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1.
The source of whitings on the Great Bahama Bank and their relationship to major changes in the chemistry of Bank waters have been among the longest and most hotly debated topics in carbonate geochemistry. In this paper, we demonstrate that the reaction kinetics of calcite with Bank waters for a given saturation state are similar to, but somewhat slower (2 to 3 times) than with Gulf Stream water. The interpretation of the reaction kinetics of suspended Bank sediment with Bank water requires that the precipitating phase be about twice as soluble as aragonite. Good agreement at equivalent saturation states was found between experimental precipitation rates and those calculated for the rate of change of Bank water chemistry in the region of whitings. These results indicate that the dominant mode of carbonate removal is via precipitation on resuspended sediments rather than the rapid pseudo-homogeneous precipitation of calcium carbonate in the water column resulting in the formation of a whiting. Estimates indicate that single aragonite needles may be resuspended many times over a period of decades during which they experience repeated overgrowth. A major portion (>98%) of suspended calcium carbonate is outside the visually dramatic whitings. Thus, as visually spectacular as they are, whitings do not represent a short-term locally massive precipitation of carbonate on the Great Bahama Bank, nor are they even likely to be the dominant sites of carbonate removal in this region. Although future refinements are needed that include seafloor processes, we have at this point arrived at a mechanistic kinetic model that provides a reasonably quantitative explanation for the hydrochemistry of the carbonate system on the northern Great Bahama Bank.  相似文献   

2.
Great quantities of fine-sized aragonite needles are produced in the shallow waters that cover the tops of the Bahama Banks and then exported to the bank margins where they accumulate with shells of pelagic organisms. To better understand these processes, we investigated Holocene-aged sediments in a core from the southwestern margin of Little Bahama Bank. The aragonite content of the sediments, ??18O of planktonic foraminifera shells, and radiocarbon ages of aragonite-rich <63 ??m sediments and coexisting planktonic foraminifera shells were determined. Sediment deposition was rapid overall, and a significant increase in deposition rate occurred 3,500?C4,000 years ago, shortly after rising sea level flooded the bank top with seawater and caused a dramatic increase in the shallow water area where aragonite production occurred. During the latest Holocene when high deposition rates minimize effects of bioturbation, aragonite-rich <63 ??m sediments are 400?C600 years older than coexisting foraminifera. This difference indicates the net age of aragonite when it was exported from the bank top. It is consistent with expectations of the ??hip-hop??n?? model (Morse et al. in Geochimica et Cosmochimica Acta 67: 2819?C2826, 2003) whereby aragonite needles on the bank top, formed initially by biologic or other processes, continue to grow for hundreds of years via precipitation of epitaxial carbonate cement from seawater. Earlier in the Holocene, when sea level was lower and the top of Little Bahama Bank was subaerially exposed, the deposition rate and aragonite content of the sediments were less, and the aragonite-rich <63 ??m sediments are about 1,000 years younger than coexisting foraminifera. This age difference can be explained by downward mixing of latest-Holocene <63 ??m material into older early-Holocene sediments.  相似文献   

3.
The stable isotope geochemistry of Miocene sediments from the leeward margin of the Great Bahama Bank was examined to investigate burial diagenetic processes in periplatform carbonates. Data indicate that, in addition to differences in bulk proportions of neritic and pelagic carbonate along the slope, rhythmic variation in primary carbonate content has controlled patterns of burial diagenesis and associated geochemical signatures throughout much of the succession examined. The present study focuses on Ocean Drilling Program Sites 1006 and 1007, the most distal of five sites drilled from marginal to deep basin environments during Leg 166. These Miocene sections are characterized by their cyclic appearance, manifest as decimetre‐ to metre‐scale alternations between light‐coloured ooze/chalk/limestone and dark‐coloured marl/marlstone. The section at Site 1006 contains a high proportion of pelagic carbonate and is unlithified to a subbottom depth of ～675 m. Fluctuations in δ18O and δ13C values at this site are independent of lithological variation and reflect primary conditions. At Site 1007, located at the toe‐of‐slope and composed of a mixture of bank‐derived and pelagic carbonate, limestones are densely cemented, show little evidence of compaction and have δ18O values up to 2‰ higher than coeval sediments at Site 1006. Marlstones at Site 1007 are poorly cemented, exhibit an increase in compaction‐related features with depth and have lower and more variable δ18O values that are similar to those of coeval sediments at Site 1006. Isotopic and petrographic characteristics of limestone interbeds result from cement precipitation from cold sea water during the first ～100 m of burial. Higher proportions of insoluble materials and pelagic carbonate seem to have inhibited diagenetic alteration in adjacent marlstones; in spite of significant compaction and pressure solution during burial, original isotopic compositions appear to be best preserved in these intervals at Site 1007. The documented contrasts in petrographic and isotopic patterns illustrate the role of primary sediment composition in controlling lithification processes in periplatform carbonates and stress the importance of considering such factors when interpreting geochemical data from ancient shelf and slope limestones.  相似文献   

