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1.
Groundwater monitoring wells are present at most hydrocarbon release sites that are being assessed for cleanup. If screened across the vadose zone, these wells provide an opportunity to collect vapor samples that can be used in the evaluation of vapor movement and biodegradation processes occurring at such sites. This paper presents a low purge volume method (modified after that developed by the U.S. EPA) for sampling vapor from monitoring wells that is easy to implement and can provide an assessment of the soil gas total petroleum hydrocarbon (TPH) and O2 concentrations at the base of the vadose zone. As a result, the small purge method allows for sampling of vapor from monitoring wells to support petroleum vapor intrusion (PVI) risk assessment. The small purge volume method was field tested at the Hal's service station site in Green River, Utah. This site is well‐known for numerous soil gas measurements containing high O2 and high TPH vapor concentrations in the same samples which is inconsistent with well‐accepted biodegradation models for the vapor pathway. Using the low purge volume method, monitoring wells were sampled over, upgradient, and downgradient of the light nonaqueous phase liquid (LNAPL) footprint. Results from our testing at Hal's show that vapor from monitoring wells over LNAPL contained very low O2 and high TPH concentrations. In contrast, vapor from monitoring wells not over LNAPL contained high O2 and low TPH concentrations. The results of this study show that a low purge volume method is consistent with biodegradation models especially for sampling at sites where low permeability soils exist in and around a LNAPL source zone.  相似文献   

2.
Active microwave remote sensing observations of backscattering, such as C‐band vertically polarized synthetic aperture radar (SAR) observations from the second European remote sensing (ERS‐2) satellite, have the potential to measure moisture content in a near‐surface layer of soil. However, SAR backscattering observations are highly dependent on topography, soil texture, surface roughness and soil moisture, meaning that soil moisture inversion from single frequency and polarization SAR observations is difficult. In this paper, the potential for measuring near‐surface soil moisture with the ERS‐2 satellite is explored by comparing model estimates of backscattering with ERS‐2 SAR observations. This comparison was made for two ERS‐2 overpasses coincident with near‐surface soil moisture measurements in a 6 ha catchment using 15‐cm time domain reflectometry probes on a 20 m grid. In addition, 1‐cm soil moisture data were obtained from a calibrated soil moisture model. Using state‐of‐the‐art theoretical, semi‐empirical and empirical backscattering models, it was found that using measured soil moisture and roughness data there were root mean square (RMS) errors from 3·5 to 8·5 dB and r2 values from 0·00 to 0·25, depending on the backscattering model and degree of filtering. Using model soil moisture in place of measured soil moisture reduced RMS errors slightly (0·5 to 2 dB) but did not improve r2 values. Likewise, using the first day of ERS‐2 backscattering and soil moisture data to solve for RMS surface roughness reduced RMS errors in backscattering for the second day to between 0·9 and 2·8 dB, but did not improve r2 values. Moreover, RMS differences were as large as 3·7 dB and r2 values as low as 0·53 between the various backscattering models, even when using the same data as input. These results suggest that more research is required to improve the agreement between backscattering models, and that ERS‐2 SAR data may be useful for estimating fields‐scale average soil moisture but not variations at the hillslope scale. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

3.
There is increasing recognition that 137Cs data remain one of the few sources of spatially distributed information concerning soil erosion. However, many of the conversion models that have been used to convert 137Cs data into soil redistribution rates failed to account for some of the key factors affecting the redistribution of 137Cs in agricultural landscapes. The conversion model presented in this paper aims to overcome some of the limitations associated with existing models and therefore to provide more realistic estimates of soil erosion rates on agricultural land. The conversion model aims at coupling soil redistribution processes directly with 137Cs redistribution. Emphasis is placed on the spatial representation of soil redistribution processes and the adequate simulation of tillage processes. The benefits of the presented model arise from the two‐dimensional spatial integration of mass balance models with soil erosion models. No a priori assumptions about the intensity of any soil redistribution process are necessary and the level of agreement between observed and simulated 137Cs inventories enables us to evaluate the performance of the model. The spatial implementation and the use of fuzzy parameter sets also allow us to assess the uncertainties associated with soil erosion estimates. It was shown that an adequate simulation of tillage processes is necessary and that simplified tillage models may lead to erroneous estimates of soil redistribution. The model was successfully applied to a study site in the Belgian Loam Belt and the results indicated that tillage is the dominant process. Furthermore, the uncertainties associated with the estimation of water erosion rates were much higher than those associated with tillage, especially for depositional areas. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

