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1.
A large set of new data concerning dissolved metal concentrations has been acquired in the Gulf of Cadiz and in the Strait of Gibraltar from 1996 to 1999. These data, associated with models (hydrodynamic, tracer advection–dispersion and mixing), have been used to assess the influence of rivers draining the South Iberian Pyrite Belt on the Gulf of Cadiz and on the Atlantic inflow in the Strait of Gibraltar.Metal concentrations in surface waters from the Gulf of Cadiz are maximal near the mouth of the Tinto/Odiel rivers with values exceeding 50 nmol/kg (Mn), 5 nmol/kg (Ni), 30 nmol/kg (Cu), 100 nmol/kg (Zn), 0.9 nmol/kg (Cd) and 45 nmol/kg (As). From the Tinto/Odiel river, a plume of contamination follows the coast in the direction of the Strait of Gibraltar. The computation of a tracer advection–dispersion model confirms that the coastal currents carry the metals discharged from the Tinto and Odiel to the Strait of Gibraltar.From temperature–salinity and metal–salinity plots, four water masses can be recognised in the Gulf of Cadiz and in the Strait of Gibraltar: North Atlantic Surface Water (NASW), North Atlantic Central Water (NACW) and metal-enriched Spanish Shelf Waters from the Gulf of Cadiz (SSW). The Mediterranean Outflow Water (MOW) is also clearly seen at depths greater than 300 m.The chemical characteristics of these various water masses have been used in a mixing model to evaluate their relative contribution to the Atlantic inflow through the Strait of Gibraltar. These contributions are seasonally variable. In June 1997, the contribution was: 80±20%, 5±5% and 15±10% for NASW, NACW and SSW, respectively. In September, the SSW contribution was apparently negligible.Finally, these relative contributions allow the evaluation of the metal fluxes in the Strait of Gibraltar. The presence of SSW in the Strait increases the metal flux to the Mediterranean Sea by a factor of 2.3 (Cu), 2.4 (Cd), 3 (Zn) and 7 (Mn). It does not modify significantly As and Ni fluxes.  相似文献   

2.
The Gulf of Cadiz: an unstable giant contouritic levee   总被引：1，自引：0，他引：1  
Recent multibeam bathymetry and acoustic imagery data provide a new understanding of the sedimentary system located in the Gulf of Cadiz which is under the influence of a strong current, the Mediterranean Outflow Water (MOW). When it comes out from the Strait of Gibraltar, the MOW is either channelled along major or secondary channels, or spills over a sedimentary levee. Frequent earthquakes and the constant current shearing generate widespread sediment deformation and instability of contourite deposits. Secondary channels can form by retrogression following an initial failure. At their mouth, sediment accumulates in the form of small sandy contourite lobes. These observations suggest that the Gulf of Cadiz system shares many similarities with channel–levee complexes formed by turbidity current activity. The main difference is that, in the Gulf of Cadiz, the main process is a strongly flowing saline current which locally interacts with gravity processes.  相似文献   

3.
High resolution seafloor images in the Gulf of Cadiz, Iberian margin   总被引：1，自引：0，他引：1  
In the Gulf of Cadiz, the hydrodynamic process acting on particle transport and deposition is a strong density-driven bottom current caused by the outflow of the saline deep Mediterranean water at the Strait of Gibraltar: the Mediterranean Outflow Water (MOW). New high resolution acoustic data including EM300 multibeam echo-sounder, deep-towed acoustic system SAR and very high resolution seismic, completed by piston cores collected during the CADISAR cruise allow to improve the understanding of the hydrodynamics of the MOW in the eastern part of the Gulf of Cadiz. Interpretation of data corrects the previous model established in this area and allows, for the first time, the accurate characterization of various bedforms and erosive structures along the MOW pathway and the precise identification of numerous gravity instabilities. The interaction between the MOW, the seafloor morphology and the Coriolis force is presently the driving force of the sedimentary distribution pattern observed on the Gulf of Cadiz continental slope.  相似文献   

