共查询到20条相似文献，搜索用时 46 毫秒
1.
为探讨化学物质在土石混合介质中的运移过程和机理,采用饱和稳态流下的Cl-1混合置换试验,测定水流和溶质运移过程,分析土石混合介质的溶质穿透曲线特征及碎石组成和含量对运移过程的影响。选用CXTFIT2.1的平衡和物理非平衡对流弥散模型,对参数弥散系数D和滞留因子R进行反求。结果显示:不同土石比的D变异较大:0.258~22.31 cm2/h。R的波动范围为0.6~1.54;碎石含量影响土石介质的溶质运移过程表现为平均孔隙流速、弥散系数、弥散度均与土石比成负指数的幂函数关系。对碎石粒径与溶质运移参数进行相关分析发现,小粒径的碎石含量增加,则孔隙流速和弥散系数有减少的趋势,而大于10 mm的碎石有利于溶质的运移。通过土石介质的非反应性阴离子的混合置换试验研究,可以为非均一介质中化学物质运移提供参考。 相似文献
2.
Application of a newly developed column test device to analyze seawater transport in sandy soils 总被引：2，自引：1，他引：1
Xiaoqiang Dong Heesoo Woo Hisoo Park Junboum Park 《Environmental Earth Sciences》2013,70(5):2397-2404
To verify the applicability of the time-continuous electrical conductivity (EC) measurement in analyzing the contaminant movement in the subsurface, a new column test device employing non-destructive four-electrode sensors was developed. Using the seawater to create a simple one-dimensional steady-flow condition, laboratory transport experiments were conducted and the EC breakthrough curves at different distances were obtained. Comparison between the EC breakthrough curves obtained from the EC sensors and those from the effluent solute chemical analysis showed that the estimated resident concentration from the EC breakthrough curves are useful in understanding solute transport in soils. The pore water velocity and longitudinal dispersion coefficient estimated using the computer code, CXTFIT, were found to be slightly underestimated, especially at sensors located at smaller distances from the outlet boundary. Results showed that the developed column test device employing the four-electrode sensors proposed in this study provides a non-destructive, convenient, and inexpensive means of evaluating the seawater transporting in soils. 相似文献
3.
为研究江汉平原—大别山区过渡带黏性层状土中溶质迁移的规律,以保守性阴离子Br-为示踪剂,通过等温吸附试验、一维弥散试验、HYDRUS-1D软件模拟反演手段,研究了Br-在黏性层状土中的吸附参数、迁移规律,模拟反演其弥散参数。结果表明：（1）Freundlich模型和Langmuir模型均能较好的拟合吸附试验结果,随着土壤中黏粒比例的增大,土壤对Br-的饱和吸附量有所增加;（2）层状土中土壤质地与结构均会影响穿透曲线的形状,但一维饱和土柱中的弥散过程主要取决于含水介质系统中黏性颗粒的占比,黏粒的增加会对溶质运移产生阻碍作用;（3）通过HYDRUS-1D软件构建模型反演弥散参数,R2均大于0.991,拟合效果较好,分析发现层状土中无论土壤组成类型还是层厚及排序的影响,其本质都是改变了土壤的平均孔隙流速从而影响弥散作用,平均孔隙流速越小其弥散系数越小;（4）试验中粉质黏土弥散系数约为0.005～0.048 cm2/d,远远小于下部砂土弥散系数0.524～7.477 cm2/d,差值达到了至少两个数量级,表明研究区内厚层黏土为控制地层,会较大程度阻碍地下水中溶质运移,上部含水层中的污染物或有机... 相似文献
4.
