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1.
《Applied Geochemistry》1994,9(6):657-675
As part of the Géologie Profonde de la France [GPF (Deep Geology of France)] Programme investigating the passive margin of the Southeast Basin of France, studies are being made on the possibility of modelling mass transfer. In the summer of 1990, when the first hole in the area (Balazuc-1) was being drilled along a basement-rooted fault, chemical monitoring of the drilling fluids (WELCOM) enabled the composition of the interstitial fluids contained within the intersected rocks to be reconstructed. The computations were compared to on-core leaching carried out during the drilling, following which the WELCOM results were calibrated. The interstitial fluids from the drilled formations show very contrasted compositions. From the top to the bottom of the hole it has been possible to distinguish: diagenetically evolved seawater within the Hettangian limestone, modified continental fluids within the upper part of the Triassic sandstone reservoirs, and evaporated seawater within the Middle Triassic evaporites. Several zones of intensive fluid circulation are also indicated by: dolomitization of the basal Hettangian limestone, circulation of fluids expelled from the evaporites within the upper part of Triassic sandstone reservoirs, and continental-derived hydrothermal fluid flow within the Lower Triassic sandstone reservoir and Carboniferous silty shale. The results show that chemical logging of drilling fluids can provide valuable data concerning interstitial fluids where other techniques are not available. 相似文献
2.
The International Association of Hydrogeologists (IAH): reflecting on 60 years of contributions to groundwater science and water management 总被引：2，自引：0，他引：2
The 60th anniversary of the founding of the International Association of Hydrogeologists (IAH) is an important milestone that allows pause for reflection on how the association has evolved over the years and the contributions it has made to groundwater science and water management. IAH was founded in 1956 at the 20th International Geological Congress and developed rapidly during the 1980s and 1990s in response to a growing global interest in groundwater mapping and in sound approaches to resource protection and sustainable aquifer management. Incorporated in 2000, IAH has now secured its position as the world’s leading international association specialising in groundwater with over 4,100 members in 131 countries. Much credit for this success must go to members, past and present, whose individual efforts and collaboration with sister institutions are documented here. These members have shaped the association’s goals and contributed selflessly to its scientific programmes, publications and educational and charitable activities. Looking ahead to the next 60 years, it is essential that IAH does not rest on past achievements but listens and adjusts to the needs of members while continuing to pursue its mission of furthering the understanding, wise use and protection of groundwater resources throughout the world. 相似文献
3.
H. Z. Abidin R. J. Davies M. A. Kusuma H. Andreas T. Deguchi 《Environmental Geology》2009,57(4):833-844
Global positioning system (GPS) and satellite-based InSAR (Interferometric Synthetic Aperture Radar) measurements of the subsidence
and uplift of a populated area of Sidoarjo, East Java are due to the eruption of the Lusi mud volcano (2006–present). These
data are the first direct quantitative measurements of deformation due to the growth of a mud volcano edifice. The GPS data
were recorded over periods of a few hours to several months and show that between June 2006 and September 2007, the earth’s
surface has been subsiding at rates of 0.1–4 cm/day. Maximum rates of subsidence occurred in an area 300–400 m to the northwest
of the main mud volcano vent. Horizontal displacements were 0.03–0.9 cm/day and were also towards this area. In general uplifts
of up to 0.09 cm/day were recorded in areas outside of the edifice. Changes in elevation measured using satellite imagery
(InSAR technique) provide regional datasets of subsidence and uplift. They confirm that during the first year a roughly circular
area was undergoing sag-like subsidence centered to the northwest of the main vent and that uplift was occurring 3–4 months
after the initiation of the eruption due to the movement Watukosek fault system. Subsidence occurred due to the weight of
mud and man-made dams and the collapse of the overburden due to removal of mud from the subsurface. Assuming constant rates
of subsidence of 4 cm/day, then in the centre of the edifice there would be up to 44 m of subsidence in 3 years, and up to
16 m in 10 years. The mud volcano is now in a self-organizing state with new fluid conduits forming as a result of the collapse.
An erratum to this article can be found at 相似文献
4.