4.
Isolated carbonate platforms occur throughout geological history, and commonly exhibit considerable spatial variability. To evaluate the controls on the nature of sediment accumulation across the expansive, shallow platform tops, this study systematically compares and contrasts patterns in surface sediments from several shallow (<10 m) Holocene Bahamian examples. Remote‐sensing data, field observations, petrographic characterization and quantitative grain‐size analyses reveal the spatial patterns of sediment accumulation on Crooked–Acklins Platform and the Berry Islands Bank. Integration of these data with synoptic observations of waves, tides and currents, along with regional geochemical data, provides a means to explore the factors that influence platform‐scale sedimentary patterns. These data illustrate that the platform interiors of both Crooked–Acklins Platform and Berry Islands Bank are blanketed with medium to coarse sand size sediment. Peloids are most common in the interior of Crooked–Acklins Platform, whereas the Berry Islands Bank includes more abundant composite grains. In both areas, very little mud is present, with surface sediments averaging <2% mud. Comparison of these results with published data from Little Bahama Bank, Great Bahama Bank and Caicos Platform suggest that, contrary to previous interpretations, the presence of open margins and/or brisk winds are not necessary for the occurrence of a platform top with little mud. Although the muddy sediment fraction of the interior can be suspended by elevated wave energy, wind‐generated current speeds in protected platform interiors are relatively low. Instead, in parts of the platform interiors, transport and winnowing of fines is enhanced greatly by tidal currents, which carry suspended sediments off the shallow platforms, even if shielded by islands. Beyond physical influences, however, regional geochemical compilations suggest that the Bahamian tides supply highly supersaturated waters rich in dissolved oxygen to these platform interiors. This exchange is interpreted to facilitate favourable conditions for calcium carbonate precipitation in the form of ooids, marine cements and hardened peloids across vast expanses of the platform interiors. Such fundamental controls on Holocene platform‐scale sediment dynamics are likely to have influenced carbonate systems through the geological record.  相似文献   

5.
Anatomy of a modern open-ocean carbonate slope: northern Little Bahama Bank   总被引：1，自引：0，他引：1  
The open-ocean carbonate slope north of Little Bahama Bank consists of a relatively steep (4°) upper slope between water depths of 200 and 900 m, and a more gentle (1–2°) lower slope between depths of 900 and 1300+ m. The upper slope is dissected by numerous, small, submarine canyons (50–150 m in relief) that act as a line source for the downslope transport of coarse-grained carbonate debris. The lower slope is devoid of any well-defined canyons but does contain numerous, small (1–5 m) hummocks of uncertain origin and numerous, larger (5–40 m), patchily distributed, ahermatypic coral mounds. Sediments along the upper slope have prograded seaward during the Cenozoic as a slope-front-fill seismic facies of fine-grained peri-platform ooze. Surface sediments show lateral gradation of both grain size and carbonate mineralogy, with the fine fraction derived largely from the adjacent shallow-water platform. Near-surface sedimentary facies along the upper slope display a gradual downslope decrease in the degree of submarine cementation from well-lithified hardgrounds to patchily cemented nodular ooze to unlithified peri-platform ooze, controlled by lateral variations in diagenetic potential and/or winnowing by bottom currents. Submarine cementation stabilizes the upper part of the slope, allowing upbuilding of the platform margin, and controls the distribution of submarine slides, as well as the headward extent of submarine canyons. Where unlithified, sediments are heavily bioturbated and are locally undergoing dolomitization. Upper slope sediments are also ‘conditioned’eustatically, resulting in vertical, cyclic sequences of diagenetically unstable (aragonite and magnesian calcite-rich) and stable (calcite-rich) carbonates that may explain the well-bedded nature of ancient peri-platform ooze sequences. Lower slope sediments have prograded seaward during the Cenozoic as a chaotic-fill seismic facies of coarse-grained carbonate turbidites and debris flow deposits with subordinate amounts of peri-platform ooze. Coarse clasts are ‘internally’derived from fine-grained upper slope sediments via incipient cementation, submarine sliding and the generation of sediment gravity flows. Gravity flows bypass the upper slope via a multitude of canyons and are deposited along the lower slope as a wedge-shaped apron of debris, parallel to the adjacent shelf edge, consisting of a complex spatial arrangement of localized turbidites and debris flow deposits. A proximal apron facies of thick, mud-supported debris flow deposits plus thick, coarse-grained, Ta turbidites, grades seaward into a distal apron facies of thinner, grain-supported debris flow deposits and thinner, finer grained Ta-b turbidites with increasing proportions of peri-platform ooze. Both the geomorphology and sedimentary facies relationships of the carbonate apron north of Little Bahama Bank differ significantly from the classic submarine fan model. As such, a carbonate apron model offers an alternative to the fan model for palaeoenvironmental analysis of ancient, open-ocean carbonate slope sequences.  相似文献   

