where k (M− 2 s− 1) can be determined from the
in the pH range 2 to 5, from 5 to 40 °C and 0.01 to 1 M.The effect of pH and ionic strength on the reaction suggest that the rates are due to
where H2A = H2CrO4, HA = HCrO4, H2B = H2SO3 and HB = HSO3. The overall rate expression over the investigated pH range can be determined from
k=kH2A–H2B(αH2A)(αH2B)2+kHA–H2B(αHA)(αH2B)2+kH2A–HB(αH2A)(αHB)2
with kH2A−H2B = 5.0 × 107, kHA–H2B = 1.5 × 106 and kH2A–HB = 6.7 × 107.Fe(III) in the range 1.5 to 20 μM exerts a small catalytic effect on the reaction and significantly lowers the initial concentration of Cr(VI) compared to the nominal value. Contrary to Fe(III), formaldehyde (20 to 200 μM) reacts with S(IV) to form the hydroxymethanesulfonate adduct (CH2OHSO3), which does not react with Cr(VI). Major cations Mg2+ and some minor elements such as Ba2+ and Cu2+ did not affect the rates. The application of this rate law to environmental conditions suggest that this reaction may have a role in acidic solutions (aerosols and fog droplets). This reaction becomes more important in the presence of high Fe(III) and low HMS concentrations, contributing to affect the atmospheric transport of chromium species and the distribution of redox species of chromium, which reach surface water from atmospheric depositions.  相似文献   

9.
Experimental Study on Crescent Waves Diffracted by A Circular Cylinder     
Kai Yan  Liang-duo Shen  Jin-wei Shang  Liang Ma  Zhi-li Zou 《中国海洋工程》2018,32(5):624-632
Crescent waves often observed on the sea surface are unusual wave pattern induced by the instability of Stokes wave. The paper presents the experimental results of the wave field around a circular cylinder generated by the diffraction of crescent wave in order to examine the difference of diffracted crescent waves from the commonly-used diffracted Stokes waves. The results show that with the existence of the cylinder, the crescent wave pattern can still get fully developed, and with the presence of this type of wave pattern, the symmetry breaking of the wave amplitude distribution occurs and there are extra wave components at the frequencies of 0.5ω0, 1.5ω0 and 2.5ω0 (ω0 is the frequency of Stokes waves) appearing in the wave amplitude spectrum.  相似文献   

10.
Anomalously low alkenone temperatures caused by lateral particle and sediment transport in the Malvinas Current region, western Argentine Basin     
Albert Benthien  Peter J. Müller 《Deep Sea Research Part I: Oceanographic Research Papers》2000,47(12):373
We analysed the alkenone unsaturation ratio (UK′37) in 87 surface sediment samples from the western South Atlantic (5°N–50°S) in order to evaluate its applicability as a paleotemperature tool for this part of the ocean. The measured UK′37 ratios were converted into temperature using the global core-top calibration of Müller et al. (1998) and compared with annual mean atlas sea-surface temperatures (SSTs) of overlying surface waters. The results reveal a close correspondence (<1.5°C) between atlas and alkenone temperatures for the Western Tropical Atlantic and the Brazil Current region north of 32°S, but deviating low alkenone temperatures by −2° to −6°C are found in the regions of the Brazil–Malvinas Confluence (35–39°S) and the Malvinas Current (41–48°S). From the oceanographic evidence these low UK′37 values cannot be explained by preferential alkenone production below the mixed layer or during the cold season. Higher nutrient availability and algal growth rates are also unlikely causes. Instead, our results imply that lateral displacement of suspended particles and sediments, caused by strong surface and bottom currents, benthic storms, and downslope processes is responsible for the deviating UK′37 temperatures. In this way, particles and sediments carrying a cold water UK′37 signal of coastal or southern origin are transported northward and offshore into areas with warmer surface waters. In the northern Argentine Basin the depth between displaced and unaffected sediments appears to coincide with the boundary between the northward flowing Lower Circumpolar Deep Water (LCDW) and the southward flowing North Atlantic Deep Water (NADW) at about 4000 m.  相似文献   

11.
A review of the analyses of ocean wave groups     
J.R. Medina  R.T. Hudspeth 《Coastal Engineering》1990,14(6)
The most common parameters and functions used to characterize wave groups in linear seas are reviewed and interrelated in a unified manner. A three-axes representation of run lengths is used to characterize wave groups using exponential and Markov chain approximations. A relationship between four parameters (Qp, Qe, κ2, and ρ2) and the correlation coefficient between consecutive wave heights [rHH(1)] is demonstrated. The wave-height function method is reviewed in some detail in order to relate the run length theory with envelope theories. The theoretical estimates used to demonstrate the relationships between the various parameters must be considered as only first-order trends to parameter estimates computed from real wave data due to the statistical variability in these estimates when computed from real wave data.  相似文献   

