首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 828 毫秒
1.
The paper presents the results of study of the Sr, C, and O isotope compositions in Upper Jurassic carbonate rocks of the Baidar Valley and Demerdzhi Plateau in the Crimean Mountains represented by different facies of the carbonate platform at the northern active margin of the Tethys. The 87Sr/86Sr value in them varies from 0.70699 to 0.70728. Based on the Sr chemostratigraphic correlation, the age of massive and layered limestones in the western part of the Ai-Petri and Baidar yailas (pastures) is estimated as late Kimmeridgian–early Tithonian, whereas the age of flyschoids of the Baidar Valley are estimated as late Tithonian–early Berriasian. The nearly synchronous formation of carbonate breccias of the Baidar Valley and Demerdzhi Plateau in late Tithonian–early Berriasian is substantiated. A summary section of Upper Jurassic rocks is compiled based on the Sr chemostratigraphic data. It has been established that δ18O values in the studied carbonate sediments vary from–2.9 to 1.3‰ (V-PDB). At the same time, shallow-water sediments in the internal part and the edge of the Crimean carbonate platform are depleted in 18O (–2.9 to +0.1‰) relative to sediments on the slope and foothill (–0.5 to +1.3‰). It is demonstrated that δ13C values do not depend on the facies properties and decrease in younger carbonate sediments from 3–3.5‰ to 1–1.5‰ in line with the Late Jurassic general trend. The δ13C values obtained for the Crimean carbonate platform turned out to be 0.5–1‰ higher than the values typical of the deep-water marine setting at the western margin of the Tethys. These discrepancies are likely related to peculiarities of water circulation and high bioproductivity in marine waters of the northern Peri-Tethys.  相似文献   

2.
New data on Sr-and C-isotopic systematics of carbonate rocks from the Upper Riphean stratotype (Karatau Group of the southern Urals) are obtained for several southwestern sections of the Bashkirian meganticlinorium, which have not been studied before. The results obtained supplement the Sr-and C-isotopic information for the group upper horizons thus detailing chemostratigraphic characterization of the entire succession. Limestone and dolostone samples used to analyze the Sr isotope composition satisfy strict geochemical criteria of the isotopic system retentivity and have been subjected to preliminary treatment in ammonium acetate to remove secondary carbonate phases. Data on 255 samples of carbonate rocks (171 studied for the first time) show that δ13C value varies in the Karatau Group succession from ?2.8 to +5.9 ‰ V-PDB with several in-phase excursions from the general trend in all the sections studied in the area 90 × 130 km. The δ13C variation trend demarcates several levels in the carbonate succession of the Karatau Group suitable for objectives of regional stratigraphy and for C-isotope chemostratigraphic subdivision of the Upper Riphean. The results of Sr isotopic analysis of 121 samples (51 unstudied before) from the Karatau Group imply that rocks in its lower part (the Katav Formation and basal horizon of the Inzer Formation) experienced considerable secondary alterations, while limestones and dolostones of the overlying interval of the group are frequently unaltered. In the “best” samples satisfying geochemical criteria of the isotopic system retentivity, the 87Sr/86Sr initial ratio increases from 0.70521–0.70532 in the lower Inzer deposits to 0.70611 in the upper Min’yar carbonates, decreasing to <0.70600 near the top of the latter. Above the regional hiatus separating the Min’yar and Uk formation, this ratio grows from 0.70533 to 0.70605–0.70609 in the limestone succession of the last formation.  相似文献   

