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1.
The importance of study of heavy metal distribution in river sediments is a component in understanding the exogenic cycling as well as in assessing the effect of anthropogenic influences of the elements. In India, the river Subernarekha flows over Precambrian terrain of Singhbhum craton in the eastern India. The geological succession in this part of India is through (1) iron ore series, (2) ultrabasic igneous rocks, (3) diorite, (4) granite, (5) newer dolerites, (6) newer tertiary and (7) alluvium. The first four groups belong to the Archaean era, and the representative is the iron ore series consisting of iron ore, manganese and chromite which are abundantly present. The primary rock types are schist and quartzite layers. One main tributary, the Kharkhai flow through granite and schist and quartzite layers. Two important creeks are Gurma and Garra, respectively. The former after originating in basic igneous area travels through schist quartzite, while the later one originates in granite area where some functional but old gold mines are located. Freshly deposited sediments of river were collected upstream and downstream the industrial zone (East Singhbhum district). Samples were collected from four locations and analysed in <63 μm sediment fraction for heavy metals like Ni, Co and Cr by adsorption stripping voltammetry on hanging mercury drop electrode and Hg by anodic stripping voltammetry using polished rotating gold disk electrode. Enrichment of these metals over and above the local natural concentration level (NCL) has been calculated and applied to determine metal-pollution index (MPI) proposed by Goncalves et al. and also geo-accumulation index (I geo) by Muller. Based on Muller’s classification, Ni, Cr and Hg have been classified from unpolluted to moderately polluted range in pre-monsoon period but for metals Ni and Cr, during the post-monsoon period the values have reached moderately polluted level while Hg has been classified under unpolluted to moderately polluted level except at the monitoring station situated upstream to Gurma Creek where it was found at unpolluted level. Presence of natural resources of the minerals is primarily the reason for their detection in river sediments (lithogenic) but some anthropogenic sources are also contributing for their presence at some sampling stations. Hg is considered to be chalcophilic in nature and is detected wherever known sulphidic ores of copper or nickel are present.  相似文献   

2.
The Ballachulish igneous complex in the Scottish Highlands, part of a widespread group of late Caledonian calcalkaline intrusions, was emplaced at a depth of 10 km into Dalradian metasediments resulting in melting of the country rocks near the intrusive contact. The greatest extent of melting occurred in the Leven schist in the 400 m wide so-called Chaotic Zone which experienced infiltration of aqueous fluids from the pluton. In contrast, adjacent to the Chaotic Zone, the feldspar-bearing Appin quartzite underwent significant melting only within a few metres of the intrusion, despite both being in contact with the same fluid source as the Leven schist and having a similar (wet) melting point. The permeability of the Appin quartzite and quartz horizons in the Leven schist to pervasive grain-edge infiltration of aqueous fluids was determined by measuring the equilibrium quartz-H2O dihedral angle for the P-T conditions of contact metamorphism. Addition of powdered samples of both rock types to the pure quartz-H2O system results in a linear decrease of the quartz-H2O dihedral angle with increasing temperature. The rate of this decrease for the Leven schist is greater than that for the Appin quartzite, and the angle decreases below 60° some 30 °C below the wet solidus (670 °C at 0.3 GPa). Charges bearing Appin quartzite had dihedral angles greater than 60° at all temperatures below the wet solidus (690 °C at 0.3 GPa). These results demonstrate that quartz-rich horizons in the Leven schist would have been permeable to infiltration of aqueous fluids close to the solidus, permitting extensive H2O-fluxed melting to occur. The Appin quartzite would have remained impermeable to grain-edge flow, consistent with the observed differences in the extent of partial melting of the two lithologies. Received: 25 November 1996 / Accepted: 29 October 1997  相似文献   

3.
Mercury concentrations (HgT) in fine-grained fraction (<63 μm) of core sediments of the Hugli–Matla–Bidyadhari estuarine complex, India were analyzed. Results revealed a wide range of spatial variations (<4–93 ng g−1 dry weight) with a definite enhancement level at the lower stretch of the estuarine complex infested with mangrove plants, which might act as a sink to HgT. An elevated concentration of Hg was encountered in surface/subsurface layer of the core in majority of the cases resulting from physical, biogenic and postdepositional diagenetic processes that remobilized and resuspended the metal from deeper sediments. A strong positive correlation was observed between the Hg and clay fraction content of the sediments, while the correlations of Hg with Al, Fe and Mn were poor. Based on the index of geoaccumulation (I geo) and effects range-low (ER-L) value, it is considered that the sediments are less polluted and thus there is less chance of ecotoxicological risk to organisms living in sediments.  相似文献   

