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1.
秦岭富水杂岩体的一些变辉长岩含有粒度较大，U、Pb含量较高的斜锆石和锆石，是U-Pb同位素测年的极好矿物。本文对秦岭富水杂岩的中粗粒角闪黑云辉长岩中的斜错石和错石分别进行了SHRIMP法和TIMS法U-Pb同位素年龄测定，获得斜锆石和锆石的U-Pb同位素年龄分别为501.4±1.2 Ma和480.0±3.4 Ma，二者相差约20 Ma；对该岩石中的斜锆石和锆石的关系及锆石的成因进行了初步研究，认为斜锆石的U-Pb同位素年龄应可解释为秦岭富水杂岩中基性岩石的形成时代，而锆石的成因比较复杂，对其U-Pb同位素年龄地质意义的合理解释需作进一步的研究。  相似文献   

2.
夏斌  林清茶  张玉泉 《地质学报》2006,80(2):287-293
本文在野外工作基础上,系统研究了云南大平糜棱岩化碱性花岗岩岩石结构构造、矿物组成、主微量元素和锆石特征等。根据岩体本身还残留有层理,在糜棱岩化之前的岩石具花岗变晶结构和含有反映区域变质成因的钠铁闪石造岩矿物,以及锆石高度富集和显示有一定层位等,认为云南大平糜棱岩化碱性花岗岩为沉积变质成因。  相似文献   

3.
对乌拉特中旗德尔斯地区黑云母二长花岗岩岩相学、锆石SHRIMP U-Pb年代学和岩石地球化学进行了研究,并讨论了岩石成因及研究区晚海西期构造演化。黑云母二长花岗岩发育两期:早期为中粗粒斑状黑云母二长花岗岩,晚期为中细粒黑云二长花岗岩。岩石中的锆石大部分具核-边结构:边部震荡环带发育,Th/U值为0.16~0.50,反映了岩浆成因;核部呈浑圆状,多数具岩浆环带,个别弱分带-无分带,Th/U值为0.06~0.44,表明核部大部分属岩浆型残留锆石,个别为变质型残留锆石。测年结果显示：边部锆石加权平均年龄为早、中二叠世((279±3) Ma、(266±3) Ma),代表黑云母二长花岗岩形成时代;核部残留锆石加权平均年龄为(1 972±63) Ma 、(1 962±43) Ma,代表源岩的形成时代。岩石属于亚碱性系列,REE配分形式呈右倾型,LREE/HREE为5.86~22.81,明显亏损高场强元素Nb,富集大离子亲石元素Rb、Ba,显示活动大陆边缘火成岩的地球化学特征。黑云母二长花岗岩地球化学属性反映了早、中二叠世古亚洲洋向华北板块北缘的俯冲作用及古亚洲洋消亡的演化历史。  相似文献   

4.
Analysis of currently available data (877 individual high-precision zircon analyses) on the composition of zircons from eclogite complexes worldwide reveals general relations in the zircon composition: an anomalous decrease in the Th concentration (no higher than 3 ppm on average) and the Th/U ratio (0.33 on average), a significant decrease in the concentrations of all REE (to 22 ppm) and particularly LREE (<2 ppm), and relatively low concentrations of Y (34 ppm), U (100 ppm), and P (41 ppm) at an elevated Hf concentration (11 400 ppm on average). The REE patterns of eclogitic zircons are noted for pronounced flat HREE patterns, poorly pronounced (if any) negative Eu anomalies, strongly reduced positive Ce anomalies (Ce/Ce* = 11 on average), and U-shaped configurations of LREE patterns up to the development of negative Nd anomalies. The relations detected in the distribution of trace elements and REE in eclogitic zircons are of universal nature and occur irrespective of the rock type (metabasites, metaultrabasites, or gneisses) and the metamorphic pressure (eclogites of high and ultrahigh pressure). The application of the aforementioned criteria makes it possible to reliable distinguish eclogitic zircons from those of magmatic or metamorphic genesis (not related to high-pressure metamorphism). Eclogites in the Belomorian Mobile Belt (in the Salma and Gridino areas) were determined to contain zircons in metagabbro eclogites; the cores of these zircons have an age of 2.8?C2.9 Ga and are of magmatic genesis, whereas their outer metamorphic zones have an age of 1.9 Ga and a trace-element composition typical of eclogitic zircons. Hence, the Belomorian Mobile Belt was affected only by single (Svecofennian, at ??1.9 Ga) episode of eclogite metamorphism of Archean rocks.  相似文献   