3.
The role of silicate and carbonate weathering in contributing to the major cation and Sr isotope geochemistry of the headwaters of the Ganga-Ghaghara-Indus system is investigated from the available data. The contributions from silicate weathering are determined from the composition of granites/ gneisses, soil profiles developed from them and from the chemistry of rivers flowing predominantly through silicate terrains. The chemistry of Precambrian carbonate outcrops of the Lesser Himalaya provided the data base to assess the supply from carbonate weathering. Mass balance calculations indicate that on an average ∼ 77% (Na + K) and ∼ 17% (Ca + Mg) in these rivers is of silicate origin. The silicate Sr component in these waters average ∼40% and in most cases it exceeds the carbonate Sr. The observations that (i) the87Sr/86Sr and Sr/Ca in the granites/gneisses bracket the values measured in the head waters; (ii) there is a strong positive correlation between87Sr/86Sr of the rivers and the silicate derived cations in them, suggest that silicate weathering is a major source for the highly radiogenic Sr isotope composition of these source waters. The generally low87Sr/86Sr (< 0.720) and Sr/Ca (∼ 0.2 nM/ μM) in the Precambrian carbonate outcrops rules them out as a major source of Sr and87Sr/86Sr in the headwaters on a basin-wide scale, however, the high87Sr/86Sr (∼ 0.85) in a few of these carbonates suggests that they can be important for particular streams. The analysis of87Sr/86Sr and Ca/Sr data of the source waters show that they diverge from a low87Sr/86Sr and low Ca/Sr end member. The high Ca/Sr of the Precambrian carbonates precludes them from being this end member, other possible candidates being Tethyan carbonates and Sr rich evaporite phases such as gypsum and celestite. The results of this study should find application in estimating the present-day silicate and carbonate weathering rates in the Himalaya and associated CO2 consumption rates and their global significance.  相似文献   

4.
锶同位素已经成为全球海平面变化、造山运动、古气候和古环境等全球地质事件研究与对比的有效工具之一。本文以四川盆地东部地区早中三叠世蒸发岩的野外剖面和钻孔岩心为主要研究对象,测试了碳酸盐岩、硫酸盐岩和石盐岩的锶同位素组成,并建立了相应的锶同位素演化曲线。研究结果显示,碳酸盐岩的87Sr/86Sr值平均为0.707 895,硬石膏岩的87Sr/86Sr值平均为0.708 174,石盐岩的87Sr/86Sr值平均为0.708 177,同时碳酸盐岩的87Sr/86Sr值从早三叠世的0.707 413快速增加到中三叠世早期的0.708 515,而后呈现下降趋势。从总体上看,这些87Sr/86Sr值与全球早中三叠世同期的87Sr/86Sr值数据接近,说明四川盆地东部地区早中三叠世钾盐的物质来源大部分为海水,并沉积于海相沉积环境,同时由于火山...  相似文献   

5.
Abundant veins filled by calcite, celestite and pyrite were found in the core of a 719 m deep borehole drilled in Oftringen near Olten, located in the north-western Molasse basin, close to the thrust of the Folded Jura. Host rocks are calcareous marl, argillaceous limestone and limestone of the Dogger and Malm. The δ18O values of vein calcite are lower than in host rock carbonate and, together with microthermometric data from fluid inclusions in vein calcite, indicate precipitation from a seawater-dominated fluid at average temperatures of 56–68°C. Such temperatures were reached at the time of maximum burial of the sedimentary pile in the late Miocene. The depth profile of δ13C and 87Sr/86Sr values and Sr content of both whole-rock carbonate and vein calcite show marked trends towards negative δ13C, high 87Sr/86Sr, and low Sr content in the uppermost 50–150 m of the Jurassic profile (upper Oxfordian). The 87Sr/86Sr of vein minerals is generally higher than that of host rock carbonate, up to very high values corresponding to Burdigalian seawater (Upper Marine Molasse, Miocene), which represents the last marine incursion in the region. No evidence for internally derived radiogenic Sr (clay minerals) has been found and so an external source is required. S and O isotope composition of vein celestite and pyrite can be explained by bacterial reduction of Miocene seawater sulphate. The available data set suggests the vein mineralization precipitated from descending Burdigalian seawater and not from a fluid originating in the underlying Triassic evaporites.  相似文献   