4.
The use of in‐field analysis of vapor‐phase samples to provide real‐time volatile organic compound (VOC) concentrations in groundwater has the potential to streamline monitoring by simplifying the sample collection and analysis process. A field validation program was completed to (1) evaluate methods for collection of vapor samples from monitoring wells and (2) evaluate the accuracy and precision of field‐portable instruments for the analysis of vapor‐phase samples. The field program evaluated three vapor‐phase sample collection methods: (1) headspace samples from two locations within the well, (2) passive vapor diffusion (PVD) samplers placed at the screened interval of the well, and (3) field vapor headspace analysis of groundwater samples. Two types of instruments were tested: a field‐portable gas chromatograph (GC) and a photoionization detector (PID). Field GC analysis of PVD samples showed no bias and good correlation to laboratory analysis of groundwater collected by low‐flow sampling (slope = 0.96, R2 = 0.85) and laboratory analysis of passive water diffusion bag samples from the well screen (slope = 1.03; R2 = 0.96). Field GC analysis of well headspace samples, either from the upper portion of the well or at the water‐vapor interface, resulted in higher variability and much poorer correlation (consistently biased low) relative to laboratory analysis of groundwater samples collected by low‐flow sample or passive diffusion bags (PDBs) (slope = 0.69 to 0.76; R2 = 0.60 to 0.64). These results indicate that field analysis of vapor‐phase samples can be used to obtain accurate measurements of VOC concentrations in groundwater. However, vapor samples collected from the well headspace were not in equilibrium with water collected from the well screen. Instead, PVD samplers placed in the screened interval represent the most promising approach for field‐based measurement of groundwater concentrations using vapor monitoring techniques and will be the focus of further field testing.  相似文献   

5.
Developing models to predict on‐site soil erosion and off‐site sediment transport at the agricultural watershed scale represent an on‐going challenge in research today. This study attempts to simulate the daily discharge and sediment loss using a distributed model that combines surface and sub‐surface runoffs in a small hilly watershed (< 1 km2). The semi‐quantitative model, Predict and Localize Erosion and Runoff (PLER), integrates the Manning–Strickler equation to simulate runoff and the Griffith University Erosion System Template equation to simulate soil detachment, sediment storage and soil loss based on a map resolution of 30 m × 30 m and over a daily time interval. By using a basic input data set and only two calibration coefficients based, respectively, on water velocity and soil detachment, the PLER model is easily applicable to different agricultural scenarios. The results indicate appropriate model performance and a high correlation between measured and predicted data with both Nash–Sutcliffe efficiency (Ef) and correlation coefficient (r2) having values > 0.9. With the simple input data needs, PLER model is a useful tool for daily runoff and soil erosion modeling in small hilly watersheds in humid tropical areas. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

6.
Water and energy fluxes at and between the land surface, the subsurface and the atmosphere are inextricably linked over all spatio‐temporal scales. Our research focuses on the joint analysis of both water and energy fluxes in a pre‐alpine catchment (55 km2) in southern Germany, which is part of the Terrestrial Environmental Observatories (TERENO). We use a novel three‐dimensional, physically based and distributed modelling approach to reproduce both observed streamflow as an integral measure for water fluxes and heat flux and soil temperature measurements at an observation location over a period of 2 years. While heat fluxes are often used for comparison of the simulations of one‐dimensional land surface models, they are rarely used for additional validation of physically based and distributed hydrological modelling approaches. The spatio‐temporal variability of the water and energy balance components and their partitioning for dominant land use types of the study region are investigated. The model shows good performance for simulating daily streamflow (Nash–Sutcliffe efficiency > 0.75). Albeit only streamflow measurements are used for calibration, the simulations of hourly heat fluxes and soil temperatures at the observation site also show a good performance, particularly during summer. A limitation of the model is the simulation of temperature‐driven heat fluxes during winter, when the soil is covered by snow. An analysis of the simulated spatial fields reveals heat flux patterns that reflect the distribution of the land use and soil types of the catchment. The water and energy partitioning is characterized by a strong seasonal cycle and shows clear differences between the selected land use types. Copyright © 2016 The Authors Hydrological Processes Published by John Wiley & Sons Ltd.  相似文献   