波浪会促进海水中溶质向海底沉积物运移,但已有研究大多未考虑海床（海底沉积物）变形效应的影响。为揭示波浪作用下海床土变形对溶质运移过程的影响机制,构建了考虑海床土变形影响的溶质运移计算模型,对波浪作用下溶质向砂质海底沉积物中的运移过程进行模拟。结果表明:海床土变形会增大孔隙水流速,进而增大溶质纵向水动力弥散系数,增强溶质运移的机械弥散作用,促进溶质向沉积物中运移;考虑海床变形时的溶质最大纵向水动力弥散系数可达不考虑海床变形时的8.5倍,约为分子扩散系数的545倍;海床土剪切模量越小,土体变形效应越明显,对溶质运移过程的影响越大;海床土饱和度的降低,会进一步加速波浪作用下溶质向海底沉积物的运移过程。 相似文献
5.
Breakthrough curves (BTCs) of chloride displaced through columns of loessial soil aggregates of different sizes were measured under saturated steady flow conditions. The data were simulated using three conceptual models. Model I (CDE) assumed that all soil water was mobile and physical equilibrium existed in the system. Model II (two-region model) partitioned the soil water into mobile and immobile regions, and convective diffusive solute transport was limited to the mobile water region. Model III (two-flow region model) also divided the soil water into two regions based on their flow velocities, but both of the regions had a non-zero flow rate. Transfer of the chloride solute between the two soil water regions was assumed to occur at a rate proportional to the difference in solute concentration. The two unknown parameters in model I, three in model II, and four in model III were estimated by fitting the experimental data. The three models could well describe all the BTCs measured for columns packed with all the aggregate sizes at the low pore water velocity (0.68 cm/h); however, the values of the fitted parameters varied greatly. The Peclet numbers derived from both the two-region (model II) and two-flow region (model III) models behaved similarly and increased with increases in aggregate size. But the Peclet numbers derived from the convection dispersion equation (model I) were about two orders of magnitude greater than those derived from the other two models. The mobile water fraction obtained for the two-flow region model decreased with increases of aggregate size. The mass transfer coefficient decreased with an increase in pore water velocity due to the shorter residence time of the chloride solute in the soil columns. 相似文献
6.
Prioritization of soil conservation measures using erodibility indices as criteria in Sikkim (India)
Erodibility indices are important parameter that can be used to describe the intensity of the soil erosion problems causing environmental concerns. These indices are convenient to estimate the susceptibility to erosion where physical measurement is very difficult. Sikkim is one such state in India where measuring erosion is a tedious process due to its difficult and inaccessible terrain conditions. In the present study, spatial variation of susceptibility of erosion in East district of Sikkim was estimated by using indices such as clay ratio, dispersion ratio, mod clay ratio and critical level of soil organic matter. The result indicates soils in East district are mostly dominated by sand particles (40.5–81.06%) in majority of soil samples. The dispersion ratio values in most of the soils were >15% indicating very high vulnerability to erosion. The values of clay ratio (3.44–9), modified clay ratio (mean value of 6.9) and critical level of soil organic matter content (<5%) indicated high susceptibility to erosion. The trends of indices were generated by IDW interpolation method to understand the spatial variation of the susceptibility to erosion. The interpolated maps were overlaid on subwatershed maps to prioritize the subwatershed for planning treatment measures. 相似文献
7.
Organic matter in small mesopores in sediments and soils 总被引：1，自引：0，他引：1
The three-way correlation among organic matter concentrations, specific surface area and small mesopores observed for many soils and sediments led to the hypothesis that enclosure within the pores might explain the apparent protection of organic matter by minerals. We test this hypothesis by examining whether the bulk of organic matter resides within small mesopores. Pore volumes as a function of pore width were measured before and after organic matter removal, and the volume differences ascribed to organic matter filling of pores. Minor changes in small mesopore size distributions upon treatments such as centrifugation and muffling indicate the robustness of the mineral matrices that form these pores. We developed an additional method to assess organic matter densities using high-resolution pycnometry, and used these densities to convert pore volumes to organic matter contents. Although smaller mesopores are shown to have sufficient volumes to contain significant fractions of the total organic matter, only small fractions of total organic matter were found to reside in them. These results are consistent with preferential association between organic matter and aluminous clay particle edges, rather than the largely siliceous clay faces that contribute most surface area and form pore walls. While simple enclosure within smaller mesopores cannot, therefore, explain protection, network effects working at larger size scales may account for exclusion of digestive agents and hence organic matter protection. 相似文献
8.