6.
We measured both mass-dependent isotope fractionation of δ88Sr (88Sr/86Sr) and radiogenic isotopic variation of Sr (87Sr/86Sr) for the Neoproterozoic Doushantuo Formation that deposited as a cap carbonate immediately above the Marinoan-related Nantuo Tillite. The δ88Sr and 87Sr/86Sr compositions showed three remarkable characteristics: (1) high radiogenic 87Sr/86Sr values and gradual decrease in the 87Sr/86Sr ratios, (2) anomalously low δ88Sr values at the lower part cap carbonate, and (3) a clear correlation between 87Sr/86Sr and δ88Sr values. These isotopic signatures can be explained by assuming an extreme greenhouse condition after the Marinoan glaciation. Surface seawater, mixed with a large amount of freshwater from continental crusts with high 87Sr/86Sr and lighter δ88Sr ratios, was formed during the extreme global warming after the glacial event. High atmospheric CO2 content caused sudden precipitation of cap carbonate from the surface seawater with high 87Sr/86Sr and lighter δ88Sr ratios. Subsequently, the mixing of the underlying seawater, with unradiogenic Sr isotope compositions and normal δ88Sr ratios, probably caused gradual decrease of the 87Sr/86Sr ratios of the seawater and deposition of carbonate with normal δ88Sr ratios. The combination of 87Sr/86Sr and δ88Sr isotope systematics gives us new insights on the surface evolution after the Snowball Earth.  相似文献   

7.
Strontium isotope compositions of ancient sulphate deposits not only provide chemostratigraphic information but also offer insight into the system in which the evaporites precipitated. Primary gypsum from two Middle Miocene (Badenian) sections in southern Poland shows steadily higher 87Sr/86Sr ratios than those expected from a marine‐derived formation. The ratios are interpreted as the result of increasing inflow into the basin at the time of gypsum precipitation. Palaeogeographic reconstructions suggest that riverine runoff sources were situated in the West and East European platforms (to the north and east, respectively) and the Carpathians (to the south), which are mostly composed of Mesozoic sedimentary rocks; their dissolution cannot be responsible for the higher 87Sr/86Sr ratios recorded. We conclude that Archaean and Palaeoproterozoic igneous and supracrustal rocks of the Ukrainian Shield were the source of the higher 87Sr/86Sr ratios recorded in the Badenian primary gypsum. A distinctive decreasing trend of 87Sr/86Sr ratios from western Ukraine to southern Poland is explained by a consistent direction of brine inflow during gypsum crystallization (typical cyclonic circulation controlled by the Coriolis effect).  相似文献   

8.
Carbonate rocks and natural waters exhibit a wide range in the concentration and isotopic composition of strontium. This wide range and the quantifiable covariation of these parameters can provide diagnostic tools for understanding processes of fluid-rock interaction. Careful consideration of the uncertainties associated with trace element partitioning, sample heterogeneity and fluid-rock interaction mechanisms is required to advance the application of the trace element and isotope geochemistry of strontium to studies of diagenesis, goundwater evolution, ancient seawater chemistry and isotope stratigraphy. A principal uncertainty involved in the application of Sr concentration variations to carbonate systems is the large range of experimental and empirical results for trace element partitioning of Sr between mineral and solution. This variation may be a function of precipitation rate, mineral stoichiometry, crystal growth mechanism, fluid composition and temperature. Calcite and dolomite in ancient limestones commonly have significantly lower Sr concentrations (20–70 p.p.m.) than would be expected from published trace element distribution coefficient values and Sr/Ca ratios of most modern sedimentary pore waters. This discrepancy probably reflects the uncertainties associated with determining distribution coefficient values. As techniques improve for the analytical measurement and theoretical modelling of Sr concentration and isotopic variations, the petrological analysis of carbonate samples becomes increasingly important. The presence of even small percentages of non-carbonate phases with high Rb concentrations and high 87 Sr86 Sr values, such as clay minerals, can have significant effects on the measured 87 Sr/86 Sr values of carbonate rocks, due to the decay of 87Rb to 87 Sr. For example, a Permian marine limestone with 50 p.p.m. Sr and 1 p.p.m. Rb will have a present-day 87 Sr/86 Sr value that is >2 × 10?4 higher than its original value. This difference is an order of magnitude greater than the analytical uncertainty, and illustrates the importance of assessing the need for and accuracy of such corrections. A quantitative evaluation of the effects of water-rock interaction on Sr concentrations and isotope compositions in carbonates strengthens the application of these geochemical tracers. Geochemical modelling that combines the use of trace elements and isotopes can be used to distinguish between different mechanisms of water-rock interaction, including diffusive and advective transport of diagenetic constituents in meteoric pore fluids during the recrystallization of carbonate minerals. Quantitative modelling may also be used to construct diagnostic fluid-rock interaction trends that are independent of distribution coefficient values, and to distinguish between mixing of mineral end-members and fluid-rock interaction.  相似文献   