Mauro F. La Russa Germana Barone Cristina M. Belfiore Paolo Mazzoleni Antonino Pezzino 《Environmental Earth Sciences》2011,62(6):1263-1272
Noto is an important Baroque urban center in south-eastern Sicily, which was completely reconstructed after the severe earthquake
of 1693. Most of its monuments and historic buildings were built in Pietra di Noto stone, a pale cream calcarenite, quarried
in outcrops located near the city. This stone, still currently used as building material, is undergoing many forms of alteration
and degradation, which cause significant damage to monuments. In this study, three commercial protective products were tested
on some Noto calcarenite samples from quarries, with the aim of assessing their protective effectiveness. In particular, petrographic
analyses by optical microscopy were carried out for textural characterization of the stone materials. Capillary water absorption,
porosimetric and colorimetric procedures, UV radiation and salt crystallization aging tests were performed to better evaluate
interactions between protective products and substrate. 相似文献
5.
Victoria E. Hamilton 《Chemie der Erde / Geochemistry》2010,70(1):7-33
The reststrahlen features in thermal infrared, or vibrational, spectra of Mg-Fe olivines ((Mg,Fe)2SiO4) exhibit trends in position, strength, and number of features that are diagnostic of the relative proportions of the Mg and Fe cations in the minerals. Although band positions move to lower wavenumbers (longer wavelengths) across the forsterite–fayalite compositional binary in a generally linear manner, specific feature shifts in transmittance data are described best by two linear fits with a break in slope near Fo70. The break in slope may be accompanied by an offset as well; both traits are attributed to structural changes in olivine brought about by distortion of the crystal lattice by Fe. Reflectance and emissivity spectra exhibit similar trends in band position with composition, and all three types of data demonstrate that some olivine band strengths change across the Mg–Fe solid solution series and also are diagnostic of composition. Olivines have been identified in a wide array of thermal infrared spectra of planetary materials and have been interpreted as being present on the surfaces of Mercury, the Moon, Mars, and a number of asteroids based on the analysis of thermal infrared spectra. New linear least squares models of the emissivity spectra of olivine-bearing Martian meteorites enable a preliminary estimation of the accuracy with which quantitative estimates of olivine abundance and solid solution composition can be derived from the spectra of mixtures. 相似文献
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The adsorption of two model siderophores, desferrioxamine B (DFOB) and aerobactin, to lepidocrocite (γ-FeOOH) was investigated by attenuated total reflection infrared spectroscopy (ATR-FTIR). The adsorption of DFOB was investigated between pH 4.0 and 10.6. The spectra of adsorbed DFOB indicated that two to three hydroxamic acid groups of adsorbed DFOB were deprotonated in the pH range 4.0-8.2. Deprotonation of hydroxamic acid groups of adsorbed DFOB at pH values well below the first acid dissociation constant of solution DFOB species (pKa = 8.3) and well below the point of zero charge of lepidocrocite (pHPZC = 7.4) suggested that the surface speciation at the lower end of this pH range (pH 4) is dominated by a surface DFOB species with inner-sphere coordination of two to three hydroxamic acids groups to the surface. Maximum adsorption of DFOB occurred at approximately pH 8.6, close to the first pKa value of the hydroxamic acid groups, and decreased at lower and higher pH values.The spectra of adsorbed aerobactin in the pH range 3-9 indicated at least three different surface species. Due to the small spectral contributions of the hydroxamic acid groups of aerobactin, the interactions of these functional groups with the surface could not be resolved. At high pH, the spectral similarity of adsorbed aerobactin with free aerobactin deprotonated at the carboxylic acid groups indicated outer-sphere complexation of the carboxylate groups. With decreasing pH, a significant peak shift of the asymmetric carboxylate stretch vibration was observed. This finding suggested that the (lateral) carboxylic acid groups are coordinated to the surface either as inner-sphere complexes or as outer-sphere complexes that are strongly stabilized at the surface by hydrogen bonding at low pH. 相似文献
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9.