12.
Improving estuarine net flux estimates for dissolved cadmium export at the annual timescale: Application to the Gironde Estuary     
Aymeric Dabrin  Jrg Schfer  Grard Blanc  Emilie Strady  Matthieu Masson  Ccile Bossy  Sabine Castelle  Naïg Girardot  Alexandra Coynel 《Estuarine, Coastal and Shelf Science》2009,84(4):429-439
Dissolved Cd (CdD) concentrations along the salinity gradient were measured in surface water of the Gironde Estuary during 15 cruises (2001–2007), covering a wide range of contrasting situations in terms of hydrology, turbidity and season. During all situations dissolved Cd concentrations displayed maximum values in the mid-salinity range, reflecting Cd addition by chloride-induced desorption and complexation. The daily net CdD fluxes from the Gironde Estuary to the coastal ocean were estimated using Boyle's method. Extrapolating CdD concentrations in the high salinity range to the freshwater end member using a theoretical dilution line produced 15 theoretical Cd concentrations (CdD0), each representative of one distinct situation. The obtained CdD0 concentrations were relatively similar (201 ± 28 ng L−1) when freshwater discharge Q was >500 m3 s−1 (508 ≤ Q ≤ 2600 m3 s−1), but were highly variable (340 ± 80 ng L−1; 247–490 ng L−1) for low discharge situations (169 ≤ Q ≤ 368 m3 s−1). The respective daily CdD net fluxes were 5–39 kg day−1, mainly depending on freshwater discharge. As this observation invalidates the existing method of estimating annual CdD net fluxes, we proposed an empirical model, using representative CdD0 values and daily freshwater discharges for the 2001–2007 period. Subsequent integration produced reliable CdD net flux estimates for the Gironde Estuary at the annual timescale that ranged between 3.8–5.0 t a−1 in 2005 and 6.0–7.2 t a−1 in 2004, depending on freshwater discharge. Comparing CdD net fluxes with the incoming CdD fluxes suggested that the annual net CdD addition in the Gironde Estuary ranged from 3.5 to 6.7 t a−1, without any clear temporal trend during the past seven years. The annual CdD net fluxes did not show a clearly decreasing trend in spite of an overall decrease by a factor 6 in Cd gross fluxes during the past decade. Furthermore, in six years out of seven (except 2003), the annual CdD net fluxes even exceeded river borne total (dissolved + particulate) gross Cd fluxes into the estuary. These observations were attributed to progressive Cd desorption from both suspended particles and bottom sediment during various sedimentation–resuspension cycles induced by tidal currents and/or continuous dredging (navigation channel) and diverse intra-estuarine sources (wet deposition, urban sources, and agriculture). Provided that gross fluxes remain stable over time, dissolved Cd exportation from the Gironde Estuary to the coastal ocean may remain at the present level for the coming decade and the estuarine sedimentary Cd stock is forecast to decrease slowly.  相似文献   

13.
14.
Seasonal variations of alkenones and U37 in the Chesapeake Bay water column     
Jennifer L. Mercer  Meixun Zhao  Steven M. Colman   《Estuarine, Coastal and Shelf Science》2005,63(4):675-682
Alkenone unsaturation indices (UK37 and UK′37) have long been used as proxies for surface water temperature in the open ocean. Recent studies have suggested that in other marine environments, variables other than temperature may affect both the production of alkenones and the values of the indices. Here, we present the results of a reconnaissance field study in which alkenones were extracted from particulate matter filtered from the water column in Chesapeake Bay during 2000 and 2001. A multivariate analysis shows a strong positive correlation between UK37 (and UK′37) values and temperature, and a significant negative correlation between UK37 (and UK′37) values and nitrate concentrations. However, temperature and nitrate concentrations also co-vary significantly. The temperature vs. UK37 relationships (UK37=0.018 (T)−0.162, R2=0.84, UK′37=0.013 (T)−0.04, R2=0.80) have lower slopes than the open-ocean equations of Prahl et al. [1988. Further evaluation of long-chain alkenones as indicators of paleoceanographic conditions. Geochimica et Cosmochimica Acta 52, 2303–2310] and Müller et al. [1998. Calibration of the alkenone paleotemperature index UK′37 based on core-tops from the eastern South Atlantic and the global ocean (60°N–60°S). Geochimica et Cosmochimica Acta 62, 1757–1772], but are similar to the relationships found in controlled studies with elevated nutrient levels and higher nitrate:phosphate (N:P) ratios. This implies that high nutrient levels in Chesapeake Bay have either lowered the UK37 vs. temperature slope, or nutrient levels are the main controller of the UK37 index. In addition, particularly high abundances (>5% of total C37 alkenones) of the tetra-unsaturated ketone, C37:4, were found when water temperatures reached 25 °C or higher, thus posing further questions about the controls on alkenone production as well as the biochemical roles of alkenones.  相似文献   