Zinc availability in relation to selected soil properties in a crude oil polluted eutric tropofluvent 总被引：2，自引：2，他引：0
M. C. Chukwuma E. T. Eshett E. U. Onweremadu Ph.D. M. A. Okon 《International Journal of Environmental Science and Technology》2010,7(2):261-270
The study investigated zinc availability in relation to selected soil properties in a crude-oil-polluted Eutric Tropofluvent in Egbema, Southeastern Nigeria. For this purpose, three treatments have been applied: unpolluted soil, polluted without vegetation and polluted with vegetation with five replicates arranged in a randomized complete block design. Guided by transect sampling technique, soil sampling was carried out in June 2008. Soil samples were collected from the three different land units using soil auger at a depth of 0–20 cm. Standard laboratory procedures were adopted in analysing the soils. Soil generated data were subjected to analysis of variance and correlation analysis. Results showed highly significant variation (p = 0.01) in bulk density, porosity, silt: clay ratio, pH, effective cation exchange capacity, percent base saturation, total nitrogen, organic matter, available phosphorus, calcium: magnesium ratio and zinc. It was found that zinc was higher in crude oil polluted soils than in non-polluted soil and it was below critical limits. Zinc availability in relation to selected soil properties in the crude oil polluted soils indicated that clay and organic matter did not affect zinc availability, while pH and effective cation exchange capacity did. A study on zinc dynamics in crude-oil-polluted soils will certainly provide further information on the management of crude-oil-polluted soils since it is one of the key micronutrient for crop productivity. 相似文献
9.
我国西部多数煤矿区矿井水往往含有较多的生产污水,导致其氨氮含量较高,利用煤矿采空区充填矸石对矿井水进行预处理已成为矿井水及矸石资源化利用的重要措施。以神华神东煤炭集团公司保德矿矸石为充填介质、以矿井水中的氨氮为研究对象,通过模拟采空区的水文地质环境,开展柱模拟实验,结合CXTFIT 2.1软件,研究氨氮在充填矸石中的运移机制,这对于评价煤矿采空区充填矸石对矿井水的预处理效果具有重要意义。结果表明:达西流速3.12 cm/h、25℃时,Cl?在充填矸石中的运移可用CDE模型较好地表征(r2=0.999),较高的纵向弥散系数(D)、溶质分子扩散系数(Df)、机械弥散系数(Dh)和弥散度(λ)值与充填矸石较大粒径、较长运移距离有关,淋出液中总溶解性固体(TDS)和Cl?的质量浓度呈显著线性关系;双点位吸附溶质运移模型能够较好地表征氨氮的运移过程,氨氮的阻滞系数R为23.79,其在矸石上的平衡吸附点位仅占总吸附点位的46%,一级动力学吸附速率常数α为3.5×10?4 h?1;氨氮的孔隙流速及水动力弥散系数远低于Cl?的数值,这主要与高含量的黏土矿物高岭石对氨氮的吸附有关;在649 h的氨氮运移过程中,亚硝酸盐和硝酸盐氮以及pH值均无明显变化,实验中后期TDS稳定,这进一步证实氨氮在模拟的矸石柱运移过程中以对流、弥散迁移及吸附为主,生物转化作用可以忽略。研究结果可为评价我国煤矿采空区地下水库的水质预处理技术提供重要理论依据。 相似文献
10.