4.
This paper presents a computational model for mapping the regional 3D distribution in which seafloor gas hydrates would be stable, that is carried out in a Geographical Information System (GIS) environment. The construction of the model is comprised of three primary steps, namely: (1) the construction of surfaces for the various variables based on available 3D data (seafloor temperature, geothermal gradient and depth-pressure); (2) the calculation of the gas function equilibrium functions for the various hydrocarbon compositions reported from hydrate and sediment samples; and (3) the calculation of the thickness of the hydrate stability zone. The solution is based on a transcendental function, which is solved iteratively in a GIS environment.The model has been applied in the northernmost continental slope of the Gulf of Cadiz, an area where an abundant supply for hydrate formation, such as extensive hydrocarbon seeps, diapirs and fault structures, is combined with deep undercurrents and a complex seafloor morphology. In the Gulf of Cadiz, the model depicts the distribution of the base of the gas hydrate stability zone for both biogenic and thermogenic gas compositions, and explains the geometry and distribution of geological structures derived from gas venting in the Tasyo Field (Gulf of Cadiz) and the generation of BSR levels on the upper continental slope.  相似文献   

5.
This study of the mixing of Mediterranean Sea Water (MW) with the surrounding waters was made possible by the Semane 2002 cruise (Sortie des Eaux Meditérranéennes dans l'Atlantique Nord-Est) that took place in the Gulf of Cadiz in July 2002. Potential temperature, salinity, oxygen, nutrients and CFC data are used to describe the water masses present in the Gulf. In the southern part of the basin, a water mass characterised by low oxygen, high nutrient and low CFC concentrations occurs along the African continental slope. This water has been identified as the modified Antarctic Intermediate Water (AAIW). It has been previously observed south of this section, at the latitude of the Canary Islands, as a northward flow between the African shelf and the islands. The modified AAIW found in the Gulf of Cadiz is situated at a density of 27.5 kg m−3. Above, at 27.3 kg m−3, the lower limb of the North Atlantic Central Water is observed as a salinity minimum. The modified AAIW enters the Gulf of Cadiz along the south-western part of the continental shelf. It flows cyclonically and exits north-westward. In the northern part of the gulf, due to the presence of the Mediterranean Undercurrent (MU), the AAIW flows off the coast. An optimum multiparameter analysis was conducted to evaluate the influence of the AAIW on the MW northwest of the basin. We show that the AAIW is present in the lower core of the MU at a proportion of 12.9±8.2% and is absent in the upper core.  相似文献   

6.
The sedimentary structure in the Gulf of Cadiz has been extensively studied by oil exploration companies. However, up to now little is known about its deep crustal structure. Moreover, the total thickness of the sedimentary layers remains unknown in large areas. The purpose of this paper is the crustal-scale interpretation of deep seismic near-vertical reflection and refraction/wide-angle reflection data obtained during the IAM (Iberian Atlantic Margins) project, carried out in 1993. Our results indicate that a continental type crust is underlying the entire Gulf of Cadiz, with progressive thinning from east to west. The sedimentary cover shows a great thickness, reaching 8 km in the center of the Gulf. Three main sedimentary units can be recognized: Jurassic-Cretaceous calcareous rocks, continuation of Algarve outcrops; the Allochthonous Units of Guadalquivir/Gulf of Cadiz, the offshore continuation of the inland Carmona nappe; and sub-horizontal post-Miocene marine sediments. The crystalline crust is divided into three main layers: the upper crust is characterized by P-wave velocity values of 5.7–6.1 km/s; the middle crust shows values of 6.3–6.4 km/s; the lower crust has a mean vertical velocity gradient of 0.02 km/s/km, with velocities between 6.9 to 7.1 km/s. The total crustal thickness varies from 27 km for the eastern part of the studied area, to 20 km for the westernmost part. The crustal thinning is more pronounced in a N-S direction than in an E-W direction. No major structures related with a defined Iberia-Africa plate boundary could be found. This revised version was published online in November 2006 with corrections to the Cover Date.  相似文献   

