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1.
Effluent from tailings impoundments of sulfide mine is an important environmental problem. The oxidation of sulfide minerals in tailings impoundments and consequent release of acid and contaminants, including heavy metals and arsenic, to tailings pore-water can last for decades to centuries. Pollution of water bodies including surface water and groundwater occurs when infiltration of precipitation is unhindered, bottom liners are absent and no drainage collection is installed. So there is a great need to develop reliable modeling techniques for characterizing geochemical interactions taking place within the tailings and predicting potential future environmental hazard which favor further prevention and remediation of the acidic mine drainage （AMD）. In this paper, a comprehensive dynamic model for tailings-water interaction was established on the basis of considering the coupling and feedback among many factors and processes such as sulfide oxidation, gangue dissolution, oxygen diffusion, water flow and mass transport,  相似文献   

2.
The generation of acid rock drainage (ARD) is a biogeochemical process that causes severe ecological impacts, threatening human health worldwide. Microbes involved in acid drainage reactions are generally considered autotrophic but heterotrophic and mixotrophic microorganisms have often been identified at ARD sites. This raises questions about the role of organic matter naturally present at these sites, such as mature hydrocarbons, in promoting the microbial processes underpinning ARD generation. To investigate this, aerobic microcosm experiments were carried out using ARD samples collected at a well-characterised site in northern England (Mam Tor, Derbyshire). Organic analyses indicated the presence of substantial amounts of mature, petroleum-derived hydrocarbons and microbial analyses indicated that the sediment hosts acidophilic bacteria with the capability of degrading petroleum-derived compounds. However, the aerobic microcosm experiments indicated that these petroleum-derived hydrocarbons were not used by the bacterial community and, therefore, are not involved in the reactions that ultimately lead to ARD generation. These observations support a primary role for autotrophs in ARD generation.  相似文献   

3.
《中国地球化学学报》2006,25(B08):84-85
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4.
《Applied Geochemistry》2000,15(9):1331-1343
This paper discusses the solid phase Fe–S geochemistry of a reactive barrier at the Nickel Rim mine site (Ontario, Canada). The barrier, designed to treat groundwater contaminated by acid mine drainage, is composed of leaf and municipal compost and wood chips. This study shows that S is accumulating in the organic material as primarily acid volatile sulfides, at concentrations up to 195 μmol S g−1 d.w. (0.63 wt% S) in a zone of preferential flow. Pyrite and/or S0 account for only a small fraction of the total reduced inorganic S, as oxidants are probably present at only low concentrations in the barrier system. The results of the solid phase analyses, the formation of disordered mackinawite (Fe1+xS) on piezometer tubing, and thermodynamic calculations indicate that the precipitation of poorly crystalline Fe monosulfides is the primary sink for Fe and S in the barrier. Siderite (FeCO3) formation is proposed as an additional Fe sink in areas of high Fe flux. Minor accumulations of acid-soluble, organically-bound S in the reactive barrier occur in zones of low aqueous Fe concentration. After 23 months of operation, the average rate of S accumulation at the up-gradient edge of the barrier is calculated to be 87 μmol S g−1 a−1 (d.w. organic material), or 47 mol S m−2 a−1 in the direction of groundwater flow. Solid phase analyses from samples collected 3 and 14 months after installation indicate that the S accumulation rate declined by a factor of 3 over that time period.  相似文献   

5.
Field and laboratory work was carded out to investigate the chemistry and ecotoxicity of stream water affected by acid mine drainage in a tributary catchment of the Pearl River in subtropical China during a major flood event that corresponded to a return period of 100 years occurred in the study area. The results indicate that stream water was affected by acid mine drainage from the Dabaoshan Mine at least to a distance of 25 km downstream of the mine water discharge point. It appears that sulfide-H^＋ from the waste rock dumps was readily available for discharging and the amount of H^＋ being transported outwards depended on the volume of out-flowing waters. However, there was a lag time for the discharge of the metals. This may be attributed to the slower release of metals, relative to H^＋, because it might take more time for the dissolution of heavy metal-bearing compounds. Fe, Zn and Al were the major metals of potential toxicity contained in the AMD-affected stream water, followed by Mn, Cu, Pb, As, Cd and Ni. Acute toxicity tests show that the AMD-affected stream water at 3.5 km downstream of the discharge point was highly toxic to the test organisms.  相似文献   