15.
Effects of bed perturbation and velocity asymmetry on ripple initiation: wave-flume experiments     
Tomohiro Sekiguchi  Tsuguo Sunamura 《Coastal Engineering》2004,50(4):231
Laboratory experiments using a wave flume were designed to examine the threshold condition for ripple formation under asymmetrical oscillatory flows on an artificially roughened bed. Three types of sand beds were prepared in the experiments: they were flat, notched, and notch-mounded beds with bed roughness increasing in this order. The beds were constructed with three kinds of well-sorted sand with similar density, but different diameters. Data analyses were made using the two dimensionless parameters: the mobility number, M, a simplified form of the Shields number, and the Ursell number, U, a surrogate for asymmetry of flow field. The result confirmed that the threshold for ripple initiation is decreased with increasing bed perturbation and that as the bed perturbation increases, the dependency of this threshold on the flow asymmetry becomes less and finally null for the notch-mounded bed. This relationship is quantified by the following equations: M=17−14.5e−0.03U on the flat bed, M=5.0−2.5e−0.1U for the notched bed, and M=2.5 for the notch-mounded bed. A comparison between the previous field data and the present laboratory findings indicates that the threshold in the notch-mounded bed experiment, M=2.5, seems to provide a critical condition for rippling in the natural environment.  相似文献   

16.
On the planing of a flat plate at high Froude numbers in a two-dimensional case     
Y.K. Chung  H.H. Chun   《Ocean Engineering》2008,35(7):646-652
We seek the solution of the planing of a flat plate at high Froude numbers by a perturbation procedure. The angle of attack of the plate is assumed to vary with the speed of the plate in the present study. A harmonic function K is introduced for the solution of the first-order disturbance potential which becomes the Green function in the limiting case when the Froude number tends to infinity. We get the solution of the first-order potential from Green's theorem applied to K and the first-order potential. Then we obtain the asymptotic solutions of the angle of attack α, lift L and drag D as follows:
where α1. Here W, LW, and U are the weight of the plate per unit width, wetted length, and speed of the plate, respectively.  相似文献   

17.
Ship hull characteristics from surface wake synthetic aperture radar (SAR) imagery     
Owen M. Griffin  Henry T. Wang  Guy A. Meadows 《Ocean Engineering》1996,23(5):363-383
Improved data collection and processing technologies along with the use of high resolution spectral techniques soon will make it possible to obtain estimates of the Kelvin wave amplitude function A(θ), ship speed U, and ship heading α from synthetic aperture radar images of ship wakes. This paper presents a series of methods for deriving additional hull characteristics such as the length L, volume V, and offsets ζ(x,z) from this spectral and surface wave information. The first method estimates the ship length by taking the Fourier transform of the slope amplitude function |kA|. The remaining estimates make use of the hull inversion code developed at the University of Michigan by Wu in 1991. The accuracy of the hull offsets predicted by the code is first determined for various options for solving the linear inversion problem. In this case, both the magnitude and phase of A(θ) are known in addition to the hull draft H. Since the draft is not often known a priori, the accuracy of the code is determined next by predicting the volume of the ship for an approximate though plausible input value of H. Finally, the accuracy of the non-linear inversion problem of obtaining offsets along the entire hull is investigated when only the magnitude but not the phase of A(θ) is known.  相似文献   

