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1.
Experimental evidence for the role of accessory phases in magma genesis   总被引:1,自引:0,他引:1  
Recent experimental studies have established petrogenetic models based on melting processes involving major phases. The possible residual character of trace-element-enriched accessory phases is not considered for temperatures well above the solidus in these models. In contrast, geochemists, applying trace element data to independently test the experimentally-based models, have concluded that residual (or fractionating) accessory phases may have an essential role in controlling the trace element (especially REE) distributions in magmas.Some recent experimental work provides data on the stability of potentially significant accessories such as sphene, rutile, apatite, zoisite and mica in basaltic compositions at elevated P and T. Sphene is stable to 1000°C with 60% melting of a hydrous tholeiite at 15 kbar. At higher pressure, rutile is the only Ti-rich accessory phase, and is present to at least 1000°C and high degrees of melting. Published REE data on sphene and rutile suggest that these phases may be important in controlling REE distribution in some magmas. For example, island are high-Mg, low-Ca-Ti tholeiites with low REE abundances and U-shaped patterns (Hickey and Frey, 1979) may reflect the role of sphene. In addition to rutile, similar close-packed Ti-rich accessory phases such as priderite, perovskite, crichtonite and loveringite may occur in mantle-derived magmas. These phases readily accommodate the REE but their possible role needs experimental confirmation.Apatite is recorded in hawaiite (1.16% P2Os) with 2% H2O added at 5–6 kbar and 1050°C within 30°C of the liquidus, but at present no other experimental data are available on its high P, T stability, although thermodynamic calculations indicate that F may increase its stability markedly. Apatite is well known in high-pressure inclusions and as a phenocryst phase in rocks of the alkaline and calc-alkaline series.Ilmenite is known as a near-liquidus phase in some mafic magmas at 5–10 kbar, but its stability decreases to near-solidus at 25–30 kbar. Zoisite occurs in hydrous mafic compositions at mantle pressures, but it is confined to temperatures < 780°C. Finally, mica has a wide temperature range of stability at mantle pressures, especially in potassic magmas, and phlogopitic mica is stable to 1040°C at 20–25 kbar in a hydrous, K-rich “tholeiite” (1.6% K2O).  相似文献   

2.
The densities of silicate liquids with basic, picritic, and ultrabasic compositions have been estimated from the melting curves of minerals at high pressures. Silicate liquids generated by partial melting of the upper mantle are denser than olivine and pyroxenes at pressures higher than 70 kbar, and garnet is the only phase which is denser than the liquid at pressures from 70 kbar to at least 170 kbar. In this pressure range, garnet and some fraction of liquid separate from ascending partially molten diapirs. It is therefore suggested that aluminium-depleted komatiite with a high Ca/OAl2O3 ratio may be derived from diapirs which originated in the deep upper mantle at pressures from 70 kbar to at least 140 kbar (200–400 km in depth), where selective separation of pyropic garnet occurs effectively. On the other hand, aluminium-undepleted komatiite is probably derived from diapirs originating at shallower depths (< 200 km). Enrichment of pyropic garnet is expected at depths greater than 200 km by selective separation of garnet from ascending diapirs. The 200-km discontinuity in the seismic wave velocity profile may be explained by a relatively high concentration of pyropic garnet at depths greater than 200 km.  相似文献   