Secondary mercury dispersion haloes were detected and defined above sulphide mineralization by in-situ mercury in soil gas measurements. The meteorological factors controlling the concentration of mercury in soil gas were investigated by long-term experiments. Different mercury compounds in soils and rocks have been determined by a thermal destruction technique. In areas with sulphide mineralization, adsorbed mercury, HgCl2, HgS, HgSO4 and organically fixed mercury are the most important mercury compounds. The concentrations, transport and secondary formation of mercury and its compounds is controlled by: (1) the content of organic matter, Fe-oxides/hydroxides and clay minerals of the soils; and (2) the composition of the underlying rocks.The occurrence of mercury-sulphur compounds indicates the topographic influence on down-slope dispersion and the direction of inclination of the ore body. HgS and HgSO4 are the dominant mercury compounds in the ore; in the bedrock, mercury occurs mainly as adsorbed mercury. 相似文献
11.
Gravely calcareous soils cover approximately most of arid lands (in percent); however, the solute transport behavior in these soils remains a current issue. This research aimed at estimating and correlating the solute transport parameters in gravely calcareous soils as being affected by different land uses through the knowledge of the soil morphological, physical, and chemical properties. Four different land use sites were selected: irrigated trees and bare, range, and alluvial sediment lands. Solute transport parameters of soil pore water velocity (V), dispersion coefficient (D), and retardation factor (R) were estimated using bromide breakthrough curve tests for surface soil columns. In addition, field Brilliant Blue FCF dye tracing experiment was conducted to determine the maximum dimensional movements. Soil morphological analysis was able to explain the heterogeneity in the solute transport parameters. Conductive solute transport mechanism with V of 17.99 m/day was favored in a high continuous pore system observed under tree lands. Presence of high gravel and CaCO3 contents under range lands increased pore system tortuosity and thus increased D magnitude up to 1,339.88 cm2/day. Existence of thin surface crusts at both bare soils and alluvial sediments had considerably restricted V down to 1.46 m/day. Dye staining technique aided the explanation of the existing variations by providing visual evidence on the preferential flow paths and patterns governing the solute transport mechanism at each site. 相似文献
12.
A number of models have been established to simulate the behaviour of solute transport due to chemical pollution, both in croplands and groundwater systems. An approximate polynomial solution to convection–dispersion equation (CDE) based on boundary layer theory has been verified for the use to describe solute transport in semi-infinite systems such as soil column. However, previous studies have only proposed low order polynomial solutions such as parabolic and cubic polynomials. This paper presents a general polynomial boundary layer solution to CDE. Comparison with exact solution suggests the prediction accuracy of the boundary layer solution varies with the order of polynomial expression and soil transport parameters. The results show that prediction accuracy increases with increasing order up to parabolic or cubic polynomial function and with no distinct relationship between accuracy and order for higher order polynomials (\(n\geqslant 3\)). Comparison of two critical solute transport parameters (i.e., dispersion coefficient and retardation factor), estimated by the boundary layer solution and obtained by CXTFIT curve-fitting, shows a good agreement. The study shows that the general solution can determine the appropriate orders of polynomials for approximate CDE solutions that best describe solute concentration profiles and optimal solute transport parameters. Furthermore, the general polynomial solution to CDE provides a simple approach to solute transport problems, a criterion for choosing the right orders of polynomials for soils with different transport parameters. It is also a potential approach for estimating solute transport parameters of soils in the field. 相似文献
13.
