首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 156 毫秒
1.
Dolomites occur extensively in the lower Cretaceous along syn-sedimentary fault zones of the Baiyinchagan Sag, westernmost Erlian Basin, within a predominantly fluvial–lacustrine sedimentary sequence. Four types of dolomite are identified, associated with hydrothermal minerals such as natrolite, analcime and Fe-bearing magnesite. The finely-crystalline dolomites consist of anhedral to subhedral crystals (2 to 10 μm), evenly commixed with terrigenous sediments that occur either as matrix-supporting grains (Fd1) or as massive argillaceous dolostone (Fd2). Medium-crystalline (Md) dolomites are composed of subhedral to euhedral crystals aggregates (50 to 250 μm) and occur in syn-sedimentary deformation laminae/bands. Coarse-crystalline (Cd) dolomites consist of non-planar crystals (mean size >1 mm), and occur as fracture infills cross-cutting the other dolomite types. The Fd1, Md and Cd dolomites have similar values of δ18O (−20·5 to −11·0‰ Vienna PeeDee Belemnite) and δ13C (+1·4 to +4·5‰ Vienna PeeDee Belemnite), but Fd2 dolomites are isotopically distinct (δ18O −8·5 to −2·3‰ Vienna PeeDee Belemnite; δ13C +1·4 to +8·6‰ Vienna PeeDee Belemnite). Samples define three groups which differ in light rare-earth elements versus high rare-earth elements enrichment/depletion and significance of Tb, Yb and Dy anomalies. Medium-crystalline dolomites have signatures that indicate formation from brines at very high temperature, with salinities of 11·8 to 23·2 eq. wt. % NaCl and Th values of 167 to 283°C. The calculated temperatures of Fd1 and Cd dolomites extend to slightly lower values (141 to 282°C), while Fd2 dolomites are distinctly cooler (81 to 124°C). These results suggest that the dolomites formed from hydrothermal fluid during and/or penecontemporaneous with sediment deposition. Faults and fractures bounding the basin were important conduits through which high-temperature Mg-rich fluids discharged, driven by an abnormally high heat flux associated with local volcanism. It is thought that differing amounts of cooling and degassing of these hydrothermal fluids, and of mixing with lake waters, facilitated the precipitation of dolomite and associated minerals, and resulted in the petrographic and geochemical differences between the dolomites.  相似文献   

2.
Calcite septarian concretions from the Permian Beaufort Group in the Maniamba Graben (NW Mozambique) allow controls on the composition and nature of diagenetic fluids to be investigated. The concretions formed in lacustrine siltstones, where they occur in spherical (1 to 70 cm in diameter) and columnar (up to 50 cm long) forms within three closely spaced, discrete beds totalling 2·5 m in thickness. Cementation began at an early stage of diagenesis and entrapped non‐compacted burrows and calcified plant roots. The cylindrical concretions overgrew calcified vertical plant roots, which experienced shrinkage cracking after entrapment. Two generations of concretionary body cement and two generations of septarian crack infill are distinguished. The early generation in both cases is a low‐Mn, Mg‐rich calcite, whereas the later generation is a low‐Mg, Mn‐rich calcite. The change in chemistry is broadly consistent with a time (burial)‐related transition from oxic to sub‐oxic/anoxic conditions close to the sediment–water interface. Geochemical features of all types of cement were controlled by the sulphate‐poor environment and by the absence of bacterial sulphate reduction. All types of cement present have δ13C ranging between 0‰ and −15‰(Vienna Peedee Belemnite, V‐PDB), and highly variable and highly depleted δ18O (down to 14‰ Vienna Standard Mean Ocean Water, V‐SMOW). The late generation of cement is most depleted in both 13C and 18O. The geochemical and isotopic patterns are best explained by interaction between surface oxic waters, pore waters and underground, 18O‐depleted, reducing, ice‐meltwaters accumulated in the underlying coal‐bearing sediments during the Permian deglaciation. The invariant δ13C distribution across core‐to‐rim transects for each individual concretion is consistent with rapid lithification and involvement of a limited range of carbon sources derived via oxidation of buried plant material and from dissolved clastic carbonates. Syneresis of the cement during an advanced stage of lithification at early diagenesis is considered to be the cause of development of the septarian cracks. After cracking, the concretions retained a small volume of porosity, allowing infiltration of anoxic, Ba‐bearing fluids, resulting in the formation of barite. The results obtained contribute to a better understanding of diagenetic processes at the shallow burial depths occurring in rift‐bound, lacustrine depositional systems.  相似文献   