3.
W. G. Ernst 《Island Arc》1999,8(2):125-153
The Dabie-Sulu belt of east-central China, the Kokchetav Complex of northern Kazakhstan, the Maksyutov Complex of the South Urals, the Dora Maira Massif of the Western Alps, and the Western Gneiss Region of southwestern Norway lie astride intracontinental suture zones. All represent collisional mountain belts. Adjoining Eurasian regions exhibit little or no evidence of a coeval calc-alkaline arc. Each metamorphic complex contains mineralogic and textural relics of the presence or former existence of coesite ± diamond. Other ultrahigh-P, moderate-T metamorphic phases, including K-rich clinopyroxene, Mg-rich garnet, ellenbergerite, lawsonite, Al-rutile, glaucophane, high-Si phengite, and associations such as coesite + dolomite, magnesite + diopside, and talc + kyanite, diopside, jadeite, or phengite also testify to pressures approaching or exceeding 2.8 GPa. Each of the five well-studied Eurasian ultrahigh-pressure complexes consists chiefly of old, cool continental crust. Deep-seated recrystallization took place during the Phanerozoic. Subduction zones constitute the only known plate-tectonic environment where such high-P, low-T conditions exist. A model involving underflow of a salient of continental crust imbedded in oceanic crust-capped lithosphere explains the ultrahigh- pressure metamorphism. Partly exhumed ultrahigh-pressure terranes consist of relatively thin sheets 7 ± 5 km thick. During early stages of plate descent, hydration of relatively anhydrous units occurs, and volatiles are expelled from hydrous rocks. If present, aqueous fluids markedly catalyze reactions. Experimental studies on MORB bulk compositions demonstrate that, for common subduction-zone P–T trajectories, amphibole (the major hydrous phase in metabasaltic rocks) dehydrates at less than ~ 2.0 GPa; accordingly, mafic blueschists and amphibolites expel H2O at great depth and, except for some coarse-grained, dry metagabbros, tend to recrystallize to eclogite. Serpentinized mantle beneath the oceanic crust devolatilizes at comparable pressures. In contrast, phengite and biotite remain stable to pressures exceeding 3.5 GPa in associated quartzofeldspathic rocks. So, under ultrahigh-pressure conditions, the micaceous lithologies that dominate the continental crust fail to evolve significant H2O, and may transform incompletely to eclogitic assemblages. Although hydrous rocks expel volatiles during compaction and shallow burial, very deep underflow of partly hydrated oceanic crust + mantle generates most of the volatile flux along and above a subduction zone prior to continental collision. As large masses of sialic crust enter the convergent plate junction, fluid evolution at deep levels severely diminishes, and both convergence and dehydration terminate. After cessation of ultrahigh-pressure recrystallization, tectonic slices of sialic massifs return to shallow depths along the subduction channel, propelled by buoyancy; collisional sheets that retain ultrahigh-pressure effects lose heat efficiently across both upper (extensional, normal fault) and lower (subduction, reverse fault) tectonic contacts. These sheets ascend to midcrustal levels rapidly at average exhumation rates of 2–12 mm/year. Surviving ultrahigh-pressure relics occur as micro-inclusions encased in dense, strong, impermeable, unreactive mineralogic hosts, and are shielded during return towards conditions characteristic of midcrustal levels. Rehydration attending decompression is incomplete; its limited extent reflects the coarse grain size and relative impermeability of the rocks undergoing retrogression, as well as declining temperature and lack of aqueous fluids.  相似文献   

4.
Hofmann[1] found that the depleted mantle (DM) and bulk continental crust (BCC) are simply compen-satory in terms of many elements and elemental ratios. High-field-strength elements (HFSE) (e.g., Zr, Hf, Nb, Ta and Ti) are immobile and thus useful to track the primary features of the ancient mafic volcanics. It has been long considered that Nb-Ta behave as identical twins during magmatic processes, based on their matching atomic radii and valence state and hence coherent geochemical affi…  相似文献   

5.
Thirty-four samples from the Changjiang and Huanghe were analyzed to characterize their rare earth element (REE) compositions. Although REE concentrations in the Changjiang sediments are higher than those of the Huanghe sediments, the former are less variable. Bulk samples and acid-leachable fractions have convex REE patterns and middle REE enrichments relative to upper continental crust, whereas flat patterns are present in the residual fractions. Source rock composition is the primary control on REE composition, and weathering processes play a minor role. Grain size exerts some influence on REE composition, as demonstrated by the higher REE contents of clay minerals in sediments from both rivers. Heavy minerals contribute about 10-20% of the total REE in the sediments. Apatite is rare in the river sediments, and contributes less than 2% of the REE content, but other heavy minerals such as sphene, allanite and zircon are important reservoirs of residual REE fractions. The Fe-Mn oxides phase accounts for about 14% of bulk REE content in the Changjiang sediments, which could be one of the more important factors controlling REE fractionation in the leachable fraction.  相似文献   

