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1.
Dipole sonic logs acquired in near‐vertical pilot wells and over the build section of nearby horizontal production wells are inverted to determine the five elastic constants characterizing a transversely isotropic formation, under the assumption of lateral homogeneity. Slowness values from a single depth in the vertical well are combined with data from the corresponding depth in the deviated well; these data are then inverted using nonlinear optimization to derive the five elastic constants. The technique is demonstrated on data from the Haynesville Shale in Texas. Estimates of the anisotropy are in line with a priori expectations; the Thomsen ε and γ parameters are well correlated and generally possess positive anellipticity, with Thomsen's ε greater than Thomsen's δ.  相似文献   

2.
The elastic moduli and anisotropy of organic-rich rocks are of great importance to geoengineering and geoprospecting of oil and gas reservoirs. In this paper, we probe into the static and dynamic moduli of the Ghareb–Mishash chalk through laboratory measurements and new analytical approaches. We define a new anisotropy parameter, ‘hydrostatic strain ratio’ (Ω), which describes the differential contraction of anisotropic rocks consequent to hydrostatic compression. Ω depends on the C11, C12, C13 and C33 stiffness constants of a transversely isotropic material, and therefore enables a unique insight into the anisotropic behaviour of TI rocks. Ω proves more sensitive to anisotropy within the weak anisotropy range, when compared with Thomsen's ε and γ parameters. We use Ω to derive static moduli from triaxial compression tests performed on a single specimen. This is done by novel employment of a hydrostatic-deviatoric combination for transversely isotropic elastic stiffnesses. Dynamic moduli are obtained from acoustic velocities measurements. We find that the bedding-normal velocities are described well by defining kerogen as the load-supporting matrix in a Hashin–Shtrikman model (‘Hashin–Shtrikman (HS) kerogen’). The dynamic moduli of the Ghareb–Mishash chalk in dry conditions are significantly higher than the static moduli. The dynamic/static moduli ratio decreases from ∼4 to ∼2 with increasing kerogen content. Both the static and dynamic moduli decrease significantly with increasing porosity and kerogen content. The effect of porosity on them is two times stronger than the effect of kerogen.  相似文献   

3.
Fractures in elastic media add compliance to a rock in the direction normal to the fracture strike. Therefore, elastic wave velocities in a fractured rock will vary as a function of the energy propagation direction relative to the orientation of the aligned fracture set. Anisotropic Thomson–Haskell matrix Rayleigh-wave equations for a vertically transverse isotropic media can be used to model surface-wave dispersion along the principal axes of a vertically fractured and transversely isotropic medium. Furthermore, a workflow combining first-break analysis and azimuthal anisotropic Rayleigh-wave inversion can be used to estimate P-wave and S-wave velocities, Thomsen's ε, and Thomsen's δ along the principal axes of the orthorhombic symmetry. In this work, linear slip theory is used to map our inversion results to the equivalent vertically fractured and transversely isotropic medium coefficients. We carried out this inversion on a synthetic example and a field example. The synthetic data example results show that joint estimation of S-wave velocities with Thomsen's parameters ε and δ along normal and parallel to the vertical fracture set is reliable and, when mapped to the corresponding vertically fractured and transversely isotropic medium, provides insight into the fracture compliances. When the inversion was carried out on the field data, results indicated that the fractured rock is more compliant in the azimuth normal to the visible fracture set orientation and that the in situ normal fracture compliance to tangential fracture compliance ratio is less than half, which implies some cementation may have occurred along the fractures. Such an observation has significant implications when modelling the transport properties of the rock and its strength. Both synthetic and field examples show the potential of azimuthal anisotropic Rayleigh-wave inversion as the method can be further expanded to a more general case where the vertical fracture set orientation is not known a priori.  相似文献   