4.
The evolution of the Indian Shield has been envisaged from the analysis of available tectono-lithostratigraphic, geochronological, geochemical and geophysical data. It appears that the Dharwar schist belts and their equivalents, except the Kolar schist belt, are not typical greenstone belts, but are representative of a transitional era of rapid transformation from simatic to sialic crust. In the Archaean—Proterozoic tract of India, relics of rocks older than 3.0 b.y. are identified in five widely separated regions of distinct tectono-litho-stratigraphic assemblages which probably represent the primordial continental nucleii. It is suggested that the growth of the Indian Shield has taken place through nucleation, accretion and merger into three protocontinents named Dharwar, Aravalli and Singhbhum. The cratonisation of the Indian unit seems to have been rapid and almost completed by the middle Proterozoic, as there is no significant variation in the composition of the clastic sediments and basalts from middle Proterozoic onwards. The continental nucleii appear to merge along the deep-seated lineaments, which are reflected on the tectonic map of India. Further, the Dharwar, Aravalli and Singhbhum protocontinents also seem to merge along a Y=shaped Narmada—Son—Godavari lineament which along with the Mahanadi lineament, between the two continental nucleii of the Singhbhum protocontinent have later developed into rift valleys.  相似文献   

5.
Pyrophyllite deposit at Madrangjodi is a large lensoidal massif overlain unconformably by Dhanjori quartzite and underlain by the parent Singhbhum granite (Phase — II). Pyrophyllite and quartz are the major minerals with minor to trace amounts of muscovite, chloritoid opaques and tourmaline. It is broadly divisible into lamellar, granular and schistose varieties. SiO2 (66.90–74.36%) and Al2O3 (20.80–27.54%) are the major oxides. The major elements data indicate its derivation from Singhbhum granite with depletion of SiO2 and increment of Al2O3. Trace and REE data are discussed to corroborate its genesis.  相似文献   

6.
Studies on the suspended particulate matter (SPM) in the Mandovi estuary, western India indicate that during the monsoon and pre-monsoon, the SPM increases, and the major and trace metals decrease from stations in the upstream to downstream of the estuary. SPM is consistently low at all stations during the post-monsoon. Trace metals (Cu, Ni, Zn, Cr, and Pb) show strong inter-relationships. They correlate well with Fe and Mn only during the monsoon. The concentrations of Cr, Cu, and Pb are high during the post-monsoon. Enrichment factors and I geo values of metals indicate that Mn shows significant to strong pollution in all seasons, while Cr, Ni, and Zn during monsoon, and Cr during the post-monsoon show moderate pollution. SPM is controlled by the turbidity maximum, while major and trace metals are governed seasonally by a combination of river discharge, resuspension, spillage of Fe–Mn particulates, and anthropogenic contamination. Incursion of saline waters deep into the river channel during the dry season facilitates aggregation and settling of particulate-borne pollutants close to the discharge area, thereby keeping the estuarine waters free from major contamination.  相似文献   

7.
Recrystallized grain size was measured from quartzite mylonite specimens collected from parts of Singhbhum shear zone in eastern India. The specimens were collected along five traverses (Mushabani, Pathargora, Surda, Rakha and Jadugoda) across the elongation of the shear zone. The sheared quartzites range from protomylonite through mylonite to ultramylonite. The microstructural studies of the specimens reflect that dynamic recrystallization was the main deformation process. Estimation of flow stresses were derived from these specimens using empirical equations relating to flow stress and recrystallized grain size. The calculated stresses range from 12–28 MPa (Mercieret al 1977), 23–49 MPa (Twiss 1977), 20–68 MPa (Christie and Ord 1980), considering all the traverses. The results show that these values can only be used semiquantitatively.  相似文献   