6.
In this study, geochemical characteristics of acid mine drainage （AMD） and its sediments from the Malan and Sitai coalmines, Shanxi Province, China, were investigated. Many analytical approaches such as IC, ICP-MS, XRD, XRF, and modeling calculation of hydrogeochemistry using PHREEQCI software were employed. The AMD is characterized by higher concentrations of iron and sulfate, a low pH, and elevated concentrations of a wide variety of heavy metals. The results of modeling calculation by PHREEQCI software demonstrate the metals in AMD are present mainly as Me^n＋ and MeSO4^n-2 species. The sediments of AMD are composed mainly of iron-beating minerals such as goethite and schwertmannite, which are controlled by pH, Fe and SO4^2- concentrations. The schwertmannite mineral has been found for the first time in China.  相似文献   

7.
《Applied Geochemistry》2002,17(5):633-648
Acid rock drainage (ARD) solution from an abandoned ore mine (pH 2.7, SO2−4 concentration 411 mmol/l, Fe concentration 93.5 mmol/l) was investigated by photon correlation spectroscopy, centrifugation, filtration, ultrafiltration, scanning electron microscopy, ICP–MS, AAS, ion chromatography, TOC analysis, and extended X-ray absorption fine structure (EXAFS) spectroscopy. A colloid concentration of ⩾1 g/l was found. The prevailing particle size was <5 nm. Iron, As and Pb were the metal constituents of the colloidal particles. The most probable mineralogical composition of the particles is a mixture of hydronium jarosite and schwertmannite. A small amount of a relatively coarse precipitate was formed in the ARD solution during the months after sampling. The colloid particles are obviously an intermediate in the precipitate formation process. The results suggest that the arsenate is bound to the colloids by the formation of a bidentate binuclear inner-sphere surface complex. However, the transformation of the colloidal material to the more aggregated long-term precipitate results in the incorporation of the arsenate into the interior of the Fe hydroxy sulfate crystal structures. Lead seems to occur as anglesite.  相似文献   

8.
Two drainage experiments were carried out to identify the hydraulic parameters of a quartz sand by using inverse modelling. Our results, based on sensitivity and error analyses, show that (i) water content measurements are essential to estimate the parameters of the van Genuchten–Mualem retention curve, (ii) the saturated conductivity (Ks) has a low sensitivity to pressure data and is not sensitive to other measures (water content and measured outflow), (iii) the inverse approach can be verified by comparing the simulated outflow to the measured one. To cite this article: H. Beydoun, F. Lehmann, C. R. Geoscience 338 (2006).  相似文献   

9.
Naturally acidic drainage associated with pyritic black shale has been observed in many locations in the Yukon Territory. While not necessarily linked to known mineral deposits, most of these natural acid rock drainage occurrences show elevated dissolved concentrations of trace elements, especially zinc, nickel, copper, cadmium and arsenic. Based on field observations, microbial investigation, chemical analyses and geochemical modeling, the fate and transport of potentially deleterious elements at two natural acid drainage occurrences with slightly different settings are examined. The Macintosh Creek is a small, acidic stream （pH 2.98-3.40）, 2 km long, located in the Macmillan Pass area of east-central Yukon amidst known sedimentary exhalative massive sulfide mineralization but remains undisturbed by exploration activities. Its trace metal content is apparently derived from groundwater discharges, which gave as much as 5.0, 2.5, 0.7, 0.13 and 0.03 mg/L ofZn, Ni, Cu and As, respectively. Interaction and sorption reactions with algal mats, biofilms and iron oxyhydroxides appear to be the dominant mechanisms attenuating aqueous contaminant transport along the stream. Cryogenic precipitation further consolidates the ferricrete formation and reduces the mobility of the sorbed metals. The tributaries of the Engineering Creek along the Dempster Highway in northern Yukon drain through a series of dolomite, phyllite, argillite, limestone, black shale, sandstone and conglomerate with no known concentration of mineralization. In this area, the water chemistry fully reflects the local geology with acidic streams invariably associated with black shale occurrences. Groundwater seeps in the headwaters area of the km-180 Creek completely enclosed in black shale gave pH 3.0 and as much as 148, 39, 2.9 and 9.1 mg/L of Zn, Ni, Cu and As, respectively. Sorption with iron oxyhydroxide and organic matter appear to dominate the attenuation of contaminant transport along the stream. However, once entered into carbonate-dominated terrains, secondary carbonate minerals exercise additional geochemical control on the local water chemistry as a result of neutralization.  相似文献   