6.
Phase assemblages for five selected compositions in the system CaSiO3-Al2O3 have been investigated in the pressure range 100–300 kbar and at about 1000°C in a diamond-anvil press coupled with laser heating. At pressures below about 250 kbar, the assemblage of grossularite plus corundum is stable for compositions containing more than 25 mole% Al2O3. Above about 250 kbar, phase assemblages for the latter compositions are truncated by those in the join CaAl2O4-SiO2. Garnet solid solutions are stable between about 10 and 25 mole% Al2O3. Grossularite transforms to a new tetragonal form at pressures greater than about 250 kbar, but the stability field for the garnet solid solutions extends to pressures up to about 300 kbar. The perovskite modification appears to be stable at pressures above about 150 kbar, but is probably limited to nearly pure CaSiO3 composition. Phase behaviour for calcium-bearing silicates or aluminosilicates in the lower mantle are apparently more complicated than was suggested earlier.  相似文献   

7.
Pyroxene (omphacitic) and garnet (pyrope-rich) are the two major mineral components of an eclogite. No high-pressure phase transformation has been observed in omphacite and pyrope in the pressure range between 30 and 200 kbar and at 1000°C. The phase behaviour of the DSDP3-18 glass (basaltic and eclogitic composition) has been investigated in the pressure range between 100 and 280 kbar at about 1000°C in a diamond-anvil press coupled with laser heating. Both omphacite and garnet were observed in the range 100 to 150 kbar and garnet is the only phase observed in the 180-kbar run. However, it was inferred from other evidence that garnet also coexists with diopside (II) in the 180-kbar run. Diopside (II) is an unquenchable phase which is impossible to preserve on release of pressure. Glasses were the only products quenched from runs carried out at pressures greater than 210 kbar. These glasses were also interpreted as diopside(II). The phase behaviour of this complex eclogite composition at pressures below 200 kbar generally resembles that of a simple enstatite-pyrope system; pyroxene progressively dissolves in garnet with increasing pressure. The P-T conditions for the pyroxene ? garnet transition and the accompanying density (or velocity) change in the eclogitic composition are not consistent with those of the 400-km discontinuity in the Earth's mantle. Thus, an eclogitic mantle composition would not undergo a phase transformation which would be capable of accounting for the major seismic discontinuity observed in the vicinity of 400 km.  相似文献   

8.
The origin of orogenic andesitic magmas is tested by calculations of REE fractionation in hydrous melts derived from partial melting of subducted ocean basalt in eclogite facies. New data on the subsolidus phase proportions of basaltic eclogite, the enrichment of LREE in altered ocean basalts, and experimentally determined REE partition coefficients (KD's) between garnet and melt have been included in trace element fractionation equations. Non-modal melting of phases combined with variation inKD's during melting is a unique feature of these calculations.Variation ofKD, melting proportions, initial proportion of subsolidus phases, degree of melting, and initial REE concentrations yield a wide range of input parameters that produce REE profiles in partial melts of basaltic eclogite matching REE profiles of some orogenic andesites. The positive correlation of REE concentration with silica content for many andesitic suites can be accounted for by non-modal melting if quartz (or a similar phase with low REEKD values) melts at a high melting proportion and garnet melts at a low melting proportion during the first stages of fusion. However, no mineralogic fractionation scheme can account for REE/silica systematics if REEKD values are linearly decreasing with increasing melting. Earlier workers who have used similar calculations to discredit the eclogite fractionation model have set overly strict, and sometimes incorrect, constraints concerning the range in REEKD values for garnet, the subsolidus proportions of phases in basaltic eclogite, and the relative concentrations of REE in subducted ocean crust undergoing partial melting.  相似文献   