6.
Core, logging and high-resolution seismic data from ODP Leg 166 were used to analyse deposits of the Neogene (Miocene–Lower Pliocene) Bahamian outer carbonate ramp. Ramp sediments are cyclic alternations of light- and dark-grey wackestones/packstones with interbedded calciturbidite packages and minor slumps. Cyclicity was driven by high-frequency sea-level changes. Light-grey layers containing shallow-water bioclasts were formed when the ramp exported material, whereas the dark-grey layers are dominantly pelagic. Calciturbidites are arranged into mounded lobes with feeder channels. Internal bedding of the lobes shows a north-directed shingling as a result of the asymmetrical growth of these bodies. Calciturbidite packages occur below and above sequence boundaries, indicating that turbidite shedding occurred during third-order sea-level highstands and lowstands. Highstand turbidites contain shallow-water components, such as green algal debris and epiphytic foraminifera, whereas lowstand turbidites are dominated by abraded bioclastic detritus. Gravity flow depocentres shifted from an outer ramp position during the early Miocene to a basin floor setting during the late Miocene to early Pliocene. This change was triggered by an intensification of the strength of bottom currents during the Tortonian, which was also responsible for shaping the convex morphology of the outer ramp. The Miocene and Lower Pliocene of the leeward flank of Great Bahama Bank provides an example of the poorly known depositional setting of the outer part of distally steepened carbonate ramps. The contrast between its sedimentary patterns and the well-known Upper Pliocene–Quaternary slope facies associations of the flat-topped Great Bahama Bank shows the strong control that the morphology of a carbonate platform exerts on the depositional architecture of the adjacent slope and base-of-slope successions.  相似文献   

7.
In an effort to constrain the mechanism of dolomitization in Neogene dolomites in the Bahamas and improve understanding of the use of chemostratigraphic tracers in shallow‐water carbonate sediments the δ34S, Δ47, δ13C, δ18O, δ44/40Ca and δ26Mg values and Sr concentrations have been measured in dolomitized intervals from the Clino core, drilled on the margin of Great Bahama Bank and two other cores (Unda and San Salvador) in the Bahamas. The Unda and San Salvador cores have massively dolomitized intervals that have carbonate associated sulphate δ34S values similar to those found in contemporaneous seawater and δ44/40Ca, δ26Mg values, Sr contents and Δ47 temperatures (25 to 30°C) indicating relatively shallow dolomitization in a fluid‐buffered system. In contrast, dolomitized intervals in the Clino core have elevated values of carbonate associated sulphate δ34S values indicating dolomitization in a more sediment‐buffered diagenetic system where bacterial sulphate reduction enriches the residual in 34S, consistent with high sediment Sr concentrations and low δ44/40Ca and high δ26Mg values. Only dolomites associated with hardgrounds in the Clino core have carbonate associated δ34S values similar to seawater, indicating continuous flushing of the upper layers of the sediment by seawater during sedimentary hiatuses. This interpretation is supported by changes to more positive δ44/40Ca values at hardground surfaces. All dolomites, whether they formed in an open fluid‐buffered or closed sediment‐buffered diagenetic system have similar δ26Mg values suggesting that the HMC transformed to dolomite. The clumped isotope derived temperatures in the dolomitized intervals in Clino yield temperatures that are higher than normal, possibly indicating a kinetic isotope effect on dolomite Δ47 values associated with carbonate formation through bacterial sulphate reduction. The findings of this study highlight the utility of applying multiple geochemical proxies to disentangle the diagenetic history of shallow‐water carbonate sediments and caution against simple interpretations of stratigraphic variability in these geochemical proxies as indicating changes in the global geochemical cycling of these elements in seawater.  相似文献   