5.
蒙古戈壁阿尔泰省巴音陶勒盖地区地处南戈壁-阿尔泰构造带南缘,区内构造活动活跃,中酸性侵入岩比较发育。采用LA-ICP-MS锆石U-Pb测年技术,对区内二长花岗岩中的锆石进行同位素年龄研究。阴极发光图像显示,锆石颗粒多为自形-半自形,且有明显的初始岩浆振荡环带,少见蚀变微区,结合较高的Th/U值(0.65~1.79),断定其为典型的岩浆成因锆石;30颗锆石的~(206)Pb/~(238)U年龄加权平均值为300.2±0.9Ma,显示二长花岗岩成岩时代为晚石炭世,代表了华力西中期的一次构造-岩浆事件,为约束南戈壁-阿尔泰构造带晚石炭世深成岩浆活动时限提供了新证据。  相似文献   

6.
云南大平糜棱岩化碱性花岗岩的锆石特征及其地质意义   总被引：19，自引：0，他引：19  
在哀牢山一金沙江新生代钾质碱性岩浆岩带的南端,云南金平县大平糜棱岩化钠闪石霓石花岗岩中锆石,主要为“变质锆石”和具有老核新壳的“变质复合型锆石”,它们皆具不规则状和圆化的外形,并常高度的富集成堆和显示有一定层位。用ELA-ICP-MS和SHRIMP对锆石定年,结果表明,变质复合型锆石中老核年龄为247．9±6．4Ma,新壳和变质锆石年龄为145．7±3．4Ma。薄片观察发现,在岩体发生糜棱岩化之前还有一次区域变质作用,呈现在糜棱岩化弱的地段岩石发育柱粒变晶结构和花岗变晶结构,而且残留有清楚的层理,由此表明该花岗岩的成因与沉积变质有关。  相似文献   

7.
对山西代县洪塘矿区富含红色和黑色两种金红石的直闪岩进行岩相观察和矿物成分分析,并就其中锆石在阴极发光下的外部形态、内部结构及矿物包裹体进行研究.所分选出的锆石按其颗粒上的相对位置、形态、阴极发光图像、SHRIMP年龄值以及内部矿物包裹体划分为复杂锆石和单成因锆石,其中复杂锆石由核部、幔部和边部锆石三类锆石组成.第1类锆石无环带,部分边缘可见溶蚀痕迹,为继承锆石.内部包裹富锾矿物组合顽火辉石+金云母,与寄主岩石的组合明显不同,反映其可能是寄主岩石形成之前保留于锆石中的原岩矿物并源于地幔.第Ⅱ类锆石为半自形-自形晶,环带较宽且清晰,推测为高级变质锆石.其内矿物包裹体主要为直闪石,其次为钙铁辉石(?),反映其形成于角闪岩相,与寄主岩石的矿物组合可能一致.第Ⅲ类锆石主要位于增生边,阴极发光亮度高,推测为流体改造的变质锆石.第Ⅳ类单成因锆石多呈自形,阴极发光下较暗,生长环带规则且较窄.矿物包裹体有钠长石+石英+白云母,对应中压绿片岩相,其形成温度和压力低于寄主岩石,它与第Ⅲ类锆石可能是在同一期后期事件中形成.结合岩相学研究结果,认为该区金红石矿床之原岩可能是岩浆岩,后期经历了至少两期构造热事件,早期热事件可能导致了锆石内U-Th-Pb体系的重置.以上研究结果表明经历复杂变质作用的变质岩中锆石内部矿物包裹体的研究分析还是探讨寄主岩石成因及所经历地质事件的有效手段.  相似文献   