3.
This paper describes and interprets the mineral and facies assemblages that occur in carbonate–evaporite shallow lacustrine deposits, considering the importance of the processes pathway (i.e. dolomitization, gypsum calcitization and silicification). The Palaeogene deposits of the Deza Formation (Almazán Basin, central‐northern Spain) are selected as a case study to determine the variety of physicochemical processes taking place in carbonate–evaporite shallow lakes and their resulting diagenetic features. Dolostones are the predominant lithology and are composed mainly of dolomite with variable amounts of secondary calcite (5 to 50%), which mainly mimic lenticular gypsum (pseudomorphs). Five morphological types of dolomite crystal were identified as follows: dolomite tubes, dolomite cylinders, rhombohedral dolomite, spheroidal and quasi‐rhombohedral dolomite, and cocoon‐shaped dolomite. The dolomite cylinders and tubes are interpreted as the dolomitized cells of a widespread microbial community. The sequence of diagenetic processes started with growth of microlenticular interstitial gypsum in a calcareous mud deposited on the playa margin mudflats, and that sometimes included microbial sediments. Immediately following growth of gypsum, dolomite replaced the original calcite (or possibly aragonite) muds, the microbial community and the gypsum. Partial or total replacement of gypsum by dolomite was related mainly to the biomineralization of endolithic microbial communities on gypsum crystals. Later calcitization took place under vadose, subaerial exposure conditions. The development of calcrete in distal alluvial settings favoured the release of silica and subsequent silicification on the playa margin mudflats. Stable isotope compositions of calcite range from ?9·02 to ?5·83‰ δ13CPDB and ?7·10 to 1·22‰ δ18OPDB; for the dolomite, these values vary from ?8·93 to ?3·96‰ δ13CPDB and ?5·53 to 2·4‰ δ18OPDB. Quartz from the cherts has δ18OSMOW values ranging from 27·1 to 31·1‰. Wide variation and relatively high δ18OSMOW values for dolomite indicate evaporitic and closed hydrological conditions; increased influx of meteoric waters reigned during the formation of secondary calcite spar.  相似文献   

4.
Limestones containing radiaxial fibrous cements were sampled along the southern slope of the late Anisian (Middle Triassic) Latemar carbonate platform in the Dolomites, northern Italy. The Latemar upper slopes comprise massive microbial boundstone, whereas lower slopes are made of clinostratified grainstone, rudstone and breccia. Samples are representative of a seawater column from near sea‐level to an aphotic zone at about 500 m water depth. Radiaxial fibrous cements were analyzed for carbon (δ13C) and oxygen (δ18O) stable isotopic composition, as well as major and trace element content, to shed light on the origin of the slope facies zonation. The δ13C vary between 1·7‰ and 2·3‰ (Vienna Pee‐Dee Belemnite), with lowest values at palaeo‐water depths between 70 m and 300 m. Radiaxial fibrous cements yielded seawater‐like rare earth element patterns with light rare earth element depletion (NdSN/YbSN ≈ 0·4), superchondritic yttrium/holmium ratios (≈55) and negative cerium anomalies. Cadmium reaches maximum values of ca 0·5 to 0·7 μg/g at palaeo‐water depths between 70 m and 300 m; barium contents (0·8 to 1·8 μg/g) increase linearly with depth. The downslope patterns of δ13C and cadmium suggest increased nutrient and organic matter contents at depths between ca 70 m and 300 m and point to an active biological pump. The peak in cadmium and the minimum of δ13C mark a zone of maximum organic matter respiration and high nutrient and organic matter availability. The base of this zone at ca 300 m depth corresponds with the transition from massive microbial boundstone to clinostratified grainstone, rudstone and breccia. The microbial boundstone facies apparently formed only in seawater enriched in organic matter, possibly because this organic matter sustained benthic microbial communities at Latemar. The base of slope microbialites on high‐relief microbial carbonate platforms may be a proxy for the depth to maximum respiration zones of Palaeozoic and Mesozoic periplatform basins.  相似文献   

5.
This paper addresses the diagenesis of carbonate conglomerates in that it assesses the potential of conglomerates in refining the paragenetic history in complex structural areas, such as the Albanian foreland fold‐and‐thrust belt. Of major interest are stylolites (burial and tectonic) which are restricted to conglomerate fragments or which crosscut the conglomerate matrix. Based on the inferred age of stylolite development in relation to burial, uplift and tectonic history, and the Lower to Middle Miocene age of the conglomerates, the succession of diagenetic events was subdivided into several stages. The Poçem polymict transgressive carbonate conglomerate (Kremenara anticline, central Albania) was deposited in a shallow marine environment. These conglomerates are covered by intertidal rhodolithic packstones–grainstones. The stable‐isotope signature of these packstones–grainstones (δ18OV‐PDB = −1·0 to +0·7‰; δ13C = +1·0 to +1·4‰) plots is within the range of marine Early and Middle Miocene values. Shortly after deposition of the conglomerates, micritization, geopetal infill and acicular calcite cementation took place. A first calcite vein generation is interpreted as having formed from a Messinian brine during shallow burial. Burial stylolites developed during further burial in the Pliocene. These stylolites serve as an important diagenetic time marker. The post‐burial stylolite meteoric calcite vein cement probably precipitated during the following telogenetic stage. Karstification and calcite concretion precipitiation pre‐date overturning of the western limb of the anticline. Reopening of subvertical fractures and tectonic stylolites in the western limb of the Kremenara anticline, followed by oil migration, represents one of the latest diagenetic events. These fractures and stylolites provide major pathways for hydrocarbon production.  相似文献   