Improper cultivation practices are seriously degrading native forest ecosystems in northern Iran. Hence, the objectives of this study are to compare selected soil properties, runoff amount, erosion and also introducing equations to predict the runoff and soil erosion in three types of land use (forest, garden and cultivated). A simple portable rainfall simulator has been set in 90 random points to create experimental rainfall. Result showed that changes in natural forest led to a significant clay, organic carbon of soil, total N and antecedent soil moisture decrease and sand, pH and bulk density increasing. The rainfall runoff experiments indicate that runoff content of the natural forest soils was 35 % and respectively 38.45 % higher than the garden and cultivated land soils .This result could be related to the higher antecedent soil moisture in natural forest compared with the other land uses. According to the obtained results, garden soil erosion and cultivated land was 1.351 and respectively 1.587 times higher than the forest. The correlation matrix revealed that runoff content was positively correlated with antecedent soil moisture, bulk density and silt, and negatively with soil organic carbon, total N and sand. Also, soil organic carbon, total N, clay and sand showed negative correlation with soil erosion, while there is a positive correlation between erosion and silt, bulk density, pH and antecedent soil moisture. The results of multiple linear regression showed that runoff in forest, garden and cultivated land can be predicted with correlation coefficient of 0.637, 0.547 and 0.624, respectively. The correlation coefficients of 0.798, 0.628 and 0.560 in equations indicate their moderate potential in simulating soil erosion. 相似文献
14.
15.
A careful selection of waste dumpsites, particularly hazardous ones, is very important for sustainable water resources management. Several laboratory experiments were carried out on the field samples to study adsorption capacity using p-dichlorobenzene (a solvent used in various industrial processes) as the test contaminant. The effect of parameters such as organic matter, clay, and iron and aluminium oxides, which are known to influence the soil adsorption capacity, are studied in the present work. Several soil samples from the Patancheru Industrial Area (Hyderabad, India) were collected and characterized. Only three soils, which had a comparatively high percentage of organic matter, clay, iron and aluminium oxide contents were used for the adsorption studies. The results clearly indicated a decrease in the adsorption capacity of the soils by as much as 75% when organic matter was removed. The other parameters such as clay and iron and aluminium oxides also play an important role in adsorption (57 and 39.8% reduction respectively). It was observed that out of the selected factors organic matter in the soils has the maximum effect regarding the adsorption of p-dichlorobenzene. Since the selected soils contain comparatively more organic matter, clay and iron and aluminium oxides in the selected industrial area, these can be used as sites for dumping hazardous waste, which can be further treated by methods like bioremediation. 相似文献
16.
C. Ramprasad L. Philip 《International Journal of Environmental Science and Technology》2017,14(4):853-866
Sorption of three surfactants and personal care products in four types of commonly occurring Indian soils was extensively studied. The soils used in the study were red soil, clay soil, compost soil and sandy soil as classified by American Society for Testing and Materials (ASTM). The three surfactants used in the study were representative of cationic, non-ionic and anionic surfactant groups. The sorption of surfactants followed the descending order: sodium dodecyl sulphate (SDS) > trimethyl amine (TMA) > propylene glycol (PG). The maximum adsorption capacity (Qmax) was obtained in compost soil (28.6 mg/g for SDS; 9.4 mg/g for TMA and 4 mg/g for PG). The rate of adsorption was the maximum in compost soil followed by clay and red soils, and minimum for sandy soils. It is found that the Freundlich model fits the isotherm data better than the Langmuir model. Freundlich coefficient (K f) increased as the organic content of soils increased. Desorption of target pollutants in tap water was 20–50% whereas acid desorbs 40–90% of target pollutants from soil matrix. It was also found that the adsorption and desorption were significantly affected by the presence of clay and organic matter. The results also indicate that surfactants and personal care products, especially TMA and PG, are highly mobile in sandy soil followed by red soil. Therefore, immobilization of target pollutants is most economical and effective in compost and clayey soils whereas for other type of soils the combination of physiochemical and biological process will be effective option for remediation. 相似文献
17.