8.
A comprehensive (mineralogical, geochronological, and geochemical) study of zircons from an eclogitized gabbronorite dike was carried out in order to identify reliable indicators (mineralogical and geochronological) of the genesis of zircons in their various populations and, correspondingly, the age of certain geological events (magmatic crystallization of the gabbroids, their eclogitization, and overprinted retrograde metamorphism). The three populations of zircons separated from two rock samples comprised xenogenic, magmatic (“gabbroic”), and metamorphic zircons, with the latter found exclusively in the sample of retrograded eclogitized gabbroids. The zircons of group I are xenogenic and have a Meso- to Neoarchean age. Mineral inclusions in them (quartz, apatite, biotite, and chlorite) are atypical of gabbroids, and the geochemistry of these zircons is very diverse. The zircons of group II contain mineral inclusions of ortho- and clinopyroxene and are distinguished for their very high U, Th, Pb, and REE concentrations and Th/U ratios. These zircons were formed during the late magmatic crystallization of the gabbroids at temperatures of 1150–1160°C, and their U-Pb age of 2389 ± 25 Ma corresponds to this process. The eclogite mineral assemblages crystallized shortly after the magmatic process, as follows from the fact that the marginal portions of the prismatic zircons contain clinopyroxene inclusions with elevated contents of the jadeite end member. The zircons of group III contain rare amphibole and biotite inclusions and have low Ti, Y, and REE concentrations, low Th/U ratios, high Hf concentrations, contain more HREE than LREE, and have an U-Pb age of 1911 ± 9.5 Ma, which corresponds to the age of the overprinted amphibolite-facies metamorphism.  相似文献   

9.
变质岩中的锆石大多遭受变质热事件的改造,但中-浅变质岩一般不甚发育新生锆石或变质增生边,不易通过现有的锆石测年技术获得该岩石的变质年龄。中-浅正变质岩的锆石为岩浆锆石与变质增生锆石的混合物,其U-Pb同位素组成可以采用二端元混合模式来表达。利用同位素稀释法(TIMS)可以获得混合锆石U-Pb年龄及对应的同位素组成;结合CL等内部结构分析,利用离子探针法(SHRIMP)可以获得岩浆锆石U-Pb年龄及对应的同位素组成,进而推算出变质增生锆石U-Pb年龄对应的同位素组成。在对滇东南南温河花岗岩锆石U-Pb年代学的研究中,我们发现同一样品的SHRIMP与TIMS U-Pb法测年结果不一致,根据上式推算出后期主变质年龄约为230 Ma,与前人利用其它测年方法获得的结果基本一致,符合研究区主变质期为印支期的区域地质背景。该方法为中-浅正变质岩年代学研究提供了一种新思路。  相似文献   

10.
We report δ7Li, Li abundance ([Li]), and other trace elements measured by ion probe in igneous zircons from TTG (tonalite, trondhjemite, and granodiorite) and sanukitoid plutons from the Superior Province (Canada) in order to characterize Li in zircons from typical Archean continental crust. These data are compared with detrital zircons from the Jack Hills (Western Australia) with U–Pb ages greater than 3.9 Ga for which parent rock type is not known. Most of the TTG and sanukitoid zircon domains preserve typical igneous REE patterns and CL zoning. [Li] ranges from 0.5 to 79 ppm, typical of [Li] in continental zircons. Atomic ratios of (Y + REE)/(Li + P) average 1.0 ± 0.7 (2SD) for zircons with magmatic composition preserved, supporting the hypothesis that Li is interstitial and charge compensates substitution of trivalent cations. This substitution results in a relatively slow rate of Li diffusion. The δ7Li and trace element data constrain the genesis of TTGs and sanukitoids. [Li] in zircons from granitoids is significantly higher than from zircons in primitive magmas in oceanic crust. TTG zircons have δ7Li (3 ± 8‰) and δ18O in the range of primitive mantle-derived magmas. Sanukitoid zircons have average δ7Li (7 ± 8‰) and δ18O higher than those of TTGs supporting genesis by melting of fluid-metasomatized mantle wedge. The Li systematics in sanukitoid and TTG zircons indicate that high [Li] in pre-3.9-Ga Jack Hills detrital zircons is a primary igneous composition and suggests the growth in proto-continental crust in magmas similar to Archean granitoids.  相似文献   

11.
对红沟铜矿床含矿火山岩进行高精度锆石LA-ICP-MS U-Pb同位素测年,获得单颗粒锆石的加权平均年龄为443.2 Ma±1.2Ma。红沟铜矿床形成时代为晚奥陶世,形成环境为晚奥陶世陆缘裂谷环境。高精度年龄的获得对于整个祁连山地区产于陆缘裂谷环境的铜多金属矿床的成矿时代和成因研究具有重要意义。  相似文献   

