共查询到17条相似文献，搜索用时 281 毫秒
1.
为了研究流量条件对岩溶管道溶质运移的影响,设计9种不同管道流量进行示踪实验,发现随着流量升高,峰值浓度逐渐增大,穿透曲线(BTC)拖尾逐渐缩短,弥散系数基本不变。在3种管道结构中,单管峰值浓度随流量升高增加的速度最快,不对称水箱峰值浓度随流量升高增加的速度最慢。相比单管道,对称水箱导致溶质瞬态存储在漩涡中明显滞后,不对称水箱导致主体溶质滞后穿透以及部分溶质瞬态存储在漩涡中滞后运移。根据中间7种流量的实验数据,拟合得到BTC特征参数与峰值时间的关系式和特征参数与流量的关系式。采用2种方法预测最大和最小流量条件下的BTC特征参数:根据流量预测峰值时间,接着根据峰值时间预测其他特征参数;分别根据流量预测多个特征参数。结果表明方法 2的预测效果较好,但在野外条件下方法 1有优势。 相似文献
2.
岩溶管道溶质运移的尺度效应研究对穿透曲线的正确解译非常重要,但目前针对单一弯曲管道中溶质运移尺度效应的研究仍比较缺乏。文章将岩溶管道和溶潭分别概化为透明软管和水箱,基于前期建立的水箱-管道系统(简称“管道系统”),在水箱下游设置不同长度的弯曲管道,通过示踪试验研究管道运移尺度对穿透曲线的影响,并采用暂时存储模型模拟试验曲线。结果表明：(1)随着水箱下游管道长度的增加,峰值质量浓度逐渐缓慢降低,穿透曲线上升段斜率无明显变化,穿透曲线拖尾逐渐缩短,表明运移管道长度增加对溶质运移的影响大于下游管道弯曲;(2)穿透曲线偏度系数、后段溶质羽穿透时间和溶质羽穿透时间与管道系统长度呈良好的负线性相关关系(R2>0.96);(3)当对称和不对称水箱管道系统长度分别增加至154.5 m和164.3 m时,偏度系数接近0,穿透曲线分布接近对称;(4)弥散系数、存储区截面积和交换系数与管道系统长度呈良好的负线性相关关系,当对称和不对称水箱管道系统长度分别增加至159.9 m和178.1 m时,存储区截面积接近0,水箱导致的溶质运移滞后效应基本消失。研究结果对野外岩溶管道穿透曲线的... 相似文献
3.
溶质暂态存储是岩溶地下水溶质运移过程中的普遍现象。为揭示岩溶管道与裂隙介质间溶质暂态存储机制,本文构建室内管道-裂隙物理模型,开展集中补给条件下的定量示踪试验,运用双区对流弥散模型实现溶质运移过程模拟。研究表明:随着集中补给水动力条件的增强,裂隙暂态存储水量呈线性增加趋势,溶质穿透曲线由单峰型向双峰型转变;管道和裂隙中的平均流速呈负相关关系,溶质在管道和裂隙中的滞留时间差决定了穿透曲线的形态;溶质暂态存储引发了穿透曲线的拖尾效应和双峰现象,对岩溶地下水溶质运移过程具有重要的控制作用。 相似文献
4.
通过将经典时间分数阶对流-弥散方程的等待时间分布函数的尾部修改为指数型,推导出了改进时间分数阶对流-弥散方程,并提出有效的时空算子分裂数值求解方法。对两个理想算例和一个实际算例进行计算,结果表明,改进的时间分数阶对流-弥散方程继承了时间分数阶对流-弥散方程能模拟穿透曲线幂率型拖尾分布的优点,还可模拟穿透曲线尾部由幂率型转换到指数型的过程;特征时间λ、分数阶指数γ和两相容量比例系数β共同决定了运移行为。改进的新模型可以区分非均质介质中流动相和非流动相中的溶质浓度, 更细微地模拟非Fick溶质运移行为。 相似文献
5.