8.
Sedimentary dynamics along carbonate slopes (Bahamas archipelago)   总被引：2，自引：0，他引：2       下载免费PDF全文
Hydroacoustic and sedimentological data in the Santaren Channel covering both the leeward slope of Great Bahama Bank and the windward slope of Cay Sal Bank allow new insights into carbonate platform slope sedimentation. The data document the interplay between depositional and erosive processes on both slopes through time and provide information on the current regime and its influence on the slope sedimentary processes. This study emphasizes the diversity and complexity of the slope morphology and the sediment distribution of the youngest high‐frequency sequence, which has developed since the last glacial maximum. The processes triggering slope failures and the formation of channels and gullies differ on both slopes. At the leeward slope of the Great Bahama Bank, extensive slope failures occurred primarily during sea‐level lowering following an interglacial. These slope failures created a slope morphology that channelizes the exported platform sediments during the subsequent highstand. At the windward slope of Cay Sal Bank, contour currents and the local tectonic regime are responsible for slope failures. During sea‐level lowstands, downwelling induces turbidity currents. The interaction of turbidity and contour currents leads to the formation of a system of furrows and slope‐parallel sediment ridges. The discovered heterogeneities in slope sedimentation improve the understanding of carbonate slope sedimentation and provide implications for sequence stratigraphic interpretation of carbonate platform slopes.  相似文献   

9.
Inorganic aragonite occurs in a wide spectrum of depositional environments and its precipitation is controlled by complex physio-chemical factors. This study investigates diagenetic conditions that led to aragonite cement precipitation in Cenozoic glaciomarine deposits of McMurdo Sound, Antarctica. A total of 42 sandstones that host intergranular cement were collected from the CIROS-1 core, located proximal to the terminus of Ferrar Glacier. Standard petrography, Raman spectroscopy and electron microprobe analysis reveal a prominent aragonite cement phase that occurs as a pore-filling blocky fabric throughout the core. Oxygen isotope compositions (δ18O = −30·0 to −8·6‰ Vienna Pee-Dee Belemnite) and clumped isotope temperatures (TΔ47 = 13·1 to 31·5°C) determined from the aragonite cements provide precise constraints on isotopic compositions (δ18Ow) of the parent fluid, which mostly range from −10·8 to −7·2‰ Vienna Standard Mean Ocean Water. The fluid δ18Ow values are consistent with those of pore water, previously identified as cryogenic brine in the nearby AND-2A core. Petrographic and geochemical data suggest that aragonite cement in the CIROS-1 core precipitated from a similar brine. The brine likely formed and infiltrated sediments in flooded glacial valleys along the western margin of McMurdo Sound during the middle Miocene Climatic Transition, and subsequently flowed basinward in the subsurface. Consequently, the brine forms as a longstanding subsurface fluid that has saturated Cenozoic sediments below southern McMurdo Sound since at least the middle Miocene. Aragonite cementation in the CIROS-1 core is interpreted to reflect its proximal position to sites of brine formation and greater likelihood of experiencing brines with sustained high carbonate saturation states and Mg/Ca ratios. This unusual occurrence expands the range of known natural occurrences of aragonite cement. Given the potential for cryogenic brine formation in glaciomarine settings, blocky aragonite, as the end member of the spectrum of aragonite cement morphology, may be more widespread in glaciomarine sediments than currently thought.  相似文献   