4.
Analysis of Thomsen parameters for finely layered VTI media   总被引：2，自引：0，他引：2  
Since the work of Postma and Backus, much has been learned about elastic constants in vertical transversely isotropic (VTI) media when the anisotropy is due to fine layering of isotropic elastic materials. Nevertheless, there has continued to be some uncertainty about the possible range of Thomsen's anisotropy parameters ε and δ for such media. We use both Monte Carlo studies and detailed analysis of Backus' equations for both two- and three-component layered media to establish the results presented. We show that ε lies in the range ?3/8 ε ½[〈v2p〉〈v?2p〉?1], for finely layered media; smaller positive and all negative values of ε occur for media with large fluctuations in the Lamé parameter λ in the component layers. We show that δ can also be either positive or negative, and that for constant density media, sign (δ) = sign (〈v?2p〉 ? 〈v?2s〉〈v2s/v2p〉). Monte Carlo simulations show that among all theoretically possible random media, positive and negative δ are equally likely in finely layered media. (Of course, the δs associated with real earth materials may span some smaller subset of those that are theoretically possible, but answering this important question is beyond our present scope.) Layered media having large fluctuations in λ are those most likely to have positive δ. This is somewhat surprising since ε is often negative or a small positive number for such media, and we have the general constraint that ε ? δ > 0 for layered VTI media. Since Gassmann's results for fluid-saturated porous media show that the mechanical effects of fluids influence only the Lamé parameter λ, not the shear modulus μ, these results suggest that small positive δ occurring together with small positive ε (but somewhat larger than δ) may be indicative of changing fluid content in a layered earth.  相似文献   

5.
Transverse isotropy with a vertical axis of symmetry is a common form of anisotropy in sedimentary basins, and it has a significant influence on the seismic amplitude variation with offset. Although exact solutions and approximations of the PP-wave reflection coefficient for the transversely isotropic media with vertical axis of symmetry have been explicitly studied, it is difficult to apply these equations to amplitude inversion, because more than three parameters need to be estimated, and such an inverse problem is highly ill-posed. In this paper, we propose a seismic amplitude inversion method for the transversely isotropic media with a vertical axis of symmetry based on a modified approximation of the reflection coefficient. This new approximation consists of only three model parameters: attribute A, the impedance (vertical phase velocity multiplied by bulk density); attribute B, shear modulus proportional to an anellipticity parameter (Thomsen's parameter ε−δ); and attribute C, the approximate horizontal P-wave phase velocity, which can be well estimated by using a Bayesian-framework-based inversion method. Using numerical tests we show that the derived approximation has similar accuracy to the existing linear approximation and much higher accuracy than isotropic approximations, especially at large angles of incidence and for strong anisotropy. The new inversion method is validated by using both synthetic data and field seismic data. We show that the inverted attributes are robust for shale-gas reservoir characterization: the shale formation can be discriminated from surrounding formations by using the crossplot of the attributes A and C, and then the gas-bearing shale can be identified through the combination of the attributes A and B. We then propose a rock-physics-based method and a stepwise-inversion-based method to estimate the P-wave anisotropy parameter (Thomsen's parameter ε). The latter is more suitable when subsurface media are strongly heterogeneous. The stepwise inversion produces a stable and accurate Thomsen's parameter ε, which is proved by using both synthetic and field data.  相似文献   

6.
This short communication presents the assessment of seismic inelastic and elastic displacement demands computed from earthquake ground motions (EQGMs) recorded in Mexico City during the intermediate‐depth intraslab Puebla‐Morelos earthquake on 19 September 2017 (Mw = 7.1). Evaluation is conducted by means of peak elastic and inelastic displacement demand spectra, inelastic displacement ratio, CR, spectra, and generalized interstory drift spectra computed for selected recording stations located in different soil sites of Mexico City, including those located in areas of reported collapsed buildings. Results of this study confirm previous observations made from interplate (subduction) EQGMs that peak inelastic displacement demands are greater than corresponding elastic counterparts for short‐to‐medium period structures, while the opposite is true for medium‐to‐long period structures. Possible basin site effects were identified from generalized interstory drift spectra. It is also shown that an equation introduced in the literature to obtain estimates of CR developed from interplate EQGMs provides also a good estimate for mean CR computed from the intermediate‐depth intraslab EQGMs.  相似文献   

7.
Viscoelastic modelling reveals that the interaction of compressional-wave velocity Cp, compressional-wave quality factor Qp, shear-wave velocity Cs, shear-wave quality factor Qs and Poisson's ratio as a function of time intercept τ and ray parameter p, is complicated; however, distinct, potentially diagnostic behaviours are seen for different combinations of viscoelastic parameters. Synthetic seismograms for three viscoelastic reservoir models show that variations in the Poisson's ratio produce visible differences when compared to the corresponding elastic synthetic seismograms; these differences are attributable to interaction of the elastic parameters with Qp and Qs. When the P-wave acoustic impedance contrast is small, viscoelastic effects become more apparent and more useful for interpretation purposes. The corresponding amplitude and net phase spectra reveal significant differences between the elastic and the viscoelastic responses. When P-wave reflectivities are large, they tend to dominate the total response and to mask the Q reflectivity effects. The attenuation effects are manifested as an amplitude decay that increases with both time and ray parameter. The sensitivity of the computed seismic responses for various combinations of viscoelastic parameters suggests the opportunity for diagnostic interpretation of τ-p seismic data. The interpretation of the viscoelastic parameters can permit a better understanding of the rock types and pore fluid distribution existing in the subsurface.  相似文献   