9.
The Cenozoic basaltic province of the Vogelsberg area (central Germany) is mainly composed of intercalated olivine to quartz tholeiites and near-primary nephelinites to basanites. The inferred mantle source for the alkaline and tholeiitic rocks is asthenospheric metasomatized garnet peridotite containing some amphibole as the main hydrous phase. Trace element modelling indicates 2 to 3% partial melting for the alkaline rocks and 5 to 7% partial melting for the olivine tholeiites. Incompatible trace element abundances and ratios as well as Nd and Sr radiogenic isotope compositions lie between plume compositions and enriched mantle compositions and are similar to those measured in Ocean Island Basalts (OIB) and the Central European Volcanic Province elsewhere. The mafic olivine tholeiites have similar Ba/Nb, Ba/La and Nd–Sr isotope ratios to the alkaline rocks indicating derivation of both magma types from chemically comparable mantle sources. However, Zr/Nb ratios are slightly higher in olivine tholeiites than in basanites reflecting some fractionation of Zr relative to Nb during partial melting. Quartz tholeiites have higher Ba/Nb, Zr/Nb, La/Nb, but lower Ce/Pb ratios and lower Nd isotope compositions than the alkaline rocks which can be explained by interaction of the basaltic melt with lower (granulite facies) crustal material or partial melts thereof during stagnation within the lower crust. It appears most likely that upwelling of hot, asthenospheric material results in the generation of primitive alkaline rocks at the base of the lithosphere at depths of 75–90 km. Lithospheric extension together with minor plume activity and probably lower lithosphere erosion induced melting of shallower heterogenous upper mantle generating a spectrum of olivine tholeiitic melts. These olivine tholeiitic rocks evolved via crystal fractionation and probably limited contamination to quartz tholeiites.  相似文献   

10.
Phase equilibria in a portion of the system forsterite-plagioclase (An50Ab50 by weight)-silica-H2O have been determined at 15 kbar pressure under H2O-saturated conditions. The composition of the liquid pertinent to the piercing point forsterite + enstatite solid solution + amphibole + liquid + vapor is similar to that of calc-alkaline andesite. The electron microprobe analysis of the glass coexisting with the above three crystalline phases is very close to that of the piercing point determined by phase assemblage observations; however, the glass near (< 8 μm) forsterite crystals is significantly depleted in the normative forsterite component. With the addition of 10 wt.% KAlSi3O8, the composition of this piercing point becomes even closer to the compositions of calc-alkaline andesites. It is also shown that the liquid coexisting with forsterite and enstatite solid solution remains silica-rich (60–62 wt.%) over a wide (~ 100°C) temperature range. The present experimental studies support the view that liquids similar in composition to calc-alkaline andesites can be generated by direct partial melting of hydrous upper mantle at least at or near 15 kbar.  相似文献   