8.
Emerald, the green gem variety of beryl (Be3Al2Si6O18), is the third most valuable gemstone after diamond and ruby. The green colour appearance of the crystal is due to trace of Cr3+ and V3+, which replaces Al3+ ions in the crystal lattice of beryl. The hue of green colour of emerald depends on the quantity of Cr3+ and V3+ present in the crystal. Be is incorporated along with Cr and/or V during the process of crystallization. Since Be is relatively rare in the upper continental crust, therefore specific geological and geochemical parameters are required for Be to be incorporated in the crystal lattice of emerald.The present work was carried out to understand the lithological and structural control of emerald occurrences in and around Gurabanda area within the Singhbhum shear zone (SSZ) of Singhbhum crustal province, eastern India. The biotite and serpentine schist belong to the Paleoproterozoic Dhanjori Group and constitute the major lithology of the area. Pegmatite and biotite schist contains a variety of gem minerals in abundance in the area and the gem quality emerald occur at the contact zone of quartz vein and mica-schist. Lithology and structure are the main controlling factors of gem-mineralization in the study area. The study indicates that regional metamorphism and deformation processes along the shear zone played a significant role in the formation of emerald deposits. It is inferred that Singhbhum shear zone facilitated a favourable condition, where the Be bearing pegmatites interacted with Cr bearing mica schist or ultramafic rocks to produce emerald crystal.  相似文献   

9.
To assess the pollution of heavy metal in dust fall, nine dust fall samples were collected during the heating period and non-heating period from Jinan, a city in northeastern China. The samples were analyzed for Cu, Pb, Zn and Cr and the contamination level of heavy metals was assessed on the basis of the geo-accumulation index (I geo). The results indicated that all of the four investigated metals accumulated significantly in the dust fall of Jinan, and the metal concentrations were much higher than background values. During the heating period, the mean values for Cu, Pb, Zn and Cr in the dust fall were 354.9, 688.5, 2,585.5 and 478.6 mg kg−1. During the non-heating period, the mean values for Cu, Pb, Zn and Cr in the dust fall were 228.2, 518.2, 1,933.9 and 96.3 mg kg−1, respectively. The I geo values calculated based on background values revealed that the contamination level of heavy metal in the dust fall ranges from moderately contaminated to heavily contaminated, and it mainly originates from traffic and industry. In this work, the dust fall residue compared to the standard reference was also chosen as the background value to calculate the I geo value. This method is useful for situations in which the background value is difficult to obtain.  相似文献   

10.
During the last two decades, the coastal environment of southeast India has experienced intense developments in industry, urbanization and aquaculture. Moreover, the 2004 mega tsunami has devastated this coast, thus affecting the coastal sediment characteristics. These two phenomena prompted a study to characterize the sediment, to understand the mechanisms influencing the distribution of heavy metals and to create baseline data for future impact assessment. Results showed that the coastal sediment was carpeted with a mosaic of sand and silty sand with a minor amount of clay. Heavy metal values showed maximum variation for Fe and minimum for Cd. Their average values showed the following decreasing trend: Fe > Cu > Zn > Pb > Cr > Ni > Cd. This study shows that the major source of metals at Kalpakkam coast are land-based anthropogenic ones, such as, discharge from industrial waste, agricultural waste, urban, municipal and slum sewage into the Buckingham canal, which in turn discharges into the sea through backwaters, particularly during northeast monsoon period. A clear signature of the role of backwater discharge increasing the concentration of a few metals in the coastal sediments during monsoon period was observed. Assessments of the degree of pollution, concentration factor (CF), geoaccumulation index (I geo) and pollution load index (PLI) have been calculated. CF values and I geo indicated that the coastal sediment is moderately polluted by Cu and Cd. Increase in Cu, Pb and Zn concentration during the monsoon period (October–January) compared to the rest of the year was noticed. Factor analysis and correlation among the heavy metals concluded that Cr, Ni, Cd and Fe are of crustal origin, whereas, Cu, Pb and Zn are from anthropogenic sources. Organic carbon content in the sediment increased during monsoon period, pointing to the role of land runoff and backwater discharge in enhancing its content. The study also elucidates the impact of the recent tsunami in depleting metal content in the coastal sediment as compared to the pre-tsunami period.  相似文献   