9.
Groundwater quality in karst regions is largely controlled by natural processes and anthropogenic activities. Over the past 10?years, dissolved Sr and its radiogenic isotope, 87Sr/86Sr, were widely used to trace the sources of solutes in groundwater. However, there is little research about hydrogeochemistry and Sr isotopic compositions of the karst groundwater in Chongqing karst area. In this paper, thirty-five representative karst groundwater samples were collected from different aquifers (limestone and dolomite) and various land use types. Hydrochemical types of karst groundwater in Chongqing were mainly of the Ca-HCO3 type or Ca(Mg)-HCO3 type. The dissolved Sr concentrations of the studied groundwater ranged from 0.57 to 15.06???mmol/L, and the 87Sr/86Sr varied from 0.70751 to 0.71627. The groundwater samples from different aquifers and land use types showed distinctive dissolved Sr concentrations and 87Sr/86Sr. The very positive relationship between Ca/Sr and Mg/Sr in dolomite and limestone aquifers suggests that Ca, Mg and Sr element come mainly from the release of carbonate rock under the groundwater?Crock?CCO2 gas interaction. According to the 87Sr/86Sr ratio, the Sr element in karst groundwater in Chongqing was controlled by the weathering of limestone, dolomite and silicate rock (allogenic water in a non-karst area). The relationship 87Sr/86Sr versus Sr2+/[K+?+?Na+] shows that the anthropogenic inputs also obviously contribute to the Sr contents. The research results show that the karst groundwater in Chongqing is facing serious crisis of water quality, and needs to be protected further.  相似文献   

10.
Condensed levels are often characterized by reworked fossils that may lead to incorrect age assessments. Strontium‐isotope stratigraphy is an important chronostratigraphic tool that can be used to verify the biostratigraphic information from condensed beds. This paper describes a study of the 87Sr/86Sr isotope ratios of 56 belemnite samples collected from 28 stratigraphic sections of the boundary between the Upper Member of the Gavilán Formation and the Zegrí Formation (Pliensbachian, Subbetic Zone). The petrographic and geochemical data (δ18O, δ13C, concentrations of Fe, Mn and Mg, and the Sr/Mn ratio) suggest that the belemnites have preserved their original marine geochemical composition. After plotting the samples in diagrams of 87Sr/86Sr values against time according to their biostratigraphic age, four different groups (A, B, C and D) were obtained with respect to the reference curve. In groups A and B, the age deduced from the Sr‐isotope ratio is in total or partial agreement, respectively, with the biostratigraphic age; therefore the 87Sr/86Sr ratio is a good method for the dating, correlation and assessment of biostratigraphic results. In groups C and D, the SIS age and the biostratigraphic age do not coincide. A graphic procedure is presented as a suitable methodology to constrain the age of the samples showing an SIS age that differs from the relative age deduced (by biostratigraphy or stratigraphic correlation) for the bed they were collected in. These situations are interpreted as being the result of reworking of the belemnites (group C) or ammonites (group D) that are included in condensed levels. These condensed levels formed during the maximum flooding event that led to the drowning of the Gavilán carbonate platform. The methodology supplied in this paper represents a valuable tool in identifying reworking processes, improving correlation and constraining biochronostratigraphic results. The values of 87Sr/86Sr represent a new contribution to the data set of 87Sr/86Sr ratios for the Pliensbachian.  相似文献   