6.
The stability of sublittoral, fine-grained sediments in a subarctic estuary   总被引：1，自引：0，他引：1  
The erodibility of natural estuarine sediments was measured in sit along a longitudinal transect of Manitounuk Sound, Hudson Bay, using the benthic flume Sea Carousel. Sedimentation processes along the transect varied from continuous, rapid, post-glacial sedimentation in the inner Sound, to glacial outcrops and seabed reworking of the outer Sound. The grain size and physical bulk properties reflect changes in depositional environment and correlate with sediment erosion threshold stress (τc), erosion rate (E), erosion type and still-water mass settling rate. There was a steady increase in τc (0·8–2·0 Pa) with distance down the Sound in parallel with the decreasing sedimentation rate (0·003–0·001 m yr?1) and increasing sediment bulk density (1650–2010 kg m?3). The near-surface friction coefficient varied up to 68° in proportion to the clay content of post-glacial material. Glacial sediments were characterized by variable results and generally higher friction coefficients. Seabed erosion in Sea Carousel began with surface creep of loose aggregates, pellets and organic debris. This was followed by Type I bed erosion at rates that varied between 0·0002 and 0·0032 kg m?2 s?1 (mean 0·0015). Type I peak erosion rate was inversely related to applied bed shear stress (τo). Type II erosion succeeded Type I, often after a broad transitional period. Simulations of suspended sediment concentration in Sea Carousel were made using four commonly used erosion (E) algorithms. The best results were obtained using Krone's dimensionless ratio relationship: E=M(τo/τc-1). Simulations were highly sensitive to the definition of erosion threshold with sediment depth [τc(z)]. Small errors in definition of τc(z) caused large errors in the prediction of suspended sediment concentration which far exceeded differences between the methods tested.  相似文献   

7.
The Trigonodus Dolomit is the dolomitized portion of the homoclinal ramp sediments of the Middle Triassic Upper Muschelkalk in the south‐east Central European Basin. Various dolomitizing mechanisms, followed by recrystallization, have been previously invoked to explain the low δ18O, high 87Sr/86Sr, extensive spatial distribution and early nature of the replacive matrix dolomites. This study re‐evaluates the origin, timing and characteristics of the dolomitizing fluids by examining petrographic and isotopic trends in the Trigonodus Dolomit at 11 boreholes in northern Switzerland. In each borehole the ca 30 m thick unit displays the same vertical trends with increasing depth: crystal size increase, change from anhedral to euhedral textures, ultraviolet‐fluorescence decrease, δ18OVPDB decrease from ?1·0‰ at the top to ?6·7‰ at the base and an 87Sr/86Sr increase from 0·7080 at the top to 0·7117 at the base. Thus, dolomites at the top of the unit record isotopic values similar to Middle Triassic seawater (δ18OVSMOW = 0‰; 87Sr/86Sr = 0·70775) while dolomites at the base record values similar to meteoric groundwaters from the nearby Vindelician High (δ18OVSMOW = ?4·0‰; 87Sr/86Sr = >0·712). According to water–rock interaction modelling, a single dolomitizing or recrystallizing fluid cannot have produced the observed isotopic trends. Instead, the combined isotopic, geochemical and petrographic data can be explained by dolomitization via seepage‐reflux of hypersaline brines into dense, horizontally‐advecting groundwaters that already had negative δ18O and high 87Sr/86Sr values. Evidence for the early groundwaters is found in meteoric calcite cements that preceded dolomitization and in fully recrystallized dolomites with isotopic characteristics identical to the groundwaters following matrix dolomitization. This study demonstrates that early groundwaters can play a decisive role in the formation and recrystallization of massive dolomites and that the isotopic and textural signatures of pre‐existing groundwaters can be preserved during seepage‐reflux dolomitization in low‐angle carbonate ramps.  相似文献   

8.
The pyroclastic deposits of the Minoan eruption (ca 3600 yr bp ) in Santorini contain abundant xenoliths. Most of these deposits are calcareous blocks of laminated‐botryoidal, stromatolite‐like buildups that formed in the shallow waters of the flooded pre‐Minoan caldera; they consist of (i) light laminae, of fibrous aragonite arranged perpendicular to layering, and (ii) dark laminae, with calcified filaments of probable biological origin. These microstructures are absent in the light laminae, suggesting a predominant inorganic precipitation of aragonite on substrates probably colonized by microbes. Internal cavities contain loose skeletal grains (molluscs, ostracods, foraminifera and diatoms) that comprise taxa typical of shallow marine and/or lagoon environments. Most of these forms are typical of warm water environments, although no typical taxa from hydrothermal vents have been observed. Past gasohydrothermal venting is recorded by the occurrence of barite, pyrolusite and pyrite traces. The most striking features of the stable isotopic data set are: (i) an overall wide range in δ13CPDB (0·16 to 12·97‰) with a narrower variation for δ18OPDB (?0·23 to 4·33‰); and (ii) a relatively uniform isotopic composition for the fibrous aragonite (δ13C = 12·40 ± 0·43‰ and δ18O = 2·42 ± 0·77‰, n = 21). The δ13C and δ18O values from molluscs and ostracods display a covariant trend, which reflects a mixing between sea water and a fluid influenced by volcano‐hydrothermal activity. Accordingly, 87Sr/86Sr from the studied carbonates (0·708758 to 0·709011 in fibrous aragonite and 0·708920 to 0·708991 in molluscs) suggests that the aragonite buildups developed in sea water under the influence of a hydrothermal/volcanic source. Significant differences in trace elements have been detected between the fibrous aragonite and modern marine aragonite cements. The caldera water from which the fibrous aragonite crusts formed received an input from a volcano‐hydrothermal system, probably producing diffuse venting of volcanogenic CO2 gas and of a fluid enriched in Ca, Mn and Ba, and depleted in Mg and probably in Sr.  相似文献   