8.
Ultrasonic (500 kHz) P‐ and S‐wave velocity and attenuation anisotropy were measured in the laboratory on synthetic, octagonal‐shaped, silica‐cemented sandstone samples with aligned penny‐shaped voids as a function of pore fluid viscosity. One control (blank) sample was manufactured without fractures, another sample with a known fracture density (measured from X‐ray CT images). Velocity and attenuation were measured in four directions relative to the bedding fabric (introduced during packing of successive layers of sand grains during sample construction) and the coincident penny‐shaped voids (fractures). Both samples were measured when saturated with air, water (viscosity 1 cP) and glycerin (100 cP) to reveal poro‐visco‐elastic effects on velocity and attenuation, and their anisotropy. The blank sample was used to estimate the background anisotropy of the host rock in the fractured sample; the bedding fabric was found to show transverse isotropy with shear wave splitting (SWS) of 1.45 ± 1.18% (i.e. for S‐wave propagation along the bedding planes). In the fractured rock, maximum velocity and minimum attenuation of P‐waves was seen at 90° to the fracture normal. After correction for the background anisotropy, the fractured sample velocity anisotropy was expressed in terms of Thomsen's weak anisotropy parameters ε, γ & δ. A theory of frequency‐dependent seismic anisotropy in porous, fractured, media was able to predict the observed effect of viscosity and bulk modulus on ε and δ in water‐ and glycerin‐saturated samples, and the higher ε and δ values in air‐saturated samples. Theoretical predictions of fluid independent γ are also in agreement with the laboratory observations. We also observed the predicted polarisation cross‐over in shear‐wave splitting for wave propagation at 45° to the fracture normal as fluid viscosity and bulk modulus increases.  相似文献   

9.
The single-crystal elastic moduli of the ilmenite phase of MgSiO3 have been determined from Brillouin spectroscopy. They are: C11 = 472, C12 = 168, C33 = 382, C13 = 70, C44 = 106, C14 = ?27, C66 = 152 and C25 = ?24 in GPa. These elastic properties are consistent with a structural mechanical model where the silicon octahedra are very stiff under compression and shear. This latter property yields an unexpectedly high shear modulus for the magnesium silicate ilmenite as compared with analogue compounds. The further transformation to perovskite will probably be associated with a significant increase in elastic properties since the strong silicon polyhedra form a structural network in this phase. The transformation of spinel and stishovite to ilmenite is associated with a slight density increase and a slight decrease in acoustic velocities. This transformation will probably not produce a seismic discontinuity even if it does occur in the Earth's mantle.  相似文献   

10.
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11.
Las Vegas Valley has had a long history of groundwater development and subsequent surface deformation. InSAR interferograms have revealed detailed and complex spatial patterns of subsidence in the Las Vegas Valley area that do not coincide with major pumping regions. This research represents the first effort to use high spatial and temporal resolution subsidence observations from InSAR and hydraulic head data to inversely calibrate transmissivities (T), elastic and inelastic skeletal storage coefficients (Ske and Skv) of the developed‐zone aquifer and conductance (CR) of the basin‐fill faults for the entire Las Vegas basin. The results indicate that the subsidence observations from InSAR are extremely beneficial for accurately quantifying hydraulic parameters, and the model calibration results are far more accurate than when using only groundwater levels as observations, and just a limited number of subsidence observations. The discrepancy between distributions of pumping and greatest levels of subsidence is found to be attributed to spatial variations in clay thickness. The Eglington fault separates thicker interbeds to the northwest from thinner interbeds to the southeast and the fault may act as a groundwater‐flow barrier and/or subsidence boundary, although the influence of the groundwater barrier to this area is found to be insignificant. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