裂隙网络管道模型弥散试验 总被引：1，自引：0，他引：1
为了探求不同裂隙几何参数对裂隙网络溶质运移的影响,基于离散裂隙网络思想和优势流、沟槽流理论,建立裂隙管道网络概念模型,搭建不同管径、不同连通方式的管道网络试验装置,进行渗流和溶质运移实验。运用应用广泛的模拟软件CHEMFLO-2000建立等效多孔介质模型,拟合不同几何参数下等效弥散度,定量刻画不同管道网络几何参数对溶质运移的影响,讨论了不同管径、连通方式等与等效弥散度之间的关系。通过进一步分析得出:在连通方式相同的情况下,不同管径的管道网络等效弥散度存在差异,但是差异不大;溶质在小管径中的穿透时间短于大管径,穿透曲线缓和程度相差不大;管道网络连通方式越复杂,其等效弥散度越大、对溶质运移的影响越大、穿透曲线越缓和、路径越长,等效弥散度越大;用这种等效弥散度的方法表征管道网络对溶质运移的影响,与多孔介质弥散度具有相似性;管道数目、管道面数目与等效弥散度成正相关关系,且等效弥散度随尺度的增大而增加。 相似文献
6.
基于CFP的岩溶管道流溶质运移数值模拟研究 总被引：2，自引：0，他引：2
多重岩溶含水介质的复杂性导致岩溶地下水流动及溶质运移的数学模拟成为地下水研究难点之一。为了探讨岩溶多重含水介质中地下水流溶质运移特征,文章构建了管道流CFP水流模型和MT3DMS溶质运移三维耦合数值模型。在阐述管道流CFP和MT3DMS基本原理的基础上,通过建立水文地质概念模型算例（1个落水洞、4个直管道）,探讨岩溶管道水流及溶质运移规律,分析讨论不同水文地质参数对浓度穿透曲线的影响。研究结果表明:管道流CFP模型能够刻画岩溶管道与基岩裂隙水流交换特征,MT3DMS模型能够模拟穿透曲线的拖尾现象,符合实际岩溶区特征。随着水力梯度、管道直径及管道渗透系数增大,孔隙度减小,浓度曲线峰值越大,峰值到达时间越快,浓度穿透曲线越对称。得出结论:耦合CFP水流模型和MT3DMS溶质运移模型能够刻画岩溶管道流溶质运移规律,为研究岩溶复杂介质污染物运移特征提供一种思路和途径。 相似文献
7.
非均质介质中溶质迁移往往出现非费克现象,传统的对流弥散方程(ADE)则难以较好地描述这种现象.采用连续时间的随机游走理论(CTRW)研究1250cm长一维非均质土柱中溶质运移问题,探讨CTRW模型中参数及非费克迁移的变化特征.研究结果表明,β值的大小与介质的非均质特征有关,非均质性越强,β值越小,但β值具有相对的稳定性,然而ADE的弥散系数则具有随尺度增大而增大的现象.对于介质非均质性较强和非费克现象较明显的溶质穿透曲线,尤其是在拖尾部分,与ADE相比,CTRW具有较高的模拟精度. 相似文献
8.
迄今为止,注入时间和静水压力对溶质在深层承压地热水中的运移规律影响研究少有报道。通过模拟35℃的低温地热环境,开展了注入时间1,2,3,4,5 h以及静水压力0,6,9 MPa条件下Cl-的运移柱模拟试验。采用CXTFIT 2.1软件进行数值模拟,探讨了孔隙型热储砂土中Cl-的运移规律和影响因素。结果表明：在模拟的低温孔隙型热储层中,不同注入时间和静水压力下,Cl-的运移曲线均呈正态对称分布,一维对流弥散(CDE)模型也可较好地表征其穿透曲线,因此溶质扩散过程符合菲克定律。注入时间的不同,会引起Cl-的穿透曲线、运移参数发生变化,这与不同注入时间条件下溶质注入总量、柱内溶质浓度差以及分子扩散能力不同有关。在不同静水压力条件下,弥散系数从0 MPa的25.22 cm2/h增加到9MPa的36.13 cm2/h,分子扩散系数、机械弥散系数以及弥散度也随之增大,因此溶质的弥散作用随静水压力的增大而增强。研究结果对于丰富地下水的溶质运移理论具有重要意义。 相似文献
9.
拖尾分布是溶质运移规律研究的热点和难点。死端孔隙、透镜体等空间结构形成的非均质性以及密度变化产生的指状流会导致溶质运移拖尾分布。论文选择保守性溶质氯化钠作为示踪剂,采用砂柱实验系统地研究了以死端孔隙导致的非均质性以及由不同浓度和温度形成的变密度条件对溶质运移拖尾分布的影响。实验结果表明:死端孔隙的存在会延迟溶质运移穿透曲线出峰时间,降低峰值及出现拖尾分布,随着死端孔隙介质体积或数量的增加这一现象越明显;随着溶液浓度的增加拖尾现象越明显,且温度的升高会加剧这一现象。对比死端孔隙、温度和浓度三者对溶质运移拖尾分布的影响,其中影响最大的是死端孔隙,其次是浓度和温度。 相似文献
10.
