等营养物、重金属和持久性有机污染物在湖泊沉积物-水界面迁移转化过程的研究进展;总结和归纳了在沉积物-水界面过程的模型研究、沉积物-水界面物质交换的定量化、界面过程与湖泊生态环境灾害关系等模型与过程效应方面的研究成果.最后对沉积物-水界面信息获取技术的研发方向、界面物质交换定量化研究的关注点,以及加强模型的应用和构建等方面进行了展望. 相似文献