10.
《Sedimentology》2018,65(6):2088-2116
Carbonate slopes and associated resedimented deposits have recently gained renewed interest because they represent volumetrically significant parts of carbonate platforms. Carbonate slopes are highly variable compositionally, architecturally and spatially due to a spectrum of sediment sources, resedimentation processes and controlling factors. Here, new high resolution acoustic data (including EM 302 multi‐beam echo‐sounder and very high resolution seismic) and piston cores document highly diverse and complex morphological features along the north‐western slope of Great Bahama Bank. The recent morphology of the slope is the result of the interplay between depositional and erosive processes that vary through time and along strike. The different sedimentary processes are recorded as a Pleistocene lowstand surface, characterized by many erosional features and a Holocene sedimentary wedge along the upper to middle slope that partially covers the underlying Pleistocene surface. Sedimentary processes during the Holocene are dominated by density cascading flows, which export muddy aragonitic sediment from the platform top towards the slope. Sedimentation rates, however, vary along strike due to platform top morphology combined with the variable strength of the basinal current. Reefs and islands in the Bimini area block off‐bank sediment export, and shoals and tidal deltas from Cat Cay to the south reduce the density cascading processes. Numerous small and large slope failure scars show the instability of the steep slopes of Great Bahama Bank. Bottom currents dominate the lower slope and the basin. Striations and moats are the morphological expressions of current directions, while areas of non‐deposition document strong current and concomitant removal of off‐bank transported sediment along parts of the slope, while the Santaren Drift and the drift on the north‐western edge of Great Bahama Bank act as the depositional locus for the fine‐grained sediments transported in the current.  相似文献   

11.
Isotopic compositions of organic (δ13C-Corg) and carbonate (δ13C-Ccarb) carbon were analyzed in the particulate matter (hereafter, particulates) and sediments from the North and Middle Caspian basins. Isotopic composition of Corg was used for assessing proportions of the allochthonous and autochthonous organic matter in the particulates. Difference between the δ13C-Corg values in surface sediments and particulates is explained by the aerobic and anaerobic diagenetic transformations. Isotopic composition of Corg in sediments may be used as a tool for reconstructing the Quaternary transgressive-regressive history of the Caspian Sea.  相似文献   

12.
Studies of the δ13C of pore water dissolved inorganic carbon (δ13C-DIC) were carried out in shallow water carbonate sediments of the Great Bahamas Bank (GBB) to further examine sediment-seagrass relationships and to more quantitatively describe the couplings between organic matter remineralization and sediment carbonate diagenesis. At all sites studied δ13C-DIC provided evidence for the dissolution of sediment carbonate mediated by metabolic CO2 (i.e., CO2 produced during sediment organic matter remineralization); these observations are also consistent with pore water profiles of alkalinity, total DIC and Ca2+ at these sites. In bare oolitic sands, isotope mass balance further indicates that the sediment organic matter undergoing remineralization is a mixture of water column detritus and seagrass material; in sediments with intermediate seagrass densities, seagrass derived material appears to be the predominant source of organic matter undergoing remineralization. However, in sediments with high seagrass densities, the pore water δ13C-DIC data cannot be simply explained by dissolution of sediment carbonate mediated by metabolic CO2, regardless of the organic matter type. Rather, these results suggest that dissolution of metastable carbonate phases occurs in conjunction with reprecipitation of more stable carbonate phases. Simple closed system calculations support this suggestion, and are broadly consistent with results from more eutrophic Florida Bay sediments, where evidence of this type of carbonate dissolution/reprecipitation has also been observed. In conjunction with our previous work in the Bahamas, these observations provide further evidence for the important role that seagrasses play in mediating early diagenetic processes in tropical shallow water carbonate sediments. At the same time, when these results are compared with results from other terrigenous coastal sediments, as well as supralysoclinal carbonate-rich deep-sea sediments, they suggest that carbonate dissolution/reprecipitation may be more important than previously thought, in general, in the early diagenesis of marine sediments.  相似文献   

13.
The Broccatello lithological unit (Lower Jurassic, Hettangian to lower parts of Upper Sinemurian) near the village of Arzo (southern Alps, southern Switzerland) is a mound-shaped carbonate deposit that contains patches of red stromatactis limestone. Within the largely bioclastic Broccatello unit, the stromatactis limestone is distinguished by its early-diagenetic cavity system, a relatively fine-grained texture, and an in-situ assemblage of calcified siliceous sponges (various demosponges and hexactinellids). A complex shallow subsurface diagenetic pathway can be reconstructed from sediment petrography in combination with comparative geochemical analysis (carbon and oxygen isotopes; trace and rare earth elements, REE + Y). This pathway includes organic matter transformation, aragonite and skeletal opal dissolution, patchy calcification and lithification, sediment shrinkage, sagging and collapse, partial REE remobilization, and multiple sediment infiltration. These processes occurred under normal-marine, essentially oxic conditions and were independent from local, recurring syn-sedimentary faulting. It is concluded that the stromatactis results from a combination of calcite mineral authigenesis and syneresis-type deformation. The natural stromatactis phenomenon may thus be best explained by maturation processes of particulate polymer gels expected to form in fine-grained carbonate sediments in the shallow subsurface. Conditions favorable for the evolution of stromatactis appear to be particularly frequent during drowning of tropical or subtropical carbonate platforms.
Daniel BernoulliEmail:
  相似文献   