10.
The Pb(II) and Ni(II) biosorption of a fungal biomass isolated from mine drainage of metal-processing industries in Balya (Bal?kesir province, Turkey) was optimized using a response surface methodology by altering parameters such as pH, initial metal concentration, contact time and biosorbent dosage. This strain was shown to be highly similar to Penicillium sp. Furthermore, zeta potential measurements and Fourier transform infrared spectroscopy were performed to understand the adsorption mechanism. A Box–Behnken design with 29 experiments was used to evaluate the interactions between independent variables. The results showed that the fungal biomass isolated from the metal mine drainage could have a significant environmental impact through the biosorption of Pb(II) and Ni(II) in waters polluted with heavy metals, particularly in the drainage from metal mines. The maximum removal values were 76 and 47 % at pH 4.5 for both Pb(II) and Ni(II), with 123 and 33 mg/L initial metal concentrations, 65 and 89 min contact times and 0.2 and 1.6 g/L biosorbent, respectively.  相似文献   

11.
Ag, Pb, Sn and Zn ores have been intensively mined and processed at Cerro Rico de Potosí, Bolivia since 1545. Acid mine drainage (AMD) and mineral processing plant effluent are prime sources of water contamination in the headwaters of the Upper Rio Pilcomayo watershed. Streams receiving AMD drainage from the slopes of Cerro Rico and surrounding landscapes were sampled during the dry (July–August 2006) and wet (March 2007) seasons of one water-year. In-stream waters contained total metal concentrations of up to 16 mg/L As, 4.9 mg/L Cd, 0.97 mg/L Co, 1,100 mg/L Fe, 110 mg/L Mn, 4.1 mg/L Pb, and 1,500 mg/L Zn with pH ranging from 2.8 to 9.5. AMD-impacted streams contained elevated concentrations of the same major ecotoxic constituents present in AMD discharges at concentrations orders of magnitude greater than in those streams unimpacted by AMD. Many of the AMD impacted water bodies are more degraded than class “D” of the Bolivian receiving water body criteria, rendering them unfit for domestic or agricultural use. Natural attenuation is insufficient to render waters safe for use, however, some of these waters are currently being utilized for irrigation and livestock watering. The data indicate that historic and current mining activities have transformed these key natural resources into potential human and environmental health hazards.  相似文献   

12.
Sediment cores were collected from the upstream of the Neath Canal in South Wales and characterized for their mineral compositions and iron speciation in order to understand the influence of sedimentary properties on the contaminants of heavy metals. The sediments in the canal have been polluted by ocherous precipitate with heavy metals such as arsenic since a major mine water discharge in spring 1993. The sediment core was obtained just from the discharge point in the canal and distinguished into three layers in the field regarding to their physical properties including visible color, sediment particle composition and dryness. X-ray diffraction （XRD） and M6ssbauer spectroscopy revealed vertical variations of minerals and iron species in depth of the sediment profile. The upper layer, reddish-brown, is wet muddy precipitant and is very fine in particle size, consisting mainly of iron oxide and hydroxide. Arsenic is rich in this layer; probably the sorption on iron oxide surface is the main mechanism. The middle layer, 22.0-27.0 cm, is soft deposit in a yellow color and contains sheet silicate, calcite and goethite. The lower part below 27.0 cm is gray to dark gray in color and contains quartz, pyrite, coal particles that are much more similar to normal aquatic sediment. The upper two layers in brown and yellow colors as newly precipitated mud from AMD contain high concentrations of As, Ni under oxic conditions. The lower part as the old canal sediments under reducing conditions contains high Cu and Zn. Chromium is enriched in the limited part of the low layer, just beneath the boundary between the middle and low parts of the sedimentary column, where the redox conditions shifted from oxic to anoxic. It is clear that the distribution of these heavy metals is closely associated with the redox condition reflected in the iron speciation. Thus different treatments are necessary for each layer of the sediment since different mineral and geochemical properties of the sediment will give different impacts on the heavy metals.  相似文献   