At four sites in Turkey and Armenia the physico-chemical properties of thermal and mineral waters were monitored continuously
during the Izmit and Düzce earthquakes that occurred along the North Anatolian fault in August and November 1999. The epicentral
distances between the moment magnitude (Mw) 7.6 Izmit earthquake and the monitoring locations were 313, 488, 1,161, and 1,395 km. At the most distant site, the specific
electrical conductivity of mineral water from a flowing artesian well dropped co-seismically and postseismically by 7%. No
changes were observed at the other sites, although the estimated earthquake strains and peak ground accelerations are much
higher. A similar pattern was observed after the Düzce earthquake, which happened three months after the Izmit event. The
response of a hydrogeological system seems to depend on the site characteristics rather than on the nature of the earthquake.
A hydrogeological model for the sensitive observation site farthest from the Izmit earthquake explains the observations in
terms of a changed mixing ratio between two fluid components. Passing seismic waves may trigger a local pore-pressure increase
according to the mechanism of advective overpressure. The preconditions for this mechanism, free gas bubbles in the aquifer
in combination with a trap for rising bubbles, is probably not fulfilled by the other groundwater systems.
Electronic Publication 相似文献
10.
《Geoforum》2013
This article critically investigates recent water governance shifts, particularly constitutional changes implemented in several Latin American countries that highlight a ‘right to water’ as well as recent efforts that invoke such a right in conjunction with bans on private water provision (e.g. Uruguay, Ecuador, and Bolivia). Drawing on legal research, document review, and interviews, the article investigates the historical, political and discursive scaffolding of these constitutional changes in several case study contexts, including attention to implementation issues and ongoing challenges following the reforms. Placing these shifts within the broader context of neoliberalization of water governance of the past several decades, the analysis attends to both the specific historical–contextual formations that are important to understand the constitutional reforms, as well as the ways these changes might be usefully understood as connected to broader political and discursive shifts and movements. Highlighting similarities and differences across the cases allows us to make conceptual contributions to debates on variegation of neoliberalized natures, as well as to discussions of alternatives to neoliberalism and postneoliberalism. We argue that although many of these reforms are partial, and not wholly resistant to neoliberalism, they are nonetheless significant for politics and debates related to ‘alternatives.’ Apart from resisting particular aspects of earlier neoliberal reforms, they are also important to stake new discursive and policy terrain on alternative priorities and uses of water. Further, the reforms also offer points of resistance to the influence of international financial institutions, or of transnational corporations. 相似文献
11.
《矿物学报》2013,(Z1)
China has accumulated massive fine grained copper mine tailings stocks because of the past mining activities in this area. The tailings contain a variety of heavy metals, and the mass percent of Cu, which is one of the main contaminants in tailings, is up to 0.2601% (analysis by XRF). The Cu can pollute soil and groundwater by rain leaching in the form of Cu(Ⅱ), furthermore ,the fine grained copper-ore-tailings can contaminant larger area by wind for its small granularity ( < 74 μm). The main cause of weathering of mine tailings is due to oxidative dissolution of sulfides. Microorganisms, such as Acidithiobacillus ferrooxidans, play an important role in weathering. These bacteria attach to exposed to mineral surfaces by excreting extracellular polymers and oxidize the sulfide mineral. Some of these bacteria also oxidize Fe2+ to Fe3+ which can chemically oxidize sulfide minerals. These reactions produce voluminous quantities of acid mine drainage and heavy metals which are harmful to the environment and human healthy. This study aims at finding the weathering effects of A. ferrooxidans to Cu(II) pollution of fine grained copper mine tailings, and our experiment applied indigenous A. ferrooxidans FJ-01 to leach the tailings. The optimum test parameters were obtained using shaking flask experiment and SEM observation under the following experimental conditions: 39 days residence time, pulp density 1%-15% (1%, 5% and 15%), 30℃, 120 rpm, pH between 1-3 and redox potential between 400-650 mV. The test results show that the leaching rate of Cu reached 43.1% when the pulp density was 1% after 33 days and kept invariant till the end of the test. In addition, the leaching rate of Cu will decrease as the increase of pulp density, and the maximum rate of 15% pulp density was only 12.5%. From the SEM, it can be seen that the fine grain of tailings flocculated to conglobation under the action of bacterial leaching. 相似文献
12.