12.
对红沟铜矿床含矿火山岩进行高精度锆石LA-ICP-MS U-Pb同位素测年,获得单颗粒锆石的加权平均年龄为443.2Ma±1.2Ma。红沟铜矿床形成时代为晚奥陶世,形成环境为晚奥陶世陆缘裂谷环境。高精度年龄的获得对于整个祁连山地区产于陆缘裂谷环境的铜多金属矿床的成矿时代和成因研究具有重要意义。  相似文献   

13.
唐勇  张辉  吕正航 《矿物岩石》2012,32(1):8-15
新疆阿勒泰可可托海地区出露大量花岗岩和伟晶岩脉,利用阴极发光显微照相(CL)、电子探针背散射(BSE)和激光剥蚀电感耦合等离子质谱技术(LA-ICP-MS),观察和分析岩石中锆石的内部结构、稀土元素及Th,U含量后结果表明:该区花岗岩锆石具振荡环带和强烈的阴极发光特征,Th/U比值较高(Th/U=0.16～0.99),轻稀土亏损、重稀土富集,具较大的Ce正异常,为典型岩浆成因锆石。伟晶岩(KP-08-11)锆石为热液锆石,不具振荡环带和阴极发光,具低的Th/U比值(0.01～0.13),强烈富集稀土元素,尤其是轻稀土元素较花岗岩锆石高一个数量级,Ce的正异常相对较低。伟晶岩(KP3-08-1)锆石为变质重结晶锆石,Th/U比值分布范围较广(0.01～0.78),强烈亏损稀土元素,稀土元素配分模式存在显著的"REE四分组效应"。微量元素特征表明,伟晶岩(KP-08-11)锆石可能结晶自富U贫Th的残余岩浆流体,而伟晶岩(KP3-08-1)的锆石经历了蜕晶质化和变质重结晶作用,但依然保持了共存伟晶岩熔体的微量元素特征。  相似文献   

14.
防虎山组的下部砂岩地层是合肥盆地最古老的中生代沉积地层,在样品FH4中选出了碎屑锆石,通过显微激光拉曼光谱、电子探针的研究发现,锆石中含有柯石英、绿辉石、多硅白云母等典型的高压-超高压(HP-UHP)矿物包裹体、熔体玻璃包裹体以及磷灰石、石英、斜长石、白云母等矿物包裹体。结合阴极发光图像所揭示的锆石内部结构的分析以及锆石的微区测年数据,对碎屑锆石的物源进行了讨论。HP-UHP矿物包裹体在具有三叠纪年龄的变质碎屑锆石中的发现,进一步证明大别造山带高压-超高压岩石在早侏罗世时期已经出露地表并为合肥盆地提供了重要物源;碎屑锆石内部结构及成因的多样性表明当时作为源区的大别造山带岩石的复杂性。  相似文献   

15.
利用阴极发光和LA-ICP-MS微区定年分析方法,对川东北前陆盆地中生界上三叠统须家河组和中侏罗统上沙溪庙组砂岩中碎屑锆石进行了U-Pb同位素分析,结果显示锆石具多成因类型,年龄具分组分段特征。上三叠统须家河组碎屑锆石年龄值有5组:213～283Ma、312～448Ma、694～710Ma、1430～1988Ma和2133～2708Ma;中侏罗统上沙溪庙组碎屑锆石年龄值有7组:163～194Ma、213～274Ma、404Ma、712Ma、1742～1972Ma、2116～2594Ma和3025～3140Ma。研究表明,川东北前陆盆地沉积物主要为源自秦岭造山带燕山期陆内造山岩浆活动产物(163～194Ma)、晚海西—印支期秦岭俯冲碰撞岩浆活动的产物(213～283Ma;213～274Ma)、北秦岭俯冲造山-构造岩浆作用的物质(312～448Ma;404Ma)、南秦岭南华纪与Rodinia超大陆裂解相关物质(694～710Ma;712Ma)、秦岭造山带褶皱基底(1430～1988Ma;1742～1972Ma)和秦岭造山带变质基底(2133～2708Ma;2116～2594Ma、3025～3140Ma)。结合已有古水流及区域资料综合分析,秦岭造山带与川东北前陆盆地具较好的盆山物质耦合关系。  相似文献   