11.
The isotopic composition of strontium in surface water in continental basins is determined primarily by the geology of the basin and to a lesser extent by climatic conditions. Consequently, the 87Sr/86Sr ratios of brines in such basins can change only as a result of changes in the geology or climate. This principle of isotope geology was studied by analysis of a suite of non-marine carbonate rocks from the Flagstaff Formation (Palaeocene-Eocene) of Utah. The samples were collected from a section in Fairview Canyon of Sanpete County. They include both limestone and dolomite and were selected to have low non-carbonate residues. The concentrations of strontium in calcites averages 383 ± 128 p.p.m., while those of dolomites increase from 354 ± 74 p.p.m. in the lower 43 m of section to a maximum of 2259 p.p.m. higher up. The increase in the strontium content of dolomite is interpreted as evidence for a change from steady-state to progressively more evaporitic conditions. Two dolomites have isotopic compositions of oxygen expressed as δ18O = -2.75‰ (relative to the PDB standard) and are enriched in 18O relative to two calcites whose average δ18O value is -9.9‰. The 87Sr/86Sr ratios of the carbonate minerals range from 0.70890 to 0.71260. These values are clearly greater than the 87Sr/86Sr ratio of marine carbonates of Early Eocene age which is 0.70744. The variation of the 87Sr/86Sr ratio in this section of the Flagstaff Formation is real and reflects the occurrence of geological events which changed the isotopic composition of Sr entering Lake Flagstaff. The non-carbonate fractions of six carbonate rocks and one sandstone fit a straight line on the strontium mixing diagram in co-ordinates of initial 87Sr/86Sr and 1/Sr concentration. These results suggest that the isotopic composition of strontium in Lake Flagstaff may have been modulated by periodic input of volcanogenic detritus of felsic composition.  相似文献   

12.
Lake water, river water, and groundwater from the Lake Qinghai catchment in the northeastern Tibetan Plateau, China have been analyzed and the results demonstrate that the chemical components and 87Sr/86Sr ratios of the waters are strictly constrained by the age and rock types of the tributaries, especially for groundwater. Dissolved ions in the Lake Qinghai catchment are derived from carbonate weathering and part from silicate sources. The chemistry of Buha River water, the largest tributary within the catchment, underlain by the late Paleozoic marine limestone and sandstones, constrains carbonate-dominated compositions of the lake water, being buffered by the waters from the other tributaries and probably by groundwater. The variation of 87Sr/86Sr ratios with cation concentrations places constraint on the Sr-isotopic compositions of the main subcatchments surrounding Lake Qinghai. The relative significance of river-water sources from different tributaries (possibly groundwater as well) in controlling the Sr distribution in Lake Qinghai provides the potential to link the influence of hydrological processes to past biological and physical parameters in the lake. The potential role of groundwater input in the water budget and chemistry of the lake emphasizes the need to further understand hydrogeological processes within the Lake Qinghai system.  相似文献   

13.
Nd and Sr isotope analyses are presented for gangue mineral samples from the giant carbonate-hosted Navan Zn–Pb deposit, Ireland, and for rocks from which Navan metals may have been derived. Analysis of gangue minerals spanning the Navan paragenetic sequence reveals systematic evolution in the composition of the mineralising fluid. Early fluid represented by replacive dolomite exhibits the lowest initial 87Sr/86Sr ratio (0.7083–0.7086), closest to that of the host limestone and to Lower Carboniferous seawater, and the highest 143Nd/144Nd ratio (0.51161–0.51176). Later generations of dolomite, barite and calcite, which encompass sulphide precipitation, have higher initial 87Sr/86Sr ratios (maximum 0.7105) and lower initial 143Nd/144Nd ratios (minimum 0.51157). All samples have initial Nd isotope ratios that are too low to have been acquired only from the host limestone. Drill core samples of presumed Ordovician volcanic and sedimentary rocks from beneath the Navan orebody have 143Nd/144Nd and 87Sr/86Sr ratios at the time of mineralisation of 0.51184–0.51217 and 0.7086–0.7138, respectively. The data are interpreted to indicate mixing of sulphide-rich, limestone-buffered brine, with a metal-bearing hydrothermal fluid, which had passed through sub-Carboniferous rocks, consistent with published fluid inclusion and S isotope data. The 143Nd/144Nd ratio of this basement-derived fluid is too low to have been imparted by flow through the Devonian Old Red Sandstone, as required in models of regional fluid flow in response to Hercynian uplift. Irrespective of whether such regional fluid flow occurred, the hydrothermal Nd must have been derived from sub-Devonian rocks. These conclusions broadly support the hydrothermal convection cell model in which brines, ultimately of surface origin, penetrated to a depth of several kilometres, leaching metals from the rocks through which they passed. The data also support increasing depth of penetration of convection cells with time. Metals were subsequently precipitated in carbonate rocks at sites of mixing with cooler, sulphide-rich fluids. However, comparison of the Navan hydrothermal gangue Nd–Sr isotope data with data from Lower Palaeozoic rocks strongly suggests that the latter cannot alone account for the “basement” signature. As the Navan deposit lies immediately north of the Iapetus Suture, this suggests that the Laurentian margin includes Precambrian basement.  相似文献   