11.
W. Cui  X. Wang 《Island Arc》1995,4(4):347-361
Abstract According to field occurrence and P-T condition, eclogites of southern Henan and northern Hubei Provinces can be divided into two types: medium temperature (MT) and low temperature (LT) eclogites. MT eclogite occurs as layers or lenticular bodies within migmatized gneiss of the Dabie Group. This study is the first to report an occurrence of the assemblages coesite and kyanite + talc in this area. Garnet exhibits a distinct prograde compositional zoning and has mineral inclusions with rotational textures indicating syntectonic growth. Five evolutionary stages are outlined. (1) Pre-eclogite stage, determined by the inclusions of barroisite + zoisite + quartz in the cores of zoned garnets. (2) Eclogite stage, characterized by garnet + omphacite + kyanite ± talc + coesite + rutile, represents the peak metamorphism. The peak conditions are estimated to be T = 600-700°C, P >27 kb. (3) Glaucophane stage, without an appearance of plagioclase, is assigned to a transitional stage. Blades of glaucophane form rims around garnet grains as a result of the reaction talc + jadeite = glaucophane. This marks the beginning of retrograde metamorphism. (4) Symplectite stage, where eclogitic minerals break down, and Amp + Pl symplectite develops around garnet or omphacite; (5) Later retrograde stage is represented by epidote-amphibolite assemblages. Low temperature eclogite appears as blocks in the Qijiaoshan Formation (part of the Susong Group). Four stages can be identified: (1) Pre-eclogite stage, amphibole + epidote + sphene inclusions occur in garnet core; (2) Eclogite stage, consists of garnet + omphacite + rutile + quartz + phengite + glaucophane + zoisite. The peak conditions are T = 490-560°C, P <15 kb; (3) Symplectitic stage, is characterized by the breakdown of eclogitic minerals; (4) Greenschist facies stage, is recorded by a greenschist facies assemblage. The difference between the two types of eclogites suggests contrasting processes. A model is proposed whereby partial melting of continental crust and the emplacement of tonalite occurs during the exhumation of ultrahigh-pressure eclogite terrain.  相似文献   

12.
A model, in which dissolved ions migrate through water films surrounding mineral grains to sites of reaction, predicts the geologically rapid occurrence of the gabbro-eclogite phase change in the earth's mantle at temperatures less than 600–800°C. In a water-undersaturated mantle, interstices within the rock can contain water vapor in equilibrium with small amounts of hydrous phases such as chlorite, tremolite or talc and in the presence of other gases such as CO2, at H2O pressures less than the lithostatic pressure of the rock. The solubility of ions in this interstitial water vapor is strongly dependent on pressure and is the rate-limiting process in the model; reaction occurs rapidly if the water pressure is at least 0.5–1 kbar. The 5 km of oceanic gabbroic crust can transform to eclogite upon subduction into the mantle at depths of several tens of kilometers, depending on the rate of heating of the descending crustal material and the nature of the minor hydrous phases present. The downward body force on the descending slab due to the eclogitization of oceanic crust is comparable to the downward forces associated with thermal contraction of the slab and the elevation of the olivine-spinel phase boundary.  相似文献   