《Sedimentary Geology》2004,163(3-4):175-210
The Mio–Pliocene in Western Europe is a period of major climatic and tectonic change with important topographic consequences. The aim of this paper is to reconstruct these topographic changes (based on sedimentological analysis and sequence stratigraphy) for the Armorican Massif (western France) and to discuss their significance. The Mio–Pliocene sands of the Armorican Massif (Red Sands) are mainly preserved in paleovalleys and are characterized by extensive fluvial sheetflood deposits with low-preservation and by-pass facies. This sedimentological study shows that the Red Sands correspond to three main sedimentary environments: fluvial (alluvial fan, low-sinuosity rivers and braided rivers), estuarine and some rare open marine deposits (marine bioclastic sands: “faluns” of French authors). Two orders of sequences have been correlated across Brittany with one or two minor A/S cycles comprised within the retrogradational trend of a major cycle. The unconformity at the base of the lower cycle is more marked than the unconformity observed at the top, which corresponds to a re-incision of the paleovalley network. A comparison of the results of the sequence stratigraphy analysis with eustatic variations and tectonic events during the Mio–Pliocene allows (1) to discuss their influence on the evolution of the Armorican Massif and (2) to compare the stratigraphic record with other west-European basins. The unconformity observed at the base of the first minor cycle may be attributed to Serravallian–Tortonian tectonic activity and/or eustatic fall, and the unconformity of the second minor cycle may be attributed to Late Tortonian–Early Messinian tectonic activity. The earlier unconformity is coeval with the development of a “smooth” paleovalley network compared to the jagged present-day relief. A single episode of Mio–Pliocene deformation recorded in Brittany may be dated as Zanclean, thus explaining the lack of the maximum flooding surface except in isolated areas. From this study, five paleogeographic maps were drawn up also indicating paleocurrent directions: three maps for the lower cycle (Tortonian retrogradational trend, Late Tortonian to Early Messinian maximum flooding surface and Messinian progradational trend) and two for the upper cycle (Pliocene retrogradational trend and Piacenzian maximum flooding surface). These maps show (1) the variations of paleocurrent directions during the Mio–Pliocene, (2) the extent of estuarine environments during the maximum flooding intervals and (3) a paleodrainage watershed oriented NNW–SSE following the regional Quessoy/Nort-sur-Erdre Fault during the retrogradational trend of the upper cycle and possibly during the progradational trend of the lower cycle. The present-day morphology of the Armorican Massif is characterized by (1) incised valleys and jagged topography, in contrast with the “smooth” morphology described for Mio–Pliocene times and (2) a main East–West drainage watershed, located to the north, separating rivers flowing towards the English Channel from rivers flowing towards the Atlantic Ocean. The Mio–Pliocene/Pleistocene paleotopographic changes seem to be controlled by climatic effects. These can be related to the change in runoff associated with warmer and wetter conditions during the Mio–Pliocene, which control the river discharge and lead to the development of extensive fluvial sheetflood deposits. Tectonic or eustatic factors exert a second-order control. 相似文献
13.
The rhyolitic Plinian eruption of the Chilean Chaitén Volcano, initiated on May 2, 2008, suddenly introduced abundant pyroclastic sediments in the Blanco River catchment area, which experienced important modifications. Before May 2, the river was characterised by gravelly and moderate to low-sinuosity channels crossing a vegetated and locally urbanised (Chaitén City) floodplain. This river, limited by steep and densely forested highlands, was connected with the Pacific Ocean via a tidally-influenced delta plain. After heavy rains in May 11–20, the river discharge increased and triggered several responses including logjam formation and breakage, crevassing, avulsion (and channel abandonment), changes in the pattern and dimensions of channels, and construction of a new delta plain area. In this context, the goals of this contribution were: i) to document the sedimentological processes within a detailed geomorphic framework and ii) to understand the influence of logjams on fluvial dynamics. Upstream of the logjam zone, the deposits are mostly composed of ash and lapilli with abundant palaeovolcanic (epiclastic) sediments, which were produced by dilute currents and debris flows. Downstream of the logjam zone, deposits are composed by ash and lapilli, both pumice-rich and lacking important participation of older (epiclastic) sediments. The abandoned and filled palaeochannel, and the proximal part of crevasse splays experienced transient dilute flows with variable sediment concentration and, subordinately, hyperconcentrated flows. The distal sectors of crevasse splays mostly record settling from suspension. At the delta plain, tephra transported by the Blanco River was mixed with older sediments by tide and wave action (dilute flows). We conclude that immediately after eruption, both geomorphic and sedimentary processes of the river were mainly controlled by a combination of high availability of incoherent pyroclastic sediments on steep slopes, abundant rains, large logs that jammed the river and huge areas of devastated forest. Logjams played an important role in the river response to the volcanic eruption; they were responsible of the marked compositional change recorded upstream and downstream of the logjam zone and its breakage resulted in downstream flooding and avulsion. The likelihood of formation of logjams in rivers draining forested volcanic areas should be considered in the evaluation of volcanic hazards related to Plinian eruptions. 相似文献
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17.