颗粒运移对蒋家沟土体渗透性影响的试验研究 总被引：4，自引：0，他引：4
对蒋家沟流域泥石流源区两种分散性不同的土(G1土具有强分散性,G2土无分散性)进行室内土柱自滤试验,研究了土柱在常水头(水头为5 cm)渗流过程中颗粒运移对土柱不同部位渗透性的影响。入渗液采用了煮沸过的清水与浓度为1 g/L的悬浮液(悬浮颗粒的粒径范围为1.6～104.74μm)。在清水渗流过程中,两种土样的入口处土层渗透性随着时间而增大,出口处土层的渗透性先增大后减少。在悬浮液渗流过程中,两种土的各土层的渗透性都有下降趋势,但在入口处土层最为显著,G1土样下降了一个数量级以上,G2下降了近两个数量级,且G2土所用时间较G1土短,即G2土的渗透性减少速率更加明显;两土柱中渗透流量都有显著减少。研究表明:土体的分散性在颗粒运移过程逐渐占主导地位,即强分散性土自身颗粒的运移明显,能抵消一部分外来颗粒的积聚堵塞作用。从试验结束后土柱的外观图像观察也发现,入渗的悬浮颗粒在土柱的各个位置都有分布,但主要沉积在入口处,这与土柱各层渗透性的变化相吻合。此外,两种土流失的颗粒都只是集中于渗流的开始阶段,流失颗粒粒径范围集中在数微米至数十微米之间。 相似文献
18.
E. Dişli 《中国地球化学学报》2010,29(4):365-374
Laboratory batch sorption and column transport experiments were performed on heterogeneous alluvial soils with a wide range of physical characteristics from wells that are located in the region between Mogan Lake and Eymir Lake, Gölba??, Ankara. The mean values for the K d of Cu were found to be highest in clay (32550.350 L/kg) and lowest in loamy sand (18170.76 L/kg). The minimum and maximum sorption capacity values (mean values) for Zn were found to be in clay (10985.148 mg/kg) and in silty loam (8597.14 mg/kg) units, respectively. Similarly, the minimum and maximum values for Mn were found in loamy sand (4908.695 mg/kg) and clay (7587.391 mg/kg) units. The non-linear least-squares optimization code “CXTFIT” was used to determine transport parameter values by curve-fitting. The results of the column experiments demonstrate dispersivity values within the range of 0.024–1.13 cm for soil samples. 相似文献
19.
蒋家沟砾石土的特性及其对斜坡失稳的意义 总被引：1，自引：0，他引：1
云南蒋家沟是世界上著名的由降雨导致泥石流、浅层滑坡频发的沟谷之一。组成蒋家沟斜坡表层的砾石土具有孔隙度高、级配宽、不均匀系数大等特点,级配曲线为上凹型或双峰型,为内在不稳定性土。X射线衍射分析表明,粒径小于1 mm 的细粒部分主要由绿泥石和伊利石等黏土矿物及次生石英组成,黏土矿物会影响砾石土的物理力学性质。在环境电镜扫描中观测了砾石土的微观结构,发现一种特殊的“桥式”胶结结构,并在遇水条件下发生断裂,不仅降低了微弱黏聚力,而且土颗粒容易分离成粒径为数十微米的散微粒。这与砾石土中黏性部分具有高分散性有关。此外这些散微粒在自滤过程中会能发生运移,并在孔喉等处积聚而堵塞孔隙,会降低砾石土的渗透性以及有利于斜坡中暂态上层滞水的积聚。 相似文献
20.
为了探索中国西南喀斯特地区石漠化过程中土壤物理性质的变异规律,采用野外采样与实验室分析相结合的方法,对贵州省荔波县及普定县不同石漠化阶段典型土壤的物理参数进行了研究。结果表明：土壤有机质质量分数随石漠化程度的加深逐渐减小;非石漠化土壤重度仅为6.15 N/m^3,随着石漠化的发展,土壤重度逐渐增大,总孔隙度随之减小;石漠化的发展导致土壤黏粒含量升高;土壤水稳性团聚体质量分数及微团聚体的结构系数均随石漠化程度加深而减小;土壤有机质质量分数与重度、砂粒含量、大于5 mm团聚体含量及结构系数的相关系数分别为-0.921 2、0.827 7、0.907 2、0.899 3,均达到极显著水平。通过封山育林等措施增加喀斯特地区有机质积累可改善土壤物理性质,对防治石漠化具有重要意义。 相似文献