7.
The freshwater discharge from the Gulf of St. Lawrence and Hudson Bay accounts for more than 80% of the total freshwater discharge from eastern Canada and approximately 70% of the total discharge from the eastern seaboard of North America, from Baffin Island to Florida. If the Gulf of Mexico is included, the Gulf of St. Lawrence/Hudson Bay discharge is still more than half of the total.Both the Gulf of St. Lawrence and Hudson Bay have some distinctly estuarine characteristics and discharges of metals can be estimated using estuarine models. For Al, Mn, Fe, Co, Ni, Cu and Zn, the distributions can be described by simple, highly significant relationships with salinity. These regressions can be used in conjunction with knowledge of water discharges to estimate net metal inputs to the North Atlantic from these two systems.Most of the discharge from the Gulf of St. Lawrence flows along the Scotian Shelf to the Gulf of Maine. Metal-salinity relationships can also be used to estimate metal transports through this region for some metals. The applicability of this estuarine model, however, tends to break down as the oceanography becomes more complex and metal distributions are determined more by oceanic rather than estuarine processes.  相似文献   

8.
Existing knowledge on the distribution of mud volcanoes (MVs) and other significant fluid/free gas-venting features (mud cones, mud pies, mud-brine pools, mud carbonate cones, gas chimneys and, in some cases, pockmark fields) discovered on the seafloor of the Mediterranean Sea and in the nearby Gulf of Cadiz has been compiled using regional geophysical information (including multibeam coverage of most deepwater areas). The resulting dataset comprises both features proven from geological sampling, or in situ observations, and many previously unrecognized MVs inferred from geophysical evidence. The synthesis reveals that MVs clearly have non-random distributions that correspond to two main geodynamic settings: (1) the vast majority occur along the various tectono-sedimentary accretionary wedges of the Africa-Eurasia subduction zone, particularly in the central and eastern Mediterranean basins (external Calabrian Arc, Mediterranean Ridge, Florence Rise) but also along its westernmost boundary in the Gulf of Cadiz; (2) other MVs characterize thick depocentres along parts of the Mesozoic passive continental margins that border Africa from eastern Tunisia to the Levantine coasts, particularly off Egypt and, locally, within some areas of the western Mediterranean back-arc basins. Meaningfully accounting for MV distribution necessitates evidence of overpressured fluids and mud-rich layers. In addition, cross-correlations between MVs and other GIS-based data, such as maps of the Messinian evaporite basins and/or active (or recently active) tectonic trends, stress the importance of assessing geological control in terms of the presence, or not, of thick seals and potential conduits. It is contended that new MV discoveries may be expected in the study region, particularly along the southern Ionian Sea continental margins.  相似文献   

9.
Heat flow anomalies provide critical information in active tectonic environments. The Gulf of Cadiz and adjacent areas are affected by the plate convergence between Africa and Europe, causing widespread deformation and faulting. Active thrust faults cause lateral movement and advection of heat that produces systematic variations in surface heat flow. In December 2003 new heat flow data were collected during the research vessel Sonne cruise SO175 in the Gulf of Cadiz over two sites of recent focused research activity: (i) the Gulf of Cadiz sedimentary prism and (ii) the Marques de Pombal escarpment. Both features have also been discussed as potential source areas of the Great Lisbon earthquake and tsunami of 1755. Background heat flow at the eastern terminus of the Horseshoe abyssal plain is about 52–59 mW/m2. Over the Gulf of Cadiz prism, heat flow decreases from ∼57 mW/m2 to unusually low values of 45 mW/m2 roughly 120 km eastward. Such low values and the heat flow trend are typical for active thrusting, supporting the idea of an east-dipping thrust fault. Slip rates are 10 ± 5 mm per year, assuming that the fault dips at 2°. A fault dipping at 5°, however, would result into slip rates of 1.5–5 mm per year, suggesting that subduction has largely ceased. Based on seismic data, the Marques de Pombal fault is interpreted as part of an active fault system located ∼100 km westward of Cape San Vincente. Heat flow over the fault is affected by refraction of heat caused by the 1 km high escarpment. Thermal models suggest that the slip rate along the fault must either be small or shear stresses acting on the fault are rather high. With respect to other fault zones, however, it is reasonable to assume that the fault's slip rate is small.  相似文献   