14.
We present strontium (Sr) isotope ratios that, unlike traditional 87Sr/86Sr data, are not normalized to a fixed 88Sr/86Sr ratio of 8.375209 (defined as δ88/86Sr = 0 relative to NIST SRM 987). Instead, we correct for isotope fractionation during mass spectrometry with a 87Sr-84Sr double spike. This technique yields two independent ratios for 87Sr/86Sr and 88Sr/86Sr that are reported as (87Sr/86Sr∗) and (δ88/86Sr), respectively. The difference between the traditional radiogenic (87Sr/86Sr normalized to 88Sr/86Sr = 8.375209) and the new 87Sr/86Sr∗ values reflect natural mass-dependent isotope fractionation. In order to constrain glacial/interglacial changes in the marine Sr budget we compare the isotope composition of modern seawater ((87Sr/86Sr∗, δ88/86Sr)Seawater) and modern marine biogenic carbonates ((87Sr/86Sr∗, δ88/86Sr)Carbonates) with the corresponding values of river waters ((87Sr/86Sr∗, δ88/86Sr)River) and hydrothermal solutions ((87Sr/86Sr∗, δ88/86Sr)HydEnd) in a triple isotope plot. The measured (87Sr/86Sr∗, δ88/86Sr)River values of selected rivers that together account for ∼18% of the global Sr discharge yield a Sr flux-weighted mean of (0.7114(8), 0.315(8)‰). The average (87Sr/86Sr∗, δ88/86Sr)HydEnd values for hydrothermal solutions from the Atlantic Ocean are (0.7045(5), 0.27(3)‰). In contrast, the (87Sr/86Sr∗, δ88/86Sr)Carbonates values representing the marine Sr output are (0.70926(2), 0.21(2)‰). We estimate the modern Sr isotope composition of the sources at (0.7106(8), 0.310(8)‰). The difference between the estimated (87Sr/86Sr∗, δ88/86Sr)input and (87Sr/86Sr∗, δ88/86Sr)output values reflects isotope disequilibrium with respect to Sr inputs and outputs. In contrast to the modern ocean, isotope equilibrium between inputs and outputs during the last glacial maximum (10-30 ka before present) can be explained by invoking three times higher Sr inputs from a uniquely “glacial” source: weathering of shelf carbonates exposed at low sea levels. Our data are also consistent with the “weathering peak” hypothesis that invokes enhanced Sr inputs resulting from weathering of post-glacial exposure of abundant fine-grained material.  相似文献   

15.
《Applied Geochemistry》1988,3(6):591-600
The Sr isotope composition of formation waters is a sensitive indicator of diagenetic processes in the host sediments, mixing processes between different bodies of water, and the connectivity of hydrological systems. The87Sr/86Sr ratio of present seawater is constant worldwife, while formation waters in hydrocarbon reservoirs have various values, depending on the aforementioned effects, in most cases different from modern seawater. This forms the basis of anatural tracer technique for seawater injection projects, involving characterization of the87Sr/86Sr ratios and Sr contents of formation waters in the reservoir before injection commences, followed by monitoring of these parameters in the produced water as injection proceeds. This method is best suited to reservoirs in which the formation waters have low Sr concentrations and87Sr/86Sr ratios much higher or lower than seawater. Available data for reservoir formation waters suggest that breakthrough recognition could be expected at <10% seawater in many sandstone reservoirs, while the method would be less sensitive in carbonate reservoir or situations where the formation waters had interacted with evaporites, as the associated waters tend to have high Sr contents. In heterogeneous but well-mapped reservoirs, it may be possible to obtain information about flow paths/mechanismsbefore breakthrough. Combination with other chemical and isotopic tracers creates a very powerful tool, the Sr method acting as a safeguard should the batch of water containing the conventional tracers be overtaken by subsequently injected seawater. The Sr method could also be used for injection projects that were begun without the addition of tracers. A natural analogue of a water injection process is found in the Jurassic Lincolnshire Limestone aquifer in England, where rapidly moving fresh meteoric water mixes progressively with an older saline formation water. The87Sr/86Sr data enable quantitative modelling of this mixing process. The infiltrating fresh water becomes progressively modified by dissolution of detrital carbonate and calcite cement in the limestone, with depth becoming increasingly dominated by Sr derived from the more soluble detrital components. The saline formation water contains water molecules of meteoric origin and an87Sr/86Sr ratio much higher than Jurassic seawater or marine carbonate; the solute content has been influence by interaction of the water with non-carbonate phases.  相似文献   