18.
Determination of gas bubble fractionation rates in the deep ocean by laser Raman spectroscopy     
S.N. White  P.G. Brewer  E.T. Peltzer 《Marine Chemistry》2006,99(1-4):12
A new deep-sea laser Raman spectrometer (DORISS—Deep Ocean Raman In Situ Spectrometer) is used to observe the preferential dissolution of CO2 into seawater from a 50%–50% CO2–N2 gas mixture in a set of experiments that test a proposed method of CO2 sequestration in the deep ocean. In a first set of experiments performed at 300 m depth, an open-bottomed 1000 cm3 cube was used to contain the gas mixture; and in a second set of experiments a 2.5 cm3 funnel was used to hold a bubble of the gas mixture in front of the sampling optic. By observing the changing ratios of the CO2 and N2 Raman bands we were able to determine the gas flux and the mass transfer coefficient at 300 m depth and compare them to theoretical calculations for air–sea gas exchange. Although each experiment had a different configuration, comparable results were obtained. As expected, the ratio of CO2 to N2 drops off at an exponential rate as CO2 is preferentially dissolved in seawater. In fitting the data with theoretical gas flux calculations, the boundary layer thickness was determined to be  42 μm for the gas cube, and  165 μm for the gas funnel reflecting different boundary layer turbulence. The mass transfer coefficients for CO2 are kL = 2.82 × 10− 5 m/s for the gas cube experiment, and kL = 7.98 × 10− 6 m/s for the gas funnel experiment.  相似文献   

19.
A 3-D model based on Navier–Stokes equations for regular and irregular water wave propagation     
Bin Li   《Ocean Engineering》2008,35(17-18):1842-1853
A spatial fixed σ-coordinate is used to transform the Navier–Stokes equations from the sea bed to the still water level. In the fixed σ-coordinate system only a very small number of vertical grid points are required for the numerical model. The time step for using the spatial fixed σ-coordinate is efficiently larger than that of using a time dependent σ-coordinate, as there is substantial truncation error involved in the time dependent σ-coordinate transformation. There is no need to carry out the σ-coordinate transformation at each time step, which can reduce computational times. It is important that wave breaking can be potentially modeled in the fixed σ-coordinate system, but in a time-dependent σ-coordinate system the wave breaking cannot be modeled. A projection method is used to separate advection and diffusion terms from the pressure terms in Navier–Stokes equations. The pressure variable is further separated into hydrostatic and hydrodynamic pressures so that the computer rounding errors can be largely avoided. In order to reduce computational time of solving the hydrodynamic pressure equation, at every time step the initial pressure is extrapolated in time domain using computed pressures from previous time steps, and then corrected in spatial domain using a multigrid method. For each time step, only a few of iterations (typically six iterations) are required for solving the pressure equation. The model is tested against available experimental data for regular and irregular waves and good agreement between calculation results and the measured data has been achieved.  相似文献   

20.
An approach for eliminating re-reflected waves     
Sheng-Wen Twu  Jyh-Jong Duann 《Ocean Engineering》1995,22(5)
Theoretical and experimental studies were conducted to eliminate the re-reflected waves in a wave channel by installing a wavefilter in front of the wavemaker. A thin porous mesh is installed in front of the wavemaker.to serve as a wavefilter. A porous-effect parameter [Chwang, A. T. and Li, W. (1983), A piston-type porous wavemaker theory. J. Engng Math. 17, 301–313], G0 = bω/μL0, is employed to characterize the transmissability of the wavefilter. Theoretical relationships are established between the amplitude of progressive wave and G0, and the distances between the wavefilter, the wavemaker and the test structure. The proper location for the wavefilter to eliminate re-reflected waves can be determined. Several experimental tests were conducted to verify the theory.Both theoretical and experimental studies show that re-reflected waves can be effectively eliminated by placing a wavefilter at a proper position between the wavemaker and the test structure, provided G0 ≤ 1. For G0 > 1 however, the wavefilter would fail.  相似文献   

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1.
《Ocean Modelling》2009,26(3-4):154-171
Ocean surface mixing and drift are influenced by the mixed layer depth, buoyancy fluxes and currents below the mixed layer. Drift and mixing are also functions of the surface Stokes drift Uss, volume Stokes transport TS, a wave breaking height scale Hswg, and the flux of energy from waves to ocean turbulence Φoc. Here we describe a global database of these parameters, estimated from a well-validated numerical wave model, that uses traditional forms of the wave generation and dissipation parameterizations, and covers the years 2003–2007. Compared to previous studies, the present work has the advantage of being consistent with the known physical processes that regulate the wave field and the air–sea fluxes, and also consistent with a very large number of in situ and satellite observations of wave parameters. Consequently, some of our estimates differ significantly from previous estimates. In particular, we find that the mean global integral of Φoc is 68 TW, and the yearly mean value of TS is typically 10–30% of the Ekman transport, except in well-defined regions where it can reach 60%. We also have refined our previous estimates of Uss by using a better treatment of the high frequency part of the wave spectrum. In the open ocean, Uss  0.013U10, where U10 is the wind speed at 10 m height.  相似文献   