10.
Frenulates are the most poorly known members of the family Siboglinidae (Polychaeta: Canalipalpata). These thread-like worms occur in reducing marine sediments worldwide, but they are often overlooked in benthic samples or too poorly preserved for adequate taxonomic evaluations. We report on a remarkable diversity of frenulates that were recently sampled from 13 mud volcanoes (350–3902 m deep) in the Gulf of Cadiz, off southern Iberia. Sampled with benthic coring devices, the bodies of these long tubiculous worms were often broken or incomplete, making them difficult to identify morphologically. Consequently, we employed DNA taxonomic methods to assess their diversity. Mitochondrial cytochrome-c-oxidase subunit 1 (COI) sequences distinguished 15 evolutionary lineages inhabiting the Gulf of Cadiz. Only four of the lineages could be assigned to currently recognized Atlantic species; the remaining 11 may be new to science. This remarkable diversity of frenulates in a small geographical region is unprecedented and is hypothesized to result from environmental heterogeneity associated with the bathymetric and geochemical settings of these mud volcanoes.  相似文献   

11.
Guimei  Huijie Xue 《Ocean Modelling》2009,29(4):234-247
Multidimensional Positive Definite Advection Transport Algorithm (MPDATA) and Monotonic Upstream Schemes for Conservation Laws (MUSCL) are compared and evaluated in a biogeochemical-like tracer model. Based on the MUSCL scheme, an adapted scheme for σ-coordinate models (MUSCL_VD) is presented. These schemes are first implemented in idealized experiments configured for a closed channel with and without a seamount, and conservation is confirmed. MUSCL_VD and MUSCL generate the same results in the flat bottom case, while MUSCL_VD is the only scheme that avoids unphysical values in the seamount experiments. When implemented in a three-dimensional model of the Gulf of Maine (GoM) with realistic topography and real-time forcing, the modeled distributions of an inert tracer concentration are sensitive to the advection schemes. The experiment with MUSCL shows persistent overshoots. MPDATA and MUSCL_VD produce similar spatial distributions and seasonal cycles with MUSCL_VD being slightly more diffusive in the horizontal and less so in the vertical. These two schemes are about equally efficient in computation.  相似文献   

12.
Facies associations in cores collected in the deep part of the Gulf of Cadiz, which is under the influence of the lower branch of the Mediterranean Outflow Water, are investigated in terms of the classical contourite model using grain-size analyses and thin sections of indurated sediment. Cores include both low-energy (contourite drift) and high-energy (channel) environments. The thin sections and grain-size distributions show that clayey fine silts and sandy coarse silts are the most common facies associations in the studied contourite sequences, while coarse-grained, gravelly contourites are less common. Grain-size distributions are unimodal in the fine-grained and bi- or trimodal in the coarser-grained contourites. This change in grain-size composition is related both to the partial removal of the fine-grained fraction and to the replenishment of the coarser-grained one. In addition, most of the contacts between individual facies are sharp rather than transitional. This suggests that the contourite sequence is only in part related to changes in bottom current velocity and flow competency, but may also be related to the supply of a coarser terrigeneous particle stock, provided by either increased erosion of indurated mud along the flanks of confined contourite channels (mud clasts), or by increased sediment supply by rivers (quartz grains) and downslope mass transport on the continental shelf and upper slope. The classical contourite facies association may therefore not be solely controlled by current velocity, but may be the product of a variety of depositional histories. The classical contourite depositional sequence should therefore be interpreted with greater care and in the light of the regional sedimentological background. In addition, the wisdom of exclusively using mean or modal particle size for the interpretation of depositional contourite processes is questioned. Instead, it is proposed that the vertical evolution of grain-size populations in the facies successions forming contourite sequences be assessed.  相似文献   