16.
The in situ measurement of Sr isotopes in carbonates by MC‐ICP‐MS is limited by the availability of suitable microanalytical reference materials (RMs), which match the samples of interest. Whereas several well‐characterised carbonate reference materials for Sr mass fractions > 1000 µg g?1 are available, there is a lack of well‐characterised carbonate microanalytical RMs with lower Sr mass fractions. Here, we present a new synthetic carbonate nanopowder RM with a Sr mass fraction of ca. 500 µg g?1 suitable for microanalytical Sr isotope research (‘NanoSr’). NanoSr was analysed by both solution‐based and in situ techniques. Element mass fractions were determined using EPMA (Ca mass fraction), as well as laser ablation and solution ICP‐MS in different laboratories. The 87Sr/86Sr ratio was determined by well‐established bulk methods for Sr isotope measurements and is 0.70756 ± 0.00003 (2s). The Sr isotope microhomogeneity of the material was determined by LA‐MC‐ICP‐MS, which resulted in 87Sr/86Sr ratios of 0.70753 ± 0.00007 (2s) and 0.70757 ± 0.00006 (2s), respectively, in agreement with the solution data within uncertainties. Thus, this new reference material is well suited to monitor and correct microanalytical Sr isotope measurements of low‐Sr, low‐REE carbonate samples. NanoSr is available from the corresponding author.  相似文献   

17.
《Applied Geochemistry》1998,13(4):463-475
Strontium isotope ratios were measured on 13 rock, 18 leachate and 28 pore-water samples from the Milk River aquifer, the confining argillaceous formations, and the glacial till mantling the recharge area. Strontium isotope ratios (87Sr/86Sr) of pore waters from the aquifer, confining units, and the glacial till ranged from 0.7069 to 0.7082. The 87Sr/86Sr ratios in aquifer pore waters decrease with increasing distance from the aquifer recharge area, and this is interpreted to be the result of mixing and water–rock interaction within the aquifer.The solute composition of the recharging groundwater is modified by the local lithology, causing distinct geochemical patterns along different flow paths within the aquifer. Whole-rock 87Sr/86Sr ratios indicate that the shales and till are generally more radiogenic than the aquifer sandstone. The authigenic carbonate cements and rock-forming minerals comprising the major lithologic units had little apparent influence on the pore-water Sr chemistry. Carbonate cement leachates from the till and the aquifer sandstone are more radiogenic than those from the confining shale formations. Feldspar separates from the aquifer sandstone have relatively radiogenic Sr isotope ratios, whereas bentonites from the Milk River and Colorado Shale Formations have whole-rock and leachate Sr isotope ratios that are relatively unradiogenic. Ratios of most Milk River aquifer pore waters are lower than those of any leachates or whole rocks analyzed, except the bentonites.The 87Sr/86Sr ratios of exchangeable Sr in the bentonites are similar to ratios found in the more evolved pore waters. Simple rock–water interaction models calculated for the whole-rock, leachate, and exchangeable-ion/pore-water pairs indicate that ion exchange with bentonite clays within the Milk River and Colorado Shale Formations appears to influence the isotopic evolution of the pore-water Sr in each of these units.  相似文献   