13.
The North China Craton (NCC) has been thinned from >200 km to <100 km in its eastern part. The ancient subcontinental lithospheric mantle (SCLM) has been replaced by the juvenile SCLM in the Meoszoic. During this period, the NCC was destructed as indicated by extensive magmatism in the Early Cretaceous. While there is a consensus on the thinning and destruction of cratonic lithosphere in North China, it has been hotly debated about the mechanism of cartonic destruction. This study attempts to provide a resolution to current debates in the view of Mesozoic mafic magmatism in North China. We made a compilation of geochemical data available for Mesozoic mafic igneous rocks in the NCC. The results indicate that these mafic igneous rocks can be categorized into two series, manifesting a dramatic change in the nature of mantle sources at ~121 Ma. Mafic igneous rocks emplaced at this age start to show both oceanic island basalts (OIB)-like trace element distribution patterns and depleted to weakly enriched Sr-Nd isotope compositions. In contrast, mafic igneous rocks emplaced before and after this age exhibit both island arc basalts (IAB)-like trace element distribution patterns and enriched Sr-Nd isotope compositions. This difference indicates a geochemical mutation in the SCLM of North China at ~121 Ma. Although mafic magmatism also took place in the Late Triassic, it was related to exhumation of the deeply subducted South China continental crust because the subduction of Paleo-Pacific slab was not operated at that time. Paleo-Pacific slab started to subduct beneath the eastern margin of Eruasian continent since the Jurrasic. The subducting slab and its overlying SCLM wedge were coupled in the Jurassic, and slab dehydration resulted in hydration and weakening of the cratonic mantle. The mantle sources of ancient IAB-like mafic igneous rocks are a kind of ultramafic metasomatites that were generated by reaction of the cratonic mantle wedge peridotite not only with aqueous solutions derived from dehydration of the subducting Paleo-Pacific oceanic crust in the Jurassic but also with hydrous melts derived from partial melting of the subducting South China continental crust in the Triassic. On the other hand, the mantle sources of juvenile OIB-like mafic igneous rocks are also a kind of ultramafic metasomatites that were generated by reaction of the asthenospheric mantle underneath the North China lithosphere with hydrous felsic melts derived from partial melting of the subducting Paleo-Pacific oceanic crust. The subducting Paleo-Pacific slab became rollback at ~144 Ma. Afterwards the SCLM base was heated by laterally filled asthenospheric mantle, leading to thinning of the hydrated and weakened cratonic mantle. There was extensive bimodal magmatism at 130 to 120 Ma, marking intensive destruction of the cratonic lithosphere. Not only the ultramafic metasomatites in the lower part of the cratonic mantle wedge underwent partial melting to produce mafic igneous rocks showing negative εNd(t) values, depletion in Nb and Ta but enrichment in Pb, but also the lower continent crust overlying the cratonic mantle wedge was heated for extensive felsic magmatism. At the same time, the rollback slab surface was heated by the laterally filled asthenospheric mantle, resulting in partial melting of the previously dehydrated rocks beyond rutile stability on the slab surface. This produce still hydrous felsic melts, which metasomatized the overlying asthenospheric mantle peridotite to generate the ultramafic metasomatites that show positive εNd(t) values, no depletion or even enrichment in Nb and Ta but depletion in Pb. Partial melting of such metasomatites started at ~121 Ma, giving rise to the mafic igneous rocks with juvenile OIB-like geochemical signatures. In this context, the age of ~121 Ma may terminate replacement of the ancient SCLM by the juvenile SCLM in North China. Paleo-Pacific slab was not subducted to the mantle transition zone in the Mesozoic as revealed by modern seismic tomography, and it was subducted at a low angle since the Jurassic, like the subduction of Nazca Plate beneath American continent. This flat subduction would not only chemically metasomatize the cratonic mantle but also physically erode the cratonic mantle. Therefore, the interaction between Paleo-Pacific slab and the cratonic mantle is the first-order geodynamic mechanism for the thinning and destruction of cratonic lithosphere in North China.  相似文献   

14.
Geochemistry and petrogenesis of ophiolites from Northern Pindos (Greece)   总被引:1,自引:0,他引:1  
The ophiolitic complex of Northern Pindos (Greece) contains ocean-floor basalts and low-Ti mafic rocks. The former rocks are similar to recent mid-ocean ridge basalts with a light REE depletion and a La/Yb ratio < 2. The low-Ti rocks resemble boninites in their high Mg and very low Ti and Zr contents and in their REE patterns which have convex-downwards shape with a slight light REE enrichment. However, their Zr/Ti, Ti/V and Zr/Y ratios are lower than in boninites. Both rock-types could be generated by dynamic partial melting of a rising upper mantle diapir. Slight enrichment in light REE, Sr, Rb and Ba in low-Ti rocks could be the result of either metasomatic or alteration processes. Although a subduction zone origin of the sequence is possible, the geochemical data do not necessarily imply such a setting.  相似文献   

15.
Modern adakite, Archean tonalite-trondhjemite- granodiorite (TTG) and adakitic rocks derived from lower continental crust are high Na and Al felsic rocks and are characterized by strong heavy REE and Y de- pletion and high Sr/Y and La/Yb ratios, which sug…  相似文献   