7.
The objective of this study was to quantify components of the water balance related to root‐water uptake in the soil below a hedgerow. At this local scale, a two‐dimensional (2D) flow domain in the x–z plane 6 m long and 1·55 m deep was considered. An attempt was made to estimate transpiration using a simulation model. The SWMS‐2D model was modified and used to simulate temporally and spatially heterogeneous boundary conditions. A function with a variable spatial distribution of root‐water uptake was considered, and model calibration was performed by adjusting this root‐water uptake distribution. Observed data from a previous field study were compared against model predictions. During the validation step, satisfactory agreement was obtained, as the difference between observed and modelled pressure head values was less than 50 cm for 80% of the study data. Hedge transpiration capacity is a significant component of soil‐water balance in the summer, when predicted transpiration reaches about 5·6 mm day?1. One of the most important findings is that hedge transpiration is nearly twice that of a forest canopy. In addition, soil‐water content is significantly different whether downslope or upslope depending on the root‐water uptake. The high transpiration rate was mainly due to the presence of a shallow water table below the hedgerow trees. Soil‐water content was not a limiting factor for transpiration in this context, as it could be in one with a much deeper water table. Hedgerow tree transpiration exerts a strong impact not only on water content within the vadose zone but also on the water‐table profile along the transect. Results obtained at the local scale reveal that the global impact of hedges at the catchment scale has been underestimated in the past. Transpiration rate exerts a major influence on water balance at both the seasonal and annual scales for watersheds with a dense network of hedgerows. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

8.
Rapidly depleting unconfined aquifers are the primary source of water for irrigation on the North China Plain. Yet, despite its critical importance, groundwater recharge to the Plain remains an enigma. We introduce a one‐dimensional soil‐water‐balance model to estimate precipitation‐ and irrigation‐generated areal recharge from commonly available crop and soil characteristics and climate data. To limit input data needs and to simplify calculations, the model assumes that water flows vertically downward under a unit gradient; infiltration and evapotranspiration are separate, sequential processes; evapotranspiration is allocated to evaporation and transpiration as a function of leaf‐area index and is limited by soil‐moisture content; and evaporation and transpiration are distributed through the soil profile as exponential functions of soil and root depth, respectively. For calibration, model‐calculated water contents of 11 soil‐depth intervals from 0 to 200 cm were compared with measured water contents of loam soil at four sites in Luancheng County, Hebei Province, over 3 years (1998–2001). Each 50‐m2 site was identically cropped with winter wheat and summer maize, but received a different irrigation treatment. Average root mean‐squared error between measured and model‐calculated water content of the top 180 cm was 4·2 cm, or 9·3% of average total water content. In addition, model‐calculated evapotranspiration compared well with that measured by a large‐scale lysimeter. To test the model, 12 additional sites were simulated successfully. Model results demonstrate that drainage from the soil profile is not a constant fraction of precipitation and irrigation inputs, but rather the fraction increases as the inputs increase. Because this drainage recharges the underlying aquifer, improving irrigation efficiency by reducing seepage will not reverse water‐table declines. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