弥散度是刻画孔隙介质中溶质运移和扩散的重要参数,对于污染物的预测和修复至关重要,但野外示踪试验往往会选择忽略真实存在的井内混合效应。通过室内砂槽实验方法,模拟具有水平分层结构的含水层,该含水层主要由3种介质充填而成。采用埋藏传感器和井中布设传感器2种监测方式,对比在有/无混合效应情况下,穿透曲线的形态差异,进而探究井内混合效应对弥散尺度依赖性的影响情况。实验结果表明,井内混合效应会使穿透曲线呈现阶梯式增长,并伴有显著的拖尾现象;当使用对流弥散方程进行计算时,混合效应会导致弥散度被高估;观测到的弥散度与真实弥散度的差异会随着注入井和观测井间距离的增加而增大;此外,2种观测方式（埋藏/井内）均能发现弥散的尺度依赖性,且井内混合效应显著增强了弥散尺度效应,该实验结果可为污染物运移的评价和预测提供参考。 相似文献
11.
A series of laboratory experiments are performed under various hydrological conditions to analyze the effect of pools in pipes on breakthrough curves (BTCs). The BTCs are generated after instantaneous injections of NaCl tracer solution. In order to test the feasibility of reproducing the BTCs and obtain transport parameters, three modeling approaches have been applied: the equilibrium model, the linear graphical method and the two-region nonequilibrium model. The investigation results show that pools induce tailing of the BTCs, and the shapes of BTCs depend on pool geometries and hydrological conditions. The simulations reveal that the two-region nonequilibrium model yields the best fits to experimental BTCs because the model can describe the transient storage in pools by the partition coefficient and the mass transfer coefficient. The model parameters indicate that pools produce high dispersion. The increased tailing occurs mainly because the partition coefficient decreases, as the number of pools increases. When comparing the tracer BTCs obtained using the two types of pools with the same size, the more appreciable BTC tails that occur for symmetrical pools likely result mainly from the less intense exchange between the water in the pools and the water in the pipe, because the partition coefficients for the two types of pools are virtually identical. Dispersivity values decrease as flow rates increase; however, the trend in dispersion is not clear. The reduced tailing is attributed to a decrease in immobile water with increasing flow rate. It provides evidence for hydrodynamically controlled tailing effects. 相似文献
12.
Tracer concentration data from field experiments conducted in several carbonate aquifers (Malaga province, southern Spain) were analyzed following a dual approach based on the graphical evaluation method (GEM) and solute transport modeling to decipher flow mechanisms in karst systems at regional scale. The results show that conduit system geometry and flow conditions are the principal factors influencing tracer migration through the examined karst flow routes. Solute transport is mainly controlled by longitudinal advection and dispersion throughout the conduit length, but also by flow partitioning between mobile and immobile fluid phases, while the matrix diffusion process appears to be less relevant. The simulation of tracer breakthrough curves (BTCs) suggests that diffuse and concentrated flow through the unsaturated zone can have equivalent transport properties under extreme recharge, with high flow velocities and efficient mixing due to the high hydraulic gradients generated. Tracer mobilization within the saturated zone under low flow conditions mainly depends on the hydrodynamics (rather than on the karst conduit development), which promote a lower longitudinal advection and retardation in the tracer migration, resulting in a marked tailing effect of BTCs. The analytical advection-dispersion equation better approximates the effective flow velocity and longitudinal dispersion estimations provided by the GEM, while the non-equilibrium transport model achieves a better adjustment of most asymmetric and long-tailed BTCs. The assessment of karst underground flow properties from tracing tests at regional scale can aid design of groundwater management and protection strategies, particularly in large hydrogeological systems (i.e. transboundary carbonate aquifers) and/or in poorly investigated ones. 相似文献
13.
R. R. Yadav Dilip Kumar Jaiswal Hareesh Kumar Yadav Gulrana 《Environmental Earth Sciences》2012,65(3):849-859
A three-dimensional model for non-reactive solute transport in physically homogeneous subsurface porous media is presented.
The model involves solution of the advection-dispersion equation, which additionally considered temporally dependent dispersion.
The model also account for a uniform flow field, first-order decay which is inversely proportional to the dispersion coefficient
and retardation factor. Porous media with semi-infinite domain is considered. Initially, the space domain is not solute free.