11.
近50年来抚仙湖重金属污染的沉积记录*   总被引：15，自引：8，他引：15  
文章以抚仙湖污染严重的北部和基本未受人类活动影响的中部为研究对象,分别采集了沉积岩芯FB和FZ,通过对岩芯的137 Cs测年和重金属元素(Cu,Ni,Ti,Cr,V,Pb,Cd和Zn)的含量分析,研究了湖泊重金属来源和污染历史,并利用地质累积指数法评价了湖泊重金属污染程度。结果表明:抚仙湖北部的平均沉积速率约为2.0~2.8mm/a;20世纪80年代以前,湖泊北部和中部的重金属元素(Cu,Ni,Ti,V,Pb,Cd,Zn)以自然来源为主;80年代以后,抚仙湖受到人类活动的影响,但湖泊中部Cu,Ni,Ti,V,Pb,Zn以及湖泊北部Cu,Ni,Ti,V仍以自然来源为主;湖泊北部Pb和Zn地质累积指数值小于1,属无污染到中度污染;北部Cd地质累积指数为3~4,达强度污染;中部Cd地质累积指数为2~3,属中强度污染;且Pb,Zn和Cd污染程度有加速增大的趋势。  相似文献   

12.
The Barabazar granite, exposed at the northern margin of Singhbhum craton, Eastern India, occurs along the South Purulia Shear Zone (SPSZ) and is emplaced into the Palaeoproterozoic metapelites and felsic volcanics of Singhbhum Group. Geochemical, petrographical and geochronological studies on the Barabazar granite addressed in the work have wide implications on understanding the geodynamics of SPSZ during Palaeoproterozoic to Mesoproterozoic. Geochemically, Barabazar granite displays limited range of major oxides, alkali enrichment and highly fractionated features (SiO2 > 75%; Eu/Eu* = 0.16–0.33; enrichment of K, Rb, Th, U and Nb; depletion of Ba, Sr, P and Ti). It is predominantly peraluminous (molar Al2O3/CaO+Na2O+K2O (A/CNK) =1.14–144) and contains abundant alkali feldspar, perthite, and minor plagioclase, biotite and accessory minerals. Geochemical and petrological data indicates that it is A-type granite, which formed in ‘Within plate granite’ tectonic set up. The Barabazar granite was emplaced at ca. 1771 Ma (Pb-Pb) in rift related environs and evolved by partial melting of stabilized lower/middle crust (initial 87Sr/86Sr = 0.7302 ± 0.0066 and μ1 = 8.5 ± 0.5). Subsequently, the shear zone (SPSZ) developed during the closure of the riftogenic basin and was reactivated during the Grenvillian orogeny (Ca. 900–1300 Ma), resulting in rehomogenisation of the strontium isotopes and thereby yielding younger whole-rock Rb-Sr isotope age of c. 971 Ma for the Barabazar granite. Probably during this tectonic event, the Singhbhum craton (Southern India Shield) would have finally juxtaposed with Northern Indian Shield along Central Indian Tectonic Zone (CITZ) during the global Grenvillian orogeny.  相似文献   

13.
The concentrations of heavy metals (Cr, Co, Ni, Cu, Zn, Pb, Cd, As, Hg, and Fe) in sediments of the Yangtze River, China, were investigated to evaluate levels of contamination and their potential sources. The lowest heavy metal concentrations were found in the source regions of the river basin. Relatively high concentrations of metals, except Cr, were found in the Sichuan Basin, and the highest concentrations were in the Xiangjiang and Shun’anhe rivers. All concentrations, except Ni, were higher than global averages. Principal component analysis and hierarchical cluster analysis showed that Zn, Pb, As, Hg, and Cd were derived mainly from the exploitation of various multi-metal minerals, industrial wastewater, and domestic sewage. Cu, Co, and Fe were derived mainly from natural weathering (erosion). Cr and Ni were derived mainly from agricultural activities, municipal and industrial wastewater. Sediment pollution was assessed using the geoaccumulation index (I geo) and enrichment factor (EF). Among the ten heavy metals assessed, Cd and Pb had the highest I geo values, followed by Cu, As, Zn, and Hg. The I geo values of Fe, Cr, Co, and Ni were <0 in all sediments. EF provided similar information to I geo: no enrichment was found for Cr, Co, and Ni. Cu, Zn, As, and Hg were relatively enriched at some sites while Cd and Pb showed significant enrichment.  相似文献   