16.
GHODRAT TORABI 《Island Arc》2012,21(3):215-229
Late Permian trondhjemites in the Anarak area occur as stocks and dykes, which cross cut the Anarak ophiolite and its overlying metasedimentary rocks, and are exposed along the northern Anarak east–west main faults. These leucocratic intrusive bodies have enclaves of all ophiolitic units and metamorphic rocks. They are composed of amphibole, plagioclase (oligoclase), quartz, zircon and muscovite. Secondary minerals are chlorite (pycnochlorite), epidote, albite, magnetite and calcite. Whole‐rock major‐ and trace‐element analyses reveal that they are characterized by high SiO 2 (67.8–71.0 wt%), Al 2 O 3 (14.9–17.1 wt%) and Na 2 O (5.3–8.6 wt%), low K 2 O (0.1–1.5 wt%; average: 0.8 wt%), low Rb/Sr ratio (0.01–0.40; average: 0.09), low Y (3–6 ppm), negative Ti, Nb and Ta anomalies, slightly negative or positive Eu anomaly, LREE enrichment and fractionated HREE. These rocks present 2 to 40 times enrichment in inclined chondrite‐normalized REE patterns. Geochemical characteristics of the Anarak trondhjemites all reflect melting of a mafic protolith at more than 10 kbar. The field evidence and whole‐rock chemistry reveal that these rocks have been crystallized from magmas derived from melting of subducted Anarak oceanic crust. This study reveals that melting of garnet amphibolite was an important element of continent formation in the study area.  相似文献   

17.
An Aleutian high-alumina basalt from the island of Atka at one atmosphere crystallizes plagioclase (1275°C) followed by olivine (1170°C) and clinopyroxene (1115°C). At oxygen fugacities along NNO, magnetite crystallizes below 1070°C, but its liquidus increases to at least 1175°C at an oxygen fugacity two log units above NNO. Phase relations at two kilobars pressure of melts containing small amounts of water are similar, although orthopyroxene and magnetite are observed to follow clinopyroxene. Amphibole crystallizes at near-liquidus temperatures only at water contents of melts approaching 4.5%. Amphibole assumes the liquidus in melts containing 5% water.Anhydrous melts crystallize plagioclase to 19 kbar, where garnet and clinopyroxene assume the liquidus. Olivine yields to clinopyroxene as the highest-temperature subliquidus phase at about 9 kbar.The array of compositions of basaltic Atka rocks, as displayed on appropriate pseudoternary projections, can be interpreted as a crystal fractionation path at moderate pressure (8 kbar) and small melt-water contents. The interpreted fractionating minerals are olivine, clinopyroxene, plagioclase, and (probably) magnetite. (The actual phenocrysts in Atka basalts like AT-1, which lacks phenocrystic clinopyroxene, must have crystallized at pressure less than 8 kbar, however.) The compositions of two-pyroxene andesites from Atka can be interpreted to lie on a lower-pressure fractionation trend at melt water contents of 2–3%. Such water contents are consistent with the complete absence of amphibole in any Atka rocks and are suggestive that water contents of the basaltic magmas, if the basalts are parental to the andesites, were 1–2%.  相似文献   

18.
143Nd/144Nd ratios, and Sm and Nd abundances, are reported for particulates from major and minor rivers of the Earth, continental sediments, and aeolian dusts collected over the Atlantic, Pacific, and Indian Oceans. Overall, Sm/Nd ratios and Nd isotopic compositions in contemporary continental erosion products vary within the small ranges of 147Sm/144Nd= 0.115 ± 0.01 and143Nd/144Nd= 0.51204 ± 0.0002 (εNd = −11.4 ± 4). The average period of residence in the continental crust is estimated to be1.70 ± 0.35Ga.