13.
The South American cordgrass, Spartina densiflora, has invaded a range of different habitats that can support different native species assemblages on salt marshes in the Gulf of Cadiz, Spain. Little is known about the mechanisms of invasion. We examined the potential for seed germination and recruitment in a field transplant experiment, representing a wide range of environments, on elevational gradients across marshes with muddy and sandy sediments. The biotic resistance of native, perennial vegetation (where present) to recruitment of the alien was also investigated. Spartina densiflora seeds were able to germinate over a greater than 2-m range of elevation in the tidal frame. Germination success on unvegetated muddy sediments was related to sediment redox potential, with poor germination at strongly negative redox potentials on the lower sites. On sandy, well-drained sediments, germination was apparently constrained by water availability at the highest elevations. Comparison of vegetated and cleared plots on the upper marsh showed that there was a negative relationship between the presence of Atriplex portulacoides and germination on the muddy sediments. Recruitment (survival of seedlings for 12 weeks) was seen only on unvegetated muddy sediments at the highest elevation. Hence the invasive success and wide elevational tolerance of S. densiflora on the marshes of the Gulf of Cadiz are not reflected in its short-term ability to become established from its prolific seed production. Colonization of sub-optimal habitats may be largely by vegetative propagules and clonal growth.  相似文献   

14.
Several types of sediment failures in the Gulf of Cadiz were observed using multibeam bathymetry, acoustic imagery and high-resolution seismic. These instabilities are mainly sediment failures and flows. Their width and length vary from 1 to more than 10 km. The failures are mainly related to high sedimentation rates, particularly in places where the Mediterranean Outflow Water (MOW) spills over, such as channel bends and the outer side of the giant contourite levee. Steep slopes are also a trigger for failure at the continental shelf-slope transition, on valley sides, on canyon flanks, and on the sides of bathymetric highs. Other mass movements are related to fluid escape (mud volcanoes) and earthquakes. In areas where the MOW flows along the seafloor, the constant shearing and related erosion can add to the overall stresses. The frequency of failures can be estimated using the deposits resulting of their distal transformations into turbidites.  相似文献   

15.
This study reports novel findings on the Pliocene?CQuaternary history of the northern Gulf of Cadiz margin and the spatiotemporal evolution of the associated contourite depositional system. Four major seismic units (P1, P2, QI and QII) were identified in the Pliocene?CQuaternary sedimentary record based on multichannel seismic profiles. These are bounded by five major discontinuities which, from older to younger, are the M (Messinian), LPR (lower Pliocene revolution), BQD (base Quaternary discontinuity), MPR (mid-Pleistocene revolution) and the actual seafloor. Unit P1 represents pre-contourite hemipelagic/pelagic deposition along the northern Gulf of Cadiz margin. Unit P2 reflects a significant change in margin sedimentation when contourite deposition started after the Early Pliocene. Mounded elongated and separated drifts were generated during unit QI deposition, accompanied by a general upslope progradation of drifts and the migration of main depocentres towards the north and northwest during both the Pliocene and Quaternary. This progradation became particularly marked during QII deposition after the mid-Pleistocene (MPR). Based on the spatial distribution of the main contourite depocentres and their thickness, three structural zones have been identified: (1) an eastern zone, where NE?CSW diapiric ridges have controlled the development of two internal sedimentary basins; (2) a central zone, which shows important direct control by the Guadalquivir Bank in the south and an E?CW Miocene palaeorelief structure in the north, both of which have significantly conditioned the basin-infill geometry; and (3) a western zone, affected in the north by the Miocene palaeorelief which favours deposition in the southern part of the basin. Pliocene tectonic activity has been an important factor in controlling slope morphology and, hence, influencing Mediterranean Outflow Water pathways. Since the mid-Pleistocene (MPR), the sedimentary stacking pattern of contourite drifts has been less affected by tectonics and more directly by climatic and sea-level changes.  相似文献   