14.
Botryoidal aragonite and its diagenesis   总被引：1，自引：0，他引：1  
Botryoidal aragonite is a spectacular growth-form occurring as mamelons, up to 100 mm in diameter. Three examples of this particular carbonate cement have been discovered in two distinct areas: in New Caledonia, small-scale mamelons have been recognized within Pleistocene reefal terraces at Ouvea, an Island of the Loyalty archipelago, and in the Red Sea, large-scale mamelons of botryoidal aragonite exist within Pleistocene reefal terraces along the Um Gheig region of the Egyptian Coast. In addition, a similar botryoidal cement, partly dolomitized but exhibiting aragonite relics, occurs within a Miocene reef in the same region. Mamelons of botryoidal aragonite are isolated and/or coalescent but grow only on fixed substrates. They occur within cavities of varied origin. Their fabrics are characterized by fans of elongate euhedral crystals of aragonite fibres. Botryoidal aragonite can be preceded or followed by other types of cements or internal sediment. Despite similar mineralogy, petrography and ultrastructure, there are differences between the fabrics of the Pleistocene botryoids from the Red Sea and Ouvea and the Miocene botryoids from the Red Sea. The former are of submarine origin as confirmed by the strontium content (8500–10,500 ppm) and isotopic composition (δ18O between -0.10 and +0.19% PDB). The latter, related to a Miocene karst, are rich in strontium (average 13,600 ppm), and have an isotopic composition (average δ18O -10.50% PDB) indicative of non-marine precipitation. Diagenesis of these botryoidal aragonites consists of slight dissolution for Pleistocene botryoids and mineralogical transformation for the Miocene botryoids. The latter exhibit the diagenetic sequence aragonite → calcite → dolomite. The aragonite to calcite transformation is a dissolution-reprecipitation process, the void distribution and size influencing the distribution and the size of the replacement calcite crystals.  相似文献   

15.
The behavior of stable carbon and oxygen isotopes in carbonates during the deposition and diagenesis of sediments in the bioproductive Upper Famennian Pripyat Trough (southern Belarus) is discussed. Limestones and clayey limestones (Corg 0.92 ± 0.11%) are characterized by very low δ13C values (–9.6 ± 0.3‰). Parental sediments of these rocks were deposited in the shallow-water zone during slow downwarping episodes of the seafloor. Lithification of the sediments took place in oxidative conditions of the diagenesis zone. Organic matter was actively oxidized by free oxygen. Carbon dioxide with isotopically light organic carbon formed in this process was used during the crystallization of diagenetic carbonates that are visually indiscernible from the sedimentational variety. Marls, clayey marls, and carbonate-bearing clays (Corg 6.02 ± 0.80%) are characterized by δ13C values as high as –3.5 ± 0.6‰. In combustible shales (Corg >10%), δ13C value is ‒1.2 ± 0.6‰). The clayey rocks mark the episodes of sedimentation in relatively deep-water conditions that appear during the uncompensated sagging of the basin floor. The diagenetic zone with free oxygen was significantly decreased or absent at all. Here, oxygen of marine sulfates was the main or single oxidizer of organic matter (sulfate reduction). The sulfate oxygen is a weaker oxidizing agent than free oxygen. Therefore, much more organic matter was retained and fossilized in clayey rocks than in carbonate rocks. Organic carbon released during the sulfate reduction and mobilized later for the diagenetic carbonate formation was insufficient for the significant decrease of δ13C values relative to the marine carbonate standard. Isotopic composition of carbonate oxygen in the studied rocks is invariable and does not depend on the content of clay and organic matter. In these rocks, δ18O values are at the level (approximately –5‰) shown for the Famennian in the Global Chemostratigraphic Chart. This fact is consistent with the supposition that oxygen isotope composition of atmospheric precipitates, which influenced the rock formation via continental flow, is close to that of sea water in low latitudes where the territory of Belarus was located in the Late Devonian.  相似文献   