《Geoforum》2015
This article examines the dynamics of double exposure, vulnerability, and resistance to neoliberal globalization and environmental change in the Chilean agricultural region of Biobio. By using climatic models and secondary Agricultural Census data from 1997 and 2007, we assess how Chilean neoliberal reforms have, since 1974, facilitated land use changes and forestry investments. We demonstrate that policy changes which incentivize forestry investments have reduced cultivated agricultural lands and native forest, and concentrated land in the hands of global agribusiness corporations. Compounding these issues, Biobio shows a climatic trend towards aridity coupled with an increasing demand for irrigation. Analyzing these conditions, we argue that the neoliberal globalization of regional agriculture under the context of climatic changes has produced a regional space of increasing vulnerabilities and uneven geographical development in Biobio. We particularly demonstrate that the Chilean mode of agricultural neoliberalization has been conducive to land dispossession—to the detriment of traditional agriculture —and has homogenized the biophysical landscape, replacing traditional crops and native forests with exotic species like pines and eucalyptus. We also examine how local producers are using resistance movements to cope with and contest neoliberal environmental changes. We conclude by evaluating the implications of these spaces of agricultural vulnerabilities and local resistances in the context of uneven geographical development at a regional and global scale. 相似文献
18.
Natural Hazards - The dual Ahar–Varzaghan earthquakes occurred on August 11, 2012, at 16:53 (Iran standard time) in East Azerbaijan province of Iran. The two quakes measured 6.3 and 6.4 on... 相似文献
19.
Maria Eugenia Varela 《Geochimica et cosmochimica acta》2008,72(13):3170-3183
Several pieces of the Allende CV3 chondrite were heated up to different final temperatures (1100, 1250, 1450 °C) with the aim to study glassy and glass-bearing inclusions in olivines as well as the glass mesostasis of chondrules and aggregates. The experiments were performed in a Pt-Pt90Rh10 heating stage at 1 bar pressure. The oxygen fugacity is estimated to have been between 10−9 and 10−10 atm at 1200 °C. The variation of the chemical composition of the heated glasses gives information concerning the behavior of the incompatible elements (with respect to the host) Al, Ca and Na. The chemical variation in the heated mesostasis glass shows that Ca exchange between the gas and condensed phases at sub-solidus temperatures can occur in a short time. Laboratory heating experiments show that glass inclusions will behave as closed systems and therefore preserved the alkalis they acquired. On the other hand, the mesostasis glass can loose them when heated to temperatures higher than 1100 °C. Evidently, the presence of Na-rich glasses, in chondrules and aggregates available to us, indicate that if there was a thermal process that did affect them, it must have been a low temperature one. 相似文献
20.
M. V. Mints 《Doklady Earth Sciences》2018,480(1):555-558
The model of supercontinent cycles is revisited on the basis of reevaluation of existing ideas on the geodynamics and tectonics of granulite gneiss belts and areals. Granulite-gneiss belts and areals of a regional scale correspond to mantle–plume (superplume) activity and form the major components of intracontinental orogens. The evolution of geodynamic settings of the Earth’s crust origin can be imagined as a “spiral sequence”: (1) interaction of mantle plumes and “embryonic” microplate tectonics during the Paleo- Mesoarchean (~3.80–2.75 Ga); (2) plume-tectonics and local plume-driven plate-tectonics within supercontinent during Neoarchean and Proterozoic (~2.75–0.85 Ga); (3) plate tectonics in the Phanerozoic along with a reduced role of mantle plumes starting from ~0.85 Ga. 相似文献