14.
The ENE-plunging macroscopic folds, traced by calc gneiss interbanded with marble and sillimanite schist within the Peninsular Gneiss around Suganapuram in the ‘Palghat gap’ in southern India, represent structures of the second generation (D2). They have folded the axial planes of a set of D1 isoclinal folds on stratification coaxially, so that the mesoscopic D1 folds range from reclined in the hinge zones, through inclined to upright in the limb zones of the D2 folds. Orthogonal relation between stratification and axial planar cleavage, and ‘M’ shaped folds on layering locate the hinge zones of the D1 folds, whereas folds on axial planar cleavage with ‘M’ shaped folds are the sites of the D2 fold hinges. Extreme variation in the shapes of the isoclinal D1 folds from class 1B through class 1C to nearly class 2 of Ramsay is a consequence of buckling followed by flattening on layers of widely varying viscosity contrast. The large ENE-trending structures in this supracrustal belt within the Peninsular Gneiss in the ‘Palghat gap’ could not have evolved by reorientation of NS-trending structures of the Dharwar tectonic province to the north by movement along the Moyar-Bhavani shear zone which marks the boundary between the two provinces. This is because the Moyar and Bhavani faults are steep dipping reverse faults with dominant dip-slip component. Deceased  相似文献   

15.
Street dust is one of the important indicators that reflect the status of urban environmental pollution. There are many studies of heavy metals contamination of street dust in capital cities; however, little attention has been paid to this kind of study in medium cities, including China. The dust samples were collected in the district of traffic crossroads in Xianyang city, Shaanxi Province. Pb, Cd, Cu, Ni, Zn, Cr and Mn concentrations were determined using atomic absorption spectrometry (AAS). The results indicate that the concentrations of heavy metals are higher than the background values of soils in Shaanxi Province. The contamination level of heavy metals is assessed by potential ecological risk index (E r), geoaccumulation index (I geo), enrichment factor (EF) and pollution index (Pi). The low I geo, EF, E r, Pi and PIn (integrated pollution index) for Mn in street dusts indicate an absence of distinct Mn pollution. The high EF, Pi and PIn of Cu and Zn indicate that there is considerable Cu and Zn pollution. It is suggested that more attention should be paid to heavy metals contamination of Cu and Zn. The assessment results of Pi and PIn suggest that Pb, Ni and Cr present strong pollution; however, their EFs indicate that they cause moderate pollution and their I geo indicates that they are unpolluted to moderately polluted. The contamination class value with different assessing methods is of the order: Pi ≈ PIn > EF > I geo > E r.  相似文献   

16.
The contents of Co, Cr, Cu, Mn, Ni, Pb and Zn in the dust samples collected from Changqing industrial park of Baoji city, NW China, were measured by XRF, while As and Hg in the dust samples were analyzed by AFS. Geo-accumulation index (I geo), pollution index (PI) and integrated pollution index (IPI) were calculated to evaluate the heavy metal contamination level of dust. The health risk due to exposure to heavy metals in dust was analyzed by the Health Risk Assessment Model of US EPA. The results show that the arithmetic means of As, Co, Cr, Cu, Hg, Mn, Ni, Pb and Zn are 23.3, 16.4, 1591.8, 178.2, 0.243, 346.5, 40.2, 1,586.2 and 1,918.8 mg kg?1, respectively, which are higher than the background values of Shaanxi soil, especially for Cr, Cu, Hg, Pb, and Zn. The mean values of I geo reveal the order of Pb > Zn > Cr > Hg > Cu > As > Co > Ni > Mn. The high I geo of Cr, Cu, Hg, Pb and Zn in dust indicates that there is considerable pollution from Cr, Cu, Hg, Pb and Zn, while the low I geo of As, Co, Mn and Ni presents no pollution in dust. The assessment results of PI support the results of I geo, and IPI indicates heavy metals in dust polluted seriously. The health risk assessment shows that ingestion of dust particles is the route for exposure to heavy metals from dust, followed by dermal adsorption. Exposure to As, Cr and Pb from dust may pose a potential health threat to children and adults. The risk of cancer from As, Co, Cr and Ni due to dust exposure is low.  相似文献   

17.
温格哈尔金矿床位于内蒙古乌拉特中旗巴音杭盖苏木境内。区内出露地层为古元古界宝音图群(Pt1BY)上部石英岩、大理岩,中上元古界温都尔庙群绿片岩(Jxhr),志留系哈达呼舒群(S1-2HD)含石榴角岩、千枚岩和变质砂岩,侵入岩以海西期二长花岗岩、石英闪长岩、斜长花岗岩为主。通过对温格哈尔金矿勘查区1∶1万物化探工作、异常查证和地质综合评价,在勘查Ⅰ区内圈定金矿化体20余条,并认为该金矿是与都尔庙群绿片岩有关的热液型金矿。  相似文献   