These results combined with data from the literature have implications for the age, history, and composition of the sedimentary mass and the continental crust: (1) The average “crustal residence age” of the whole sedimentary mass is about 1.9 Ga. (2) The range of Nd isotope compositions in the continent derived particulate input to the oceans is the same as Atlantic sediments and seawater, but lower than those of the Pacific, demonstrating the importance of Pacific volcanism to Pacific Nd chemistry. (3) The average ratio of Sm/Nd is about 0.19 in the upper continental crust, and has remained so since the early Archean. This precludes the likelihood of major mafic to felsic or felsic to mafic trends in the overall composition of the upper continental crust through Earth history. (4) Sediments appear to be formed primarily by erosion of continental crust having similar Sm/Nd ratios, rather than by mixing of mafic and felsic compositions. (5) The average ratio of 143Nd/144Nd≈ 0.5117 (εNd ≈ −17) in the upper continental crust, assuming its mean age is about 2 Ga. (6) The uniformity of the SmNd isotopic systematics in river and aeolian particulates primarily reflects efficient recycling of old sediment by sedimentary processes on a short time scale compared to the amount of time the material has resided in the crust.  相似文献   


19.
Huronian basalts from central Ontario, Canada, dated at about 2450 Ma and associated with an early rifting episode, are classified as siliceous, low-TiNb tholeiites. They display strong enrichment in large-ion lithophile (LILE) and light rare earth (LREE) elements compared to modern oceanic lavas. The tectonic setting and geochemistry resemble Mesozoic rift-related low-Ti flood basalts, including the Ferrar Group of Antarctica, and the Parana and equivalent Etendeka volcanics of south Brazil and Namibia, respectively. High LILE/LREE ratios are also similar to subduction-related island arc tholeiites, and it is suggested that enrichment of the Huronian lithospheric mantle source occurred through ancient subduction of crustal material, probably during formation and consolidation of the Archean continental crust.Melting models suggest that Huronian subcontinental mantle source compositions, derived from least contaminated, aphyric, mafic end-members, had already undergone a complex evolution, including withdrawal of Archean basalts and hydrous enrichment in incompatible components. Despite several subsequent melting episodes and a second, probably magmatic, enrichment event, however, many aspects of the Huronian source signature were preserved, and appeared in later basaltic products of this mantle mass. Keweenawan volcanics, for example, dated at about 1100 Ma, preserve low P, Zr, Ti and HREE abundances.  相似文献   

20.
An introduction to ultrahigh-pressure metamorphism   总被引:6,自引:0,他引:6  
Abstract Ultrahigh-pressure (UHP) metamorphism refers to mineralogical and structural readjustment of supracrustal protoliths and associated mafic-ultramafic rocks at mantle pressures greater than ∼ 25 kbar (80-90 km). Typical products include metapelite, quartzite, marble, granulite, eclogite, paragneiss and orthogneiss; minor mafic and ultramafic rocks occur as eclogitic-ultramafic layers or blocks of various dimensions within the supracrustal rocks. For appropriate bulk compositions, metamorphism at great depths produces coesite, microdiamond and other characteristic UHP minerals with unusual compositions. Thus far, at least seven coesite-bearing eclogitic terranes and three diamond-bearing UHP regions have been documented. All lie within major continental collision belts in Eurasia, have similar supracrustal protoliths and metamorphic assemblages, occur in long, discontinuous belts that may extend several hundred kilometers or more, and typically are associated with contemporaneous high-P blueschist belts. This paper defines the P-T regimes of UHP metamorphism and describes mineralogical, petrological and tectonic characteristics for a few representative UHP terranes including the western gneiss region of Norway, the Dora Maira massif of the western Alps, the Dabie Mountains and the Su-Lu region of east-central China, and the Kokchetav massif of the former USSR. Prograde P-T paths for coesite-bearing eclogites require abnormally low geothermal gradients (approximately 7°C/km) that can be accomplished only by subduction of cold, oceanic crust-capped lithosphere ± pelagic sediments or an old, cold continent. The preservation of coesite inclusions in garnet, zircon, omphacite, kyanite and epidote, and microdiamond inclusions in garnet and zircon during exhumation of an UHP terrane requires either an extraordinarily fast rate of denudation (up to 10 cm/year) or continuous refrigeration in an extensional regime (retreating subduction zone).  相似文献   

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