16.
New data collected along the slopes of Little and Great Bahama Bank and the abyssal plain of the Bahama Escarpment provides new insights about contour current‐related erosive structures and associated deposits. The Bahamian slope shows abundant evidence of bottom current activity such as furrows, comet‐like structures, sediment waves and drifts. At a seismic scale, large erosion surfaces and main periods of drift growth resulted from current acceleration related to plate tectonic processes and progressive opening and closure of gateways and long‐term palaeoclimate evolution. At present‐day, erosion features and contourite drifts are either related to relatively shallow currents (<1000 m water depth) or to deep currents (>2500 m water depth). It appears that the carbonate nature of the drifts does not impact the drift morphology at the resolution addressed in the present study. Classical drift morphologies defined in siliciclastic environments are found, such as mounded, plastered and separated drifts. In core, contourite sequences show a bi‐gradational trend that resembles classical contourite sequences in siliciclastic deposits showing a direct relationship with a change in current velocity at the sea floor. However, in a carbonate system the peak in grain size is associated with increased winnowing rather than increased sediment supply as in siliciclastic environments. In addition, the carbonate contourite sequence is usually thinner than in siliciclastics because of lower sediment supply rates. Little Bahama Bank and Great Bahama Bank contourites contain open‐ocean input and slope‐derived debris from glacial episodes. Inner platform, platform edge and open ocean pelagic input characterize the classical periplatform ooze during interglacials. In all studied examples, the drift composition depends on the sea floor topography surrounding the drift location and the type of sediment supply. Carbonate particles are derived from either the slope or the platform in slope and toe of slope drifts, very deep contourites have distant siliciclastic sources of sediment supply. The recent discovery of the importance of a large downslope gravitary system along Bahamian slopes suggests frequent interactions between downslope and along‐slope (contour currents) processes. The interlayering of mass flow deposits and contourites at a seismic scale or the presence of surface structures associated with both contour currents and mass flow processes shows that both processes act at the same location. Finally, contour currents have an important impact on the repartition of deep‐water coral mounds. Currents can actively interact with mounds as a nutrient and oxygen supplier or have a passive interaction, with mounds solely being obstacles orienting erosion and deposition.  相似文献   

17.
Vertical profiles of trace metal (Cd, Pb, Zn, Cu, Ni) concentrations, organic matter content, carbonate content and granulometric composition were determined in two sediment cores from the submarine pit Dragon Ear (Middle Adriatic). Concentrations of the analyzed metals (Cd: 0.06–0.12 mg kg−1, Pb: 28.5–67.3 mg kg−1, Zn: 17.0-65.4 mg kg−1, Cu: 21.1–51.9 mg kg−1, Ni: 27.8–40.2 mg kg−1) were in usual range for Adriatic carbonate marine sediments. Nevertheless, concentrations of Cu, Zn, and especially Pb in the upper layer of sediments (top 12 cm) were higher than in bottom layer, while Cd and Ni concentration profiles were uniform. Regression analysis and principal component analysis were used to interpret distribution of trace metals, organic matter and carbonate content in sediment cores. Results of both analysis showed that concentrations of all trace metals in the core below the entrance to the pit were significantly positively correlated with organic matter and negatively correlated with carbonate, while in the core more distant from the entrance only Pb showed significant positive correlation with organic matter. Obtained results indicated that, except for lead which was enriched in surface sediment, in the time of sampling (before the building of the nautical marina) investigated area belonged to unpolluted areas.  相似文献   

18.
The large acoustic data set acquired during the Carambar cruises is composed of high resolution bathymetry, backscatter data and very‐high resolution seismic lines which allow for an overview of the morphology and sediment transfer processes from the shallow upper slope to the abyssal plain of a modern carbonate system: the north‐eastern slope of the Little Bahama Bank. Surficial distribution of the acoustic facies and echofacies reflects a wide variety of sedimentary processes along and across the slope. The western sector of the Little Bahama Bank is dominated by depositional processes whereas its eastern sector, which is incised in the lower slope by giant canyons, is affected by erosion and bypass processes. Datasets suggest that currents play an important role both in along‐slope sedimentary processes and in the abyssal plain. The Antilles Current appears to affect a large part of the middle and lower slopes. The absence of sizeable present‐day channel/levée complexes or lobes at the mouth of the canyon – revealed by the bathymetric map – indicates that the southward flowing Deep Western Boundary Current influences modern abyssal sediment deposition. Based on depositional processes and indicators of canyon maturity observed in facies distribution, the current study proposes that differential subsidence affects the eastern versus western part of the bank. The morphology of the Great Abaco Canyon and Little Abaco Canyon, which extend parallel to the platform, and the Little Bahama Bank slope appears to be related to the Great Abaco Fracture Zone.  相似文献   