9.
Although the anaerobic biodegradation of methyl tert‐butyl ether (MTBE) and tert‐butyl alcohol (TBA) has been documented in the laboratory and the field, knowledge of the microorganisms and mechanisms involved is still lacking. In this study, DNA‐stable isotope probing (SIP) was used to identify microorganisms involved in anaerobic fuel oxygenate biodegradation in a sulfate‐reducing MTBE and TBA plume. Microorganisms were collected in the field using Bio‐Sep® beads amended with 13C5‐MTBE, 13C1‐MTBE (only methoxy carbon labeled), or 13C4‐TBA. 13C‐DNA and 12C‐DNA extracted from the Bio‐Sep beads were cloned and 16S rRNA gene sequences were used to identify the indigenous microorganisms involved in degrading the methoxy group of MTBE and the tert‐butyl group of MTBE and TBA. Results indicated that microorganisms were actively degrading 13C‐labeled MTBE and TBA in situ and the 13C was incorporated into their DNA. Several sequences related to known MTBE‐ and TBA‐degraders in the Burkholderiales and the Sphingomonadales orders were detected in all three 13C clone libraries and were likely to be primary degraders at the site. Sequences related to sulfate‐reducing bacteria and iron‐reducers, such as Geobacter and Geothrix, were only detected in the clone libraries where MTBE and TBA were fully labeled with 13C, suggesting that they were involved in processing carbon from the tert‐butyl group. Sequences similar to the Pseudomonas genus predominated in the clone library where only the methoxy carbon of MTBE was labeled with 13C. It is likely that members of this genus were secondary degraders cross‐feeding on 13C‐labeled metabolites such as acetate.  相似文献   

10.
Propane biosparging and bioaugmentation were applied to promote in situ biodegradation of 1,4‐dioxane at Site 24, Vandenberg Air Force Base (VAFB), CA. Laboratory microcosm and enrichment culture testing demonstrated that although native propanotrophs appeared abundant in the shallow water‐bearing unit of the aquifer (8 to 23 ft below ground surface [bgs]), they were difficult to be enriched from a deeper water‐bearing unit (82 to 90 feet bgs). Bioaugmentation with the propanotroph Rhodococcus ruber ENV425, however, supported 1,4‐dioxane biodegradation in microcosms constructed with samples from the deep aquifer. For field testing, a propane‐biosparging system consisting of a single sparging well and four performance monitoring wells was constructed in the deep aquifer. 1,4‐dioxane biodegradation began immediately after bioaugmentation with R. ruber ENV425 (36 L; 4 × 109 cells/mL), and apparent first‐order decay rates for 1,4‐dioxane ranged from 0.021 day?1 to 0.036 day?1. First‐order propane consumption rates increased from 0.01 to 0.05 min?1 during treatment. 1,4‐dioxane concentrations in the sparging well and two of the performance monitoring wells were reduced from as high as 1090 µg/L to <2 µg/L, while 1,4‐dioxane concentration was reduced from 135 µg/L to 7.3 µg/L in a more distal third monitoring well. No 1,4‐dioxane degradation was observed in the intermediate aquifer control well even though propane and oxygen were present. The demonstration showed that propane biosparging and bioaugmentation can be used for in situ treatment of 1,4‐dioxane to regulatory levels.  相似文献   

11.
Despite widespread bench‐terracing, stream sediment yields from agricultural hillsides in upland West Java remain high. We studied the causes of this lack of effect by combining measurements at different spatial scales using an erosion process model. Event runoff and sediment yield from two 4‐ha terraced hillside subcatchments were measured and field surveys of land use, bench‐terrace geometry and storage of sediment in the drainage network were conducted for two consecutive years. Runoff was 3·0–3·9% of rainfall and sediment yield was 11–30 t ha−1 yr−1 for different years, subcatchments and calculation techniques. Sediment storage changes in the subcatchment drainage network were less than 2 t ha−1, whereas an additional 0·3–1·5 t ha−1 was stored in the gully between the subcatchment flumes and the main stream. This suggests mean annual sediment delivery ratios of 86–125%, or 80–104% if this additional storage is included. The Terrace Erosion and Sediment Transport (TEST) model developed and validated for the studied environment was parameterized using erosion plot studies, land use surveys and digital terrain analysis to simulate runoff and sediment generation on the terraced hillsides. This resulted in over‐estimates of runoff and under‐estimates of runoff sediment concentration. Relatively poor model performance was attributed to sample bias in the six erosion plots used for model calibration and unaccounted covariance between important terrain attributes such as slope, infiltration capacity, soil conservation works and vegetation cover. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