16.
The sedimentary processes on the northern shelf of the Gulf of Cadiz (SW Spain) are basically controlled by two factors: the different rates of fluvial supply between the northern and southern sectors and the dominant water flows toward the SE. The distribution of heavy minerals shows differences between the two sectors with predominance of ultrastable minerals in the southern sector, in relation to the different supply rates. This distribution is related to the sea-level change during the Holocene, fluvial supplies, and oceanographic factors. The application of statistical multivariate methods to heavy mineral data shows the principal heavy mineral association (epidote—garnet—rutile), which is very similar to that in neighboring terrestrial areas and offers the possibility of referring factors to source areas.  相似文献   

17.
Within the Central waters of the North Atlantic Ocean there is a significant east–west difference in salinity, similar to that caused by Mediterranean Water at deeper levels. In this paper we hypothesize that the salinity of the Central Water is influenced by the saline Mediterranean Outflow Water, despite physical separation of the two water masses by a salinity minimum over most of the ocean basin. It is suggested that there occurs a cross-isopycnal flux of salinity from the Mediterranean Outflow Water towards the low-density Central Water (detrainment) in the eastern Gulf of Cadiz, not far from the Strait of Gibraltar, where the two water masses are in physical contact. Laboratory experiments, inverse modeling and direct current observations are applied to support the hypothesis.  相似文献   

18.
In order to identify the major sources of trace metals (TM) in the Portuguese coastal waters, 58 surface water samples were collected during September 1988. The area sampled extended from the Tagus Estuary (down to a salinity of 25) to cape Ste Marie on the southern coast of Portugal. Dissolved metal concentrations in the fully marine waters ranged from 30 to 250 pM for Cd, 0.7–15 nM for Cu, 0.9–20 nM for Zn and 1.8–4.5 nM for Ni. Within the Tagus Estuary (salinity 25), concentrations increased to 3400 pM for Cd, 26 nM for Cu, 14 nM for Ni and 230 nM for Zn.The large-scale distribution of these metals is dominated by two strong continental sources, both probably linked to the exploitation of pyrite ores. In the Tagus Estuary, TM enrichments can be mostly attributed to a pyrite roasting plant located on the shore in front of Lisbon. Concerning the south Portuguese shelf waters, several hypotheses are proposed to explain their elevated metal concentrations. We particularly discussed the likely influence of the Tinto/Odiel rivers located 100 km eastward, an influence well known in the shelf waters of the Gulf of Cadiz. These rivers are extremely metal-rich because of acid mine tailings originating from their catchment. Between these two regions, upwelling of relatively metal-poor water largely contributes to the dilution of the continental inputs. Indeed, water exchanges on the shelf linked to the upwelling involve water fluxes 500 times higher than the Tagus River flow, and renew the coastal waters that are thus cleaned from terrestrial contamination. Contrary to many other upwelling systems in non-contaminated areas, the Portuguese upwelling does not act as a source of trace-metal enrichment of the continental margin waters.  相似文献   

19.
Sediment cores and grab samples were collected in the Upper Gulf of Thailand to determine sedimentation rates and to determine if metal concentrations reflect anthropogenic inputs.Accumulation rates of sediments in the Upper Gulf measured using the 210Pb method, appear to vary from ca. 4 to 11 mm yr?1. Sediment budgets suggest that little of the sediment delivered to the Upper Gulf by the major rivers is ultimately transported to the Lower Gulf. Metal concentrations in Upper Gulf sediments appear to be dominantly controlled by natural inputs.  相似文献   

20.
Detailed reviews of high-resolution acoustic studies in the continental slope of the Gulf of Cadiz has revealed the following gas-related features: acoustic turbidity and blanking, bright spots, ancient and modern pockmarks, high-amplitude diffractions, acoustic plumes and turbidity in the water column, and BSRs. The origin of the gas is believed to be biogenic and thermogenic. The BSR-like acoustic anomalies occur intermittently in some areas of the upper slope and tend to occur in the volcanoes/diapirs. The pressure–temperature conditions deduced for the location of those acoustic anomalies do not correspond to the conditions of stability of gas hydrates. It is suggested that these volcanoes/diapirs intrusions may locally induce anomalously higher pore pressure conditions on the immediately surrounding sediments, affecting the stability field of the gas hydrates.  相似文献   

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