9.
《Sedimentary Geology》2006,183(1-2):51-69
The Chicxulub Sedimentary Basin of the northwestern Yucatan Peninsula, Mexico, which was formed because of the largest identified Phanerozoic bolide impact on Earth, became a site of deposition of dominantly marine carbonate sediments during most of the Cenozoic Era. This is a study of the filling and diagenetic history of this basin and surrounding areas. The study makes use of lithologic, biostratigraphic, petrographic, and geochemical data obtained on core samples from boreholes drilled throughout the northwestern Yucatan Peninsula.The core sample data indicate that: 1) The Chicxulub Sedimentary Basin concentrated the deposition of pelagic and outer-platform sediments during the Paleocene and Eocene, and, in places, during the Early Oligocene, as well, and filled during the Middle Miocene, 2) deeper-water limestone also is present within the Paleocene and Lower Eocene of the proposed Santa Elena Depression, which is located immediately south of the Basin, 3) shallow-water deposits are relatively more abundant outside the Basin and Depression than inside, 4) the autigenic and allogenic silicates from the Paleogene formations are the most abundant inside the Depression, 5) sediment deposition and diagenesis within the Basin also were controlled by impact crater topography, 6) the abundance of the possible features of subaerial exposure increases upward and outward from the center of the Basin, and 7) the formation of replacive low-magnesium calcite and dolomite, dedolomitization, dissolution, and precipitation of vug-filling calcite and dolomite cement have been more common outside the Basin than inside.δ18O in whole-rock (excluding vug-filling) calcite from core samples ranges from − 7.14‰ to + 0.85‰ PDB. δ13C varies from − 6.92‰ to + 3.30‰ PDB. Both stable isotopes correlate inversely with the abundance of subaerial exposure features indicating that freshwater diagenesis has been extensive especially outside and at the edge of the Chicxulub Sedimentary Basin.δ18O and δ13C in whole-rock (excluding vug-filling) dolomite ranges from − 5.54‰ to + 0.87‰ PDB and − 4.63‰ to + 3.38‰ PDB, respectively. Most dolomite samples have negative δ18O and positive δ13C suggesting that replacive dolomitization involved the presence of a fluid dominated by freshwater and/or an anomalously high geothermal gradient.Most dolomite XRD-determined mole percent CaCO3 varies between 51 and 56. Replacive dolomite is larger, more euhedral, and less stoichiometric inside the Chicxulub Sedimentary Basin than outside.  相似文献   

10.
In topographic flat areas, sedimentary settings may vary from one outcrop to another. In these settings, calcite precipitates may yield macroscopically similar columnar features, although they are products of different sedimentary or diagenetic processes. Three columnar calcite crystal fabrics, i.e. rosettes, palisade crusts and macro-columnar crystal fans, have been differentiated near and at the contact between Upper Tournaisian dolomites and limestones along the southern margin of the Brabant-Wales Palaeohigh. Their petrographic characteristics, and geochemical and fluid inclusion data provide information on the (dia)genetic processes involved. Rosettes composed of non-luminescent columnar calcite crystal fans (1–5 cm in diameter) developed on top of one another, forming discrete horizons in repetitive sedimentary cycles. The cycles consist of three horizons: (I) a basal horizon with fragments from the underlying horizon, (II) a micrite/microspar horizon with incipient glaebules, (III) an upper horizon consisting of calcite rosettes, with desiccation features. The petrographical features and δ18O signatures of −10·0 to −5·5‰ and δ13C values of −5·5 to −3·2‰ support either evaporative growth, an evaporative pedogenic origin, or overprinting of marine precipitates. Palisade crusts, composed of a few to 10 mm long non-luminescent calcite crystals, coat palaeokarst cavities. Successive palisade growth-stages occur which are separated by thin laminae of micrite or detrital quartz, displaying a geopetal arrangement. Palisade crusts are interpreted as intra-Mississippian speleothems. This interpretation is supported by their petrographic characteristics and isotopic signature (δ18O = −8·7 to −6·5‰ and δ13C = −4·8 to −2·5‰). Macro-columnar crystals, 1–50 cm long, developed mainly perpendicular to cavity walls and dolomite clasts. Crystal growth stages in the macro-columnar crystals are missing. δ18O values vary between −16·4 and −6·8‰ and δ13C values between −5·2 and −0·9‰. These features possibly support a late diagenetic high temperature precipitation in relation to hydrothermal karstification.  相似文献   