12.
Seismic anisotropy of shales   总被引：3，自引：0，他引：3  
Shales are a major component of sedimentary basins, and they play a decisive role in fluid flow and seismic‐wave propagation because of their low permeability and anisotropic microstructure. Shale anisotropy needs to be quantified to obtain reliable information on reservoir fluid, lithology and pore pressure from seismic data, and to understand time‐to‐depth conversion errors and non‐hyperbolic moveout. A single anisotropy parameter, Thomsen's δ parameter, is sufficient to explain the difference between the small‐offset normal‐moveout velocity and vertical velocity, and to interpret the small‐offset AVO response. The sign of this parameter is poorly understood, with both positive and negative values having been reported in the literature. δ is sensitive to the compliance of the contact regions between clay particles and to the degree of disorder in the orientation of clay particles. If the ratio of the normal to shear compliance of the contact regions exceeds a critical value, the presence of these regions acts to increase δ, and a change in the sign of δ, from the negative values characteristic of clay minerals to the positive values commonly reported for shales, may occur. Misalignment of the clay particles can also lead to a positive value of δ. For transverse isotropy, the elastic anisotropy parameters can be written in terms of the coefficients W200 and W400 in an expansion of the clay‐particle orientation distribution function in generalized Legendre functions. For a given value of W200, decreasing W400 leads to an increase in δ, while for fixed W400, δ increases with increasing W200. Perfect alignment of clay particles with normals along the symmetry axis corresponds to the maximum values of W200 and W400, given by and . A comparison of the predictions of the theory with laboratory measurements shows that most shales lie in a region of the (W200, W400)‐plane defined by W400/W200≤Wmax400/Wmax200 .  相似文献   

13.
Elastic parameters such as Young's modulus, Poisson's ratio, and density are very important characteristic parameters that are required to properly characterise shale gas reservoir rock brittleness, evaluate gas characteristics of reservoirs, and directly interpret lithology and oil‐bearing properties. Therefore, it is significant to obtain accurate information of these elastic parameters. Conventionally, they are indirectly calculated by the rock physics method or estimated by approximate formula inversion. The cumulative errors caused by the indirect calculation and low calculation accuracy of the approximate Zoeppritz equations make accurate estimation of Young's modulus, Poisson's ratio, and density difficult in the conventional method. In this paper, based on the assumption of isotropy, we perform several substitutions to convert the Zoeppritz equations from the classical form to a new form containing the chosen elastic constants of Young's modulus, Poisson's ratio, and density. The inversion objective function is then constructed by utilising Bayesian theory. Meanwhile, the Cauchy distribution is introduced as a priori information. We then combine the idea of generalised linear inversion with an iterative reweighed least squares algorithm in order to solve the problem. Finally, we obtain the iterative updating formula of the three elastic parameters and achieve the direct inversion of these elastic parameters based on the exact Zoeppritz equations. Both synthetic and field data examples show that the new method is not only able to obtain the two elastic parameters of Young's modulus and Poisson's ratio stably and reasonably from prestack seismic data but also able to provide an accurate estimation of density information, which demonstrates the feasibility and effectiveness of the proposed method. The proposed method offers an efficient seismic method to identify a “sweet spot” within a shale gas reservoir.  相似文献   

14.
Tritium concentrations in river and stream waters from different locations can be compared by normalizing them using the ratio of tritium concentrations in precipitation and surface water (Cp/Cs) in the study area. This study uses these ratios in a hydrological residence time context to make regional‐ and global‐scale comparisons about river basin dynamics. Prior to the advent of nuclear weapons testing, the Cp/Cs ratio was greater than or equal to 1 everywhere because of the decay of tritium in the watershed after it was deposited by precipitation. After an initial increase in the ratios during the bomb peak, the ratio dropped to less than 1 for most surface waters in the following years. This post‐bomb change in the ratio is due to the retention of the bomb‐pulse water in watersheds on timescales that are long relative to the residence time of tritium in the atmosphere. Ratios were calculated for over 6500 measurements of tritium in river and stream waters compiled by the International Atomic Energy Agency. These measurements span the post‐nuclear era (1940s to present) and include many long‐term datasets, which make it possible to examine residence times of waters in watersheds on a global basis. Plotting Cp/Cs versus time shows that ratios tended to reach a minimum in approximately one to two decades after the bomb peak for most locations. This result suggests that changes affecting quantity and quality of river flows need to be assessed on a multi‐decadal timescale. These long lag times have significant implications for assessing climate or land‐use change impacts on a large number of river systems around the world. The continuing value of tritium in studying surface water systems for both the Southern and Northern Hemisphere is also demonstrated. Published 2014. This article is a U.S. Government work and is in the public domain in the USA.  相似文献   