18.
The Kyrpy Group of the East European platform is regarded by tradition as correlative with the Lower Riphean Burzyan Group of the Bashkirian meganticlinorium in the southern Urals. Age and correlation of the Kyrpy Group remain problematic, however, because of a limited geochronological information and controversial interpretation of paleontological materials. Data of C-and Sr-isotope chemostratigraphy contribute much to the problem solution. In the Kyrpy Group of the Kama-Belaya aulacogen, the Kaltasy Formation carbonates 1300 to 2400 m thick (boreholes 133 and 203 of the Azino-Pal’nikovo and Bedryazh areas) show 87Sr/86Sr ratios ranging around 0.7040 and narrow diapasons of δ13C values: about 0.5‰ (V-PDB) in shallow-water facies and-2.0‰ (V-PDB) in sediments of deeper origin. Despite the facies dependence of carbon isotope composition, δ13C variations not greater than ±1.0‰ are depicted in chemostratigraphic profiles of carbonate rocks characterizing separate stratigraphic intervals up to 800 m thick in the above borehole sections. Low 87Sr/86Sr ratios and almost invariant δ13C values in carbonates of the Kaltasy Formation are obviously contrasting with these parameters in the Middle and Upper Riphean deposits, being comparable with isotopic characteristics of the Lower Riphean sediments (Mesoproterozoic deposits older than 1300 Ma). Consequently, the results obtained evidence in favor of the Early Riphean age of the Kaltasy Formation and the Kyrpy Group as a whole.  相似文献   

19.
现有公布的数据显示,海水87Sr/86Sr值在中三叠世安尼期较为平稳,有别于早三叠世因环境导致的动荡变化,为二叠纪末生物大灭绝之后生物复苏的加速期,而罗平生物群就是该加速期的标志性生物群。本文研究了含罗平生物群层位标准剖面-大凹子剖面上连续沉积的26件碳酸盐岩样品的锶同位素组成与演化,用于了解含罗平生物群层位沉积海水锶同位素的变化趋势。结果显示:(1)碳酸盐岩中Sr平均值大于2000×10-6,主要来自于文石和海洋成岩作用;(2)低Mn和Mn/Sr0.4说明:87Sr/86Sr数据在很大程度上能代表同时期海水中的87Sr/86Sr比值;(3)这些样品的87Sr/86Sr值变化在0.707969～0.708253,平均值为0.708025,锶同位素比值变化曲线呈小幅度的起伏波动,其值明显大于同时期欧洲等地公布的数据,但同华南其他地区公布的数据具有相似性,推测含罗平生物群层位锶同位素组成仅代表区域事件,受印支运动影响。  相似文献   

20.
The Pb-Sr-O-C isotope compositions of calcite marbles of the Derbina Formation, exposed in the northwestern part of the Derbina block of the East Sayan, were studied. Rocks of the Derbina Formation were metamorphosed under high-temperature amphibolite facies conditions. The carbonate constituent of marbles contains (ppm) 15–130 Mn, 130–160 Fe, 0.008–0.039 Rb, 645–2190 Sr, 0.565–0.894 U, and 0.288–1.42 Pb. These concentrations are similar to those in modern carbonate sediments. The values of δ13C in marbles of the Derbina Formation range from–0.6 to +1.4‰ PDB; the values of δ18O range from 21.5 to 28.6‰ SMOW. The 87Sr/86Sr ratio values in the two least altered rocks, which meet geochemical criteria of the Rb-Sr system preservation in high-grade carbonate rocks, are 0.70804 and 0.70829. The protolith ages of marbles determined using Sr and C chemostratigraphy lie within the interval of 560–530 Ma, which is regarded as the period of carbonate sedimentation. The slope of the straight line on the 206Pb/204Pb–207Pb/204Pb diagram (n = 9, MSWD = 19) constructed on the basis of the data points of bulk carbonate constituents of all samples studied and those representing leachate steps of one of them in 0.5N HBr yields Late Vendian age (556 ± 31 (2σ) Ma. Taking into account the data on Sr and C isotope systematics of Derbina marbles, this age is regarded as the age of early diagenesis of carbonate sediments close to the age of sedimentation. Thus, metacarbonate rocks of the Derbina Formation preserved the pre-metamorphic chemostratigraphic and isotope-geochronological information. The age obtained testifies that formation of the carbonate cover of the Derbina block occurred in the Late Vendian. At the end of the Cambrian, carbonate deposits were metamorphosed during the Early Caledonian tectonic event in the southeastern part of the Central Asian Fold Belt.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号