19.
Carbonate-rich sediments at shoal to shelf depths (<200 m) represent a major CaCO3 reservoir that can rapidly react to the decreasing saturation state of seawater with respect to carbonate minerals, produced by the increasing partial pressure of atmospheric carbon dioxide (pCO2) and “acidification” of ocean waters. Aragonite is usually the most abundant carbonate mineral in these sediments. However, the second most abundant (typically ∼24 wt%) carbonate mineral is high Mg-calcite (Mg-calcite) whose solubility can exceed that of aragonite making it the “first responder” to the decreasing saturation state of seawater. For the naturally occurring biogenic Mg-calcites, dissolution experiments have been used to predict their “stoichiometric solubilities” as a function of mol% MgCO3. The only valid relationship that one can provisionally use for the metastable stabilities for Mg-calcite based on composition is that for the synthetically produced phases where metastable equilibrium has been achieved from both under- and over-saturation. Biogenic Mg-calcites exhibit a large offset in solubility from that of abiotic Mg-calcite and can also exhibit a wide range of solubilities for biogenic Mg-calcites of similar Mg content. This indicates that factors other than the Mg content can influence the solubility of these mineral phases. Thus, it is necessary to turn to observations of natural sediments where changes in the saturation state of surrounding waters occur in order to determine their likely responses to the changing saturation state in upper oceanic waters brought on by increasing pCO2. In the present study, we investigate the responses of Mg-calcites to rising pCO2 and “ocean acidification” by means of a simple numerical model based on the experimental range of biogenic Mg-calcite solubilities as a function of Mg content in order to bracket the behavior of the most abundant Mg-calcite phases in the natural environment. In addition, observational data from Bermuda and the Great Bahama Bank are also presented in order to project future responses of these minerals. The numerical simulations suggest that Mg-calcite minerals will respond to rising pCO2 by sequential dissolution according to mineral stability, progressively leading to removal of the more soluble phases until the least soluble phases remain. These results are confirmed by laboratory experiments and observations from Bermuda. As a consequence of continuous increases in atmospheric CO2 from burning of fossil fuels, the average composition of contemporary carbonate sediments could change, i.e., the average Mg content in the sediments may slowly decrease. Furthermore, evidence from the Great Bahama Bank indicates that the amount of abiotic carbonate production is likely to decline as pCO2 continues to rise.  相似文献   

20.
Marbles from western part of the Krkonoše-Jizera Terrane (northern part of the Bohemian Massif) have been studied to obtain mineropetrographic and chemical reference data for provenance studies. Samples from six different quarries were analysed by mineralogical-petrographic and geochemical methods (optical microscopy, X-ray diffraction, stable isotope ratio analysis, cathodoluminescence, bulk magnetic susceptibility). Petrographic characteristics permit a distinction between fine-grained to medium-grained marbles from the Jizera Mts (amphibolite metamorphic facies) and fine-grained marbles from the Ještěd Mts (low-grade greenschist facies). The samples studied are mainly calcitic, with the exception of those from Raspenava in which dolomite is abundant in two types. The mineralogical composition of the insoluble residues is clinochlore ± serpentine ± tremolite ± diopside ± pyrite + magnetite in case of the locality Raspenava and clinochlore + muscovite ± quartz ± pyrite ± rutile ± haematite in case of the localities from the Ještěd Mts. δ13C and δ18O variations in primary and secondary carbonate phases allow to distinguish genetically different carbonate veins and permit quarry separation in one case (Raspenava, Jizera Mts). The δ13C and δ18O values of the groundmass range from −1 to +3‰ and from −8 to −20‰ (PDB), respectively. The δ13C and δ18O values of secondary carbonate veins decrease to −3‰ and reach more negative values up to −26‰ in case of δ18O. The fabric of cathodomicrofacies allows the distinction between calcite and dolomite, except three localities (Pilínkov, Horní Hanychov, Jitrava—rose type) with majority of quenchers (high content of iron in carbonate). The genetically different calcite is characterised by a pale and dark orange luminescence distribution. Serpentine, tremolite, forsterite, opaque minerals and quartz have no luminescence and very dull luminescence, respectively. The majority of studied marbles exhibits low values of the bulk magnetic susceptibility, with the exception of those from Raspenava rich in magnetite.  相似文献   

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