11.
Authigenic calcite and dolomite and biogenic aragonite occur in Holocene pan sediments in a Mediterranean‐type climate on the western coastal plain of South Africa. Sediment was analysed from a Late Pleistocene coastal pan at Yzerfontein and four Holocene inland pans ranging from brackish to hypersaline. The pans are between 0·08 and 0·14 km2 in size. The δ18OPDB values of carbonate minerals in the pan sediments range from ?2·41 to 5·56‰ and indicate precipitation from evaporative waters. Covariance of total organic content and percentage carbonate minerals, and the δ13CPDB values of pan carbonate minerals (?8·85 to ?1·54‰) suggest that organic matter degradation is a significant source of carbonate ions. The precipitation of the carbonate minerals, especially dolomite, appears to be mediated by sulphate‐reducing bacteria in the black sulphidic mud zone found in the brine‐type hypersaline pans. The knobbly, sub‐spherical texture of the carbonate minerals suggests that the precipitation of the carbonate minerals, particularly dolomite, is related to microbial processes. The 87Sr/86Sr ratios of pan carbonate minerals (0·7108 to 0·7116) are slightly higher than modern sea water and indicate a predominantly sea water (marine aerosol) source for calcium (Ca2+) ions with relatively minor amounts of Ca2+ derived from the chemical weathering of bedrock.  相似文献   

12.
Core 2011804‐0010 from easternmost Lancaster Sound provides important insights into deglacial timing and style at the marine margin of the NE Laurentide Ice Sheet (LIS). Spanning 13.2–11.0 cal. ka BP and investigated for ice‐rafted debris (IRD), foraminifera, biogenic silica and total organic carbon, the stratigraphy comprises a lithofacies progression from proximal grounding line and sub‐ice shelf environments to open glaciomarine deposition; a sequence similar to deposits from Antarctic ice shelves. These results are the first marine evidence of a former ice shelf in the eastern Northwest Passage and are consistent with a preceding phase of ice streaming in eastern Lancaster Sound. Initial glacial float‐off and retreat occurred >13.2 cal. ka BP, followed by formation of an extensive deglacial ice shelf during the Younger Dryas, which acted to stabilize the retreating margin of the NE LIS until 12.5 cal. ka BP. IRD analyses of sub‐ice shelf facies indicate initial high input from source areas on northern Baffin Island delivered to Lancaster Sound by a tributary ice stream in Admiralty Inlet. After ice shelf break‐up, Bylot Island became the dominant source area. Foraminifera are dominated by characteristic ice‐proximal glaciomarine benthics (Cassidulina reniforme, Elphidium excavatum f. clavata), complemented by advected Atlantic water (Cassidulina neoteretis, Neogloboquadrina pachyderma) and enhanced current indicators (Lobatula lobatula). The biostratigraphy further supports the ice shelf model, with advection of sparse faunas beneath the ice shelf, followed by increased productivity under open water glaciomarine conditions. The absence of Holocene sediments in the core suggests that the uppermost deposits were removed, most likely due to mass transport resulting from the site's proximity to modern tidewater glacier margins. Collectively, this study presents important new constraints on the deglacial behaviour of the NE Laurentide Ice Sheet, with implications for past ice sheet stability, ice‐rafted sediment delivery, and ice−ocean interactions in this complex archipelago setting.  相似文献   

13.
《Applied Geochemistry》2005,20(1):23-39
Hydrothermal alteration at Los Azufres geothermal field is mostly propylitic with a progressive dehydration with depth and temperature increase. Argillic and advanced argillic zones overlie the propylitic zone owing to the activity of gases in the system. The deepest fluid inclusions (proto-fluid) are liquid-rich with low salinity, with NaCl dominant fluid type and ice melting temperatures (Tmi) near zero (0 °C), and salinities of 0.8 wt% NaCl equivalent. The homogenization temperature (Th)  = 325 ± 5 °C. The boiling zone shows Th = ±300 °C and apparent salinities between 1 and 4.9 wt% NaCl equivalent, implying a vaporization process and a very important participation of non-condensable gases (NCGs), mostly CO2. Positive clathrate melting temperatures (fusion) with Th = 150 °C are observed in the upper part of the geothermal reservoir (from 0 to 700 m depth). These could well be the evidence of a high gas concentration. The current water produced at the geothermal wells is NaCl rich (geothermal brine) and is fully equilibrated with the host rock at temperatures between T = 300 and 340 °C. The hot spring waters are acid-sulfate, indicating that they are derived from meteoric water heated by geothermal steam. The NCGs related to the steam dominant zone are composed mostly of CO2 (80–98% of all the gases). The gases represent between 2 and 9 wt% of the total mass of the fluid of the reservoir.The authors interpret the evolution of this system as deep liquid water boiling when ascending through fractures connected to the surface. Boiling is caused by a drop of pressure, which favors an increase in the steam phase within the brine ascending towards the surface. During this ascent, the fluid becomes steam-dominant in the shallowest zone, and mixes with meteoric water in perched aquifers. Stable isotope compositions (δ18O–δD) of the geothermal brine indicate mixing between meteoric water and a minor magmatic component. The enrichment in δ18O is due to the rock–water interaction at relatively high temperatures. δ13C stable isotope data show a magmatic source with a minor meteoric contribution for CO2. The initial isotopic value δ34SRES = −2.3‰, which implies a magmatic source. More negative values are observed for shallow pyrite and range from δ34S (FeS2) = −4‰ to −4.9‰, indicating boiling. The same fractionation tendencies are observed for fluids in the reservoir from results for δ18O.  相似文献   