16.
The intensity of the redistribution of trace elements in zircons significantly varies depending on the types of secondary processes affecting the magmatic rocks. The Neoarchean alkaline granites of the Keivy structure in the Kola Peninsula are employed as an illustrative example of differences in the variation dynamics of the proportions of certain elements (REE, Th, U, Hf, and others) with the transition from the magmatic to metamorphic crystallization of zircons during Proterozoic amphibolite-facies metamorphism over-printed onto the rocks. Changes are detected in the proportions of LREE and HREE, in the Ce4+/Ce3+ and Th/U ratios, and in other incompatible elements. The data obtained by geochemically comparing the redistribution of certain elements and their pairs in zircons during amphibolite-facies metamorphism and Phanerozoic hydrothermal alteration (literature data) are used to gain insight into the genesis of detrital Hadean zircons. Certain similarities and remarkable differences are detected in the effects of Hadean processes and Phanerozoic-Precambrian magmatism and secondary recrystallization on the behavior of chemical elements.  相似文献   

17.
锆石的形态标型和成分标型可用于反演岩浆的演化过程和构造环境.为探讨西藏桑耶地区晚白垩世的石英二长闪长岩的岩浆成因、演化过程及其物理化学条件,采用成因矿物学方法对石英二长闪长岩中的锆石的形态标型、成分标型及其构造环境进行了系统研究.结果表明,锆石的延长系数多集中于1.5:1～3.0:1,锆石群型多为S10和P10锆石形态...  相似文献   

18.
锆石中两种成分变化趋势及其成因标型意义   总被引：11，自引：1，他引：11  
鲍学昭 《矿物学报》1995,15(4):404-410
锆石从晶体中心至边缘的两种成分变化趋势与成因有内在联系。岩浆成因锆石从中心至边缘具有ＺｒＯ２含量及ＺｒＯ２／ＨｆＯ２值下降，ＨｆＯ２和（ＵＯ２＋ＴｈＯ２）含量上升的特征，而变质成因锆石则与此相反，本文论述了它们的成因及成因标型意义。  相似文献   

19.
东坪碲金矿床是与碱性侵入岩有关的国内规模最大的碲金矿床。虽然前人已对该矿床做过大量研究,但其成矿年龄仍存在较大争议。文章通过对矿床中辉钼矿Re-Os和锆石U-Pb年龄进行研究,对成矿年龄和矿床成因进行限定。矿床中的辉钼矿存在浸染状和细脉状两种产状。浸染状辉钼矿通常产于正长岩,与硫化物共生,Re-Os模式年龄为(401.1±2.1)和(402.8±2.1) Ma。细脉状辉钼矿主要产在石英-硫化物脉中,其内部及裂隙中产出大量自然金,Re-Os模式年龄为(380.3±2.0)和(376.9±2.9) Ma。含金石英脉中的岩浆锆石U-Pb年龄为(394±1.7) Ma,热液锆石U-Pb年龄为(382±4.7) Ma。辉钼矿与锆石年龄一致,且与水泉沟碱性杂岩体侵位年龄相吻合,因此认为东坪碲金矿床存在泥盆纪成矿,可能与水泉沟岩体岩浆活动有关。矿床经历了晚侏罗世—早白垩世岩浆流体的交代、活化、富集过程,最终形成大型碲金矿床。矿床中的碲主要来自上地幔或洋壳物质的部分熔融,水泉沟碱性岩浆出溶的高氧逸度、中偏碱性的流体和脱气作用为碲的迁移和富集提供了重要条件。  相似文献   

20.
Zircon is a widely-used heavy mineral in geochronological and geochemical research because it can extract important information to understand the history and genesis of rocks. Zircon has various types, and an accurate examination of zircon type is a prerequisite procedure before further analysis. Cathodoluminescence (CL) imaging is one of the most reliable ways to classify zircons. However, current CL image examination is conducted by manual work, which is time-consuming, bias-prone, and requires expertise. An automated and bias-free method for zircon classification is absent but necessary. To this end, deep convolutional neural networks (DCNNs) and transfer learning are applied in this study to classify the common types of zircons, i.e., igneous, metamorphic, and hydrothermal zircons. An atlas with over 4000 CL images of these three types of zircons is created, and three DCNNs are trained using these images. The results of this study indicate that the DCNNs can distinguish hydrothermal zircons from other zircons, as indicated by the highest accuracy of 100%. Although similar textures in igneous and metamorphic zircons pose great challenges for zircon classification, the DCNNs successfully classify 95% igneous and 92% metamorphic zircons. This study demonstrates the high accuracy of DCNNs in zircon classification and presents the great potentiality of deep learning techniques in numerous geoscientific disciplines.  相似文献   

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