12.
Post‐wildfire runoff was investigated by combining field measurements and modelling of infiltration into fire‐affected soils to predict time‐to‐start of runoff and peak runoff rate at the plot scale (1 m2). Time series of soil‐water content, rainfall and runoff were measured on a hillslope burned by the 2010 Fourmile Canyon Fire west of Boulder, Colorado during cyclonic and convective rainstorms in the spring and summer of 2011. Some of the field measurements and measured soil physical properties were used to calibrate a one‐dimensional post‐wildfire numerical model, which was then used as a ‘virtual instrument’ to provide estimates of the saturated hydraulic conductivity and high‐resolution (1 mm) estimates of the soil‐water profile and water fluxes within the unsaturated zone. Field and model estimates of the wetting‐front depth indicated that post‐wildfire infiltration was on average confined to shallow depths less than 30 mm. Model estimates of the effective saturated hydraulic conductivity, Ks, near the soil surface ranged from 0.1 to 5.2 mm h?1. Because of the relatively small values of Ks, the time‐to‐start of runoff (measured from the start of rainfall), tp, was found to depend only on the initial soil‐water saturation deficit (predicted by the model) and a measured characteristic of the rainfall profile (referred to as the average rainfall acceleration, equal to the initial rate of change in rainfall intensity). An analytical model was developed from the combined results and explained 92–97% of the variance of tp, and the numerical infiltration model explained 74–91% of the variance of the peak runoff rates. These results are from one burned site, but they strongly suggest that tp in fire‐affected soils (which often have low values of Ks) is probably controlled more by the storm profile and the initial soil‐water saturation deficit than by soil hydraulic properties. Published 2013. This article is a U.S. Government work and is in the public domain in the USA.  相似文献   

13.
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14.
A cell‐based long‐term hydrological model (CELTHYM) that can be integrated with a geographical information system (GIS) was developed to predict continuous stream flow from small agricultural watersheds. The CELTHYM uses a cell‐by‐cell soil moisture balance approach. For surface runoff estimation, the curve number technique considering soil moisture on a daily basis was used, and release rate was used to estimate baseflow. Evapotranspiration was computed using the FAO modified Penman equation that considered land‐use‐based crop coefficients, soil moisture and the influence of topography on radiation. A rice paddy field water budget model was also adapted for the specific application of the model to East Asia. Model sensitivity analysis was conducted to obtain operational information about the model calibration parameters. The CELTHYM was calibrated and verified with measured runoff data from the WS#1 and WS#3 watersheds of the Seoul National University, Department of Agricultural Engineering, in Hwaseong County, Kyounggi Province, South Korea. The WS#1 watershed is comprised of about 35·4% rice paddy fields and 42·3% forest, whereas the WS#3 watershed is about 85·0% forest and 11·5% rice paddy fields. The CELTHYM was calibrated for the parameter release rate, K, and soil moisture storage coefficient, STC, and results were compared with the measured runoff data for 1986. The validation results for WS#1 considering all daily stream flow were poor with R2, E2 and RMSE having values of 0·40, ?6·63 and 9·69 (mm), respectively, but validation results for days without rainfall were statistically significant (R2 = 0·66). Results for WS#3 showed good agreement with observed data for all days, and R2, E2 and RMSE were 0·92, 0·91 and 2·23 (mm), respectively, suggesting potential for CELTHYM application to other watersheds. The direct runoff and water balance components for watershed WS#1 with significant areas of paddy fields did not perform well, suggesting that additional study of these components is needed. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