13.
Compared to the regional groundwater, at B. S. nickel mine （W. Australia）, the groundwater in the vicinity of the tailings storage facility displays low pH （minimum 2.9, mean 4.95）, high electrical conductivity, and elevated concentrations of A1 and heavy metals （Co, Mn, Zn, Ni and Cu）. Contours of heavy metal concentrations and pH values show that the acid drainage, which was developed from sulfide tailings and confined to the tailings storage facility, is concentrated at the northwest comer of the facility, moving northwest-southeastward across the northeast part of the facility. There has been no significant rainfall to contribute to the groundwater recharge in the study region, thus groundwater fluctuations around the facility are from infiltration through the evaporation pond and tailing slurry in the facility. Infiltration waters continuously leach the tailing pile which contains sulfide minerals including pyrrhotite, pentlandite, and trace amounts of chalcopyrite, pyrite, etc. Oxidation of these minerals led to the formation of acidic water and this acidic water assists the dissolution of sulfide minerals, which are transported into the groundwater. Therefore, it is no surprise that the heavy metals tend to move down the tailing profile, as opposed to being concentrated on the upper part of the regional weathered profile （by adsorption of weathered clay that normally resides on the surface）. Quarterly monitoring （from November 2003 to August 2004） of the contaminated groundwater showed median pH values about 5, groundwater levels and heavy metal concentrations remained stable except for May 2004, when both decreased simultaneously.  相似文献   

14.
Yang  Song-Yue  Chang  Che-Hao  Hsu  Chih-Tsung  Wu  Shiang-Jen 《Natural Hazards》2022,111(3):2297-2315

Coupled 1D–2D hydrodynamic models are widely utilized in flood hazard mapping. Previous studies adopted conceptual hydrological models or 1D hydrodynamic models to evaluate the impact of drainage density on river flow. However, the drainage density affects not only river flow, but also the flooded area and location. Therefore, this work adopts the 1D–2D model SOBEK to investigate the impact of drainage density on river flow. The uncertainty of drainage density in flood hazard mapping is assessed by a designed case and a real case, Yanshuixi Drainage in Tainan, Taiwan. Analytical results indicate that under the same return period rainfall, reduction in tributary drainages in a model (indicating a lower drainage density) results in an underestimate of the flooded area in tributary drainages. This underestimate causes higher peak discharges and total volume of discharges in the drainages, leading to flooding in certain downstream reaches, thereby overestimating the flooded area. The uncertainty of drainage density decreases with increased rainfall. We suggest that modeling flood hazard mapping with low return period rainfalls requires tributary drainages. For extreme rainfall events, a lower drainage density could be selected, but the drainage density of local key areas should be raised.

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15.
Half a millennium mercury production at Idrija is reflected in increased mercury contents in all environmental segments. The bulk of roasting residues from the middle of the 19th century to 1977 was discharged directly into the Idrijca River, and the material was carried at high waters to the Soca River and farther into the Adriatic Sea. It has been estimated that 45500 tons of mercury were emitted into the environment during the operating period of the mine, which ceased production in 1994. In the lower reaches of the Idrijca the riverine deposits with high mercury contents have been, and will be in the future a source of mercury polluted sediment. Stream sediments were monitored at the same locations along the Idrijca and Soca rivers （70 kin） every 5 years since 1991 （1991-2005）. Grain size distribution was determined by dry sieving and fractions for geochemical analysis were prepared （〈0.04 and 〈0.125 mm）. Soils on river terraces were sampled at 5 localities in the lower course of Idrijca. At two locations of the terrace profiles the samples of averaged meadow forage and plantain （Plantago lanceolata） were collected within a 50-meters radius. We found that there was no decrease in mercury concentration in active river sediments during the last 20 years. Upstream from the Idrija Town the mercury concentrations in active river sediments vary from 1 to 10 mg/kg （average 3.3 mg/kg）. From Idrija to Spodnja Idrija the mercury concentrations increase extremely and vary greatly （32-4,121 mg/kg, the average is 734 mg/kg）. From Spodnja ldrija to the Idrijca-Soca confluence is the average 218 mg/kg, and 57 mg/kg downstream in the Soca River sediments.  相似文献   