14.
The study focuses on the formation of lacustrine dolomite in late Miocene lakes, located at the East Mediterranean margins (Northern Israel). These lakes deposited the sediments of the Bira (Tortonian) and Gesher (Messinian) formations that comprise sequences of dolostone and limestone. Dolostones are bedded, consist of small‐sized (<7 μm), Ca‐rich (52 to 56 mol %) crystals with relatively low ordering degrees, and present evidence for replacement of CaCO3 components. Limestones are comprised of a wackestone to mudstone matrix, freshwater macrofossils and intraclasts (mainly in the Bira Formation). Sodium concentrations and isotope compositions differ between limestones and dolostones: Na = ~100 to 150 ppm; ~1000 to 2000 ppm; δ18O = ?3·8 to ?1·6‰; ?2·0 to +4·3‰; δ13C = ?9·0 to ?3·4‰; ?7·8 to 0‰ (VPDB), respectively. These results indicate a climate‐related sedimentation during the Tortonian and early Messinian. Wet conditions and positive freshwater inflow into the carbonate lake led to calcite precipitation due to intense phytoplankton blooms (limestone formation). Dry conditions and enhanced evaporation led to precipitation of evaporitic CaCO3 in a terminal lake, which caused an increased Mg/Ca ratio in the residual waters and penecontemporaneous dolomitization (dolostone formation). The alternating lithofacies pattern reveals eleven short‐term wet–dry climate‐cycles during the Tortonian and early Messinian. A shift in the environmental conditions under which dolomite formed is indicated by a temporal decrease in δ18O of dolostones and Na content of dolomite crystals. These variations point to decreasing evaporation degrees and/or an increased mixing with meteoric waters towards the late Messinian. A temporal decrease in δ13C of dolostones and limestones and appearance of microbial structures in close association with dolomite suggest that microbial activity had an important role in allowing dolomite formation during the Messinian. Microbial mediation was apparently the main process that enabled local growth of dolomite under wet conditions during the latest Messinian.  相似文献   

15.
A major re‐organization of regional drainages in eastern Tibet and south‐western China took place in the Cenozoic as deformation from the growing Himalayas and Tibetan Plateau affected an increasingly wider area. The effects of these changes on the regional sediment routing systems is not well constrained. This study examines the geochemical and Nd signatures of sedimentary rocks from the Ying‐Qiong and Nanxiong basins on the northern margin of the South China Sea to constrain and identify any significant changes in sediment source. Upper Cretaceous to Lower Eocene sedimentary rocks in the Nanxiong Basin show higher Th/Sc, La/Sc, Th/Cr and Th/Co ratios and lower Eu/Eu* ratios than PAAS (post‐Archaean Australian Shale), which indicates that Palaeozoic sedimentary rocks of the South China Block were the main basin sediment source. In contrast, Oligocene to Pleistocene sedimentary rocks of the Ying‐Qiong Basin show an abrupt change in these trace‐element ratios between 16·3 and 10·4 Ma, indicating a mid‐Miocene shift in provenance. ɛNd values from the Ying‐Qiong Basin (range = −11·1 to −2·1) reinforce this, with pre‐13·8 Ma sedimentary rocks having average ɛNd of −5·6 (range = −2·1 to −7·4), and post‐13·8 Ma sedimentary rocks having average ɛNd of −9·3 (range = −8·7 to −11·1). During the Oligocene, the centre of rifting transferred south and basins on the north margin of the South China Sea experienced rapid subsidence. Further uplift and erosion then exposed Mesozoic and Cenozoic granites that supplied large amounts of granitic detritus, especially to the Ying‐Qiong Basin. Then a change occurred at ca 13 Ma resulting in less input from local sources (i.e. the fault blocks formed by Mesozoic‐Cenozoic tectonics and magmatism) to an increasing contribution of older continental material, mostly from Indochina to the west of the South China Sea.  相似文献   

16.
Lower Cretaceous (Hauterivian) bioclastic sandstone turbidites in the Scapa Member (North Sea Basin) were extensively cemented by low-Mg calcite spars, initially as rim cements and subsequently as concretions. Five petrographically distinct cement stages form a consistent paragenetic sequence across the Scapa Field. The dominant and pervasive second cement stage accounts for the majority of concretions, and is the focus of this study. Stable-isotope characterization of the cement is hampered by the presence of calcitic bioclasts and of later cements in sponge spicule moulds throughout the concretions. Nevertheless, trends from whole-rock data, augmented by cement separates from synlithification fractures, indicate an early calcite δ18O value of+0·5 to -1·5‰ PDB. As such, the calcite probably precipitated from marine pore fluids shortly after turbidite deposition. Carbon isotopes (δ13C=0 to -2‰ PDB) and petrographic data indicate that calcite formed as a consequence of bioclastic aragonite dissolution. Textural integrity of calcitic nannoplankton in the sandstones demonstrates that pore fluids remained at or above calcite saturation, as expected for a mineral-controlled transformation. Electron probe microanalyses demonstrate that early calcite cement contains <2 mol% MgCO3, despite its marine parentage. Production of this cement is ascribed to a combination of an elevated aragonite saturation depth and a lowered marine Mg2+/Ca2+ ratio in early Cretaceous ‘calcite seas’, relative to modern oceans. Scapa cement compositions concur with published models in suggesting that Hauterivian ocean water had a Mg2+/Ca2+ ratio of ≤1. This is also supported by consideration of the spatial distribution of early calcite cement in terms of concretion growth kinetics. In contrast to the dominant early cement, late-stage ferroan, 18O-depleted calcites were sourced outwith the Scapa Member and precipitated after 1–2 km of burial. Our results emphasize that bioclast dissolution and low-Mg calcite cementation in sandstone reservoirs should not automatically be regarded as evidence for uplift and meteoric diagenesis.  相似文献   