2.
粗糙海面L 和C 双波段的代价函数多参量遥感反演分析   总被引:1,自引:0,他引:1  
齐震  魏恩泊  刘淑波 《海洋科学》2012,36(1):100-107
利用代价函数(cost function)方法,通过分析粗糙海面L和C双波段多极化遥感亮温对海表盐度、温度、风速和有效波高等参数的敏感性以及L和C双波段多极化的代价函数收敛特性,建立了反演海表盐度、温度、风速和有效波高等多参数的L和C双波段多极化代价函数模式。双波段遥感模式分析结果表明:(1)对于双参数的联合反演,L和C双波段垂直极化代价函数联合反演海表盐度和温度可以获得较好的反演结果。(2)L波段垂直极化和C波段水平极化代价函数联合反演海表盐度和风速较好。(3)对于三参数联合反演,L波段垂直极化和C波段的双极化联合反演盐度、温度和风速的精度较高。(4)L波段亮温对有效波高的敏感性较低(C波段经验模式不含有效波高),使得有效波高反演误差较大,L和C波段经验模式不适合反演有效波高参数。另外,为了定量分析L和C双波段代价函数的多参量遥感反演结果,采用加性噪音模拟亮温方法,对上述L和C双波段多极化模式的盐度、温度和风速等多参数联合反演误差进行了分析,均得出较好的结果。结论表明L和C双波段代价函数联合反演多参量可以明显提高参量反演精度,为粗糙海表面多参量的反演提供了新的方法和途径。  相似文献   

3.
Changes from winter (July) to summer (February) in mixed layer carbon tracers and nutrients measured in the sub-Antarctic zone (SAZ), south of Australia, were used to derive a seasonal carbon budget. The region showed a strong winter to summer decrease in dissolved inorganic carbon (DIC;  45 µmol/kg) and fugacity of carbon dioxide (fCO2;  25 µatm), and an increase in stable carbon isotopic composition of DIC (δ13CDIC;  0.5‰), based on data collected between November 1997 and July 1999.The observed mixed layer changes are due to a combination of ocean mixing, air–sea exchange of CO2, and biological carbon production and export. After correction for mixing, we find that DIC decreases by up to 42 ± 3 µmol/kg from winter (July) to summer (February), with δ13CDIC enriched by up to 0.45 ± 0.05‰ for the same period. The enrichment of δ13CDIC between winter and summer is due to the preferential uptake of 12CO2 by marine phytoplankton during photosynthesis. Biological processes dominate the seasonal carbon budget (≈ 80%), while air–sea exchange of CO2 (≈ 10%) and mixing (≈ 10%) have smaller effects. We found the seasonal amplitude of fCO2 to be about half that of a study undertaken during 1991–1995 [Metzl, N., Tilbrook, B. and Poisson, A., 1999. The annual fCO2 cycle and the air–sea CO2 flux in the sub-Antarctic Ocean. Tellus Series B—Chemical and Physical Meteorology, 51(4): 849–861.] for the same region, indicating that SAZ may undergo significant inter-annual variations in surface fCO2. The seasonal DIC depletion implies a minimum biological carbon export of 3400 mmol C/ m2 from July to February. A comparison with nutrient changes indicates that organic carbon export occurs close to Redfield values (ΔP:ΔN:ΔC = 1:16:119). Extrapolating our estimates to the circumpolar sub-Antarctic Ocean implies a minimum organic carbon export of 0.65 GtC from the July to February period, about 5–7% of estimates of global export flux. Our estimate for biological carbon export is an order of magnitude greater than anthropogenic CO2 uptake in the same region and suggests that changes in biological export in the region may have large implications for future CO2 uptake by the ocean.  相似文献   