16.
In this study, a digital elevation model was used for hydrological study/watershed management, topography, geology, tectonic geomorphology, and morphometric analysis. Geographical information system provides a specialized set of tools for the analysis of topography, watersheds, and drainage networks that enables to interpret the tectonic activities of an area. The drainage system maps of Zagros Mountains in southwest Iran have been produced using multi-temporal datasets between 1950 and 2001 to establish the changes between geomorphic signatures and geomorphic aspect during time and to correlate them with recent neo-tectonics. This paper discusses the role of drainage for interpreting the scenario of the tectonic processes as one of important signatures. The study shows variation in drainage network derived from topography maps. Thus, changes in drainage pattern, stream length, stream gradient, and the number of segment drainage order from 1950 to 2001 indicate that Zagros Mountain has been subjected to recent neo-tectonic processes and emphasized to be a newly active zone.  相似文献   

17.
《Applied Geochemistry》1995,10(6):705-713
The project began in an attempt to develop technology to ameliorate acid mine drainage (AMD) problems occurring at the Sherman Iron Ore Mine of Temagami, Ontario, Canada. A series of laboratory experiments were conducted to evaluate the effectiveness of an electrochemical approach to ameliorate AMD. An electrochemical cell was constructed using a block of massive sulphide-graphite rock from the mine site as the cathode, scrap iron as the sacrificial anode, and acidic leachate collected from the mine site as the electrolyte. The cell was effective at raising the pH of ≈ 41.0 L of leachate from 3.0 to a maintenance value of ≈ 5.6. This result was accompanied by a significant decrease in redox potential from > 650 to < 300 mV. Furthermore, iron sulphate precipitate formed, with a concomitant lowering of Al, Cd, Co, Cu and Ni solution concentrations. The study clearly demonstrated the proposed electrochemical approach to be a technically feasible and practical method of ameliorating AMD.  相似文献   

18.
Acid mine drainage （AMD） has been recognized as a major environmental pollution problem over past decades. This pollutant effluent is complex and is characterized by elevated concentrations of iron and sulfate, low pH, and high concentrations of a wide variety of metals depending on the host rock geology. Massive inadvertent discharges from acid mines have given rise to dramatic cases of ecological damage. These events indicate an improved understanding of the mechanism controlling metal transport to the river is important, since the aquatic ecology will be affected, to some degree, dependent on the phase （dissolved or particulate） in which the metal is transported. In this study, polluted water samples were collected along the Hengshi River near the Dabaoshan mine, Guangdong, China, in April 2005. The concentrations of dissolved Cu, Zn, Cd and Pb have been determined using ICP-MS and the chemical speciation of those metals in suspended particles was examined using BCR methods and SEM/EDX mineralogical analysis. Combining these two sets of data, the intention was to develop geochemical concepts, which explain the behavior of Cu, Zn, Cd and Pb in particle-water interactions of heavy metals in AMD. The results show that the dissolved heavy metals exhibited non-conservative behavior in the Hengshi River. The dissolved and particulate Cu, Zn, Cd and Pb have the similar spatial distribution, which decreased gradually along the river except in the lower reaches because of the absorption-desorption between dissolved and particulate phases. Although the metal concentrations in both phases were elevated, dissolved metals were dominant and had the maximum concentrations in the low pH region.  相似文献   

19.
Research on the origin of acid mine drainage(AMD)is helpful to find a way to avoid and remediate AMD and its pollution.AMD is mainly from pyrite(FeS2)-containing minerals(such as coal and ore)during mining process and reproduction,and is common and danger…  相似文献   

20.
Sediment cores were collected from the upstream of the Neath Canal in South Wales and characterized for their mineral compositions and iron speciation in order to understand the influence of sedimentary properties on the contaminants of heavy metals. The …  相似文献   

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