17.
Carbonates often accompany lake and lake‐margin deposits in both modern and ancient geological settings. If these carbonates are formed in standing water, their stable isotope values reflect the aquatic chemistry at the time of precipitation and may provide a proxy for determining regional hydrologic conditions. Carbonate rhizoliths and water samples were collected from a playa lake in eastern Nevada. Pilot Valley (～43°N) is a closed‐basin, remnant playa from the Quaternary desiccation of palaeo‐Lake Bonneville. Water is added to the playa margin by free convection of dense brines to the east and forced convection of freshwater off the alluvial fan to the west. Both freshwater and saline springs dot the playa margin at the base of an alluvial fan. Water samples collected from seven springs show a range from ?16 to ?0·2‰ (Vienna Standard Mean Ocean Water), and are consistent with published values. The δ18Ocalcite values from rhizolith samples range from ?18·3 to ?6·7‰ (Vienna Pee Dee Belemnite), and the average is ?12‰ V‐PDB (1 ? σ SD 2‰). With the exception of samples from Little Salt Spring, the range in the δ18Ocalcite values collected from the rhizoliths confirms that they form in equilibrium with ambient water conditions on the playa. The initial geochemical conditions for the spring waters are dictated by local hydrology: freshwater springs emerge in the northern part of the basin to the east of a broad alluvial fan, and more saline springs emerge to the south where the influence of the alluvial fan diminishes. Rhizoliths are only found near the southern saline springs and their δ13Ccalcite values, along with their morphology, indicate that they only form around saltgrass (Distichlis sp.). As the residence time of water on the playa increases, evaporation, temperature change and biological processes alter the aquatic chemistry and initiate calcite precipitation around the plant stems. The range in δ18Ocalcite values from each location reflects environmental controls (e.g. evaporation and temperature change). These rhizoliths faithfully record ambient aquatic conditions during formation (e.g. geochemistry and water depth), but only record a partial annual signal that is constrained by saltgrass growth and the presence of standing water on the playa margin.  相似文献   

18.
This paper presents a case study of the sublacustrine precipitation of hydrothermal silica ± TiO2 in the Ediacaran Mançour Group of the Saghro inlier, Anti‐Atlas, Morocco. Lacustrine carbonates containing stromatolitic mats and bioherms occur in ephemeral ponds developed within the Oued Da'ra caldera. Its syn‐eruptive infill consists of pyroclastites, ashflow tuffs, and subsidiary lava flows and sills, whereas inter‐eruptive deposition is mainly represented by slope‐related debris‐flow breccias and landslides, alluvial fans and fluvial channels. Carbonate production took place in a mosaic of differentially subsiding, fault‐bounded intra‐caldera blocks controlled by episodic collapse‐induced drowning, pyroclastic blanketing and migration of alluvial/fluvial environments. After microbial carbonate production, the carbonates recorded several early‐diagenetic processes, punctuated by polyphase fissuring (controlling secondary permeability) locally linked to hydrothermal influx. Three generations of carbonate cements are recognisable: (i) fibrous, botryoidal and blocky/drusy mosaics of calcite; (ii) idiotopic mosaics of dolomite caused by flushing of hypersaline Mg‐rich brines; and (iii) euhedral to drusy calcite via dedolomitization. The δ13C and δ18O values from carbonate cements broadly become successively isotopically lighter, as a result of meteoric and hydrothermal influence, and were probably overprinted by the Panafrican‐3 phase that affected the top of the Mançour Group. Two mechanisms of silicification are involved: (i) early‐diagenetic occlusion of interparticle pores at the sediment/water interface of pyroclastic substrates and reefal core and flanks; and (ii) hydrothermal precipitation of silica ± TiO2 lining fissures and vuggy porosity encased in the host rock. Silica conduits cross‐cutting lacustrine mats and bioherms exhibit high potential of preservation in collapsed volcanic calderas. Primary fluid inclusions of hydrothermal silica contain brine relics with NaCl/CaCl2 ratios of 2·1 to 4·4, representing minimum entrapment temperatures of about 142 to 204°C, and abiotic hydrocarbons (heavy alkanes) related to serpentinization of the volcanic and volcanosedimentary basement of the Oued Dar'a caldera.  相似文献   