15.
Stone forest (‘Shilin’ in Chinese) is a unique karst landform with a complex evolution process. Based mainly on the characteristics and interrelationships of sub‐soil, soil and sub‐aerial erosion in Lunan karst area, the authors develop a triplex erosion model to describe the evolution of stone forest, and apply it to examine the current development stage and the prospect of the Lunan Stone Forest. The study shows that sub‐soil corrosion, a basic driving force for the vertical scope of a stone forest, usually occurs within 10 m below ground surface but is observed to be most active within the top 2 m, which constitutes the best development zone for stone forest. Under modern climatic conditions, the tip of the stone pillars in Lunan karst area is lowering at a rate of 10·4 mm ka?1, whereas the base of the stone pillars is deepening at 26·17 mm ka?1. Therefore, the height of stone pillars is increasing at a rate of 15·77 mm ka?1. Considering that soil erosion in the study area is as high as 650 mm ka?1, the visible height of the stone forest is actually increasing at a rate of 639·6 mm ka?1. However, the best evolution time for Lunan Stone Forest has already passed despite the fact that it is still growing taller at the present time. This is because the soil layer, which plays an extremely significant role in the heightening of stone pillars, is rapidly thinning at a rate of 623·83 mm ka?1. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

16.
Both the rate and the vertical distribution of soil disturbance modify soil properties such as porosity, particle size, chemical composition and age structure; all of which play an important role in a soil's biogeochemical functioning. Whereas rates of mixing have been previously quantified, the nature of bioturbation's depth dependence remains poorly constrained. Here we constrain, for the first time, the relationship between mixing rate and depth in a bioturbated soil in northeast Queensland, Australia using a novel method combining OSL (optically‐stimulated luminescence) ages and meteoric beryllium‐10 (10Be) inventories. We find that the best fit mixing rate decreases non‐linearly with increasing soil depth in this soil and the characteristic length scale of 0.28 m over which the mixing coefficient decays is comparable to reported rooting depth coefficients. In addition we show that estimates of surface mixing rates from OSL data are highly dependent on erosion rate and that erosion rate must be constrained if accurate mixing rates are to be quantified. We calculate surface diffusion‐like mixing coefficients of 1.8 × 10?4 and 2.1 × 10?4 m2 yr?1 for the studied soil for two different estimates of soil erosion. © 2014 The Authors. Earth Surface Processes and Landforms Published by John Wiley & Sons Ltd.  相似文献   

17.
This study evaluates the theory, and some practical aspects of using temperature measurements to assess aerobic biodegradation in hydrocarbon contaminated soil. The method provides an easily applicable alternative for quantifying the rate of biodegradation and/or evaluating the performance of in situ remediation systems. The method involves two nonintrusive procedures for measuring vertical temperature profiles down existing monitoring wells; one using a thermistor on a cable for one‐time measurements and the other using compact temperature data loggers deployed for 3‐month to 1‐year period. These vertical temperature profile measurements are used to identify the depth and lateral extent of biodegradation as well as to monitor seasonal temperature changes throughout the year. The basic theory for using temperature measurements to estimate the minimum rate of biodegradation will be developed, and used to evaluate field measurements from sites in California where biodegradation of spilled petroleum hydrocarbons is due to natural processes. Following, temperature data will be used to evaluate the relative rates of biodegradation due to natural processes and soil vapor extraction (SVE) at a former refinery site in the North‐Central United States. The results from this study show that the temperature method can be a simple, cost effective tool for assessing biodegradation in the soil, and optimizing remediation systems at a wide variety of hydrocarbon spill sites.  相似文献   