15.
A vertically fractured transversely isotropic (VFTI) elastic medium is one in which any number of sets of vertical aligned fractures (each set has its normal lying in the horizontal x1, x2‐plane) pervade the medium and the sets of aligned fractures are the only features of the medium disturbing the axi‐symmetry about the x3‐axis implying that in the absence of fractures, the background medium is transversely isotropic (TI). Under the assumptions of long wavelength equivalent medium theory, the compliance matrix of a fractured medium is the sum of the background medium's compliance matrix and a fracture compliance matrix. For sets of parallel rotationally symmetric fractures (on average), the fracture compliance matrix is dependent on 3 parameters − its normal and tangential compliance and its strike direction. When one fracture set is present, the medium is orthorhombic and the analysis is straightforward. When two (non‐orthogonal) or more sets are present, the overall medium is in general elastically monoclinic; its compliance tensor components are subject to two equalities yielding an 11 parameter monoclinic medium. Constructing a monoclinic VFTI medium with n embedded vertical fracture sets, requires 5 TI parameters plus 3×n fracture set parameters. A deconstruction of such an 11 parameter monoclinic medium involves using its compliance tensor to find a background transversely isotropic medium and several sets of vertical fractures which, in the long wavelength limit, will behave exactly as the original 11 parameter monoclinic medium. A minimal deconstruction, would be to determine, from the 11 independent components, the transversely isotropic background (5 parameters) and two fracture sets (specified by 2 × 3 = 6 parameters). Two of the background TI medium's compliance matrix components are known immediately by inspection, leaving nine monoclinic components to be used in the minimal deconstruction of the VFTI medium. The use of the properties of a TI medium, which are linear relations on its compliance components, allows the deconstruction to be reduced to solving a pair of non‐linear equations on the orientations of two fracture sets. A single root yielding a physically meaningful minimum deconstruction yields a unique minimal representation of the monoclinic medium as a VFTI medium. When no such root exists, deconstruction requires an additional fracture set and uniqueness is lost. The boundary between those monoclinic media that have a unique minimal representation and those that do not is yet to be determined.  相似文献   

16.
Although there is no assumption of pore geometry in derivation of Gassmann's equation, the pore geometry is in close relation with hygroscopic water content and pore fluid communication between the micropores and the macropores. The hygroscopic water content in common reservoir rocks is small, and its effect on elastic properties is ignored in the Gassmann theory. However, the volume of hygroscopic water can be significant in shaly rocks or rocks made of fine particles; therefore, its effect on the elastic properties may be important. If the pore fluids in microspores cannot reach pressure equilibrium with the macropore system, assumption of the Gassmann theory is violated. Therefore, due to pore structure complexity, there may be a significant part of the pore fluids that do not satisfy the assumption of the Gassmann theory. We recommend that this part of pore fluids be accounted for within the solid rock frame and effective porosity be used in Gassmann's equation for fluid substitution. Integrated study of ultrasonic laboratory measurement data, petrographic data, mercury injection capillary pressure data, and nuclear magnetic resonance T2 data confirms rationality of using effective porosity for Gassmann fluid substitution. The effective porosity for Gassmann's equation should be frequency dependent. Knowing the pore geometry, if an empirical correlation between frequency and the threshold pore‐throat radius or nuclear magnetic resonance T2 could be set up, Gassmann's equation can be applicable to data measured at different frequencies. Without information of the pore geometry, the irreducible water saturation can be used to estimate the effective porosity.  相似文献   

17.
An approximation is developed that allows mapped 4D seismic amplitudes and time‐shifts to be related directly to the weighted linear sum of pore pressure and saturation changes. The weights in this relation are identified as key groups of parameters from a petroelastic model and include the reservoir porosity. This dependence on groups of parameters explains the inherent non‐uniqueness of this problem experienced by previous researchers. The proposed relation is of use in 4D seismic data feasibility studies and inversion and interpretation of the 4D seismic response in terms of pore pressure and water saturation changes. A further result is drawn from analysis of data from the North Sea and West Africa, which reveals that the relative interplay between the effects of pore pressure and saturation changes on the seismic data can be simplified to the control of a single, spatially variant parameter CS/CP. Combining these results with those from published literature, we find that CS/CP = 8 appears to be a generality across a range of clastic reservoirs with a similar mean porosity. Using this CS/CP value, an in situ seismic‐scale constraint for the rock stress sensitivity component of the petroelastic model is constructed considering this component carries the largest uncertainty.  相似文献   