19.
The surface sediments of two mud mounds (“Mound 11” and “Mound 12”) offshore southwest Costa Rica contain abundant authigenic carbonate concretions dominated by high-Mg calcite (14–20 mol-% MgCO3). Pore fluid geochemical profiles (sulfate, sulfide, methane, alkalinity, Ca and Mg) indicate recent carbonate precipitation within the zone of anaerobic oxidation of methane (AOM) at variable depths. The current location of the authigenic carbonate concretions is, however, not related to the present location of the AOM zone, suggesting mineral precipitation under past geochemical conditions as well as changes in the flow rates of upward migrating fluids. Stable oxygen and carbon isotope analysis of authigenic carbonate concretions yielded δ18Ocarbonate values ranging between 34.0 and 37.7 ‰ Vienna standard mean ocean water (VSMOW) and δ13Ccarbonate values from ?52.2 to ?14.2 ‰ Vienna Pee Dee belemnite (VPDB). Assuming that no temperature changes occurred during mineral formation, the authigenic carbonate concretions have been formed at in situ temperature of 4–5 °C. The δ18Ocarbonate values suggest mineral formation from seawater-derived pore fluid (δ18Oporefluid = 0 ‰ VSMOW) for Mound 12 carbonate concretions but also the presence of an emanating diagenetic fluid (δ18Oporefluid ≈5 ‰) in Mound 11. A positive correlation between δ13Ccarbonate and δ18Ocarbonate is observed, indicating the admixing of two different sources of dissolved carbon and oxygen in the sediments of the two mounds. The carbon of these sources are (1) marine bicarbonate (δ13Cporefluid ≈0 ‰) and (2) bicarbonate which formed during the AOM (δ13Cporefluid ≈?70 ‰). Furthermore, the δ18Oporefluid composition, with values up to +4.7 ‰ Vienna standard mean ocean water (VSMOW), is interpreted to be affected by the presence of emanating, freshened and boron-enriched fluids. Earlier, it has been shown that the origin of 18O-enriched fluids are deep diagenetic processes as it was indicated by the presence of methane with thermogenic signature (δ13CCH4 = ?38 ‰). A combination of present geochemical data with geophysical observations indicates that Mounds 11 and 12 represent a single fluid system interconnected by deep-seated fault(s).  相似文献   

20.
ABSTRACT Gravity cores of Holocene sediments from a shallow ephemeral lake in the Coorong region (Pellet Lake, southeastern coastal Australia) show a mineral assemblage and sequence particular to its hydrology. The mineralogical sequence above an initial dolomitic siliciclastic sand reflects conditions of increasing salinity in the lower portions of the core (i.e. organic-rich aragonite to magnesite + hydromagnesite + aragonite) followed by a relative decrease in salinity (i.e. magnesite + aragonite + hydromagnesite to aragonite + hydromagnesite) in the upper portions of the core. This sequence is capped by ? 0.4 m of micritic dolomite and minor amounts of hydromagnesite, with the relative abundance of dolomite increasing upwards. Three stratigraphically and spatially distinct dolomite units (upper, lower and margin) are recognized using stable carbon and oxygen isotope data, unit cell calculations and MgCO3 mole per cent data of the dolomite. Detailed X-ray diffraction (XRD) analyses of samples with more than 80% dolomite shows that the dolomite is ordered. Average unit cell parameters, calculated from the XRD patterns, indicate that the upper dolomite unit has crystal lattices expanded in the co direction (co= 16.09 Å) relative to ideal dolomite (co= 16.02 Å) and contracted in the ao direction (ao= 4.796 Å) relative to ideal dolomite (ao= 4.812 Å). The mol fraction of MgCO3 in the upper dolomite shows up to 4.0 ±M 2.0 mole per cent excess Mg in the dolomite crystal lattice (calculated from XRD). This unusual dolomite crystal chemistry is probably generated by rapid precipitation from solutions which have greatly elevated Mg/Ca ratios. Transmission electron microscopy reveals that the upper dolomite has a heterogeneous microstructure which also suggests rapid precipitation from solution. The modulated microstructure found in calcium-rich dolomite is completely lacking. Dolomite ordering reflections are present in electron diffraction patterns, but are weak. Stable oxygen and carbon isotope values of the upper dolomite are tightly grouped (ave. δ18O ～+ 7.55%o, δ13C ～+ 4.10%o), yet show three upward-lightening oxygen cycles. The oxygen cycles correlate with three upward decreases in the calculated Mg content of the dolomite zone. These cycles may indicate the increased importance of rain-water dilution of the brine at times when the water in the lake was at its shallowest levels. Analyses of the lower dolomite and the margin dolomite suggest that these units precipitated more slowly from less evaporitic brines than the upper dolomite unit. The lower dolomite is close to stoichiometric, has less evaporitic stable isotope values than the upper dolomite, and has only a slightly expanded co-axis. The margin dolomite is Ca-rich, has a more homogeneous microstructure, and has expanded ao and co axes. The abundance of relatively soluble Mg-bearing phases, such as hydromagnesite and magnesite, may supply additional magnesium for the dolomitization of aragonite and calcite during subsequent diagenesis and burial of the sediment. This process may leave a finely laminated dolomicrite deposit which retains little, if any, evidence of evaporite minerals.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号