18.
The caesium‐137 method of quantifying soil erosion is used to provide field data for validating the capability of the SHETRAN modelling system for predicting long‐term (30‐year) erosion rates and their spatial variability. Simulations were carried out for two arable farm sites (area 3–5 ha) in central England for which average annual erosion rates of 6·5 and 10·4 t ha?1 year?1 had already been determined using caesium‐137 measurements. These rates were compared with a range of simulated values representing the uncertainty in model output derived from uncertainty in the evaluation of model parameters. A successful validation was achieved in that the simulation range contained the measured rate at both sites, whereas the spatial variability was reproduced excellently at one site and partially at the other. The results indicate that, as the caesium‐137 technique measures the erosion caused by all the processes acting at a site, it is relevant to hydrologically based models such as SHETRAN only if erosion by wind, agricultural activities and other processes not represented in the model are insignificant. The results also indicate a need to reduce the uncertainty in model parameter evaluation. More generally, the caesium‐137 technique is shown to provide field data that improve the severity of the validation procedure (accounting for internal as well as outlet conditions) and that add spatial variability to magnitude as a condition for identifying unrealistic parameter sets when seeking to reduce simulation uncertainty. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

19.
Constructed wetlands are being utilized worldwide to effectively reduce excess nutrients in agricultural runoff and wastewater. Despite their frequency, a multi‐dimensional, physically based, spatially distributed modelling approach has rarely been applied for flow and solute transport in treatment wetlands. This article presents a two‐dimensional hydrodynamic and solute transport modelling of a large‐scaled, subtropical, free water surface constructed wetland of about 8 km2 in the Everglades of Florida, USA. In this study, MIKE 21 was adopted as the basic model framework. Field monitoring of the time series hydrological and chloride data, as well as spatially distributed data such as bathymetry and vegetation distribution, provided the necessary model input and testing data. Simulated water level profiles were in good agreement with the spatio‐temporal variations of measured ones. On average, the root‐mean‐square error of model calibration on annual water level fluctuations was 0·09 m. Manning's roughness coefficients for the dense emergent and submerged aquatic vegetation areas, which were estimated as a function of vegetation type, ranged from 0·67 to 1·0 and 0·12 to 0·15 s/m1/3, respectively. The solute transport model calibration for four monitoring sites agreed well with the measured annual variations in chloride concentration with an average percent model error of about 15%. The longitudinal dispersivity was estimated to be about 2 m and was more than an order of magnitude higher than the transverse one. This study is expected to play the role of a stepping stone for future modelling efforts on the development and application of more advanced flow and transport models applicable to a variety of constructed wetland systems, as well as to the Everglades stormwater treatment areas in operation or in preparation. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

20.
Detailed site investigations to assess potential inhalation exposure and risk to human health associated with the migration of petroleum hydrocarbon vapors from the subsurface to indoor air are frequently undertaken at leaking underground storage tank (UST) sites, yet documented occurrences of petroleum vapor intrusion are extremely rare. Additional assessments are largely driven by low screening‐level concentrations derived from vapor transport modeling that does not consider biodegradation. To address this issue, screening criteria were developed from soil‐gas measurements at hundreds of petroleum UST sites spanning a range of environmental conditions, geographic regions, and a 16‐year time period (1995 to 2011). The data were evaluated to define vertical separation (screening) distances from the source, beyond which, the potential for vapor intrusion can be considered negligible. The screening distances were derived explicitly from benzene data using specified soil‐gas screening levels of 30, 50, and 100 µg/m3 and nonparametric Kaplan‐Meier statistics. Results indicate that more than 95% of benzene concentrations in soil gas are ≤30 µg/m3 at any distance above a dissolved‐phase hydrocarbon source. Dissolved‐phase petroleum hydrocarbon sources are therefore unlikely to pose a risk for vapor intrusion unless groundwater (including capillary fringe) comes in contact with a building foundation. For light nonaqueous‐phase liquid (LNAPL) hydrocarbon sources, more than 95% of benzene concentrations in soil gas are ≤30 µg/m3 for vertical screening distances of 13 ft (4 m) or greater. The screening distances derived from this analysis are markedly different from 30 to 100 ft (10 to 30 m) vertical distances commonly found cited in regulatory guidance, even with specific allowances to account for uncertainty in the hydrocarbon source depth or location. Consideration of these screening distances in vapor intrusion guidance would help eliminate unnecessary site characterization at petroleum UST sites and allow more effective and sustainable use of limited resources.  相似文献   

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