Analytical solutions are obtained for uniform and varying pulse-type input source conditions. The governing solute transport
equation is solved analytically by employing Laplace transformation technique (LTT). The solutions are illustrated and the
behavior of solute transport may be observed for different values of retardation factor, for which simpler models that account
for solute adsorption through a retardation factor may yield a misleading assessment of solute transport in ‘‘hydrologically
sensitive’’ subsurface environments. 相似文献
14.
Comparison of numerical simulation of solute transport with observed experimental data in a silt loam subsoil 总被引：1，自引：0，他引：1
Solute transport experiments were conducted on loamy soils of north-eastern Iowa, USA, and the results were compared with
a numerical solution of a classical advection-dispersion transport model developed in this study. Flow experiments in the
laboratory on undisturbed soil columns showed a flow rate of water much higher than was estimated from the soil properties
and grain-size analysis data, suggesting preferential flow regime in the soil. In contrast, the relative concentration peaks
of Cl– and Br– in the effluent were only approximately 70% of those predicted by the classical advection-dispersion equation (ADE). In addition,
the experimental breakthrough curves (BTCs) showed greater tailings of these ions than the model solution. These observations
suggest a loss of solute mass during transport from the dynamic flowing regions to a stagnant, immobile water phase in the
soil matrix. Experiments in small disturbed soil columns showed that movement of Cl– and Br– is in good agreement with predictions of the classical ADE when the tracers are applied as a continuous source. However,
in the case of a pulse source, the BTCs of Cl– and Br– matched the model only in the ascending part of the curves. Such variation indicates greater retardation of these ions than
that of simulation, probably caused by the decrease in soil permeability due to cation exchange reactions in the soil involving
monovalent and divalent cation pairs such as K+–Ca2+ and K+–Mg2+. In addition, retardation occurred as a result of the continuous saturation of soil columns which seemed to have caused an
expansion of clay minerals, thus resulting in decreased soil permeability. In both the continuous and the pulse-source experiments,
K+ was not detected in the effluent samples, which seemed to have been lost in exchange reactions and adsorption.
Received: 20 November 1998 · Accepted: 19 July 1999 相似文献
15.
16.
Lianchuan Zhou Xiaomin Chen Xiaoliang Li Xinqiang Yang Daimin Huang Wen Xia Chen Cui 《Environmental Earth Sciences》2011,63(2):273-278
The characteristics of nitrate vertical transport in soils collected from Libo and Puding in Guizhou Province were studied
by simulating soil column in laboratory. The results were as follows: (1) Vertical transport velocity of nitrate decreased,
and the breakthrough curves (BTCs) of nitrate were more dispersed, in each horizon from surface layer to bottom layer in every
soil profile. As rocky desertification progressed, the BTCs experienced a gentle up and down trend, and tailing was more obvious.
(2) An analytical solute transport model (CXTFIT 2.0) was used to estimate nitrate dispersion coefficient (D) and average pore water velocity (V) from the observed BTCs. The results showed that CXTFIT 2.0 model was suitable in fitting the nitrate transport in these
soils. The dispersion coefficient was found to be a function of average pore water velocity. (3) The transport of nitrate
was mainly affected by the soil structural coefficient. As soil structural coefficient decreased, nitrate outflow was retarded,
and the peak concentration was reduced. Soil bulk density, organic matter, and clay also affected the vertical transport of
nitrate. Low bulk density, clay content, and high organic matter content were each associated with faster nitrate transport. 相似文献
17.
径向弥散是指溶质在径向流场下的迁移规律,被广泛用于描述含水层修复领域中污染物的迁移过程.然而,在现有描述径向弥散的模型中,往往忽略了井内混合效应对溶质径向弥散的影响.建立新的注入井附近溶质径向运移动力学模型,同时考虑井内混合效应与弥散度的尺度效应.采用Laplace变换推导该模型的半解析解,利用Stehfest数值逆变换获取溶质在实数空间的解.通过与不考虑混合效应的模型对比研究混合效应对溶质径向弥散的影响,并利用室内渗流槽中的溶质径向弥散实验数据验证模型的合理性与适用性.结果表明:混合效应和尺度效应对注水井附近溶质径向弥散有显著影响.具体地讲,井内的混合效应越显著,在井壁处及含水层中的穿透曲线越低,溶质浓度达到峰值所需时间越长,与不考虑混合效应模型的差异越明显;随尺度效应的增强,溶质提前穿透且扩散范围变大,溶质浓度达到峰值所需时间越长;与前人的模型相比,本研究模型能更好地模拟注水井附近的溶质径向弥散问题. 相似文献