18.
Summary Mineral chemistry and petrological data of chromites from chromitite bands in the N–S trending schist belt of Nuggihalli (southern Karnataka, India), belonging to the Dharwar craton of South India, are presented in this paper. Crystal chemical data indicate a komatiitic affinity of the chromitite. P–T calculations of the chromite-hosting peridotites yielded a pressure range of 13 to 28 kbar and temperatures ranging from 775 to 1080 °C; the oxygen fugacity (log fO2) varies from +0.5 to +1.6 above the QFM buffer. The P, T and fO2 data indicate that Nuggihalli chromitites crystallized in an environment akin to the upper mantle. The studied samples also show partial resetting; the lower temperatures ranging from 515 to 680 °C are ascribed to subsequent metamorphism of the area.  相似文献   

19.
Concentration and distribution of heavy metals (Cd, Cu, Pb and Zn) in urban soils of Hangzhou, China, were measured based on different land uses. The contamination degree of heavy metals was assessed on the basis of pollution index (PI), integrated pollution index (IPI) and geoaccumulation index (I geo). The 0.1 mol l−1 HCl extraction procedure and gastric juice simulation test (GJST) were used to evaluate the potential mobility and environmental risk of heavy metals in urban soils. The average concentration of Cd, Cu, Pb and Zn in urban soils was measured at 1.2 (with a range of 0.7–4.6), 52.0 (7.4–177.3), 88.2 (15.0–492.1) and 206.9 (19.3–1,249.2) mg kg−1, respectively. The degree of contamination increased in the order of industrial area (IA) > roadside (RS) > residential and commercial areas (RC) > public park and green areas (PG). The PIs for heavy metals indicated that there is a considerable Cd, Cu, Pb and Zn pollution, which originate from traffic and industrial activities. The IPI of these four metals ranged from 1.6 to 11.8 with a mean of 3.5, with the highest IPI in the industrial area. The assessment results of I geo also supported that urban soil were moderately contaminated with Cd and to a lesser extent also with Cu, Pb and Zn. The IP and I geo values reveal the pollution degree of heavy metal was the order of Cd > Pb > Zn ≈ Cu. It was shown that mobility and bioavailability of the heavy metals in urban soils increased in the order of Cd > Cu > Zn ≈ Pb. Owing to high mobility of Cd and Cu in the urban soils, further investigations are needed to understand their effect on the urban environment and human health. It is concluded that industrial activities and emissions from vehicles may be the major source of heavy metals in urban contamination. Results of this study present a rough guide about the distribution and potential environmental and health risk of heavy metals in the urban soils.  相似文献   

20.
Pu  Wanqiu  Sun  Jiaqi  Zhang  Fangfang  Wen  Xingyue  Liu  Wenhu  Huang  Chengmin 《中国地球化学学报》2019,38(5):753-773

Metallic ore mining causes heavy metal pollution worldwide. However, the fate of heavy metals in agrosystems with long-term contamination has been poorly studied. Dongchuan District (Yunnan, southwest China), located at the middle reaches of the Xiaojiang River, is a well-known 2000-year-old copper mining site. In this work, a survey on soil heavy metal contents was conducted using a handheld X-ray fluorescence instrument to understand the general contamination of heavy metals in the Xiaojiang River Basin. Furthermore, river water, soil, and rice samples at six sites along the fluvial/alluvial fans of the river were collected and analyzed to implement an environmental assessment and an evaluation of irrigated agrosystem. V, Zn, and Cu soil levels (1724, 1047, and 696 mg·kg−1, respectively) far exceeded background levels. The geo-accumulation indexes (Igeo) showed that cultivated soils near the mining sites were polluted by Cd and Cu, followed by Zn, V, Pb, Cr, Ni, and U. The pollution index (Pi) indicated that rice in the area was heavily polluted with Pb, Cr, Cd, Ni, Zn, and Cu. The difference in orders of metal concentrations between the soil and rice heavy metal contamination was related to the proportion of bioavailable heavy metals in the soil. The crop consumption risk assessment showed that the hazard quotient exceeded the safe threshold, indicating a potential carcinogenic risk to consumers. The Nemerow integrated pollution index and health index indicated that the middle of the river (near the mining area) was the heaviest polluted site.

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