4.
The wave transmission, reflection and energy dissipation characteristics of ‘’-type breakwaters were studied using physical models. Regular and random waves in a wide range of wave heights and periods and a constant water depth were used. Five different depths of immersion (two emerged, one surface flushing and two submerged conditions) of this breakwater were selected. The coefficient of transmission, Kt, and coefficient of reflection, Kr, were obtained from the measurements, and the coefficient of energy loss, Kl was calculated using the law of balance of energy. It was found that the wave transmission is significantly reduced with increased relative water depth, d/L, whether the vertical barrier of the breakwater is surface piercing or submerged, where ‘d’ is the water depth and ‘L’ is the wave length. The wave reflection decreases and energy loss increases with increased wave steepness, especially when the top tip of the vertical barrier of this breakwater is kept at still water level (SWL). For any incident wave climate (moderate or storm waves), the wave transmission consistently decreases and the reflection increases with increased relative depth of immersion, Δ/d from −0.142 to 0.142. Kt values less than 0.3 can be easily obtained for the case of Δ/d=+0.071 and 0.142, where Δ is the height of exposure (+ve) or depth of immersion (−ve) of the top tip of the vertical barrier. This breakwater is capable of dissipating wave energy to an extent of 50–80%. The overall performance of this breakwater was found to be better in the random wave fields than in the regular waves. A comparison of the hydrodynamic performance of ‘’-type and ‘T’-type shows that ‘T’-type breakwater is better than ‘’-type by about 20–30% under identical conditions.  相似文献   

5.
Estimation of the leeway drift of small craft   总被引:1,自引:0,他引:1  
Small craft (<6·4 m) leeway is determined as a function of the wind speed in the range of 5–20 knots (3·6–10·3 m/sec). Leeway is calculated relative to the surface current by measurement of the separation distance of the small craft from a dyed patch of surface water at sea, using time-sequenced aerial photography. Leeway increases linearly with wind speed for small craft equipped with or without a sea anchor in the wind range studied. Leeway for small craft without sea anchor can be calculated from the equation UL = 0.07 UW + 0.04 where UW is the wind speed at 2 m elevation. Leeway for small craft drifted off the be calculated from the equation ULD = 0·05 UW − 0·12. The small craft drifted off the downwind direction in about 80% of the experiments. The drift angle is variable and difficult to predict.  相似文献   

6.
Monte Carlo simulation of wave spectra was carried out to provide an assessment of JONSWAP spectral model and parameters. The simulation method is found to be satisfactory because (a) it excludes the spectral variability due to geophysical factors from the sampling errors in the spectral estimates and the statistical uncertainty in determining the model parameters; and (b) the simulated spectra can represent ideal spectral estimates where the sampling errors have been minimized by increasing the degrees of freedom of the spectra. The latter (b) allows both the magnitude of sampling errors to be evaluated and errors due to statistical uncertainty to be isolated. Thus, the stimulation study provides a useful error analysis to assess the JONSWAP spectral model and parameters. For instance, it is found from the results that the sampling errors could be as high as 20% while errors due to uncertainty in determining the model parameter could be as high as 17%. However, the overall errors may be reduced to the minimum of approx. 15% if the simulated spectra have 80 degrees of freedom and constant values of σa and σb i.e. σa = 0.07 and σb = 0.09. This implies that the maximum accuracy of 85% may be achieved in JONSWAP spectral model even though the α parameter has been underestimated by about 1.5%. The overestimated values of γ might come from the underestimated α and the biased φm estimator caused by the statistical uncertainty in the presence of a sharp spectral peak. Although the scale parameters (α and φm) exhibit smaller errors and variability than the shape parameters (ψ, σa and σb), they are more sensitive to the degrees of freedom of the spectra and their estimators are not better than the estimators of shape parameters. The simulation experiments have also shown that simulated spectra at 20–40 degrees of freedom contain a substantial amount of sampling errors. Therefore, the measured wave spectra at the same degrees of freedom (20–40) are not suitable and should not be used for evaluating the accuracy of any wave spectral model.  相似文献   

7.
Predictions of maximum wave height Hmax are made at Cromer, Happisburgh and Lowestoft on the East Anglian Coast using the formula Hmax = CKRKS U2/g where C is a constant, KR, KS are refraction and shoaling cofficients, U is wind speed and g is the acceleration due to gravity. Comparisonsare made with the models of Darbyshire Draper (1963) and Bretschneider (1958) Using this wave prediction formula, an estimate of the wave climate in the southern North Sea is deduced for the gales of 2–3 January 1976.  相似文献   

8.
The rates of the reduction of Cr(VI) with S(IV) were measured in deaerated NaCl solution as a function of pH, temperature and ionic strength. The rates of the reaction were found to be first order with respect to Cr(VI) and second order with respect to S(IV), in agreement with previous results obtained at concentrations two order higher than the present study. The reaction also showed a first-order dependence of the rates on the concentration of the proton and a small influence of temperature with an apparent energy of activation ΔHapp of 22.8 ± 3.4 kJ/mol. The rates were independent of ionic strength from 0.01 to 1 M. The rate of Cr(VI) reduction is described by the general expression
−d[Cr(VI)]/dt=k[Cr(VI)][S(IV)]2
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