18.
At moderate temperatures, the elastic properties of natural MgAl2O4 spinel differ in several significant ways from properties of synthetic spinels. Below 1000 K, the ultrasonic resonant frequencies of an ordered natural spinel change significantly after heat treatment; at higher temperatures, both types of spinels have similar resonant responses. The temperature derivatives of the elastic constants of an ordered spinel also differ from those of disordered spinels at moderate temperatures; again, at higher temperatures, both types of spinels have similar behaviors. The Raman spectra also differ below 1000 K for ordered natural and disordered spinels and are similar at higher temperatures and after cooling to ambient temperature. We associate these changes in ultrasonic resonance and Raman spectra of spinel with cation disordering at high temperature which may be quenched by cooling. We deduce estimates of the inversion parameter from the relative intensities of the two A1g Raman modes in very good agreement with estimates made from other measurements. We find thatC 11 andC 12 decrease by 4 and 8%, respectively, with 20% inversion in spinel;C 44 is less sensitive to cation order. These results imply that previous measurements of the adiabatic elastic constants of spinels at ambient conditions have been affected by the state of cation disorder of the specimen.  相似文献   

19.
During bed‐load transport by overland ?ow, momentum is transferred from the ?ow to the bed via grain collisions, resulting in a decrease in ?ow velocity and an increase in ?ow resistance, herein termed bed‐load transport resistance. In overland ?ow on mobile plane beds, total ?ow resistance f consists of grain resistance fg and bed‐load transport resistance fbt. In order to identify and evaluate the relative importance of the factors controlling fbt, 38 ?ume experiments were performed on slopes of 2·7 and 5·5° using sediment with median diameters of 0·74 and 1·16 mm. All ?ows were supercritical and turbulent. This study is an extension of a recent study by Gao and Abrahams (Earth Surface Processes and Landforms 2004, vol. 29, pp. 423–435). These authors found that fbt is controlled by three factors: sediment concentration C, dimensionless sediment diameter D*, and relative submergence h/D, where h is ?ow depth, D is median sediment diameter. However, a new dimensional analysis identi?es two additional factors: Froude number F and slope S. Multiple regression analyses reveal (1) that these ?ve factors together explain 97 per cent of the variance of fbt, and (2) that S controls fbt entirely through C. The variable C is therefore redundant, and a new functional equation relating fbt to D*, h/D, S and F is developed. This equation may be used to predict fbt. An advantage of this equation is that it may be used to predict fbt without measuring bed‐load transport rate. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

20.
The potential for trichloroethene (TCE) biodegradation in a fractured dolomite aquifer at a former chemical disposal site in Smithville, Ontario, Canada, is assessed using chemical analysis and TCE and cis‐DCE compound‐specific isotope analysis of carbon and chlorine collected over a 16‐month period. Groundwater redox conditions change from suboxic to much more reducing environments within and around the plume, indicating that oxidation of organic contaminants and degradation products is occurring at the study site. TCE and cis‐DCE were observed in 13 of 14 wells sampled. VC, ethene, and/or ethane were also observed in ten wells, indicating that partial/full dechlorination has occurred. Chlorine isotopic values (δ37Cl) range between 1.39 to 4.69‰ SMOC for TCE, and 3.57 to 13.86‰ SMOC for cis‐DCE. Carbon isotopic values range between ?28.9 and ?20.7‰ VPDB for TCE, and ?26.5 and ?11.8‰ VPDB for cis‐DCE. In most wells, isotopic values remained steady over the 15‐month study. Isotopic enrichment from TCE to cis‐DCE varied between 0 and 13‰ for carbon and 1 and 4‰ for chlorine. Calculated chlorine‐carbon isotopic enrichment ratios (?Cl/?C) were 0.18 for TCE and 0.69 for cis‐DCE. Combined, isotopic and chemical data indicate very little dechlorination is occurring near the source zone, but suggest bacterially mediated degradation is occurring closer to the edges of the plume.  相似文献   

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